WO2018099251A1 - 纳米硅镓的隔热、防爆玻璃及其制备方法 - Google Patents
纳米硅镓的隔热、防爆玻璃及其制备方法 Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C27/00—Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
- C03C27/06—Joining glass to glass by processes other than fusing
- C03C27/10—Joining glass to glass by processes other than fusing with the aid of adhesive specially adapted for that purpose
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- the invention relates to the technical field of buildings, in particular to a nano-silicon gallium heat insulation, explosion-proof glass and a preparation method thereof.
- the present invention provides an energy-saving, low-cost, low-cost nano-silicon gallium insulation, explosion-proof glass and a preparation method thereof.
- the present invention relates to a nano-silicon gallium heat-insulating, explosion-proof glass comprising two pieces of glass and a layer of heat-insulating film, the heat-insulating film being held between two pieces of glass, the heat-insulating film being weighted Number of copies, including the following ingredients:
- the heat insulation film further comprises ethyl acetate, butyl acetate and methyl ether, and the total amount of ethyl acetate, butyl acetate and methyl ether is 5-10 parts by weight.
- the heat insulation film further comprises nano zinc oxide, and the nano zinc oxide is 1-2 parts by weight.
- the heat insulation film further comprises a nano aerogel, and the nano aerogel is 0.5-1 parts by weight.
- the invention also discloses a method for preparing nano-silicon gallium heat insulation and explosion-proof glass, comprising the following synthesis steps:
- polyvinyl butyral resin, nano silica, nano gallium oxide, ethyl acetate, butyl acetate, methyl ether, nano zinc oxide and nano aerogel are added to a hot melt furnace and stirred to uniformly mix;
- Preparation of the heat-insulating film feeding the stirred uniform mixture into a casting machine to cast a film-forming material, and then winding the coil into a heat-insulating film;
- Glass cutting preparation the glass is cut by an automatic cutting machine, the cut glass is edging, and then the glass is placed in an automatic cleaning and drying machine for cleaning;
- Film-synthesized finished product After drying, the glass is placed in an automatic laminating production line, and a heat-insulating film is attached. The other film is covered on the heat-insulating film, and the film is heated and pressed by the autoclave to make the film and the upper and lower glass melt firmly. put them together.
- the raw materials are calculated in parts by weight, respectively, 80-90 parts of polyvinyl butyral resin; 1-2 parts of nano-silica; 0.5-1 parts of nano-gallium oxide; 2-4 parts of ester; 2-4 parts of butyl acetate; 1-2 parts of methyl ether; 1-3 parts of nano zinc oxide; and 0.5-1 part of nano aerogel.
- the raw materials are successively put into the hot melting furnace for stirring and mixing.
- the polyvinyl butyral resin is first added to the hot melting furnace; ethyl acetate, butyl acetate and methyl ether are added for heating. Stir; then add nano-silica to stir; add nano-gallium oxide to stir; finally add nano-aerogel to stir.
- the mixture in the preparation process of the heat-insulating film, the mixture is heated to a temperature of 80-120 degrees, the mixture is completely melted, and then sent to a casting machine, and cast into a film material of 0.3-1.2 MM, which is wound into heat insulation. Film roll.
- the glass after the cutting preparation is subjected to the tempering process of the glass
- the specific process is as follows: the cleaned glass is placed in a tempering furnace for tempering, and then the tempered glass is placed The homogenizing furnace is detonated to eliminate the stress of the tempered glass, and then the glass is cleaned and dried, and then placed in an automatic laminating production line for the filming process.
- the nano-silicon gallium heat-insulating and explosion-proof glass of the invention combines nano-silica and nano-silica, and the prepared glass has good light transmittance, heat insulation, ultraviolet shielding and lowering. Noise and other performance, the construction and material price per square meter is only one tenth of LOW-E glass and heat insulation film, the coating has good water resistance and high Surface hardness, strong adhesion, good acid and alkali resistance, mildew resistance, moisture resistance, temperature resistance, wear resistance and flame retardant properties. It can be widely used in transparent insulation and energy saving of automotive glass, architectural glass and plexiglass. It is an excellent replacement product for similar products such as building film.
- FIG. 1 is a flow chart of a method for preparing a nano-silicon gallium heat-insulating and explosion-proof glass according to the present invention.
