WO2017113945A1 - Gel composition, spray, and tape for attracting insects, and method of reducing insect pest damage - Google Patents

Gel composition, spray, and tape for attracting insects, and method of reducing insect pest damage Download PDF

Info

Publication number
WO2017113945A1
WO2017113945A1 PCT/CN2016/102789 CN2016102789W WO2017113945A1 WO 2017113945 A1 WO2017113945 A1 WO 2017113945A1 CN 2016102789 W CN2016102789 W CN 2016102789W WO 2017113945 A1 WO2017113945 A1 WO 2017113945A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
gel composition
parts
spray
tape
Prior art date
Application number
PCT/CN2016/102789
Other languages
French (fr)
Chinese (zh)
Inventor
罗昌炎
布里斯托詹姆斯•T
林文鸿
黄弘宗
Original Assignee
江苏龙灯化学有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 江苏龙灯化学有限公司 filed Critical 江苏龙灯化学有限公司
Publication of WO2017113945A1 publication Critical patent/WO2017113945A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/02Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A01N25/06Aerosols
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/24Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/16Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system

Definitions

  • the present invention relates to the field of agriculture, and in particular to a gel-like composition for attracting insects, a spray for attracting insects, an insect-inducing tape, and a method for reducing insect damage.
  • Drosophila (Tephritidae) is one of the most devastating agricultural pests in the world.
  • Diptera (Diptera), commonly known as melon or melon, is the most important pest of melons and fruits, distributed in tropical and subtropical regions. There are more than 80 species of 16 families, such as watermelon, cantaloupe, courgette, loofah, bitter gourd, pumpkin, melon and tomato. The adult spawning tube of the fruit fly penetrates into the epidermis of the young melon to lay eggs.
  • the wound is condensed with glue, deformed and sag, the skin is hard, and the melon tastes bitter, which seriously affects the quality and yield of the melon.
  • the fruit fly also belongs to the diptera (Diptera), also known as the needle bee, the fruit worm, the orange fruit fly, the orange fruit fly, the yellow fly, the melon and so on.
  • Diptera also known as the needle bee, the fruit worm, the orange fruit fly, the orange fruit fly, the yellow fly, the melon and so on.
  • Many countries and regions in Southeast Asia and Oceania including India, Bhutan, Thailand, Vietnam, Laos, Nepal, Pakistan, Bangladesh, Cambodia, Sri Lanka, Malaysia, Indonesia, China (Hunan, Guangdong, Hainan, Guangxi, Fujian) , Sichuan, Yunnan, Guizhou, Taiwan, the Philippines, Ryukyu, Hawaii) are generally affected by fruit flies.
  • the female adult eggs of the fruit fly are produced on the skin or surface of the melon and fruit, and some are produced in the stem tissue.
  • the young fruit is more seriously damaged.
  • the larvae of the fruit fly of the melon flies eat the flesh of the crop, causing the fruit to rot or deform, which seriously affects the yield and quality of the crop, causing serious damage to the economic interests of the grower.
  • the current control methods for fruit flies mainly include the anti-male treatment method, the chemical control method, the food trapping method, the trapping method, the suiting method, and the yellow sticky paper method.
  • the anti-androgenic treatment method utilizes the strong male-like characteristics of fruit-based clove oil or gram fly, and carries out a large number of ways to prevent and kill males in the field, which allows the poisonous methyl clove oil or the fly to trap male flies. So that the female can not find the males to mate and produce the invalid eggs, so that the field group of the fruit fly is gradually reduced; the chemical control method is to use the killing when the density of the fruit flies is increased or when the fruit of the melon is gradually matured.
  • Insecticides are fully sprayed and culled on adults to reduce their oviposition hazards, but the fly has strong flight ability, and the medicament is not easy to effectively control adults;
  • the food trap method refers to the high density of fruit flies, and the food inducer Killing male and female adults, food decoy can be hydrolyzed with pesticides to form toxic bait;
  • trapping method refers to using methyl clove oil or gram fly into the trap and hanging inside and outside the orchard for trapping;
  • the fruit on the fruit tree is bagged;
  • the yellow paper method refers to the use of Drosophila adults to significantly improve the yellow color, while the yellow paper is hung in the orchard to capture the adult fly.
  • the chemical control method has strong flight ability in the field, resulting in high control cost and poor control effect;
  • the anti-male treatment method requires the addition of toxic agents and a large amount of spraying, which causes environmental pollution and the female flies still exist.
  • the treatment of the standard has not been cured;
  • the food trapping method will cause pollution to the environment due to the addition of toxic agents, and the trapping distance is small, the effect is not significant;
  • the bagging method has high cost, long process, and the application of fruit trees is limited, if the bag is improper, it is easy Affects plant growth;
  • the trap method has the disadvantages of high cost, complicated placement process, and vulnerability to environmental damage.
  • An insect control formulation comprising methyl eugenol, a cockroach and a biodegradable wax carrier is provided in document CN 104349677 A, and optionally further comprises an insect toxic agent.
  • the insect control preparation contains an insect poison, there is a problem of environmental pollution, and when the insect poison is not contained, the control efficiency against the fruit fly is still low.
  • the present invention provides a gel-like composition for attracting insects capable of further improving the control efficiency of Drosophila, and a spray for attracting insects. , a tape that attracts insects and a method of reducing insect damage.
  • the present invention provides a gel-like composition for attracting insects, the gel composition comprising a fly ketone and a methyl eugenol, wherein the gel composition further comprises a pressure sensitive adhesive, a solid phase carrier and a solvent .
  • the present invention also provides a spray for attracting insects, the spray comprising an attractant and a propellant; wherein the attractant is a gel composition as described above.
  • the present invention provides an insect-inducing tape comprising a tape-shaped substrate, an adhesive colloid layer coated on one side of the tape-shaped substrate, and coated on the other side of the tape-shaped substrate An attractant colloid layer; wherein the attractant colloid layer comprises a gelatinous composition as described above.
  • the present invention provides a method of reducing insect hazards, wherein the method comprises using a gel composition as described above, a spray as described above, and a tape as described above in a crop planting site. At least one of them to trap insects.
  • the gel composition of the present invention can reduce the ratio of the number of fruits with insect pests to the total number of fruits (hazard rate) to 5-15 in a test experiment conducted on a citrus, watermelon, mango or the like planting site. %, significantly lower than existing insect control formulations.
  • the present invention provides a gel-like composition for attracting insects, the gel composition comprising a fly ketone and a methyl eugenol, wherein the gel composition further comprises a pressure sensitive adhesive, a solid phase carrier and a solvent .
  • fly ketone and methyl eugenol have a strong temptation effect on fruit flies, and the fruit fly instinctively approaches the material releasing lactone and methyl eugenol until it contacts, thereby being adhered to the gel composition of the present invention. Both of them are commercially available and can be uniformly dispersed in the gel composition.
  • Fly ketone refers to 4-(p-acetoxyphenyl)-2-butanone
  • English name is 4-(p-acetoxyphenyl)-2-butanone (cue-lure), which is CAS No. 3572-06-3
  • the compound registered; its molecular formula is: C 12 H 14 O 3 structural formula is:
  • Methyl eugenol refers to 1,2-dimethoxy-4-(2-propenyl)benzene, the English name is 1,2-dimethoxy-4-(2-propenyl)-benzene (Methyl eugenol), which is CAS.
  • the content of each component in the gel composition can be varied within a wide range, for example, the content of methyl eugenol is 0.1-20 parts by weight relative to 1 part by weight of the ketidone, and the pressure sensitive adhesive The content is 0.25 to 25 parts by weight, the content of the solid phase carrier is 0.05 to 10 parts by weight, and the content of the solvent is 0.25 to 25 parts by weight.
