WO2018142971A1 - 一体化成形体及びその製造方法 - Google Patents
一体化成形体及びその製造方法 Download PDFInfo
- Publication number
- WO2018142971A1 WO2018142971A1 PCT/JP2018/001605 JP2018001605W WO2018142971A1 WO 2018142971 A1 WO2018142971 A1 WO 2018142971A1 JP 2018001605 W JP2018001605 W JP 2018001605W WO 2018142971 A1 WO2018142971 A1 WO 2018142971A1
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- Prior art keywords
- core layer
- molded body
- resin
- sandwich structure
- fibers
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Definitions
- the present invention is used, for example, as a part or casing portion of a personal computer, OA device, mobile phone, etc., and is suitable for applications that require lightweight, high strength, high rigidity, and thin wall thickness, and an excellent design surface.
- the present invention relates to an integrated molded body and a manufacturing method thereof.
- another structure is joined to a sandwich structure composed of a core layer made of reinforcing fibers and resin, and a skin layer made of reinforcing fibers and resin, and integrally molded.
- Small and light-weight molded structures are known, but such molded structures are required to be thinner and more reliable in joining.
- Patent Literature 1 “a laminated member (II) having a sandwich structure and a laminated member (II) in which a resin member (III) is arranged at least partially around a plate end portion of the laminated member (II).
- a configuration in which the resin member (III) forms a convex shape at least partially with respect to the soft member layer (IIb)” is described. In other words, there is disclosed an effect of “high strength, high rigidity, and thinning”.
- the soft member layer (IIb) a foam material, a resin sheet or the like can be preferably used for weight reduction, and the purpose of using the laminated member (II) having a relatively low compressive strength, such as a foam material, is more in injection molding.
- the object is to easily form the resin member (III) into a convex shape and to reduce the weight of the laminated member (II) (paragraph [0023]).
- the soft member layer (IIb) is joined.
- Patent Document 2 “at least two inclined surfaces in which the fiber reinforced resin A is disposed in a mold as a preform, and the side surfaces contacting the resin B of the fiber reinforced resin A are inclined at different angles from each other.
- a manufacturing method of forming a side surface having a shape before insert molding and supplying the liquefied resin B to insert-mold the fiber reinforced resin A is described. Is difficult to form a closed space in which the resin B hardly flows, and the resin B can flow until it makes good contact over the entire side surface of the fiber reinforced resin A.
- the fiber reinforced resin A and the resin B "Adhesiveness and its reliability are ensured" are disclosed.
- Patent Document 2 there is no description on how to create a side surface having a shape having at least two inclined surfaces inclined concavely at different angles. Certainly, by providing an inclination, the resin B easily flows in insert molding, but it takes time to process a complicated shape that provides the inclination. Moreover, since the inclination of two different angles is provided, it is difficult to make the fiber reinforced resin A thinner.
- a sandwich structure having a core material and a skin material provided on both surfaces of the core material, the core material and the skin material have short fibers dispersed randomly in the matrix resin. It is made of fiber reinforced resin, the reinforcing fiber content in the core material is 20 to 80 wt%, the reinforcing fiber content in the skin material is 30 to 80 wt%, and the flexural modulus of the skin material is required to be 10 GPa or more. And the apparent density of the core material is 0.2 to 1.2 g / cm 3 or more, preferably, the porosity of the skin material is less than 10 vol%, and the porosity of the core material is 10 to 80 vol%.
- Patent Document 3 a mat-like molded body containing reinforcing fibers for a core material and a matrix resin is formed by heating and pressing, and a mat containing reinforcing fibers for a skin material and a matrix resin.
- a method of obtaining a sandwich structure having a light weight and high rigidity by sandwiching a molded article formed by heating and pressing and the description of joining the sandwich structure and another structure is as follows. None has been done or suggested.
- the first member and the second member are disclosed to be bonded via an adhesive layer, and the thermoplastic resin constituting the adhesive layer is It is described that they are integrated by impregnating the reinforcing fiber bundle constituting the fiber reinforcing material (II).
- the first member and the second member are overlapped via the adhesive layer, so the thickness of the joint portion Becomes thicker than the surroundings.
- Patent Document 5 discloses a molding method using the shape restoring force of discontinuous fibers in the core layer. That is, “a skin material made of a non-expandable fiber-reinforced thermoplastic resin is disposed on at least one surface of the core layer to form a molding substrate, and the molding substrate is heated and melted to melt the core layer and the skin. The material is integrated with the discontinuous fibers in the core layer, and the core layer is expanded so that the core layer has a predetermined low density by expressing the shape restoring force of the core layer. Is manufactured in a mold and press-molded ”, whereby“ the core layer has a desired low density, thereby reducing the weight of the structure.
- High mechanical properties of the structure is achieved by setting the desired expansion ratio and appropriately increasing the thickness of the core layer compared to the initial thickness before expansion. Effect is disclosed.
- a structure having high mechanical properties can be obtained by appropriately increasing the thickness of the core layer compared to the initial thickness before expansion, but the structure itself is thinned. Has its limits. Further, there is no suggestion regarding joining the sandwich-like structure and another structure using the function of developing the shape restoring force of the core layer.
- Patent Document 6 An integrated molded body and a method for manufacturing the same are provided (Patent Document 6).
- Patent Document 6 At least a part of a plate end portion of a sandwich structure composed of a core layer made of discontinuous fibers and a thermoplastic resin (A) and a skin layer made of continuous fibers and a resin (B) is used as a joint portion.
- An integrated molded body having a region higher than the rate and a manufacturing method thereof are provided.
- Patent Document 6 it has been found that the following problems still remain with only the technique provided by Patent Document 6 above. That is, in particular, when the integrated molded body shown in FIG. 4 of Patent Document 6 is molded, for example, as shown in FIG. 1, the plate end portion of the sandwich structure 103 composed of the core layer 101 and the skin layer 102 is formed. When the integrated molded body 106 is formed by arranging another structure (C) 105 as the joint 104, the core layer 101 a of the main body 107 other than the joint 104 in the sandwich structure 103 is formed.
- C another structure
- the resin R forming another structure (C) 105 to be joined is placed in the mold 108. Will be injected.
- the injection resin R is supplied to the entire region where the joint 104 is formed. At that time, the heat of the injection resin R is transferred to the internal core layer 101 through the skin layer 102, and the comparison is made in the core layer 101.
- the object of the present invention is to pay attention to the remaining problems in the technology provided by the above-mentioned Patent Document 6 and integrate the sandwich structure and another structure while taking advantage of the technology of Patent Document 6. In this case, it is possible to easily mold excellent design surfaces by preventing the occurrence of sink marks due to heat transfer from the injection resin, light weight, high strength and high rigidity, and different structures.
- An object of the present invention is to provide an integrated molded body having a high bonding strength and capable of being thinned, and a method for manufacturing the same.
- the integrated molded body according to the present invention employs the following configuration.
- a sandwich structure composed of a core layer made of discontinuous fibers and a thermoplastic resin (A) and a skin layer made of continuous fibers and a resin (B) is used as a joint, and the joint
- the sandwich structure has a stepped portion at least at a part of the end portion, and the stepped portion forms a main body portion that forms a high surface in the stepped portion, and a boundary surface that connects a high surface and a low surface of the stepped portion.
- the integrated molded article according to any one of (9).
- the sandwich structure has another step portion in addition to a part of the end portion and the another structure (C) is arranged, and the another step portion is on both sides of the other step portion.
- a main body portion forming a high surface, another boundary surface portion forming another boundary surface connecting a high surface on both sides of the other stepped portion and a low surface positioned between the high surfaces on both sides, and the main body portions on both sides
- the other structure (C) is not in contact with the other boundary surface, and is composed of another thinnest portion having a core layer with a porosity lower than that of the core layer in the core layer.
- the core layer is formed by expanding a core layer precursor composed of discontinuous fibers and a thermoplastic resin (A) in the thickness direction by a springback by heating to form a void.
- the discontinuous fiber constituting the core layer is present as a fiber bundle composed of 500 or less single fibers, and the fiber bundle is randomly oriented, according to any one of (1) to (15) Integrated molded body.
- Discontinuous fibers constituting the core layer are dispersed in the form of monofilaments, discontinuous single fibers (a), and other discontinuous single fibers (b) intersecting the discontinuous single fibers (a).
- the manufacturing method of the integrally molded body which concerns on this invention employ
- At least a part of an end portion of a sandwich structure composed of a core layer made of discontinuous fibers and a thermoplastic resin (A) and a skin layer made of continuous fibers and a resin (B) is used as a bonding portion, and the bonding
- a step of forming a molded body precursor by arranging a skin layer precursor in which the continuous fiber is impregnated with the resin (B) on both surfaces of the core layer precursor [3] A step of heat-press-molding the molded body precursor, solidifying or curing the skin layer precursor to form a skin layer, and integrating the core layer precursor and the skin layer [4] A press die is brought into contact with each other to develop the restoring force of the discontinuous fibers in the core layer precursor to form voids in the core layer and expand the sandwich structure to a predetermined thickness.
- Sandwich structure forming step comprising the thinnest wall portion having a core layer having a porosity lower than the porosity of the core layer in the boundary surface portion and the main body portion [5]
- the shaped sandwich structure is placed in a mold, and the molten resin of another structure (C) is brought into contact with the boundary surface of the joint in the mold.
- the sandwich structure and the other structure (C) are joined by injecting the resin in a state where it is blocked in the middle of the mold so as to be in contact with at least a part of the thinnest wall portion.
- the core layer precursor containing discontinuous fibers and the thermoplastic resin (A) is softened to the thermoplastic resin (A).
- a skin layer precursor in which a skin layer is disposed only in a region corresponding to the main body portion on at least one surface of the core layer is formed, and heated by pressing.
- (18) or (19) wherein the skin layer precursor is solidified or cured to form a skin layer, and the main body portion is expanded to a predetermined thickness and includes a core layer having voids.
- a method for producing an integrated molded body (21) A thermoplastic resin film or non-woven fabric is disposed on the skin layer or core layer constituting the joint, or an adhesive is applied, and then the resin of another structure (C) melted is injection molded.
- a stepped portion is provided at the end of the sandwich structure by forming a portion having a different porosity and different thickness of the core layer, and a part of the stepped portion.
