WO2017188513A1 - Brosse à dents jetable revêtue d'une pâte dentifrice liquide - Google Patents

Brosse à dents jetable revêtue d'une pâte dentifrice liquide Download PDF

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Publication number
WO2017188513A1
WO2017188513A1 PCT/KR2016/008096 KR2016008096W WO2017188513A1 WO 2017188513 A1 WO2017188513 A1 WO 2017188513A1 KR 2016008096 W KR2016008096 W KR 2016008096W WO 2017188513 A1 WO2017188513 A1 WO 2017188513A1
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WO
WIPO (PCT)
Prior art keywords
liquid toothpaste
toothpaste
disposable toothbrush
toothbrush
liquid
Prior art date
Application number
PCT/KR2016/008096
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English (en)
Korean (ko)
Inventor
김주형
Original Assignee
주식회사 수호천사엔젤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 수호천사엔젤 filed Critical 주식회사 수호천사엔젤
Priority to CN201680076720.3A priority Critical patent/CN108471873A/zh
Publication of WO2017188513A1 publication Critical patent/WO2017188513A1/fr

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Classifications

    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B11/00Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B11/00Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water
    • A46B11/0003Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water containing only one dose of substance, e.g. single-use toothbrushes
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B11/00Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water
    • A46B11/0006Brushes with reservoir or other means for applying substances, e.g. paints, pastes, water specially adapted to feed the bristle upper surface
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof

