WO2019014968A1 - 基于原位的抗菌织带制备方法 - Google Patents

基于原位的抗菌织带制备方法 Download PDF

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WO2019014968A1
WO2019014968A1 PCT/CN2017/095526 CN2017095526W WO2019014968A1 WO 2019014968 A1 WO2019014968 A1 WO 2019014968A1 CN 2017095526 W CN2017095526 W CN 2017095526W WO 2019014968 A1 WO2019014968 A1 WO 2019014968A1
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cotton fiber
antibacterial
situ
concentration
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何平
李笑
陈小玲
黄科
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江苏金秋弹性织物有限公司
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Abstract

基于原位的抗菌织带制备方法,包括如下内容,将棉纤维进入高碘酸钠内制备得到氧化棉纤维,再浸入聚乙烯亚胺制备得到聚乙烯亚胺接枝棉纤维,再进入硝酸银内制备得到抗菌棉纤维,然后进行织带正常交织形成抗菌织带。该方法制备得到的抗菌肩带,具有很好的耐皂洗度及高效持久的抗菌性,经30次洗涤后,杀菌率仍可以达到95-100%,对织带的自身结构不会破坏,应用广泛,且制备工艺简单。

Description

[根据细则37.2由ISA制定的发明名称] 基于原位的抗菌织带制备方法 技术领域
本发明专利涉及一种织带,具体涉及一种基于原位的抗菌织带制备方法。
背景技术
织带是以各种纱线和弹性芯线为原料制成狭幅状织物或管状织物,广泛用于服饰、鞋材、箱包、工业、农业、军需和交通运输等各产业领域中,在服装领域,织带主要作为文胸肩带或内裤松紧带使用,通常其是直接与皮肤接触,因此就要求服装领域的织带具有柔软性,透气性的要求,而棉纤维的柔软吸湿性能使得其作为织带的最常用纤维。
然而棉纤维制备的棉织品虽然穿着舒适,但其具有较大的比表面积和较强的吸湿能力,导致棉制品极易附着微生物,并为其繁殖和传播创造条件,从而造成纤维强力的损伤、滋生细菌,甚至造成疾病的传播,影响人体的健康。
近年来,纳米技术迅猛发展,一些纳米无机抗菌剂因具备显著的广谱抗菌性能而被应用于纺织服装领域,目前织带的抗菌整理主要采用后整理法,因技术简单,容易实施,而被广泛应用,然而后整理法常常会出现由于纳米银的结合不牢固,而使得整理后织带抗菌效果不够持久,耐洗性较差。
发明内容
发明的目的:本发明的目的在于提供一种基于原位的抗菌织带制备方法,采用原液纺丝法先将棉纤维进行抗菌处理,形成抗菌棉纤维,在进行织带的织造,形成的织带抗菌性能持久性好,多次洗涤后抗菌性能不受过多影响。
本发明采用的技术方案:一种基于原位的抗菌织带制备方法,具体包括如下步骤:
a、将棉纤维置于一定浓度的高碘酸钠溶液中避光氧化反应30-300min,反应温度30-100℃,浴比1:50,得到氧化棉纤维;
b、将氧化棉纤维浸渍在一定浓度的聚乙酰亚胺溶液中,反应温度30-90℃,浴比1:50,得到聚乙酰亚胺接枝棉纤维;
c、将步骤处理后得到的聚乙酰亚胺接枝棉纤维以1:60的浴比浸渍在浓度为0.05-0.25mol/L的硝酸银水溶液中,在25~35℃下,反应1~24小时,在棉纤维表面形成银纳米粒子负载,依次用去离子水和无水乙醇洗涤3次,在40℃下,真空干燥6~10小时,得抗菌棉纤维;
d、使用整经机,分别将加捻66'40D/12F*2高弹尼龙,抗菌棉纤维,及加捻40D/12F高弹尼龙整到盘头上;
e、开启提花机进行胚带交织,其中加捻66'40D/12F*2高弹尼龙和棉纤维混纺作为经线,加捻40D/12F高弹尼龙作为纬线,控制提花机速度为700~800r/min;
f、将交织好的胚带浸入带有环保型乳液状改性丙烯酸酯助剂的染液中进行染色处理,水温为30℃下浸泡5min,在80℃下水洗5min,然后在115℃下水洗5min;
g、包装整理。
作为优选,在所述步骤a中,所述高碘酸钠的浓度0.1-10g/L。