- FIG. It is a general
- molding which shows the remaining problem in patent document 6.
- FIG. It is a schematic perspective view of the integrated molded object which concerns on one Embodiment of this invention.
- FIG. 3 is a schematic cross-sectional view in the thickness direction of the integrated molded body viewed along the line A-A ′ in FIG. 2.
- FIG. 2 It is a general
- the integrated molded body according to the present invention includes at least a part of an end portion of a sandwich structure composed of a core layer composed of discontinuous fibers and a thermoplastic resin (A) and a skin layer composed of continuous fibers and a resin (B). It is an integrated molded body in which another structure (C) is arranged in the joint portion as a joint portion,
- the sandwich structure has a stepped portion at least at a part of the end portion, and the stepped portion forms a main body portion that forms a high surface in the stepped portion, and a boundary surface that connects a high surface and a low surface of the stepped portion.
- It is composed of a thinnest wall portion having a core layer with a porosity lower than the porosity of the core layer in the boundary surface portion and the main body portion, and the another structure (C) is not in contact with the boundary surface, It is an integrated molded body characterized in that it is joined to at least a part of the thinnest portion.
- FIG. 2 shows an integrated molded body according to an embodiment of the present invention
- FIG. 3 shows a schematic cross section in the thickness direction of the integrated molded body seen along the line AA ′ of FIG. Yes.
- the core layer 3 is composed of discontinuous fibers 4 and a thermoplastic resin (A) of matrix resin, and the core layer 3 has a certain size.
- a gap 5 is formed.
- At least a part of the end portion of the sandwich structure 1 is provided with a joint portion 6, and the joint portion 6 has a resin (C) constituting another structure (C) 7 (for convenience, a matrix resin constituting a core layer).
- thermoplastic resin (A) a matrix resin constituting the skin layer as a resin (B), and a matrix resin constituting another structure (C) as a resin (C)).
- a step portion 11 is provided at least at a part of the end portion of the sandwich structure 1, and the step portion 11 includes a main body portion 8 forming a high surface 8 a in the step portion 11, and a high surface 8 a and a low surface of the step portion 11.
- the thinnest wall portion 10 includes a boundary surface portion 9 that forms a boundary surface 9a that connects 10a and a core layer 3b that has a lower porosity than the porosity of the core layer 3a in the main body portion 8.
- the another structure (C) 7 is not in contact with the boundary surface 9a, and is joined to only at least a part of the thinnest portion 10.
- this integrated molded body 100 first, compared to a case where another structure (C) is simply joined to the side flat portion of the sandwich structure, the joining area can be increased, and the effect of increasing the joining strength is obtained. can get.
- Another structural body (C) 7 is bonded to at least a part of 10, and the lower surface side of FIG. 3 is formed on the design surface.
- the joint 6 may be provided over the entire circumference of the sandwich structure 1 or may be provided only at a necessary portion in the circumferential direction of the sandwich structure 1. What is necessary is just to determine according to the use of the integrated molded object 100.
- another structural body (C) 7 in the integrated molded body 100 is not in contact with the boundary surface 9a and is joined to only at least a part of the thinnest portion 10.
- the structure is formed, for example, as shown in FIG. 4 shown in contrast with FIG.
- the shaped sandwich structure 1 is placed in the mold 12, and the resin (C) constituting another structure (C) 7 is injected into the mold 12.
- the resin R injected on the inner surface side of the mold 12 integrally with the mold 12 or separately from the mold 12 is divided into the side surface 10b of the thinnest portion 10 and a part (end) of the upper surface 10a.
- the damming portion 13 is disposed so as to be in contact with only the portion (part of the portion side) and not to contact the boundary surface 9a.
- the resin R is injected so as to be bonded to only a part of the thinnest wall portion 10, so that the boundary layer portion 9 and the core layer 3 in the main body portion 8 as shown in FIG.
- the heat of the injection resin R is transferred, and in the core layer 3 in the region having a relatively large number of voids, the amount of shrinkage of the core layer during cooling is increased.
- the problem that there is a risk of occurrence of a defect such as deformation due to sink due to shrinkage of the resin is solved, and a desired design surface can be reliably obtained.
- the thickness of another structure (C) 7 is changed to the thickness of the main body 8.
- the thickness of the main body portion 8 and the thickness of the portion consisting only of another structure (C) 7 joined via the joint portion 6 are the same. It is possible to make the thickness of the integrated molded body 100 uniform throughout. Alternatively, the thickness and shape of the integrated molded body 100 including another structure (C) 7 within a predetermined range can be obtained. As a result, the entire integrated molded body 100 can be reduced in thickness and weight.
- the porosity of the core layer 3 in the region where the main body portion 8 is formed in the integrated molded body 100 as described above is 50% or more and 80% or less, and the porosity of the core layer 3 in the region where the thinnest portion 10 is formed is 0. % Or more and less than 50%.
- a desired thickness can be formed by providing a certain gap in the core layer and changing the void ratio.
- the porosity of the core layer 3 in the region where the main body portion 8 is formed is preferably 52 to 78%, more preferably 58 to 75%, and still more preferably 60 to 70%. If the porosity is less than 50%, a certain height in the main body portion 8 cannot be secured, and the effect of increasing the bonding strength between the sandwich structure 1 and another structure (C) 7 may be weakened.
- the porosity of the core layer 3 in the region where the thinnest portion 10 is formed is preferably 0 to 45%, more preferably 0 to 40%, and still more preferably 0 to 35%.
- the porosity is 50% or more, a certain height difference cannot be secured between the main body 8 and the effect of increasing the bonding strength between the sandwich structure 1 and another structure (C) may be weakened. .
- the boundary surface 9 a of the boundary surface portion 9 preferably has an angle ⁇ of 1 to 20 ° with respect to the in-plane direction of the main body portion 8.
- the angle ⁇ is 90 °
- the boundary surface 9a of the boundary surface portion 9 rises vertically from the thinnest wall portion 10, but the present invention is also established in such a case as described later.
- This angle ⁇ (°) is more preferably 2 to 10 °, still more preferably 3 to 8 °.
- the length Lb from the end face of the sandwich structure 1 of the joint portion 6 is preferably in the range of 3 to 30 mm.
- the length Lb is preferably in the range of 3 to 30 mm.
- the thickness Db of the main body 8 of the sandwich structure 1 is in the range of 0.4 to 2 mm, and the thickness Tc of the joint 6 is in the range of 0.1 to 1.7 mm.
- Db / Tc is preferably in the range of 1.1-20.
- Db is less than 0.4 mm or Db / Tc is less than 1.1, the bonding strength between the sandwich structure 1 and another structure (C) 7 may be weakened.
- Db exceeds 2 mm or Db / Tc exceeds 20 the sandwich structure 1 may be prevented from being thinned.
- the distance L from the edge of the main body 8 on the side of the boundary surface 9 to another structure (C) 7 joined to at least a part of the thinnest wall 10 is in the range of 0.1 to 30 mm. Is preferred.
- the distance L is less than 0.1 mm, it is difficult to ensure a non-contact state with the boundary surface portion 9 of another structure (C) 7, and when it exceeds 30 mm, the other structure (C) 7 and the main body portion There is a possibility that the space formed between the first and second members becomes too long, resulting in problems in application of the integrated molded body 100.
- the angle ⁇ of the boundary surface 9 a of the boundary surface portion 9 with respect to the in-plane direction of the main body portion 8 can be 90 °, In this case, although it does not substantially appear as a region for forming the boundary surface portion 9, a non-contact state with respect to the boundary surface portion 9 of another structure (C) 7 is secured as illustrated.
- Parameters relating to each shape other than the angle ⁇ in this case are represented in FIG. 6 using the same reference numerals as those used in FIG.
- FIG. 7 shows a case where a bonding layer is provided on the skin layer 2, and illustrates the case where the angle of the boundary surface 9 a of the boundary surface portion 9 described above with respect to the in-plane direction of the main body portion 8 is 90 °.
- the bonding layer 21 is provided in advance on the skin layer 2 constituting the bonding portion 6, and then another structure (C) 7 is formed.
- a stepped portion and a bonding layer 21 can be provided on the upper and lower skin layers 2. With these configurations, the bonding force between the skin layer 2 and another structure (C) 7 can be enhanced.
- the bonding layer 21 an acrylic, epoxy, styrene, nylon, ester or the like adhesive, a thermoplastic resin film, a nonwoven fabric, or the like can be used.
- a thermoplastic resin layer as a bonding layer on the outermost layer of the skin layer 2 or the core layer 3. If the bonding layer 21 provided on the outermost layer of the skin layer 2 or the core layer 3 is made of the same material as that of another structure (C) 7, it is possible to increase the bonding strength.
- the resin provided in the outermost layer of the skin layer 2 or the core layer 3 is not particularly limited as long as it has good compatibility even if it is not the same resin as the adhesive used for the bonding layer.
- Another structure (C) It is preferable to select the most suitable one according to the type of the resin constituting 7.
- the continuous fiber used for the skin layer 2 means a reinforcing fiber continuous in a length of 150 mm or more, preferably 200 mm or more in at least one direction. That is, the discontinuous fiber used in the present invention means a fiber having a length of less than 150 mm.
- the discontinuous fiber used for the core layer 3 is not particularly limited, and examples thereof include metal fibers such as aluminum, brass, and stainless steel, polyacrylonitrile (PAN) -based, rayon-based, lignin-based, and pitch-based carbon.
- Insulating fiber such as fiber, graphite fiber, glass, organic fiber such as aramid resin, polyphenylene sulfide resin, polyester resin, acrylic resin, nylon resin, polyethylene resin, inorganic fiber such as silicon carbide and silicon nitride Is mentioned.
- the surface treatment may be given to these fibers.
- the surface treatment examples include a treatment with a coupling agent, a treatment with a sizing agent, a treatment with a binding agent, and an adhesion treatment of an additive in addition to a process for depositing a metal as a conductor.
- these reinforcing fibers may be used individually by 1 type, and may use 2 or more types together.
- PAN-based, pitch-based, and rayon-based carbon fibers that are excellent in specific strength and specific rigidity are preferably used from the viewpoint of weight reduction effect.
- glass fibers are preferably used from the viewpoint of improving the economical efficiency of the resulting molded article, and it is particularly preferable to use carbon fibers and glass fibers in combination from the balance of mechanical properties and economic efficiency.
