WO2019015306A1 - 果蔬相温预冷兼容多耦合抗衰老处理技术及装备 - Google Patents

果蔬相温预冷兼容多耦合抗衰老处理技术及装备 Download PDF

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WO2019015306A1
WO2019015306A1 PCT/CN2018/075718 CN2018075718W WO2019015306A1 WO 2019015306 A1 WO2019015306 A1 WO 2019015306A1 CN 2018075718 W CN2018075718 W CN 2018075718W WO 2019015306 A1 WO2019015306 A1 WO 2019015306A1
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Prior art keywords
cooling
tunnel
cooling box
fruit
partition
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PCT/CN2018/075718
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English (en)
French (fr)
Inventor
李喜宏
杨维巧
汤尧
张宇峥
朱刚
唐宪谱
潘艳芳
贾晓昱
王雨
Original Assignee
宁夏中玺枣业股份有限公司
天津科技大学
李喜宏
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Application filed by 宁夏中玺枣业股份有限公司, 天津科技大学, 李喜宏 filed Critical 宁夏中玺枣业股份有限公司
Priority to US16/166,119 priority Critical patent/US11252973B2/en
Publication of WO2019015306A1 publication Critical patent/WO2019015306A1/zh

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/04Freezing; Subsequent thawing; Cooling
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/04Freezing; Subsequent thawing; Cooling
    • A23B7/0425Freezing; Subsequent thawing; Cooling the material not being transported through or in the apparatus, with or without shaping, e.g. in the form of powder, granules or flakes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/144Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/144Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23B7/152Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere comprising other gases in addition to CO2, N2, O2 or H2O ; Elimination of such other gases
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/154Organic compounds; Microorganisms; Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/157Inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

Definitions

  • the invention belongs to the field of fresh-keeping of fruits and vegetables, and particularly relates to a multi-coupling anti-aging treatment technology and equipment for phase preheating of fruits and vegetables.
  • the preservation of fruits and vegetables is based on post-harvest physiology and pathology, temperature, humidity, gas and anti-corrosion.
  • the temperature effect rate is about 60%-70%, humidity, gas and anti-corrosion each account for 10%-15%, so there is no chilling damage. Under the condition of freezing damage, the lower the temperature of fresh fruits and vegetables, the better.
  • the field hot pre-cooling is determined as the first 1 km of the cold chain.
  • the cold storage invented by Australian engineer James for fruit and vegetable storage is regarded as the first revolution of technology.
  • the CA (Air Conditioning) library invented by Kidd and West of the University of Cambridge in the United Kingdom was hailed as the second revolution. It was also said that the decompression storage technology proposed by Bouguer in 1962 or the Japanese Yamagen Zhaomei proposed in 1972. The ice storage technology for the third revolution.
  • the cold storage relies on mechanical cooling to cool the temperature at any temperature, the temperature difference is ⁇ 0.5-1 °C; the CA library can adjust the storage environment oxygen and carbon dioxide gas concentration on the basis of the cold storage; the ice temperature library and the cold storage principle are the same, but the temperature control accuracy is up to the decompression technology ⁇ 0.1 ° C, however, the common defects of cold storage, air conditioning, decompression and ice temperature library technology is heat transfer and mass transfer, the operation needs to constantly use humidifier humidification, while the cooling fan is continuously defrost.
  • Lingwu Changzao is an excellent fresh fruit variety with local characteristics in Ningxia. Its fruit is bright, fleshy, sweet and sour. It is rich in vitamins and minerals, especially the highest content of VC. It is known as a live "vitamin pill”. The reputation of "King of the Fruits".
  • the heat of Lingwu long jujube is higher after harvesting. The higher temperature will increase the respiration intensity of jujube, which will eventually lead to aging and deterioration.
  • Pre-cooling is one of the important means to maintain the quality of Lingwu long jujube and extend the shelf life. Pre-cooling can reduce product loss and save energy.
  • the traditional cold storage library is large, and the number of fruits and vegetables is relatively high. When a large number of fruits and vegetables are pre-cooled at the same time, the pre-cooling efficiency is low, the pre-cooling takes a long time, and the energy consumption is large.
  • Pre-cooling can not prevent corrosion and mildew.
  • the sealing can not be cooled, pre-cooling for 10 hours, the gold processing time is within 10 hours, and at the same time, the anti-corrosion and anti-mildew are completed, and the pre-cooling and anti-corrosion and anti-mildew prevention are completed in prime time. senescence.
  • the existing cold storage is mostly static pre-cooling, the heat transfer and mass transfer is slow, the cooling capacity is low, the pre-cooling takes a long time, and the water dispersion is easy to be lost;
  • the fruit and vegetable treatment methods are mostly the pre-cooling treatment of fruits and vegetables. After the treatment, the preservative treatment is carried out, and it is easy to miss the best preservation period of fruits and vegetables.
  • the conventional tunnel differential pressure pre-cooling has only one cooling method, and it is impossible to select a specific cooling method for the varieties of fruits and vegetables, such as Lingwu long jujube at high temperature and high temperature. In the wet environment, the method of rapid cooling is easy to produce plaque disease; 4.
