WO2017175981A1 - 주름 은폐용 화장료 조성물 - Google Patents
주름 은폐용 화장료 조성물 Download PDFInfo
- Publication number
- WO2017175981A1 WO2017175981A1 PCT/KR2017/002743 KR2017002743W WO2017175981A1 WO 2017175981 A1 WO2017175981 A1 WO 2017175981A1 KR 2017002743 W KR2017002743 W KR 2017002743W WO 2017175981 A1 WO2017175981 A1 WO 2017175981A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- wax
- cosmetic composition
- dimethicone
- oil
- crosspolymer
- Prior art date
Links
- 230000037303 wrinkles Effects 0.000 title claims abstract description 99
- 239000002537 cosmetic Substances 0.000 title claims abstract description 68
- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 239000001993 wax Substances 0.000 claims description 106
- 239000003921 oil Substances 0.000 claims description 78
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 65
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 64
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 64
- 229940008099 dimethicone Drugs 0.000 claims description 54
- 229920002545 silicone oil Polymers 0.000 claims description 31
- -1 polyphenylmethylsiloxane Polymers 0.000 claims description 30
- 229920006037 cross link polymer Polymers 0.000 claims description 26
- 239000000843 powder Substances 0.000 claims description 21
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000012185 ceresin wax Substances 0.000 claims description 11
- 239000000839 emulsion Substances 0.000 claims description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 8
- 229920002379 silicone rubber Polymers 0.000 claims description 8
- 239000003974 emollient agent Substances 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 235000019271 petrolatum Nutrition 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 150000003626 triacylglycerols Chemical class 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- DDJSWKLBKSLAAZ-UHFFFAOYSA-N cyclotetrasiloxane Chemical compound O1[SiH2]O[SiH2]O[SiH2]O[SiH2]1 DDJSWKLBKSLAAZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000010696 ester oil Substances 0.000 claims description 4
- 239000004200 microcrystalline wax Substances 0.000 claims description 4
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- SCRSFLUHMDMRFP-UHFFFAOYSA-N trimethyl-(methyl-octyl-trimethylsilyloxysilyl)oxysilane Chemical compound CCCCCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C SCRSFLUHMDMRFP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052582 BN Inorganic materials 0.000 claims description 3
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 239000004264 Petrolatum Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- 150000002430 hydrocarbons Chemical class 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 229940066842 petrolatum Drugs 0.000 claims description 3
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 claims description 2
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 claims description 2
- 241001553290 Euphorbia antisyphilitica Species 0.000 claims description 2
- 239000004166 Lanolin Substances 0.000 claims description 2
- RGMZNZABJYWAEC-UHFFFAOYSA-N Methyltris(trimethylsiloxy)silane Chemical compound C[Si](C)(C)O[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C RGMZNZABJYWAEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 240000000111 Saccharum officinarum Species 0.000 claims description 2
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 2
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 2
- 239000012164 animal wax Substances 0.000 claims description 2
- 235000013871 bee wax Nutrition 0.000 claims description 2
- 239000012166 beeswax Substances 0.000 claims description 2
- 239000004203 carnauba wax Substances 0.000 claims description 2
- 235000013869 carnauba wax Nutrition 0.000 claims description 2
- 229940085262 cetyl dimethicone Drugs 0.000 claims description 2
- 229940110456 cocoa butter Drugs 0.000 claims description 2
- 235000019868 cocoa butter Nutrition 0.000 claims description 2
- 239000007799 cork Substances 0.000 claims description 2
- 229940086555 cyclomethicone Drugs 0.000 claims description 2
- JJRDHFIVAPVZJN-UHFFFAOYSA-N cyclotrisiloxane Chemical compound O1[SiH2]O[SiH2]O[SiH2]1 JJRDHFIVAPVZJN-UHFFFAOYSA-N 0.000 claims description 2
- 229940090934 diphenylsiloxy phenyl trimethicone Drugs 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- ANXXYABAFAQBOT-UHFFFAOYSA-N dodecyl-methyl-bis(trimethylsilyloxy)silane Chemical compound CCCCCCCCCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C ANXXYABAFAQBOT-UHFFFAOYSA-N 0.000 claims description 2
- 150000002194 fatty esters Chemical class 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- PNJMJEXVQAFSBS-UHFFFAOYSA-N hexyl-methyl-bis(trimethylsilyloxy)silane Chemical compound CCCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C PNJMJEXVQAFSBS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012182 japan wax Substances 0.000 claims description 2
- 235000019388 lanolin Nutrition 0.000 claims description 2
- 229940039717 lanolin Drugs 0.000 claims description 2
- 229940073663 methyl trimethicone Drugs 0.000 claims description 2
- 239000012170 montan wax Substances 0.000 claims description 2
- 235000019809 paraffin wax Nutrition 0.000 claims description 2
- 239000012169 petroleum derived wax Substances 0.000 claims description 2
- 235000019381 petroleum wax Nutrition 0.000 claims description 2
- 229940057874 phenyl trimethicone Drugs 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229940099549 polyglycerin-3 Drugs 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 claims description 2
- 239000012178 vegetable wax Substances 0.000 claims description 2
- 239000008307 w/o/w-emulsion Substances 0.000 claims description 2
- 241001071864 Lethrinus laticaudis Species 0.000 claims 1
- 229940074167 capryl methicone Drugs 0.000 claims 1
- GSANOGQCVHBHIF-UHFFFAOYSA-N tetradecamethylcycloheptasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 GSANOGQCVHBHIF-UHFFFAOYSA-N 0.000 claims 1
- CIAZJIQGPOGZDS-UHFFFAOYSA-N trimethyl-(methyl-tetradecyl-trimethylsilyloxysilyl)oxysilane Chemical compound CCCCCCCCCCCCCC[Si](C)(O[Si](C)(C)C)O[Si](C)(C)C CIAZJIQGPOGZDS-UHFFFAOYSA-N 0.000 claims 1
- 239000011236 particulate material Substances 0.000 abstract 2
- 235000019198 oils Nutrition 0.000 description 68
- 239000000499 gel Substances 0.000 description 53
- 230000000694 effects Effects 0.000 description 29
- 230000000052 comparative effect Effects 0.000 description 23
