WO2018024191A1 - Procédé de préparation d'un matériau en mousse dopé au graphène - Google Patents

Procédé de préparation d'un matériau en mousse dopé au graphène Download PDF

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Publication number
WO2018024191A1
WO2018024191A1 PCT/CN2017/095422 CN2017095422W WO2018024191A1 WO 2018024191 A1 WO2018024191 A1 WO 2018024191A1 CN 2017095422 W CN2017095422 W CN 2017095422W WO 2018024191 A1 WO2018024191 A1 WO 2018024191A1
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Prior art keywords
parts
mixture
graphene
foamed
rubber
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PCT/CN2017/095422
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English (en)
Chinese (zh)
Inventor
杨与畅
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福建新峰二维材料科技有限公司
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Publication of WO2018024191A1 publication Critical patent/WO2018024191A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853—Vinylacetate
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/02—Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04—Plastics, rubber or vulcanised fibre
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00—Mixing; Kneading
    • B29B7/002—Methods
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34—Auxiliary operations
    • B29C44/60—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/48—Wearing apparel
    • B29L2031/50—Footwear, e.g. shoes or parts thereof
    • B29L2031/504—Soles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2451/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2451/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond

Definitions

  • the invention relates to the field of polymer materials, in particular to a method for preparing a foamed material doped with graphene.
  • the foaming material is widely used in the manufacture of sports equipment, seat cushions, children's floors, sports shoes, etc. due to its light weight, good softness, cushioning, sound absorption, shock absorption, heat preservation and filtration.
  • the application in the foam sole of different materials has the following problems: PE foam sole has poor elasticity, poor anti-slip performance, easy deformation after wearing for a long time; EVA foam sole mechanical strength, tear resistance and resistance The peelability is not good enough; therefore, the application of the foamed material to the sole is limited to some extent.
  • Graphene has a unique two-dimensional periodic honeycomb lattice structure, and the existence of a stable carbon six-membered ring in its structural unit gives it excellent thermal properties, mechanical properties and electrical conductivity. Therefore, the addition of graphene to the foaming material can effectively improve the mechanical properties such as tear resistance and peeling resistance of the foamed sole, thereby widening the application range of the sole.
  • the specific surface area of graphene is huge and there is an inherent van der Waals force between the sheets, so graphene is extremely easy to agglomerate; at the same time, polyethylene and the like are non-polar polymers, and the compatibility with graphene is poor, which makes it difficult for graphene to be in polyethylene.
  • the graphene is added purely to the foamed material, and the performance improvement effect on the foamed material is not remarkable.
  • the object of the present invention is to solve the problem that the existing foaming material is doped with graphene, and to provide a method for preparing a foaming material doped with graphene, which can avoid graphite by effectively and uniformly dispersing graphene into the foaming material.
  • the olefin itself agglomerates to enhance the mechanical properties of the foamed material.
  • the present invention provides the following technical solution: a method for preparing a foamed material which is effectively doped with graphene, the method comprising the following steps: (1) granulation: 100 parts by weight The main material, 0.5-10 parts of graphene oxide, 1-4 parts of dispersion accelerator, 0.5-5 parts of lubricant are stirred and mixed to obtain a mixture; the obtained mixture is melt-mixed, and after cooling, pass through the pelletizing The machine performs pelletizing to obtain pellets containing graphene; (2) mixing: the pellet obtained in the step (1) is 100 parts by weight with 4-15 parts of the AC foaming agent, and 1-4 parts of the sulfide Zinc oxide, 1-5 parts of stearic acid, 15-45 parts of filler calcium powder or talc, 1-4 parts of DCP crosslinker and 0.5-3 parts of TAIC crosslinking aid together The refining machine performs the refining; (3) the opening: the mixture obtained in the step (2) is put into the rubber mixing machine for secondary mixing