  • the preservative can not be added in the pre-cooling, and the preservative can not add the preservative at the same time, because of heat and mass transfer.
  • Preservatives do not work, 1-MCP, people are toxic, and each sputum in this application is a closed, independent space, unit operation. 5.
  • the first major defect of traditional pre-cooling technology is heat transfer and mass transfer. Cold storage static pre-cooling, differential pressure tunnel pre-cooling, cold water pre-cooling, vacuum pre-cooling and other fruit and vegetable pre-cooling technology, the common feature is that the fruit and vegetable pre-cooling and cooling also continuously lose water, the faster the cooling rate in the pre-cooling process, the water loss The bigger. 6.
  • the second major drawback of traditional pre-cooling technology is environmental development. Pre-cooling is not compatible with anti-aging and anti-aging treatment. Based on the above-mentioned first pre-cooling heat and mass transfer defect, even in the fully enclosed box process technology, the cooling system of the refrigeration system enhances the heat exchange of the environmental phase while adsorbing the moisture and physiological regulator of the environmental phase.
  • Preservatives and other media, resulting in fruit and vegetable pre-cooling and disease resistance and anti-aging treatment can not be compatible, that is to say because cooling priority has to sacrifice the best time for disease resistance and anti-aging, such as ethylene antagonist 1-MCP (1-methylcyclopropene
  • the optimal treatment time is within 24 hours after harvest, and the optimal time for pre-cooling of fruits and vegetables is also 24 hours after harvest. Therefore, it is necessary to pre-cool and then 1-MCP treatment. 7.
  • the third major drawback of the traditional pre-cooling technology is that the air-conditioning, decompression and ice-temperature precise temperature control cannot be coordinated, that is to say, the gas-conditioning and decompression can not meet the precise temperature control of the large heat exchange.
  • the comparative patent number is CN105794953A.
  • the patent name is a differential pressure pre-cooling system and method. It mainly introduces a differential pressure pre-cooling system and method which can rapidly cool fruits and vegetables, and at the same time supplement the water lost from fruits and vegetables in the process of cooling. It has improved the fresh-keeping rate of fruit and vegetable agricultural products, and there are problems: it is impossible to pre-cool the fruits and vegetables with preservative treatment.
  • the comparison utility number is CN 205174974 U
  • the utility model name is the tunnel type differential pressure pre-cooling device for kiwifruit, which solves the shortcomings of the traditional pre-cooling library and the ripening library function, and realizes pre-cooling and ripening.
  • a library and dual use make full use of the space and time used by the library, reduce the construction cost, there are problems: no fumigation box, single function, can only ripen, can not create a closed internal circulation state.
  • the new practical model is CN 204132285 U.
  • the utility model name is a miniature differential pressure type rapid pre-cooling and gas fumigation device.
  • the utility model can simultaneously control gas and humidity, has a simple structure, and the volume of the fruit and vegetable storage room is adjustable. It is easy to operate and has problems: although the pre-cooling and ripening are solved, it is impossible to pre-cool the fruit and vegetable varieties, and it is easy to produce pre-cooling diseases of fruits and vegetables.
  • the present application provides a new set of pre-cooling systems, which perfectly solves the above problems.
  • the object of the present invention is to overcome the deficiencies of the prior art, and provide a multi-coupling anti-aging treatment technology and equipment for phase preheating of fruits and vegetables, which has the advantages of quick pre-cooling and convenient operation, and is added with a preservative, and is suitable for being in an orchard. Pre-cooling in real time.
  • the technical solution adopted by the present invention is:
  • a fruit and vegetable phase temperature pre-cooling compatible multi-coupling anti-aging treatment equipment including a cold storage, and a plurality of differential pressure pre-cooling devices are placed in the cold storage, and the structure of the differential pressure pre-cooling device comprises: a gas-tight tunnel pre-cooling box, which is pre-cooled in the tunnel
  • a partition is fixed in parallel with the top wall of the cold box, and the partition extends to the bottom of the tunnel pre-cooling box.
  • One side of the partition is parallel to the side wall of the box to fix a ventilation plate, and the other end of the partition Install a section of windshield vertically downwards, and install an axial flow fan at a corner of the tunnel pre-cooling box.
  • the corner is the angle between the partition and the ventilation panel.
  • the air inlet of the axial flow fan corresponds to the upper space of the partition, and the air outlet corresponds.
  • a plurality of fruit frames are arranged in the tunnel pre-cooling box, which are located between the ventilation plate and the windshield, and the frame of the Lingwu long jujube fruit is stacked on the fruit frame;
  • the array In the upper part of the tunnel pre-cooling box on the upper part of the partition plate, the array is sealed and installed with a plurality of rows of vacuum heat exchange tubes.
  • One end of the vacuum heat exchange tube is located in the tunnel pre-cooling box, and one end is located in the cold storage, and the low temperature in the cold storage is introduced through the vacuum heat exchange tube.
