WO2018232804A1 - 一种led器件的制备方法 - Google Patents

一种led器件的制备方法 Download PDF

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Publication number
WO2018232804A1
WO2018232804A1 PCT/CN2017/093085 CN2017093085W WO2018232804A1 WO 2018232804 A1 WO2018232804 A1 WO 2018232804A1 CN 2017093085 W CN2017093085 W CN 2017093085W WO 2018232804 A1 WO2018232804 A1 WO 2018232804A1
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quantum dot
led device
microspheres
preparing
graphene
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PCT/CN2017/093085
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English (en)
French (fr)
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王恺
陈威
郝俊杰
徐冰
孙小卫
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广东昭信光电科技有限公司
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Publication of WO2018232804A1 publication Critical patent/WO2018232804A1/zh

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/50—Wavelength conversion elements
    • H01L33/501—Wavelength conversion elements characterised by the materials, e.g. binder
    • H01L33/502—Wavelength conversion materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005—Processes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/52—Encapsulations

Definitions

  • the present invention relates to the field of illumination technologies, and in particular, to a method for fabricating an LED device.
  • quantum dots Due to the wavelength tunability of quantum dots, narrow half-width and high quantum yield, quantum dots are widely used, and these excellent characteristics make quantum dots can be used for wide color gamut display.
  • a general quantum dot-LED (QD-LED) is prepared by uniformly dispersing quantum dots of a specific wavelength in a polymer matrix to form a light conversion layer, and then covering the LED chip to obtain desired luminescence characteristics.
  • this method still encounters many problems, such as: the matching between the quantum dot surface ligand and the polymer is poor; the quantum dot is easily eroded by water and oxygen; and the quantum dot layer cannot effectively utilize the light emission of the LED chip. These factors all lead to low light conversion efficiency and luminous efficiency. More seriously, in high-power LED devices (such as operating currents exceeding 20 mA), QD-LEDs of this structure will inevitably face heat dissipation problems due to poor thermal conductivity.
  • the quantum dots are directly mixed with a resin or a silica gel, and the mixed solution is directly dispensed on the LED chip to be cured to obtain a QD-LED.
  • the method can effectively improve the light conversion efficiency, and more blue light can be converted by the quantum dots, thereby effectively improving the lumen efficiency of the QD-LED.
  • the heat generated at the same time can be effectively conducted by the chip and the substrate.
  • the quantum dots prior to use, the quantum dots must be chemically treated to be compatible with a resin or silica gel matrix. The quantum yield of quantum dots will be greatly reduced, resulting in low luminous efficiency of QD-LEDs.
  • the current quantum dot-LED device manufacturing methods can not achieve high luminous efficiency and high light conversion efficiency, and it is difficult to meet the market demand. Only a method for preparing quantum dot-LED devices with high luminous efficiency and high light conversion efficiency can be found. Meet the needs of the market.
  • the technical problem to be solved by the present invention is to provide a method for preparing a quantum dot-LED device which can prepare high luminous efficiency and high light conversion efficiency.
  • a method of preparing an LED device comprising the steps of:
  • Preparing a quantum dot microsphere solution taking a graphene powder dispersed in a solvent, adding quantum dot microspheres, adding a material for encapsulation, and mixing to obtain a mixed viscous solution;
  • the quantum dot microspheres comprise mesoporous material microspheres and quantum dots dispersed within the mesopores of the mesoporous material microspheres.
  • the mesoporous material microspheres are at least one of mesoporous silica microspheres, mesoporous polymer microspheres, mesoporous molecular sieves, and mesoporous glass spheres.
  • the quantum dot microspheres are prepared by a swelling process.
  • the step of preparing the quantum dot microspheres comprises: taking the mesoporous material microspheres and the quantum dots dispersed in a solvent, heating for a period of time, removing the solvent, and obtaining quantum dots. ball.
  • the material for encapsulation is any one of a silicone resin, an epoxy resin, a UV curable adhesive, and an organic polymer.
  • the organic polymer is any of PMMS, PS.
  • the step of preparing the quantum dot microsphere solution further comprises adding a phosphor to the graphene powder and the quantum dot microspheres to obtain the mixed viscous solution.
  • the graphene powder has a width or length of from 0.1 to 2 ⁇ m.
  • the quantum dot microspheres have a mass fraction of 0.5-20% in the mixed viscous solution.
  • the quantum dot microspheres have a mass fraction of 2% in the mixed viscous solution.
  • Graphene a honeycomb planar film with one or several atomic layer thickness, has excellent physical properties such as high light transmittance, good thermal conductivity, excellent mechanical strength, and good stability, and can be effectively Blocking molecules such as water, oxygen, etc.
  • the present invention provides a method of preparing an LED device, which incorporates graphene into a quantum dot-LED packaging system.
  • graphene and quantum dots are directly mixed for quantum dot-LED devices, graphene will directly recombine with quantum dots, causing quenching of quantum dots.
  • quantum dot microspheres are used instead of quantum dot powders in conventional LED devices.
  • the use of quantum dot microspheres mixed with graphene can prevent quenching of quantum dots, can effectively maintain the luminescent properties of quantum dots, and ensure high light conversion efficiency and high luminous efficiency of LED devices.
  • Figure 1 is a schematic diagram of the preparation process of quantum dot microspheres.
  • Figure 2 is an electron micrograph of a quantum dot microsphere.
  • Figure 3 is a comparison of fluorescence spectra of quantum dot powders and quantum dot microspheres.
  • Figure 4 is a schematic diagram of graphene blocking water oxygen.
  • FIG. 5 is a schematic view showing heat conduction of the QD-LED device of Embodiment 1.
  • Figure 6 is a comparison of long-term lighting stability of different graphene doping amounts.