Definitions

  • the present invention relates to a disposable toothbrush, and more particularly to a toothbrush coated with a liquid toothpaste for single use.
  • Toothbrushes are oral hygiene tools used with toothpaste, with bristles arranged in multiple rows. Toothpaste is embedded in brush heads for the purpose of cleaning and polishing teeth, and contains various kinds of substances for oral hygiene.
  • toothpaste is sold in a tube container laminated mainly of a flexible material such as aluminum or synthetic resin so as to squeeze with a finger.
  • the toothbrush used for single use is calculated
  • Disposable toothbrushes are liquid toothpaste coated on the bristles.
  • Korean Patent Publication No. 2001-0075492 proposes a liquid toothpaste that does not go too fast and deeply with a toothbrush by adjusting the ratio of water and a humectant.
  • the liquid toothpaste has a problem of inconvenience in use due to low shape retention and fluidity.
  • Formability refers to the characteristic that the fluidity is large when it is large, and flows straight like water.
  • Korean Laid-open Patent No. 2004-0021851 contains casein sodium to improve the shape retention and dispersion stability of liquid toothpaste. As such, the composition of the liquid toothpaste has been variously presented according to its purpose.
  • the conventional liquid dentifrice composition contains mostly abrasives.
  • abrasive mainly precipitated silica, silica gel, calcium dihydrogen phosphate, calcium carbonate, hydrous alumina, insoluble sodium methyphosphate, calcium pyrophosphate, zirconium silicate, hydroxyapatite, etc. are used alone or in combination. Brushing can cause cervical wear and tear, which can lead to tooth hypersensitivity. Furthermore, chemical additives contained in liquid toothpaste may adversely affect dental health.
  • the problem to be solved by the present invention is to provide a disposable toothbrush coated with a liquid toothpaste is well adsorbed, there is no component lost in the drying process, there is no abrasive for dental health and significantly reduce the content of chemical additives.
  • Disposable toothbrush coated with a liquid toothpaste for solving the problems of the present invention includes a toothbrush in which a plurality of bristles are planted, an organosilicon compound layer formed on the surface of the bristles and a liquid toothpaste layer applied to the glass silicon compound layer.
  • the organosilicon compound layer may be hydrophilized with an organosiloxane as a source gas.
  • the organosiloxane source gas may be any one selected from tetramethyldisiloxane (TMDSO), hexamethyldisiloxane (HMDSO), tetraethylorthosilicate (TEOS), and hexamethylcyclotrisiloxane (HMCTSO).
  • the organosiloxane source gas may be hexamethylcyclotrisiloxane (HMCTSO).
  • the organosilicon compound is preferably SiO x Cy (-H) (1.0 ⁇ x ⁇ 2.4 and 0.0 ⁇ y ⁇ 1.0).
  • the liquid toothpaste forming the liquid toothpaste layer may be treated by focused ultrasound.
  • the liquid toothpaste layer is 0.001% by weight of general toothpaste components containing periodontal disease prevention agent, sweetener, wetting agent, pH adjuster, water-soluble coating agent, foaming agent, solubilizer, colorant, flavoring agent and other unavoidable components
  • general toothpaste components containing periodontal disease prevention agent, sweetener, wetting agent, pH adjuster, water-soluble coating agent, foaming agent, solubilizer, colorant, flavoring agent and other unavoidable components
  • licorice extract, green tea extract 0.001% to 50% by weight of the natural component containing at least one component selected from xylitol and 0.001% to 50% by weight of a solvent which is any one or a mixture of purified water and ethanol It may include.
  • the disposable toothbrush coated with the liquid toothpaste of the present invention by forming an organosilicon compound layer on the bristles, adsorption is well performed, there is no component lost during the drying process, there is no abrasive for dental health and significantly increased the amount of chemical additives Reduce In addition, it is possible to improve the shape retention and fluidity of the liquid toothpaste using a focused ultrasound device.
  • FIG. 1 is a cross-sectional view showing a disposable toothbrush coated with a liquid toothpaste according to the present invention.
  • An embodiment of the present invention provides a toothbrush by forming an organosilicon compound layer on the bristles, adsorption is good, there is no component lost during the drying process, there is no abrasive for dental health and significantly reduce the content of chemical additives.
  • adsorption is good, there is no component lost during the drying process, there is no abrasive for dental health and significantly reduce the content of chemical additives.
  • the composition of the liquid toothpaste in order to achieve the object of the present invention in detail, it will be described in detail the toothbrush coated with the liquid toothpaste.
  • Liquid toothpaste of the present invention is coated on the bristle of the toothbrush used for single use in a special place, such as a business trip, travel process, hotel, aircraft.
  • FIG. 1 is a cross-sectional view showing a disposable toothbrush coated with a liquid toothpaste according to an embodiment of the present invention.
  • the liquid toothpaste layer 3 is coated on the bristles 2 planted in a plurality of rows in the toothbrush 1. Uncoated, some show a partially coated liquid toothpaste layer 3. Between the liquid toothpaste layer 3 and the bristle 2, the liquid toothpaste layer 3 is easily applied to the bristle 2, and there is an organosilicon compound layer 4 for enhancing the bonding force.
  • the liquid toothpaste composition constituting the liquid toothpaste layer 3 will be described in detail, and then the organosilicon compound layer 4 will be described in detail.
  • Liquid toothpaste composition of the present invention is largely divided into solvents and general toothpaste components, natural ingredients, other inevitable components and solvents.
  • the general toothpaste component is 0.001% to 10% by weight
  • the natural component is 0.001% to 10% by weight
  • the other components are 0.001% to 10% by weight
  • the solvent is 30% by weight relative to the liquid toothpaste component It consists of 95% by weight.
  • the inevitable components may include a thickener.
  • the solvent is applied to any one of purified water, ethanol or a mixture thereof.
  • the general toothpaste component comprises a periodontal disease prevention agent, a sweetener, a humectant, a pH adjusting agent, a water-soluble coating agent, a foaming agent, a solubilizer, a colorant, a flavoring agent and other unavoidable ingredients.
  • the periodontal disease prevention agent is 0.001% to 10% by weight
  • the sweetener is 0.001% to 10% by weight
  • the wetting agent is 0.001% to 10% by weight
  • the pH adjuster is 0.001% by weight %
  • the water-soluble coating agent is 0.001% to 10% by weight
  • the blowing agent is 0.001% to 10% by weight
  • the solubilizer is 0.001% to 10% by weight
  • the colorant is 0.001% to 10% by weight %
  • the flavoring agent is 0.001% to 10% by weight
  • the other unavoidable components are comprised from 0.001% to 10% by weight.
  • the periodontal disease preventive agents include tranexamic acid, tocopherol acetate, pyridoxine hydrochloride, allantoin, allantoin hydroxyaluminum, aminocaproic acid, and the like, in particular, allantoin and allantoin hydroxyaluminum.
  • the sweeteners include sodium saccharin hydrate, sorbitol, xylitol, steviol glycosides, erythritol, sucralose, aspartame, acetal palmkei, vitamin C, sodium chloride, and the like.
  • the humectant includes glycerin, sorbitol solution, polyethylene glycol, propylene glycol, amorphous sorbitol solution, and the like, and glycerin is commonly used.
  • the pH adjusting agent is preferably citric acid, and the citric acid has a strong sterilizing effect with detoxification action, the water content is 99.5% citric anhydride is more preferable.
