WO2018117040A1 - 微細気泡を含む気液を生成するための装置およびシステム - Google Patents

微細気泡を含む気液を生成するための装置およびシステム Download PDF

Info

Publication number
WO2018117040A1
WO2018117040A1 PCT/JP2017/045363 JP2017045363W WO2018117040A1 WO 2018117040 A1 WO2018117040 A1 WO 2018117040A1 JP 2017045363 W JP2017045363 W JP 2017045363W WO 2018117040 A1 WO2018117040 A1 WO 2018117040A1
Authority
WO
WIPO (PCT)
Prior art keywords
gas
liquid
wall
bubble
pump
Prior art date
Application number
PCT/JP2017/045363
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
神野 浩
太郎 神野
Original Assignee
オオノ開發株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by オオノ開發株式会社 filed Critical オオノ開發株式会社
Priority to CN201780083273.9A priority Critical patent/CN110167662A/zh
Priority to JP2018557971A priority patent/JP7050304B2/ja
Priority to KR1020197018388A priority patent/KR20190095311A/ko
Publication of WO2018117040A1 publication Critical patent/WO2018117040A1/ja

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F23/00Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
    • B01F23/20Mixing gases with liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/30Injector mixers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/60Pump mixers, i.e. mixing within a pump

Definitions

  • the present invention relates to a gas-liquid mixing device, a pump device, a bubble refining device, and a system for generating a gas-liquid containing fine bubbles, and more particularly to refining bubbles in a gas-liquid.
  • Patent Document 1 discloses a swirl type fine bubble generator.
  • a high-speed swirling flow is generated in a gas-liquid two-phase gas-liquid, and a swirling cavity portion made of a negative pressure gas is formed in the swirling flow center by a gas-liquid centrifugal separation action.
  • An object of the present invention is to obtain a compact system for efficiently generating gas-liquid containing fine bubbles capable of performing from the generation of bubbles to the miniaturization of the bubbles by pumping of the liquid.
  • the present inventors have a gas-liquid mixing device having a compact configuration capable of efficiently generating gas-liquid containing fine bubbles, and pumping gas-liquid while miniaturizing bubbles contained in gas-liquid.
  • the present invention has completed a pump device that can perform the operation and a bubble refining device that can refine the bubbles contained in the gas-liquid simply by passing the gas-liquid containing bubbles.
  • a compact system for efficiently generating gas-liquid containing fine bubbles can be realized.
  • the processes from gas intake and bubble generation to bubble miniaturization can be performed by liquid pumping.
  • the present invention provides the following items.
  • a gas-liquid mixing device for generating a gas-liquid containing fine bubbles, A container body having an outer wall and an inner wall; A liquid introduction part for introducing liquid into the container body; A gas introduction part for introducing gas into the container body; A swirl part in the container body for swirling the liquid and the gas to generate the gas-liquid;
  • a gas-liquid mixing device comprising: a gas-liquid discharge unit that discharges the gas-liquid.
  • the gas-liquid mixing device according to any one of Items 1 to 4, wherein the inner wall has a shape that is at least partially reduced in diameter toward the gas-liquid discharge unit.
  • Item 6 Item 6.
  • the gas-liquid mixing device according to any one of Items 1 to 5, wherein the liquid introduction part is connected in a tangential direction to the inner wall.
  • a pump device for generating gas-liquid containing fine bubbles A pump body having an outer wall and an inner wall; A pump suction part for sucking the gas-liquid; A rotating part that rotates so that the inhaled gas-liquid swirls; A driving unit for rotating the rotating unit; A pump device comprising: a gas-liquid discharge unit that discharges the swirled gas-liquid.
  • Item 8 Item 8.
  • Item 9 Item 9.
  • Item 10 Item 10.
  • a bubble refining device for generating gas-liquid containing fine bubbles A bubble refiner main body having an outer wall and an inner wall; A gas-liquid introduction part for introducing the gas-liquid; A swivel unit that swirls the introduced gas and liquid; A bubble miniaturization apparatus comprising: a gas-liquid discharge unit that discharges the gas-liquid.
  • Item 13 Item 13.
  • the bubble miniaturization apparatus according to Item 11 or 12, wherein the inner wall has irregularities arranged at least partially along the substantially axial direction of the inner wall.
  • Item 14 Item 14.
  • the bubble miniaturization device according to Item 13, which is subordinate to Item 12, wherein the unevenness of the swivel part and the unevenness of the inner wall are nested.
  • Item 15 Item 15.
  • the bubble refining device according to Item 14, wherein the unevenness of the swivel portion and the unevenness of the inner wall are provided in a spiral shape.
  • (Item 16) The gas-liquid mixing device according to any one of items 1 to 6, The pump device according to any one of items 7 to 10, A system for generating a gas-liquid containing fine bubbles, comprising the bubble refining device according to any one of items 11 to 15.
  • (Item 17) A gas-liquid mixing method for generating a gas-liquid containing fine bubbles using the fine mixing apparatus according to item 1, A liquid introduction step for introducing liquid into the container body from the liquid introduction section; A gas introduction step of introducing gas into the container body from a gas introduction portion; Producing a gas-liquid by turning the liquid and the gas introduced into the container body by a turning unit in the container body; A gas-liquid mixing method including a step of discharging the gas-liquid by a gas-liquid discharge unit.
  • (Item 18) A method for producing a gas-liquid containing fine bubbles using the pump device according to item 7, Inhaling gas and liquid into the pump suction part; Rotating the gas and liquid sucked into the pump suction part by a rotating part so as to rotate; And a step of discharging the gas-liquid rotated so as to swivel by a gas-liquid discharge unit.
  • (Item 19) A bubble refining method for generating a gas-liquid containing fine bubbles by having the bubble refining apparatus according to item 11, Introducing the gas-liquid into the gas-liquid introduction part; A step of swirling the introduced gas-liquid by a swivel unit; And a step of discharging the swirled gas-liquid by a gas-liquid discharge unit.