- 239000011734 sodium Substances 0.000 description 12
- 229910052708 sodium Inorganic materials 0.000 description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- 239000004721 Polyphenylene oxide Substances 0.000 description 8
- 229920000570 polyether Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000012071 phase Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- 229960003237 betaine Drugs 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- 239000004909 Moisturizer Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000004122 cyclic group Chemical group 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 230000001333 moisturizer Effects 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000001153 anti-wrinkle effect Effects 0.000 description 2
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229940043264 dodecyl sulfate Drugs 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 229940075529 glyceryl stearate Drugs 0.000 description 2
- 238000010191 image analysis Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 210000002374 sebum Anatomy 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- MQILKRLZMJKIJE-UHFFFAOYSA-N (1-decanoyloxy-3-octanoyloxypropan-2-yl) dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC(COC(=O)CCCCCCC)COC(=O)CCCCCCCCC MQILKRLZMJKIJE-UHFFFAOYSA-N 0.000 description 1
- ZYJZBFYRVKLOAA-KRWDZBQOSA-N (2s)-2-(hexadecanoylamino)butanedioic acid Chemical compound CCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CC(O)=O ZYJZBFYRVKLOAA-KRWDZBQOSA-N 0.000 description 1
- BJDAUCLANVMIOB-UHFFFAOYSA-N (3-decanoyloxy-2,2-dimethylpropyl) decanoate Chemical compound CCCCCCCCCC(=O)OCC(C)(C)COC(=O)CCCCCCCCC BJDAUCLANVMIOB-UHFFFAOYSA-N 0.000 description 1
- PAFJZWHXMSQJKV-UQZRNVAESA-N (3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol;octadecanoic acid Chemical compound OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.OC[C@@H](O)C1OC[C@H](O)[C@H]1O.CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O PAFJZWHXMSQJKV-UQZRNVAESA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- UNTXZFOXVBGXGZ-UHFFFAOYSA-N 1,3,5,7,9,11,13-heptaoxa-2$l^{2},4$l^{2},6$l^{2},8$l^{2},10$l^{2},12$l^{2},14$l^{2}-heptasilacyclotetradecane Chemical compound O1[Si]O[Si]O[Si]O[Si]O[Si]O[Si]O[Si]1 UNTXZFOXVBGXGZ-UHFFFAOYSA-N 0.000 description 1
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- LDMOEFOXLIZJOW-UHFFFAOYSA-N 1-dodecanesulfonic acid Chemical compound CCCCCCCCCCCCS(O)(=O)=O LDMOEFOXLIZJOW-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- PHTZMGCAFZLFOL-UHFFFAOYSA-N 14-methylpentadecyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCCCCCCCCCCCCCC(C)C PHTZMGCAFZLFOL-UHFFFAOYSA-N 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- ABEXEQSGABRUHS-UHFFFAOYSA-N 16-methylheptadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C ABEXEQSGABRUHS-UHFFFAOYSA-N 0.000 description 1
- ONJJOWWTHJFYOO-UHFFFAOYSA-N 16-methylheptadecyl 3,5,5-trimethylhexanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CC(C)CC(C)(C)C ONJJOWWTHJFYOO-UHFFFAOYSA-N 0.000 description 1
- DGSZGZSCHSQXFV-UHFFFAOYSA-N 2,3-bis(2-ethylhexanoyloxy)propyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(OC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DGSZGZSCHSQXFV-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- PDHFSBXFZGYBIP-UHFFFAOYSA-N 2-[2-(2-hydroxyethylsulfanyl)ethylsulfanyl]ethanol Chemical compound OCCSCCSCCO PDHFSBXFZGYBIP-UHFFFAOYSA-N 0.000 description 1
- ZCOLQXXFCPFSNU-UHFFFAOYSA-N 2-[methyl(tetradecanoyl)amino]ethanesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCC(=O)N(C)CCS(O)(=O)=O ZCOLQXXFCPFSNU-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- QSNJNCHUFWULBZ-UHFFFAOYSA-N 2-ethylhexyl 16-methylheptadecanoate Chemical compound CCCCC(CC)COC(=O)CCCCCCCCCCCCCCC(C)C QSNJNCHUFWULBZ-UHFFFAOYSA-N 0.000 description 1
- LCVHZNSIAYNAGX-UHFFFAOYSA-N 2-ethylhexyl 3,5,5-trimethylhexanoate Chemical compound CCCCC(CC)COC(=O)CC(C)CC(C)(C)C LCVHZNSIAYNAGX-UHFFFAOYSA-N 0.000 description 1
- LWLRMRFJCCMNML-UHFFFAOYSA-N 2-ethylhexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(CC)CCCC LWLRMRFJCCMNML-UHFFFAOYSA-N 0.000 description 1
- VDHIEQOYPSVNIM-UHFFFAOYSA-N 2-hexyldecyl 2-ethylhexanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)C(CC)CCCC VDHIEQOYPSVNIM-UHFFFAOYSA-N 0.000 description 1
- OVFAVSHTEIQRPQ-UHFFFAOYSA-N 2-hydroxybutyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(O)CC OVFAVSHTEIQRPQ-UHFFFAOYSA-N 0.000 description 1
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 description 1
- QNJOVLAFLJQFBF-UHFFFAOYSA-N 2-octyldodecyl 16-methylheptadecanoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C QNJOVLAFLJQFBF-UHFFFAOYSA-N 0.000 description 1
- MPJSWQKTHQXGQA-UHFFFAOYSA-M 3,3-dimethyl-3-azoniabicyclo[3.1.1]heptane;chloride Chemical compound [Cl-].C1[N+](C)(C)CC2CC1C2 MPJSWQKTHQXGQA-UHFFFAOYSA-M 0.000 description 1
- PBFGMXZRJIUGKU-UHFFFAOYSA-N 3-decanoyloxybutyl decanoate Chemical compound CCCCCCCCCC(=O)OCCC(C)OC(=O)CCCCCCCCC PBFGMXZRJIUGKU-UHFFFAOYSA-N 0.000 description 1
- LFESLSYSZQYEIZ-UHFFFAOYSA-N 3-octanoyloxybutyl octanoate Chemical compound CCCCCCCC(=O)OCCC(C)OC(=O)CCCCCCC LFESLSYSZQYEIZ-UHFFFAOYSA-N 0.000 description 1
- AUKODEQPZHYYRB-UHFFFAOYSA-N 4-(7-methyloctanoyloxy)butyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OCCCCOC(=O)CCCCCC(C)C AUKODEQPZHYYRB-UHFFFAOYSA-N 0.000 description 1
- IKDHIMYPOLRLJB-UHFFFAOYSA-N 4-hydroxybutyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCO IKDHIMYPOLRLJB-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
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- NEOZOXKVMDBOSG-UHFFFAOYSA-N propan-2-yl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC(C)C NEOZOXKVMDBOSG-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229940080237 sodium caseinate Drugs 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 description 1
- CAVXVRQDZKMZDB-UHFFFAOYSA-M sodium;2-[dodecanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O CAVXVRQDZKMZDB-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- ZNYIJXQYUNSKDX-NTISSMGPSA-M sodium;hydron;(2s)-2-(tetradecanoylamino)pentanedioate Chemical compound [Na+].CCCCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O ZNYIJXQYUNSKDX-NTISSMGPSA-M 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229940104261 taurate Drugs 0.000 description 1
- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
Definitions
- the present invention relates to a cosmetic composition for hiding wrinkles.