  • the water-soluble coating agent is xanthan gum, aribian gum, carboxymethyl cellulose sodium, carbomer, PVP and the like, of which carboxymethyl cellulose sodium is preferred.
  • the blowing agent according to an embodiment of the present invention is applied sodium lauryl sulfate.
  • the sodium lauryl sulfate is an anionic surfactant used to uniformly disperse a liquid or a solid in a liquid that does not mix well with each other.
  • the solubilizer is also called an emulsifier, and polyoxyethylene hydrogenated castor oil (trade name HCO-60) is preferable.
  • the coloring agent is a triphenylmethane pigment blue No. 1, the flavoring agent peppermint oil, spearmint oil, eucalyptus oil, lemon oil, winter green, sage, methyl salicylate, other fruit extract, L Menthol, diementhol, menthol, diecampa and the like.
  • the natural ingredients replaced the chemical components through extracts such as licorice, green tea. Reducing the amount of chemical additives to the natural ingredients, there is an excellent effect in the prevention of tooth decay and oral disease as toothpaste with less irritation. It is also effective in oral cleansing, bad breath removal and plaque removal. In addition, no abrasive is required and therefore suitable for use by users with weak teeth, especially young children. It does not add fluorine and adds tooth decay prevention ingredient with natural ingredients, so you can feel refreshing and refreshing after brushing teeth. It keeps teeth white and healthy.
  • licorice extract As the natural ingredients, there are licorice extract, green tea extract and xylitol, and these may be applied alone or in combination.
  • the licorice serves to soften the taste and promote the effect of the toothpaste with detoxification.
  • Licorice contains gurucronic acid, a glycithin glycoside, similar to the corticosteroids, and it has the effect of smoothing metabolism and stabilizing nerves. Therefore, it is effective for oral ulcers and analgesic, and also has the effect of relieving pain and cramps.
  • strong bactericidal action prevents the activity of a wide range of cells in the oral cavity.
  • licorice has the effects of gum disease prevention, tartar formation inhibition, antibacterial anti-inflammatory action, bad breath removal, plaque removal, gingivitis and periodontal disease prevention.
  • the green tea is a catechin component to sterilize the oral bacteria to prevent tooth decay and bad breath.
  • the xylitol is a pentose structure composed of five carbons to prevent tooth decay by disinfecting mutans bacteria.
  • the liquid toothpaste of the present invention can induce uniform dispersion by using a focused ultrasound device (not shown).
  • Ultrasound refers to a wave having a frequency of 20 KHz or more, and a form in which the ultrasonic wave is focused at a high intensity is called focused ultrasound, and the focused ultrasound generator includes a transducer that emits ultrasonic waves, and specifies the emitted ultrasonic wave. Focus at one point (called "focus").
  • the focused ultrasound apparatus can freely adjust the focal length.
  • the focused ultrasound device comprises a refractive lens. It is disposed in the refractive lens unit accommodating space and detachably mounted to the ultrasonic radiation plane, and refractions the focused ultrasound radiation emitted from the ultrasonic radiation plane to adjust the focal length of the ultrasonic wave to a set value.
  • each component is refined by a focused ultrasound device and uniformly dispersed in each other.
  • the specific surface area of each component is increased, so that the amount of bubbles is generated, and the adsorption occurs well on the organosilicon compound layer 4 and is more firmly fixed.
  • the enlarged specific surface area of the liquid toothpaste component reduces the drying time of the liquid toothpaste layer (3).
  • the liquid toothpaste of the present invention does not contain an abrasive component, thereby causing cervical abrasion, thereby preventing periodontal disease such as hypersensitivity to teeth.
  • by reducing the chemical additives contained in the liquid toothpaste it is possible to improve dental health.
  • Toothbrush coated with liquid toothpaste are Toothbrush coated with liquid toothpaste
  • the liquid toothpaste layer 3 is applied to the organosilicon compound layer 4 formed on the bristles 2.
  • the organosilicon compound layer 4 is formed by hydrophilic treatment of an organosiloxane as a source gas by atmospheric pressure plasma.
  • Atmospheric pressure plasma apparatus has the advantages of low cost, low process temperature, and can perform the process continuously.
  • a gas nozzle is disposed between the two metal electrodes to discharge the gas required in the process toward the bristle 2.
  • a plasma is formed between the metal electrode and the ground to convert the gas discharged through the gas nozzle into a plasma state.
  • Gases used in the present invention include an organosiloxane source gas, a carrier gas for loading and moving the source gas, an inert gas for stabilizing the plasma, and an oxidant gas for generating an oxygen plasma.
  • the organosiloxane which is the source gas
  • the source gas has an adequate vapor pressure in which a sufficient amount of the compound can be included in the carrier gas while using the excess heating to volatilize it so as not to reach the spontaneous ignition temperature of the mixture.
  • the organosiloxane source is preferably tetramethyldisiloxane (TMDSO), hexamethyldisiloxane (HMDSO), tetraethylorthosilicate (TEOS) and hexamethylcyclotrisiloxane (HMCTSO), wherein HMCTSO is C 6 H 18 O 3 It is more preferable because it has a chemical structure of Si 3 and has a relatively higher vapor pressure than other materials even at atmospheric pressure.
  • TMDSO tetramethyldisiloxane
  • HMDSO hexamethyldisiloxane
  • TEOS tetraethylorthosilicate
  • HMCTSO hexamethylcyclotrisiloxane
  • the source gas is carried in a well known carrier gas and mixed with an inert gas to stabilize the formation of the plasma and carried to the gas nozzle.
  • the inert gas may be any one selected from nitrogen gas, argon gas, neon and helium gas. When considering the stability of the plasma, helium gas is preferable, but even if nitrogen gas is used, nitrogen gas may be used since the hydrophilic effect of the present invention is sufficiently expressed.
  • an organosilicon compound is generated.
  • the organosilicon compound serves to improve the adhesion between the bristles (2) and the liquid toothpaste layer (3).
  • the thickness of an organosilicon compound changes with the characteristics of the bristles 2, 50-2,000 GPa is preferable.
  • the organosilicon compound according to an embodiment of the present invention may be SiOxCy ( ⁇ H), where 1.0 ⁇ x ⁇ 2.4 and 0.0 ⁇ y ⁇ 1.0 are satisfied.
  • SiOxCy (-H) the organosilicon compound, has a contact angle of about 80 °.
  • the surface of the brush head 2 coated with the organosilicon compound is plasma-treated using an oxygen plasma generated by an oxidant gas through an atmospheric pressure plasma apparatus.
  • the oxidant gas includes O 2 , O 3 , NO, NO 2 , N 2 O, N 2 O 3 and N 2 O 4 .
  • Preferred oxidant is oxygen (O 2 ).
  • additional gases such as CO 2 and N 2 may be included.
  • Preferred gas mixtures are air or a mixture of oxygen and nitrogen.
  • the organosilicon compound layer 4 according to the embodiment of the present invention may be formed in a yarn state.
  • the bristle 2 is cut in the yarn to an appropriate size and planted in the body of the toothbrush 1.
  • the toothbrush 1 has a plurality of bristles 2 planted by cutting the yarn having the organosilicon compound layer 4 formed to a desired length.
  • the liquid toothpaste layer 3 is applied on the organosilicon compound layer 4.
  • the method of applying the liquid toothpaste layer 3 is not necessarily limited thereto, but may use dipping, spraying, or the like.