  • the rapid cooling under the airtight adjustment of the tunnel pre-cooling box is realized;
  • An ultrasonic atomizer is installed on the side of the upper part of the separator near the axial flow fan, and the ultrasonic atomizer is filled with the preservative solution. During the process of the cold air circulation, the fan is circulated to the corner of the tunnel pre-cooling box. Providing an ozone generating device and an ultraviolet sterilizing device in the pre-cooling box of the hermetic tunnel;
  • the preservative component is: 1 to 3 parts of methyl jasmonate, 2 to 3 parts of Tekto, 2 to 3 parts of sodium persulfate, 2 to 3 parts of salicylic acid, and 0.5 to 1 part of 1-MCP.
  • the size of the preservative solution particles sprayed in the ultrasonic atomizer is in the range of 0.5 to 0.8 ⁇ m.
  • the length of the wind deflector is 1/3 of the length of the ventilating plate.
  • the preparation step of the preservative is as follows: the components are installed in parts by weight, and the raw materials are dissolved in water, and the amount of water added is 80-100 parts.
  • the tunnel pre-cooling box is a plastic treasury or a tunnel pre-cooling box sidewall made of a heat insulating board.
  • the size of the preservative solution particles sprayed in the ultrasonic atomizer is in the range of 0.5 to 0.8 ⁇ m.
  • the invention is provided with a heat exchange tube in the upper part of the differential pressure pre-cooling device, the axial flow type exhaust fan absorbs heat from the cargo pile, the hot air enters the ventilation duct, and the heat exchange tube exchanges the cold air in the cold storage with the hot air in the cargo, Significantly improve the efficiency of pre-cooling.
  • the preservative of the invention adds the preservative of the molecular intercalation occupying function to the goods at the same time of pre-cooling, and pre-cools the fresh-keeping treatment of the goods, which can obviously shorten the pre-storage treatment time and improve the shelf life of the goods.
  • the invention changes the traditional tunnel differential pressure pre-cooling device in a fully enclosed form, and does not mass transfer with the heat pipe, can seal the preservative, prevent the volatilization agent from volatilizing, reduce the moisture loss of the cargo during the pre-cooling process, and reduce the pre-cooling process.
  • the cooling capacity is lost and the pre-cooling efficiency is accelerated.
  • the invention adopts the full-closed form to reduce the moisture loss of the cargo, which is 2-3 times of the cold, and reduces the loss of the cold.
  • the heat exchange tube is added on the basis of the traditional tunnel differential pressure pre-cooling device, which can significantly improve the pre-cooling efficiency. It is 3-5 times higher than static pre-cooling and nearly doubled than open differential pressure pre-cooling. Adding preservatives during pre-cooling shortens the processing time before storage by 2 times and the shelf life of goods by 1.5 times. Significantly increase the shelf life of goods
  • the device is fully sealed.
  • the upper end of the tunnel is equipped with a vacuum heat exchange tube.
  • the vacuum tube extends through the ventilation duct and extends into the tunnel.
  • the axial flow exhaust fan extracts the hot air from the tunnel through the heat exchange tube, and the heat exchange tube will cool the cold outside the tunnel. Exchange with the hot air of the cargo in the tunnel, causing the temperature in the tunnel to continuously decrease, forming a closed internal circulation state, which can significantly accelerate the pre-cooling efficiency, constant temperature, no humidification, and save energy.
  • the invention adds preservative in the pre-cooling device at the same time of pre-cooling, and adds preservative during high-efficiency heat transfer and pre-cooling of gold, and the pre-cooled goods are treated with preservative by means of sealed internal circulation to achieve pre-cooling.
  • the effect of preserving the goods can significantly shorten the pre-storage treatment time and increase the shelf life of the goods.
  • the pre-cooling of the invention can quickly cool down, and the cooling rate of the device is set for different fruit and vegetable varieties.
  • Heat transfer does not transfer mass.
  • the refrigeration system and the pre-cooling and cooling system are independent of each other.
  • the pre-cooling system of fruits and vegetables is not insulated, and the forced exchange of heat during cooling is achieved by the forced convection of the heat exchange tubes and the axial fans.
  • Cooling is compatible with disease resistance and anti-aging.
  • the pre-cooling and cooling system only has the forced exchange of heat, and there is no medium exchange or transfer. Therefore, it is possible to carry out pre-cooling and perform antagonists such as 1-MCP and an inducer such as methyl jasmonate in the first time after fruit and vegetable harvesting.
  • Anti-disease agents such as calcium chloride, bactericides such as sulfur dioxide, ozone, or physical preservation such as static electricity, electric fields, etc., preservatives may be gases, or liquid nano-atomizing gases.
  • Pre-cooling and cooling can simultaneously adjust the gas composition as the gas-regulating library.
  • the pressure-reducing library adjusts the pressure and the temperature fluctuation of the ice temperature library is ⁇ 0.1°C.
  • Figure 1 is a schematic view showing the structure of a differential pressure precooling apparatus.
  • FIG. 2 is a schematic structural view of a differential pressure pre-cooling system.
  • a fruit and vegetable phase temperature pre-cooling is compatible with multi-coupling anti-aging treatment technology and equipment.
  • the whole equipment includes a cold storage 11 and a plurality of differential pressure pre-cooling devices are placed in the cold storage.