  • the sheet-like foam material pulled out from the rubber mixer and cut into pieces; (4) hot-press foaming: the sheet-like foaming material is foamed in a hot press, and then the mold is cooled by water to At room temperature, a molded foam sole is obtained.
  • the host material of the step (1) is at least one of ethylene-vinyl acetate copolymer, polyethylene or recycled material.
  • the dispersion promoter of the step (1) is at least one of MAH-g-PE, MAH-g-EVA, MAH-g-HDPE, MAH-g-SEBS, and MAH-g-LLPDE. .
  • the agitation mixing of the step (1) to obtain a mixture is specifically carried out by a high speed mixer for 5-30 min.
  • step (1) the mixture obtained by a is melt-mixed, specifically, the mixture obtained by adding a to the twin-screw extruder is melt-mixed, wherein the screw speed is 20-200 rpm and the temperature is 130-200 ° C.
  • the mixing time is 5-20 min; the cooling is that the mixture is extruded by twin-screw and then cooled by a water tank.
  • the temperature of the mixing in the step (2) is 120-130 ° C, and the mixing time is 2-5 min.
  • the temperature for performing the second mixing in the step (3) is 110-140 ° C.
  • the rubber compound is subsequently adjusted into a sheet, and the sheet material which is pulled out from the rubber mixer and cut into pieces is specifically adjusted to adjust the mixture rubber to a sheet of 1-1.5 mm thickness.
  • the rubber mixer was pulled out and cut into a sheet-shaped foamed material of 40 cm * 80 cm.
  • the sheet-like foaming material is foamed in a hot press, and then the mold is cooled by water to room temperature, and the formed foamed sole is specifically filled with a sheet-like material at a temperature of 165. -190 ° C heat
  • the machine is foamed for 10-20 min, and then the mold is cooled by water to room temperature to obtain a molded foam sole.
  • the invention has the beneficial effects that by adding a dispersing accelerator while adding the graphene to the foaming material, the strong polar reactive group is introduced, the compatibility is increased, and the dispersion of the graphene in the polymer is improved. Therefore, the graphene is effectively doped in the foamed material, thereby improving the tear resistance and peeling resistance of the foamed sole.
  • the invention discloses a preparation method of a foaming material which is effectively doped with graphene, and the method comprises the following steps: (1) granulation: 100 parts by weight of the host material, 0.5-10 parts of graphene oxide 1-4 parts of a dispersion accelerator, 0.5-5 parts of a lubricant are stirred and mixed to obtain a mixture; the obtained mixture is melt-mixed, and after cooling, it is diced by a pelletizer to obtain a pellet containing graphene. ;
  • the pellet obtained in the step (1) is 100 parts by weight with 4-15 parts of the AC foaming agent, 1-4 parts of the vulcanizing agent zinc oxide, 1-5 parts of stearic acid, 15-45 parts of filler calcium powder or talc, 1-4 parts of DCP cross-linking agent and 0.5-3 parts of TAIC cross-linking aid are placed in an internal mixer for mixing;
  • Hot-press foaming The sheet-like foaming material is foamed in a hot press, and then the mold is cooled by water to room temperature to obtain a molded sole.
  • the main material of the step (1) is at least one of ethylene-vinyl acetate copolymer, polyethylene or recycled material;
  • the dispersion promoter is maleic anhydride grafted polyethylene (MAH-g-PE), Maleic anhydride grafted ethylene-vinyl acetate copolymer (MAH-g-EVA), maleic anhydride grafted ethylene propylene diene monomer (MAH-g-HDPE), maleic anhydride grafted styrene-ethylene-butadiene -styrene triblock copolymer (MAH-g-SEBS), at least one of maleic anhydride grafted linear low density polyethylene (MAH-g-LLPDE).
  • MAH-g-PE Maleic anhydride grafted polyethylene
  • MAH-g-EVA Maleic anhydride grafted ethylene-vinyl acetate copolymer
  • MAH-g-HDPE maleic anhydride grafted ethylene propy
  • Maleic anhydride grafting compatibilizers provide high polarity and reactivity by introducing strong polar reactions, increasing the compatibility between materials, while maleic anhydride grafting compatibilizer is an unsaturated organic
  • the basic material of the acid anhydride can be bonded to a functional group such as a hydroxyl group or a carboxyl group on the surface of the graphene oxide, which can effectively avoid the agglomeration of the graphene itself, and facilitate the dispersion in the polymer, thereby performing effective graphene doping on the foamed material.
  • EVA ethylene-vinyl acetate copolymer
  • graphene oxide 2 parts of graphene oxide
  • MAH-g-EVA maleic anhydride grafted ethylene-vinyl acetate copolymer