作为优选,在所述步骤b中,所述聚乙酰亚胺溶液的浓度为1-10g/L。
作为优选,在所述步骤e中,加捻66'40D/12F*2高弹尼龙和抗菌棉纤维的混纺比例为1:2。
有益效果:本发明所揭示的一种基于原位的抗菌织带制备方法,先将棉纤维进行抗菌处理,棉纤维经高碘酸钠氧化后,其表面的羟基基团被氧化为醛基甚至羧基,与聚乙酰亚胺表面的氨基发生交联反应,生成聚乙酰亚胺接枝棉纤维,相对于传统的浸渍处理,聚乙酰亚胺与棉纤维两者之间的结合牢度大大提高,同时聚乙酰亚胺和纳米银可实现协同抗菌。
本发明方法制备得到的抗菌肩带,具有很好的耐皂洗度及高效持久的抗菌性,经30次洗涤后,杀菌率仍可以达到95-100%,对织带的自身结构不会破坏,应用广泛,且制备工艺简单。
具体实施方式
下面结合具体实施例对本发明具体实施例进行详细阐述:
实施例1
本发明所揭示的一种基于原位的抗菌织带制备方法,其包括如下步骤:
a、将棉纤维置于浓度为0.1g/L的高碘酸钠溶液中避光氧化反应200min,反应温度80℃,浴比1:50,得到氧化棉纤维;
b、将氧化棉纤维浸渍在浓度为6g/L的聚乙酰亚胺溶液中,反应温度60℃,浴比1:50,得到聚乙酰亚胺接枝棉纤维;
c、将步骤处理后得到的聚乙酰亚胺接枝棉纤维以1:60的浴比浸渍在浓度为0.15mol/L的硝酸银水溶液中,在35℃下,反应14小时,在棉纤维表面形成银纳米粒子负载,依次用去离子水和无水乙醇洗涤3次,在40℃下,真空干燥6小时,得抗菌棉纤维;
d、使用整经机,分别将加捻66'40D/12F*2高弹尼龙,抗菌棉纤维,及加捻40D/12F高弹尼龙整到盘头上;
e、开启提花机进行胚带交织,其中加捻66'40D/12F*2高弹尼龙和棉纤维混纺作为经线,混纺比例为1:2,加捻40D/12F高弹尼龙作为纬线,控制提花机速度为700r/min;
f、将交织好的胚带浸入带有环保型乳液状改性丙烯酸酯助剂的染液中进行染色处理,水温为30℃下浸泡5min,在80℃下水洗5min,然后在115℃下水洗5min;
g、包装整理。
实施例2
本发明所揭示的一种基于原位的抗菌织带制备方法,其包括如下步骤:
a、将棉纤维置于浓度为8g/L的高碘酸钠溶液中避光氧化反应300min,反应温度100℃,浴比1:50,得到氧化棉纤维;
b、将氧化棉纤维浸渍在浓度为2g/L的聚乙酰亚胺溶液中,反应温度90℃,浴比1:50,得到聚乙酰亚胺接枝棉纤维;
c、将步骤处理后得到的聚乙酰亚胺接枝棉纤维以1:60的浴比浸渍在浓度为0.05-0.25 mol/L的硝酸银水溶液中,在20℃下,反应20小时,在棉纤维表面形成银纳米粒子负载,依次用去离子水和无水乙醇洗涤3次,在40℃下,真空干燥9小时,得抗菌棉纤维;
d、使用整经机,分别将加捻66'40D/12F*2高弹尼龙,抗菌棉纤维,及加捻40D/12F高弹尼龙整到盘头上;
e、开启提花机进行胚带交织,其中加捻66'40D/12F*2高弹尼龙和棉纤维混纺作为经线,混纺比例为1:2,加捻40D/12F高弹尼龙作为纬线,控制提花机速度为780r/min;
f、将交织好的胚带浸入带有环保型乳液状改性丙烯酸酯助剂的染液中进行染色处理,水温为30℃下浸泡5min,在80℃下水洗5min,然后在115℃下水洗5min;
g、包装整理。
实施例3
本发明所揭示的一种基于原位的抗菌织带制备方法,其包括如下步骤:
a、将棉纤维置于浓度为10g/L的高碘酸钠溶液中避光氧化反应60min,反应温度30℃,浴比1:50,得到氧化棉纤维;
b、将氧化棉纤维浸渍在浓度为1g/L的聚乙酰亚胺溶液中,反应温度30℃,浴比1:50,得到聚乙酰亚胺接枝棉纤维;
c、将步骤处理后得到的聚乙酰亚胺接枝棉纤维以1:60的浴比浸渍在浓度为0.05mol/L的硝酸银水溶液中,在25℃下,反应3小时,在棉纤维表面形成银纳米粒子负载,依次用去离子水和无水乙醇洗涤3次,在40℃下,真空干燥6小时,得抗菌棉纤维;
d、使用整经机,分别将加捻66'40D/12F*2高弹尼龙,抗菌棉纤维,及加捻40D/12F高弹尼龙整到盘头上;
e、开启提花机进行胚带交织,其中加捻66'40D/12F*2高弹尼龙和棉纤维混纺作为经线,混纺比例为1:2,加捻40D/12F高弹尼龙作为纬线,控制提花机速度为700r/min;
f、将交织好的胚带浸入带有环保型乳液状改性丙烯酸酯助剂的染液中进行染色处理,水温为30℃下浸泡5min,在80℃下水洗5min,然后在115℃下水洗5min;
g、包装整理。
以上所述仅是本发明的优选实施方式,应当指出:对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。