- aramid fibers are preferably used from the viewpoint of improving the impact absorbability and formability of the obtained molded product, and it is particularly preferable to use carbon fibers and aramid fibers in combination from the balance of mechanical properties and impact absorbability. Further, from the viewpoint of improving the conductivity of the obtained molded product, reinforcing fibers coated with a metal such as nickel, copper, ytterbium, etc. can also be used. Among these, PAN-based carbon fibers having excellent mechanical properties such as strength and elastic modulus can be used more preferably.
- the type of the thermoplastic resin (A) used for the core layer 3 is not particularly limited, and any of the thermoplastic resins exemplified below can be used.
- polyester resins such as polyethylene terephthalate (PET) resin, polybutylene terephthalate (PBT) resin, polytrimethylene terephthalate (PTT) resin, polyethylene naphthalate (PEN resin), liquid crystal polyester resin, polyethylene (PE) resin, polypropylene ( Polyolefin resins such as PP) resin and polybutylene resin, polyarylene sulfide resins such as polyoxymethylene (POM) resin, polyamide (PA) resin, polyphenylene sulfide (PPS) resin, polyketone (PK) resin, polyether ketone (PEK) ) Resin, polyether ether ketone (PEEK) resin, polyether ketone ketone (PEKK) resin, polyether nitrile (PEN) resin, polytetrafluoro
- PET polyethylene
- crystalline resin such as liquid crystal polymer (LCP), styrene resin, polycarbonate (PC) resin, polymethyl methacrylate (PMMA) resin, polyvinyl chloride (PVC) resin, polyphenylene ether (PPE) resin, Amorphous resin such as polyimide (PI) resin, polyamideimide (PAI) resin, polyetherimide (PEI) resin, polysulfone (PSU) resin, polyethersulfone resin, polyarylate (PAR) resin, etc.
- LCP liquid crystal polymer
- PC polycarbonate
- PMMA polymethyl methacrylate
- PVC polyvinyl chloride
- PPE polyphenylene ether
- Amorphous resin such as polyimide (PI) resin, polyamideimide (PAI) resin, polyetherimide (PEI) resin, polysulfone (PSU) resin, polyethersulfone resin, polyarylate (PAR) resin, etc.
- Resin phenoxy resin, thermoplastic resin such as polystyrene resin, polyolefin resin, polyurethane resin, polyester resin, polyamide resin, polybutadiene resin, polyisoprene resin, fluorine resin, acrylonitrile resin, etc.
- thermoplastic resin such as polystyrene resin, polyolefin resin, polyurethane resin, polyester resin, polyamide resin, polybutadiene resin, polyisoprene resin, fluorine resin, acrylonitrile resin, etc.
- a polyolefin resin is preferable from the viewpoint of light weight of the obtained molded product
- a polyamide resin is preferable from the viewpoint of strength
- an amorphous material such as a polycarbonate resin, a styrene resin, and a modified polyphenylene ether resin from the viewpoint of surface appearance.
- Resin is preferable, polyarylene sulfide resin is preferable from the viewpoint of heat resistance, and polyether ether ketone resin
- the illustrated thermoplastic resin may contain an impact improver such as an elastomer or a rubber component, and other fillers and additives as long as the object of the present invention is not impaired.
- an impact improver such as an elastomer or a rubber component
- other fillers and additives as long as the object of the present invention is not impaired.
- these include inorganic fillers, flame retardants, conductivity imparting agents, crystal nucleating agents, ultraviolet absorbers, antioxidants, vibration damping agents, antibacterial agents, insect repellents, deodorants, anti-coloring agents, heat stabilizers. , Release agents, antistatic agents, plasticizers, lubricants, colorants, pigments, dyes, foaming agents, antifoaming agents, or coupling agents.
- the continuous fibers used in the skin layer 2 can be, for example, the same type of reinforcing fibers as the discontinuous fibers used in the core layer 3 described above.
- the tensile elastic modulus of the continuous fiber is preferably 360 to 1000 GPa, more preferably 500 to 800 GPa from the viewpoint of the rigidity of the sandwich structure.
- the rigidity of the sandwich structure may be inferior.
- the tensile elastic modulus is larger than 1000 GPa, the crystallinity of the reinforcing fiber needs to be increased, and the reinforcing fiber is manufactured. It becomes difficult.
- the tensile elastic modulus of the reinforcing fiber is within the above range, it is preferable from the viewpoint of further improving the rigidity of the sandwich structure and improving the productivity of the reinforcing fiber.
- the tensile elastic modulus of the reinforcing fiber can be measured by a strand tensile test described in JIS R7601-1986.
- the resin (B) used for the skin layer 2 is not particularly limited, and a thermoplastic resin or a thermosetting resin can be used.
- a thermoplastic resin for example, the same type of resin as the thermoplastic resin (A) used in the core layer 3 described above can be used.
- thermosetting resins include unsaturated polyester resins, vinyl ester resins, epoxy resins, phenol (resole type) resins, urea / melamine resins, polyimide resins, maleimide resins, and benzoxazine resins. Resins and the like can be preferably used. For these, a resin in which two or more kinds are blended may be applied.
- an epoxy resin is particularly preferable from the viewpoint of mechanical properties of the molded body and heat resistance.
- the epoxy resin is preferably contained as a main component of the resin to be used in order to express its excellent mechanical properties, and specifically, it is preferably contained by 60% by weight or more per resin composition.
- the resin used for the other structural body (C) is not particularly limited, and the above-described thermoplastic resin or thermosetting resin can be used.
- thermoplastic resin or thermosetting resin can be used.
- PPS resin is used from the viewpoint of heat resistance and chemical resistance
- polycarbonate resin and styrene resin are used from the viewpoint of molded product appearance and dimensional stability
- polyamide resin is used from the viewpoint of strength and impact resistance of the molded product. More preferably used.
- a resin (C) containing reinforcing fibers as the resin (C) used for another structure (C) in order to increase the strength and rigidity of the integrated molded body.
- reinforcing fibers include metal fibers such as aluminum fibers, brass fibers, and stainless fibers, carbon fibers such as polyacrylonitrile, rayon, lignin, and pitch, graphite fibers, glass fibers, silicon carbide fibers, and silicon nitride.
- Inorganic fibers such as fibers, organic fibers such as aramid fibers, polyparaphenylene benzobisoxazole (PBO) fibers, polyphenylene sulfide fibers, polyester fibers, acrylic fibers, nylon fibers, and polyethylene fibers can be used. These reinforcing fibers may be used alone or in combination of two or more.
- carbon fiber is preferable from the viewpoint of the balance of specific strength, specific rigidity, and lightness, and at least polyacrylonitrile-based carbon fiber is preferably included from the viewpoint of excellent specific strength and specific elastic modulus.
- the resin (C) constituting another structure (C) may contain other fillers and additives within a range not impairing the object of the present invention, depending on required properties.
- inorganic fillers non-phosphorous flame retardants, conductivity imparting agents, crystal nucleating agents, ultraviolet absorbers, antioxidants, vibration damping agents, antibacterial agents, insect repellents, deodorants, anti-coloring agents, heat stabilizers , Mold release agents, antistatic agents, plasticizers, lubricants, colorants, pigments, dyes, foaming agents, antifoaming agents, coupling agents and the like.
- the sandwich structure 1 preferably has a rectangular parallelepiped shape having a smaller side area than the bottom area.
- the so-called thin-walled rectangular parallelepiped shape which has a smaller side area compared to the bottom area, such as a PC housing
- the area of the side surface is narrow, and strong bonding strength is required to join another structure to that part. is necessary.
- the joining configuration of the present invention and the joining method described later even if the joint portion has a small area, another structure can be joined with strong strength. .
- the core layer 3 is preferably formed by expanding a core layer precursor composed of discontinuous fibers and the thermoplastic resin (A) in the thickness direction by spring back by heating to form a void. .
- the molded body containing the discontinuous fibers constituting the core layer 3 and the thermoplastic resin (A) is heated and pressurized to a temperature equal to or higher than the softening point or melting point of the resin, then the pressure is released, and the residual stress of the discontinuous fibers Desired voids can be formed in the core layer 3 by expanding with a restoring force to return to the original state upon release, so-called springback.
- the restoration action is suppressed by a certain pressurizing means or the like in a part of the area, the porosity can be suppressed low.
- the discontinuous fibers constituting the core layer 3 are preferably 5 to 75% by mass, and the thermoplastic resin (A) is preferably 25 to 95% by mass.
- the blending ratio between the discontinuous fibers and the thermoplastic resin (A) is one element that specifies the porosity.
- the resin component contained in the core layer 3 is removed and the weight of only the discontinuous fiber remaining is measured. Can be obtained.
- a method for removing the resin component contained in the core layer 3 include a melting method and a burning method.
- the weight can be measured using an electronic scale or an electronic balance.
- the blending ratio of the core layer 3 is preferably 7 to 70% by mass of the discontinuous fibers, 30 to 93% by mass of the thermoplastic resin (A), more preferably 20 to 50% by mass of the discontinuous fibers.
- the resin (A) is 50 to 80% by mass, more preferably 25 to 40% by mass of discontinuous fibers and 60 to 75% by mass of the thermoplastic resin (A). If the discontinuous fibers are less than 5% by mass and the thermoplastic resin (A) is more than 95% by mass, it is difficult for spring back to occur, so that the porosity cannot be increased and the core layer 3 has a different porosity. In some cases, it is difficult to provide the region, and as a result, the bonding strength with another structure (C) 7 also decreases. On the other hand, when the discontinuous fiber is more than 75% by mass and the thermoplastic resin (A) is less than 25% by mass, the specific rigidity of the sandwich structure 1 is lowered.
- the number average fiber length of the discontinuous fibers constituting the core layer is preferably 0.5 to 50 mm.
- the number average fiber length of the discontinuous fibers is preferably 0.8 to 40 mm, more preferably 1.5 to 20 mm, and still more preferably 3 to 10 mm.
- the number average fiber length is shorter than 0.5 mm, it may be difficult to form voids having a certain size or more.
- the number average fiber length is longer than 50 mm, it is difficult to randomly disperse from the fiber bundle, and the core layer 3 cannot generate sufficient spring back, so the size of the gap is limited. The bonding strength with the structure (C) 7 is reduced.
