WO2018179895A1 - Composition de shampooing - Google Patents

Composition de shampooing Download PDF

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Publication number
WO2018179895A1
WO2018179895A1 PCT/JP2018/004484 JP2018004484W WO2018179895A1 WO 2018179895 A1 WO2018179895 A1 WO 2018179895A1 JP 2018004484 W JP2018004484 W JP 2018004484W WO 2018179895 A1 WO2018179895 A1 WO 2018179895A1
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Prior art keywords
mass
component
towel drying
content
hair
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PCT/JP2018/004484
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English (en)
Japanese (ja)
Inventor
大沼　克典
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ライオン株式会社
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Priority to MYPI2019005217A priority Critical patent/MY192299A/en
Publication of WO2018179895A1 publication Critical patent/WO2018179895A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • the present invention relates to a shampoo composition.
  • shampoo is to clean the hair and scalp, but many of today's consumers are more foamy, smooth on the fingers, and easier to rinse than those with superior cleaning power that can damage the hair
  • consumers are demanding a touch that feels good.
  • Consumers who do not use a dryer in particular tend to seek good fingering after towel drying and lightness after towel drying because the wet hair state from towel drying to drying lasts for a long time. It is in.
  • the hair is soft and voluminous, and that state continues for a long time.
  • shampoos containing cationic polymers such as quaternary cellulose derivatives, water-soluble collagen derivatives, and polysiloxanes
  • shampoos containing acylated peptides are proposed as techniques for imparting volume to hair after shampooing.
  • cationic polymers such as quaternary cellulose derivatives, water-soluble collagen derivatives, and polysiloxanes
  • shampoos containing acylated peptides are proposed as techniques for imparting volume to hair after shampooing.
  • Patent Documents 2 to 3 have a problem in that the goodness of fingering after towel drying is insufficient and the storage stability at high temperatures cannot be ensured.
  • an object of the present invention is to provide a shampoo composition which is excellent in fingering after towel drying and the lightness of hair after towel drying and excellent in storage stability at high temperatures.
  • a shampoo composition having a mass ratio (C / E) of 1.0 to 3.0 is excellent in fingering after towel drying and lightness of hair after towel drying due to the synergistic effect of each component. It was found that it has storage stability at a high temperature as a preparation.
  • This invention is based on the said knowledge by this inventor, and as a means for solving the said subject, it is as follows. ⁇ 1> (A) 5% by mass to 30% by mass of an anionic surfactant containing polyoxyethylene alkyl ether sulfate, (B) 0.1% by mass to 1.5% by mass of an amidopropyl betaine type amphoteric surfactant, (C) 0.05% by mass to 0.5% by mass of a cationized guar gum having a viscosity of 25 mPa ⁇ s to 1,000 mPa ⁇ s at 25 ° C.
  • the component (A) contains (A1) polyoxyethylene alkyl ether sulfate and (A2) alkyl sulfate, and the content of the component (A1) and the content of the component (A2)
  • ⁇ 5> The shampoo composition according to any one of ⁇ 1> to ⁇ 4>, wherein the component (F) is an emulsion having a number average particle diameter of 10 ⁇ m to 40 ⁇ m.
  • ⁇ 6> The above-mentioned ⁇ 1>, wherein the viscosity at 25 ° C. of the 0.5 mass% aqueous solution of the component (D) neutralized to pH 7 with sodium hydroxide is 40,000 mPa ⁇ s to 62,000 mPa ⁇ s.
  • a shampoo composition having good properties can be provided.
  • the shampoo composition of the present invention comprises (A) an anionic surfactant, (B) an amidopropyl betaine amphoteric surfactant, (C) a cationized guar gum, (D) a carboxyvinyl polymer, (E) It contains sodium chloride and (F) dimethylpolysiloxane, and further contains other components as necessary.
  • the anionic surfactant of the component (A) is contained in order to impart good fingering after towel drying, lightness of hair after towel drying, and storage stability at high temperature.
  • the anionic surfactant of component (A) contains polyoxyethylene alkyl ether sulfate (hereinafter sometimes referred to as “(A1) component”), and alkyl sulfate (hereinafter referred to as “(A2) component”. It is preferable to further contain an anionic surfactant other than the component (A1) and the component (A2).
  • mold anionic surfactant which has a sulfuric acid residue the sulfonate type which has a sulfonic acid residue
  • examples thereof include an anionic surfactant, a carboxylate anionic surfactant having a carboxylic acid residue, and an amino acid salt anionic surfactant having an amino acid salt residue. These may be used alone or in combination of two or more.
