Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
  • C08J5/18—Manufacture of films or sheets
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
  • D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
  • D21H11/18—Highly hydrated, swollen or fibrillatable fibres
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
  • D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
  • D21H11/20—Chemically or biochemically modified fibres
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/005—Microorganisms or enzymes
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
  • D21H17/03—Non-macromolecular organic compounds
  • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H19/00—Coated paper; Coating material
  • D21H19/10—Coatings without pigments
  • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
  • D21H19/34—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H19/00—Coated paper; Coating material
  • D21H19/36—Coatings with pigments
  • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
  • D21H19/52—Cellulose; Derivatives thereof
• • C—CHEMISTRY; METALLURGY
  • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
  • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
  • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
  • C12N9/14—Hydrolases (3)
  • C12N9/24—Hydrolases (3) acting on glycosyl compounds (3.2)
• • C—CHEMISTRY; METALLURGY
  • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
  • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
  • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
  • C12N9/14—Hydrolases (3)
  • C12N9/24—Hydrolases (3) acting on glycosyl compounds (3.2)
  • C12N9/2402—Hydrolases (3) acting on glycosyl compounds (3.2) hydrolysing O- and S- glycosyl compounds (3.2.1)
  • C12N9/2405—Glucanases
  • C12N9/2434—Glucanases acting on beta-1,4-glucosidic bonds
  • C12N9/2437—Cellulases (3.2.1.4; 3.2.1.74; 3.2.1.91; 3.2.1.150)
• • C—CHEMISTRY; METALLURGY
  • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
  • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
  • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
  • C12N9/14—Hydrolases (3)
  • C12N9/24—Hydrolases (3) acting on glycosyl compounds (3.2)
  • C12N9/2402—Hydrolases (3) acting on glycosyl compounds (3.2) hydrolysing O- and S- glycosyl compounds (3.2.1)
  • C12N9/2477—Hemicellulases not provided in a preceding group
  • C12N9/248—Xylanases
• • C—CHEMISTRY; METALLURGY
  • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
  • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
  • C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
  • C12N9/14—Hydrolases (3)
  • C12N9/24—Hydrolases (3) acting on glycosyl compounds (3.2)
  • C12N9/2402—Hydrolases (3) acting on glycosyl compounds (3.2) hydrolysing O- and S- glycosyl compounds (3.2.1)
  • C12N9/2477—Hemicellulases not provided in a preceding group
  • C12N9/2488—Mannanases