- discontinuous fibers are directly extracted from the discontinuous fiber group and measured by microscopic observation. If the resin is attached to the discontinuous fiber group, dissolve the resin from the discontinuous fiber group using a solvent that dissolves only the resin contained in the discontinuous fiber group, filter the remaining discontinuous fiber, and measure by microscopic observation. If there is no solvent to dissolve the resin, or if there is no solvent to dissolve the resin, burn the resin only in a temperature range where the discontinuous fibers do not oxidize, and separate the discontinuous fibers and measure by microscopic observation (burning off) Law).
- the dissolution method is preferably used because the change in the weight of the discontinuous fibers is small.
- the discontinuous fibers constituting the core layer are present as a fiber bundle composed of 500 or less single fibers and are randomly oriented.
- the discontinuous fibers constituting the core layer are dispersed in a monofilament shape, and the discontinuous single fibers (a) and other discontinuous single fibers (a) intersecting the discontinuous single fibers (a).
- the average value of the two-dimensional orientation angle formed with the fiber (b) is preferably 10 to 80 degrees.
- discontinuous fibers exist in a fiber bundle composed of 500 or less single fibers and are randomly oriented, discontinuous fibers constituting the core layer can intersect and exist, so that a large spring back can be obtained. It is possible to form a void having a certain size or more.
- “dispersed in a monofilament shape” means a ratio of single fibers having a two-dimensional contact angle of 1 degree or more with respect to discontinuous fibers arbitrarily selected in the core layer of the sandwich structure (hereinafter referred to as fibers). (Also referred to as a dispersion ratio) is 80% or more, in other words, in a constituent element, two or more single fibers are in contact with each other and a parallel bundle is less than 20%. Therefore, here, only those in which the weight fraction of the fiber bundle having 100 or less filaments in the core layer composed of at least discontinuous fibers corresponds to 100% are targeted.
- the two-dimensional contact angle is an angle formed by a discontinuous single fiber and a discontinuous single fiber that comes into contact with the discontinuous single fiber. Of the angles to be formed, it is defined as an angle on the acute angle side of 0 degree or more and 90 degrees or less.
- This two-dimensional contact angle will be further described with reference to the drawings.
- 9 (a) and 9 (b) show an embodiment of the present invention, and a schematic diagram when discontinuous fibers in the core layer of the sandwich structure are observed from the plane direction (a) and the thickness direction (b).
- the evaluation target of the two-dimensional contact angle is the discontinuous single fibers 15 to 17, and the two discontinuous single fibers that are in contact with each other are formed.
- the angle 20 is an acute angle side of 0 degree to 90 degrees.
- the method for measuring the two-dimensional contact angle is not particularly limited, and for example, a method of observing the orientation of discontinuous fibers from the surface of the core layer 3 of the sandwich structure 1 can be exemplified. In this case, it becomes easier to observe the discontinuous fibers by polishing the surface of the sandwich structure 1 to expose the discontinuous fibers of the core layer 3. Moreover, the method of imaging
- the core layer 3 is placed at a high temperature in a heating furnace or the like to burn off the thermoplastic resin component.
- Examples of the method of observing the orientation of the discontinuous fibers from the mat made of the discontinuous fibers taken out using an optical microscope or an electron microscope can be exemplified. Based on the observation method, the fiber dispersion rate is measured by the following procedure. With all discontinuous single fibers (discontinuous single fibers 15-17 in FIG. 9) in contact with randomly selected discontinuous single fibers (discontinuous single fibers 14 in FIG. 9) Measure the two-dimensional contact angle. This is performed for 100 discontinuous single fibers, and the total number of all discontinuous single fibers whose two-dimensional contact angle is measured, and the number of discontinuous single fibers whose two-dimensional contact angle is 1 degree or more, and The ratio is calculated from the ratio.
- the discontinuous fibers constituting the core layer 3 are randomly dispersed.
- the term “discontinuous fibers are randomly dispersed” means that the average value of the two-dimensional orientation angles of arbitrarily selected reinforcing fibers in the sandwich structure 1 is 30 to 60 degrees.
- the two-dimensional orientation angle is an angle formed by discontinuous single fibers and discontinuous single fibers intersecting with the discontinuous single fibers, and the discontinuous single fibers intersecting with each other are formed. Of the angles, it is defined as an angle on the acute angle side of 0 degrees or more and 90 degrees or less. This two-dimensional orientation angle will be further described with reference to the drawings.
- the discontinuous single fiber 14 when the discontinuous single fiber 14 is used as a reference, the discontinuous single fiber 14 intersects with other discontinuous single fibers 15-19.
- Crossing here means a state in which a discontinuous single fiber as a reference is observed crossing another discontinuous single fiber in a two-dimensional plane to be observed.
- the continuous single fibers 15 to 19 do not necessarily need to be in contact with each other, and the state observed when they are projected is not an exception. That is, when the discontinuous single fiber 14 serving as a reference is viewed, all of the discontinuous single fibers 15 to 19 are to be evaluated for the two-dimensional orientation angle. In FIG. Of the two angles formed by the two discontinuous single fibers, the angle 20 on the acute angle side is 0 degree or more and 90 degrees or less.
- the method for measuring the two-dimensional orientation angle is not particularly limited.
- a method for observing the orientation of discontinuous fibers from the surface of the component can be exemplified, and the same means as the method for measuring the two-dimensional contact angle described above.
- the average value of the two-dimensional orientation angle is measured by the following procedure. With all the discontinuous single fibers (discontinuous single fibers 15-19 in FIG. 9) intersecting with randomly selected discontinuous single fibers (discontinuous single fibers 14 in FIG. 9) The average value of the two-dimensional orientation angle is measured. For example, in the case where there are many other discontinuous single fibers intersecting a certain discontinuous single fiber, the average value obtained by randomly selecting 20 other discontinuous single fibers that intersect may be used instead. Good. The measurement is repeated a total of 5 times based on another discontinuous single fiber, and the average value is calculated as the average value of the two-dimensional orientation angle.
- the discontinuous fibers are monofilamentally and randomly dispersed, the above-described discontinuous fibers are uniformly dispersed in the core layer 3 rather than being dispersed in a fiber bundle composed of 500 or less single fibers. be able to.
- the sandwich structure 1 may be weak in a region having a lot of voids locally. For this reason, it is preferable that the voids exist in the core layer 3 in a uniformly continuous state from the viewpoint of increasing the strength of the sandwich structure 1.
- the fiber dispersion rate of the core layer 3 made of discontinuous fibers is preferably 90% or more, and more preferably as it approaches 100%. Further, the average value of the two-dimensional orientation angle of the discontinuous fibers is preferably 40 to 50 degrees, and it is more preferable as it approaches 45 degrees which is an ideal angle.
- the discontinuous fiber mat suitably used for the core layer 3 having voids or the molded body in which the discontinuous fibers are impregnated with the thermoplastic resin (A) includes, for example, 500 discontinuous fibers in advance.
- the fiber bundles and / or monofilaments are produced.
- a manufacturing method of the discontinuous fiber mat specifically, an airlaid method in which the discontinuous fiber is formed into a dispersion sheet by an air flow, or a carding method in which the discontinuous fiber is formed by mechanically combing and forming a sheet. Or a dry process using a radrite method in which discontinuous fibers are stirred in water to make paper.
- a method of adjusting the stirring conditions of the discontinuous fibers a method of diluting the reinforcing fiber concentration of the dispersion, a method of adjusting the viscosity of the dispersion, and dispersion
- a method for suppressing vortex flow when transferring the liquid can be exemplified.
- the discontinuous fiber mat is preferably manufactured by a wet method, and the discontinuous fiber mat is adjusted by increasing the concentration of input fibers or adjusting the flow rate (flow rate) of the dispersion and the speed of the mesh conveyor.
- the proportion of reinforcing fibers can be easily adjusted. For example, by slowing down the mesh conveyor with respect to the flow rate of the dispersion liquid, the orientation of the fibers in the resulting mat made of discontinuous fibers becomes difficult to take in the take-off direction, and the mat made of bulky discontinuous fibers It can be manufactured.
- the mat composed of discontinuous fibers may be composed of discontinuous fibers alone, the discontinuous fibers are mixed with a powder or fiber-shaped matrix resin component, or the discontinuous fibers are mixed with an organic compound or an inorganic compound.
- Mixed or discontinuous reinforcing fibers may be sealed with a resin component.
- the present invention uses at least a part of an end portion of a sandwich structure composed of a core layer made of discontinuous fibers and a thermoplastic resin (A) and a skin layer made of continuous fibers and a resin (B) as a joint,
- An integrated molded body manufacturing method in which another structure (C) is bonded to a bonded portion, and comprising at least the following steps [1] to [5]. is there.
- a step of forming a molded body precursor by arranging a skin layer precursor in which the continuous fiber is impregnated with the resin (B) on both surfaces of the core layer precursor [3] A step of heat-press-molding the molded body precursor, solidifying or curing the skin layer precursor to form a skin layer, and integrating the core layer precursor and the skin layer [4] A press die is brought into contact with each other to develop the restoring force of the discontinuous fibers in the core layer precursor to form voids in the core layer and expand the sandwich structure to a predetermined thickness.
- Sandwich structure forming step comprising a thinnest wall portion having a core layer with a porosity lower than the porosity of the core layer in the boundary surface portion and the main body portion [5]
- the shaped sandwich structure is placed in a mold, and the molten resin of another structure (C) is brought into contact with the boundary surface of the joint in the mold.
- the sandwich structure and the other structure (C) are joined by injecting the resin in a state where it is blocked in the middle of the mold so as to be in contact with at least a part of the thinnest wall portion. Integration process
- FIG. 10 [1] shows a step [1] of preparing a core layer precursor 33 in which a thermoplastic resin (A) layer 32 is arranged on both surfaces of a web 31 made of discontinuous fibers.
- the thermoplastic resin (A) layer 32 is preferably a film or a nonwoven fabric from the viewpoint of workability to be laminated with another base material.
- FIG. 10 [2] shows a step [2] in which a skin layer precursor 34 in which continuous fibers are impregnated with resin (B) is disposed on both sides of the core layer precursor 33 to form a molded body precursor.
- the skin layer precursor 34 is preferably, for example, a prepreg in which continuous fibers are impregnated with a resin (B) made of a thermosetting resin or a thermoplastic resin.