  • sulfate type anionic surfactant examples include alkyl sulfates and alkenyl sulfates of the component (A2), polyoxyalkylene alkyl ether sulfates and polyoxyalkylene alkenyl ether sulfates of the component (A1), Polyoxyalkylene alkyl phenyl ether sulfate, glyceride sulfate, amide ether sulfate and the like can be mentioned.
  • sulfonate-type anionic surfactant examples include alkylbenzene sulfonate, sulfosuccinic acid alkyl ester salt, polyoxyalkylene sulfosuccinic acid alkyl ester salt, ⁇ -olefin sulfonate, alkane sulfonate, ⁇ -sulfo Examples include fatty acid ester salts.
  • carboxylate-type anionic surfactant examples include higher fatty acid salts having 10 or more carbon atoms and alkyl ether carboxylates.
  • amino acid salt type anionic surfactant examples include N-acyl-L-glutamate and lauroylmethylalanine salt.
  • the salt is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include alkali metal salts such as sodium and potassium; ammonium; alkanolamine and the like.
  • the polyoxyalkylene alkyl ether sulfate as the component (A1) is an anionic surfactant represented by the following general formula (A1).
  • General formula (A1) [In the general formula (A1), R 1 represents an alkyl or alkenyl group having 10 to 18 carbon atoms, M 1 represents any one of an alkali metal, ammonium, and an alkanolamine, and m represents The number of added moles is an average number of 1 to 5. ]
  • R 1 is preferably an alkyl group having 12 to 16 carbon atoms from the viewpoint of good fingering after towel drying in the shampoo composition and storage stability at high temperature.
  • the m is preferably 2 to 3 from the viewpoint of lightness of the hair after towel drying.
  • the M 1 is particularly preferably ammonium from the viewpoint of lightness of the hair after towel drying.
  • an appropriately synthesized product or a commercially available product may be used as the component (A1).
  • the commercially available products include POE (3) ammonium lauryl ether sulfate (trade name: Texapon ALES 70, manufactured by BASF), POE (2) sodium lauryl ether sulfate (trade name: Sinoline SPE-1250, Shin Nippon Rika) Etc.).
  • the alkyl sulfate of the component (A2) is an anionic surfactant represented by the following general formula (A2).
  • R 2 represents an alkyl group having 10 to 18 carbon atoms, and M 2 represents any one of an alkali metal, ammonium, and alkanolamine.
  • R 2 is preferably an alkyl group having 12 to 16 carbon atoms from the viewpoint of good fingering after towel drying in the shampoo composition and storage stability at high temperature.
  • the M 2 is particularly preferably ammonium from the viewpoint of lightness of the hair after towel drying.
  • an appropriately synthesized product or a commercially available product may be used as the component (A2).
  • the commercially available products include ammonium lauryl sulfate (trade name: Texapon ALS 70, manufactured by BASF), sodium lauryl sulfate (trade name: Texapon K12, manufactured by BASF), and the like.
  • the content of the component (A) is 5 masses with respect to the total amount of the shampoo composition, from the viewpoint of good fingering after towel drying, lightness of hair after towel drying, and storage stability at high temperature. % To 30% by mass, preferably 10% to 25% by mass. When the content of the component (A) is less than 5% by mass, the goodness of fingers after towel drying, the lightness of hair after towel drying, and the storage stability at high temperature deteriorate, and the content is 30% by mass. If it exceeds, the goodness of fingering after towel drying will deteriorate.
  • the mass ratio (A1 / A2) between the content of the component (A1) and the content of the component (A2) 1 to 7 is preferable, and 1.2 to 3 is more preferable from the viewpoints of good passage and lightness of the hair after towel drying.
  • the mass ratio (A1 / A2) is less than 1, the goodness of fingering after towel drying may be deteriorated, and when it is more than 7, the lightness of hair after towel drying may be deteriorated.
  • polyoxyalkylene alkyl ether sulfate ammonium salt As a combination of the component (A1) and the component (A2), polyoxyalkylene alkyl ether sulfate ammonium salt, from the viewpoint of good fingering after towel drying and lightness of hair after towel drying, A combination with an alkyl sulfate ammonium salt is preferred.
  • the content of the component (A1) is based on the total amount of the shampoo composition from the viewpoints of good fingering after towel drying, lightness of hair after towel drying, and storage stability at high temperature.
  • the amount is preferably 3% by mass to 18% by mass and more preferably 6% by mass to 15% by mass with respect to the total amount.