  • the lubricant is placed in a high-speed mixer for mixing for 10 min; then the mixed mixture is added to a twin-screw extruder for melt mixing, the screw speed is 120 rpm, and the mixture is kneaded at 150 ° C for 10 min; After cooling, the pelletizing operation is performed by a pelletizer to obtain pellets containing graphene;
  • pellets were crosslinked with 8 parts of AC foaming agent, 2 parts of zinc oxide, 1 part of stearic acid, 25 parts of calcium powder, 1 part of DCP crosslinking agent and 0.5 part of TAIC.
  • the agent is placed in an internal mixer for mixing, and the temperature is 120 ° C for 3 minutes; then the mixed mixture is put into a rubber mixing machine for secondary mixing, and the materials are thoroughly mixed to obtain a uniformly mixed rubber;
  • the opening temperature was controlled at 125 ° C; then the material was adjusted to a 1 mm thick piece, which was pulled out from the rubber mixer and cut into a 40 cm * 80 cm sheet-like foam material;
  • the sheet-like foaming material was foamed in a hot press at 180 ° C for 15 min, and then the mold was cooled by water to room temperature to obtain a molded sole.
  • EVA ethylene-vinyl acetate copolymer
  • graphene oxide 5 parts
  • MAH-g-PE maleic anhydride grafted polyethylene
  • lubricant 1 part of lubricant
  • the mixture was mixed in a high-speed mixer for 10 minutes; then the mixed mixture was added to a twin-screw extruder for melt mixing, the screw rotation speed was 120 rpm, and the mixture was kneaded at 150 ° C for 10 minutes; then, after being extruded by twin-screw, cooled by a water tank, The pelletizing operation is performed by a pelletizer to obtain pellets containing graphene;
  • the pellets were crosslinked with 10 parts of AC foaming agent, 2 parts of zinc oxide, 1 part of stearic acid, 20 parts of calcium powder, 2 parts of DCP crosslinking agent and 1 part of TAIC.
  • the agent is placed together in an internal mixer for mixing, and the temperature is 120 ° C for 5 minutes; then the mixed mixture is put into a rubber mixing machine for secondary mixing, and the materials are thoroughly mixed to obtain a uniformly mixed rubber;
  • the opening temperature was controlled at 125 ° C; then the material was adjusted to a 1 mm thick piece, which was pulled out from the rubber mixer and cut into a 40 cm * 80 cm sheet-like foam material;
  • the sheet-like foaming material was foamed in a hot press at 180 ° C for 15 min, and then the mold was cooled to room temperature by water to obtain a molded sole.
  • PE polyethylene
  • MAH-g-LLPDE maleic anhydride grafted linear low density polyethylene
  • lubricant 100 parts of PE (polyethylene), 8 parts of graphene oxide, 3 parts of MAH-g-LLPDE (maleic anhydride grafted linear low density polyethylene), and 2 parts of lubricant are placed in a high speed mixer. Mixing for 20 min; then mixing the uniformly mixed mixture into a twin-screw extruder for melt mixing, screw rotation speed of 100 rpm, and kneading at 150 ° C for 20 min; followed by extrusion by twin-screw, cooling through a water tank, and then passing through a pelletizer a pelletizing operation to obtain a pellet containing graphene;
  • pellets were crosslinked with 9 parts of AC foaming agent, 3 parts of zinc oxide, 2 parts of stearic acid, 25 parts of calcium powder, 1.5 parts of DCP crosslinking agent and 1 part of TAIC.
  • the agent is placed in an internal mixer for mixing, and the temperature is 120 ° C for 3 minutes; then the mixed mixture is put into a rubber mixing machine for secondary mixing, and the materials are thoroughly mixed to obtain a uniformly mixed rubber;
  • the opening temperature was controlled at 128 ° C; then the material was adjusted to a 1 mm thick piece, pulled out from the rubber mixer and cut into 40 cm * 80 cm sheet foam material;
  • the sheet foam material was foamed in a hot press at 175 ° C for 20 min, and then the mold was cooled to room temperature by water to obtain a molded sole.
  • pellets were crosslinked with 8 parts of AC foaming agent, 2 parts of zinc oxide, 1 part of stearic acid, 25 parts of calcium powder, 1 part of DCP crosslinking agent and 0.5 part of TAIC.
  • the agent is placed in an internal mixer for mixing, and the temperature is 120 ° C for 3 minutes; then the mixed mixture is put into a rubber mixing machine for secondary mixing, and the materials are thoroughly mixed to obtain a uniformly mixed rubber;
  • the opening temperature was controlled at 125 ° C; then the material was adjusted to a 1 mm thick piece, which was pulled out from the rubber mixer and cut into a 40 cm * 80 cm sheet-like foam material;
  • the sheet-like foaming material was foamed in a hot press at 180 ° C for 15 min, and then the mold was cooled to room temperature by water to obtain a molded sole.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