  • the gelatinous composition has a methyl eugenol content of 0.5 to 5 parts by weight and a pressure sensitive adhesive content of 1 to 1 part by weight of the chlorfenapyr.
  • the content of the solid phase carrier is from 0.4 to 4 parts by weight, and the solvent is contained in an amount of from 1 to 10 parts by weight, based on 10 parts by weight.
  • the gelled composition has a prominent trapping effect on fruit flies.
  • the fly ketone comprises from about 1% to about 40% by weight of the composition, preferably from about 1% to about 20% by weight;
  • the methyl eugenol comprises the composition From about 1% by weight to about 50% by weight, preferably from about 3% by weight to about 20% by weight;
  • the pressure sensitive adhesive comprises from about 5 to 60% by weight of the composition, preferably from about 10% to 50% by weight;
  • the solid phase carrier From about 0.1% to about 10% by weight of the composition, preferably from about 0.1% to about 7% by weight;
  • the solvent comprises from about 2% to about 30% by weight of the composition, preferably from about 5% to about 25% by weight .
  • a gelled composition according to the present invention wherein the pressure sensitive adhesive refers to an adhesive that is sensitive to pressure.
  • the pressure sensitive adhesive may be selected in a wide range as long as it can function as a fruit fly, and may include, for example, an ethylene propylene copolymer, a petroleum resin, a polybutene, and any viscous polymer compound.
  • the pressure sensitive adhesive is selected from at least one of an ethylene propylene copolymer, a petroleum resin, and a polybutene. More preferably, the pressure sensitive adhesive has a weight average molecular weight of from 300 to 3,000.
  • the gel composition of the present invention has safe, stable, high-adhesion, low-resistance insect trapping characteristics, and has a viscosity which is unstoppable to most insects, that is, when the insect contacts the present invention The gelatinous composition is stuck and cannot be removed.
  • the solid phase carrier may be a substance which is solid and capable of supporting an active ingredient.
  • the solid phase carrier may be selected in a wide range as long as it can adsorb fly ketone and methyl eugenol to have a sustained release effect, for example, the solid phase carrier may include zeolite, such as synthetic zeolite, natural. At least one of zeolite and regenerated zeolite, white carbon black, such as precipitated silica, fumed silica, and ultrafine silica gel, activated carbon.
  • the solid support may comprise zeolite and/or silica.
  • the zeolite preferably has a specific surface area of 10 to 200 m 2 /g and an average particle diameter of 10 to 50 ⁇ m.
  • the silica preferably has a specific surface area of 100 to 200 m 2 /g and an average particle diameter of 10 to 25 nm.
  • the gel composition of the present invention has a good sustained release property and is capable of maintaining the enticing effect on insects for a long period of time, that is, having a long life cycle and avoiding the disadvantage of frequent application.
  • a colloidal composition according to the present invention wherein the solvent is preferably a saturated aliphatic hydrocarbon such as Zhengji Alkane, cyclohexane and n-octane.
  • the solvent is n-hexane.
  • the gel composition further comprises a clove complex oil and/or a hydrolyzed protein.
  • the clove composite essential oil and the hydrolyzed protein can significantly enhance the enticing ability to insects, thereby increasing the control effect of the gel composition of the present invention on harmful insects.
  • the content of the clove complex oil is 0.05-20 parts by weight, preferably 1-10 parts by weight, and the hydrolyzed protein content is 0.05-% with respect to 1 part by weight of the ketidone. 10 parts by weight, preferably 1 to 5 parts by weight.
  • the clove composite essential oil refers to a product obtained by extracting a plant such as clove as a raw material, and can be obtained by a commercially available product;
  • the hydrolyzed protein is a product obtained by hydrolyzing a protease using a yeast protein as a raw material, and can pass the product.
  • Commercially available are examples of commercially available.
  • the gel composition may be a coating agent, i.e., the gel composition of the present invention may be applied to a solid surface, i.e., to form a trapping point capable of trapping insects.
  • yellow pigment can be selectively incorporated into the gel composition of the present invention.
  • the yellow pigment may be selected from all common yellow pigments that are capable of dyeing the formulation. Likewise, suitable yellows for the active ingredients are known in the art.
  • the yellow pigment includes, but is not limited to, at least one of Metanil yellow G, Reactive yellow K-6G, and Yellow Pigment 2G.
  • a non-polar solvent and an emulsifier may be selectively incorporated in the gel composition of the present invention.
  • the yellow pigment is dissolved in a non-polar solvent, an emulsifier is added, and finally miscible with the gel composition.
  • the non-polar solvent may be selected from all common non-polar solvents which are capable of solubilizing the active compound employed.
  • suitable non-polar solvents are known in the art. Examples of non-polar solvents which may be mentioned include chloroform, benzene, liquid paraffin, vegetable oil, diethyl ether, ethyl acetate and the like.
  • the non-polar solution The agent is ethyl acetate.
  • the emulsifiers include, but are not limited to, lecithin, monoglycerides, diglycerides, sorbitan monooleate, polyoxyethylene sorbitan monooleate (Tween 80), sorbitan monolaurate At least one of polyethylene oxide-sorbitan monooleate, fatty acid, and sorbitan tristearic acid.
  • the emulsifier Tween 80 is included in the formulation.
  • the weight ratio of the yellow pigment to the non-polar solvent may be 1: (8-12).
  • the weight ratio of the yellow pigment to the emulsifier may be 1: (1-3). The amount of the yellow pigment is such that the content of the yellow pigment in the gel composition is from 0.2 to 0.8% by weight.
  • a UV blocker and an antioxidant can also be selectively added.
  • UV blockers that may be included include, but are not limited to, beta-carotene and/or p-aminobenzoic acid.
  • Antioxidants that may be included include, but are not limited to, at least one of butylated hydroxyanisole (BHA), dibutylhydroxytoluene (BHT), and vitamin E.
  • the preparation method of the gel composition of the present invention is not particularly required as long as the components are uniformly mixed; for example, the pressure sensitive adhesive can be dissolved in a solvent, and then fly ketone, methyl eugenol, and solid are added.
  • the phase carrier optionally also added to the clove complex oil and/or hydrolyzed protein, is mixed well.
  • the pressure sensitive adhesive may be dissolved in a solvent, and then the fly ketone, the methyl eugenol, the solid phase carrier, and optionally the clove compound oil may be further added.
  • the invention provides a spray for attracting insects, the spray comprising an attractant and a propellant; wherein the attractant is a gelled composition as described above.
  • the propellant in the spray, may be included in an amount of 30 to 60% by weight, preferably 40 to 50% by weight.
  • the propellant includes dimethyl ether, propane and butane.
  • the content of propane is 0.5 to 0.7 part by weight with respect to 1 part by weight of dimethyl ether; and the content of butane is 1 to 2 parts by weight.
  • the gel composition as described above can be uniformly dispersed in the compressed propellant, and under the push of the compressed propellant, the spray is controllably sprayed on the surface of the object, and the propellant is volatilized, leaving the above
  • the gelled composition covers the surface of the object to form an insect trapping point.
  • the present invention provides an insect-inducing tape comprising a tape-shaped substrate, an adhesive colloid layer coated on one side of the tape-shaped substrate, and coated on the other side of the tape-shaped substrate An attractant colloid layer; wherein the attractant colloid layer comprises a gelatinous composition as described above.
  • the adhesive tape further comprises a release film covering the layer of the attractant colloid.
  • the adhesive tape may be adhered to the surface of the object via the adhesive colloid layer, and then the release film on the attractant colloid layer may be peeled off, thereby exposing the gel composition as described above to form an insect trapping point.