- FIG. 10 [3] shows a step [3] in which the core layer precursor 33 and the skin layer precursor 34 are integrated by hot press molding using the upper die 35 and the lower die 36 to form a sandwich structure. Yes.
- the resin (B) used for the skin layer precursor 34 is a thermosetting resin, it is cured or solidified by heating, but in the case of a thermoplastic resin, it is softened by heating. After that, cooling is required to a temperature at which the thermoplastic resin solidifies.
- the pressure when impregnating the web 31 made of discontinuous fibers with the thermoplastic resin (A) layer 32 in the form of a film or a nonwoven fabric is preferably 0.5 to 30 MPa, more preferably 1 to 5 MPa. It is good to do.
- the pressure is lower than 0.5 MPa, the discontinuous fiber web 31 may not be impregnated with the thermoplastic resin (A) layer 32, and when the pressure is higher than 30 MPa, the discontinuous fibers of the core layer precursor 33 may become thermoplastic resin ( A) By flowing through the layer 32, the discontinuous fiber web 31 may be broken.
- the temperature when the thermoplastic resin (A) layer 32 is impregnated with the film or nonwoven fabric is preferably a temperature higher than the melting point or softening point of the thermoplastic resin, and the melting point or softening point + 10 ° C. or higher. More preferably, the melting point or softening point is 20 ° C. or higher.
- the melting point or softening point of the thermoplastic resin is preferably + 150 ° C. or lower.
- the resin (B) is a thermosetting resin
- a prepreg impregnated in continuous fibers is prepared as a skin layer precursor.
- a laminated body in which the skin layer precursor 34 is arranged on at least one surface of the core layer precursor 33 obtained in the step [1] is formed, and this laminated body is heated by hot press molding to give a pressure of 0.5 to 30 MPa.
- the skin layer precursor resin (B) is cured to produce a skin layer.
- the resin (B) is a thermoplastic resin
- the prepreg impregnated in the continuous fiber can be used as the skin layer precursor 34, which is heated by hot press molding to give a pressure of 0.5 to 30 MPa.
- the skin layer can be produced by transporting to a press machine for cooling and pressurizing to a temperature at which the thermoplastic resin is solidified.
- the core layer precursor and the skin layer precursor are simultaneously subjected to hot press molding, so that the discontinuous fiber web of the core layer precursor enters the skin layer and the anchoring effect by the discontinuous fiber web causes the core
- An integrated molded body of the layer precursor and the skin layer precursor can be obtained. It is preferable that the core layer or core layer precursor and the skin layer are firmly adhered from the viewpoint of maximizing the bending characteristics of the sandwich structure.
- a press molding machine and a double belt press can be suitably used as equipment for producing the core layer precursor and the skin layer.
- a batch type it is preferable to apply the former, and when a thermoplastic resin is used, productivity can be improved by using an intermittent press system in which two or more machines for heating and cooling are arranged in parallel.
- productivity can be improved by using an intermittent press system in which two or more machines for heating and cooling are arranged in parallel.
- a continuous type it is preferable to apply the latter, and since continuous processing can be easily performed, the continuous productivity is excellent.
- FIG. 10 [4] A is a diagram illustrating a process of developing the restoring force of the discontinuous fibers in the core layer precursor and expanding it to a predetermined thickness.
- die which provided the shape of the main-body part other than is shown.
- the upper die 35 is changed to a die having a cavity (region) 37 corresponding to the main body portion of the sandwich structure, and the core layer is formed by press molding again.
- the bonding force of the thermoplastic resin (A) to the discontinuous fibers is weakened by heating of the press molding, and then the residual stress of the reinforcing fibers is released by releasing the pressure.
- the internal discontinuous fiber mat is spring-backed, and a core layer having voids whose thickness is adjusted to a predetermined expansion ratio is obtained.
- the main body portion and the joint portion as shown in FIG. It is possible to shape the sandwich structure 1 having regions with different core layer porosity.
- the sandwich structure and the other structure (C) are separately molded in advance and joined together.
- (2) a method in which a sandwich structure is formed in advance and another structure (C) is formed, and at the same time, both are joined.
- a sandwich structure is press-molded and another structure (C) is produced by injection molding.
- welding means such as hot plate welding, vibration welding, ultrasonic welding, laser welding, resistance welding, induction heating welding and the like.
- the sandwich structure is press-molded and then inserted into an injection mold, and the material for forming another structure (C) is injection-molded into the mold and integrated. There is a way to make it. From the viewpoint of mass productivity of the integrally molded product, the method (2) is preferable, and insert injection molding or outsert injection molding is preferably used.
- the voids formed in the core layer are formed by using the core layer precursor containing discontinuous fibers and the thermoplastic resin (A) as the softening of the thermoplastic resin (A). It is preferably formed by heating and pressurizing above the point or melting point, then releasing the pressurization and expanding by springback. In this way, the entire core layer precursor is heated and pressed at once, and the pressure is released, so that even if the sandwich structure having a large area or the joint has a complicated stepped portion, the entire sandwich structure Can be accurately molded at a time.
- the porosity can be controlled by adjusting the thickness of the core layer. As the thickness of the core layer is increased when releasing the pressure, the amount of expansion due to the springback increases, and the porosity formed in the core layer can be increased. Specifically, the cavity height of the upper mold is set to a predetermined core layer height, and when the number of product types increases, the distance between the upper mold and the lower mold is controlled when releasing the pressure. Methods can also be used.
- the skin layer can be deformed along the shape of the upper die region 37 by the spring back of the core layer precursor, but the joint is formed by other methods. be able to.
- a hot air oven and an IR (infrared) heater can be suitably used as equipment for heating the skin layer precursor and the core layer precursor.
- a bonding layer is provided on the skin layer or the core layer of the sandwich structure, and then the resin (C) of another structure melted is injection-molded, so that the peripheral end of the sandwich structure is formed. It is preferable that another structure (C) is joined and integrated by solidifying or curing the injection molding resin (C) at the formed portions having different thicknesses.
- the method of providing the bonding layer on the skin layer or the core layer of the sandwich structure is to apply an adhesive of the same material as that of another structure (C) to the portion formed on the side surface of the peripheral edge of the sandwich structure.
- a method of laminating a film or non-woven fabric of the same material as another structure (C) on the outermost layer of the skin layer or core layer, and integrating the bonding layer with the sandwich structure by hot press molding From the viewpoint of excellent productivity, there is a method in which a film or non-woven fabric of the same material as another structure (C) is laminated on the outermost layer of the skin layer or core layer, and the bonding layer is integrated with the sandwich structure by hot press molding. preferable.
- a stepped portion is formed at the end of the sandwich structure, and another structure (C) is joined only to at least a part of the thinnest portion.
- another structure (C) is joined only to at least a part of the thinnest portion.
- a similar structure can be provided in a portion other than the end of the sandwich structure.
- FIG. 11 as shown in the schematic cross-sectional view in the thickness direction of the integrated molded body 200 showing an example in which another step portion and another structure (C) are provided in addition to the end portion of the sandwich structure, Steps 42 similar to those shown in FIGS.
- FIGS. 2 and 3 are formed on at least a part of the end of the sandwich structure 41, and another structure (C ) 44 is joined, but in this example, the sandwich structure 41 is formed with another step 45 in an arbitrary portion other than a part of the end, and another structure (C) 44.
- a separate structure body (C) 46 is arranged, and this another stepped portion 45 includes a main body portion 47 that forms a high surface 47 a on both sides of the another stepped portion 45, and both sides of the other stepped portion 45.
- Another structure (C) 46 is not in contact with another boundary surface 48 a, and is joined only to at least a part of another thinnest portion 49.
- another boundary surface 48a located on both sides of the stepped portion 45 has the same inclination angle as that shown in FIGS. 2 and 3, and the other structural body (C) 46 is different from the other.
- the thinnest portion 49 is joined to a part of the upper surface of the upper core layer.
- the technique of joining another structure (C) in the present invention to at least a part of the thinnest wall portion without contacting the boundary surface of the boundary surface portion is applied to a portion other than the end portion of the sandwich structure body.
- the possibility of the occurrence of defects on the design surface side due to this can be removed, and a desired integrated molded body can be obtained more reliably and easily.
- FIG. 41 When the technique of the present invention is applied to a portion other than the end portion of the sandwich structure, a part of the end portion of the sandwich structure 41 is shown in FIG.
- the other boundary surface 52a of the other stepped surface portion 52 (one other boundary surface portion 52 in the illustrated example) of the other stepped portion 51 formed in an arbitrary portion other than the upper surface (another surface of the thinnest portion 49)
- the lower surface of the step portion 51 of the step portion 51 rises vertically, and another structure (C) 53 is not in contact with the other boundary surface 48a and the other boundary surface 52a. It is joined to at least a part of the thin portion 49.
- another structure (C) 53 is arrange
- FIG. thus, as long as another structure (C) 53 adopts a structure that does not contact another boundary surface 48a and another boundary surface 52a, the other structure (C) 53 can be disposed at an arbitrary position, and the other stepped portions 45 and 51 are substantially formed. It can be formed into an arbitrary shape, and the other structures (C) 46 and 53 to be joined can also be formed into an arbitrary shape and size.
- a structure applicable to the end portion of the sandwich structure described above for example, the boundary surface of the boundary surface portion is 1 in the in-plane direction of the main body portion.
- Structure having an angle of ⁇ 20 ° structure in which a bonding layer is provided at least in part between the skin layer and another structure (C), and voids in the core layer in the region forming the main body
- another structure (C) Structure with a thickness Tc in the range of 0.1 to 1.7 mm at the joint, Structure with Db / Tc in the range of 1.1 to 20, Thinnest from the boundary side edge of the main body Distance to another structure (C) joined to only at least part of the part L is for the structure in the range of 0.1
- the test piece is set to have a size of 50 mm in length and 25 mm in width in a plane perpendicular to the thickness direction of the integrated molded body so that the joint is in the center in the longitudinal direction.
- the distance between the fulcrums was 32 times the thickness of the test piece, and the bending strength was determined according to ASTM D790, which was defined as the bonding strength.
- ASTM D790 which was defined as the bonding strength.
- the obtained bonding strength was evaluated according to the following criteria.
