WO2018205566A1 - 一种水体生物修复的方法及装置 - Google Patents
一种水体生物修复的方法及装置 Download PDFInfo
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- WO2018205566A1 WO2018205566A1 PCT/CN2017/113881 CN2017113881W WO2018205566A1 WO 2018205566 A1 WO2018205566 A1 WO 2018205566A1 CN 2017113881 W CN2017113881 W CN 2017113881W WO 2018205566 A1 WO2018205566 A1 WO 2018205566A1
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- water body
- aeration
- water
- bioremediation
- microporous
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/348—Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the way or the form in which the microorganisms are added or dosed
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Definitions
- the invention relates to a method and a device for biological repair of water.
- Chinese Patent Application No. 201010539843.0 discloses a method and system for remediation and treatment of a polluted river water body.
- Chinese Patent Application No. 201310006749.2 discloses a polluted water body treatment system and a construction method thereof, which are disclosed in the two patent applications. The methods are all conventional sewage treatment methods to deal with water pollution control, with large workload, low efficiency and large investment.
- the primary object of the present invention is to provide a device for biologically strengthening and repairing water bodies, which can rapidly improve the microbial ecological environment of water bodies.
- the device is suitable for the recovery of black and odorous water bodies in rivers and lakes, and the aeration and activation of aquaculture waters. It is also suitable for industrial sewage treatment and aeration and aeration of urban domestic sewage, and improved aeration of rivers and lakes.
- Another object of the present invention is to provide a method of bioremediation of a water body.
- the method is exposed through micropores High-availability biofilters consisting of a gas aeration system, a carbon fiber eco-based, and a composite microbial generator, rapidly increasing the dissolved oxygen content in the water, forming a high biomass, agitating sediments at the bottom of the river, and causing organic pollution.
- the substances such as rapid degradation of organic matter, nitrification, ammoniation, etc., improve the quality of water, thereby limiting and eliminating the environmental conditions of excessive proliferation of cyanobacteria, achieving the effect of improving and repairing the ecology of the water body, and restoring the self-purification function of the water body.
- a water body biological repairing device comprises a microporous aeration and aeration system, a carbon fiber ecological base, a composite microbial generating device, a circulating fluidized activated flushing system and a tank; the microporous aeration and aeration system is composed of a vortex blower,
- the microporous tube aerator is composed of an aerated oxygen aerator and a microporous aeration tube; the box is divided into four regions from bottom to top and sequentially provided with a microporous tube aerator or aeration increase Oxygen grid, carbon fiber eco-based, composite microbial generating device, and circulating fluidized activated flushing system; wherein the vortex blower is disposed outside the tank and combined with the microporous tube aerator or aerated oxygenation grid, and micropores
- the aeration tube is connected, and the microporous aeration tube is disposed in the area of the composite
- the microporous aeration and aeration system is composed of a vortex blower, a microporous tube aerator or an aerated oxygenation grid (one or only one or less) and a microporous aeration tube.
- the microporous tube aerator diaphragm has a pore size of 80 to 100 microns.
- the microporous aeration has a dissolved oxygen content of 2.0 to 4.0 mg/L.
- the composite microbial generating device is mainly composed of a porous cylindrical stainless steel tube or a porous sintered ceramic tube, a micro-aeration tube, a solidified microbial agent and a filter bed.
- the filter bed is composed of one or more of natural zeolite, ceramsite and volcanic rock filter materials; the curing microbial agent is photosynthetic bacteria, Thiobacillus, actinomycetes, lactic acid bacteria, yeast, Bacillus, anti- One or several of the nitrifying bacteria and the nitrifying bacteria are combined.
- the carbon fiber has an ecological base specific surface area of 1000 to 3000 m 2 /g.
- the carbon fiber ecological-based microbial membrane is fast, the biofilm is easy to fall off, the material is stable, acid and alkali resistant, aging resistant, and the specific surface area is huge.
- the circulating fluidized activated flushing system includes a microcirculating water pump.
- the function of circulating fluidized activation flushing system is to activate the indigenous flora, accelerate the flow of water, increase the dissolved oxygen content of the water body, activate the water body, reduce the loss and input of the composite microorganisms, and secondly, inoculate and proliferate the proliferating flora. Make water Body biological balance; Third, circulating fluidized flushing, so that the filter material gap is smooth, not easy to block.
- the water body bioremediation device is also provided with a floating body.
- the floating body is optional according to the use condition, and is a high-density foam rubber type, and the height of the water body bioremediation device in the polluted water body is adjusted according to the water depth, and is usually placed outside the tank.
- the biological filter tank that is, the inside of the box body needs to be anti-corrosion, and the material such as FRP anti-corrosion or corrosion-resistant stainless steel can be used.