- Cosmetics to improve wrinkles can be divided into functional cosmetics and functional cosmetics that remove wrinkles by acting on the factors that cause wrinkles, and the cosmetics that have the effect of concealing wrinkles temporarily by filling the wrinkles and reflecting light at the wrinkles. .
- Cosmetics that temporarily hide wrinkles by causing diffuse reflection at the wrinkles area have an excessive amount of powder added to have a heavy and stiff feeling and cause cloudiness when applied to the skin.
- due to the moisture absorption and oil absorption properties of the powder has a problem that it is difficult to show a continuous effect due to the phenomenon that the skin is dry and sticking to the skin due to the dryness and sticking phenomenon occurs on the skin.
- the principle of diffuse reflection of light is as follows.
- light is irradiated on a material, some of the light is reflected off the surface and some is transmitted, depending on the refractive index of the material.
- some of the light is reflected from particles on the surface, while others are refracted and transmitted at a certain angle.
- the transmitted light is the same on the surface of the second particle inside, depending on the refractive index of the material and the internal particle structure, the light reflected from the surface of the second particle is reflected at a different angle than the light reflected from the first particle. . This phenomenon occurs continuously between particles located inside, and the reflected light is reflected at different angles and finally diffusely reflects the light.
- the present inventors have discovered problems of the composition containing the powder, and as a result of earnest research efforts to develop a cosmetic composition having excellent anti-wrinkle property and usability while exhibiting a wrinkle concealing effect, it may include an oil wax gel including silicone oil and wax.
- an oil wax gel including silicone oil and wax.
- An object of the present invention is to provide a cosmetic composition capable of concealing wrinkles by causing diffuse reflection of light at a wrinkled portion without using powder, a cosmetic comprising the same, and a method for hiding wrinkles comprising applying the composition to the skin.
- the cosmetic composition for hiding wrinkles causes light diffuse reflection in the wrinkles without using powder and effectively fills the wrinkles of the skin to temporarily conceal wrinkles, and also does not use powder to provide a feeling of use when applying the skin. It is excellent and has no turbidity and the adhesion to the skin can be maintained for a long time.
- FIG. 1 is a view showing a change in wrinkle depth (wrinkle concealment effect result) according to the application of an oil wax gel according to an embodiment.
- FIG. 2 is a view showing a change in the number of wrinkles (wrinkle concealment effect results) according to the application of the oil wax gel according to an embodiment.
- FIG 3 is a view showing a change in wrinkle length (wrinkle concealment effect result) according to the application of the oil wax gel according to an embodiment.
- FIG. 4 is a view showing a change in roughness (wrinkle concealment effect result) according to the application of the oil wax gel according to an embodiment.
- Figure 5 is a comparison photo of the skin wrinkle concealment effect before and after the treatment of the oil wax gel according to one embodiment.
- the present invention provides a cosmetic composition for hiding wrinkles comprising an oil wax gel comprising a silicone oil and a wax.
- Diffuse reflection is a form of light reflection whereby light is reflected at different angles to give a visual concealment effect.
- the specular reflection of light is a reflection of light that is antiparallel to the visual concealment effect due to the parallel progression of light. Form.
- it is essential to design a composition and a three-dimensional structure that can effectively induce diffuse reflection of light.
- the use of powder induced such diffuse reflection of light.
- the use of powder may cause a drop in feeling when the skin is applied, clouding occurs, and the adhesion to the skin may be reduced when used for a long time.
- Oil wax gels refer to oily solids consisting of fluid oils and crystalline solid oils (I. Takeo, N. Koichi, and S. Masashi, Colloids and Surfaces A, 194, 233, 2001). More specifically, the oil wax gel is a gel formed by surrounding oil in a three-dimensional structure formed by combining fine wax crystals. Such an oil wax gel may vary in hardness depending on the type of oil and the shape of the three-dimensional structure formed by the wax, as well as optical properties such as the reflection form of light. The three-dimensional structure formed by the wax may be influenced by the blending ratio of the oil and the wax and / or the kind of the wax.
- an oil wax gel containing a silicone oil and wax when using an oil wax gel containing a silicone oil and wax can be applied to the cosmetic composition for hiding wrinkles by forming an oil wax gel that can effectively induce diffused reflection of light without including the powder used in the past Found.
- the wax particles in the oil wax gel effectively diffuse diffused light to conceal wrinkles temporarily when applied to the wrinkles. It was found that the effect is excellent.
- hardness is a factor that may affect the feeling of use of the cosmetic composition as well as to fill the irregularities of the skin due to the wrinkles to achieve the wrinkle concealment effect.
- the hardness of the oil wax gel is 100 to 4000 dyn / cm 2 It was confirmed that the excellent coating feeling on the skin can effectively fill the wrinkles and also the wrinkle concealment effect.