L'invention concerne un procédé de préparation d'un matériau en mousse dopé au graphène. Le procédé comprend : (1) une granulation : l'agitation et le mélange de 100 parties de matériaux principaux, de 0,5 à 10 parties d'oxyde de graphène, de 1 à 4 parties d'accélérateur dispersé, de 0,5 à 5 parties de lubrifiants en poids pour obtenir un mélange, le mélange à l'état fondu et le refroidissement du mélange obtenu, et le découpage en dés du mélange à l'aide d'un dispositif de coupe en dés, pour obtenir un matériau granulaire contenant du graphène ; (2) un mélange interne à piston : le placement de 100 parties des matériaux granulaires obtenus à l'étape (1), de 4 à 15 parties d'agents moussants AC, de 1 à 4 parties d'agents de vulcanisation : de l'oxyde de zinc, de 1 à 5 parties d'acide stéarique, de 15 à 45 parties de charges: de la poudre de calcium ou de la poudre de talc, de 1 à 4 parties d'agents de réticulation DCP, et de 0,5 à 3 parties de co-agents de réticulation TAIC en poids dans un mélangeur interne à piston afin de mélanger ; (3) un broyage ouvert : l'ajustement d'un mélange de caoutchouc en une pièce, l'extraction de la pièce d'un mélangeur d'affinage de caoutchouc et la coupe de la pièce en un matériau en feuille ; (4) un moussage par compression thermique : le placement du matériau en feuille dans un compresseur thermique pour le moussage, et le refroidissement à l'eau d'un moule à la température ambiante, pour obtenir une semelle de chaussure en mousse formée. Le procédé permet d'empêcher le graphène de s'agréger, de façon à améliorer la propriété mécanique du matériau en mousse.
PCT/CN2017/095422 2016-08-01 2017-08-01 Procédé de préparation d'un matériau en mousse dopé au graphène WO2018024191A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201610619593.9A CN107674292A (zh) 2016-08-01 2016-08-01 一种掺杂石墨烯的发泡材料的制备方法
CN201610619593.9 2016-08-01