  • Figure 7 is a fluorescence spectrum of a QD-LED device with a graphene doping amount of 0.03%.
  • the invention provides a preparation method of a quantum dot-LED device (QD-LED device) with high luminous efficiency and high light conversion efficiency, comprising the following steps:
  • FIG. 1 Schematic diagram of the preparation process of quantum dot microspheres is shown in Figure 1.
  • Measure 10 mL of solvent and 2 mL of quantum dot solution (the mass of quantum dots is 0.5-5). Mg, preferably 2 mg)
  • the solvent may be selected from n-hexane, chloroform, ethanol, methanol, etc., and 100 mg of mesoporous material microspheres may be weighed (the size of the microspheres may be 1-60 ⁇ m, and the mesopores are 5-15).
  • the quantum dot solution may be obtained by dispersing any conventional quantum dot powder in a solvent, and may be a red quantum dot, a yellow quantum dot or a green quantum dot. In this embodiment, the quantum dot is a red quantum dot.
  • the mesoporous material microsphere optional mesoporous material microspheres are any one or any of mesoporous silica microspheres, mesoporous polymer microspheres, mesoporous molecular sieves, mesoporous glass spheres, mesopores
  • the polymer microspheres may be selected from mesoporous polymethyl methacrylate microspheres.
  • the mesoporous material microspheres are mesoporous silica microspheres.
  • quantum dot microspheres are prepared by a swelling method, quantum dots and mesoporous silica microspheres are dispersed in a solvent, a solvent is heated, mesoporous silica microspheres are swollen, and quantum dots are dispersed into mesoporous dioxide.
  • the mesoporous or mesoporous surface of silicon, the volatile solvent, and the mesoporous silica shrink, and the quantum dots are confined inside the mesopores to realize the preparation of quantum dot microspheres.
  • the prepared quantum dot microspheres and quantum dot solution were analyzed by fluorescence spectroscopy to obtain a fluorescence spectrum comparison between the quantum dot powder and the quantum dot microspheres.
  • Fig. 3 it can be seen from Fig. 3 that the quantum dots are prepared into quantum dots.
  • the luminous efficiency of the ball is not significantly reduced.
  • the small image in Fig. 3 is the state of the quantum dot microspheres under sunlight and ultraviolet light.
  • the quantum dot microspheres are yellow powder in sunlight and red uniform light powder under ultraviolet light.
  • the graphene is a honeycomb planar film having one or several atomic layer thicknesses, and the width or length of the graphene powder may be selected from 100 nm to 2 ⁇ m, preferably about 500 nm, and the thickness is 5 nm.
  • the diagram of graphene blocking water and oxygen is shown in Fig. 4.
  • Graphene is a lamellar structure covering the quantum dot microspheres. Graphene has excellent water and oxidation resistance, and can block water and oxygen for quantum dot microspheres. Protect it.
  • the mixed viscous solution is used in the LED device, and the mixed viscous solution prepared above can be directly coated on the LED chip and cured at 130 ° C for 30 min to obtain a QD-LED device, and the coating process can be dispensing, Common processes such as spraying.
  • the heat conduction diagram of the obtained QD-LED device is shown in Fig. 5.
  • Graphene has good heat conduction characteristics, and after incorporating graphene, the collective heat dissipation performance of the silicone resin is improved, and the service life of the QD-LED device can be prolonged.
  • the mixed viscous solution may also be solidified to form a quantum dot microsphere composite film, and the quantum dot microsphere composite film is packaged on the LED chip by remote encapsulation to obtain a remote LED device.
  • the QD-LED device was prepared according to the preparation method as described in Example 1, and the doping amount test of graphene was performed to control the graphene to have substantially the same size, the width or length was about 500 nm, and the thickness was 5 nm, and the graphene was changed. And controlling the mass fraction of the graphene powder in the mixed viscous solution to be 0%, 0.01%, 0.03%, 0.05%, and 0.1%, respectively, to obtain a QD-LED device for long-term lighting stability comparison Analysis and comparison of spectral energy distribution of QD-LED devices, the results of comparative analysis of spectral energy distribution are shown in Table 1, and the results of long-term lighting stability comparison analysis are shown in Fig. 6.
  • the luminescence performance is only 31% of the initial value; when the mass fraction of graphene powder is 0.01%-0.05%, the long-term lighting stability of the QD-LED device is improved compared with the QD-LED device without the addition of graphene.
  • the mass fraction of graphene powder is 0.1%, the long-term lighting stability of the QD-LED device is worse than that of the QD-LED device without the addition of graphene, and when the mass fraction of the graphene powder is 0.03%, QD- LED devices have the best stability.
  • FIG. 7 A QD-LED device with a graphene doping amount of 0.03% was subjected to long-term illumination fluorescence spectrum analysis, and FIG. 7 was obtained.
  • the 0h curve in the figure indicates the initial luminescence performance of the QD-LED device, and the 200h curve indicates that the QD-LED device illuminates for 200 hours. After the luminescence performance, it can be seen that the QD-LED device still maintains 112% of the initial luminescence performance after lighting for 200 hours.
  • the small image in Fig. 7 is the lighting effect, and the QD-LED device emits strong red luminescence.
  • the invention provides a preparation method of a white LED device (QD-LED device) with high luminous efficiency and high light conversion efficiency, comprising the following steps:
  • the quantum dot microspheres were prepared by the procedure as described in Example 1.
  • the mesoporous material microspheres were mesoporous molecular sieves, and the quantum dots were selected from red quantum dots.
  • the graphene is a honeycomb planar film having one or several atomic layer thicknesses, and the width or length of the graphene powder may be selected from 100 nm to 2 ⁇ m, preferably about 500 nm, and the thickness is 5 nm.
  • the mixed viscous solution is used in the LED device, and the mixed viscous solution prepared above can be directly coated on the LED chip and cured at 130 ° C for 30 min to obtain a white LED device, and the coating process can be dispensing and spraying.
  • the fluorescence spectrum of the white LED device is shown in Figure 8.