- a and B were acceptable and C and D were unacceptable.
- Example 1 As shown in FIG. 10 [4] B, when manufacturing a sandwich structure having different core layer porosity between the main body portion and the thinnest wall portion, an upper die 35 having an angle of 4 degrees at the boundary surface portion is used. Thus, a sandwich structure having an interface angle ( ⁇ ) of 4 degrees was obtained.
- the sandwich structure obtained above was set in an injection mold, clamped, and then the molten resin (C) was injection molded to produce an integrated molded body shown in the schematic diagram of FIG. .
- the integrated molded body had high bonding strength, and a good appearance without a design surface side dent in the vicinity of the bonded portion with another structure (C) bonded to the sandwich structure was obtained.
- Table 1 summarizes the characteristics of the integrated molded body.
- Example 2 As shown in FIG. 10 [4] B, when manufacturing a sandwich structure having different core layer porosity between the main body portion and the thinnest wall portion, an upper die 35 having an angle of 90 degrees at the boundary surface portion is used. As a result, a sandwich structure having an interface angle ( ⁇ ) of 90 degrees was obtained.
- the sandwich structure obtained above was set in an injection mold, clamped, and then the molten resin (C) was injection molded to produce an integrated molded body shown in the schematic diagram of FIG. .
- the integrated molded body had high bonding strength, and a good appearance without a design surface side dent in the vicinity of the bonded portion with another structure (C) bonded to the sandwich structure was obtained.
- Table 1 summarizes the characteristics of the integrated molded body.
- Example 3 As shown in FIG. 10 [4] B, when manufacturing a sandwich structure having different core layer porosity between the main body portion and the thinnest wall portion, an upper die 35 having an angle of 2 degrees at the boundary surface portion is used. As a result, a sandwich structure having an interface angle ( ⁇ ) of 2 degrees was obtained.
- the sandwich structure obtained above was set in an injection mold, clamped, and then the molten resin (C) was injection molded to produce an integrated molded body shown in the schematic diagram of FIG. .
- the integrated molded body had high bonding strength, and a good appearance without a design surface side dent in the vicinity of the bonded portion with another structure (C) bonded to the sandwich structure was obtained.
- Table 1 summarizes the characteristics of the integrated molded body.
- Example 4 As shown in FIG. 10 [4] B, when manufacturing a sandwich structure in which the porosity of the core layer of the main body portion and the thinnest wall portion is different, the upper die 35 having an angle of 18 degrees at the boundary surface portion is used. Thus, a sandwich structure having an interface angle ( ⁇ ) of 18 degrees was obtained.
- the sandwich structure obtained above was set in an injection mold, clamped, and then the molten resin (C) was injection molded to produce an integrated molded body shown in the schematic diagram of FIG. .
- the integrated molded body had high bonding strength, and a good appearance without a design surface side dent in the vicinity of the bonded portion with another structure (C) bonded to the sandwich structure was obtained.
- Table 1 summarizes the characteristics of the integrated molded body.
- the sandwich structure was produced in the same manner as in Example 1. After the obtained sandwich structure is set in an injection mold and clamped, when the molten resin (C) is injection molded, the length (Lb) of the joint is as short as 2 mm. An integrated molded body shown in the schematic diagram of FIG. 5 was produced. Although the good appearance without the design surface side dent in the vicinity of the joint portion with another structure (C) joined to the sandwich structure was obtained, the joint strength of the integrally molded product was low and did not reach the acceptable level. As a result, it was found from the comparison with Example 3 that the joint strength (Lb) is preferably 3 mm in order to make the joint strength acceptable. Table 1 summarizes the characteristics of the integrated molded body.
- Example 1 The sandwich structure was produced in the same manner as in Example 1. When the obtained sandwich structure is set in an injection mold, clamped, and then the molten resin (C) is injection molded, another structure as shown in FIG. An integrated molded body joined with (C) was produced. Although the integrated molded body has high bonding strength, the design surface side dent in the vicinity of the bonded portion with another structure (C) bonded to the sandwich structure was large. Table 1 summarizes the characteristics of the integrated molded body.
- Example 2 A sandwich structure was produced in the same manner as in Example 4. After the obtained sandwich structure was set in an injection mold and clamped, when the molten resin (C) was injection molded, the length (Lb) of the joint was as short as 2 mm, As shown in FIG. 1, an integrated molded body in which another structure (C) was joined to the boundary surface portion was manufactured. The integrated molded body had low bonding strength and did not reach the acceptable level. Moreover, the design surface side dent of the junction part vicinity with another structure (C) joined to the sandwich structure was also large. Table 1 summarizes the characteristics of the integrated molded body.
- the integrated molded body and the method for producing the same according to the present invention can be applied to any application that requires light weight, high strength, high rigidity, and thinning.
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Abstract
Description
(1)不連続繊維と熱可塑性樹脂(A)からなるコア層及び連続繊維と樹脂(B)からなるスキン層から構成されるサンドイッチ構造体の少なくとも端部の一部を接合部とし、前記接合部に別の構造体(C)を配した一体化成形体であって、