  • the present invention provides a method of reducing insect hazards, wherein the method comprises using a gel composition as described above, a spray as described above, and a tape as described above in a crop planting site. At least one of them to trap insects.
  • one or more trap points are set in the crop planting land using at least one of the gel composition as described above, the spray as described above, and the tape as described above.
  • the trapping point may include a fixed object and a gel composition as described above adhered to the fixed object; the fixed object preferably uses at least one of waste such as a plastic bottle, an advertising oil paper, and a fertilizer bag.
  • the spacing between two adjacent trap points is 100-300 meters.
  • the crops may include citrus, grapefruit, persimmon, guava, longan, lychee, mango, lotus, avocado, sapodilla, carambola, alfalfa, papaya, peach, sacora, watermelon, cantaloupe, courgette, loofah. At least one of bitter gourd, pumpkin, melon, tomato, terminal meringue, moon orange, and sorrel.
  • the gel composition of the present invention is particularly suitable for trapping fruit flies, it is not limited thereto.
  • the gel composition of the present invention can trap insects including fruit flies, yellow leafhoppers, mosquitoes, At least one of flies, thrips, whitefly, and moths.
  • the raw materials used are all commercially available, specifically: cockroach is purchased from Guangzhou Shengxun Company, product number is CAS 3572-06-3; methyl eugenol is purchased from Yunfa Chemical company, commodity number is 93-15-2; ethylene propylene copolymer is purchased from Deyuan Company, product number is 303P, weight average molecular weight is 20,000-50000amu; petroleum resin is purchased from Shenzhen Yoshida Company, product number is 64742-16- 1, the weight average molecular weight is 10000-30000 amu; polybutene is purchased from Dalin Company of Korea, the product number is PB-2100, the weight average molecular weight is 30,000-60000 amu; the zeolite is purchased from Weixin Company, the product number is JMAX, and the specific surface area is 30- 100m 2 /g, average particle size is 10-50 ⁇ m; white carbon black is purchased from Weixin Company, product number is JMAX-2, specific surface area is
  • a gelatinous composition was prepared according to the following steps: the pressure sensitive adhesive was dissolved in a solvent of n-hexane, and then a fly ketone, a methyl eugenol, a solid phase carrier, optionally a clove complex oil and/or a hydrolyzed protein were further added.
  • Example 1 The products of Examples 1-8 and Comparative Example 1 were separately mixed with an equal weight of propellant (a mixture of dimethyl ether, propane and butane in a weight ratio of 3:2:5) under pressure, and charged. In the spray can, the respective sprays were obtained.
  • propellant a mixture of dimethyl ether, propane and butane in a weight ratio of 3:2:5
  • test citrus orchards separated by more than 1000 m are delineated, and different sprays are used at intervals of 200 m in 9 test citrus orchards.
  • the trapping point was set as the experimental group, and the trapping point was not set in the remaining one test citrus orchard as a control group.
  • a fixed object 1.5L Coca-Cola plastic bottle
  • the spraying agent is evenly sprayed once on the fixed object to obtain the trapping point.
  • the trapping point is determined every 14 days after the trapping point is set.
  • the ratio of the number of fruits to the total number of fruits is shown in Table 2.
  • Examples 1-8 can greatly reduce the hazard rate of the fruit fly and the fruit fly in a longer period than the comparison.
  • the content of the methyl eugenol is 0.5 to 5 parts by weight
  • the content of the pressure sensitive adhesive is 1-10 parts by weight
  • the content of the solid phase carrier is 0.4 to 4 parts by weight
  • the content of the solvent is 1-10 parts by weight.
  • the gel composition of the present invention can further reduce the hazard rate of the fruit fly and the fruit fly.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catching Or Destruction (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a gel composition for attracting insects, and the gel composition comprises cuelure and methyl eugenol, wherein the gel composition further comprises a pressure sensitive adhesive, a solid-phase carrier, and a solvent. In another aspect, the present invention also provides a spray for attracting insects, a tape for attracting insects, and a method of reducing insect pest damage. By employing the above technical solution, the gel composition in the present invention lowers a ratio of the number of damaged fruits by insect pests to the total number of fruits (a damage rate) to 5-15%, which is significantly lower than the existing insect control agents.

Description

一种引诱昆虫的胶状组合物及喷雾剂和胶带以及降低昆虫危害的方法Gum composition for attracting insects, spray and tape, and method for reducing insect damage 技术领域Technical field
本发明涉及农业领域,具体地,涉及一种引诱昆虫的胶状组合物、一种引诱昆虫的喷雾剂、一种引诱昆虫的胶带以及一种降低昆虫危害的方法。The present invention relates to the field of agriculture, and in particular to a gel-like composition for attracting insects, a spray for attracting insects, an insect-inducing tape, and a method for reducing insect damage.
背景技术Background technique
果蝇(实蝇科)是世界上最具破坏性的农业害虫之一。本申请所使用的术语“果蝇”表示属于双翅目(Diptera)实蝇科的所有蝇类,包括瓜实蝇和果实蝇。Drosophila (Tephritidae) is one of the most devastating agricultural pests in the world. The term "drosophila" as used herein, denotes all flies belonging to the family Diptera, including cucurbit flies and fruit flies.
瓜实蝇属双翅目(Diptera),俗称瓜蝇或瓜仔蜂,为瓜果类最重要害虫,分布于热带及亚热带地区。瓜实蝇所危害的植物多达16科80种以上,例如西瓜、洋香瓜、胡瓜、丝瓜、苦瓜、南瓜、冬瓜及蕃茄等。瓜实蝇成虫产卵管刺入幼瓜表皮内产卵,幼虫孵化后即在瓜内蛀食,受害的瓜先局部变黄,而后全瓜腐烂变臭,造成大量落瓜,即使不腐烂,刺伤处凝结着流胶,畸形下陷,果皮硬实,瓜味苦涩,严重影响瓜的品质和产量。Diptera (Diptera), commonly known as melon or melon, is the most important pest of melons and fruits, distributed in tropical and subtropical regions. There are more than 80 species of 16 families, such as watermelon, cantaloupe, courgette, loofah, bitter gourd, pumpkin, melon and tomato. The adult spawning tube of the fruit fly penetrates into the epidermis of the young melon to lay eggs. After the larva hatches, the larvae feed in the melon, and the damaged melon first turns yellow, and then the whole melon rots and becomes stinky, causing a large amount of melon, even if it does not rot, thorn The wound is condensed with glue, deformed and sag, the skin is hard, and the melon tastes bitter, which seriously affects the quality and yield of the melon.
果实蝇亦属于双翅目(Diptera),又称针蜂、蛀果虫、桔小实蝇、桔大实蝇、黄苍蝇、瓜蛆等。东南亚及大洋洲的多个国家和地区(包括印度、不丹、泰国、越南、寮国、尼泊尔、巴基斯坦、孟加拉国、柬埔寨、斯里兰卡、马来西亚、印度尼西亚、中国大陆(湖南、广东、海南、广西、福建、四川、云南、贵州)、台湾、菲律宾、琉球、夏威夷)普遍受果实蝇的危害。果实蝇雌成虫卵产于瓜果的皮下或表面上,还有部份产于茎部组织中。特别是幼嫩果实受害较严重。瓜果蝇的卵毈化后之幼虫蛀食农作物的果肉,导致果实腐烂或畸型,严重影响农作物的产量及质量,给种植者的经济利益造成严重的损害。 The fruit fly also belongs to the diptera (Diptera), also known as the needle bee, the fruit worm, the orange fruit fly, the orange fruit fly, the yellow fly, the melon and so on. Many countries and regions in Southeast Asia and Oceania (including India, Bhutan, Thailand, Vietnam, Laos, Nepal, Pakistan, Bangladesh, Cambodia, Sri Lanka, Malaysia, Indonesia, China (Hunan, Guangdong, Hainan, Guangxi, Fujian) , Sichuan, Yunnan, Guizhou, Taiwan, the Philippines, Ryukyu, Hawaii) are generally affected by fruit flies. The female adult eggs of the fruit fly are produced on the skin or surface of the melon and fruit, and some are produced in the stem tissue. In particular, the young fruit is more seriously damaged. The larvae of the fruit fly of the melon flies eat the flesh of the crop, causing the fruit to rot or deform, which seriously affects the yield and quality of the crop, causing serious damage to the economic interests of the grower.