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  • Microelectronics & Electronic Packaging (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
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  • Luminescent Compositions (AREA)

Abstract

一种LED器件的制备方法，将石墨烯引入量子点-LED封装体系。如果将石墨烯与量子点直接混合用于量子点-LED器件，石墨烯会与量子点直接复合，引起量子点的猝灭。制备方法使用了量子点微球代替传统LED器件中的量子点粉末，采用量子点微球与石墨烯混合，能够防止量子点猝灭，可以有效地保持量子点的发光性能，保证LED器件的高光转化效率和高发光效率。

Description

一种LED器件的制备方法
技术领域
本发明涉及照明技术领域，具体涉及一种LED器件的制备方法。
背景技术
由于量子点的波长可调性、窄半峰宽以及高的量子产率，量子点被广泛应用，同时这些优异的特性使得量子点可以用于宽色域显示。
一般的量子点-LED（QD-LED）的制备方法，是将特定波长的量子点均匀分散在聚合物基体中，形成光转换层，而后覆盖在LED芯片上，得到所需的发光特性。但是该方法仍然遇到很多问题，如：量子点表面配体与聚合物之间的匹配性较差；量子点易被水、氧侵蚀；同时量子点层无法有效地利用LED芯片的发光。这些因素都会导致低的的光转换效率和发光效率。更严重的是，在大功率的LED器件中（例如工作电流超过20毫安），这种结构的QD-LED由于比较差的热传导特性，将不可避免的面临散热问题。
另外一种QD-LED制备方法，将量子点直接与树脂或硅胶混合，将混合液直接点胶在LED芯片上，固化得到QD-LED。该方法可以有效的提高光转换效率，更多的蓝光可以被量子点转换，有效的提高QD-LED的流明效率。同时产生的热量可以被芯片及基板有效的传导。但是在使用前，量子点必须进行化学处理，以兼容树脂或硅胶基体。量子点的量子产率将较大的降低，从而引起QD-LED低的发光效率。
综上，目前的量子点-LED器件的制备方法都无法实现高发光效率和高光转化效率，难以满足市场需求，只有找到一种制备高发光效率和高光转化效率的量子点-LED器件的方法才能满足市场的需求。
发明内容
本发明所要解决的技术问题是提供可以制备高发光效率和高光转化效率的量子点-LED器件的制备方法。
本发明所采取的技术方案是：
一种LED器件的制备方法，包括以下步骤：
制备量子点微球溶液：取石墨烯粉末分散于溶剂中，加入量子点微球，再加入用于封装的材料，混合，得到混合粘稠溶液；
将所述混合粘稠溶液用于LED器件中。（权利要求中不能有“等”这类使得保护范围不清楚的词）
在一些优选的实施方式中，所述量子点微球包括介孔材料微球和量子点，所述量子点分散在所述介孔材料微球的介孔内部。
在一些进一步优选的实施方式中，所述介孔材料微球为介孔二氧化硅微球、介孔聚合物微球、介孔分子筛、介孔玻璃球中的至少一种。
在一些进一步优选的实施方式中，所述量子点微球是通过溶胀法制备得到的。
在一些更进一步优选的实施方式中，所述量子点微球的制备步骤包括：取所述介孔材料微球和所述量子点分散在溶剂中，加热一段时间，去除溶剂，得到量子点微球。
在一些优选的实施方式中，所述用于封装的材料为有机硅树脂、环氧树脂、紫外固化胶、有机聚合物中的任一种。
在一些进一步优选的实施方式中，所述有机聚合物为PMMS、PS中的任一种。
在一些优选的实施方式中，所述制备量子点微球溶液的步骤中还包括加入荧光粉与石墨烯粉末、量子点微球混合，得到所述混合粘稠溶液。
在一些优选的实施方式中，所述石墨烯粉末的宽度或长度为0.1-2μm。