- the present invention it is possible to cover the wrinkles temporarily by causing light reflection at the wrinkles without using powder and effectively covering up the wrinkles of the skin. It can provide a cosmetic composition that can be maintained for a long time without adhesion to the skin.
- the present invention can provide a cosmetic composition for covering up wrinkles comprising an oil wax gel including a silicone oil and a wax.
- the silicone oil and 1 to 50 parts by weight of the wax may be blended to form an oil wax gel that more effectively causes diffuse reflection of light. Outside the content ratio, the diffuse reflection of light may be reduced, so that the effect of concealing wrinkles may be insufficient or may not have a hardness suitable for skin application.
- the content of the silicone oil is 1 to 50 parts by weight of the wax is 5 to 95 parts by weight, specifically 10 to 80 parts by weight, more specifically 15 to 70 parts by weight, more specifically 20 to 55 parts by weight, even more specific And 30 to 50.5 parts by weight. If it exceeds 95 parts by weight, the oil wax gel may collapse completely and no wrinkle concealment effect may be exhibited, and the formulation stability is greatly reduced. In addition, when less than 5 parts by weight, the hardness may be too high to be applied to the skin.
- the wax content is 5 to 95 parts by weight of the silicone oil is 1 to 50 parts by weight, specifically 2.5 to 20 parts by weight, more specifically 5 to 18.5 parts by weight, more specifically 7.5 to 15 parts by weight, even more Specifically, it may be 7.5 to 12.5 parts by weight. If less than 1 part by weight, no wax oil gel is formed and the formulation stability is greatly reduced. In addition, when it exceeds 50 parts by weight, the hardness may be too high to be applied to the skin.
- the appropriate hardness range can directly affect the wrinkle concealment effect.
- the appropriate hardness range considering the wrinkle concealment effect and the applicability is 100 to 4000 dyn / cm 2 , preferably 500 to 2500 dyn / cm 2 , more preferably 700 to 2000 dyn / cm 2, as described above. , Even more preferably 900 to 1200 dyn / cm 2 , most preferably 1000 dyn / cm 2 .
- the hardness is out of the hardness, specifically, the hardness is 4000 dyn / cm 2 If it exceeds, there is a problem that can not be applied to the skin becomes heavy and stiff.
- the hardness is less than 100 dyn / cm 2 shows the separation of properties and deterioration of feeling.
- silicone oil means a liquid polymerized siloxane compound having an organic side chain.
- Various silicone oils exist depending on the type of the organic side chain.
- the silicone oil may be included in an amount of 5 to 95 wt% based on the weight of the total oil wax gel. When the content of the above range may be excellent wrinkle hiding effect and hardness is appropriate.
- the silicone oil may be a cyclic silicone oil, a linear silicone oil, or a silicone oil substituted with one or more functional groups.
- the silicone oil is cyclopentasiloxane, cyclomethicone, cyclotetrasiloxane, cyclohexasiloxane, cycloheptasiloxane, decamethylcyclopentasiloxane, cyclotetrasiloxane, cyclotrisiloxane, dimethicone, capryldimethicone, capryldimethicone Prillylmethicone, caprylylmethicone, cetearylmethicone, hexadecylmethicone, hexylmethicone, laurylmethicone, myrimethylmethicone, phenylmethicone, stearylmethicone, stearyldimethicone, tri Fluoropropyl
- the silicone oil may be a combination of cyclic silicone oil and linear silicone oil.
- This combination of cyclic silicone oil and linear silicone oil may be advantageous for the formation of a three-dimensional structure suitable for causing diffuse reflection of light and / or for proper hardness control of the oil wax gel.
- the silicone oil may be a combination of cyclopentasiloxane and silicone oils excluding cyclopentasiloxane.
- silicone oils other than cyclopentasiloxane and cyclopentasiloxane may be advantageous for the formation of a three-dimensional structure suitable for causing diffuse reflection of light and / or for appropriate hardness control of the oil wax gel.
- cyclopentasiloxane is a kind of silicone oil and the IUPAC name is decamethylcyclo pentasiloxane.
- the cyclopentasiloxane may be included in an amount of 30 to 50% by weight, preferably 35 to 45% by weight based on the weight of the total oil wax gel.
- Silicone oils other than the cyclopentasiloxane may be included in an amount of 1 to 40% by weight, preferably 5 to 35% by weight, more preferably 10 to 30% by weight, based on the weight of the total oil wax gel.
- wax refers to alcoholic components that are solid at room temperature, such as alcohol fatty acid esters that are insoluble in water.
- the wax may be included in an amount of 1 to 50% by weight based on the weight of the total oil wax gel. If the wax is less than 1% by weight, no oil wax gel is formed. If the wax is more than 50% by weight, an oil wax gel having too high hardness may be formed and may not be applicable to the skin.
- the wax is a mineral wax selected from the group consisting of ceresin wax, paraffin wax, petrolatum wax, petroleum wax, ozokerite, montan wax and microcrystalline wax; Animal waxes selected from the group consisting of beeswax and lanolin; Vegetable waxes selected from the group consisting of candelilla, ouricurry, carnauba wax, Japan wax, cocoa butter, cork fiber and sugar cane wax; Hydrogenated oils that are solid at 25 ° C .; Fatty esters and glycerides; Synthetic waxes selected from the group consisting of polyethylene waxes and waxes obtained by Fischer-Tropsch synthesis; And silicone wax may be one or more selected from the group consisting of, but is not limited thereto. That is, in the present invention, the wax may be used alone or in combination of two or more kinds.
- the wax may be ceresin wax.
- the wax may be a combination of ceresin wax and other waxes other than the aforementioned ceresin wax.
- ceresin wax is a white or yellowish wax material obtained by refining wax, which is mainly used as a binder or thickener in cosmetics.
- the ceresin wax may be included in an amount of 1 to 50% by weight, preferably 5 to 20% by weight based on the total weight of the oil wax gel.
- Waxes other than the ceresin wax may be included in an amount of 1 to 20% by weight, preferably 2.5 to 15% by weight, more preferably 5 to 10% by weight, based on the total weight of the oil wax gel.
- the cosmetic composition may be one containing no powder. Since the cosmetic composition of the present invention does not use powder, it has an excellent feeling when applying the skin, there is no clouding phenomenon, and adhesion to the skin can be maintained for a long time.