目前的果蝇防治方法主要包括灭雄处理法、药剂防治法、食物诱杀法、诱补器法、套装法、黄色粘纸法。其中,灭雄处理法是利用果基丁香油或克蝇具有的强烈诱雄虫特性,在田间进行大量诱杀雄虫的防治方式,该方式让含毒的甲基丁香油或克蝇诱杀雄蝇,使雌虫找不到雄虫交尾而产下无效卵,使果蝇的田间族群逐渐降低;药剂防治法是在瓜果实蝇密度升高时或结果期瓜果实逐渐成熟时,使用杀虫剂进行全面喷洒,对成虫进行扑杀,可降低其产卵危害,但果蝇飞行能力强,药剂不易对成虫有效防治;食物诱杀法是指果蝇发生密度高时,以食物诱杀剂渗杀雌雄成虫,食物诱杀剂可用水解蛋白加入杀虫剂配成含毒诱饵;诱补器法是指利用甲基丁香油或克蝇置入诱补器中并悬挂于果园内外进行诱捕;套装法使指对果树上的果实进行套袋;黄色粘纸法是指利用果蝇成虫对黄色均有明显徧好,而将黄色纸悬挂于果园中以捕捉果蝇成虫。上述防治方法中,药剂防治法因田间范围中,蝇虫飞行能力强,导致防治成本高,防治效果差;灭雄处理法因需添加毒性药剂且大量喷洒,会造成环境污染且雌蝇依然存在,治标未治本;食物诱杀法因添加毒性药剂,会对环境造成污染,且诱杀距离小,效果不够显著;套袋法成本高、工序长,且适用果树受局限,如果套袋不当,还易影响植物生长;诱补器法存在成本高、放置工序复杂、易受环境破坏的缺陷。The current control methods for fruit flies mainly include the anti-male treatment method, the chemical control method, the food trapping method, the trapping method, the suiting method, and the yellow sticky paper method. Among them, the anti-androgenic treatment method utilizes the strong male-like characteristics of fruit-based clove oil or gram fly, and carries out a large number of ways to prevent and kill males in the field, which allows the poisonous methyl clove oil or the fly to trap male flies. So that the female can not find the males to mate and produce the invalid eggs, so that the field group of the fruit fly is gradually reduced; the chemical control method is to use the killing when the density of the fruit flies is increased or when the fruit of the melon is gradually matured. Insecticides are fully sprayed and culled on adults to reduce their oviposition hazards, but the fly has strong flight ability, and the medicament is not easy to effectively control adults; the food trap method refers to the high density of fruit flies, and the food inducer Killing male and female adults, food decoy can be hydrolyzed with pesticides to form toxic bait; trapping method refers to using methyl clove oil or gram fly into the trap and hanging inside and outside the orchard for trapping; The fruit on the fruit tree is bagged; the yellow paper method refers to the use of Drosophila adults to significantly improve the yellow color, while the yellow paper is hung in the orchard to capture the adult fly. Among the above-mentioned control methods, the chemical control method has strong flight ability in the field, resulting in high control cost and poor control effect; the anti-male treatment method requires the addition of toxic agents and a large amount of spraying, which causes environmental pollution and the female flies still exist. The treatment of the standard has not been cured; the food trapping method will cause pollution to the environment due to the addition of toxic agents, and the trapping distance is small, the effect is not significant; the bagging method has high cost, long process, and the application of fruit trees is limited, if the bag is improper, it is easy Affects plant growth; the trap method has the disadvantages of high cost, complicated placement process, and vulnerability to environmental damage.
文献CN104349677A中给出了一种昆虫防治制剂,其包含甲基丁香酚、诱蝇酮和可生物降解的蜡载体,并且可选地进一步包含了昆虫毒剂。在该昆虫防治制剂包含昆虫毒剂时会存在环境污染的问题,而不含有昆虫毒剂时,对果蝇的防治效率仍然较低。An insect control formulation comprising methyl eugenol, a cockroach and a biodegradable wax carrier is provided in document CN 104349677 A, and optionally further comprises an insect toxic agent. When the insect control preparation contains an insect poison, there is a problem of environmental pollution, and when the insect poison is not contained, the control efficiency against the fruit fly is still low.
发明内容Summary of the invention
为了克服现有的昆虫防治剂对果蝇的防治效率较低的缺陷,本发明提供了一种能够进一步提高对果蝇的防治效率的引诱昆虫的胶状组合物、一种引诱昆虫的喷雾剂、一种引诱昆虫的胶带以及一种降低昆虫危害的方法。 In order to overcome the defect that the existing insect control agent has low control efficiency against Drosophila, the present invention provides a gel-like composition for attracting insects capable of further improving the control efficiency of Drosophila, and a spray for attracting insects. , a tape that attracts insects and a method of reducing insect damage.
一方面,本发明提供了一种引诱昆虫的胶状组合物,该胶状组合物含有诱蝇酮和甲基丁香酚,其中,该胶状组合物还含有压敏胶、固相载体和溶剂。In one aspect, the present invention provides a gel-like composition for attracting insects, the gel composition comprising a fly ketone and a methyl eugenol, wherein the gel composition further comprises a pressure sensitive adhesive, a solid phase carrier and a solvent .
另一方面,本发明还提供了一种引诱昆虫的喷雾剂,所述喷雾剂包括引诱物和推进剂;其中,所述引诱物为如上所述的胶状组合物。In another aspect, the present invention also provides a spray for attracting insects, the spray comprising an attractant and a propellant; wherein the attractant is a gel composition as described above.
另一方面,本发明还提供了一种引诱昆虫的胶带,所述胶带包括带状基体、涂布在所述带状基体的一面的黏附胶体层和涂布在所述带状基体的另一面的引诱胶体层;其中,所述引诱胶体层含有如上所述的胶状组合物。In another aspect, the present invention provides an insect-inducing tape comprising a tape-shaped substrate, an adhesive colloid layer coated on one side of the tape-shaped substrate, and coated on the other side of the tape-shaped substrate An attractant colloid layer; wherein the attractant colloid layer comprises a gelatinous composition as described above.
另一方面,本发明还提供了一种降低昆虫危害的方法,其中,该方法包括在农作物种植地中使用如上所述的胶状组合物、如上所述的喷雾剂和如上所述的胶带中的至少一种来诱捕昆虫。In another aspect, the present invention provides a method of reducing insect hazards, wherein the method comprises using a gel composition as described above, a spray as described above, and a tape as described above in a crop planting site. At least one of them to trap insects.
通过上述技术方案,在柑橘、西瓜、芒果等种植地进行的测试实验中,本发明的胶状组合物能够将带有虫害的果实数占总果实数的比例(危害率)降低至5-15%,显著地低于现有的昆虫防治制剂。According to the above technical solution, the gel composition of the present invention can reduce the ratio of the number of fruits with insect pests to the total number of fruits (hazard rate) to 5-15 in a test experiment conducted on a citrus, watermelon, mango or the like planting site. %, significantly lower than existing insect control formulations.