  • the structure of the differential pressure pre-cooling device includes: a gas-tight tunnel Pre-cooling box 3 (not insulated), a partition 5 is fixed in parallel with the top wall in the upper part of the tunnel pre-cooling box, and the partition extends to the bottom of the tunnel pre-cooling box, and one side of the partition is spaced from the side wall of the box
  • a ventilating plate 6 is fixed in parallel, and the ventilating holes are uniformly distributed on the ventilating plate, the hole spacing is 5cm*5cm each, the diameter is 1cm, and the other side of the partition plate is provided with a windshield 12 (the hole spacing is 20cm*20cm each, each diameter 1cm) for preventing the circulating wind from sloping through the end of the partition, and installing the axial fan
  • a plurality of fruit frames 8 are arranged in the tunnel pre-cooling box, which are located between the ventilation plate and the windshield, and the frame of the Lingwu long jujube fruit is stacked on the fruit frame, and a plurality of rows can be arranged, and each row is stacked vertically.
  • a large batch of pre-cooling can be achieved.
  • the height of the windshield is 1/3 of the length of the ventilation plate.
  • the array is sealed and installed with a plurality of rows of vacuum heat exchange tubes 1 (5 square centimeters each), one end of the vacuum heat exchange tube is located in the tunnel pre-cooling box, and one end is located in the cold storage, and the cold storage is inside.
  • the low temperature is introduced into the tunnel pre-cooling box through the vacuum heat exchange tube, and the rapid cooling under the airtight adjustment of the tunnel pre-cooling box is realized, and the cold air is quickly circulated into the fruit frame through the circulation of the axial flow fan.
  • the heat pipe is fixed to the tunnel pre-cooling box through the fixing frame 2.
  • An ultrasonic atomizer 9 is installed on the side of the upper part of the partition near the axial flow fan, and the ultrasonic atomizer is filled with the preservative solution.
  • the fan circulates the preservative to each of the tunnel pre-cooling boxes.
  • the size of the preservative solution particles sprayed in the ultrasonic atomizer ranges from 0.5 to 0.8 ⁇ m. The particles of this size can promote the absorption of the preservative by the micropores on the surface of Lingwu long jujube and improve the preservation effect.
  • an absorption layer 10 is placed on the inner layer of the tunnel pre-cooling box for adsorbing excessive droplets of preservative. After adsorption, the excess preservative can be reused by washing the adsorption layer, and the whole device forms a full seal. surroundings. Compared with the open pre-cooling of the prior art, it has completely different effects. The open pre-cooling is unable to add the preservative. This application is the first time to complete the deep contact between the preservative and the fruit in the cold stage, and complete the pre-cooling and preservation. Two processes.
  • the tunnel pre-cooling box can be made of aluminum plate and steel plate with a thickness of 1-2 mm.
  • the supporting keel 13 can be arranged in the cold storage. It plays the role of fixing and supporting the tunnel pre-cooling box.
  • the length and height of the pre-cooling box are shown in the figure, the width is 2.5-2.6 meters, and the heat pipe is deep into the tunnel pre-cooling box 40-50cm.
  • the vacuum heat exchange tube carries out heat exchange; the long stack is composed of several baskets of jujube; the vacuum heat exchange tube has a size of (outer diameter ⁇ wall thickness) of ⁇ 19 mm ⁇ 2 mm, a length of 80-100 mm, a material of carbon steel and an internal vacuum.
  • the vacuum heat exchange tube structure is: a sealed metal tube, the inner wall of which is covered with a core network of a material having a capillary structure, wherein the middle is empty, and the tube is filled with a certain heat carrier (liquid nitrogen).
  • the axial flow exhaust fan has a rated air volume of 11,000 m 3 /h and a wind speed of 1.6 m/s, creating a pressure difference of 0.16 Pa.
  • the hourly air volume is 40-60 times the volume of the tunnel pre-cooling box.
  • the total heat exchange is 80-100 watts per hour.
  • An ozone generating device 14 may be added to the above apparatus to perform ozone sterilization on the fruit in the storage. It is also possible to install a UV sterilizing device 15 for sterilizing the circulating air.
  • the differential pressure pre-cooling device is pre-cooled for 1-2 hours, and a molecular intercalation-site-inducing preservative is added to the ultrasonic atomizer, and the composition is as follows: in parts by mass: methyl jasmonate 1 ⁇ 3 parts (anti-cold damage, cell membrane integrity), Tecdo 2 to 3 parts (preservative) 2 to 3 parts of sodium hydrogen peroxide (sterilization, bacteria and fungi), 2 to 3 parts of salicylic acid (anti-aging, fog Effect), 1-MCP0.5-1 part (anti-aging, ethylene antagonist, grab target, ethylene can not function).
  • the components are loaded in parts by weight, and the raw materials are dissolved in water, and the amount of water added is 80-100 parts, and the pH is adjusted to about 8. After the ultrasonication, a recovery gas is formed, which is circulated together with the wind circulating in the tunnel pre-cooling box to complete the preservative coverage of the Lingwu long jujube.
  • the device can ensure that the jujube picked in the first time can be placed in the fresh-keeping store to ensure the freshness at all times and the moisture at the moment of locking.
  • the relevant parameters in the preservation process are as follows:
  • Humidity measurement It has been verified by experiments that the internal humidity of the 8 tons of cargo is balanced with the external humidity.