  • a gas-liquid mixing device configured to efficiently generate a gas-liquid containing fine bubbles
  • a pump device capable of pumping gas-liquid while miniaturizing bubbles contained in the gas-liquid
  • a bubble refining device or a combination thereof which can refine bubbles contained in a gas / liquid simply by passing the gas / liquid contained therein. Furthermore, by using these apparatuses, a compact system for efficiently generating gas-liquid containing fine bubbles can be realized.
  • FIG. 1 is a view for explaining a cyclone type gas-liquid mixing apparatus according to Embodiment 1 of the present invention.
  • FIG. 1 (a) shows an appearance of the gas-liquid mixing apparatus 100
  • FIG. FIG. 1 (a) shows a cross-sectional structure taken along the line Ib-Ib
  • FIG. 1 (c) shows a cross-sectional structure taken along the line Ic-Ic in FIG. 1 (b).
  • FIG. 2 is a diagram for explaining a pump device according to Embodiment 2 of the present invention.
  • FIG. 2 (a) shows an appearance of the pump device 200
  • FIG. 2 (b) shows a diagram of FIG. 2 (a).
  • FIG. 2C shows a structure taken along the line IIb-IIb
  • FIG. 3 is a view for explaining a bubble miniaturization apparatus 300 according to Embodiment 3 of the present invention.
  • FIG. 3 (a) shows an appearance of the bubble miniaturization apparatus 300
  • FIG. 3 (a) shows the structure of the cross section taken along line IIIb-IIIb
  • FIG. 3 (c) shows an enlarged view of the IIIc portion of FIG. 3 (b).
  • 4 is a diagram for explaining components of the bubble miniaturization apparatus 300 shown in FIG. 3B, and FIG. 4A shows the outer cylindrical body 310 of the bubble miniaturization apparatus 300, and FIG. (B) shows the inner side columnar body 320 which comprises the bubble miniaturization apparatus 300.
  • FIG. 5 is a diagram for explaining a fine bubble generation system 1000 according to Embodiment 4 of the present invention, and schematically shows a configuration of the fine bubble generation system 1000.
  • FIG. 6 is a perspective view for explaining an example of use of the fine bubble generating system 1000 shown in FIG.
  • fine bubbles is a general term for generally called microbubbles and nanobubbles, and generally means bubbles having a diameter of 50 ⁇ m or less.
  • FIG. 1 is a view for explaining a swirl type gas-liquid mixing apparatus according to Embodiment 1 of the present invention.
  • FIG. 1 (a) shows an appearance of the gas-liquid mixing apparatus 100
  • FIG. FIG. 1 (a) shows a cross-sectional structure taken along the line Ib-Ib
  • FIG. 1 (c) shows a cross-sectional structure taken along the line Ic-Ic in FIG. 1 (b).
  • the gas-liquid mixing apparatus 100 includes a mixing container (container body) 101 for mixing liquid and gas having an inner wall and an outer wall, and a swivel portion (substantially cylindrical body for swirling the liquid and gas). (Flow path forming body) 110, a gas introduction part 102 for introducing gas into the mixing container, a liquid introduction part 103 for introducing liquid into the mixing container, and for discharging gas / liquid from the inside of the mixing container 101 Gas-liquid discharge unit 104.
  • the means for introducing the gas into the gas introduction unit 102 may be self-contained or forced.
  • the gas is introduced into the mixing container 101 from the gas introduction unit 102 in a self-contained manner.
  • the self-contained type it is not necessary to provide a separate drive source for the gas supply operation, and the apparatus can be miniaturized.
  • the amount of gas corresponding to the amount of supply liquid introduced into the liquid introduction unit 103 can be varied following the fluctuation of the supply liquid amount, and can always be adjusted to an appropriate amount and stably supplied. .
  • a control valve for adjusting the gas introduction amount may be provided.
  • the gas introduction section may be introduced from the gas introduction section 102 shown in FIG. 1 or a pipe between the pump 200 and the bubble miniaturization apparatus 300 described later. It may be introduced from the road or from both. When a large amount of gas is forcedly introduced, it is preferably introduced from a pipe line between the pump 200 and the bubble refining device 300.
  • the liquid introduced into the liquid introduction unit 103 may be tap water or pressurized water, but is not limited thereto.
  • the gas-liquid mixing apparatus 100 of the present invention may further include a pressure reducing valve for coping with fluctuations in the liquid supply pressure.
  • a plurality of different liquids may be introduced into the liquid introduction part 103 of the gas-liquid mixing apparatus 100 of the present invention.
  • “different liquids” mean not only different types of liquids but also different supply pressures and supply sources.
  • the gas-liquid mixing apparatus 100 of the present invention includes a first conduit for introducing the first liquid, And a second pipe for introducing two liquids.
  • the first liquid is tap water and the second liquid is pressurized water, but is not limited thereto.
  • the shape of the mixing container 101 can take any shape as long as the liquid introduced by the liquid introduction unit 103 does not prevent the swirling unit from turning into a swirling flow.
  • it may be a substantially cylindrical body, a substantially elliptical body, or a substantially spherical body. That is, the shape of the mixing vessel may be any shape as long as the inner wall thereof has a substantially circular cross section (Ic-Ic cross section in FIG. 1B) perpendicular to the swirling central axis of the swirling flow.
  • the mixing container 101 may or may not have a reduced diameter portion 101 b whose inner wall is reduced in diameter toward the gas-liquid discharge portion 104. In a preferred embodiment, as shown in FIG.
  • the mixing container 101 includes a cylindrical portion 101a and a reduced diameter portion 101b.
  • the angular velocity of turning is increased in the reduced diameter portion 101b, thereby increasing the shearing force of the gas-liquid discharged from the discharge portion, thereby achieving bubble division.
  • the shape of the reduced diameter portion 101b may be conical or hemispherical.
  • the reduced diameter portion 101b is conical, but the present invention is not limited to this.
