WO2019054260A1 - 硬質表面用液体洗浄剤組成物 - Google Patents

硬質表面用液体洗浄剤組成物 Download PDF

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Publication number
WO2019054260A1
WO2019054260A1 PCT/JP2018/032959 JP2018032959W WO2019054260A1 WO 2019054260 A1 WO2019054260 A1 WO 2019054260A1 JP 2018032959 W JP2018032959 W JP 2018032959W WO 2019054260 A1 WO2019054260 A1 WO 2019054260A1
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WO
WIPO (PCT)
Prior art keywords
less
mass
component
detergent composition
liquid detergent
Prior art date
Application number
PCT/JP2018/032959
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
中川陽介
Original Assignee
花王株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 花王株式会社 filed Critical 花王株式会社
Priority to SG11201913843WA priority Critical patent/SG11201913843WA/en
Priority to MYPI2020001267A priority patent/MY191106A/en
Priority to CN201880043715.1A priority patent/CN110914399B/zh
Publication of WO2019054260A1 publication Critical patent/WO2019054260A1/ja

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08Liquid soap, e.g. for dispensers; capsuled
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus

Definitions

  • the liquid detergent composition for hard surface according to the present invention causes the silicic acid molecules to be sequentially released from the vicinity of the surface of the silicic acid polymer which is the cause of the water stain. It is guessed that it is because it can be removed.
  • the liquid detergent composition for a hard surface according to the present invention contains 0% by mass or more, preferably 0.2% by mass or more, more preferably 0.5% by mass or more of the component (b) from the viewpoint of detergency. It is preferably at least 1% by mass, more preferably at least 2% by mass, still more preferably at least 3% by mass, and from the viewpoint of economy, 10% by mass or less, preferably 8% by mass or less, more preferably 7% by mass % Or less, more preferably 6% by mass or less.
  • the content of the component (b) is converted to an acid type.
  • R 1c is preferably an alkyl or alkenyl group having a carbon number of preferably 9 or more, more preferably 11 or more, and preferably 15 or less, more preferably 13 or less. Preferred are decyl, undecyl, dodecyl and tridecyl.
  • R 2c and R 3c are preferably methyl groups.
  • R 4c represents a hydrocarbon group having 8 to 22 carbon atoms, preferably an alkyl group or an alkenyl group, more preferably an alkyl group, and R 5c and R 6c are the same or different and have 1 or more carbon atoms] 3 or less alkyl group is shown.
  • E represents an alkylene group having 1 to 5 carbon atoms.
  • the sorbitan nonionic surfactant, aliphatic alkanolamide, fatty acid monoglyceride and sucrose fatty acid ester preferably have a carbon number of 8 to 18 and more preferably a carbon number of 12 to 14 and a linear or branched alkyl group. What has is preferable.
  • the mass ratio of the content of the anionic surfactant to the total content of the components (a) and (b) [anionic surfactant / (((a) ) + (B)) is preferably 0.30 or less, more preferably 0.28 or less, still more preferably 0.25 or less, still more preferably 0.2 or less, more preferably from the viewpoint of rinseability Is 0.1 or less, more preferably 0.05 or less, still more preferably 0.01 or less, and preferably 0 or more, and may be 0.
  • component (d) is preferably at least one selected from smectite clay minerals, natural polymers and synthetic polymers, and is selected from nonionic polysaccharides, natural polymers and synthetic polymers. 1 or more types are more preferable, and 1 or more types selected from nonionic polysaccharides are still more preferable.
  • the component (d) is preferably at least one selected from hydroxyethyl cellulose, xanthan gum and polyvinyl pyrrolidone, with hydroxyethyl cellulose being more preferred.
  • carbon number 8 dibutylene diglycol
  • dipropylene glycol monobutyl ether (carbon number 10) can be mentioned.
  • the liquid detergent composition for a hard surface according to the present invention preferably has a component (f) of at least 0.3% by mass, more preferably at least 0.5% by mass, and high temperature stability from the viewpoint of detergency.
  • the content is preferably 10% by mass or less, more preferably 5% by mass or less, still more preferably 3% by mass or less, still more preferably 2% by mass or less, still more preferably 1.5% by mass or less.
  • the stock solution of the hard surface liquid detergent composition is adhered to the hard surface as it is, that is, without changing the composition.
  • the liquid detergent composition for a hard surface is brought into contact with a hard surface to which a water stain is attached, without being attached to a wet absorbent cotton.
  • the composition of the hard surface liquid detergent composition may vary. That is, after being in contact with a hard surface, the composition of the hard surface liquid detergent composition may be diluted or concentrated.
  • component (a) 0.2% by mass or more and 10% by mass or less of one or more selected from phosphonic acid type chelating agents and phosphoric acid type chelating agents (hereinafter referred to as component (a)), other than component (b)
  • component (a) A liquid detergent composition for a hard surface comprising 0% by mass to 10% by mass of a chelating agent (hereinafter referred to as component (b)), (c) a surfactant (hereinafter referred to as component (c)) and water.
  • Component (b) is preferably 0.2% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, still more preferably 2% by mass or more, still more preferably 3% by mass or more
  • the liquid detergent composition for a hard surface according to ⁇ 1> which contains preferably 8% by mass or less, more preferably 7% by mass or less, still more preferably 6% by mass or less.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
PCT/JP2018/032959 2017-09-12 2018-09-06 硬質表面用液体洗浄剤組成物 WO2019054260A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SG11201913843WA SG11201913843WA (en) 2017-09-12 2018-09-06 Liquid detergent composition for hard surfaces
MYPI2020001267A MY191106A (en) 2017-09-12 2018-09-06 Liquid detergent composition for hard surfaces
CN201880043715.1A CN110914399B (zh) 2017-09-12 2018-09-06 硬质表面用液体清洁剂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017-174962 2017-09-12
JP2017174962A JP6990071B2 (ja) 2017-09-12 2017-09-12 硬質表面用液体洗浄剤組成物

