WO2018107315A1 - 一种常压下两步冶炼高氮钢的方法 - Google Patents

一种常压下两步冶炼高氮钢的方法 Download PDF

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WO2018107315A1
WO2018107315A1 PCT/CN2016/109408 CN2016109408W WO2018107315A1 WO 2018107315 A1 WO2018107315 A1 WO 2018107315A1 CN 2016109408 W CN2016109408 W CN 2016109408W WO 2018107315 A1 WO2018107315 A1 WO 2018107315A1
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steel
nitrogen
smelting
furnace
molten steel
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PCT/CN2016/109408
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孙瑞涛
李永栋
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孙瑞涛
李永栋
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Priority to PCT/CN2016/109408 priority Critical patent/WO2018107315A1/zh
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/10Handling in a vacuum
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting

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  • the invention relates to the field of high-nitrogen steel smelting process, in particular to a method for smelting high-nitrogen steel in two steps under normal pressure.
  • Nitrogen-containing steels having a nitrogen content exceeding the solubility limit at atmospheric pressure are referred to as high nitrogen steels.
  • the performance and quality of high nitrogen steels have been significantly improved. It has good toughness and combines high strength, corrosion resistance, wear resistance, creep performance and fatigue strength.
  • high-pressure plasma arc melting, pressurized electroslag remelting, counter-pressure casting, and powder metallurgy and other high-nitrogen steel smelting processes were developed abroad, but China's work in this area is relatively backward.
  • High-nitrogen steel has excellent mechanical properties and good corrosion resistance, and has received extensive attention at home and abroad.
  • the prior art high-nitrogen steel smelting is either filled with nitrogen or directly placed into a metal containing nitrogen, and the smelting process is cumbersome, and the smelting process needs to be maintained at a certain very pressure state during the smelting process. Failure to make full use of discarded metals is not conducive to the effective use of resources.
  • the present invention provides the following technical solution: a method for smelting high nitrogen steel in two steps under normal pressure, comprising the following steps:
  • S4 The first step of high-nitrogen steel smelting, when the temperature in the electric arc furnace or the induction furnace rises to 1600 degrees Celsius, the stirring is stopped, and manganese nitride is added into the molten steel, and the ratio of manganese to nitrogen in the manganese nitride is nitrogen.
  • Manganese 12:88, after adding manganese nitride, the mixture of molten steel and manganese nitride is stirred. At this time, the engine speed is 2000r/min, and the molten steel and manganese nitride are completely fused, and the stirring is stopped;
  • S5 The second step of high-nitrogen steel smelting, transfer the completely fused molten steel and manganese nitride into the VD furnace, and fill the bottom of the VD furnace with nitrogen.
  • the bottom blowing nitrogen pressure is 0.25MPa-0.75. MPa, flow rate is 130-360 liters / minute; after the vacuum treatment is completed, the bottom blowing nitrogen pressure is 0.10MPa-0.20MPa, the flow rate is 19-76 liters / minute;
  • the pore size of the sieve in the step S6 ranges from 0.08 to 0.9 cm.
  • the model of the high pressure water gun in the step S2 is DW-0951V-1, and the clamping force of the lifting clamp is greater than 2000N.
  • the invention smelts the molten steel by using the discarded steel blocks, so that the discarded steel blocks can be fully utilized to achieve the effective utilization of resources; the smelting process requires only two steps. First, input manganese nitride, and then use nitrogen to protect, to achieve efficient and rapid industrial production; through the final filtration stage, the waste slag larger than 0.9 is completely filtered. Produce high quality high nitrogen steel.
  • the invention has simple production process, simple steps, and can effectively save resources and time in the production process, thereby smelting better high-nitrogen steel.
  • the invention provides a technical solution: a method for smelting high nitrogen steel in two steps under normal pressure, comprising the following steps:
  • S2 Steel block cleaning, the steel block after derusting is clamped by the lifting clamp, and the steel block is lifted to a distance of 50 cm from the horizontal plane, the outlet pipe of the high pressure water gun is connected with the cleaning liquid tank, and the steel is pressed by the high pressure water gun.