  • a swirl unit 110 is accommodated in the cylindrical portion 101a, and a swirl flow path Rp for flowing liquid and gas while swirling is formed between the inner wall surface of the mixing container 101 and the outer peripheral surface of the swirl unit 110. ing.
  • a gas introduction unit 102 is formed on the upper surface of the swirl unit 110, and a gas passage 111 for guiding the liquid from the gas introduction unit 102 to the swirl passage Rp is formed on the upper part of the swirl unit 110.
  • a liquid introduction part 103 for introducing liquid into the swirl passage Rp is formed on the upper part of the cylindrical part 101a.
  • the shape of the swivel unit 110 is not limited to the substantially cylindrical body in the present embodiment.
  • a substantially elliptic cylinder It may be a substantially spherical body. That is, the shape of the swirling unit 110 may be a shape in which a cross section (Ic-Ic cross section in FIG. 1B) perpendicular to the swirling central axis of the swirling flow is formed in a substantially circular shape.
  • the surface of the swivel unit 110 is provided with at least one groove 121 that is a recess along the circumferential direction in the axial direction.
  • channels 121 may be arbitrary. In the exemplary embodiment, as shown in FIG. 1B, three grooves 121 are formed at regular intervals in the axial direction, but the present invention is not limited to this.
  • the groove 121 may be formed in a spiral shape along the outer peripheral surface of the swivel unit 110. In one embodiment, the shape of the groove 121 can take any shape.
  • the groove 121 has a triangular shape in the cross section including the pivot center axis, but the present invention is not limited to this.
  • a turning part 110 that is, a baffle 110b which is at least one protrusion around the axis of the turning part main body 110a is provided.
  • the interval between the baffles 110b and the baffles 110b and the number of the baffles 110b when the plurality of baffles 110b are provided around the axis of the swivel unit main body 110a may be arbitrary.
  • the interval between the baffles and the number of baffles can be appropriately determined by those skilled in the art based on the diameter of the swivel unit.
  • the distance between the baffle 110b and the baffle 110b is approximately equal to the distance between the tip of the baffle 110b and the inner wall of the swivel body 110a (plus or minus 10%).
  • the spacing between the baffle 110b and the baffle 110b can be about 10 mm to about 50 mm, about 15 mm to about 40 mm, or about 20 mm to about 30 mm.
  • the number of baffles 110b may be 1 to 20, 4 to 16, 6 to 14, or 10 to 12.
  • twelve baffles 110b are arranged at regular intervals around the axis of the swivel unit main body 110a, but the present invention is not limited to this.
  • the shape of the baffle 110b can take any shape as long as it collides with the swirling flow swirled by the swirling unit and the bubbles are decomposed.
  • the cross-sectional shape perpendicular to the axis of the swivel unit main body 110a may be flat or curved.
  • a flat plate is used as the cross-sectional shape perpendicular to the axis of the swivel unit main body 110a.
  • the baffle 110b can be formed by various methods.
  • the baffle 110b may be formed by pouring a material into a mold, or may be formed by machining the material.
  • the orientation of the baffle 110b can take any orientation as long as the liquid introduced by the liquid introduction unit 103 is swirled by the swirl unit.
  • the inclination angle A may be about 90 °, 0 ° to less than 90 ° (inclination in a direction along the turning direction S), or more than 90 ° to less than 180 ° (the turning direction S). It may be inclined in the opposite direction).
  • the tilt angle A is about 30 ° to about 80 °, about 40 ° to about 80 °, about 50 ° to about 80 °, about 30 ° to about 70 °, about 40 ° to about 70 °, Or about 45 ° to about 65 °, with about 45 ° to about 65 ° being preferred for bubble generation and refinement.
  • the inclination angle A may be the same for each baffle or may be different. In the preferred embodiment, as shown in FIG. 1C, the inclination angle A is set to about 60 ° in the direction along the turning direction S, but the present invention is not limited to this.
  • the inside of the reduced diameter portion 101b is a hollow region
  • the reduced diameter portion 101b is a truncated cone-shaped cylindrical body whose diameter decreases toward the gas-liquid discharge portion 104
  • the gas-liquid flowing into the reduced diameter portion 101b is The angular velocity of the turning is increased in the reduced diameter portion 101b.
  • a gas-liquid discharge portion 104 for discharging gas-liquid from the inside of the mixing container 101 is formed at the lower end portion of the reduced diameter portion 101b.
  • the gas Ar supplied to the gas-liquid mixing apparatus 100 is introduced from the gas introduction unit 102 into the swirl passage Rp through the liquid passage 111. Further, the liquid Wa supplied to the gas-liquid mixing apparatus 100 is supplied to the turning passage Rp from the tangential direction of the outer peripheral surface of the turning portion main body 110a via the liquid introduction portion 103. The liquid Wa supplied to the swirl passage Rp is mixed with the gas Ar blown out from the liquid passage 111 at the upper part of the casing cylindrical portion 101a, and the outer periphery of the swivel body 110a as the liquid Wa (gas liquid M1) containing the gas Ar. It flows toward the gas-liquid discharge unit 104 while turning along the surface.
  • the gas-liquid M1 collides with the baffle 110b provided in the groove 121 of the swivel unit main body 110a while flowing along the outer peripheral surface of the swivel unit main body 110a while flowing toward the gas-liquid discharge unit 104.
  • the bubbles contained in the gas-liquid M1 are more finely decomposed.
  • the gas-liquid mixing apparatus 100 swirls the mixing container (container body) 101 for mixing the gas Ar and the liquid Wa and the gas-liquid M1 including the gas Ar and the liquid Wa.
  • a swirl flow path Rp for flowing liquid and gas while swirling is formed between the inner wall surface of the mixing container 101 and the outer peripheral surface of the swirl section 110.
  • grooves 121 along the circumferential direction are formed in the axial direction at regular intervals on the surface of the swivel unit 110, and the baffles 110b are arranged in the grooves 121 around the axis of the swivel unit main body 110a at regular intervals.