  • the content of the component (A1) is less than 3% by mass, the goodness of fingering after towel drying and storage stability at high temperatures may be deteriorated. Later, the lightness of the hair may worsen.
  • the content of the component (A2) is 2% by mass with respect to the total amount of the shampoo composition, from the viewpoint of good fingering after towel drying, lightness of hair after towel drying, and storage stability at high temperature. It is preferably ⁇ 12% by mass, more preferably 4% by mass to 10% by mass. When the content of the component (A2) is less than 2% by mass, the lightness of the hair after towel drying and storage stability at high temperature may be deteriorated. The goodness of following fingers may be worse.
  • amidopropyl betaine-type amphoteric surfactant of the component (B) is not particularly limited and may be appropriately selected depending on the intended purpose. However, alkylamidopropyl betaines having an alkyl group having 10 to 16 carbon atoms are preferred. .
  • amidopropyl betaine laurate trade name: AMPHITOL 20AB (manufactured by Kao Corporation), trade name: Tego Beta L 10SOK (manufactured by Evonik), trade name: Miteine LPB (manufactured by Miwon) , And product name: Enajicol L-30B (manufactured by Lion Corporation); as palm oil fatty acid amidopropyl betaine, product name: Amphitol 55AB (manufactured by Kao Corporation), product name: Tego Betain L7 (manufactured by Evonik), product name : Mitine CA (manufactured by Miwon), and trade name: MIRATAIN BET C-30 (manufactured by Solvay).
  • coconut oil fatty acid amidopropyl betaine is preferable from the viewpoint of the goodness of fingers after
  • the content of the component (B) is 0. From the viewpoint of good finger-drying after towel drying, lightness of hair after towel drying, and storage stability at high temperature, with respect to the total amount of the shampoo composition. 1% by mass to 1.5% by mass, preferably 0.3% by mass to 1.2% by mass. When the content of the component (B) is less than 0.1% by mass, the goodness of the finger after towel drying is deteriorated, and when it exceeds 1.5% by mass, the lightness of the hair after towel drying, In addition, the storage stability at high temperatures deteriorates.
  • ⁇ (C) Cationized guar gum The cationized guar gum as the component (C) is also referred to as guar hydroxypropyltrimonium chloride, O- [2-hydroxy-3- (trimethylammonio) propyl] guar gum, and the like. And is added to impart storage stability at high temperatures.
  • the viscosity of the component (C) as a viscosity at 25 ° C. of a 1% by mass aqueous solution, from the viewpoint of good fingering after towel drying, lightness of hair after towel drying, and storage stability at high temperature, 25 mPa ⁇ s to 1,000 mPa ⁇ s, preferably 25 mPa ⁇ s to 100 mPa ⁇ s. Those having a viscosity of less than 25 mPa ⁇ s are not marketed. If the viscosity exceeds 1,000 mPa ⁇ s, the lightness of the hair after towel drying becomes worse.
  • a commercial item may be used and what was synthesize
  • the commercial products include JAGUAR series (manufactured by Solvay) such as JAGUAR Excel (300 mPa ⁇ s to 1,000 mPa ⁇ s) and Jaguar C-500 (25 mPa ⁇ s to 65 mPa / s); -N-Hance series (manufactured by Ashland) such as Hance 3299 (25 mPa ⁇ s to 65 mPa ⁇ s).
  • the viscosity (mPa * s) in () shows the viscosity in 25 degreeC of 1 mass% aqueous solution.
  • the viscosity is measured using a viscometer (Brookfield BM type viscometer, manufactured by Tokyo Keiki Co., Ltd.). The measurement can be performed at 30 ° C. for 20 seconds and at 25 ° C. with 3 rotors.
  • a viscometer Brookfield BM type viscometer, manufactured by Tokyo Keiki Co., Ltd.
  • the measurement can be performed at 30 ° C. for 20 seconds and at 25 ° C. with 3 rotors.
  • the content of the component (C) is 0.05% from the viewpoint of good fingering after towel drying, lightness of hair after towel drying, and storage stability at high temperature with respect to the total amount of the shampoo composition. % By mass to 0.5% by mass.
  • the content of the component (C) is less than 0.05% by mass, the goodness of fingers after towel drying and storage stability at high temperatures may be deteriorated, and the content exceeds 0.5% by mass.
  • the lightness of the hair after towel drying may deteriorate.
  • the carboxyvinyl polymer as the component (D) is contained for imparting lightness of hair after towel drying and storage stability at high temperature.