Publications (1)

Publication Number Publication Date
WO2019054260A1 true WO2019054260A1 (ja) 2019-03-21

Family

ID=65723678

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2018/032959 WO2019054260A1 (ja) 2017-09-12 2018-09-06 硬質表面用液体洗浄剤組成物

Country Status (6)

Country Link
JP (1) JP6990071B2 (zh)
CN (1) CN110914399B (zh)
MY (1) MY191106A (zh)
SG (1) SG11201913843WA (zh)
TW (1) TWI775937B (zh)
WO (1) WO2019054260A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021251484A1 (ja) * 2020-06-12 2021-12-16 花王株式会社 硬質表面用洗浄剤組成物

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW202204588A (zh) * 2020-06-12 2022-02-01 日商花王股份有限公司 硬質表面用清潔劑組合物

Citations (7)

* Cited by examiner, † Cited by third party
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JPH10204480A (ja) * 1997-01-22 1998-08-04 Kao Corp 台所まわり用液体洗浄剤組成物
JP2000510504A (ja) * 1996-06-06 2000-08-15 モンサント・カンパニー キサンタンガムを含有する酸性洗浄組成物
JP2010059296A (ja) * 2008-09-03 2010-03-18 Kao Corp 硬質表面用洗浄剤組成物
JP2010280588A (ja) * 2009-06-03 2010-12-16 Lion Corp 塗布タイプの義歯洗浄用液状組成物
US20130035276A1 (en) * 2011-08-05 2013-02-07 Ecolab Usa Inc. Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale
US20160177233A1 (en) * 2014-12-22 2016-06-23 Ecolab Usa Inc. Warewashing composition containing alkanol amine phosphonate and methods of use
JP2017043644A (ja) * 2015-08-24 2017-03-02 株式会社Adeka 酸性cip用洗浄剤組成物およびcip洗浄方法

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CN1091798C (zh) * 1994-10-13 2002-10-02 普罗格特-甘布尔公司 含有胺和阴离子表面活性剂的洗涤剂组合物
EP0709451A1 (en) * 1994-10-28 1996-05-01 The Procter & Gamble Company Stable liquid detergent compositions
CN1421518A (zh) * 2000-11-22 2003-06-04 上海白猫有限公司 商业洗碗机专用液体餐具洗涤剂
CN101144050A (zh) * 2006-09-12 2008-03-19 长葛市天润有色金属研究所 浴盆瓷砖清洗剂的制造方法
EP2264138B2 (en) * 2009-06-19 2023-03-08 The Procter & Gamble Company Liquid hand dishwashing detergent composition
JP2014031431A (ja) * 2012-08-02 2014-02-20 Adeka Corp ケイ酸スケール用洗浄剤組成物およびケイ酸スケールの洗浄方法
CN103602526A (zh) * 2013-10-15 2014-02-26 青岛叁鼎卫生制品有限公司 一种餐具杀菌洗涤剂
EP2924107A1 (en) * 2014-03-28 2015-09-30 The Procter and Gamble Company Water soluble unit dose article
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US10731111B2 (en) * 2015-11-25 2020-08-04 Conopco, Inc. Liquid laundry detergent composition
CN106854576A (zh) * 2017-01-05 2017-06-16 长沙协浩吉生物工程有限公司 一种生物洗碗机专用洗涤剂的配制方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000510504A (ja) * 1996-06-06 2000-08-15 モンサント・カンパニー キサンタンガムを含有する酸性洗浄組成物
JPH10204480A (ja) * 1997-01-22 1998-08-04 Kao Corp 台所まわり用液体洗浄剤組成物
JP2010059296A (ja) * 2008-09-03 2010-03-18 Kao Corp 硬質表面用洗浄剤組成物
JP2010280588A (ja) * 2009-06-03 2010-12-16 Lion Corp 塗布タイプの義歯洗浄用液状組成物
US20130035276A1 (en) * 2011-08-05 2013-02-07 Ecolab Usa Inc. Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale
US20160177233A1 (en) * 2014-12-22 2016-06-23 Ecolab Usa Inc. Warewashing composition containing alkanol amine phosphonate and methods of use
JP2017043644A (ja) * 2015-08-24 2017-03-02 株式会社Adeka 酸性cip用洗浄剤組成物およびcip洗浄方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021251484A1 (ja) * 2020-06-12 2021-12-16 花王株式会社 硬質表面用洗浄剤組成物

Also Published As

Publication number Publication date
TWI775937B (zh) 2022-09-01
JP2019048963A (ja) 2019-03-28
TW201920639A (zh) 2019-06-01
JP6990071B2 (ja) 2022-01-12
SG11201913843WA (en) 2020-03-30
MY191106A (en) 2022-05-30
CN110914399A (zh) 2020-03-24
CN110914399B (zh) 2021-09-28

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