  • the gas liquid M1 collides with the baffle 110b provided in the groove 121 of the swivel unit main body 110a while flowing along the outer peripheral surface of the swivel unit main body 110a while flowing toward the gas-liquid discharge unit 104.
  • Gas liquid Bubbles contained in 1 becomes to be more finely divided.
  • the gas-liquid mixing apparatus 100 of the present invention efficiently generates fine bubbles by providing the protruding portion (baffle 110b) in the swivel unit 110, compared to the case where the protruding portion (baffle 110b) is not provided. Therefore, the gas-liquid mixing device and the fine bubble generating system can be downsized.
  • the gas-liquid mixing apparatus of the present invention has a new function of refining bubbles contained in the mixed gas-liquid in addition to the original function of the gas-liquid mixing apparatus that mixes gas and liquid to generate gas-liquid. Can have functions.
  • FIG. 2 is a diagram for explaining a pump device according to Embodiment 2 of the present invention.
  • FIG. 2 (a) shows an appearance of the pump device 200
  • FIG. 2 (b) shows a diagram of FIG. 2 (a).
  • FIG. 2C shows a structure taken along the line IIb-IIb
  • FIG. 2C shows a structure taken along the line IIc-IIc in FIG.
  • the pump device 200 includes a pump body 200a and a pump drive unit 201a that drives the pump body 200a.
  • the pump main body 200a has a cylindrical casing (pump casing) 201.
  • the pump casing 201 has a pump suction portion 202 for sucking gas and liquid into the pump casing 201, and an outside from the pump casing 201.
  • a pump discharge unit 203 for discharging gas and liquid is provided.
  • a fin rotating body (impeller) 211 is provided in the pump housing 201, which is a rotating part that rotates so that the sucked gas-liquid turns.
  • the fin rotating body 211 is attached to a pump driving unit 201a that is a driving unit that rotates the fin rotating unit 211 via a rotating body driving shaft 201b.
  • the fin rotator 211 includes a shaft-side rotating plate 211a fixed to the rotating member drive shaft 201b, an opposing rotating plate 211b disposed so as to face the shaft-side rotating plate 211a, and the shaft-side rotating plate 211a and the counter-rotating plate. 211b and at least one centrifugal fin 211c attached between them.
  • the shape of the centrifugal fins 211c can take any shape as long as it can generate a swirling flow by applying a centrifugal force to the gas-liquid sucked from the pump suction unit 202.
  • the cross-sectional shape perpendicular to the rotating body drive shaft 201b may be a flat plate shape or a curved plate shape having a predetermined radius of curvature.
  • the centrifugal fin 211c is a curved plate having an arc shape as a cross-sectional shape perpendicular to the rotating body drive shaft 201b as shown in FIG. 2C, but the present invention is not limited to this.
  • the shape of the centrifugal fin 211c may be flat along the axial direction of the rotating body drive shaft 201b, or may be a twisted spiral. In a preferred embodiment, the shape of the centrifugal fins 211c is a spiral shape along the axial direction of the rotating body drive shaft 201b.
  • the distance between the centrifugal fins 211c and the centrifugal fins 211c is about 10 mm to about 50 mm, about 15 mm to about 40 mm, or about 20 mm to about 30 mm. It is not limited to. A person skilled in the art can select an appropriate interval according to the size of the pump device 100, the output of the pump device 100, and the like.
  • the number of the centrifugal fins 211c may be 1 to 20, 4 to 16, 6 to 14, or 10 to 12.
  • 10 to 12 centrifugal fins 211c are arranged at regular intervals around the axis of the rotating body drive shaft 201b (12 in the example of FIG. 2 (c)), miniaturization of the bubbles can be achieved effectively.
  • the orientation of the centrifugal fins 211c can take any orientation as long as centrifugal force can be applied to the gas-liquid sucked from the pump suction portion 202.
  • the direction may be perpendicular to the rotation direction of the rotating body drive shaft 201b (inclination angle B is about 90 °), or it may be inclined in the direction along the rotation direction (inclination angle B is more than 0 ° to less than 90 °). Or may be inclined in a direction opposite to the rotation direction (inclination angle B greater than 90 ° to less than 180 °).
  • the tilt angle B is about 120 ° to about 170 °, about 130 ° to about 170 °, about 130 ° to about 160 °, about 120 ° to about 150 °, about 120 ° to about 140, or It can be about 130 ° to about 140 °.
  • the inclination angle B may be the same for each centrifugal fin, or may be different. In the preferred embodiment, as shown in FIG. 2 (c), the inclination angle B is set to about 135 ° in the direction along the direction opposite to the rotation direction X of the rotating body drive shaft 201b, but the present invention is not limited to this. Not.
  • the orientation (inclination angle B) of the centrifugal fin 211c is determined by the radius of curvature when the centrifugal fin 211c is a curved plate having a predetermined radius of curvature. If the radius of curvature (inclination angle B) is increased too much, the fluid pressure increases and the swirl flow velocity increases, so that bubbles can be made finer efficiently. However, the occurrence of cavitation is induced, and stable gas-liquid supply is hindered. There is also. On the other hand, if the radius of curvature (inclination angle B) is too small, the fluid pressure drops and the swirling flow velocity slows down, which may make the bubble miniaturization inefficient. Liquid supply can be performed.
  • the orientation (inclination angle B) of the centrifugal fins 211c can appropriately select the orientation (inclination angle B) of the centrifugal fins 211c based on the required efficiency of fine bubbles and the stability of gas-liquid supply.
  • the radius of curvature of the centrifugal fin 211c is about 1/4 to about 1/1, about 1/3 to about 3/4, or about 1/2 to about 2 / of the outer size of the impeller 212.
  • centrifugal fins 211c it is possible to arrange an arbitrary number of the centrifugal fins 211c at arbitrary positions within a range in which a centrifugal force can be applied to the gas-liquid sucked from the pump suction unit 202 to generate a swirling flow.
  • one centrifugal fin 211c may be arranged, a plurality of centrifugal fins 211c may be arranged at regular intervals in the circumferential direction of the rotating body drive shaft 201b, or the plurality of centrifugal fins 211c may be driven by a rotating body. They may be arranged at different intervals in the circumferential direction of the shaft 201b.