  • the static pre-cooling takes 10 hours, and the open differential pressure pre-cooling takes 8 hours.
  • the simple differential pressure pre-cooling involved in the present invention is only required. 5 hours. It is 2-3 times cold when it is still.
  • Fruit weight loss rate It was verified by experiments that 8 tons of cargo was pre-cooled, the weight loss of static pre-cooled fruit was 1.05%, and the weight loss of open-type differential pressure pre-cooled fruit was 0.83%. The simple differential pressure was 0.65% of the weight loss of the pre-cooling device. Significantly better than the other two ways of encountering cold.
  • the invention can significantly shorten the pre-storage treatment time after the addition of the co-excited bio-inducing anti-preservative, and the time is shortened by 2 times.
  • the preservation time of the preservative agent Lingwu long jujube is 30 days, and the jujube after adding the preservative The preservation time is increased to 90 days, and the shelf life of the goods is extended by 3 times.

Abstract

一种果蔬相温预冷兼容多耦合抗衰老处理装备,该设备包括冷库(11),在冷库(11)内放置多个差压预冷装置,该差压预冷装置包括气密封隧道预冷箱(3),在气密封隧道预冷箱(3)中设置臭氧发生装置(14)和紫外杀菌装置(15)。该设备采用全封闭的形式,能够减少预冷过程中货物水分流失、减少预冷过程中冷量散失以及加快预冷效率。

Description

果蔬相温预冷兼容多耦合抗衰老处理技术及装备
优先权号:201710584178.9,申请日:2017-07-18,优先权国:中国
技术领域
本发明属于果蔬保鲜领域,具体涉及一种果蔬相温预冷兼容多耦合抗衰老处理技术及装备。
背景技术
果蔬保鲜以采后生理病理为基础,温度、湿度、气体和防腐为手段,其中温度作用率约60%-70%,湿度、气体和防腐各占10%-15%,因此,在不产生冷害或冻害条件下,果蔬保鲜温度越低越好,尽快脱除田间热预冷被定为冷链最先1公里,1851年澳大利亚工程师詹姆斯发明的冷库用于果蔬贮藏被誉为技术第一次革命,1927年英国剑桥大学基德和韦斯特发明的CA(气调)库被誉为第二次革命,也有人说1962年美国布格提出的减压贮藏技术或1972年日本山根昭美提出的冰温库贮藏技术为第三次革命。
其中,冷库依靠机械制冷任意降温恒温,温差±0.5-1℃;CA库在冷库基础上任意调节贮藏环境氧和二氧化碳气体浓度;冰温库与冷库原理相同,但控温精度高达减压技术±0.1℃,但是,冷库、气调库、减压库和冰温库技术的共性缺陷是传热又传质,运行时需要不断地使用加湿器加湿,同时冷风机又不断地除霜。
灵武长枣是宁夏具有地方特色的优良鲜果品种,其果实色艳、肉厚、酸甜可口,富含多种维生素和矿物质,尤其VC含量最高,被誉为活“维生素丸”,有“百果之王”的美誉。灵武长枣采后所带的热量较大,较高的品温会增加长枣呼吸强度,最终导致衰老和变质,预冷是保持灵武长枣品质,延长货架期的重要手段之一,通过预冷可以减少产品损耗,节省能源,但是传统冷库库体大,对果蔬数量要求较高,且大量果蔬同时预冷时预冷效率低,预冷耗时长,耗能大。
预冷不能防腐、防霉,在密闭环境下,密闭不能降温,预冷10个小时,黄金处理时间是10小时之内,同时完成防腐防霉,在黄金时间内完成预冷和防腐防霉防衰老。