Definitions

• the present invention relates to a barrier film having a good and stable oxygen transmission rate (OTR) even at high relative humidity's (RH). More particularly, the present invention relates to a method of manufacturing such a film and a film produced.
• OTR oxygen transmission rate
• MFC microfibrillated cellulose
• Aulin et al. Oxygen and oil barrier properties of microfibrillated cellulose films and coatings, Cellulose (2010) 17:559-574, Lavoine et al., Microfibrillated cellulose - Its barrier properties and applications in cellulosic materials: A review, Carbohydrate polymers 90 (2012) 735-764, Kumar et al., Comparison of nano- and microfibrillated cellulose films, Cellulose (2014) 21 :3443-3456), whereas the gas barrier properties are very dependent on the moisture or the relative humidity in the surrounding environment. Therefore, it is quite common that MFC films have to be coated with a polymer film to prevent moisture or water vapor to swell and disrupt the MFC film.
• EP2554589A1 where MFC dispersion was modified with silane coupling agent.
• the EP2551 104A1 teaches the use of MFC and polyvinyl alcohol (PVOH) and/or polyuronic acid with improved barrier properties at higher relative humidity (RH).
• Another solution is to coat the film with a film having good barrier properties at high RH and/or low water vapor transmission rate.
• the JP2000303386A discloses e.g. latex coated on MFC film, while
• MFC films have good barrier properties. It is especially challenge to dewater the film at high production speeds due to the characteristics properties of microfibrillated cellulose.
• MFC films are used as barriers, it is crucial that the films don't have any pinholes or other defects that negatively would affect the barrier properties.
• the surface of the MFC film is smooth making the dewatering even more challenging since wire markings or other surface defects will negatively affect the barrier properties of the film.
• the present invention relates to a method for manufacturing a film wherein the method comprises the steps of; providing a suspension comprising a microfibrillated cellulose, adding an enzyme to the suspension, mixing the enzyme with the suspension to form a mixture, applying said mixture to a wire to form a fibrous web and drying said web to form said film.
• the enzyme is preferably an enzyme decomposing cellulose and/or hemicellulose such as cellulase, xylanase and/or mannanase.
• the enzyme may be cellulase with an activity above 20 0000 CMU/g and/or xylanase with an activity above 20 0000 nkat/ml.
• the microfibrillated cellulose is preferably native, i.e. it is a chemically unmodified microfibrillated cellulose.
• the temperature of the suspension when the enzyme is added is preferably between 30-70°C. By increasing the temperature of the suspension the microfibrillated cellulose material is more accessible for the enzyme.
• the mixture is preferably stored for a period of at least 5 minutes, preferably at least 15 minutes or even more preferably at least 30 minutes before being applied to said wire.
• the storage time needs to be sufficient in order to make sure that the enzyme has enough time to decompose the material needed.
• the dry content of the mixture is preferably between 0.01 -0.5% by weight.
• the dry content before addition of the enzymes needs to low enough so the enzymes can be evenly mixed in the suspension.
• the method may further comprise the step of mechanical treating the suspension comprising microfibrillated cellulose prior to the addition of the enzyme. In this way the MFC will be more reactive to the enzymatic treatment.
• the wire is preferably part of a paper or board machine making it possible to produce the film at high production speeds.
• the fibrous web is preferably dewatered on the wire.
• the dewatering rate on the wire is improved with the present invention.
• the production speed on the wire is preferably between 150-1500 m/min. It has been found possible to be able to produce a film comprising MFC and even very high amounts of MFC at a high production speed.
• the dry content of the fibrous web before drying is preferably between
• the present invention it is possible to increase the dry content before drying due to the improved dewatering properties of the MFC used.
• the demand of the subsequent drying step is reduced and the drying can then be done at a lower energy demand or at shorter time.
• the drying is preferably done at a temperature between 100-150°C.
• the mixture may further comprise any one of a starch, carboxymethyl cellulose, a filler, retention chemicals, flocculation additives, deflocculating additives, dry strength additives, wet strength additives, softeners, surface active agents or mixtures thereof. It may be possible to add additives that will improve different properties of the mixture and/or the produced film. It has been found that the retention of chemicals in the web or film is improved. Therefore, the amount of chemicals can be reduced without reducing their effects.
• the film preferably has an oxygen transmission rate in the range of from 0.1 to 300 cc/m 2 /24h according to ASTM D-3985, at a relative humidity of 50 % at 23 ° C and/or at a relative humidity of 85% at 38 ° C.
• the suspension preferably comprises between 50-100 wt-% of microfibrillated cellulose by total amount of organic material in the
• the present invention further relates to a film produced according to the method described above wherein said film comprises microfibrillated cellulose and has an oxygen transmission rate in the range of from 0.1 to 300 cc/m 2 /24h measured according to ASTM D-3985, at a relative humidity of 50 % at 23 ° C and/or at a relative humidity of 85% at 38 ° C.
• said film comprises microfibrillated cellulose and has an oxygen transmission rate in the range of from 0.1 to 300 cc/m 2 /24h measured according to ASTM D-3985, at a relative humidity of 50 % at 23 ° C and/or at a relative humidity of 85% at 38 ° C.