  • the surface of the block is subjected to high pressure washing.
  • the model of the high pressure water gun is DW-0951V-1, and the clamping force of the lifting clamp is 2000N, the number of flushing is 2 times, and the time of each flushing is 8 minutes;
  • S4 The first step of high-nitrogen steel smelting, when the temperature in the electric arc furnace or the induction furnace rises to 1600 degrees Celsius, the stirring is stopped, and manganese nitride is added into the molten steel, and the ratio of manganese to nitrogen in the manganese nitride is nitrogen.
  • Manganese 12:88, after adding manganese nitride, the molten steel and manganese nitride are mixed, at this time the engine The rotation speed is 2000r/min, and the molten steel and the manganese nitride are completely fused, and the stirring is stopped;
  • S5 The second step of high-nitrogen steel smelting, transferring the completely fused molten steel and manganese nitride into the VD furnace, and filling the bottom of the VD furnace with nitrogen gas.
  • the bottom blowing nitrogen pressure is 0.25 MPa, and the flow rate is 0.25 MPa. 130 liter / minute; after the end of the vacuum treatment, the bottom blowing nitrogen pressure is 0.10 MPa, the flow rate is 19 liters / minute;
  • the invention provides a technical solution: a method for smelting high nitrogen steel in two steps under normal pressure, comprising the following steps:
  • S2 Steel block cleaning, the steel block after derusting is clamped by the lifting clamp, and the steel block is lifted to a distance of 160 cm from the horizontal plane, the outlet pipe of the high pressure water gun is connected with the cleaning liquid tank, and the steel is pressed by the high pressure water gun.
  • the surface of the block is subjected to high pressure washing.
  • the model of the high pressure water gun is DW-0951V-1, and the clamping force of the lifting clamp is 3000N, the number of flushing is 4 times, and the time of each flushing is 13 minutes;
  • S5 The second step of high-nitrogen steel smelting, transferring the completely fused molten steel and manganese nitride into the VD furnace, and filling the bottom of the VD furnace with nitrogen gas.
  • the bottom blowing nitrogen pressure is 0.75 MPa, and the flow rate is 0.75 MPa. Is 360 liters / minute; after the vacuum treatment is completed, the bottom blowing nitrogen pressure is 0.20 MPa, the flow rate is 76 liters / minute;
  • the invention provides a technical solution: a method for smelting high nitrogen steel in two steps under normal pressure, comprising the following steps:
  • S2 Steel block cleaning, the steel block after derusting is clamped by the lifting clamp, and the steel block is lifted to a distance of 100 cm from the horizontal plane, the outlet pipe of the high pressure water gun is connected with the cleaning liquid tank, and the steel is pressed by the high pressure water gun.
  • the surface of the block is subjected to high pressure washing.
  • the model of the high pressure water gun is DW-0951V-1, and the clamping force of the lifting clamp is 2500N, the number of flushing is 3 times, and the time of each flushing is 9 minutes;
  • S4 The first step of high-nitrogen steel smelting, when the temperature in the electric arc furnace or the induction furnace rises to 1600 degrees Celsius, the stirring is stopped, and manganese nitride is added into the molten steel, and the ratio of manganese to nitrogen in the manganese nitride is nitrogen.
  • Manganese 12:88, after adding manganese nitride, the mixture of molten steel and manganese nitride is stirred. At this time, the engine speed is 2000r/min, and the molten steel and manganese nitride are completely fused, and the stirring is stopped;
  • the invention smelts molten steel by using abandoned steel blocks, so that the discarded steel blocks are fully utilized, and the effective utilization of resources is achieved; the smelting process requires only two steps, firstly inputting manganese nitride, and then using nitrogen to protect, Efficient and fast industrial production effect; through the final filtration stage, the waste slag with a diameter greater than 0.9 is completely filtered to produce high quality high nitrogen steel.