  • centrifugal fins 211c are arranged at regular intervals along the circumferential direction of the rotating body drive shaft 201b, but the present invention is not limited to this. Centrifugal fins 211c are arranged such that when the rotating body drive shaft 201b rotates in the direction of arrow X, the gas-liquid flowing from the pump suction portion 202 into the fin rotating body 211 is converted into arcuate centrifugal fins 211c in the pump housing 201. Along the outer side of the pump housing 201.
  • an impeller (baffle) 212 that is at least one protrusion is disposed on the inner wall of the pump housing 201 along the inner peripheral surface thereof.
  • the shape of the impeller 212 can take any shape as long as the impeller 212 can collide with the gas-liquid swung toward the outside of the pump housing 201 by the centrifugal force of the centrifugal fins 211c.
  • the shape of the impeller 212 may be, for example, a flat plate shape as a cross-sectional shape perpendicular to the axis of the pump housing 201, or may be a curved plate shape having a predetermined radius of curvature. In a preferred embodiment, as shown in FIG.
  • the cross-sectional shape perpendicular to the axis of the pump housing 201 is a flat plate shape, but the present invention is not limited to this.
  • the shape of the centrifugal fin 211c may be flat along the axial direction of the rotating body drive shaft 201b, or may be a twisted spiral.
  • the shape of the centrifugal fins 211c is a spiral shape along the axial direction of the rotating body drive shaft 201b.
  • the orientation of the impeller 212 is arbitrary as long as the impeller 212 can collide with the gas-liquid swung toward the outside of the pump housing 201 by the centrifugal force by the centrifugal fins 211c.
  • the orientation can be taken.
  • the direction may be perpendicular to the rotation direction X (inclination angle C is about 90 °), or may be inclined in the direction along the rotation direction X (inclination angle C is more than 0 ° to less than 90 °).
  • it may be inclined in the direction opposite to the rotation direction X (the inclination angle C is more than 90 ° to less than 180 °).
  • the tilt angle C is about 30 ° to about 80 °, about 40 ° to about 80 °, about 50 ° to about 80 °, about 30 ° to about 70 °, about 40 ° to about 70 °, Or from about 45 ° to about 60 °.
  • the inclination angle C may be the same for each impeller 212 or may be different. In the preferred embodiment, as shown in FIG. 2C, the impeller 212 is oriented along the rotational direction X and has an inclination angle C of about 60 °, but the present invention is not limited to this.
  • the space formed by the pump housing 201 and the impeller 212 becomes too small, and it becomes difficult for the swirling flow swirled by the centrifugal fins 211c to enter the space well. Turbulence cannot be generated.
  • the orientation (inclination angle C) of the impeller 212 is determined by the curvature radius when the impeller 212 has a curved plate shape having a predetermined curvature radius. If the radius of curvature (inclination angle C) is increased too much, the fluid pressure increases and the swirling flow velocity increases, so that bubbles can be made finer efficiently. However, this causes cavitation and hinders stable gas-liquid supply. There is. On the other hand, if the radius of curvature (inclination angle C) is too small, the fluid pressure drops and the swirl flow velocity slows down, which may make the bubble miniaturization inefficient. However, the occurrence of cavitation is suppressed and stable gas-liquid Supply can be made.
  • the size of the radius of curvature of the impeller 212 is approximately 1 / of the size of the outer shape of the impeller 212. It can be from 4 to about 1/1, from about 1/3 to about 3/4, or from about 1/2 to about 2/3.
  • the relationship between the orientation of the centrifugal fins 211c and the orientation of the impeller 212 can be any relationship.
  • the orientations of the centrifugal fins 211c and the impeller 212 may be the same, or the orientations of the centrifugal fins 211c and the impeller 212 may be different.
  • the centrifugal fin 211c and the impeller 212 become substantially straight. In this way, the swirl flow can smoothly flow into the space between the inner wall of the pump casing 201 and the impeller 212.
  • positioning of the impeller 212 can arrange
  • one impeller 212 may be disposed, a plurality of impellers 212 may be disposed at regular intervals along the circumferential direction of the pump housing 201, or a plurality of impellers 212 may be disposed on the pump housing 201. They may be arranged at different intervals along the circumferential direction.
  • ten impellers 212 are arranged at regular intervals along the circumferential direction of the pump housing 201, but the present invention is not limited to this.
  • the small gap (clearance) between the centrifugal fins 211c and the impeller 212 can take any value. If the gap is made too small, the swirling flow rate increases, but the amount of discharged water decreases, and a desired gas-liquid discharge amount cannot be secured. On the other hand, if the gap is too large, a desired gas-liquid discharge amount can be secured, but the swirling flow rate decreases and a desired turbulent flow cannot be obtained between the centrifugal fins 211c and the impeller 212, making it difficult to refine the bubbles. It becomes.
  • a gap between the centrifugal fin 211c and the impeller 212 is selected based on conditions such as the required gas-liquid discharge amount and fine bubble diameter. For example, the gap distance is about 0.5 mm to about 5 mm, about 0.7 mm to about 3 mm, or about 1 mm to about 2 mm.
  • the fin rotating body 211 that is the rotating portion of the pump main body 200a is driven by the pump driving portion 201a, and the gas-liquid M1 containing bubbles is supplied from the pump suction portion 202 into the pump housing 201.
  • the gas / liquid M ⁇ b> 1 in the pump housing 201 is rotated in the pump housing 201 by the rotation of the fin rotator 211.
  • the gas-liquid M1 swirls in the pump casing 201 in this way the gas-liquid M1 in the pump casing 201 is swung in the pump casing 201 by centrifugal force, and the pump casing 201 starts from the center of the pump casing 201.