• the film preferably has a basis weight of less than 100 g/m 2 , preferably between 10-100 g/m 2 . Since the dewatering properties of the film is improved it is possible to produce a film with higher basis weight at good production speed.
• the film is preferably a multilayer film comprising more than one layer.
• the film preferably comprises between 50-100 wt-% of microfibrillated cellulose by total amount of organic material of the film.
• the method according to the present invention relates to a method for manufacturing a film wherein the method comprises the steps of: providing a suspension comprising a microfibrillated cellulose, adding an enzyme to the suspension, mixing the enzyme with the suspension to form a mixture, applying said mixture to a wire to form a fibrous web and drying said web to form said film.
• an enzyme to the suspension comprising microfibrillated cellulose it was surprisingly found that the dewatering of the formed fibrous web was improved. Even more surprising was that the barrier properties of the formed film was remained or even improved, even at high humidity. The oxygen barrier properties of the film was shown to improve. Also, the grease and aroma barrier properties of the film was improved.
• a cellulose decomposing enzyme to the suspension comprising microfibrillated cellulose the enzyme will decompose or "eat" the
• microfibrillated cellulose The enzyme will attach to accessible surface areas of the fibrils and decompose it to even smaller fibrils or dissolve it by decomposing the MFC to mono- oligo- or polysaccharides. It was found that the smallest MFC materials have the largest number of accessible surface areas, leading to that the enzymes attaches and decomposes the finer material to a larger extent compared to the coarser MFC material present.
• the decomposed or dissolved fine material will be removed, i.e. the retention of the finest material is reduced, leading to that the dewatering of the produced MFC film is strongly improved. Due to the removal of the finer material the barrier properties of the film were expected to be deteriorated.
• the barrier properties at high humidity of the film were improved.
• the enzymatic treatment of the MFC material will affect the moisture absorption properties of the film.
• the enzyme will decompose the MFC material in such a way that the moisture absorption properties of the material is reduced leading to that the MFC film will be more resistant against high humidity.
• Another theory to the improved barrier and dewatering properties of the film is that the retention of additives added to the mixture is improved.
• the presence of e.g. retention chemicals or strength chemicals is increased which also leads to improved dewatering and improved physical properties of the film.
• another advantage with the present invention is that the amount of chemicals added can be reduced since the retention of the chemicals is improved.
• the enzyme added to the suspension is preferably an enzyme that decomposes cellulose and/or hemicellulose, such as cellulase, xylanase and/or mannanse.
• the enzyme may be cellulase with an activity above 20 0000 CMU/g which activity may be determined on a CMC substrate at 60°C and pH 4.8.
• the enzyme may also be xylanase with an activity above 20 0000 nkat/ml when measured against birch xylan at pH 5, 50°C and a 50mM Na-citrate as pH buffer. It may be preferred to use a mixture of both cellulase and xylanase.
• microfibrillated cellulose is preferably native, i.e. it is a chemically unmodified microfibrillated cellulose.
• Native microfibrillated cellulose comprises both cellulose and hemicellulose and a mixture of cellulase and xylanase may then be preferred to use.
• the temperature of the suspension comprising MFC is preferably between 30-70°C, even more preferably between 40-60°C, before the enzyme is added to the suspension.
• the temperature range chosen is dependent on the enzyme used and on the optimal working conditions for that specific enzyme or mixture of enzymes.
• the pH value of the suspension comprising MFC is preferably between 4-8, even more preferably between 5-7, before the enzyme is added to the suspension. It is important that the pH value of the suspension is within the mentioned range so the climate for the enzyme is as beneficial as possible. Too high or too low pH will either decrease the activity of the enzyme or even deactivate it.
• the enzyme is added to the suspension in any suitable way. If the production of the film is done on a paper or paperboard machine it is possible to add the enzyme to the white water being recovered from the dewatering of the mixture on the wire. The white water comprising the enzyme is thereafter added to the suspension.
• the enzyme may also be added during production of the MFC, preferably to the last mechanical treatment stage of the fibers to produce MFC. However, it is important that the addition of the enzymes is not done too soon if added during MFC production. It is important that the suspension comprises a substantially amount of MFC in order for the treatment with enzymes to efficient.
• the suspension and the enzyme is mixed to form a mixture and it is important that the mixing is thorough making the enzyme to be in contact with all the fines and fibrils in the suspension.
• the mixing may be done in any conventional way. It might for example be possible to mix the enzyme with the suspension by using a high shear mixing device or by pumping the
• the mixture need to be stored for a certain period of time to make sure that the enzyme has enough time to decompose the material. It is preferred that the mixture is stored for a period of at least 5 minutes, preferably at least 15 minutes or even more preferably at least 30 minutes before being applied to said wire.
• the enzymatic treatment By measuring for example the viscosity, the water retention value, the amount of sugars or by measuring the dewatering rate of the mixture it is possible to determine when the enzymatic treatment is sufficient, i.e. how long time is needed, which enzyme to use, how much enzyme to dose and which activity of the enzyme that is needed. Parameters that can affect the enzymatic activity and which needs to be optimized are e.g. time,