- a method for preparing a nano-silicon gallium heat-insulating and explosion-proof glass comprises the following synthesis steps:
- Preparation of the mixture firstly add the polyvinyl butyral resin to the hot melt furnace; add ethyl acetate, butyl acetate, methyl ether and stir for 5 minutes; then add nano silica to stir for 2 minutes; then add nano-gallium oxide stirring 2 minutes; finally add nano aerogel and stir for 10 minutes;
- Preparation of the heat-insulating film heating the mixture to a uniform temperature of 80-120 degrees, the mixture is completely melted, and then sent to a casting machine, cast into a film material after 0.3-1.2 MM, and wound into a coil of the heat-insulating film;
- Glass cutting preparation the glass is cut by an automatic cutting machine, the cut glass is edging, and then the glass is placed in an automatic cleaning and drying machine for cleaning;
- Tempering treatment of glass The cleaned glass is placed in a tempering furnace for tempering, and then the tempered glass is placed in a homogenizing furnace for detonation to eliminate the stress of the tempered glass, and then the glass is cleaned and dried and placed in an automatic clamp.
- the glue production line carries out the filming process
- Film-synthesized finished product After drying, the glass is placed in an automatic laminating production line, and a heat-insulating film is attached. The other film is covered on the heat-insulating film, and the film is heated and pressed by the autoclave to make the film and the upper and lower glass melt firmly. put them together.
- the raw materials are calculated in parts by weight, respectively, 80-90 parts of polyvinyl butyral resin; 1-2 parts of nano-silica; 0.5-1 parts of nano-gallium oxide; 2-4 parts of ethyl acetate; 2-4 parts of butyl acetate; 1-2 parts of methyl ether; 1-3 parts of nano zinc oxide; and 0.5-1 part of nano aerogel.
- polyvinyl butyral resin 80 parts 1 part of nano-silica; 0.5 parts of nano-gallium oxide; ethyl acetate 2 Parts; 2 parts of butyl acetate; 1 part of methyl ether; 1 part of nano zinc oxide; and 0.5 part of nano aerogel.