- the powder is silica (Silica), polymethyl methacrylate (PMMA), alumina (Alumina), talc (Talk), mica (Mica), barium sulfate (BaSO sulfate), titanium dioxide (Titanium dioxide) , TiO 2), zinc oxide (ZnO), or boron nitride may be any one or more selected from the group consisting of, but is not limited thereto.
- the oil wax gel may further include an emollient.
- the emollient can be used to control the feel of the oil wax gel.
- the emollient may be included in an amount of 1 to 30% by weight, preferably 2.5 to 25% by weight, more preferably 5 to 20% by weight, based on the total weight of the oil wax gel.
- the emollient may be one or more selected from the group consisting of natural or synthetic triglycerides, ester oils and hydrocarbon oils.
- the natural or synthetic triglycerides include C8-12 acid triglyceride, C12-18 acid triglyceride, caprylic / capric / triglyceride, caprylic / capric / laurictriglyceride, C10-40 isoalkyl acid Triglycerides and C 10-18 triglycerides and the like can be exemplified, but is not limited thereto.
- ester oil As the ester oil, ascorbyl palmitate, ascorbyl linoleate, ascorbyl stearate, distearyl maleate, benzyl benzoate, benzyllaurate, butylene glycol dicaprylate / dicaprate, butylene glycol diisononanoate , Butylene glycol laurate, butylene glycol stearate, butyl isostearate, cetearyl isonanoate, cetearyl nonanoate, cetyl caprylate, cetylethylhexanoate, cetyl isononanoate, Ethylhexyl caprylate / caprate, ethylhexyl isononanoate, ethylhexyl isostearate, ethyl hexyl laurate, hexyl laurate, octyldodecyl isostearate, isopropyl is
- the hydrocarbon oil may be liquid paraffin (liquid paraffin, mineral oil), paraffin, petrolatum, microcrystalline wax, squalane, and the like, but are not limited thereto.
- the oil wax gel may further comprise a silicone elastomer.
- the silicone elastomer can be used to control the feel of the oil wax gel.
- the silicone elastomer may be included in an amount of 1 to 30% by weight, preferably 2.5 to 25% by weight, more preferably 5 to 20% by weight based on the total weight of the oil wax gel.
- the silicone elastomer is dimethicone crosspolymer, cetearyl dimethicone crosspolymer, cetearyl dimethicone / vinyl dimethicone crosspolymer, dimethicone / vinyl dimethicone crosspolymer, dimethicone / pig-10 Crosspolymer, Dimethicone / Pig-15 Crosspolymer, Dimethicone / Polyglyceryl-3 Crosspolymer, Dimethicone / Sylsesquioxane Copolymer, Dimethicone / Phenylvinylmethicone Crosspolymer, Vinyl Dimethicone / Lauryl Dimethicone Crosspolymer, Dimethicone / bis-isobutyl Fiji-20 Crosspolymer, Fiji-12 Dimethicone / Fiji-20 Crosspolymer, Lauryl Dimethicone Fiji-15 Crosspolymer and Lauryl Dimethicone / Polyester It may be
- the present invention comprises the cosmetic composition, wherein the composition is formulated as a solid, O / W emulsion, W / O emulsion, W / O / W emulsion, O / W / O emulsion or aqueous dispersion.
- the composition is formulated as a solid, O / W emulsion, W / O emulsion, W / O / W emulsion, O / W / O emulsion or aqueous dispersion.
- the cosmetic composition may be one containing an oil wax gel, and a wax.
- the oil phase forming the O / W emulsion may be used in an amount of 0.1% to 70% by weight based on the total weight of the composition, and may form a stable emulsion in the above range.
- the oily phase may comprise an oil wax gel of the present invention.
- the cosmetic composition for anti-wrinkle according to the present invention for formulation into the emulsion may further comprise a surfactant.
- the surfactant may be included in the oil phase.
- the surfactant may affect the size of the emulsified particles, the stability of the emulsion and the feeling of use depending on the type and content thereof.
- the said surfactant can be used individually or in mixture of 2 or more types of synthetic surfactant or natural surfactant.
- the surfactant may be an anionic surfactant, cationic surfactant, amphoteric surfactant or nonionic surfactant.
- the nonionic surfactants include sorbitan monostearate, cetheares-20, sorbitan sesquistearate, sorbitas sequilate, lipophilic glyceryl stearate, octyldodeces-16, polysorbate 20, polysorbate 40, polysorbate 60, polysorbate 65, polysorbate 80, polysorbate 85, polyoxyethylene-cured castor oil, sebum, sebum polymer, and the like, but is not limited thereto.
- the nonionic surfactants also include dimethicone copolyols as organically modified organopolysiloxanes.
- the organopolysiloxane may be a polydimethyl siloxane modified to include a polyether chain including a polyethylene oxide chain, a polypropylene oxide chain, a mixture of such chains or a moiety derived from both ethylene oxide and propylene oxide; Or an alkyl-modified dimethicone copolyol including a C2-C30 pendant side chain may be used, but is not limited thereto.
- the dimethicone copolyols and other silicone-based surfactants may be prepared from polydimethylsiloxane polyether copolymers having pendant polyethylene oxide side chains, polydimethylsiloxane polyether copolymers having pendant polypropylene oxide side chains, pendant mixed polyethylene oxide and polypropylene oxide side chains.
- dimethicone copolyols are lauryl dimethicone copolyol, lauryl polydimethylsiloxyethyl dimethicone copolyol, dimethicone copolyol acetate, dimethicone copolyol adipate, dimethicone copolyolamine, dimethicone copolyol Behenate, dimethicone copolyol butylether, dimethicone copolyol hydroxy stearate, dimethicone copolyol isostearate, dimethicone copolyol laurate, dimethicone copolyol methyl ether, dimethicone copolyol phosphate or dimethicone co Polyol stearate or the like may be used, but is not limited thereto.