现有技术的不足之处在于:
1、现有冷库多为静置预冷,传热传质慢,冷量利用率低,预冷耗时长,易造成水分散失;2、果蔬处理方式多为先进行果蔬预冷处理。待处理完后进行保鲜剂处理,容易错过果蔬最佳保鲜期;3、传统隧道差压预冷仅有一种降温方式,无法针对果蔬的品种选取特定的降温方式,如灵武长枣在高温高湿的环境下采取快速降温的方式易产生凹斑病;4、现有技术中预冷中不能加保鲜剂,预冷同时不能加保鲜剂,原因是传热传质。保鲜剂不能起作用,1-MCP,人进去有毒,本申请中每剁都是密闭的独立空间,单元操作。5、传统预冷技术第一大缺陷是传热又传质。冷库静止预冷、差压隧道风预冷、冷水预冷、真空预冷等果蔬预冷技术,共性特点是果蔬预冷降温的同时也不断地失水,预冷过程中降温速度越快失水量越大。6、传统预冷技 术第二大缺陷是环境开发,预冷与抗病抗衰老处理不能兼容。基于上述第一个预冷传热传质缺陷,果蔬预冷过程中,即使是全封闭性箱式工艺技术,制冷系统的冷风机强化换热的同时也吸附环境相的水分、生理调节剂、防腐剂等介质,致使果蔬预冷与抗病抗衰老处理不能兼容执行,也就是说因为降温优先不得不牺牲抗病抗衰老最佳时间,比如乙烯拮抗剂1-MCP(1-甲基环丙烯)最佳处理时间是采后24小时内,而果蔬预冷最佳时间也是采后24小时,因而,不得不选择先预冷再1-MCP处理。7、传统预冷技术第三大缺陷是气调、减压和冰温精准控温不能协同,也就是说气调和减压的同时不能满足较大换热量的精准控温。
据检索,与本申请相关的专利文献,具体公开内容及对比分析如下:
1、对比专利号为CN105794953A,专利名为一种差压预冷系统及方法,主要介绍一种差压预冷系统及方法能够使果蔬迅速冷却,同时在降温过程中补充了果蔬农产品流失的水分,提高了果蔬农产品的保鲜率,存在问题:无法在预冷的同时对果蔬进行保鲜剂处理。
2、对比实用号为CN 205174974 U,实用新型名为,用于猕猴桃的隧道式差压预冷装置,解决了传统的预冷库和催熟库功能单一性的缺点,实现了预冷与催熟一库两用,充分利用了库体使用的空间与时间,降低了建造成本,存在问题:无熏蒸盒,功能单一,只能催熟,无法营造密闭内循环状态。
3、对比实用新型号为CN 204132285 U,实用新型名称为一种微型差压式快速预冷及气体熏蒸装置,该实用新型能同时控气、控湿,结构简单、果蔬存放室容积可调,操作方便,存在问题:虽然解决了预冷和催熟与一体,但无法针对果蔬品种进行预冷处理,容易产生果蔬预冷疾病。
为了解决上述问题,本申请提供一套新的预冷系统,完美解决了上述问题。
发明内容
本发明的目的在于克服现有技术的不足之处,提供一种果蔬相温预冷兼容多耦合抗衰老处理技术及装备,具有预冷快,操作便捷的优点,加入保鲜剂,适合在果园内实时进行预冷。
为解决上述技术问题,本发明采用的技术方案是:
一种果蔬相温预冷兼容多耦合抗衰老处理设备,包括冷库,在冷库内放置多个差压预冷装置,差压预冷装置的结构为:包括气密封隧道预冷箱,在隧道预冷箱内上部与顶壁间隔平行固装一隔板,隔板延伸至隧道预冷箱底部,隔板的一侧与箱体侧壁间隔平行固装一通风板,隔板另一侧端部垂直向下安装一段挡风板,在隧道预冷箱的一个转角安装轴流风机,该转角为隔板与通风板之间的转角,轴流风机的进风口对应隔板上部空间,出风口对应通风板与隧道预冷箱之间的空间;
在隧道预冷箱内设置多个果实框架,位于通风板与挡风板之间,果实框架上叠放灵武长枣果实框;
在隔板上部的隧道预冷箱上臂,阵列密封安装多排真空换热管,真空换热管的一端位于隧道预冷箱内,一端位于冷库内,将冷库内的低温通过真空换热管导入到隧道预冷箱内,实现隧道预冷箱内气密调节下的快速降温;
在隔板上部靠近轴流风机的一侧安装个超声波雾化器,超声波雾化器内填充保鲜剂溶液, 在冷风循环的过程中,将风机将保鲜剂循环到隧道预冷箱的每一个角落;在气密封隧道预冷箱设置臭氧发生装置和紫外杀菌装置;
所述保鲜剂成分为:茉莉酸甲酯1~3份,特克多2~3份、过钠氧化氢2~3份,水杨酸2~3份、1-MCP0.5-1份。
而且,所述超声波雾化器内喷出的保鲜剂溶液微粒的大小为范围0.5-0.8μm。
而且,挡风板的长度为通风板长度的1/3。
而且,保鲜剂的制备步骤如下:将各组分安装重量份数取原料,用水溶解,加水量为80-100份。
而且,所述隧道预冷箱为塑料大帐或采用保温板制作的隧道预冷箱侧壁。
而且,超声波雾化器内喷出的保鲜剂溶液微粒的大小为范围0.5-0.8μm。
本发明具有积极有益的效果:
1、本发明在差压预冷装置上部装有换热管,轴流式排风机从货堆吸收热,热风进入通风管道,换热管将冷库中的冷风与货物中的热风进行交换,可显著提高预冷效率。