在一些优选的实施方式中，所述混合粘稠溶液中所述量子点微球的质量分数为0.5-20%。
在一些进一步优选的实施方式中，所述混合粘稠溶液中所述量子点微球的质量分数为2%。
本发明的有益效果是：
石墨烯，是一种有一个或几个原子层厚度的蜂窝状平面薄膜，具有透光率高、导热导电性能好、优异的机械强度、稳定性好等优异的物理性能，而且同时可以有效地阻挡水、氧等分子，本发明提供了一种LED器件的制备方法，将石墨烯引入量子点-LED封装体系。但是将石墨烯与量子点直接混合用于量子点-LED器件，石墨烯会与量子点直接复合，引起量子点的猝灭，本发明中使用量子点微球代替传统LED器件中的量子点粉末，采用量子点微球与石墨烯混合，能够防止量子点猝灭，可以有效地保持量子点的发光性能，保证LED器件的高光转化效率和高发光效率。
附图说明
图1为量子点微球的制备过程示意图。
图2为量子点微球的电镜图。
图3为量子点粉末与量子点微球的荧光光谱对比图。
图4为石墨烯阻挡水氧示意图。
图5为实施例1的QD-LED器件的热传导示意图。
图6为不同石墨烯掺杂量的长期点亮稳定性对比图。
图7为0.03%石墨烯掺杂量的QD-LED器件荧光光谱图。
图8为实施例3的白光LED器件荧光光谱图。
具体实施方式
实施例1：
本发明提供了一种高发光效率和高光转化效率的量子点-LED器件（QD-LED器件）的制备方法，包括以下步骤：
（1）制备量子点微球
量子点微球的制备过程示意图如图1所示，量取10 mL溶剂、2 mL量子点溶液（其中含有量子点的质量0.5-5 mg，优选2 mg），所述溶剂可选用正己烷、氯仿、乙醇、甲醇等，称取100 mg介孔材料微球（微球大小粒径可选1-60 μm，介孔大小5-15 nm，优选30 μm大小微球，7 nm孔径），60℃下作用一定时间1-4 h，加热除去正己烷，洗涤微球粉末，正己烷、氯仿、乙醇、甲醇等溶剂均可洗涤，优选正己烷，真空干燥得到量子点微球，制成的量子点微球的电镜图如图2所示，微球的粒径为1-60 μm。所述量子点溶液可以是由任意常规的量子点粉末分散于溶剂中得到，可以是红色量子点、黄色量子点或者绿色量子点，在本实施例中，所述量子点是红色量子点。所述介孔材料微球可选介孔材料微球为介孔二氧化硅微球、介孔聚合物微球、介孔分子筛、介孔玻璃球中的任一种或任意几种，介孔聚合物微球可选介孔聚甲基丙烯酸甲酯微球，在本实施例中，所述介孔材料微球是介孔二氧化硅微球。本实施例是采用溶胀法制备得到量子点微球，量子点和介孔二氧化硅微球分散于溶剂中，加热溶剂，介孔二氧化硅微球肿大，量子点分散进入介孔二氧化硅的介孔内部或介孔表面，挥发溶剂，介孔二氧化硅收缩，将量子点局限在介孔内部，实现量子点微球的制备。
将制备得到的量子点微球与量子点溶液进行荧光光谱分析，得到量子点粉末与量子点微球的荧光光谱对比图如图3，从图3中可以看到将量子点制备成量子点微球，其发光效率没有明显降低，图3中小图分别是量子点微球在日光下和紫外光下的状态，量子点微球在日光下呈黄色粉末，在紫外光下呈红色均匀发光粉末。
（2）制备量子点微球溶液
取0.5mg石墨烯粉末加入乙醇的水溶液中，石墨烯是有一个或几个原子层厚度的蜂窝状平面薄膜，石墨烯粉末的宽度或长度可选100nm-2μm，优选500nm左右，厚度为5nm，超声分散30min，加入上述制备得到的量子点微球20mg，再加入1g硅树脂，充分混合均匀，真空脱泡，得到含有均匀分散的石墨烯、量子点微球、硅树脂的混合粘稠溶液。石墨烯阻挡水氧示意图如图4所示，石墨烯为片层结构，覆盖在量子点微球上，石墨烯具有优异的抗水、抗氧性能，可以为量子点微球阻挡水、氧，对其起保护作用。
（3）将所述混合粘稠溶液用于LED器件中
将所述混合粘稠溶液用于LED器件中，可以直接将上述制备得到的混合粘稠溶液涂覆到LED芯片上，130℃固化30min，得到QD-LED器件，涂覆工艺可以是点胶、喷涂等常用工艺。得到的QD-LED器件的热传导示意图如图5所示，石墨烯具有良好的热传导特性，掺入石墨烯后，提高了硅树脂集体的散热性能，可以延长QD-LED器件的使用寿命。