本发明的其他特征和优点将在随后的具体实施方式部分予以详细说明。Other features and advantages of the invention will be described in detail in the detailed description which follows.
具体实施方式detailed description
以下对本发明的具体实施方式进行详细说明。应当理解的是,此处所描述的具体实施方式仅用于说明和解释本发明,并不用于限制本发明。Specific embodiments of the present invention will be described in detail below. It is to be understood that the specific embodiments described herein are merely illustrative and not restrictive.
一方面,本发明提供了一种引诱昆虫的胶状组合物,该胶状组合物含有诱蝇酮和甲基丁香酚,其中,该胶状组合物还含有压敏胶、固相载体和溶剂。In one aspect, the present invention provides a gel-like composition for attracting insects, the gel composition comprising a fly ketone and a methyl eugenol, wherein the gel composition further comprises a pressure sensitive adhesive, a solid phase carrier and a solvent .
其中,诱蝇酮和甲基丁香酚对果蝇具有强烈的诱惑作用,果蝇会本能地向释放诱蝇酮和甲基丁香酚的物料靠近直至接触,从而被本发明的胶状组合物黏住,二者均可通过商购获得,可以均匀地分散在所述胶状组合物中。Among them, fly ketone and methyl eugenol have a strong temptation effect on fruit flies, and the fruit fly instinctively approaches the material releasing lactone and methyl eugenol until it contacts, thereby being adhered to the gel composition of the present invention. Both of them are commercially available and can be uniformly dispersed in the gel composition.
诱蝇酮是指4-(对乙酰氧基苯基)-2-丁酮,英文名为4-(p-acetoxyphenyl)-2-butanone(cue-lure),是CAS No.3572-06-3所登录的化合物;其分子式为:C12H14O3结构式为: Fly ketone refers to 4-(p-acetoxyphenyl)-2-butanone, English name is 4-(p-acetoxyphenyl)-2-butanone (cue-lure), which is CAS No. 3572-06-3 The compound registered; its molecular formula is: C 12 H 14 O 3 structural formula is:
Figure PCTCN2016102789-appb-000001
Figure PCTCN2016102789-appb-000001
甲基丁香酚是指1,2-二甲氧基-4-(2-丙烯基)苯,英文名为1,2-dimethoxy-4-(2-propenyl)-benzene(Methyl eugenol),是CAS No.93-15-2所登录的化合物;其分子式为C11H14O2,结构式为:Methyl eugenol refers to 1,2-dimethoxy-4-(2-propenyl)benzene, the English name is 1,2-dimethoxy-4-(2-propenyl)-benzene (Methyl eugenol), which is CAS. A compound registered in No. 93-15-2; its molecular formula is C 11 H 14 O 2 , and its structural formula is:
Figure PCTCN2016102789-appb-000002
Figure PCTCN2016102789-appb-000002
其中,该胶状组合物中,各组分的含量可以在较大范围内变化,例如,相对于1重量份的诱蝇酮,甲基丁香酚的含量为0.1-20重量份,压敏胶的含量为0.25-25重量份,固相载体的含量为0.05-10重量份,溶剂的含量为0.25-25重量份。Wherein, the content of each component in the gel composition can be varied within a wide range, for example, the content of methyl eugenol is 0.1-20 parts by weight relative to 1 part by weight of the ketidone, and the pressure sensitive adhesive The content is 0.25 to 25 parts by weight, the content of the solid phase carrier is 0.05 to 10 parts by weight, and the content of the solvent is 0.25 to 25 parts by weight.
其中,根据本发明优选的一种实施方式,该胶状组合物中,相对于1重量份的诱蝇酮,甲基丁香酚的含量为0.5-5重量份,压敏胶的含量为1-10重量份,固相载体的含量为0.4-4重量份,溶剂的含量为1-10重量份。在该优选实施方式中,所述胶状组合物对果蝇具有突出的诱捕效果。 Wherein, according to a preferred embodiment of the present invention, the gelatinous composition has a methyl eugenol content of 0.5 to 5 parts by weight and a pressure sensitive adhesive content of 1 to 1 part by weight of the chlorfenapyr. The content of the solid phase carrier is from 0.4 to 4 parts by weight, and the solvent is contained in an amount of from 1 to 10 parts by weight, based on 10 parts by weight. In the preferred embodiment, the gelled composition has a prominent trapping effect on fruit flies.
在本发明的胶状组合物一种实施方式中,诱蝇酮占组合物的约1重量%至约40重量%,优选约1重量%至约20重量%;甲基丁香酚占组合物的约1重量%至约50重量%,优选占约3重量%至约20重量%;压敏胶占组合物的约5重量至60%重量,优选约10重量%至50重量%;固相载体占组合物的约0.1重量%至约10重量%,优选约0.1重量%至约7重量%;溶剂占组合物的约2重量%至约30重量%,优选约5重量%至约25重量%。In one embodiment of the gel composition of the present invention, the fly ketone comprises from about 1% to about 40% by weight of the composition, preferably from about 1% to about 20% by weight; the methyl eugenol comprises the composition From about 1% by weight to about 50% by weight, preferably from about 3% by weight to about 20% by weight; the pressure sensitive adhesive comprises from about 5 to 60% by weight of the composition, preferably from about 10% to 50% by weight; the solid phase carrier From about 0.1% to about 10% by weight of the composition, preferably from about 0.1% to about 7% by weight; the solvent comprises from about 2% to about 30% by weight of the composition, preferably from about 5% to about 25% by weight .
根据本发明的胶状组合物,其中,所述压敏胶是指对压力有敏感性的胶粘剂。所述压敏胶可以在较宽的范围内选择,只要能够起到黏附果蝇的作用即可,例如可以包括乙烯丙烯共聚物、石油树脂、聚丁烯,以及任何具有黏性的高分子化合物,例如橡胶类、塑料类、增稠剂类等各种油性及水性高分子聚合物中的至少一种。优选地,所述压敏胶选自乙烯丙烯共聚物、石油树脂和聚丁烯中的至少一种。更优选地,所述压敏胶的重均分子量为300-3000。在该优选情况下,本发明的胶状组合物具有安全、稳定、高黏着性、低抗阻力性的昆虫诱捕特性,能够具有让绝大多数昆虫无法抗拒的黏性,即昆虫一旦接触本发明的胶状组合物就被黏住无法脱身。A gelled composition according to the present invention, wherein the pressure sensitive adhesive refers to an adhesive that is sensitive to pressure. The pressure sensitive adhesive may be selected in a wide range as long as it can function as a fruit fly, and may include, for example, an ethylene propylene copolymer, a petroleum resin, a polybutene, and any viscous polymer compound. For example, at least one of various oily and water-based high molecular polymers such as rubbers, plastics, and thickeners. Preferably, the pressure sensitive adhesive is selected from at least one of an ethylene propylene copolymer, a petroleum resin, and a polybutene. More preferably, the pressure sensitive adhesive has a weight average molecular weight of from 300 to 3,000. In this preferred case, the gel composition of the present invention has safe, stable, high-adhesion, low-resistance insect trapping characteristics, and has a viscosity which is unstoppable to most insects, that is, when the insect contacts the present invention The gelatinous composition is stuck and cannot be removed.