- the lower part of the box body is provided with a polluted water body inlet
- the upper part of the box body is provided with a purified water outlet, wherein the position of the polluted water body inlet is higher than the microporous tube type aerator or the aeration oxygenation grid, and the position of the water outlet after purification Higher than the composite microbial generator.
- a method of biological restoration of water includes the following steps:
- the water body to be treated enters the water body bioremediation device, and the microporous aeration and oxygenation system is used to increase the dissolved oxygen content of the water body through the microporous aeration and aeration system, and the dissolved oxygen content is adjusted to be ⁇ 2 mg/L, preferably controlled at 2.0 ⁇ 4.0mg/L, to stabilize the organic pollutants in the polluted water, ammoniation, nitrification, etc.;
- the water body flows upward through the carbon fiber ecological base to form a biofilm on the carbon fiber ecological base; the indigenous microbial flora is optimized, the sewage substrate is continuously contacted, and adsorption, mass transfer, metabolism and the like are used to purify the sewage;
- the water body treated by the carbon fiber ecological base membrane flows through the composite microbial generating device to convert the macromolecular organic matter in the polluted water body into soluble organic small molecules, and activates the indigenous flora through the circulating fluidized activation system, and utilizes the microorganism pair
- the nitrogen and phosphorus elements in the water body are effectively adsorbed, transformed and degraded, inhibiting the algae reproduction, and completing the bioremediation of the water body.
- the method controls the water body pH ⁇ 7 during the treatment, and the water temperature is 20-35 °C.
- the principle of the invention is as follows: the eutrophication, black odor water body increases the dissolved oxygen content of the water body through microporous aeration and oxygen activation, activates aerobic microorganisms, and stabilizes and degrades the organic pollutants of the polluted water body in a short time. Nitrification and other effects.
- the polluted water enters the bioremediation device and is activated by microporous aeration and reactivation.
- the extracellular enzyme is used to pollute the large molecules in the water body.
- the organic matter is converted into soluble organic small molecules, which are subjected to primary decomposition, absorption and degradation by enzymatic reaction.
- the circulating fluidization activation system activates the indigenous flora, accelerates the proliferation and reproduction of the indigenous beneficial bacteria, and uses microorganisms to carry out nitrogen and phosphorus in the water. Effective adsorption, transformation and degradation, inhibit algae reproduction, bio-enhancement repair water body self-cleaning function, restore ecological balance.
- the present invention has the following advantages and beneficial effects:
- the water body bioremediation device of the invention can be placed in a river or a polluted water body of a lake, and naturally absorbs water in the direction of the aerated water flow to carry out bioremediation of the black and odorous water body; or puts on the land shore and sucks into the black and odorous water body for bioremediation.
- Figure 1 is a schematic view showing the structure of a water body bioremediation device according to the present invention, wherein: 1--contaminated water body inlet, 2-microporous tube aerator, 3-carbon fiber ecological base, 4-complex microbial device, 5-microporous exposure Trachea, 6-purified outlet, 7-vortex blower, 8-microcirculation pump, 9-float.
- a water body bioremediation device as shown in FIG. 1 , comprises a microporous aeration and aeration system, a carbon fiber ecological base 3, a composite microbial generating device 4, a circulating fluidized activation flushing system, and a tank; the microporous exposure
- the gas aeration system is composed of a vortex blower 7, a microporous tube aerator 2 and a microporous aeration tube 5; the tank is divided into four regions from bottom to top and a microporous tube aerator 2 is arranged in turn.
- the microporous tube aerator diaphragm has a pore size of 80 to 100 micrometers.
- the microporous aeration has a dissolved oxygen content of 2.0 to 4.0 mg/L.
- the composite microbial generating device 4 is mainly composed of a porous cylindrical stainless steel tube or a porous sintered ceramic tube, a micro-aeration tube, a solidified microbial agent and a filter bed.
- the filter bed is composed of one or more of natural zeolite, ceramsite and volcanic rock filter materials; the curing microbial agent is photosynthetic bacteria, Thiobacillus, actinomycetes, lactic acid bacteria, yeast, Bacillus, anti- One or several of the nitrifying bacteria and the nitrifying bacteria are combined.
- the carbon fiber eco-based 3 has a specific surface area of from 1,000 to 3,000 m 2 /g.
- the circulating fluidized activation flushing system includes a microcirculation water pump 8.
- the water body bioremediation device is also provided with a floating body 9.
- the floating body is optional according to the use condition, and is a high-density foam rubber type, and the height of the water body bioremediation device in the polluted water body is adjusted according to the water depth, and is usually placed outside the tank.
- the inside of the box needs to be anti-corrosion, and the material such as FRP anti-corrosion or corrosion-resistant stainless steel can be used.
- the lower part of the box body is provided with a polluted water body inlet 1, and the upper part of the box body is provided with a purified water outlet port 6, wherein the position of the polluted water body inlet is higher than the microporous tube type aerator or the aeration oxygenation grid, and the purified water outlet The location is higher than the composite microbial generator.