  • the viscosity of the component (D) is the viscosity at 25 ° C. of a 0.5% by weight aqueous solution when neutralized to pH 7 with sodium hydroxide, the lightness of the hair after towel drying, and the storage stability at high temperatures. From this point, 40,000 mPa ⁇ s to 62,000 mPa ⁇ s is preferable, and 43,000 mPa ⁇ s to 62,000 mPa ⁇ s is more preferable. When the viscosity is less than 40,000 mPa ⁇ s, the storage stability at high temperature may be deteriorated, and when it exceeds 62,000 mPa ⁇ s, the lightness of the hair after towel drying may be deteriorated. .
  • a commercial item may be used and what was synthesize
  • the commercially available products include Carbopol Silk 100 (43,000 mPa ⁇ s to 62,000 mPa ⁇ s), Carbopol 980 (40,000 mPa ⁇ s to 60,000 mPa ⁇ s), and Carbopol 940 (40,000 mPa ⁇ s).
  • S-60,000 mPa ⁇ s) (all of which are manufactured by Lubrizol); Hibiswaco 105 (7000 mPa ⁇ s-14,000 mPa ⁇ s) (which is manufactured by Wako Pure Chemical Industries, Ltd.).
  • the viscosity in parentheses indicates the viscosity at 25 ° C. of a 0.5 mass% aqueous solution when neutralized to pH 7 with sodium hydroxide.
  • the viscosity is measured using a viscometer (Brookfield BM type viscometer, manufactured by Tokyo Keiki Co., Ltd.). The measurement can be carried out under the condition of 25 rpm at 30 rpm for 1 minute with 6 rotors.
  • the content of the component (D) is 0.05% from the viewpoint of good finger-handing after towel drying, lightness of hair after towel drying, and storage stability at high temperature with respect to the total amount of the shampoo composition. % By mass to 0.5% by mass, preferably 0.07% by mass to 0.4% by mass. When the content of the component (D) is less than 0.05% by mass, lightness of the hair after towel drying and storage stability at high temperature may be deteriorated, and the content exceeds 0.5% by mass. And the goodness of fingering after towel drying may worsen.
  • component (E) commercially available products may be used, or those appropriately synthesized may be used.
  • Examples of the commercially available products include Japanese Pharmacopoeia sodium chloride “Inui” (manufactured by Kanto Chemical Co., Inc.), NaCL (manufactured by PT. Cheetham Garam Indonesia, Inc.) and the like under the trade name.
  • the content of the component (E) is 0.05 with respect to the total amount of the shampoo composition from the viewpoint of good finger-drying after towel drying, lightness of hair after towel drying, and storage stability at high temperature. % By mass to 0.5% by mass, preferably 0.1% by mass to 0.4% by mass. When the content of the component (E) is less than 0.05% by mass, the goodness of fingering after towel drying may deteriorate, and when the content exceeds 0.5% by mass, the hair after towel drying Lightness and storage stability at high temperature may deteriorate.
  • the dimethylpolysiloxane as the component (F) is contained in order to give good fingering after towel drying.
  • (F) kinematic viscosity at 25 ° C. of the component, towels goodness of finger combability after drying, and in terms of lightness of the hair after towel drying 100,000mm 2 / s ⁇ 1,000,000mm 2 / s 300,000 mm 2 / s to 600,000 mm 2 / s are preferable.
  • the kinematic viscosity is less than 100,000 mm 2 / s, may merit of finger combability after towel drying is deteriorated, when it exceeds 1,000,000 mm 2 / s, the hair after towel dry light May worsen.
  • the component (F) is preferably pre-emulsified with an emulsifier from the viewpoint of production efficiency and dispersion stability of the shampoo composition.
  • an emulsifier and the emulsification method at the time of emulsifying the said (F) component According to the objective, it can select suitably.
  • component (F) component a commercial item may be used and what was synthesize
  • Specific examples of the component (F) commercially available as an emulsion include, under the trade name, BY22-029 [kinematic viscosity of silicone: 100,000 mm 2 / s, number average particle size: 0.5 ⁇ m] (Toray Dow Corning), DC-7137 (silicone kinematic viscosity: 600,000 mm 2 / s, number average particle size: 35 ⁇ m) (manufactured by Dow Corning); KM-902 (silicone kinematic viscosity: 500,000 mm 2 / s) , Number average particle size: 0.5 ⁇ m], X-52-2479 J [kinematic viscosity of silicone: 300,000 mm 2 / s, number average particle size: 25.0 ⁇ m] (above, manufactured by Shin-Etsu Chemical Co., Ltd.); DMS-55 [kinematic viscosity
  • the number average particle diameter of the component (F) in the emulsion is 10 ⁇ m to 40 ⁇ m from the viewpoint of good fingering after towel drying, lightness of hair after towel drying, and storage stability at high temperature. Preferably, 15 ⁇ m to 30 ⁇ m is more preferable. When the number average particle size is less than 10 ⁇ m, the goodness of fingering after towel drying may deteriorate, and when it exceeds 40 ⁇ m, the lightness of the hair after towel drying and storage stability at high temperatures may be obtained. May decrease.