  • the pump device 200 of the present invention efficiently generates fine bubbles by providing the protrusion (impeller 212) on the inner wall of the pump body 200a, compared to the case where the protrusion (impeller 212) is not provided. Therefore, the pump device and the fine bubble generating system can be downsized. Further, the pump device 200 of the present invention has a new function of refining bubbles contained in the gas and liquid in addition to the original function of the pump for sucking gas and liquid and discharging the gas and liquid to the outside.
  • FIG. 3 is a view for explaining a bubble miniaturization apparatus 300 according to Embodiment 3 of the present invention.
  • FIG. 3 (a) shows an appearance of the bubble miniaturization apparatus 300
  • FIG. 3 (a) shows the structure of the cross section taken along line IIIb-IIIb
  • FIG. 3 (c) shows an enlarged view of the IIIc portion of FIG. 3 (b).
  • the bubble miniaturization apparatus 300 swirls gas and liquid with the outer cylindrical body 310 that is the main body of the bubble miniaturization apparatus and has an inner wall and an outer wall.
  • An inner columnar body 320 that is a revolving part, a gas-liquid introducing part 301 for introducing gas-liquid into the outer cylindrical body 310, and a gas-liquid discharging part for discharging gas-liquid from the outer cylindrical body 310 to the outside 302.
  • the gas-liquid introduction part 301 is provided at one end of the outer cylindrical body 310
  • the gas-liquid discharge part 302 is provided at the other end of the outer cylindrical body 310.
  • the outer cylindrical body 310 and the inner columnar body 320 are formed by fitting the inner columnar body 320 into the outer cylindrical body 310, thereby rotating the gas-liquid M ⁇ b> 2 and turning the outer cylinder.
  • a swirl passage Rp2 for flowing from one end side to the other end side of the shaped body 310 is formed.
  • FIG. 4 is a diagram for explaining components of the bubble miniaturization apparatus 300 shown in FIG. 3B, and FIG. 4A shows the outer cylindrical body 310 of the bubble miniaturization apparatus 300, and FIG. (B) shows the inner side columnar body 320 which comprises the bubble miniaturization apparatus 300.
  • FIG. 4A shows the outer cylindrical body 310 of the bubble miniaturization apparatus 300
  • FIG. (B) shows the inner side columnar body 320 which comprises the bubble miniaturization apparatus 300.
  • the outer cylindrical body 310 includes an introduction-side peripheral wall portion 311 having a gas-liquid introduction portion 301, a discharge-side peripheral wall portion 313 having a gas-liquid discharge portion 302, and an introduction-side peripheral wall portion 311 and a discharge-side peripheral wall portion 313. It has the cylindrical uneven
  • grooved part 312 can take arbitrary shapes.
  • grooved part 312 can be arbitrary.
  • the interval may be constant, or the interval of the unevenness may be varied depending on the place to be arranged, or may be spiral.
  • the axial arrangement interval of the concave and convex outer cylindrical body 310 provided in the cylindrical concave-convex portion 312 is a constant interval of about 0.5 to about 7 mm, about 1 to about 5 mm, about 2 to about 3 mm. In a preferred embodiment, as shown in FIG.
  • the unevenness provided on the cylindrical body uneven portion 312 is a spiral thread groove 312a, and the unevenness provided on the columnar uneven portion described later. Although it arrange
  • the inner columnar body 320 includes an introduction side end 321 fitted to the introduction side peripheral wall 311 of the outer cylindrical body 310, a discharge side end 325 fitted to the discharge side peripheral wall 313 of the outer cylindrical body 310, It has a columnar body uneven portion 323 facing the tubular body uneven portion 312 of the outer tubular body 310.
  • the shape of the unevenness provided in the columnar uneven portion 323 can take any shape.
  • grooved part 323 may be arbitrary.
  • the interval may be constant, or the interval of the unevenness may be varied depending on the place to be arranged, or may be spiral.
  • the axial arrangement interval of the concave and convex outer cylindrical body 310 provided in the cylindrical concave-convex portion 312 is a constant interval of about 0.5 to about 7 mm, about 1 to about 5 mm, about 2 to about 3 mm.
  • the unevenness provided in the columnar uneven portion 323 is a screw thread 323 a having a spiral shape, and a thread groove 312 a provided in the tubular uneven portion 312.
  • the gap distance between the thread 323a provided in the columnar uneven portion 323 and the screw groove 312a provided in the tubular uneven portion 312 can be arbitrary.
  • the interval may be constant, or the interval between the irregularities may be varied depending on the place of arrangement.
  • the distance between the screw thread 323a provided in the columnar uneven portion 323 and the screw groove 312a provided in the cylindrical uneven portion 312 is about 0.5 to about 7 mm, about 1 to about 5 mm, about 1. 5 to about 3 mm.
  • a portion between the introduction side end 321 and the columnar uneven portion 323 of the inner columnar body 320 serves as an introduction side swivel portion 322 that imparts a swirling force to the introduced gas-liquid M2, and the discharge of the inner columnar body 320 is performed.
  • a portion between the side end portion 325 and the columnar uneven portion 323 serves as a discharge side turning portion 324 that applies a turning force to the gas-liquid M3 to be discharged.
  • the outer peripheral surface of the columnar uneven portion 323 is formed on the inner peripheral surface of the cylindrical uneven portion 312.
  • a thread 323a is formed in the thread groove 312a so that the screw advances in the opposite direction so as to be in a nested state.
  • the cylindrical uneven portion 312 of the outer cylindrical body 310 is formed.
  • the gas-liquid M2 flowing from one end side to the other end side of the outer cylindrical body 310 while turning along the thread groove 312a collides with the thread 323a of the columnar uneven portion 323 of the inner columnar body 320.
  • the gas-liquid M2 supplied to the bubble miniaturization apparatus 300 is introduced from the gas-liquid introduction unit 301 into the turning passage Rp2.
  • the gas-liquid M2 introduced into the turning passage Rp2 is moved between the introduction-side peripheral wall portion 311 of the outer cylindrical body 310 and the introduction-side turning portion 322 of the inner columnar body 320 by the force introduced from the gas-liquid introduction portion 301.