- the anionic surfactants are sodium laurate, sodium palmitate, sodium lauryl sulfate, potassium lauryl sulfate, triethanolamine salt of POE-lauryl sulfate, sodium POE-lauryl sulfate, sodium lauroyl sarco Sin, sodium N-myristoyl-N-methyl-taurine, sodium N-cocoyl-N-methyl taurate, sodium lauroylmethyl taurate, sodium POE-oleyl ether phosphate, sodium POE-stearyl ether phosphate , Sodium di-2-ethylhexyl sulfosuccinate, sodium monolauroyl monoethanol amido polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, sodium linear dodecyl sulfonate, sodium linear Dodecylzensulfonate, monosodium N-lauroylglutamate, disodium N-ste
- the cationic surfactants include stearyltrimethylammonium chloride, lauryltrimethyl ammonium chloride, distearyldimethyl-ammonium chloride, poly (N, N'-dimethyl-3,5-methylenepiperidinium) chloride, cetylpyridinium chloride , Alkyltetraammonium salt, alkyldimethylbenzylammonium salt, alkylisoquinolinium salt, dialkyl-morpholinium salt, POE-alkylamine, alkylamine salt, polyamine fatty acid derivative, amyl alcohol fatty acid derivative, benzalkonium chloride or benzethonium chloride Etc. may be used, but is not limited thereto.
- amphoteric surfactants are sodium 2-undecyl-N, N, N '-(hydroxyethylcarboxymethyl) -2-imidazoline, disodium 2-cocoyl-2-imidazolinium hydroxide- 1-carboxyethyloxy, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkyl betaine, amide betaine or sulfobetaine and the like can be used. It may be, but is not limited thereto.
- the water phase forming the W / O emulsion may be used in an amount of 0.1% to 70% by weight based on the total weight of the composition for improving the freshness and moisture of the cosmetic.
- the aqueous phase may include a water-soluble raw material that can exhibit skin moisturizing or nutrition, usability, low temperature stability or efficacy, water, polyol, polymer compound, urea, moisturizer or carbomer may be used, but It is not limited.
- the polyol may be used as a moisturizer, and glycerin, dipropylene glycol, butylene glycol, pentylene glycol, methylpropanediol, sorbitol, diglycerin, erythritol, pentaerythritol, polybutylene glycol-10, poly Glycerin-3, Polyglycerin-4, Polyglycerin-6, Polyglycerin-10, Polyglycerin-20, Polyglycerin-40, Sorves-5, Sorves-6, Sorves-20, Sorves-30, Sorbet S-40, inositol, maltitol, maltose, met, mannitol, mannose, lactitol, lactose, dihydroxypropyl PG-glucoside, dithiaoctanediol, fructose, glucamine, methylglucamine, glucose, 1, 2,6-hexanechiol
- Cosmetic compositions according to the invention can be prepared by conventional methods used in the art.
- the cosmetic composition for hiding wrinkles may further contain a fragrance.
- the fragrance may be contained in an amount of 0.01 to 1.00% by weight based on the total weight of the cosmetic.
- the cosmetics may further include one or more cosmetically acceptable carriers formulated in general skin cosmetics, and may include, for example, oils, water, surfactants, moisturizers, lower alcohols, thickeners, chelating agents, A pigment, a preservative, a fragrance, etc. can be mix
- the present invention provides a method for concealing wrinkles, comprising applying the cosmetic composition to the skin.
- the cosmetic composition and the wrinkle concealment are as described above.
- the cosmetic composition of the present invention was applied to the eyes of adult men and women confirmed the excellent wrinkle concealment effect (Table 3), by applying the composition to the back of the hand to the skin wrinkle concealment before and after application As a result, it was confirmed that the wrinkles are effectively concealed (FIG. 5). Therefore, it was confirmed that the present invention can provide a method for concealing wrinkles comprising applying the cosmetic composition to the skin.
- Example 1 and 2 and Comparative example 1 to 3 oil wax gel and oil Powder Cosmetics Produce
- the hardness of the oil wax gels of Examples 1 to 2 and Comparative Examples 1 to 3 prepared above are shown in Table 2 below. Hardness was measured by using adapter # 3 with Fudoh Rheometer RT-3005D from Rheotec Co. The hardness was measured to a depth of 2 mm at 2 cm / min. The average value was derived after five measurements.
- Example 1 Example 2 Comparative Example 1 Comparative Example 2 Comparative Example 3 Hardness (dyn / cm 2 ) 2490 3120 60 5000 Not measurable
- Example 1 and Example 2 when the oil wax gel is applied to the skin, it effectively covers the wrinkles due to the wrinkles and shows the wrinkle hiding effect.
- the oil wax gel of Comparative Example 1 when the oil wax gel of Comparative Example 1 was applied to the skin, the oil wax gel completely collapsed in the skin, and thus the wrinkle concealing effect could not be felt.
- the hardness was too high to apply to the skin.
- the oil powder cosmetics obtained from the composition ratio of Comparative Example 3 it was possible to apply to the skin, but the feeling was not good.
- the oil wax gel of Example 1 was applied to the eyes of seven adult men and women, and the wrinkle concealment effect was measured through image analysis with PRIMOS lite (GFM). Specifically, it evaluated by the wrinkle depth, wrinkle length, the number of wrinkles, and roughness items.
- GFM PRIMOS lite
- the oil wax gel of Example 1 has an excellent wrinkle concealment effect in all of the wrinkle depth, wrinkle length, number of wrinkles, and roughness.
- Example 16 monitor agents with wrinkles in their 30s and 50s were tested for usability of the cosmetic compositions of Example 1 and Comparative Example 3.
- the test items were wrinkle concealment, cloudiness, jungle, agglomeration, dryness, and satisfaction, and the average score results of giving 0 to 5 points to each item are shown in Table 4 below.
- Example 1 While the wrinkle hiding power is superior to Comparative Example 3 containing a lot of powder, high scores were obtained in all items such as cloudiness, dryness, jungle, and agglomeration.
- a cosmetic composition for hiding wrinkles of Comparative Example 4 was prepared in an amount ratio shown in Table 5 below.
- the oily parts of paragraphs 1 to 7 were dissolved by heating to 70 ° C. in a separate vessel. 11 and 12 were added to the water phase parts of 8 to 10, and dispersed sufficiently at room temperature, heated to 70 ° C., the oil phase parts were mixed, and first emulsified at 70 ° C. through a homogenizer. In this case, 15 terms dissolved in a small amount of purified water were added thereto, followed by secondary emulsification and cooling to 50 ° C., and 14 terms well dispersed in 13 terms were added thereto, followed by tertiary emulsification and cooling to room temperature.