也可以将所述混合粘稠溶液固化形成量子点微球复合薄膜，将量子点微球复合薄膜采用远程封装的方式封装在LED芯片上，制得远程LED器件。
实施例2：
按照如实施例1所述的制备方法制备QD-LED器件，进行石墨烯的掺杂量试验，控制石墨烯的尺寸基本相同，宽度或长度为500nm左右，厚度为5nm，改变石墨烯的投加量，分别控制所述混合粘稠溶液中所述石墨烯粉末的质量分数为0%、0.01%、0.03%、0.05%、0.1%，分别制得QD-LED器件，进行长期点亮稳定性对比分析和QD-LED器件光谱能量分布对比分析，得到光谱能量分布对比分析结果如表1所示，得到长期点亮稳定性对比分析结果如图6所示。
从表1中可以看到，加入石墨烯后，QD-LED器件的出光特性有一定的降低，随着石墨烯掺杂浓度的增大，红光、蓝光及总光谱能量均逐渐降低。由于水气、氧气分子可以侵蚀量子点表面，形成缺陷，从而导致量子点较低的发光效率，引起QD-LED器件发光性能的降低；但是从图6中可以看到，由于石墨烯优异的抗水、抗氧性能，以及良好的热传导特性，掺杂0.03wt%石墨烯的量子点LED，点亮200h后，仍保持112%的初始发光性能；但是没有添加石墨烯的QD-LED器件，其发光性能只有初始值的31%；从当石墨烯粉末的质量分数为0.01%-0.05%时，QD-LED器件的长期点亮稳定性较没有添加石墨烯的QD-LED器件有所提升，而当石墨烯粉末的质量分数为0.1%时，QD-LED器件的长期点亮稳定性较没有添加石墨烯的QD-LED器件更差，而且当石墨烯粉末的质量分数为0.03%时，QD-LED器件的稳定性最佳。
综上，尽管加入石墨烯后，QD-LED器件的出光特性有一定的降低，但是随着石墨烯的加入，能够显著提升QD-LED器件的稳定性，尤其是当石墨烯掺杂量为0.03%时。
表1 不同石墨烯掺杂量的光谱能量分布对比分析结果
石墨烯掺杂量 0 0.01wt% 0.03wt% 0.05wt% 0.1wt%
红光(*10-3 mW) 6.43 5.51 4.46 3.36 1.03
蓝光(*10-3 mW) 6.09 5.84 4.32 3.10 1.90
总光谱(*10-3 mW) 12.52 11.35 8.78 6.46 2.93
取石墨烯掺杂量为0.03%的QD-LED器件进行长期点亮荧光光谱分析，得到图7，图中0h曲线表示QD-LED器件的初始发光性能，200h曲线表示QD-LED器件点亮200h后的发光性能，可以看到QD-LED器件点亮200h后仍保持112%的初始发光性能，图7中小图为点亮效果，QD-LED器件发出较强红色发光。
实施例3：
本发明提供了一种高发光效率和高光转化效率的白光LED器件（QD-LED器件）的制备方法，包括以下步骤：
（1）制备量子点微球
采用如实施例1中所述的步骤制备量子点微球，所述介孔材料微球是介孔分子筛，量子点选用红色量子点。
（2）制备量子点微球溶液
取0.5mg石墨烯粉末加入乙醇的水溶液中，石墨烯是有一个或几个原子层厚度的蜂窝状平面薄膜，石墨烯粉末的宽度或长度可选100nm-2μm，优选500nm左右，厚度为5nm，超声分散30min，加入20mg上述制备得到的量子点微球和25 mgYAG：Ce黄色荧光粉，再加入1g硅树脂，充分混合均匀，真空脱泡，得到含有均匀分散的石墨烯、量子点微球、荧光粉硅树脂的混合粘稠溶液。
（3）将所述混合粘稠溶液用于LED器件中
将所述混合粘稠溶液用于LED器件中，可以直接将上述制备得到的混合粘稠溶液涂覆到LED芯片上，130℃固化30min，得到白光LED器件，涂覆工艺可以是点胶、喷涂等常用工艺，白光LED器件荧光图谱如图8所示，图8中小图为点亮效果，QD-LED器件发出较强白光发光，显色指数CRI（Ra）=91.1，R9=97；发光效率为71 lm/W。