2、本发明在预冷的同时在货物中加入分子插层占位功能的保鲜剂,预冷的同时对货物进行保鲜处理,可明显缩短贮藏前处理时间、提高货物保鲜期。
3、本发明改变传统隧道差压预冷装置采用全封闭的形式,用热管不传质,能够把保鲜剂封闭起来,防止保鲜剂挥发,减少预冷过程中货物水分流失、减少预冷过程中冷量散失,加快预冷效率。
4、本发明采用全密闭形式,减少货物水分流失,是静止遇冷得2-3倍,减少冷量散失,在传统隧道差压预冷装置基础上加入换热管,可显著提高预冷效率,比静止预冷提高3-5倍,比开放式差压预冷提高近1倍。在预冷时加入保鲜剂,缩短贮藏前处理时间缩短2倍,货物保鲜期延长1.5倍。显著增加货物的保鲜期
5、本装置为全密闭状态,隧道上端安装有真空换热管,真空管贯穿通风管道伸入隧道内,轴流式排风机抽取隧道内的热风经过换热管,换热管将隧道外冷库冷风与隧道内货物热风进行交换,促使隧道内温度不断降低,形成一个密闭内循环状态,可以明显加快预冷效率,恒温,不加湿,节省能耗。
6、本发明在预冷的同时在预冷装置中加入保鲜剂,高效热传递和预冷黄金期间加入保鲜剂,通过装置密闭内循环,对预冷货物进行保鲜剂处理,达到预冷的同时对货物进行保鲜处理的效果,可明显缩短贮藏前处理时间、提高货物保鲜期。
7、本发明预冷能够快速降温,针对不同果蔬品种有针对性的设定装置的降温速率。
8、传热不传质。制冷系统与预冷降温体系相互独立,果蔬预冷体系气密不保温,其中降温时热量强制交换依靠换热管和轴流风机强制对流协同实现。
9、降温与抗病抗衰老多兼容。预冷降温体系只有热量强制交换,没有介质相互交换或转移,因而,可以在果蔬采后第一时间内,开展预冷同时进行拮抗剂如1-MCP、诱抗剂如茉莉酮酸甲酯、抗病剂如氯化钙、杀菌剂如二氧化硫、臭氧,或物理如静电、电场等保鲜处理,保鲜剂可以是气体,也可以是液体纳米雾化气体。
10、降温与气调、减压和冰温精准控温协同。预冷降温同时可以像气调库一样任意调节气体成分,减压库一样调节压力和冰温库一样温度波动≤±0.1℃。
附图说明
图1为差压预冷装备的结构示意图。
图2为差压预冷系统的结构示意图。
具体实施方式
以下结合具体实施例进一步阐述本发明。下述实施例中所涉及的方法,如无特别说明均为常规方法。
一种果蔬相温预冷兼容多耦合抗衰老处理技术及装备,整个装备的机构包括冷库11,在冷库内放置多个差压预冷装置,差压预冷装置的结构为:包括气密封隧道预冷箱3(不保温),在隧道预冷箱内上部与顶壁间隔平行固装一隔板5,隔板延伸至隧道预冷箱底部,,隔板的一侧与箱体侧壁间隔平行固装一通风板6,通风板上均布通气孔,孔距5cm*5cm每个,直径1cm,隔板另一侧安装一挡风板12(孔距20cm*20cm每个,每个直径为1cm),用于防止循环风从隔板端部倾斜穿过,在隧道预冷箱的一个转角安装轴流风机4,该转角为隔板与通风板之间的转角,轴流风机的进风口对应隔板上部空间,出风口对应通风板与隧道预冷箱之间的空间,流风机开启后,风从通风板穿出,流经枣框,再循环至隔板上部,经过枣框后流出,在返回到隔板上部空间,完成一轮降温循环,实现其在隧道预冷箱内的循环,由于隔板和通风板的存在,在遇冷箱体内上下部产生差压,能够提供循环速率,促进气体循环。
在隧道预冷箱内设置多个果实框架8,位于通风板与挡风板之间,果实框架上叠放灵武长枣果实框7,可设置多排,每排竖直叠放多个,可以实现大批量的一次预冷。其中,挡风板的高度为通风板长度的1/3。
在隔板上部的隧道预冷箱上臂,阵列密封安装多排真空换热管1(5平方厘米每个),真空换热管的一端位于隧道预冷箱内,一端位于冷库内,将冷库内的低温通过真空换热管导入到隧道预冷箱内,实现隧道预冷箱内气密调节下的快速降温,在通过轴流风机的循环,将冷气迅速循环到果实框内。热管通过固定架2固装在隧道预冷箱上。
在隔板上部靠近轴流风机的一侧安装个超声波雾化器9,超声波雾化器内填充保鲜剂溶液,在冷风循环的过程中,将风机将保鲜剂循环到隧道预冷箱的每一个角落,超声波雾化器内喷出的保鲜剂溶液微粒的大小为范围0.5-0.8μm,该大小的微粒能够促进灵武长枣表面的微孔对保鲜剂的吸收,提高保鲜效果。
本申请在隧道预冷箱内层放置一层吸收层10,用于吸附过多的保鲜剂液滴,吸附后,通过清洗吸附层,多余的保鲜剂还能够重复使用,整个装置形成一个全密闭环境。与现有技术的敞开式预冷,具有完全不同的效果,敞开式预冷是不能够加入保鲜剂的,本申请首次完成了再遇冷阶段保鲜剂与果实的深度接触,完成预冷和保鲜两个过程。
所述隧道预冷箱的可以铝板、钢板,厚度1-2mm,为了防止预冷箱倾倒,可以在冷库内设置支撑龙骨13。起到隧道预冷箱的固定和支撑的作用。预冷箱长度和高度如图中表示,宽度2.5-2.6米,热管深入到隧道预冷箱内40-50cm。