- Example 1 Sixteen monitors with wrinkles in their 30s and 50s were tested for usability of the cosmetic compositions of Example 1 and Comparative Example 4.
- the test items were wrinkle concealment, cloudiness, jungle, agglomeration, dryness, and satisfaction. Each item was given 0 to 5 points, and the average score results are shown in Table 6 below.
- Example 1 While the wrinkle hiding power is superior to Comparative Example 4 containing a lot of powder, high scores were obtained in all the items such as whitening, jungle, agglomeration and dryness.
- Example 1 The cosmetic composition for wrinkle hiding of Example 1 was apply
Abstract
Description
성분 | 실시예 1 | 실시예 2 | 비교예 1 | 비교예 2 | 비교예 3 |
1. 사이클로펜타실록산 | To 100 | To 100 | To 100 | To 100 | To 100 |
2. 디메치콘 | 10 | 10 | 10 | 10 | 10 |
3. 헥실데실에칠헥사노에이트(에스터오일) | 10 | 10 | 10 | 10 | 10 |
4. 디메치콘/비닐디메치콘클스폴리머(실리콘 엘라스터머) | 10 | 10 | 10 | 10 | 10 |
5. 세레신 왁스 | 20 | 20 | 0.5 | 55 | |
6. 마이크로크리스탈린왁스 | 20 | ||||
7. 실리카 | 20 |
실시예1 | 실시예2 | 비교예 1 | 비교예 2 | 비교예 3 | |
경도(dyn/cm2) | 2490 | 3120 | 60 | 5000 | 측정불가 |
주름 깊이 (㎛) | 주름 길이 (㎛) | 주름 개수 | 거칠기 (㎛) | |
사용전 | 60.00 | 203.00 | 341.67 | 33.10 |
사용후 | 55.33 | 185.67 | 279.00 | 31.90 |
감소율(%) | 7.78 | 8.54 | 18.34 | 3.63 |
항목 | 실시예 1 | 비교예 3 |
주름은폐 | 4.6 | 4.4 |
백탁 | 4.7 | 3.8 |
건조함 | 4.2 | 3.5 |
밀림 | 3.9 | 3.6 |
뭉침 | 4.3 | 4.1 |
만족도 | 4.5 | 3.9 |
성분 | 함량(중량%) |
1. 세테아릴알코올 | 1.00 |
2. 쉐어버터 | 8.00 |
3. 카프릴릭/카프릭트리글리세라이드 | 8.00 |
4. 글리세릴스테아레이트 | 1.00 |
5. 피이지-100스테아레이트 | 1.00 |
6. 폴리글리세릴-3메칠글루코오스디스테아레이트 | 2.00 |
7. 디메치콘 | 12.00 |
8. 정제수 | Up to 100 |
9. 글리세린 | 5.00 |
10. 트리소듐이디티에이 | 0.02 |
11. 잔탄검 | 0.10 |
12. 카보폴 | 0.30 |
13. 정제수 | 15.00 |
14. 실리카 | 15.00 |
15. 중화제 | 0.30 |
항목 | 실시예 1 | 비교예 4 |
주름은폐 | 4.6 | 4.4 |
백탁 | 4.7 | 3.8 |
밀림 | 3.9 | 3.6 |
뭉침 | 4.3 | 4.1 |
건조함 | 4.2 | 3.5 |
만족도 | 4.5 | 3.9 |
Claims (16)
- 오일 왁스 겔을 포함하는 주름 은폐용 화장료 조성물.
- 제1항에 있어서, 상기 오일 왁스 겔은 실리콘 오일 및 왁스를 포함하는 것인, 주름 은폐용 화장료 조성물.
- 제1항에 있어서, 상기 오일 왁스 겔은 실리콘 오일 5 내지 95 중량부 및 왁스 1 내지 50 중량부를 포함하는 것인, 주름 은폐용 화장료 조성물.
- 제1항에 있어서, 상기 오일 왁스 겔의 경도는 100 내지 4000 dyn/cm2인 것인, 주름 은폐용 화장료 조성물.
- 제2항에 있어서, 상기 실리콘 오일은 사이클로펜타실록산, 사이클로메치콘, 사이클로테트라실록산, 사이클로헥사실록산, 사이클로헵타실록산, 데카메틸사이클로펜타실록산, 사이클로테트라실록산, 사이클로트리실록산, 디메치콘, 카프릴디메치콘, 카프릴릴트리메치콘, 카프릴릴메치콘, 세테아릴메치콘, 헥사데실메치콘, 헥실메치콘, 라우릴메치콘, 미리스칠메치콘, 페닐메치콘, 스테아릴메치콘, 스테아릴디메치콘, 트리플루오로프로필메치콘, 세틸디메치콘, 폴리페닐메칠실록산, 디메틸폴리실록산, 메틸페닐폴리실록산, 메틸크트리메치콘, 디페닐실록시페닐트리메치콘, 카프릴릴메치콘 및 페닐트리메치콘으로 이루어진 군으로부터 선택된 어느 하나 이상인 것인, 주름 은폐용 화장료 조성물.
- 제2항에 있어서, 상기 왁스는 세레신 왁스, 파라핀 왁스, 바셀린 왁스, 석유 왁스, 오조케라이트(ozokerite), 몬탄 왁스 및 미세결정형왁스로 이루어진 군으로부터 선택되는 미네랄 왁스; 밀랍 및 라놀린으로 이루어진 군으로부터 선택되는 동물성 왁스; 칸델릴라, 오리큐리 (ouricurry), 카르나우바 왁스, 저팬 왁스, 코코아 버터, 코르크 섬유 및 사탕수수 왁스로 이루어진 군으로부터 선택되는 식물성 왁스; 25℃에서 고형인 수소화 오일; 지방에스테르 및 글리세리드; 폴리에틸렌 왁스 및 피셔-트롭시(Fischer-Tropsch) 합성으로 얻은 왁스로 이루어진 군으로부터 선택되는 합성 왁스; 및 실리콘 왁스로 이루어진 군으로부터 선택되는 1종 이상의 왁스인 것인, 주름 은폐용 화장료 조성물.