• the present invention improves the dewatering of a suspension comprising microfibnllated cellulose and it is well known for a person skilled in the art to know when a good or adequate dewatering is achieved. Thus, it is obvious for a person skilled in the art to optimize the enzymatic treatment so that good dewatering properties of the suspension comprising microfibnllated cellulose is achieved.
• the suspension is a suspension which is a fraction of a first suspension.
• the method according to the invention may then comprise the steps of: providing a first suspension comprising microfibnllated cellulose, fractionate the first suspension into a suspension and a second suspension, adding enzyme to the suspension, mixing the enzyme with the suspension to form a mixture, optionally mixing the mixture with the second suspension to form a second mixture, applying said mixture or optional second mixture to a wire to form a fibrous web and drying said web to form said film.
• the second suspension may also be treated with enzymes before being mixed with the mixture.
• the fraction of the second suspension is preferably the reject, i.e. comprising a larger MFC material.
• One advantage with fractionating the first suspension is that the enzymatic treatment can be more tailor made since the material of each fraction will be homogenous and the optimal enzymatic treatment can then easier be applied.
• the method may further comprise the step of mechanical treating the suspension comprising microfibnllated cellulose prior to the addition of the enzyme.
• the active surfaces of the microfibnllated cellulose is increased making the MFC more reactive to the enzymatic treatment.
• the mechanical treatment may be done in any conventional way, e.g. by refining or homogenization.
• the film is thereafter produced by applying said mixture or second mixture to a wire to form a fibrous web and drying said web to form at least one layer of said film.
• the dry content of the at least one layer of the film after drying is preferably above 95% by weight.
• the drying is preferably done by increasing the temperatures.
• Temperatures used during drying may be between 50-200°C, preferably between 100-150°C.
• the drying may be done in any conventional equipment.
• the enzymes is killed leaving no residual enzyme activity in the final product, which is important if the film should be used in e.g. food contact applications. Thus, it is important that the temperature during drying is high enough to kill the enzymes. Also, since the dry content of the film is
• the activity of the enzymes is terminated at such high dry contents. It is also possible to kill the enzymes by other methods than applying heat, e.g. by radiation or addition of chemicals. It is important that the produced film has no residual enzyme activity if to be used for sensitive end uses e.g. in food applications.
• the wire is preferably a wire of a paper making machine, i.e. any kind of paper making machine known to a person skilled in the art used for making paper, paperboard, tissue or any similar products.
• the mixture is the applied onto the wire and the fibrous web formed on the wire is then dewatered.
• the dewatered fibrous web is thereafter dried by increasing the temperature of the web to form the film.
• the mixture is applied onto a fibrous web on a wire, to produce a paper or paperboard product to which the mixture is applied to form a coated product.
• the production speed for the production of the film on a wire is preferably between 150-1500 m/min, preferably between 200-1200 m/min and even more preferred between 300-1000 m/min. It has been found possible to be able to produce a MFC film having good barrier properties at an increased production speed due to the improved dewatering properties of the MFC used.
• the microfibri Hated cellulose of the suspension is produced from mechanical, thermomechanical or chemical pulp.
• the microfibri Hated cellulose is preferably produced from kraft pulp.
• the microfibrillated cellulose preferably has a Schopper Riegler value (SR°) of more than 80, preferably more than 90, even more preferred more than 93 or even more preferred more than 95.
• the Schopper-Riegler value can be obtained through the standard method defined in EN ISO 5267-1 . This high SR value is
• the dry solid content of this kind of web, before disintegrated and measuring SR is less than 50 % (w/w).
• SR value The SR value specified herein, is to be understood as an indication but not a limitation, to reflect the characteristics of the MFC material itself.
• microfibrillated cellulose is preferably produced from never dried pulp since it was found that never dried MFC has much higher accessibility for enzymes compared to MFC produced from dried pulp. It is also preferred that the microfibrillated cellulose has a very low lignin content since lignin could negatively affect the enzymatic activity.
• the mixture may further comprise additives, preferably any one of a starch, carboxymethyl cellulose, a filler, retention chemicals, flocculation additives, deflocculating additives, dry strength additives, wet strength additives, softeners, surface active agents, or mixtures thereof. It may be possible to add additives that will improve different properties of the mixture and/or the produced film.
• additives preferably any one of a starch, carboxymethyl cellulose, a filler, retention chemicals, flocculation additives, deflocculating additives, dry strength additives, wet strength additives, softeners, surface active agents, or mixtures thereof. It may be possible to add additives that will improve different properties of the mixture and/or the produced film.
• the present invention also relates to a film, comprising microfibrillated cellulose, which film has an oxygen transmission rate in the range of from 0.1 to 300 cc/m 2 /24h measured according to the standard ASTM D-3985, at a relative humidity of 50 % at 23 ° C and/or at a relative humidity of 85% at 38 ° C.