  • a turning force is applied.
  • the gas-liquid M2 to which the turning force is applied passes through a portion where the inner peripheral surface of the cylindrical body uneven portion 312 of the outer cylindrical body 310 and the outer peripheral surface of the columnar uneven portion 323 of the inner columnar body 320 face each other.
  • the bubble miniaturization apparatus 300 includes the outer cylindrical body 310 by providing the outer cylindrical body 310 with unevenness (screw groove 312a) and / or the inner columnar body 320 with unevenness (thread 323a).
  • fine bubbles can be efficiently generated as compared with the case where the inner columnar body 320 is not provided with irregularities, it is possible to reduce the size of the bubble refining device and the fine bubble generating system.
  • the bubble miniaturization apparatus 300 may be used by connecting a plurality (for example, three or more) in series based on the required size and amount of fine bubbles.
  • a plurality for example, three or more
  • the introduction of gas is forced and the gas is introduced from the gas introduction unit 102 and / or the pipe between the pump device 200 and the microbubble device 300, it is effective and generates a large amount of microbubbles. It becomes possible.
  • the fine bubble generation system 1000 according to the fourth embodiment includes any one or more of the gas-liquid mixing device 100 according to the first embodiment, the pump device 200 according to the second embodiment, and the bubble refinement device 300 according to the third embodiment.
  • the fine bubble generating system of the present invention includes the gas-liquid mixing device 100 according to the first embodiment and the pump device 200 according to the second embodiment.
  • the fine bubble generation system of the present invention includes a pump device 200 according to the second embodiment and a bubble refinement device 300 according to the third embodiment.
  • the fine bubble generation system of the present invention includes the gas-liquid mixing device 100 according to the first embodiment and the bubble refinement device 300 according to the third embodiment.
  • FIG. 5 is a diagram for explaining a fine bubble generation system 1000 according to Embodiment 4 of the present invention, and schematically shows a configuration of the fine bubble generation system 1000.
  • the fine bubble generation system 1000 according to the fourth embodiment includes the gas-liquid mixing device 100 according to the first embodiment, the pump device 200 according to the second embodiment, and the bubble refinement device 300 according to the third embodiment.
  • the gas-liquid discharge part 104 of the gas-liquid mixing apparatus 100 is connected to the pump housing 201 of the pump apparatus 200 by a pipe (not shown), and the pump discharge part 203 of the pump apparatus 200 is an air bubble refiner. It is connected to 300 gas-liquid introduction parts 301 by piping (not shown).
  • this fine bubble generation system 1000 the supplied gas Ar and liquid Wa are introduced into the gas-liquid mixing device 100 by the pumping force of the pump device 200, and the gas Ar and liquid introduced into the gas-liquid mixing device 100. Wa is mixed in the gas / liquid mixing device 100 by the pumping force of the pump device 200 and supplied to the pump device 200 as gas / liquid M1. Further, in the pump device 200, the bubbles are further refined inside the pump device 200 by the pumping force of the pump device 200, and the gas / liquid M2 including the further refined bubbles is supplied from the pump device 200 to the bubble refinement device 300. Is done.
  • the supplied gas-liquid M2 is sent from the gas-liquid introduction part 301 of the bubble miniaturization apparatus 300 to the gas-liquid discharge part 302 while turning by the pumping force of the pump apparatus 200.
  • a gas-liquid M3 in which bubbles contained in the gas-liquid M2 are further miniaturized is generated.
  • the fine bubble generating system 1000 of the present invention includes the baffle 110b in the gas-liquid mixing device 100, the impeller 212 in the pump device 200, and the thread groove 312a and the screw thread 323a in the bubble miniaturization device 300. Since finer bubbles can be generated more efficiently than when the mixing device 100, the pump device 200, and the bubble refining device 300 are each used alone, it is possible to reduce the size of the fine bubble generation system. . It should also be noted that the fine bubble generation system 1000 of the present invention can efficiently perform water supply and fine bubble generation simultaneously.
  • the gas-liquid M3 generated by the microbubble generation system 1000 of the present invention is discharged from the bubble micronizer 300 and used for various purposes, for example, water supply to a bathtub, water supply to a shower head, or water supply to a washing machine. Needless to say, it is useful not only for small-scale water environments but also for large-scale water environments.
  • FIG. 6 is a perspective view for explaining an example of use of the fine bubble generating system 1000 shown in FIG.
  • the gas-liquid M3 generated in the fine bubble generating system 1000 is supplied to the bathtub 50.
  • the bathtub main body 51 is provided with a bathtub water supply port 52 and a bathtub drainage port 53.
  • the bathtub water supply port 52 is connected to the gas-liquid discharge unit 302 of the fine bubble generating system 1000
  • the bathtub drain port 53 is connected to the liquid introducing unit 103 of the fine bubble generating system 1000.
  • the gas / liquid M3 is circulated between the fine bubble generating system 1000 and the bathtub 50, and in the bathtub 50, the gas / liquid M3 in which the bubbles are miniaturized is always supplied from the fine bubble generating system 1000. Will be.
  • the present invention is useful in the field of gas-liquid generation including fine bubbles.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
PCT/JP2017/045363 2016-12-19 2017-12-18 微細気泡を含む気液を生成するための装置およびシステム WO2018117040A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201780083273.9A CN110167662A (zh) 2016-12-19 2017-12-18 用于生成包含微气泡的气液的装置以及系统
JP2018557971A JP7050304B2 (ja) 2016-12-19 2017-12-18 微細気泡を含む気液を生成するための装置およびシステム
KR1020197018388A KR20190095311A (ko) 2016-12-19 2017-12-18 미세기포를 포함하는 기액을 생성하기 위한 장치 및 시스템