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- Joining Of Glass To Other Materials (AREA)
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Abstract
一种纳米硅镓的隔热、防爆玻璃及其制备方法。该玻璃以重量份数计算,包括聚乙烯醇缩丁醛树脂80-90份;纳米二氧化硅1-2份;纳米氧化镓0.5-1份;乙酸乙酯2-4份;乙酸丁酯2-4份;甲醚1-2份;纳米氧化锌1-3份;以及纳米气凝胶0.5-1份。将纳米二氧化硅与纳米氧化镓结合使用,制备的玻璃具有良好的透光性、隔热保温、隔紫外线、降噪等性能,涂层具有良好的耐水性、较高的表面硬度,强的附着力,良好的耐酸碱性、抗霉变、抗潮湿、耐温差、耐磨性和阻燃性能。可广泛应用于汽车玻璃、建筑玻璃、有机玻璃的透明隔热保温与节能。
Description
本发明涉及建筑的技术领域,尤其涉及一种纳米硅镓的隔热、防爆玻璃及其制备方法。
随着人们对居住要求的提高和建筑水平的进步,各种玻璃在住宅中应用的比例呈现明显上升的趋势。让玻璃既透明又隔热、保温,一直是困扰着技术专家的一个重大课题。传统解决玻璃隔热问题主要使用隔热贴膜、热反射膜和LOW-E玻璃,这些产品透光性差,目前使用最多的LOW-E玻璃,存在严重的光污染和缺乏防爆功能以及昂贵的价格使大众难以接受,市场急需安全、节能减排、价廉物美的升级换代产品。
发明内容
针对上述技术中存在的不足之处,本发明提供一种节能减排、价格低廉的纳米硅镓的隔热、防爆玻璃及其制备方法。
为了达到上述目的,本发明一种纳米硅镓的隔热、防爆玻璃,包括两块玻璃以及一层隔热膜,所述隔热膜加持在两块玻璃之间,所述隔热膜以重量份数计算,包括以下成分:
聚乙烯醇缩丁醛树脂80-90份;
纳米二氧化硅1-2份;
以及纳米氧化镓0.5-1份。
其中,所述隔热膜还包括乙酸乙酯、乙酸丁酯以及甲醚,以重量份数计算,乙酸乙酯、乙酸丁酯以及甲醚共计为5-10份。
其中,所述隔热膜还包括纳米氧化锌,以重量份数计算,纳米氧化锌为1-2份。
其中,所述隔热膜还包括纳米气凝胶,以重量份数计算,纳米气凝胶为0.5-1份。
其中,以重量份数计算,具体包括
聚乙烯醇缩丁醛树脂85份;
纳米二氧化硅1.5份;
纳米氧化镓0.5份;
乙酸乙酯2份;
乙酸丁酯2份;
甲醚1份;
纳米氧化锌1.5份;
以及纳米气凝胶0.5份。
本发明还公开了一种纳米硅镓的隔热、防爆玻璃的制备方法,包括以下合成步骤:
备料混合:将聚乙烯醇缩丁醛树脂、纳米二氧化硅、纳米氧化镓、乙酸乙酯、乙酸丁酯、甲醚、纳米氧化锌以及纳米气凝胶加入热熔炉中搅拌使之均匀混合;
隔热膜的制备:将搅拌均匀混合物送入流延机流延成膜料,再收卷成隔热膜的卷料;
玻璃的切割准备:采用自动切割机将玻璃进行玻璃切割,将切割的玻璃进行磨边处理,然后将玻璃置于自动清洗干燥机中进行清洗;
贴膜合成成品:玻璃进行烘干后置于自动夹胶生产线,贴上隔热膜,在隔热膜上面再覆盖另一块玻璃,通过高压釜加温、高压,使膜与上下玻璃熔解牢牢贴合在一起。
其中,在备料混合的过程中,各原材料以重量份数计算,分别为聚乙烯醇缩丁醛树脂80-90份;纳米二氧化硅1-2份;纳米氧化镓0.5-1份;乙酸乙酯2-4份;乙酸丁酯2-4份;甲醚1-2份;纳米氧化锌1-3份;以及纳米气凝胶0.5-1份。
其中,在备料混合的过程中,各原材料先后投入热熔炉内进行搅拌混合,具体的,首先将聚乙烯醇缩丁醛树脂加入热熔炉中;添加乙酸乙酯、乙酸丁酯、甲醚加温搅拌;然后添加纳米二氧化硅搅拌;再添加纳米氧化镓搅拌;最后添加纳米气凝胶搅拌。
其中,在隔热膜的制备过程中,将搅拌均匀混合物的加热80-120度,使混合物完全熔解后再送入流延机中,流延成0.3-1.2MM后的膜料,收卷成隔热膜的卷料。
其中,在贴膜合成成品的过程中,进行切割准备后的玻璃还要进行玻璃的钢化处理过程,具体过程如下:将清洗干净的玻璃置于钢化炉中进行钢化,然后将钢化好的玻璃置于均质炉进行引爆,消除钢化玻璃的应力,再将玻璃进行清洗烘干后置于自动夹胶生产线进行贴膜过程。
本发明的有益效果是:
与现有技术相比,本发明的纳米硅镓的隔热、防爆玻璃,将纳米二氧化硅与纳米氧化硅结合使用,制备的玻璃具有良好的透光性、隔热保温、隔紫外线、降噪等性能,每平方米施工及材料价格仅为LOW-E玻璃及隔热贴膜的十分之一,涂层具有良好的耐水性、较高
的表面硬度,强的附着力,良好的耐酸碱性、抗霉变、抗潮湿、耐温差、耐磨性和阻燃性能。可广泛应用于汽车玻璃、建筑玻璃、有机玻璃的透明隔热保温与节能,是建筑贴膜等同类产品的优良换代产品。
图1为本发明纳米硅镓的隔热、防爆玻璃的制备方法的流程图。
为了更清楚地表述本发明,下面结合附图对本发明作进一步地描述。
参阅图1,本发明一种纳米硅镓的隔热、防爆玻璃的制备方法,包括以下合成步骤:
备料混合:首先将聚乙烯醇缩丁醛树脂加入热熔炉中;添加乙酸乙酯、乙酸丁酯、甲醚加温搅拌5分钟;然后添加纳米二氧化硅搅拌2分钟;再添加纳米氧化镓搅拌2分钟;最后添加纳米气凝胶搅拌10分钟;
隔热膜的制备:将搅拌均匀混合物的加热80-120度,使混合物完全熔解后再送入流延机中,流延成0.3-1.2MM后的膜料,收卷成隔热膜的卷料;
玻璃的切割准备:采用自动切割机将玻璃进行玻璃切割,将切割的玻璃进行磨边处理,然后将玻璃置于自动清洗干燥机中进行清洗;
玻璃的钢化处理:将清洗干净的玻璃置于钢化炉中进行钢化,然后将钢化好的玻璃置于均质炉进行引爆,消除钢化玻璃的应力,再将玻璃进行清洗烘干后置于自动夹胶生产线进行贴膜过程;
贴膜合成成品:玻璃进行烘干后置于自动夹胶生产线,贴上隔热膜,在隔热膜上面再覆盖另一块玻璃,通过高压釜加温、高压,使膜与上下玻璃熔解牢牢贴合在一起。
在本实施例中,备料混合的过程,各原材料以重量份数计算,分别为聚乙烯醇缩丁醛树脂80-90份;纳米二氧化硅1-2份;纳米氧化镓0.5-1份;乙酸乙酯2-4份;乙酸丁酯2-4份;甲醚1-2份;纳米氧化锌1-3份;以及纳米气凝胶0.5-1份。
各原材料可进行以下三种方式的配比:
1、聚乙烯醇缩丁醛树脂85份;纳米二氧化硅1.5份;纳米氧化镓0.5份;乙酸乙酯2份;乙酸丁酯2份;甲醚1份;纳米氧化锌1.5份以及纳米气凝胶0.5份。
2、聚乙烯醇缩丁醛树脂80份;纳米二氧化硅1份;纳米氧化镓0.5份;乙酸乙酯2
份;乙酸丁酯2份;甲醚1份;纳米氧化锌1份;以及纳米气凝胶0.5份。
3、聚乙烯醇缩丁醛树脂90份;纳米二氧化硅2份;纳米氧化镓1份;乙酸乙酯4份;乙酸丁酯4份;甲醚2份;纳米氧化锌3份;以及纳米气凝胶1份。
以上公开的仅为本发明的几个具体实施例,但是本发明并非局限于此,任何本领域的技术人员能思之的变化都应落入本发明的保护范围。
Claims (10)
- 一种纳米硅镓的隔热、防爆玻璃,其特征在于,包括两块玻璃以及一层隔热膜,所述隔热膜加持在两块玻璃之间,所述隔热膜以重量份数计算,包括以下成分:聚乙烯醇缩丁醛树脂 80-90份;纳米二氧化硅 1-2份;以及纳米氧化镓 0.5-1份。
- 根据权利要求1所述的纳米硅镓的隔热、防爆玻璃,其特征在于,所述隔热膜还包括乙酸乙酯、乙酸丁酯以及甲醚,以重量份数计算,乙酸乙酯、乙酸丁酯以及甲醚共计为5-10份。
- 根据权利要求2所述的纳米硅镓的隔热、防爆玻璃,其特征在于,所述隔热膜还包括纳米氧化锌,以重量份数计算,纳米氧化锌为1-2份。
- 根据权利要求3所述的纳米硅镓的隔热、防爆玻璃,其特征在于,所述隔热膜还包括纳米气凝胶,以重量份数计算,纳米气凝胶为0.5-1份。
- 根据权利要求4所述的纳米硅镓的隔热、防爆玻璃,其特征在于,以重量份数计算,具体包括聚乙烯醇缩丁醛树脂 85份;纳米二氧化硅 1.5份;纳米氧化镓 0.5份;乙酸乙酯 2份;乙酸丁酯 2份;甲醚 1份;纳米氧化锌 1.5份;以及纳米气凝胶 0.5份。
- 一种纳米硅镓的隔热、防爆玻璃的制备方法,其特征在于,包括以下合成步骤:备料混合:将聚乙烯醇缩丁醛树脂、纳米二氧化硅、纳米氧化镓、乙酸乙酯、乙酸丁酯、甲醚、纳米氧化锌以及纳米气凝胶加入热熔炉中搅拌使之均匀混合;隔热膜的制备:将搅拌均匀混合物送入流延机流延成膜料,再收卷成隔热膜的卷料;玻璃的切割准备:采用自动切割机将玻璃进行玻璃切割,将切割的玻璃进行磨边处理,然后将玻璃置于自动清洗干燥机中进行清洗;贴膜合成成品:玻璃进行烘干后置于自动夹胶生产线,贴上隔热膜,在隔热膜上面再覆盖另一块玻璃,通过高压釜加温、高压,使膜与上下玻璃熔解牢牢贴合在一起。
- 根据权利要求6所述的纳米硅镓的隔热、防爆玻璃的制备方法,其特征在于,在备料混合的过程中,各原材料以重量份数计算,分别为聚乙烯醇缩丁醛树脂80-90份;纳米二氧化硅1-2份;纳米氧化镓0.5-1份;乙酸乙酯2-4份;乙酸丁酯2-4份;甲醚1-2份;纳米氧化锌1-3份;以及纳米气凝胶0.5-1份。
- 根据权利要求6所述的纳米硅镓的隔热、防爆玻璃的制备方法,其特征在于,在备料混合的过程中,各原材料先后投入热熔炉内进行搅拌混合,具体的,首先将聚乙烯醇缩丁醛树脂加入热熔炉中;添加乙酸乙酯、乙酸丁酯、甲醚加温搅拌;然后添加纳米二氧化硅搅拌;再添加纳米氧化镓搅拌;最后添加纳米气凝胶搅拌。
- 根据权利要求6所述的纳米硅镓的隔热、防爆玻璃的制备方法,其特征在于,在隔热膜的制备过程中,将搅拌均匀混合物的加热80-120度,使混合物完全熔解后再送入流延机中,流延成0.3-1.2MM后的膜料,收卷成隔热膜的卷料。
- 根据权利要求6所述的纳米硅镓的隔热、防爆玻璃的制备方法,其特征在于,在贴膜合成成品的过程中,进行切割准备后的玻璃还要进行玻璃的钢化处理过程,具体过程如下:将清洗干净的玻璃置于钢化炉中进行钢化,然后将钢化好的玻璃置于均质炉进行引爆,消除钢化玻璃的应力,再将玻璃进行清洗烘干后置于自动夹胶生产线进行贴膜过程。
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