  • the invention has simple production process, simple steps, and can effectively save resources and time in the production process, thereby smelting better high-nitrogen steel.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

一种常压下两步冶炼高氮钢的方法,包括以下步骤:S1:钢块除锈;S2:钢块清洗;S3:钢水冶炼;S4:高氮钢冶炼第一步,当电弧炉或感应熔炉内的温度升高到1600摄氏度的时候,停止搅拌,并向钢水内加入氮化锰,氮化锰中锰和氮的比例为氮:锰=12:88,加入氮化锰后再对钢水和氮化锰的合液进行搅拌,此时发动机的转速为2000r/min,待钢水和氮化锰完全融合,停止搅拌;S5:高氮钢冶炼第二步,将完全融合的钢水和氮化锰转移至VD炉内,并向VD炉底部充入氮气,VD炉真空处理过程中;S6:高氮钢浇筑。该生产工艺简单,步骤精简,在生产的过程中能有效的节省资源和时间,从而冶炼出较佳的高氮钢

Description

一种常压下两步冶炼高氮钢的方法 技术领域
本发明涉及高氮钢冶炼工艺领域,具体为一种常压下两步冶炼高氮钢的方法。
背景技术
氮含量超过大气压下溶解度极限的含氮钢称为高氮钢。与常规钢种相比,高氮钢的性能、质量有着显著的改善。它具有良好的韧性,并兼有高的强度、耐腐蚀性、耐磨损性,蠕变性能和疲劳强度也明显改善。在20世纪80年代,国外相继开发了高压等离子弧熔炼、增压电渣重熔法、反压铸造法以及粉末冶金等高氮钢冶炼工艺,但我国在这方面的工作相对比较落后。高氮钢具有优异的力学性能、良好的耐腐蚀性能,因而受到国内外的广泛重视。
现有技术中的高氮钢冶炼要么是充入氮气,要么是直接放入含有氮元素的金属,并且冶炼的过程比较繁琐,冶炼过程需要保持在一定的非常压的状态,在冶炼的过程中没有充分利用废弃的金属,不利于实现资源的有效利用。
发明内容
本发明的目的在于提供一种常压下两步冶炼高氮钢的方法,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案:一种常压下两步冶炼高氮钢的方法,包括以下步骤:
S1:钢块除锈,将废弃的钢块均匀切割,并置于除锈槽内,向除锈槽内倒入除锈液和水,且除锈液和水完全浸泡住钢块,浸泡时间为1-3小时,浸泡的过程中保持水温为22-34摄氏度;
S2:钢块清洗,将除锈过后的钢块用起吊夹具夹紧,并将钢块提升到距离水平面50-160厘米处,将高压水枪的出水管与清洗液槽接通,并利用高压水枪对钢块的表面进行高压冲洗,冲洗的次数不少于2次,且每次冲洗的时 间为8-13分钟;
S3:钢水冶炼,将清洗好的钢块放入电弧炉或感应熔炉内进行炼制,电弧炉或感应熔炉内的温度为1518-1540摄氏度,当电弧炉或感应熔炉内的钢块刚刚变成钢水的时候,将电弧炉或感应熔炉内的温度升高到1560-1600摄氏度,并利用搅拌设备对钢水进行搅拌,其中搅拌机中的搅拌叶所用的金属为钼或钨,搅拌机中发动机的转速为1200r/min;
S4:高氮钢冶炼第一步,当电弧炉或感应熔炉内的温度升高到1600摄氏度的时候,停止搅拌,并向钢水内加入氮化锰,氮化锰中锰和氮的比例为氮:锰=12:88,加入氮化锰后再对钢水和氮化锰的合液进行搅拌,此时发动机的转速为2000r/min,待钢水和氮化锰完全融合,停止搅拌;