- 제1항에 있어서, 상기 화장료 조성물은 분체를 포함하지 않는 것인, 주름 은폐용 화장료 조성물.
- 제7항에 있어서, 상기 분체는 실리카(Silica), 폴리메틸메타크릴레이트(PMMA), 알루미나 (Alumina), 탤크 (Talk), 마이카(Mica), 황산바륨 (Barium sulfate, BaSO4), 이산화티탄(Titanium dioxide, TiO2), 산화아연(Zinc oxide, ZnO), 질화붕소 (Boron nitride)로 이루어진 군으로부터 선택된 어느 하나 이상인 것인, 주름 은폐용 화장료 조성물.
- 제1항에 있어서, 상기 오일 왁스 겔은 에몰리언트를 추가로 포함하는 것인, 주름 은폐용 화장료 조성물.
- 제9항에 있어서, 상기 에몰리언트는 전체 오일 왁스 겔의 중량 기준으로 1 내지 30 중량%의 함량으로 포함되는 것인, 주름 은폐용 화장료 조성물.
- 제9항에 있어서, 상기 에몰리언트는 천연 또는 합성 트리글리세라이드, 에스터오일 및 하이드로카본오일로 이루어진 군으로부터 선택되는 1종 이상인 것인, 주름 은폐용 화장료 조성물.
- 제1항에 있어서, 상기 오일 왁스 겔은 실리콘 엘라스터머를 추가로 포함하는 것인, 주름 은폐용 화장료 조성물.
- 제12항에 있어서, 상기 실리콘 엘라스터머는 전체 오일 왁스 겔의 중량 기준으로 1 내지 30 중량%의 함량으로 포함되는 것인, 주름 은폐용 화장료 조성물.
- 제12항에 있어서, 상기 실리콘 엘라스터머는 디메치콘크로스폴리머, 세테아릴디메치콘크로스폴리머, 세테아릴디메치콘/비닐디메치콘크로스폴리머, 디메치콘/비닐디메치콘크로스폴리머, 디메치콘/피이지-10크로스폴리머, 디메치콘/피이지-15크로스폴리머, 디메치콘/폴리글리세릴-3크로스폴리머, 디메치콘/실세스퀴옥산코폴리머, 디메치콘/페닐비닐디메치콘크로스폴리머, 비닐디메치콘/라우릴디메치콘크로스폴리머, 디메치콘/비스-이소부틸피피지-20크로스폴리머, 피이지-12디메치콘/피피지-20크로스폴리머, 라우릴디메치콘피이지-15크로스폴리머 및 라우릴디메치콘/폴리글리세린-3크로스폴리머, 폴리실리콘-11로 이루어진 군으로부터 선택된 1종 이상인 것인, 주름 은폐용 화장료 조성물.
- 제1항 내지 제14항 중 어느 한 항의 조성물을 포함하며, 상기 조성물이 고형, O/W 에멀젼, W/O 에멀젼, W/O/W 에멀젼, O/W/O 에멀젼 또는 수분산액으로 제형화된 것인, 주름 은폐용 화장품.
- 제1항 내지 제14항 중 어느 한 항의 화장료 조성물을 피부에 도포하는 단계를 포함하는, 주름 은폐 방법.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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EP17779281.9A EP3441061B1 (en) | 2016-04-04 | 2017-03-14 | Cosmetic composition for concealing wrinkles |
US16/089,780 US11058614B2 (en) | 2016-04-04 | 2017-03-14 | Cosmetics concealing wrinkles |
CN201780021684.5A CN108883053A (zh) | 2016-04-04 | 2017-03-14 | 隐藏皱纹的化妆组合物 |
JP2018552192A JP6812456B2 (ja) | 2016-04-04 | 2017-03-14 | シワ隠し用化粧料組成物 |
CN202310799032.1A CN116637046A (zh) | 2016-04-04 | 2017-03-14 | 油-蜡凝胶和用于隐藏皱纹的化妆组合物、化妆品和方法 |
US17/339,548 US11504308B2 (en) | 2016-04-04 | 2021-06-04 | Cosmetics concealing wrinkles |
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KR10-2016-0041203 | 2016-04-04 | ||
KR1020160041203A KR101812877B1 (ko) | 2016-04-04 | 2016-04-04 | 주름 은폐용 화장료 조성물 |
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US16/089,780 A-371-Of-International US11058614B2 (en) | 2016-04-04 | 2017-03-14 | Cosmetics concealing wrinkles |
US17/339,548 Continuation US11504308B2 (en) | 2016-04-04 | 2021-06-04 | Cosmetics concealing wrinkles |
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US (2) | US11058614B2 (ko) |
EP (1) | EP3441061B1 (ko) |
JP (1) | JP6812456B2 (ko) |
KR (1) | KR101812877B1 (ko) |
CN (2) | CN116637046A (ko) |
TW (1) | TWI735555B (ko) |
WO (1) | WO2017175981A1 (ko) |
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KR102320517B1 (ko) * | 2020-12-30 | 2021-11-03 | 한국콜마주식회사 | 오일 분산형 화장료 조성물 |
KR102318246B1 (ko) * | 2020-12-30 | 2021-10-28 | 한국콜마주식회사 | 실리콘 오일 조성물 및 이를 포함하는 화장료 조성물 |
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JP2019510783A (ja) | 2019-04-18 |
TW201735900A (zh) | 2017-10-16 |
US20210290498A1 (en) | 2021-09-23 |
KR20170115144A (ko) | 2017-10-17 |
EP3441061A4 (en) | 2019-09-18 |
US11058614B2 (en) | 2021-07-13 |
KR101812877B1 (ko) | 2017-12-28 |
US20190117526A1 (en) | 2019-04-25 |
JP6812456B2 (ja) | 2021-01-13 |
CN108883053A (zh) | 2018-11-23 |
TWI735555B (zh) | 2021-08-11 |
US11504308B2 (en) | 2022-11-22 |
EP3441061A1 (en) | 2019-02-13 |
CN116637046A (zh) | 2023-08-25 |
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