根据本发明的胶状组合物,其中,所述固相载体可以是呈固态且能够负载活性成分的物质。所述固相载体可以在较宽的范围内选择,只要能吸附诱蝇酮和甲基丁香酚以使其具有缓释效果即可,例如所述固相载体可以包括沸石,如合成沸石、天然沸石和再生沸石,白炭黑,如沉淀二氧化硅、气相二氧化硅和超细二氧化硅凝胶,活性炭中的至少一种。优选地,所述固相载体可以包括沸石和/或白炭黑。所述沸石优选比表面积为10-200m2/g,平均粒径10-50μm。所述白炭黑优选比表面积100-200m2/g,平均粒径10-25nm。在该优选情况下,本发明的胶状组合物具有良好的缓释性能,能够在较长的时间内保持对昆虫的诱惑性,即具有较长的使用周期,避免了频繁施用的弊端。A gelled composition according to the present invention, wherein the solid phase carrier may be a substance which is solid and capable of supporting an active ingredient. The solid phase carrier may be selected in a wide range as long as it can adsorb fly ketone and methyl eugenol to have a sustained release effect, for example, the solid phase carrier may include zeolite, such as synthetic zeolite, natural. At least one of zeolite and regenerated zeolite, white carbon black, such as precipitated silica, fumed silica, and ultrafine silica gel, activated carbon. Preferably, the solid support may comprise zeolite and/or silica. The zeolite preferably has a specific surface area of 10 to 200 m 2 /g and an average particle diameter of 10 to 50 μm. The silica preferably has a specific surface area of 100 to 200 m 2 /g and an average particle diameter of 10 to 25 nm. In this preferred case, the gel composition of the present invention has a good sustained release property and is capable of maintaining the enticing effect on insects for a long period of time, that is, having a long life cycle and avoiding the disadvantage of frequent application.
根据本发明的胶状组合物,其中,所述溶剂优选饱和脂肪烃,例如正己 烷、环己烷和正辛烷等。在本发明的一种优选实施方式中,所述溶剂为正己烷。A colloidal composition according to the present invention, wherein the solvent is preferably a saturated aliphatic hydrocarbon such as Zhengji Alkane, cyclohexane and n-octane. In a preferred embodiment of the invention, the solvent is n-hexane.
根据本发明的一种优选实施方式,其中,所述胶状组合物还含有丁香复合精油和/或水解蛋白。其中,所述丁香复合精油和所述水解蛋白能够显著地增强对昆虫的诱惑力,从而增加本发明的胶状组合物对有害昆虫的防治效果。According to a preferred embodiment of the present invention, the gel composition further comprises a clove complex oil and/or a hydrolyzed protein. Among them, the clove composite essential oil and the hydrolyzed protein can significantly enhance the enticing ability to insects, thereby increasing the control effect of the gel composition of the present invention on harmful insects.
其中,更优选地,所述胶状组合物中,相对于1重量份的诱蝇酮,丁香复合精油的含量为0.05-20重量份,优选1-10重量份,水解蛋白的含量为0.05-10重量份,优选1-5重量份。More preferably, in the gel composition, the content of the clove complex oil is 0.05-20 parts by weight, preferably 1-10 parts by weight, and the hydrolyzed protein content is 0.05-% with respect to 1 part by weight of the ketidone. 10 parts by weight, preferably 1 to 5 parts by weight.
其中,所述丁香复合精油是指以丁香等植物为原料进行萃取后获得的产物,可以通过商购获得;所述水解蛋白是指以酵母蛋白为原料进行蛋白酶的水解后获得的产物,可以通过商购获得。Wherein, the clove composite essential oil refers to a product obtained by extracting a plant such as clove as a raw material, and can be obtained by a commercially available product; the hydrolyzed protein is a product obtained by hydrolyzing a protease using a yeast protein as a raw material, and can pass the product. Commercially available.
根据本发明的一种优选实施方式,所述胶状组合物可以是涂布剂,即,可以将本发明的胶状组合物涂刷于固体表面,即形成能够诱捕昆虫的诱捕点。According to a preferred embodiment of the present invention, the gel composition may be a coating agent, i.e., the gel composition of the present invention may be applied to a solid surface, i.e., to form a trapping point capable of trapping insects.
由于黄色能够对昆虫产生引诱作用,因此优选地,本发明的胶状组合物中可以选择性地掺入黄色色素。所述黄色色素可选自能够使制剂染色的所有常用黄色色素。同样地,用于活性成分的合适的黄色是本领域已知的。所述黄色色素包括但不限于皂黃(Metanil yellow G)、活性嫩黄K-6G(Reactive yellow K-6G)和黄色色素2G中的至少一种。Since yellow can attract an insect, it is preferred that a yellow pigment can be selectively incorporated into the gel composition of the present invention. The yellow pigment may be selected from all common yellow pigments that are capable of dyeing the formulation. Likewise, suitable yellows for the active ingredients are known in the art. The yellow pigment includes, but is not limited to, at least one of Metanil yellow G, Reactive yellow K-6G, and Yellow Pigment 2G.
进一步优选地,为了使得所述黄色色素分散均匀,本发明的胶状组合物中可以选择性地掺入非极性溶剂和乳化剂。优选地,所述黄色色素溶于非极性溶剂中,再加入乳化剂,最后再与胶装组合物互溶。所述非极性溶剂可选自能够使所用活性化合物溶解的所有常用非极性溶剂。同样地,合适的非极性溶剂是本领域已知的。可以提及的非极性溶剂的实例包括氯仿、苯、液状石蜡、植物油、乙醚、乙酸乙酯等。在一种优选实施方式中,所述非极性溶 剂为乙酸乙酯。所述乳化剂包括但不限于卵磷脂、甘油单酯、甘油二酯、山梨聚糖单油酸酯、聚氧乙烯脱水山梨醇单油酸酯(吐温80)、山梨聚糖单月桂酸酯、聚环氧乙烷-山梨聚糖单油酸酯、脂肪酸、和山梨聚糖三硬脂酸中的至少一种。在一种优选实施方式中,乳化剂吐温80包含在制剂中。其中,黄色色素与非极性溶剂的重量比可以为1:(8-12)。其中,黄色色素与乳化剂的重量比可以为1:(1-3)。黄色色素的用量使得所述胶状组合物中,黄色色素的含量为0.2-0.8重量%。Further preferably, in order to make the yellow pigment dispersion uniform, a non-polar solvent and an emulsifier may be selectively incorporated in the gel composition of the present invention. Preferably, the yellow pigment is dissolved in a non-polar solvent, an emulsifier is added, and finally miscible with the gel composition. The non-polar solvent may be selected from all common non-polar solvents which are capable of solubilizing the active compound employed. Likewise, suitable non-polar solvents are known in the art. Examples of non-polar solvents which may be mentioned include chloroform, benzene, liquid paraffin, vegetable oil, diethyl ether, ethyl acetate and the like. In a preferred embodiment, the non-polar solution The agent is ethyl acetate. The emulsifiers include, but are not limited to, lecithin, monoglycerides, diglycerides, sorbitan monooleate, polyoxyethylene sorbitan monooleate (Tween 80), sorbitan monolaurate At least one of polyethylene oxide-sorbitan monooleate, fatty acid, and sorbitan tristearic acid. In a preferred embodiment, the emulsifier Tween 80 is included in the formulation. Wherein, the weight ratio of the yellow pigment to the non-polar solvent may be 1: (8-12). Wherein, the weight ratio of the yellow pigment to the emulsifier may be 1: (1-3). The amount of the yellow pigment is such that the content of the yellow pigment in the gel composition is from 0.2 to 0.8% by weight.
在一些实施方式中,还可选择性加入UV阻隔剂和抗氧化剂。可包含的UV阻隔剂实例包括但不限于β-胡萝卜素和/或对-氨基苯甲酸。可包含的抗氧化剂包括但不限于丁基羟基茴香醚(BHA)、二丁基羟基甲苯(BHT)和维生素E中的至少一种。In some embodiments, a UV blocker and an antioxidant can also be selectively added. Examples of UV blockers that may be included include, but are not limited to, beta-carotene and/or p-aminobenzoic acid. Antioxidants that may be included include, but are not limited to, at least one of butylated hydroxyanisole (BHA), dibutylhydroxytoluene (BHT), and vitamin E.