  • the number average particle diameter can be determined by using a laser diffraction method (ISO 13320 / JIS Z 8825-1 compliant) or a Coulter counter particle size distribution measuring apparatus.
  • the content of the component (F) is dimethylpolypropylene based on the total amount of the shampoo composition from the viewpoints of good fingering after towel drying, lightness of hair after towel drying, and storage stability at high temperature. 0.5 mass% to 5 mass% is preferable, and 1 mass% to 3 mass% is more preferable in terms of siloxane purity. When the content is less than 0.5% by mass, the goodness of fingering after towel drying may deteriorate. When the content exceeds 5% by mass, the goodness of fingering after towel drying, The lightness of the hair and the storage stability at high temperatures may deteriorate.
  • Mass ratio (B / D)> As mass ratio (B / D) of said (B) component and said (D), from the point of the goodness of a finger after towel drying, the lightness of the hair after towel drying, and the storage stability at high temperature 1.5 to 20 is preferable, and 3 to 10 is more preferable. If the mass ratio (B / D) is less than 1.5, the goodness of fingering after towel drying may deteriorate, and if it exceeds 20, the hair is light after towel drying and at high temperatures. The storage stability of may deteriorate.
  • the mass ratio (C / E) between the component (C) and the component (E) is 1.0 to 3.0 from the viewpoint of lightness of the hair after towel drying and storage stability at high temperature. Yes, 1.2 to 1.8 is preferable. If the mass ratio (C / E) is less than 1.0, the lightness of the hair after towel drying and storage stability at high temperatures may be deteriorated. Later, the lightness of the hair may worsen.
  • the other components are not particularly limited as long as the effects of the present invention are not impaired, and can be appropriately selected according to the purpose. Examples thereof include various additive components widely used in general shampoo compositions. It is done.
  • hydrocarbons such as liquid paraffin and squalane
  • esters such as isopropyl myristate
  • vegetable oils such as camellia oil, almond oil and jojoba oil
  • plant extracts such as birch extract
  • Nonionic surfactants such as polyoxyethylene alkyl ether, glycerin fatty acid ester, sucrose fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene hydrogenated castor oil; lauric acid amidopropyl hydroxysulfobetaine, Amphoteric surfactants other than the component (B) such as lauryl dimethylamine oxide; gallic acid derivatives; amino acids such as glycine, serine, arginine; pyrrolidone carboxylic acid or salt, herbal medicine, vitamins, glycyrrhizic acid dipotassium Anti-inflammatory agents such as glycyrrhetinic acid; anti-dandruff agents such as piroctone olamine and zinc pyrithione; bactericides such as isopropylmethylphenol and triclosan; tar dyes; ultraviolet absorbers such as oxybenson and 2-ethylhexyl methoxycinnamate; dibutyl Antioxid
  • the pH of the shampoo composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 5.0 to 6.0 at 25 ° C.
  • the pH can be measured, for example, at 25 ° C. using a pH meter (HM-30G, manufactured by Toa DKK Corporation) of the shampoo composition diluted 10 times with purified water.
  • the pH of the shampoo composition can be adjusted using a desired pH adjuster.
  • the pH adjuster is not particularly limited and may be appropriately selected depending on the intended purpose. For example, citric acid, succinic acid, sulfuric acid, sodium hydroxide, potassium hydroxide, 2-amino-2-methyl-1 -Propanol, monoethanolamine, salts thereof and the like.
  • the viscosity of the shampoo composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 1 Pa ⁇ s to 30 Pa ⁇ s at 25 ° C.
  • the viscosity is measured using a viscometer (Brookfield BM type viscometer, manufactured by Tokyo Keiki Co., Ltd.). The measurement can be performed under the condition of 25 ° C. after 30 seconds at 30 rpm with a 4-rotor.
  • the shampoo composition can be used by filling a container.
  • the container is not particularly limited and can be appropriately selected according to the purpose.