• the amount of microfibrillated cellulose in the produced film and thus also in the suspension is preferably between 50-100 wt-% by total dry weight of the film, preferably between 60-100wt-% by total dry weight of the film and even more preferred between 70-100% by total dry weight of the film.
• the film or suspension may also comprises longer or normal cellulosic fibers as well, preferably chemical, mechanical or thermomechanical pulp fibers.
• the fibers may be produced from hardwood or softwood fibers.
• the film may have a basis weight of less than 100 g/m 2 , or less than 70 g/ m 2 , or less than 50 g/m 2 , or less than 40 g/m 2 , or less than 30g/m 2 .
• the basis weight is preferably at least 10 g/m 2 , preferably between 10-100 g/m 2 , even more preferred between 10-70 g/m 2 , more preferred between 10-50 g/m 2 and most preferred between 10-30 g/m 2 .
• Microfibrillated cellulose shall in the context of the patent application mean a nano scale cellulose particle fiber or fibril with at least one dimension less than 100 nm. MFC comprises partly or totally fibrillated cellulose or lignocellulose fibers. The liberated fibrils have a diameter less than 100 nm, whereas the actual fibril diameter or particle size distribution and/or aspect ratio (length/width) depends on the source and the
• the smallest fibril is called elementary fibril and has a diameter of approximately 2-4 nm (see e.g. Chinga-Carrasco, G., Cellulose fibres, nanofibrils and microfibrils, : The morphological sequence of MFC components from a plant physiology and fibre technology point of view, Nanoscale research letters 2011, 6:417), while it is common that the aggregated form of the elementary fibrils, also defined as microfibril (Fengel, D., Uitrastructurai behavior of cell wall polysaccharides, Tappi J., March 1970, Vol 53, No. 3.), is the main product that is obtained when making MFC e.g. by using an extended refining process or pressure-drop disintegration
• the length of the fibrils can vary from around 1 to more than 10 micrometers.
• a coarse MFC grade might contain a substantial fraction of fibrillated fibers, i.e.
• MFC Middle-MediaCardion cellulose
• fibrillated cellulose cellulose
• nanofibrillated cellulose fibril aggregates
• nanoscale cellulose fibrils cellulose nanofibers
• cellulose nanofibrils cellulose nanofibrils
• cellulose microfibrils fibrillated cellulose
• nanofibrillated cellulose fibril aggregates
• nanoscale cellulose fibrils nanoscale cellulose fibrils
• cellulose nanofibers cellulose nanofibers
• cellulose nanofibrils cellulose nanofibrils
• cellulose microfibrils fibrillated cellulose
• nanofibrillated cellulose fibril aggregates
• nanoscale cellulose fibrils cellulose nanofibers
• cellulose nanofibrils cellulose nanofibrils
• MFC can also be characterized by various physical or physical-chemical properties such as large surface area or its ability to form a gel-like material at low solids (1 -5 wt%) when dispersed in water.
• the cellulose fiber is preferably fibrillated to such an extent that the final specific surface area of the formed MFC is from about 1 to about 200 m2/g, or more preferably 50-200 m2/g when determined for a freeze-dried material with the BET method.
• MFC multi-pass refining
• pre-hydrolysis followed by refining or high shear disintegration or liberation of fibrils.
• One or several pre-treatment step is usually required in order to make MFC manufacturing both energy efficient and sustainable.
• the cellulose fibers of the pulp to be supplied may thus be pre-treated
• the nanofibrillar cellulose may contain some hemicelluloses; the amount is dependent on the plant source.
• Mechanical disintegration of the pre-treated fibers is carried out with suitable equipment such as a refiner, grinder, homogenizer, colloider, friction grinder, ultrasound sonicator, fluidizer such as microfluidizer, macrofluidizer or fluidizer-type homogenizer.
• the product might also contain fines, or nanocrystalline cellulose or e.g. other chemicals present in wood fibers or in papermaking process.
• the product might also contain various amounts of micron size fiber particles that have not been efficiently fibrillated.
• MFC is produced from wood cellulose fibers, both from hardwood or softwood fibers. It can also be made from microbial sources, agricultural fibers such as wheat straw pulp, bamboo, bagasse, or other non-wood fiber sources. It is preferably made from pulp including pulp from virgin fiber, e.g. mechanical, chemical and/or thermomechanical pulps. It can also be made from broke or recycled paper.
• MFC includes, but is not limited to, the new proposed TAPPI standard W13021 on cellulose nanofibril (CNF) defining a cellulose nanofiber material containing multiple elementary fibrils with both crystalline and amorphous regions, having a high aspect ratio with width of 5-30nm and aspect ratio usually greater than 50.
• CNF cellulose nanofibril
• the activity of the enzyme used in KP5 was 96 400 CMU/g and the activity of the enzyme used in KP6 was 63 300 nkat/ml.
• test points having enzyme dosing (KP5 and KP6) in the wet-end had improved oxygen barrier properties compared to reference test point KP 4.1 showing as the oxygen transmission rate (OTR) was substantially lower with the test points KP5 and KP6. Furthermore, the dewatering rate of the films according to the invention (KP5 and KP6) was improved.
• Example 1 were extrusion polyethylene-coated with 25 g/m 2 of low-density polyethylene (LDPE).
• LDPE low-density polyethylene
• the oxygen transmission rate (OTR) of the PE-coated MFC films was measured in 38 °C and 85% relative humidity (RH) conditions, i.e. tropical conditions. Also, the OTR was measured after storing the PE-coated films in
• the oil and grease resistance of the MFC films KP 4.1 , KP5 and KP6 were tested according to the modified ASTM F1 19-82 method. Chicken fat was used as grease and the test was performed in an oven at 60°C.
• Break-through time period visually noticeable fat spot/spots on the TLC plate placed under the material, actual penetration of the fat through the material