其中,本发明的胶状组合物的制备方法没有特别的要求,只要将各组分均匀地混合即可;例如可以将压敏胶溶于溶剂,然后加入诱蝇酮、甲基丁香酚、固相载体,可选地还加入丁香复合精油和/或水解蛋白,再混合均匀。其中,在本发明的胶状组合物还含有黄色色素的情况下,可以将压敏胶溶于溶剂,然后加入诱蝇酮、甲基丁香酚、固相载体,可选地还加入丁香复合精油和/或水解蛋白,再混合均匀,得到混合物A;然后将黃色色素溶于非极性溶剂,再加入乳化剂混合均匀,得到混合物B;接着将混合物A和混合物B混合均匀。Wherein, the preparation method of the gel composition of the present invention is not particularly required as long as the components are uniformly mixed; for example, the pressure sensitive adhesive can be dissolved in a solvent, and then fly ketone, methyl eugenol, and solid are added. The phase carrier, optionally also added to the clove complex oil and/or hydrolyzed protein, is mixed well. Wherein, in the case where the gel composition of the present invention further contains a yellow pigment, the pressure sensitive adhesive may be dissolved in a solvent, and then the fly ketone, the methyl eugenol, the solid phase carrier, and optionally the clove compound oil may be further added. And / or hydrolyzed protein, and then uniformly mixed to obtain a mixture A; then the yellow pigment is dissolved in a non-polar solvent, and then added with an emulsifier and uniformly mixed to obtain a mixture B; then, the mixture A and the mixture B are uniformly mixed.
另一方面,本发明提供了一种引诱昆虫的喷雾剂,所述喷雾剂包括引诱物和推进剂;其中,所述引诱物为如上所述的胶状组合物。In another aspect, the invention provides a spray for attracting insects, the spray comprising an attractant and a propellant; wherein the attractant is a gelled composition as described above.
其中,所述喷雾剂中,所述推进剂的含量可以为30-60重量%,优选为40-50重量%。Wherein, in the spray, the propellant may be included in an amount of 30 to 60% by weight, preferably 40 to 50% by weight.
其中,优选地,所述推进剂包括二甲醚、丙烷和丁烷。所述推进剂中,相对于1重量份的二甲醚,丙烷的含量为0.5-0.7重量份;丁烷的含量为1-2重量份。 Among them, preferably, the propellant includes dimethyl ether, propane and butane. In the propellant, the content of propane is 0.5 to 0.7 part by weight with respect to 1 part by weight of dimethyl ether; and the content of butane is 1 to 2 parts by weight.
其中,如上所述的胶状组合物可以均匀地分散在被压缩的推进剂中,在被压缩的推进剂的推动下,喷雾剂可控地喷涂于物体表面,推进剂挥发,留下如上所述的胶状组合物覆盖于物体表面,形成昆虫诱捕点。Wherein, the gel composition as described above can be uniformly dispersed in the compressed propellant, and under the push of the compressed propellant, the spray is controllably sprayed on the surface of the object, and the propellant is volatilized, leaving the above The gelled composition covers the surface of the object to form an insect trapping point.
另一方面,本发明还提供了一种引诱昆虫的胶带,所述胶带包括带状基体、涂布在所述带状基体的一面的黏附胶体层和涂布在所述带状基体的另一面的引诱胶体层;其中,所述引诱胶体层含有如上所述的胶状组合物。In another aspect, the present invention provides an insect-inducing tape comprising a tape-shaped substrate, an adhesive colloid layer coated on one side of the tape-shaped substrate, and coated on the other side of the tape-shaped substrate An attractant colloid layer; wherein the attractant colloid layer comprises a gelatinous composition as described above.
其中,所述胶带还含有覆盖在所述引诱胶体层上的剥离膜。其中,可以将所述胶带经黏附胶体层粘贴于物体表面,然后剥离所述引诱胶体层上的剥离膜,从而将如上所述的胶状组合物暴露,形成昆虫诱捕点。Wherein, the adhesive tape further comprises a release film covering the layer of the attractant colloid. Wherein, the adhesive tape may be adhered to the surface of the object via the adhesive colloid layer, and then the release film on the attractant colloid layer may be peeled off, thereby exposing the gel composition as described above to form an insect trapping point.
另一方面,本发明还提供了一种降低昆虫危害的方法,其中,该方法包括在农作物种植地中使用如上所述的胶状组合物、如上所述的喷雾剂和如上所述的胶带中的至少一种来诱捕昆虫。In another aspect, the present invention provides a method of reducing insect hazards, wherein the method comprises using a gel composition as described above, a spray as described above, and a tape as described above in a crop planting site. At least one of them to trap insects.
其中,优选地,使用如上所述的胶状组合物、如上所述的喷雾剂和如上所述的胶带中的至少一种在农作物种植地中设置一个或多个诱捕点。其中,诱捕点可以包括固定物体和黏附在所述固定物体上的如上所述的胶状组合物;所述固定物体优选使用废弃物,例如塑料瓶、广告油纸和肥料袋中的至少一种。Among them, preferably, one or more trap points are set in the crop planting land using at least one of the gel composition as described above, the spray as described above, and the tape as described above. Wherein the trapping point may include a fixed object and a gel composition as described above adhered to the fixed object; the fixed object preferably uses at least one of waste such as a plastic bottle, an advertising oil paper, and a fertilizer bag.
更优选地,多个所述诱捕点中,相邻两个诱捕点之间的间距为100-300米。More preferably, among the plurality of trap points, the spacing between two adjacent trap points is 100-300 meters.
其中,所述农作物可以包括柑橘、柚子、柿子、番石榴、龙眼、荔枝、芒果、莲雾、酪梨、人心果、杨桃、枇杷、木瓜、桃李、释迦果、西瓜、洋香瓜、胡瓜、丝瓜、苦瓜、南瓜、冬瓜、蕃茄、榄仁、月橘和无患子中的至少一种。The crops may include citrus, grapefruit, persimmon, guava, longan, lychee, mango, lotus, avocado, sapodilla, carambola, alfalfa, papaya, peach, sacora, watermelon, cantaloupe, courgette, loofah. At least one of bitter gourd, pumpkin, melon, tomato, terminal meringue, moon orange, and sorrel.
其中,尽管本发明的胶状组合物特别适合用于诱捕果蝇,但并不局限于此,事实上,本发明的胶状组合物能够诱捕昆虫可以包括果蝇、黄条叶蚤、蚊虫、苍蝇、蓟马、白粉虱和飞蛾类中的至少一种。 Wherein, although the gel composition of the present invention is particularly suitable for trapping fruit flies, it is not limited thereto. In fact, the gel composition of the present invention can trap insects including fruit flies, yellow leafhoppers, mosquitoes, At least one of flies, thrips, whitefly, and moths.
以下通过实施例进一步详细说明本发明。The invention will now be described in further detail by way of examples.