S5:高氮钢冶炼第二步,将完全融合的钢水和氮化锰转移至VD炉内,并向VD炉底部充入氮气,VD炉真空处理过程中,底吹氮气压力为0.25MPa-0.75MPa,流量为130-360升/分钟;所述真空处理结束后,底吹氮气压力为0.10MPa-0.20MPa,流量为19-76升/分钟;
S6:高氮钢浇筑,将钢水、氮化锰与氮气的冶炼液通过导管转移至吊包内,导管内设有不少于2个滤网,滤网孔径的大小按照VD炉到吊包的方向依次减小,吊包内的冶炼液再依次由行车输送至铸型处进行浇筑。
优选的,所述步骤S1中除锈液和水的比例为除锈液:水=2:1。
优选的,所述步骤S6中滤网的孔径范围在0.08-0.9cm之间。
优选的,所述步骤S2中高压水枪的型号为DW-0951V-1,且起吊夹具的夹持力大于2000N。
与现有技术相比,本发明的有益效果是:本发明通过利用废弃的钢块冶炼钢水,使得废弃的钢块得到充分的利用,达到资源的有效利用的效果;冶炼的过程只需两步,先投入氮化锰,再利用氮气做保护,达到高效、快速的工业生产效果;通过最后的过滤阶段,将直径大于0.9的废渣完全过滤,产 生高质的高氮钢。本发明生产工艺简单,步骤精简,在生产的过程中能有效的节省资源和时间,从而冶炼出较佳的高氮钢。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例一
本发明提供一种技术方案:一种常压下两步冶炼高氮钢的方法,包括以下步骤:
S1:钢块除锈,将废弃的钢块均匀切割,并置于除锈槽内,向除锈槽内倒入除锈液和水,除锈液和水的比例为除锈液:水=2:1,且除锈液和水完全浸泡住钢块,浸泡时间为1小时,浸泡的过程中保持水温为22摄氏度;
S2:钢块清洗,将除锈过后的钢块用起吊夹具夹紧,并将钢块提升到距离水平面50厘米处,将高压水枪的出水管与清洗液槽接通,并利用高压水枪对钢块的表面进行高压冲洗,高压水枪的型号为DW-0951V-1,且起吊夹具的夹持力为2000N,冲洗的次数为2次,且每次冲洗的时间为8分钟;
S3:钢水冶炼,将清洗好的钢块放入电弧炉或感应熔炉内进行炼制,电弧炉或感应熔炉内的温度为1518摄氏度,当电弧炉或感应熔炉内的钢块刚刚变成钢水的时候,将电弧炉或感应熔炉内的温度升高到1560摄氏度,并利用搅拌设备对钢水进行搅拌,其中搅拌机中的搅拌叶所用的金属为钼或钨,搅拌机中发动机的转速为1200r/min;
S4:高氮钢冶炼第一步,当电弧炉或感应熔炉内的温度升高到1600摄氏度的时候,停止搅拌,并向钢水内加入氮化锰,氮化锰中锰和氮的比例为氮:锰=12:88,加入氮化锰后再对钢水和氮化锰的合液进行搅拌,此时发动机的 转速为2000r/min,待钢水和氮化锰完全融合,停止搅拌;
S5:高氮钢冶炼第二步,将完全融合的钢水和氮化锰转移至VD炉内,并向VD炉底部充入氮气,VD炉真空处理过程中,底吹氮气压力为0.25MPa,流量为130升/分钟;所述真空处理结束后,底吹氮气压力为0.10MPa,流量为19升/分钟;
S6:高氮钢浇筑,将钢水、氮化锰与氮气的冶炼液通过导管转移至吊包内,导管内设有不少于2个滤网,滤网孔径的大小按照VD炉到吊包的方向依次减小,滤网的孔径为0.08cm,吊包内的冶炼液再依次由行车输送至铸型处进行浇筑。