Landscapes

• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Organic Chemistry (AREA)
• Genetics & Genomics (AREA)
• Bioinformatics & Cheminformatics (AREA)
• Zoology (AREA)
• Wood Science & Technology (AREA)
• Biochemistry (AREA)
• Medicinal Chemistry (AREA)
• Microbiology (AREA)
• Manufacturing & Machinery (AREA)
• Biomedical Technology (AREA)
• General Engineering & Computer Science (AREA)
• Biotechnology (AREA)
• General Health & Medical Sciences (AREA)
• Molecular Biology (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Materials Engineering (AREA)
• Polymers & Plastics (AREA)
• Manufacture Of Macromolecular Shaped Articles (AREA)
• Laminated Bodies (AREA)
• Paper (AREA)
• Application Of Or Painting With Fluid Materials (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Enzymes And Modification Thereof (AREA)
• Polysaccharides And Polysaccharide Derivatives (AREA)

Priority Applications (6)

Applications Claiming Priority (2)

Publications (1)

Family

ID=66173574

Family Applications (1)

Country Status (8)

Cited By (5)

Families Citing this family (5)

Citations (12)

Family Cites Families (24)

• 2017
  • 2017-10-20 SE SE1751305A patent/SE542193C2/en unknown
• 2018
  • 2018-10-17 WO PCT/IB2018/058043 patent/WO2019077514A1/en not_active Ceased
  • 2018-10-17 US US16/757,093 patent/US11795280B2/en active Active
  • 2018-10-17 JP JP2020521947A patent/JP7324746B2/ja active Active
  • 2018-10-17 CA CA3079132A patent/CA3079132A1/en active Pending
  • 2018-10-17 EP EP18868513.5A patent/EP3697833B1/en active Active
  • 2018-10-17 BR BR112020007688-0A patent/BR112020007688B1/pt active IP Right Grant
  • 2018-10-17 CN CN201880068282.5A patent/CN111479858B/zh not_active Expired - Fee Related

Patent Citations (12)

Non-Patent Citations (7)

Also Published As

Similar Documents

Legal Events