  • aluminum laminate tube, EVAL tube, aluminum tube, glass-deposited plastic tube tube, mechanical or differential pressure dispenser container, squeeze Examples include containers, laminate film containers, dropper containers, bottle containers, and pump-type containers.
  • the material of the laminate film include polyethylene, polyethylene terephthalate, polyester, biaxially stretched polypropylene, unstretched polypropylene, polyacrylonitrile, synthetic resin such as ethylene-vinyl acetate copolymer, paper, aluminum vapor-deposited plastic, and the like.
  • the laminate film generally has a multilayer of two or more layers, and is generally preferably 2 to 5 layers in consideration of strength, flexibility, weather resistance and the like.
  • the material of the bottle is appropriately selected from, for example, resins such as polyethylene, polypropylene, polyethylene terephthalate, polystyrene, polyvinyl chloride, ethylene-vinyl alcohol resin, acrylonitrile / styrene resin, ABS resin, polyamide, and glass.
  • the structure of the container is preferably a single layer or a layer structure of two or more layers.
  • the shampoo composition has good finger-handling after towel drying, lightness of hair after towel drying, and good storage stability at high temperatures.
  • shampoo for skin cleansing shampoo for damage care
  • Mild shampoo rinse-in shampoo
  • dandruff removing shampoo and the like.
  • Step 1 After wetting the hair of 20 female panelists with sufficient water, apply the shampoo composition to the hair of the panelists at a usage rate of about 6 g / dose, and massage the scalp with your fingers. Foamed enough to cover with foam.
  • Step 2 Next, using a shower with a flow rate of 250 mL / 3 seconds, it was washed away with tap water at a temperature of 40 ° C.
  • Step 3 Next, the moisture of the hair was sufficiently wiped off with a towel, and then naturally dried.
  • step 3 of the evaluation method the “goodness of fingers after towel drying” immediately after the moisture of the hair was sufficiently wiped with a towel was evaluated based on the following evaluation criteria.
  • step 3 of the evaluation method “lightness of hair after towel drying” immediately after the moisture of the hair was sufficiently wiped off with a towel was evaluated based on the following evaluation criteria.
  • Evaluation criteria are set in four stages according to the number of people judged as “good” for “goodness of finger after towel drying” and “lightness of hair after towel drying”. It was.
  • the shampoo composition of the present invention is excellent in fingering after towel drying and light in hair after towel drying and has good storage stability at high temperature, for example, shampoo for skin cleansing, damage care It can be suitably used for shampoos, mild shampoos, rinse-in shampoos, dandruff shampoos and the like.

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Abstract

L'invention concerne une composition de shampooing comprenant : (A) 5 à 30 % en masse d'un tensioactif anionique; (B) 0,1 à 1,5 % en masse d'un tensioactif amphotère de type amidopropyle bétaïne; (C) 0,05 à 0,5 % en masse d'une gomme de guar cationique; (D) 0,05 à 0,5 % en masse d'un polymère carboxyvinylique; (E) 0,05 à 0,5 % en masse de chlorure de sodium; et (F) un diméthylpolysiloxane, le rapport en masse (C/E) du contenu du composant (C) au contenu du composant (E) étant de 1,0 à 3,0.
PCT/JP2018/004484 2017-03-31 2018-02-08 Composition de shampooing WO2018179895A1 (fr)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007176895A (ja) * 2005-12-28 2007-07-12 Kao Corp 水性毛髪洗浄剤
JP2008115107A (ja) * 2006-11-06 2008-05-22 Kao Corp 水性毛髪洗浄剤
WO2014148245A1 (fr) * 2013-03-21 2014-09-25 ライオン株式会社 Composition de shampooing
WO2015163338A1 (fr) * 2014-04-24 2015-10-29 ライオン株式会社 Composition pour shampooing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007176895A (ja) * 2005-12-28 2007-07-12 Kao Corp 水性毛髪洗浄剤
JP2008115107A (ja) * 2006-11-06 2008-05-22 Kao Corp 水性毛髪洗浄剤
WO2014148245A1 (fr) * 2013-03-21 2014-09-25 ライオン株式会社 Composition de shampooing
WO2015163338A1 (fr) * 2014-04-24 2015-10-29 ライオン株式会社 Composition pour shampooing

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE GNPD "SHAMPOO", XP055555354, retrieved from Mintel Database accession no. ID 4416343 *

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JP6845726B2 (ja) 2021-03-24
JP2018172312A (ja) 2018-11-08

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