- the main component of the filter material used in the examples is a natural zeolite of 100 mesh to 200 mesh, and the solidified microbial agent is composed of a main component of photosynthetic bacteria, nitrifying bacteria, lactic acid bacteria, and sulfur bacteria.
- the power is 2.2kw
- the oxygen-enhancing capacity is 4.5 ⁇ 14kg
- the water bioremediation device is 4 cubic volumes. .
- the water transparency is greater than 25cm
- the dissolved oxygen content of the water is DO ⁇ 2mg/L.
- the contents of BOD 5 , CODcr, SS, NH 3 -N, TN and TP in water before and after treatment are shown in Table 2.
- the main component of the filter material used in the examples is a zeolite of 30 to 80 mesh and a volcanic rock.
- the solidified microbial agent is composed of components such as photosynthetic bacteria, Thiobacillus, nitrifying bacteria, denitrifying bacteria, yeast, and Bacillus.
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- Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
Description
项目 | pH值 | 氨氮 | 亚硝酸盐 |
处理前 | 8.3 | 0.4 | 0.6 |
经2个月修复后 | 8.1 | 0.1 | 0.05 |
名称 | BOD5 | CODcr | SS | NH3-N | TN | TP |
原水质数据(mg/L) | 75 | 156 | 43 | 34.8 | 44.4 | 2.6 |
经3个月修复后水质数据(mg/L) | 12.2 | 31.2 | 20 | 2.6 | 11.2 | 0.6 |
Claims (10)
- 一种水体生物修复装置,其特征在于,包括微孔曝气增氧系统、碳素纤维生态基、复合微生物发生装置、循环流化活化冲洗系统以及箱体;所述微孔曝气增氧系统由漩涡鼓风机、微孔管式曝气器或是曝气增氧格、以及微孔曝气管组成;箱体自下而上分为4个区域并依次设置有微孔管式曝气器或是曝气增氧格,碳素纤维生态基,复合微生物发生装置,以及循环流化活化冲洗系统;其中漩涡鼓风机设置在箱体外部并与微孔管式曝气器或是曝气增氧格、以及微孔曝气管连接,微孔曝气管设置在复合微生物发生装置区域。
- 根据权利要求1所述的一种水体生物修复装置,其特征在于,所述微孔管式曝气器膜片孔径为80~100微米。
- 根据权利要求1所述的一种水体生物修复装置,其特征在于,所述复合微生物发生装置主要由多孔圆筒不锈钢管或是多孔烧结陶瓷管,微细增氧管,固化微生物剂和滤床组成。
- 根据权利要求3所述的一种水体生物修复装置,其特征在于,所述滤床为天然沸石、陶粒和火山岩中的一种或几种配伍组成;所述固化微生物剂为光合菌、硫杆菌、放线菌、乳酸菌、酵母菌、芽孢杆菌、反硝化细菌和硝化细菌中的一种或几种。
- 根据权利要求1所述的一种水体生物修复装置,其特征在于,所述碳素纤维生态基比表面积为1000~3000m2/g。
- 根据权利要求1所述的一种水体生物修复装置,其特征在于,所述循环流化活化冲洗系统包括微循环水泵。
- 根据权利要求1所述的一种水体生物修复装置,其特征在于,所述水体生物修复装置还设置有浮体。
- 根据权利要求1所述的一种水体生物修复装置,其特征在于,所述箱体下部设有污染水体入口,箱体上部设有净化后出水口,其中污染水体入口的位 置高于微孔管式曝气器或是曝气增氧格,净化后出水口的位置高于复合微生物发生装置。
- 一种水体生物修复的方法,其特征在于,包括以下步骤:待处理水体进入水体生物修复装置,通过微孔曝气增氧系统进行微孔曝气增氧活化增加水体溶氧量,调节溶解氧含量≥2mg/L;经曝气活化后的水体向上流经碳纤维生态基,在碳纤维生态基上形成生物膜;经碳素纤维生态基挂膜处理后的水体流经复合微生物发生装置,将水体中大分子的有机物转化为可溶性的有机小分子,同时通过循环流化活化系统激活土著菌群,利用微生物对水体中的氮、磷元素进行有效吸附、转化和降解,抑制藻类繁殖,完成水体生物修复。
- 根据权利要求9所述的一种水体生物修复的方法,其特征在于,所述方法在处理过程中控制水体pH≥7,水温在20~35℃。
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CN117125812A (zh) * | 2023-09-13 | 2023-11-28 | 华北水利水电大学 | 一种无污泥好氧池微生物生态修复发生系统及其制作方法 |
CN117125812B (zh) * | 2023-09-13 | 2024-05-17 | 华北水利水电大学 | 一种无污泥好氧池微生物发生系统及其制作方法 |
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