实施例二
本发明提供一种技术方案:一种常压下两步冶炼高氮钢的方法,包括以下步骤:
S1:钢块除锈,将废弃的钢块均匀切割,并置于除锈槽内,向除锈槽内倒入除锈液和水,除锈液和水的比例为除锈液:水=2:1,且除锈液和水完全浸泡住钢块,浸泡时间为3小时,浸泡的过程中保持水温为34摄氏度;
S2:钢块清洗,将除锈过后的钢块用起吊夹具夹紧,并将钢块提升到距离水平面160厘米处,将高压水枪的出水管与清洗液槽接通,并利用高压水枪对钢块的表面进行高压冲洗,高压水枪的型号为DW-0951V-1,且起吊夹具的夹持力为3000N,冲洗的次数为4次,且每次冲洗的时间为13分钟;
S3:钢水冶炼,将清洗好的钢块放入电弧炉或感应熔炉内进行炼制,电弧炉或感应熔炉内的温度为1540摄氏度,当电弧炉或感应熔炉内的钢块刚刚变成钢水的时候,将电弧炉或感应熔炉内的温度升高到1600摄氏度,并利用搅拌设备对钢水进行搅拌,其中搅拌机中的搅拌叶所用的金属为钼或钨,搅拌机中发动机的转速为1200r/min;
S4:高氮钢冶炼第一步,当电弧炉或感应熔炉内的温度升高到1600摄氏 度的时候,停止搅拌,并向钢水内加入氮化锰,氮化锰中锰和氮的比例为氮:锰=12:88,加入氮化锰后再对钢水和氮化锰的合液进行搅拌,此时发动机的转速为2000r/min,待钢水和氮化锰完全融合,停止搅拌;
S5:高氮钢冶炼第二步,将完全融合的钢水和氮化锰转移至VD炉内,并向VD炉底部充入氮气,VD炉真空处理过程中,底吹氮气压力为0.75MPa,流量为360升/分钟;所述真空处理结束后,底吹氮气压力为0.20MPa,流量为76升/分钟;
S6:高氮钢浇筑,将钢水、氮化锰与氮气的冶炼液通过导管转移至吊包内,导管内设有不少于2个滤网,滤网孔径的大小按照VD炉到吊包的方向依次减小,滤网的孔径为0.9cm,吊包内的冶炼液再依次由行车输送至铸型处进行浇筑。
实施例三
本发明提供一种技术方案:一种常压下两步冶炼高氮钢的方法,包括以下步骤:
S1:钢块除锈,将废弃的钢块均匀切割,并置于除锈槽内,向除锈槽内倒入除锈液和水,除锈液和水的比例为除锈液:水=2:1,且除锈液和水完全浸泡住钢块,浸泡时间为2小时,浸泡的过程中保持水温为31摄氏度;
S2:钢块清洗,将除锈过后的钢块用起吊夹具夹紧,并将钢块提升到距离水平面100厘米处,将高压水枪的出水管与清洗液槽接通,并利用高压水枪对钢块的表面进行高压冲洗,高压水枪的型号为DW-0951V-1,且起吊夹具的夹持力为2500N,冲洗的次数为3次,且每次冲洗的时间为9分钟;
S3:钢水冶炼,将清洗好的钢块放入电弧炉或感应熔炉内进行炼制,电弧炉或感应熔炉内的温度为1524摄氏度,当电弧炉或感应熔炉内的钢块刚刚变成钢水的时候,将电弧炉或感应熔炉内的温度升高到1578摄氏度,并利用搅拌设备对钢水进行搅拌,其中搅拌机中的搅拌叶所用的金属为钼或钨,搅 拌机中发动机的转速为1200r/min;
S4:高氮钢冶炼第一步,当电弧炉或感应熔炉内的温度升高到1600摄氏度的时候,停止搅拌,并向钢水内加入氮化锰,氮化锰中锰和氮的比例为氮:锰=12:88,加入氮化锰后再对钢水和氮化锰的合液进行搅拌,此时发动机的转速为2000r/min,待钢水和氮化锰完全融合,停止搅拌;
S5:高氮钢冶炼第二步,将完全融合的钢水和氮化锰转移至VD炉内,并向VD炉底部充入氮气,VD炉真空处理过程中,底吹氮气压力为0.66MPa,流量为220升/分钟;所述真空处理结束后,底吹氮气压力为0.19MPa,流量为56升/分钟;