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Abstract

La présente invention concerne une brosse à dents jetable revêtue d'une pâte dentifrice liquide, laquelle est bien adsorbée, ne présente pas de constituants perdus durant un processus de séchage, a une teneur significativement réduite en additifs chimiques et ne présente aucun abrasif, afin d'assurer la santé des dents. La brosse à dents comprend une brosse à dents dans laquelle sont plantés une pluralité de poils, une couche de composé d'organosilicium formée sur les surfaces des poils, et une couche de pâte dentifrice liquide appliquée sur une couche de composé de verre-silicium.
PCT/KR2016/008096 2016-04-25 2016-07-25 Brosse à dents jetable revêtue d'une pâte dentifrice liquide WO2017188513A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201680076720.3A CN108471873A (zh) 2016-04-25 2016-07-25 涂布液体牙膏的一次性牙刷

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020160049812A KR101761198B1 (ko) 2016-04-25 2016-04-25 액상치약이 코팅된 일회용 칫솔
KR10-2016-0049812 2016-04-25

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WO2017188513A1 true WO2017188513A1 (fr) 2017-11-02

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
KR20190088805A (ko) * 2018-01-19 2019-07-29 김한수 발포 정제형 치약 조성물 및 그 제조방법
KR20200099801A (ko) * 2019-02-15 2020-08-25 주식회사 메디덴코 항균 성능이 개선된 치약 조성물 및 이를 포함하는 치약

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WO2020116671A1 (fr) * 2018-12-05 2020-06-11 주식회사 브러시월드 Brosse à dents modulaire biodégradable et respectueuse de l'environnement
KR102086746B1 (ko) * 2018-12-05 2020-04-20 주식회사 브러시월드 생분해성 필라멘트에 치약이 도포된 친환경 칫솔
CN115413878B (zh) * 2022-10-19 2023-09-19 西安交通大学口腔医院 一种牙刷刷毛及其制备方法、一种牙刷

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KR20090036935A (ko) * 2007-10-10 2009-04-15 이유경 치약 성분의 칫솔모
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KR101164978B1 (ko) * 2009-11-26 2012-07-12 김주형 칫솔모에 치약 성분을 코팅시키는 방법
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Publication number Priority date Publication date Assignee Title
KR20190088805A (ko) * 2018-01-19 2019-07-29 김한수 발포 정제형 치약 조성물 및 그 제조방법
KR102055301B1 (ko) 2018-01-19 2019-12-12 김한수 발포 정제형 치약 조성물 및 그 제조방법
KR20200099801A (ko) * 2019-02-15 2020-08-25 주식회사 메디덴코 항균 성능이 개선된 치약 조성물 및 이를 포함하는 치약
KR102196459B1 (ko) 2019-02-15 2020-12-30 주식회사 메디덴코 항균 성능이 개선된 치약 조성물 및 이를 포함하는 치약

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