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Cited By (5)

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CN108997647A (zh) * 2018-08-06 2018-12-14 晋江蓝鲸鞋业有限公司 鞋底用减震片材及其制备工艺
CN109265808A (zh) * 2018-08-06 2019-01-25 晋江蓝鲸鞋业有限公司 鞋底用低压缩变形片材及其制备工艺
CN110183770A (zh) * 2019-06-05 2019-08-30 福建五持恒科技发展有限公司 一种石墨烯橡塑发泡鞋底胶粒及其制备方法
CN110982132A (zh) * 2019-11-14 2020-04-10 浙江恒诚鞋业有限公司 抗臭氧橡胶鞋底及其制备方法
CN113583288A (zh) * 2021-07-27 2021-11-02 浙江润阳新材料科技股份有限公司 一种发泡材料及其制备方法

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CN109161072A (zh) * 2018-06-30 2019-01-08 杭州高烯科技有限公司 一种石墨烯-发泡聚乙烯复合材料及其制备方法
CN109161085A (zh) * 2018-06-30 2019-01-08 杭州高烯科技有限公司 一种石墨烯-发泡eva复合材料及其制备方法
CN110016181A (zh) * 2019-05-08 2019-07-16 福建五持恒科技发展有限公司 石墨烯再生橡塑发泡鞋垫及其制备方法
CN110054831A (zh) * 2019-05-08 2019-07-26 福建五持恒科技发展有限公司 一种石墨烯再生eva发泡鞋底胶粒及其制备方法
CN110144075A (zh) * 2019-06-05 2019-08-20 福建五持恒科技发展有限公司 一种石墨烯再生橡胶发泡鞋底胶粒及其制备方法
CN110818990A (zh) * 2019-10-28 2020-02-21 茂泰(福建)鞋材有限公司 一种轻便慢跑鞋鞋底的制备方法
CN110885487A (zh) * 2019-10-28 2020-03-17 茂泰(福建)鞋材有限公司 一种可生物降解发泡鞋底的制备方法
CN110885486A (zh) * 2019-10-28 2020-03-17 茂泰(福建)鞋材有限公司 一种发泡鞋底的制作方法
CN110938250A (zh) * 2019-11-14 2020-03-31 浙江恒诚鞋业有限公司 发泡鞋底及其制备方法
CN112029248A (zh) * 2020-09-08 2020-12-04 吴乙胜 一种高弹性环保型塑胶板材及其制备工艺
CN115071159B (zh) * 2022-08-23 2022-12-02 张家港梦康生活家居科技有限公司 基于自控温发泡通道的石墨烯地垫生产线

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB521764A (en) * 1938-11-25 1940-05-30 Craigpark Electric Cable Compa Improved rubber-like compositions
CN102924801A (zh) * 2012-10-25 2013-02-13 陕西科技大学 一种复合发泡材料的制备方法
CN104530612A (zh) * 2014-12-31 2015-04-22 宁波市中迪鞋业有限公司 一种耐磨登山鞋
CN204617215U (zh) * 2015-05-12 2015-09-09 藍石科技(開曼)有限公司 一种轻便鞋
CN105001529A (zh) * 2015-08-26 2015-10-28 东莞市海塑实业有限公司 一种发泡导电热塑性动态硫化橡胶复合材料及其制备方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1321150C (zh) * 2005-09-12 2007-06-13 上海汽车集团股份有限公司 热塑性发泡nvh材料及其制造方法
CN102443214B (zh) * 2011-09-23 2013-04-03 福建师范大学 一种高倍率聚乙烯发泡材料的制备方法
CN103908035A (zh) * 2014-03-04 2014-07-09 青岛亨达股份有限公司 Eva独立中底凉鞋制作方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB521764A (en) * 1938-11-25 1940-05-30 Craigpark Electric Cable Compa Improved rubber-like compositions
CN102924801A (zh) * 2012-10-25 2013-02-13 陕西科技大学 一种复合发泡材料的制备方法
CN104530612A (zh) * 2014-12-31 2015-04-22 宁波市中迪鞋业有限公司 一种耐磨登山鞋
CN204617215U (zh) * 2015-05-12 2015-09-09 藍石科技(開曼)有限公司 一种轻便鞋
CN105001529A (zh) * 2015-08-26 2015-10-28 东莞市海塑实业有限公司 一种发泡导电热塑性动态硫化橡胶复合材料及其制备方法

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108997647A (zh) * 2018-08-06 2018-12-14 晋江蓝鲸鞋业有限公司 鞋底用减震片材及其制备工艺
CN109265808A (zh) * 2018-08-06 2019-01-25 晋江蓝鲸鞋业有限公司 鞋底用低压缩变形片材及其制备工艺
CN110183770A (zh) * 2019-06-05 2019-08-30 福建五持恒科技发展有限公司 一种石墨烯橡塑发泡鞋底胶粒及其制备方法
CN110982132A (zh) * 2019-11-14 2020-04-10 浙江恒诚鞋业有限公司 抗臭氧橡胶鞋底及其制备方法
CN113583288A (zh) * 2021-07-27 2021-11-02 浙江润阳新材料科技股份有限公司 一种发泡材料及其制备方法

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