真空换热管进行热量交换;长龙堆垛由数筐枣组成;真空换热管尺寸为(外径×壁厚)为φ19mm×2mm,长度为80-100mm,材质为碳钢,内部真空。真空换热管结构为:一根密封的金属管,管内壁覆盖一层有毛细结构的材料的做成的芯网,其中间是空的,管内装有一定的热载体(液氮)。
真空换热管原理:真空换热器当受热端开始受热时,管壁周围液体瞬间汽化,产生蒸汽,此时这部分压力就会变大,蒸汽流就会在压力的牵引下向冷凝端流动,蒸汽流到达冷凝端后冷凝成液体,同时也会放出大量热,最后借助毛细力回到蒸汽受热端完成一次循环。
轴流式排风机额定风量为11000m 3/h,风速为1.6m/s,营造的压差为0.16Pa。每小时风量为隧道预冷箱体积的40-60倍。总换热量为每小时、每立方80-100瓦。
上述装置中还可以加入臭氧发生装置14,能够库内的对果实进行臭氧杀菌。还可以安装一个紫外杀菌装置15,对循环空气进行杀菌。
上述预冷系统中,差压预冷装置在进行预冷1-2小时后,在超声波雾化器中加入分子插层占位诱导保鲜剂,成分如下,以质量份计:茉莉酸甲酯1~3份(防冷害,细胞膜完整性),特克多2~3份(防腐)过钠氧化氢2~3份(杀菌,细菌和真菌),水杨酸2~3份(防老化、雾化效果)、1-MCP0.5-1份(防衰老,乙烯拮抗剂,抢靶位,乙烯起不来作用)。
上述保鲜剂的制备步骤如下:
将各组分安装重量份数取原料,用水溶解,加水量为80-100份,调节pH至8左右。经过超声后形成恢复性气体,与隧道预冷箱内循环的风一起循环,完成对灵武长枣的保鲜剂覆盖。
保鲜剂的使用方法如下:
本装置能够能够保证能够将第一时间摘得的大枣放入的保鲜库中,保证时时刻刻的新鲜,锁住时时刻刻的水分,以灵武长枣为例,通过本冷库保险后,以灵武长枣为例,保鲜过程中的相关参数如下:
湿度测定:经试验验证,使8吨货物内部湿度与外度湿度达到平衡,静止预冷需10个小时,开放式差压预冷需8小时,本发明所涉及的简约差压预冷仅需5小时。是静止遇冷得2-3倍。
温度测定:经试验验证,使8吨货物由20℃降低至0℃,静止预冷需要24小时,开放式差压预冷需要13小时,本发明所设计的简约差压预冷仅需8小时,简约差压预冷装置遇冷效率比静止预冷提高3-5倍,比开放式差压预冷提高近1倍。
果实失重率:经试验验证,预冷8吨货物,静止预冷果实失重1.05%,开放式差压预冷果实失重0.83%,简约差压是预冷装置果实失重0.65%。显著优于其他两种遇冷方式。
通过实验发现,本发明加入共激发型生物诱抗保鲜剂后,可显著缩短贮藏前处理时间,时间缩短2倍,未加保鲜剂灵武长枣保鲜时间为30天,加入保鲜剂后长枣保鲜时间增加到90天,货物保鲜期延长3倍。

Claims (4)

  1. 一种果蔬相温预冷兼容多耦合抗衰老处理设备,包括冷库,其特征在于:在冷库内放置多个差压预冷装置,差压预冷装置的结构为:包括气密封隧道预冷箱,在隧道预冷箱内上部与顶壁间隔平行固装一隔板,隔板延伸至隧道预冷箱底部,隔板的一侧与箱体侧壁间隔平行固装一通风板,隔板另一侧端部垂直向下安装一段挡风板,在隧道预冷箱的一个转角安装轴流风机,该转角为隔板与通风板之间的转角,轴流风机的进风口对应隔板上部空间,出风口对应通风板与隧道预冷箱之间的空间;
    在隧道预冷箱内设置多个果实框架,位于通风板与挡风板之间,果实框架上叠放灵武长枣果实框;
    在隔板上部的隧道预冷箱上臂,阵列密封安装多排真空换热管,真空换热管的一端位于隧道预冷箱内,一端位于冷库内,将冷库内的低温通过真空换热管导入到隧道预冷箱内,实现隧道预冷箱内气密调节下的快速降温;
    在隔板上部靠近轴流风机的一侧安装个超声波雾化器,超声波雾化器内填充保鲜剂溶液,在冷风循环的过程中,将风机将保鲜剂循环到隧道预冷箱的每一个角落;在气密封隧道预冷箱设置臭氧发生装置和紫外杀菌装置;
    所述保鲜剂成分为:茉莉酸甲酯1~3份,特克多2~3份、过钠氧化氢2~3份,水杨酸2~3份、1-MCP 0.5-1份。
  2. 根据权利要求1所述的果蔬相温预冷兼容多耦合抗衰老处理设备,其特征在于:所述超声波雾化器内喷出的保鲜剂溶液微粒的大小为范围0.5-0.8μm。
  3. 根据权利要求1所述的果蔬相温预冷兼容多耦合抗衰老处理设备,其特征在于:挡风板的长度为通风板长度的1/3。
  4. 根据权利要求1所述的果蔬相温预冷兼容多耦合抗衰老处理设备,其特征在于:保鲜剂的制备步骤如下:将各组分安装重量份数取原料,用水溶解,加水量为80-100份。
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