前記サンドイッチ構造体は少なくとも端部の一部に段差部を有し、該段差部は、該段差部における高い面を形成する本体部、段差部の高い面と低い面をつなぐ境界面を形成する境界面部及び前記本体部におけるコア層の空隙率よりも低い空隙率のコア層を有する最薄肉部から構成され、かつ、前記別の構造体(C)は前記境界面に接しておらず、前記最薄肉部の少なくとも一部のみと接合されていることを特徴とする一体化成形体。
(2)前記境界面部の境界面は、前記本体部の面内方向に対して、1~20°の角度を有している、(1)に記載の一体化成形体。
(3)前記スキン層と前記別の構造体(C)との間の少なくとも一部に接合層が設けられている、(1)または(2)に記載の一体化成形体。
(4)前記コア層と前記別の構造体(C)との間の少なくとも一部に接合層が設けられている、(1)~(3)のいずれかに記載の一体化成形体。
(5)前記本体部を形成する領域における前記コア層の空隙率が50%以上80%以下、前記最薄肉部を形成する領域における前記コア層の空隙率が0%以上50%未満である、(1)~(4)のいずれかに記載の一体化成形体。
(6)前記サンドイッチ構造体の全周にわたって前記接合部が形成されてなる、(1)~(5)のいずれかに記載の一体化成形体。
(7)前記接合部の前記サンドイッチ構造体の端面からの長さLbが3~30mmの範囲にある、(1)~(6)のいずれかに記載の一体化成形体。
(8)前記本体部の厚さDbが0.4~2mm、前記接合部の厚さTcが0.1~1.7mmの範囲にある、(1)~(7)のいずれかに記載の一体化成形体。
(9)Db/Tcが1.1~20の範囲にある、(8)に記載の一体化成形体。
(10)前記本体部の前記境界面部側端縁から前記最薄肉部の少なくとも一部のみと接合された前記別の構造体(C)までの距離Lが0.1~30mmの範囲にある、(1)~(9)のいずれかに記載の一体化成形体。
(11)前記サンドイッチ構造体は前記端部の一部以外にも別の段差部を有するとともに前記別の構造体(C)が配され、前記別の段差部は、該別の段差部の両側における高い面を形成する本体部、該別の段差部の両側の高い面と該両側の高い面間に位置する低い面をつなぐ別の境界面を形成する別の境界面部及び前記両側の本体部におけるコア層の空隙率よりも低い空隙率のコア層を有する別の最薄肉部から構成され、かつ、前記別の構造体(C)は前記別の境界面に接しておらず、前記別の最薄肉部の少なくとも一部のみと接合されている、(1)~(10)のいずれかに記載の一体化成形体。
(12)前記本体部の厚さと、前記接合部を介して接合された前記別の構造体(C)のみからなる部分の厚さとが同じ厚さを有する、(1)~(11)のいずれかに記載の一体化成形体。
(13)前記コア層は、不連続繊維と熱可塑性樹脂(A)とからなるコア層前駆体を加熱によるスプリングバックにより厚さ方向に膨張させて空隙を形成させてなる、(1)~(12)のいずれかに記載の一体化成形体。
(14)前記コア層を構成する不連続繊維が5~75重量%、熱可塑性樹脂(A)が25~95重量%の範囲にある、(1)~(13)のいずれかに記載の一体化成形体。
(15)前記コア層を構成する不連続繊維の数平均繊維長が0.5~50mmの範囲にある、(1)~(14)のいずれかに記載の一体化成形体。
(16)前記コア層を構成する不連続繊維が500本以下の単繊維からなる繊維束で存在し、前記繊維束がランダムに配向してなる、(1)~(15)のいずれかに記載の一体化成形体。
(17)コア層を構成する不連続繊維がモノフィラメント状に分散し、不連続な単繊維(a)と、前記不連続な単繊維(a)と交差する他の不連続な単繊維(b)とで形成される二次元配向角の平均値が10~80度の範囲にある、(16)に記載の一体化成形体。
(18)不連続繊維と熱可塑性樹脂(A)からなるコア層及び連続繊維と樹脂(B)からなるスキン層から構成されるサンドイッチ構造体の少なくとも端部の一部を接合部とし、前記接合部に、別の構造体(C)を接合させる一体化成形体の製造方法であって、少なくとも以下の工程[1]~工程[5]からなることを特徴とする、一体化成形体の製造方法。
[1]前記不連続繊維からなるウエブの少なくとも片面に前記熱可塑性樹脂(A)層を配したコア層前駆体を準備する工程
[2]前記コア層前駆体の両面に、前記連続繊維に前記樹脂(B)を含浸させたスキン層前駆体を配して成形体前駆体を形成する工程
[3]前記成形体前駆体を加熱プレス成形し、前記スキン層前駆体を固化または硬化させてスキン層を形成するとともに、前記コア層前駆体と前記スキン層とを一体化させる工程
[4]前記コア層前駆体中の前記不連続繊維の復元力を発現させコア層内に空隙を形成させて前記サンドイッチ構造体を所定厚さに膨張させるにあたり、プレス金型を当接させることにより前記サンドイッチ構造体の少なくとも端部の一部に段差部を形成し、該段差部を、該段差部における高い面を形成する本体部、段差部の高い面と低い面をつなぐ境界面を形成する境界面部及び前記本体部におけるコア層の空隙率よりも低い空隙率のコア層を有する最薄肉部から構成するサンドイッチ構造体賦形工程
[5]金型内に前記賦形されたサンドイッチ構造体を配置し、金型内の前記接合部に対し、溶融させた別の構造体(C)の樹脂を、前記境界面には接せず前記最薄肉部の少なくとも一部のみと接するように樹脂の流動を金型内の途中でせき止めた状態にて射出することにより、前記サンドイッチ構造体と前記別の構造体(C)を接合して一体化させる工程
(19)前記[4]サンドイッチ構造体賦形工程において、不連続繊維と熱可塑性樹脂(A)とを含有する前記コア層前駆体を、前記熱可塑性樹脂(A)の軟化点または融点以上に加熱及び加圧した後、加圧を解除し、スプリングバックにより膨張させることにより前記空隙を形成させる、(18)に記載の一体化成形体の製造方法。
(20)前記[2]成形体前駆体の形成工程において、前記コア層の少なくとも一方の表面における本体部に相当する領域にのみにスキン層を配したスキン層前駆体を形成し、加熱プレスにより前記スキン層前駆体を固化または硬化してスキン層を形成するとともに、所定厚さに膨張させて空隙を有するコア層を備えた前記本体部を形成する、(18)または(19)に記載の一体化成形体の製造方法。
(21)前記接合部を構成するスキン層又はコア層に熱可塑性樹脂フィルム若しくは不織布を配置、又は接着剤を塗布し、その後に溶融させた別の構造体(C)の樹脂を射出成形することにより、前記サンドイッチ構造体と別の構造体(C)とを接合一体化させる、(18)~(20)のいずれかに記載の一体化成形体の製造方法。
前記サンドイッチ構造体は少なくとも端部の一部に段差部を有し、該段差部は、該段差部における高い面を形成する本体部、段差部の高い面と低い面をつなぐ境界面を形成する境界面部及び前記本体部におけるコア層の空隙率よりも低い空隙率のコア層を有する最薄肉部から構成され、かつ、前記別の構造体(C)は前記境界面に接しておらず、前記最薄肉部の少なくとも一部のみと接合されていることを特徴とする一体化成形体である。
本発明は、不連続繊維と熱可塑性樹脂(A)からなるコア層及び連続繊維と樹脂(B)からなるスキン層から構成されるサンドイッチ構造体の少なくとも端部の一部を接合部とし、前記接合部に、別の構造体(C)を接合させる一体化成形体の製造方法であって、少なくとも以下の工程[1]~工程[5]からなることを特徴とする一体化成形体の製造方法である。
[1]前記不連続繊維からなるウエブの少なくとも片面に前記熱可塑性樹脂(A)層を配したコア層前駆体を準備する工程
[2]前記コア層前駆体の両面に、前記連続繊維に前記樹脂(B)を含浸させたスキン層前駆体を配して成形体前駆体を形成する工程
[3]前記成形体前駆体を加熱プレス成形し、前記スキン層前駆体を固化または硬化させてスキン層を形成するとともに、前記コア層前駆体と前記スキン層とを一体化させる工程
[4]前記コア層前駆体中の前記不連続繊維の復元力を発現させコア層内に空隙を形成させて前記サンドイッチ構造体を所定厚さに膨張させるにあたり、プレス金型を当接させることにより前記サンドイッチ構造体の少なくとも端部の一部に段差部を形成し、該段差部を、該段差部における高い面を形成する本体部、段差部の高い面と低い面をつなぐ境界面を形成する境界面部及び前記本体部におけるコア層の空隙率よりも低い空隙率のコア層を有する最薄肉部から構成するサンドイッチ構造体賦形工程
[5]金型内に前記賦形されたサンドイッチ構造体を配置し、金型内の前記接合部に対し、溶融させた別の構造体(C)の樹脂を、前記境界面には接せず前記最薄肉部の少なくとも一部のみと接するように樹脂の流動を金型内の途中でせき止めた状態にて射出することにより、前記サンドイッチ構造体と前記別の構造体(C)を接合して一体化させる工程
図10[1]は、不連続繊維からなるウエブ31の両面に熱可塑性樹脂(A)層32を配したコア層前駆体33を準備する工程[1]を示している。熱可塑性樹脂(A)層32は他の基材と積層する作業性の観点からフィルムや不織布が好ましい。
一体化成形体から接合部を含んだ小片を切り出し、エポキシ樹脂に包埋した後、一体化成形体の厚さ方向の断面を研磨することで試料を作製した。この試料をレーザー顕微鏡((株)キーエンス製、VK-9510)を用いて撮影した後、画像計測ツールを用いて、図5に示すように、サンドイッチ構造体に接合された別の構造体(C)の接合部長さ(Lb)、境界面部端縁から別の構造体(C)までの距離(L)、サンドイッチ構造体の境界面部角度(θ)を測定した。
一体化成形体のうち、接合部が長手方向中央となるように、一体化成形体の厚さ方向に垂直な面内において長さ50mm、幅25mmのサイズになるように試験片を切り出し、支点間距離が試験片厚さの32倍で、ASTM D790に準拠して曲げ強度を求め、これを接合強度とした。さらに、得られた接合強度を以下の基準で評価した。A、Bが合格であり、C、Dが不合格とした。
A:100MPa以上
B:60MPa以上100MPa未満
C:40MPa以上60MPa未満
D:40MPa未満あるいは測定不可
図1に示すような、サンドイッチ構造体に接合された別の構造体(C)との接合部近傍の意匠面側凹みを表面粗さ計((株)東京精密製、サーフコム480A)のうねり測定で測定するとともに、目視で外観を確認した。さらに、得られた凹み量と外観を以下の基準で評価した。○が合格であり、△、×が不合格とした。
○:凹みが5μm未満でかつ目視で凹みが見えない
△:凹みが5μm以上20μm未満
×:凹みが20μm以上
図10〔4〕Bに示すような、本体部と最薄肉部とのコア層の空隙率が異なるサンドイッチ構造体を製造する際に、境界面部に4度の角度をつけた上型35を用いることで、境界面部の角度(θ)が4度のサンドイッチ構造体を得た。
図10〔4〕Bに示すような、本体部と最薄肉部とのコア層の空隙率が異なるサンドイッチ構造体を製造する際に、境界面部に90度の角度をつけた上型35を用いることで、境界面部の角度(θ)が90度のサンドイッチ構造体を得た。
図10〔4〕Bに示すような、本体部と最薄肉部とのコア層の空隙率が異なるサンドイッチ構造体を製造する際に、境界面部に2度の角度をつけた上型35を用いることで、境界面部の角度(θ)が2度のサンドイッチ構造体を得た。
図10〔4〕Bに示すような、本体部と最薄肉部とのコア層の空隙率が異なるサンドイッチ構造体を製造する際に、境界面部に18度の角度をつけた上型35を用いることで、境界面部の角度(θ)が18度のサンドイッチ構造体を得た。
サンドイッチ構造体は実施例1同様に作製した。得られたサンドイッチ構造体を射出成形金型内にセットし、型締めを行った後、溶融させた樹脂(C)を射出成形した際に、接合部の長さ(Lb)が2mmと短い、図5の模式図に示す一体化成形体を製造した。サンドイッチ構造体に接合された別の構造体(C)との接合部近傍の意匠面側凹みが無い良外観が得られたが、一体化成形体の接合強度が低く合格レベルに達しなかった。その結果、接合強度も合格レベルにするには、実施例3との比較から、接合部の長さ(Lb)を3mmとすることが好ましいことが判明した。一体化成形体の特性をまとめて表1に示す。
サンドイッチ構造体は実施例1同様に作製した。得られたサンドイッチ構造体を射出成形金型内にセットし、型締めを行った後、溶融させた樹脂(C)を射出成形した際に、図1に示すように境界面部まで別の構造体(C)が接合した一体化成形体を製造した。一体化成形体は接合強度が高いものの、サンドイッチ構造体に接合された別の構造体(C)との接合部近傍の意匠面側凹みが大きかった。一体化成形体の特性をまとめて表1に示す。
サンドイッチ構造体は実施例4同様に作製した。得られたサンドイッチ構造体を射出成形金型内にセットし、型締めを行った後、溶融させた樹脂(C)を射出成形した際に、接合部の長さ(Lb)が2mmと短く、図1に示すように境界面部まで別の構造体(C)が接合した一体化成形体を製造した。一体化成形体は接合強度が低く合格レベルに達しなかった。また、サンドイッチ構造体に接合された別の構造体(C)との接合部近傍の意匠面側凹みも大きかった。一体化成形体の特性をまとめて表1に示す。
2 スキン層
3 コア層
3a 空隙率の高いコア層
3b 空隙率の低いコア層
4 コア層内での繊維
5 空隙
6 接合部
7 別の構造体(C)
8 本体部
8a 段差部の高い面
9、42 境界面部
9a 境界面
10、43 最薄肉部
10a 段差部の低い面(最薄肉部の上面)
10b 最薄肉部の側面
11 段差部
12 金型
13 せき止め部
14、15、16、17、18、19 不連続な単繊維
20 二次元接触角、二次元配向角
21 接合層
31 不連続繊維ウエブ
32 熱可塑性樹脂(A)
33 コア層前駆体
34 スキン層前駆体