Claims (4)

  1. 一种基于原位的抗菌织带制备方法,其特征在于:具体包括如下步骤:
    a、将棉纤维置于一定浓度的高碘酸钠溶液中避光氧化反应30-300min,反应温度30-100℃,浴比1:50,得到氧化棉纤维;
    b、将氧化棉纤维浸渍在一定浓度的聚乙酰亚胺溶液中,反应温度30-90℃,浴比1:50,得到聚乙酰亚胺接枝棉纤维;
    c、将步骤处理后得到的聚乙酰亚胺接枝棉纤维以1:60的浴比浸渍在浓度为0.05-0.25mol/L的硝酸银水溶液中,在25~35℃下,反应1~24小时,在棉纤维表面形成银纳米粒子负载,依次用去离子水和无水乙醇洗涤3次,在40℃下,真空干燥6~10小时,得抗菌棉纤维;
    d、使用整经机,分别将加捻66'40D/12F*2高弹尼龙,抗菌棉纤维,及加捻40D/12F高弹尼龙整到盘头上;
    e、开启提花机进行胚带交织,其中加捻66'40D/12F*2高弹尼龙和棉纤维混纺作为经线,加捻40D/12F高弹尼龙作为纬线,控制提花机速度为700~800r/min;
    f、将交织好的胚带浸入带有环保型乳液状改性丙烯酸酯助剂的染液中进行染色处理,水温为30℃下浸泡5min,在80℃下水洗5min,然后在115℃下水洗5min;
    g、包装整理。
  2. 根据权利要求1所述的一种基于原位的抗菌织带制备方法,其特征在于:在所述步骤a中,所述高碘酸钠的浓度0.1-10g/L。
  3. 根据权利要求1所述的一种基于原位的抗菌织带制备方法,其特征在于:在所述步骤b中,所述聚乙酰亚胺溶液的浓度为1-10g/L。
  4. 根据权利要求1所述的一种基于原位的抗菌织带制备方法,其特征在于:在所述步骤e中,加捻66'40D/12F*2高弹尼龙和抗菌棉纤维的混纺比例为1:2。
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