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016-245683 2016-12-19
JP2016245683 2016-12-19

Publications (1)

Publication Number Publication Date
WO2018117040A1 true WO2018117040A1 (ja) 2018-06-28

Family

ID=62626605

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2017/045363 WO2018117040A1 (ja) 2016-12-19 2017-12-18 微細気泡を含む気液を生成するための装置およびシステム

Country Status (5)

Country Link
JP (1) JP7050304B2 (zh)
KR (1) KR20190095311A (zh)
CN (1) CN110167662A (zh)
TW (1) TW201827121A (zh)
WO (1) WO2018117040A1 (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109092092A (zh) * 2018-09-30 2018-12-28 深圳市享宝科技有限公司 微纳米气泡发生装置
CN115007010A (zh) * 2022-06-14 2022-09-06 江苏惠尔泵业有限公司 一种可调节流量高扬程气液混合泵
JP7142386B1 (ja) 2021-06-15 2022-09-27 荒川工業株式会社 微細気泡発生器
DE102022120583A1 (de) 2021-08-18 2023-02-23 Drägerwerk AG & Co. KGaA Passiver Gasmischer mit einer hohlen Schraube

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN208771227U (zh) * 2018-08-02 2019-04-23 上海捷乔纳米科技有限公司 微气泡产生器
JP2021069999A (ja) * 2019-10-31 2021-05-06 キヤノン株式会社 ウルトラファインバブル生成方法、ウルトラファインバブル含有液の製造装置および製造方法
CN113522080A (zh) * 2020-04-13 2021-10-22 中国石油化工股份有限公司 微纳米气泡发生装置和危害气体净化系统
CN112316770B (zh) * 2020-08-29 2024-02-09 浙江恒盈环境科技有限公司 一种气泡喷头以及气泡产生方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52134597U (zh) * 1976-04-09 1977-10-13
US4389312A (en) * 1981-10-05 1983-06-21 Harold Beard Variable venturi sewerage aerator
JP2004278434A (ja) * 2003-03-17 2004-10-07 Torishima Pump Mfg Co Ltd 渦巻ポンプ
US20130113125A1 (en) * 2010-07-15 2013-05-09 Korea Institute Of Machinery & Materials Rotating unit-based micro-sized bubble generator
JP2013223828A (ja) * 2012-04-20 2013-10-31 Bridgestone Corp 撹拌混合装置
JP2014057926A (ja) * 2012-09-19 2014-04-03 Takagi Co Ltd 浄水装置および浄水の製造方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4903292B1 (ja) 2011-05-17 2012-03-28 修一 石川 旋回式微細気泡発生装置

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52134597U (zh) * 1976-04-09 1977-10-13
US4389312A (en) * 1981-10-05 1983-06-21 Harold Beard Variable venturi sewerage aerator
JP2004278434A (ja) * 2003-03-17 2004-10-07 Torishima Pump Mfg Co Ltd 渦巻ポンプ
US20130113125A1 (en) * 2010-07-15 2013-05-09 Korea Institute Of Machinery & Materials Rotating unit-based micro-sized bubble generator
JP2013223828A (ja) * 2012-04-20 2013-10-31 Bridgestone Corp 撹拌混合装置
JP2014057926A (ja) * 2012-09-19 2014-04-03 Takagi Co Ltd 浄水装置および浄水の製造方法

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109092092A (zh) * 2018-09-30 2018-12-28 深圳市享宝科技有限公司 微纳米气泡发生装置
JP7142386B1 (ja) 2021-06-15 2022-09-27 荒川工業株式会社 微細気泡発生器
WO2022264568A1 (ja) * 2021-06-15 2022-12-22 荒川工業株式会社 微細気泡発生器
JP2022190862A (ja) * 2021-06-15 2022-12-27 荒川工業株式会社 微細気泡発生器
CN117320801A (zh) * 2021-06-15 2023-12-29 荒川工业株式会社 微细气泡发生器
US12048907B1 (en) 2021-06-15 2024-07-30 Arakawa Industry Co., Ltd. Fine bubble generator
DE102022120583A1 (de) 2021-08-18 2023-02-23 Drägerwerk AG & Co. KGaA Passiver Gasmischer mit einer hohlen Schraube
CN115007010A (zh) * 2022-06-14 2022-09-06 江苏惠尔泵业有限公司 一种可调节流量高扬程气液混合泵
CN115007010B (zh) * 2022-06-14 2023-08-08 江苏惠尔泵业有限公司 一种可调节流量高扬程气液混合泵

Also Published As

Publication number Publication date
CN110167662A (zh) 2019-08-23
JP7050304B2 (ja) 2022-04-08
KR20190095311A (ko) 2019-08-14
JPWO2018117040A1 (ja) 2019-10-24
TW201827121A (zh) 2018-08-01

Similar Documents

Publication Publication Date Title
WO2018117040A1 (ja) 微細気泡を含む気液を生成するための装置およびシステム
KR101829734B1 (ko) 서브 나노 마이크로 버블 발생장치
JP4636420B2 (ja) 微細気泡発生装置
CN108704504A (zh) 文丘里微气泡发生器及其在臭氧催化氧化中的应用
WO2008038763A1 (fr) Appareil de production d'un écoulement tourbillonnaire, procédé de production d'un écoulement tourbillonnaire, appareil de génération de phase vapeur, appareil de génération de microbulles, mélangeur de fluides et buse d'injection de fluides
JP2007069071A (ja) 微細気泡発生装置およびそれが組み込まれた微細気泡循環システム
KR20170104351A (ko) 미세기포 발생장치
CN110891674A (zh) 微气泡产生设备和微气泡产生方法,以及具有该微气泡产生设备的淋浴装置和油水分离装置
JP4426612B2 (ja) 微細気泡発生ノズル
CA2723743C (en) Device for mixing gas into a flowing liquid
JP2007111686A (ja) 同軸円筒型マイクロナノバブル発生装置
KR101667492B1 (ko) 미세기포 발생장치
KR102313214B1 (ko) 코일형 노즐을 구비하는 초미세기포 발생시스템
JP2009166026A (ja) 気液混合気泡発生装置
KR101874897B1 (ko) 선회방식 마이크로 버블 발생장치
WO2018151171A1 (ja) 汚水浄化用の気泡発生装置
US20210213400A1 (en) Gas-liquid mixing device
JP2010012454A (ja) 旋回式微細気泡発生器
JP2012091153A (ja) 微細気泡発生装置
JPWO2018131714A1 (ja) 流体混合装置、およびこのような混合装置を用いた混合流体の製造方法
JP2008274394A (ja) 酸洗装置及び方法
KR20220037313A (ko) 나노버블발생장치용 연결관
KR102603861B1 (ko) 미세버블 발생 장치
RU2809579C1 (ru) Вихревой гидродинамический смеситель
JP7235364B1 (ja) 気体溶解装置

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17884935

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2018557971

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 20197018388

Country of ref document: KR

Kind code of ref document: A

122 Ep: pct application non-entry in european phase

Ref document number: 17884935

Country of ref document: EP

Kind code of ref document: A1