S6:高氮钢浇筑,将钢水、氮化锰与氮气的冶炼液通过导管转移至吊包内,导管内设有不少于2个滤网,滤网孔径的大小按照VD炉到吊包的方向依次减小,滤网的孔径为0.1cm,吊包内的冶炼液再依次由行车输送至铸型处进行浇筑。
本发明通过利用废弃的钢块冶炼钢水,使得废弃的钢块得到充分的利用,达到资源的有效利用的效果;冶炼的过程只需两步,先投入氮化锰,再利用氮气做保护,达到高效、快速的工业生产效果;通过最后的过滤阶段,将直径大于0.9的废渣完全过滤,产生高质的高氮钢。本发明生产工艺简单,步骤精简,在生产的过程中能有效的节省资源和时间,从而冶炼出较佳的高氮钢。
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。

Claims (4)

  1. 一种常压下两步冶炼高氮钢的方法,其特征在于:包括以下步骤:
    S1:钢块除锈,将废弃的钢块均匀切割,并置于除锈槽内,向除锈槽内倒入除锈液和水,且除锈液和水完全浸泡住钢块,浸泡时间为1-3小时,浸泡的过程中保持水温为22-34摄氏度;
    S2:钢块清洗,将除锈过后的钢块用起吊夹具夹紧,并将钢块提升到距离水平面50-160厘米处,将高压水枪的出水管与清洗液槽接通,并利用高压水枪对钢块的表面进行高压冲洗,冲洗的次数不少于2次,且每次冲洗的时间为8-13分钟;
    S3:钢水冶炼,将清洗好的钢块放入电弧炉或感应熔炉内进行炼制,电弧炉或感应熔炉内的温度为1518-1540摄氏度,当电弧炉或感应熔炉内的钢块刚刚变成钢水的时候,将电弧炉或感应熔炉内的温度升高到1560-1600摄氏度,并利用搅拌设备对钢水进行搅拌,其中搅拌机中的搅拌叶所用的金属为钼或钨,搅拌机中发动机的转速为1200r/min;
    S4:高氮钢冶炼第一步,当电弧炉或感应熔炉内的温度升高到1600摄氏度的时候,停止搅拌,并向钢水内加入氮化锰,氮化锰中锰和氮的比例为氮:锰=12:88,加入氮化锰后再对钢水和氮化锰的合液进行搅拌,此时发动机的转速为2000r/min,待钢水和氮化锰完全融合,停止搅拌;
    S5:高氮钢冶炼第二步,将完全融合的钢水和氮化锰转移至VD炉内,并向VD炉底部充入氮气,VD炉真空处理过程中,底吹氮气压力为0.25MPa-0.75MPa,流量为130-360升/分钟;所述真空处理结束后,底吹氮气压力为0.10MPa-0.20MPa,流量为19-76升/分钟;
    S6:高氮钢浇筑,将钢水、氮化锰与氮气的冶炼液通过导管转移至吊包内,导管内设有不少于2个滤网,滤网孔径的大小按照VD炉到吊包的方向依次减小,吊包内的冶炼液再依次由行车输送至铸型处进行浇筑。
  2. 根据权利要求1所述的一种常压下两步冶炼高氮钢的方法,其特征在 于:所述步骤S1中除锈液和水的比例为除锈液:水=2:1。
  3. 根据权利要求1所述的一种常压下两步冶炼高氮钢的方法,其特征在于:所述步骤S6中滤网的孔径范围在0.08-0.9cm之间。
  4. 根据权利要求1所述的一种常压下两步冶炼高氮钢的方法,其特征在于:所述步骤S2中高压水枪的型号为DW-0951V-1,且起吊夹具的夹持力大于2000N。
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