Claims (10)

  1. 一种LED器件的制备方法，其特征在于，包括以下步骤：
    制备量子点微球溶液：取石墨烯粉末分散于溶剂中，加入量子点微球，再加入用于封装的材料，混合，得到混合粘稠溶液；
    将所述混合粘稠溶液用于LED器件中。
  2. 根据权利要求1所述的LED器件的制备方法，其特征在于，所述量子点微球包括介孔材料微球和量子点，所述量子点分散在所述介孔材料微球的介孔内部。
  3. 根据权利要求2所述的LED器件的制备方法，其特征在于，所述介孔材料微球为介孔二氧化硅微球、介孔聚合物微球、介孔分子筛、介孔玻璃球中的至少一种。
  4. 根据权利要求2所述的LED器件的制备方法，其特征在于，所述量子点微球是通过溶胀法制备得到的。
  5. 根据权利要求4所述的LED器件的制备方法，其特征在于，所述量子点微球的制备步骤包括：取所述介孔材料微球和所述量子点分散在溶剂中，加热一段时间，去除溶剂，得到量子点微球。
  6. 根据权利要求1-5任一项所述的LED器件的制备方法，其特征在于，所述用于封装的材料为有机硅树脂、环氧树脂、紫外固化胶、有机聚合物中的任一种。
  7. 根据权利要求6所述的LED器件的制备方法，其特征在于，所述有机聚合物为PMMS、PS中的任一种。
  8. 根据权利要求1-5任一项所述的LED器件的制备方法，其特征在于，所述制备量子点微球溶液的步骤中还包括加入荧光粉与石墨烯粉末、量子点微球混合，得到所述混合粘稠溶液。
  9. 根据权利要求1-5任一项所述的LED器件的制备方法，其特征在于，所述石墨烯粉末的宽度或长度为0.1-2μm。
  10. 根据权利要求1-5任一项所述的LED器件的制备方法，其特征在于，所述混合粘稠溶液中所述量子点微球的质量分数为0.5-20%。
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