35 プレス金型の上型
36 プレス金型の下型
37 プレス金型の間隙が異なる領域
45,51 別の段差部
46、53 別の構造体(C)
47 本体部
47a 別の段差部の高い面
48、52 別の境界面部
48a、52a 別の境界面
49 別の最薄肉部
49a 別の段差部の低い面(別の最薄肉部の上面)
50a 空隙率の高いコア層
50b 空隙率の低いコア層
100、200、201 一体化成形体
Claims (21)
- 不連続繊維と熱可塑性樹脂(A)からなるコア層及び連続繊維と樹脂(B)からなるスキン層から構成されるサンドイッチ構造体の少なくとも端部の一部を接合部とし、前記接合部に別の構造体(C)を配した一体化成形体であって、
前記サンドイッチ構造体は少なくとも端部の一部に段差部を有し、該段差部は、該段差部における高い面を形成する本体部、段差部の高い面と低い面をつなぐ境界面を形成する境界面部及び前記本体部におけるコア層の空隙率よりも低い空隙率のコア層を有する最薄肉部から構成され、かつ、前記別の構造体(C)は前記境界面に接しておらず、前記最薄肉部の少なくとも一部のみと接合されていることを特徴とする一体化成形体。 - 前記境界面部の境界面は、前記本体部の面内方向に対して、1~20°の角度を有している、請求項1に記載の一体化成形体。
- 前記スキン層と前記別の構造体(C)との間の少なくとも一部に接合層が設けられている、請求項1または2に記載の一体化成形体。
- 前記コア層と前記別の構造体(C)との間の少なくとも一部に接合層が設けられている、請求項1~3のいずれかに記載の一体化成形体。
- 前記本体部を形成する領域における前記コア層の空隙率が50%以上80%以下、前記最薄肉部を形成する領域における前記コア層の空隙率が0%以上50%未満である、請求項1~4のいずれかに記載の一体化成形体。
- 前記サンドイッチ構造体の全周にわたって前記接合部が形成されてなる、請求項1~5のいずれかに記載の一体化成形体。
- 前記接合部の前記サンドイッチ構造体の端面からの長さLbが3~30mmの範囲にある、請求項1~6のいずれかに記載の一体化成形体。
- 前記本体部の厚さDbが0.4~2mm、前記接合部の厚さTcが0.1~1.7mmの範囲にある、請求項1~7のいずれかに記載の一体化成形体。
- Db/Tcが1.1~20の範囲にある、請求項8に記載の一体化成形体。
- 前記本体部の前記境界面部側端縁から前記最薄肉部の少なくとも一部のみと接合された前記別の構造体(C)までの距離Lが0.1~30mmの範囲にある、請求項1~9のいずれかに記載の一体化成形体。
- 前記サンドイッチ構造体は前記端部の一部以外にも別の段差部を有するとともに前記別の構造体(C)が配され、前記別の段差部は、該別の段差部の両側における高い面を形成する本体部、該別の段差部の両側の高い面と該両側の高い面間に位置する低い面をつなぐ別の境界面を形成する別の境界面部及び前記両側の本体部におけるコア層の空隙率よりも低い空隙率のコア層を有する別の最薄肉部から構成され、かつ、前記別の構造体(C)は前記別の境界面に接しておらず、前記別の最薄肉部の少なくとも一部のみと接合されている、請求項1~10のいずれかに記載の一体化成形体。
- 前記本体部の厚さと、前記接合部を介して接合された前記別の構造体(C)のみからなる部分の厚さとが同じ厚さを有する、請求項1~11のいずれかに記載の一体化成形体。
- 前記コア層は、不連続繊維と熱可塑性樹脂(A)とからなるコア層前駆体を加熱によるスプリングバックにより厚さ方向に膨張させて空隙を形成させてなる、請求項1~12のいずれかに記載の一体化成形体。
- 前記コア層を構成する不連続繊維が5~75重量%、熱可塑性樹脂(A)が25~95重量%の範囲にある、請求項1~13のいずれかに記載の一体化成形体。
- 前記コア層を構成する不連続繊維の数平均繊維長が0.5~50mmの範囲にある、請求項1~14のいずれかに記載の一体化成形体。
- 前記コア層を構成する不連続繊維が500本以下の単繊維からなる繊維束で存在し、前記繊維束がランダムに配向してなる、請求項1~15のいずれかに記載の一体化成形体。
- コア層を構成する不連続繊維がモノフィラメント状に分散し、不連続な単繊維(a)と、前記不連続な単繊維(a)と交差する他の不連続な単繊維(b)とで形成される二次元配向角の平均値が10~80度の範囲にある、請求項16に記載の一体化成形体。
- 不連続繊維と熱可塑性樹脂(A)からなるコア層及び連続繊維と樹脂(B)からなるスキン層から構成されるサンドイッチ構造体の少なくとも端部の一部を接合部とし、前記接合部に、別の構造体(C)を接合させる一体化成形体の製造方法であって、少なくとも以下の工程[1]~工程[5]からなることを特徴とする、一体化成形体の製造方法。
[1]前記不連続繊維からなるウエブの少なくとも片面に前記熱可塑性樹脂(A)層を配したコア層前駆体を準備する工程
[2]前記コア層前駆体の両面に、前記連続繊維に前記樹脂(B)を含浸させたスキン層前駆体を配して成形体前駆体を形成する工程
[3]前記成形体前駆体を加熱プレス成形し、前記スキン層前駆体を固化または硬化させてスキン層を形成するとともに、前記コア層前駆体と前記スキン層とを一体化させる工程
[4]前記コア層前駆体中の前記不連続繊維の復元力を発現させコア層内に空隙を形成させて前記サンドイッチ構造体を所定厚さに膨張させるにあたり、プレス金型を当接させることにより前記サンドイッチ構造体の少なくとも端部の一部に段差部を形成し、該段差部を、該段差部における高い面を形成する本体部、段差部の高い面と低い面をつなぐ境界面を形成する境界面部及び前記本体部におけるコア層の空隙率よりも低い空隙率のコア層を有する最薄肉部から構成するサンドイッチ構造体賦形工程
[5]金型内に前記賦形されたサンドイッチ構造体を配置し、金型内の前記接合部に対し、溶融させた別の構造体(C)の樹脂を、前記境界面には接せず前記最薄肉部の少なくとも一部のみと接するように樹脂の流動を金型内の途中でせき止めた状態にて射出することにより、前記サンドイッチ構造体と前記別の構造体(C)を接合して一体化させる工程 - 前記[4]サンドイッチ構造体賦形工程において、不連続繊維と熱可塑性樹脂(A)とを含有する前記コア層前駆体を、前記熱可塑性樹脂(A)の軟化点または融点以上に加熱及び加圧した後、加圧を解除し、スプリングバックにより膨張させることにより前記空隙を形成させる、請求項18に記載の一体化成形体の製造方法。
- 前記[2]成形体前駆体の形成工程において、前記コア層の少なくとも一方の表面における本体部に相当する領域にのみにスキン層を配したスキン層前駆体を形成し、加熱プレスにより前記スキン層前駆体を固化または硬化してスキン層を形成するとともに、所定厚さに膨張させて空隙を有するコア層を備えた前記本体部を形成する、請求項18または19に記載の一体化成形体の製造方法。
- 前記接合部を構成するスキン層又はコア層に熱可塑性樹脂フィルム若しくは不織布を配置、又は接着剤を塗布し、その後に溶融させた別の構造体(C)の樹脂を射出成形することにより、前記サンドイッチ構造体と別の構造体(C)とを接合一体化させる、請求項18~20のいずれかに記載の一体化成形体の製造方法。
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JP2018511296A JP6960108B2 (ja) | 2017-01-31 | 2018-01-19 | 一体化成形体及びその製造方法 |
KR1020197020803A KR20190113777A (ko) | 2017-01-31 | 2018-01-19 | 일체화 성형체 및 그의 제조 방법 |
SG11201906941RA SG11201906941RA (en) | 2017-01-31 | 2018-01-19 | Integrally molded body and method for producing same |
US16/482,059 US20200061952A1 (en) | 2017-01-31 | 2018-01-19 | Integrally molded body and method of producing same |
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EP (1) | EP3578353A4 (ja) |
JP (1) | JP6960108B2 (ja) |
KR (1) | KR20190113777A (ja) |
CN (1) | CN110139747B (ja) |
SG (1) | SG11201906941RA (ja) |
TW (1) | TWI738964B (ja) |
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Cited By (4)
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CN112389035A (zh) * | 2019-08-19 | 2021-02-23 | 仁宝电脑工业股份有限公司 | 复合材料结构 |
WO2024095814A1 (ja) * | 2022-10-31 | 2024-05-10 | 東レ株式会社 | 多孔質サンドイッチ構造体及びそれを用いた一体化成形体 |
JP7482278B1 (ja) | 2023-01-31 | 2024-05-13 | マクセル株式会社 | 樹脂成形体 |
WO2024116786A1 (ja) * | 2022-11-29 | 2024-06-06 | パナソニックオートモーティブシステムズ株式会社 | パネル体、表示装置、およびパネル体の製造方法 |
Families Citing this family (6)
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EP3778210B1 (en) * | 2018-03-30 | 2023-11-15 | Toray Industries, Inc. | Method for manufacturing molded article and preform of molded article |
WO2020094671A1 (de) * | 2018-11-05 | 2020-05-14 | Mitsubishi Chemical Advanced Materials Composites Ag | Verfahren zur herstellung eines thermoplastisch verformbaren faserverstärkten flächigen halbzeugs |
DE102020206045A1 (de) * | 2020-05-13 | 2021-11-18 | Ford Global Technologies, Llc | Verfahren zur Herstellung eines Hohlkörper-Verbundbauteils, sowie Projektil zum Einsatz in einem solchen Verfahren |
JP7512919B2 (ja) * | 2021-02-02 | 2024-07-09 | トヨタ自動車株式会社 | ハイブリッド成形体、成形装置、及び成形方法 |
CN117083710A (zh) * | 2021-03-25 | 2023-11-17 | 株式会社巴川制纸所 | 传热体 |
TW202241693A (zh) | 2021-04-19 | 2022-11-01 | 仁寶電腦工業股份有限公司 | 複合材料結構 |
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- 2018-01-19 EP EP18747457.2A patent/EP3578353A4/en not_active Withdrawn
- 2018-01-19 SG SG11201906941RA patent/SG11201906941RA/en unknown
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CN112389035A (zh) * | 2019-08-19 | 2021-02-23 | 仁宝电脑工业股份有限公司 | 复合材料结构 |
WO2024095814A1 (ja) * | 2022-10-31 | 2024-05-10 | 東レ株式会社 | 多孔質サンドイッチ構造体及びそれを用いた一体化成形体 |
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JP6960108B2 (ja) | 2021-11-05 |
KR20190113777A (ko) | 2019-10-08 |
CN110139747B (zh) | 2021-05-11 |
CN110139747A (zh) | 2019-08-16 |
TW201834843A (zh) | 2018-10-01 |
TWI738964B (zh) | 2021-09-11 |
SG11201906941RA (en) | 2019-08-27 |
JPWO2018142971A1 (ja) | 2019-11-14 |
EP3578353A4 (en) | 2020-09-02 |
EP3578353A1 (en) | 2019-12-11 |
US20200061952A1 (en) | 2020-02-27 |
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