以下实施例中,如无特别说明,所用的原料均为市售品,具体地:诱蝇酮购自广州升讯公司,商品号为CAS 3572-06-3;甲基丁香酚购自允发化工公司,商品号为93-15-2;乙烯丙烯共聚物购自德渊公司,商品号为303P,重均分子量为20000-50000amu;石油树脂购自深圳吉田公司,商品号为64742-16-1,重均分子量为10000-30000amu;聚丁烯购自韩国大林公司,商品号为PB-2100,重均分子量为30000-60000amu;沸石购自惟信公司,商品号为JMAX,比表面积为30-100m2/g,平均粒径为10-50μm;白炭黑购自惟信公司,商品号为JMAX-2,比表面积为130m2/g,平均粒径为16nm;丁香复合精油购自顶韵公司,商品号为HC016;水解蛋白购自磐升股份有限公司,商品号为PB Gelatins。In the following examples, unless otherwise specified, the raw materials used are all commercially available, specifically: cockroach is purchased from Guangzhou Shengxun Company, product number is CAS 3572-06-3; methyl eugenol is purchased from Yunfa Chemical company, commodity number is 93-15-2; ethylene propylene copolymer is purchased from Deyuan Company, product number is 303P, weight average molecular weight is 20,000-50000amu; petroleum resin is purchased from Shenzhen Yoshida Company, product number is 64742-16- 1, the weight average molecular weight is 10000-30000 amu; polybutene is purchased from Dalin Company of Korea, the product number is PB-2100, the weight average molecular weight is 30,000-60000 amu; the zeolite is purchased from Weixin Company, the product number is JMAX, and the specific surface area is 30- 100m 2 /g, average particle size is 10-50μm; white carbon black is purchased from Weixin Company, product number is JMAX-2, specific surface area is 130m 2 /g, average particle size is 16nm; clove compound essential oil is purchased from top rhyme company The product number is HC016; the hydrolyzed protein was purchased from Yusheng Co., Ltd., and the product number is PB Gelatins.
实施例1-8及对比例1Examples 1-8 and Comparative Example 1
参照表1按照如下步骤制备胶状组合物:将压敏胶溶于溶剂正己烷,然后加入诱蝇酮、甲基丁香酚、固相载体,可选地还加入丁香复合精油和/或水解蛋白,再混合均匀,得到混合物A;将黃色色素(黃色色素2G)溶于非极性溶剂(乙酸乙酯),再加入乳化剂(Tween-80),得到混合物B,其中,黄色色素与非极性溶剂和乳化剂的重量比为1:10:2;将混合物A和混合物B按照10:1的重量比混合均匀,得到胶状组合物;EB表示乙烯丁烯共聚物,HR表示石油树脂,PB表示聚丁烯10;NH表示正己烷;X表示对比例1。Referring to Table 1, a gelatinous composition was prepared according to the following steps: the pressure sensitive adhesive was dissolved in a solvent of n-hexane, and then a fly ketone, a methyl eugenol, a solid phase carrier, optionally a clove complex oil and/or a hydrolyzed protein were further added. And mixing evenly to obtain a mixture A; dissolving the yellow pigment (yellow pigment 2G) in a non-polar solvent (ethyl acetate), and then adding an emulsifier (Tween-80) to obtain a mixture B, wherein the yellow pigment and the non-polar The weight ratio of the solvent to the emulsifier is 1:10:2; the mixture A and the mixture B are uniformly mixed in a weight ratio of 10:1 to obtain a gel composition; EB represents an ethylene butene copolymer, and HR represents a petroleum resin. PB represents polybutene 10; NH represents n-hexane; and X represents Comparative Example 1.
表1Table 1
Figure PCTCN2016102789-appb-000003
Figure PCTCN2016102789-appb-000003
Figure PCTCN2016102789-appb-000004
Figure PCTCN2016102789-appb-000004
测试实施例1Test Example 1
在加压条件下,将实施例1-8和对比例1的产品分别与等重量的推进剂(重量比为3:2:5的二甲醚、丙烷和丁烷混合物)混合均匀,装入喷雾罐中,得到各自的喷雾剂。The products of Examples 1-8 and Comparative Example 1 were separately mixed with an equal weight of propellant (a mixture of dimethyl ether, propane and butane in a weight ratio of 3:2:5) under pressure, and charged. In the spray can, the respective sprays were obtained.
在发生瓜实蝇和果实蝇虫害的柑橘种植地中,在柑橘结实期,划定彼此间隔1000米以上的10块测试柑橘园,在其中9块测试柑橘园中以200m的间距使用不同的喷雾剂设置诱捕点,以作为实验组,剩余的1块测试柑橘园中不设置诱捕点,作为对照组。其中,每个诱捕点上设置一个固定物体(1.5L的可口可乐塑料瓶),在固定物体上使用上述喷雾剂均匀喷涂一次,即得到诱捕点,设置诱捕点后每隔14天测定带有虫害的果实数占总果实数的比例(危害率),结果如表2所示。In the citrus planting where cucurbit flies and fruit fly pests occur, in the citrus fruiting period, 10 test citrus orchards separated by more than 1000 m are delineated, and different sprays are used at intervals of 200 m in 9 test citrus orchards. The trapping point was set as the experimental group, and the trapping point was not set in the remaining one test citrus orchard as a control group. Among them, a fixed object (1.5L Coca-Cola plastic bottle) is set on each trapping point, and the spraying agent is evenly sprayed once on the fixed object to obtain the trapping point. The trapping point is determined every 14 days after the trapping point is set. The ratio of the number of fruits to the total number of fruits (hazard rate) is shown in Table 2.
表2Table 2
Figure PCTCN2016102789-appb-000005
Figure PCTCN2016102789-appb-000005
根据表2的数据可见,实施例1-8与对比相比,能够在较长的周期内大大降低瓜实蝇和果实蝇的危害率。并且,在优选相对于1重量份的诱蝇酮, 甲基丁香酚的含量为0.5-5重量份,压敏胶的含量为1-10重量份,固相载体的含量为0.4-4重量份,溶剂的含量为1-10重量份的情况下,本发明的胶状组合物能够进一步降低瓜实蝇和果实蝇的危害率。According to the data of Table 2, Examples 1-8 can greatly reduce the hazard rate of the fruit fly and the fruit fly in a longer period than the comparison. Also, preferably, relative to 1 part by weight of the ketidone, The content of the methyl eugenol is 0.5 to 5 parts by weight, the content of the pressure sensitive adhesive is 1-10 parts by weight, the content of the solid phase carrier is 0.4 to 4 parts by weight, and the content of the solvent is 1-10 parts by weight. The gel composition of the present invention can further reduce the hazard rate of the fruit fly and the fruit fly.
以上详细描述了本发明的优选实施方式,但是,本发明并不限于上述实施方式中的具体细节,在本发明的技术构思范围内,可以对本发明的技术方案进行多种简单变型,这些简单变型均属于本发明的保护范围。The preferred embodiments of the present invention have been described in detail above, but the present invention is not limited to the specific details of the above embodiments, and various simple modifications can be made to the technical solutions of the present invention within the scope of the technical idea of the present invention. These simple variants All fall within the scope of protection of the present invention.
另外需要说明的是,在上述具体实施方式中所描述的各个具体技术特征,在不矛盾的情况下,可以通过任何合适的方式进行组合,为了避免不必要的重复,本发明对各种可能的组合方式不再另行说明。It should be further noted that the specific technical features described in the above specific embodiments may be combined in any suitable manner without contradiction. To avoid unnecessary repetition, the present invention has various possibilities. The combination method will not be described separately.
此外,本发明的各种不同的实施方式之间也可以进行任意组合,只要其不违背本发明的思想,其同样应当视为本发明所公开的内容。 In addition, any combination of various embodiments of the invention may be made as long as it does not deviate from the idea of the invention, and it should be regarded as the disclosure of the invention.

Claims (17)

  1. 一种引诱昆虫的胶状组合物,该胶状组合物含有诱蝇酮和甲基丁香酚,其特征在于,该胶状组合物还含有压敏胶、固相载体和溶剂。A gel-like composition for attracting insects, the gel composition comprising a fly ketone and a methyl eugenol, characterized in that the gel composition further comprises a pressure sensitive adhesive, a solid phase carrier and a solvent.
  2. 根据权利要求1所述的胶状组合物,其中,该胶状组合物中,相对于1重量份的诱蝇酮,甲基丁香酚的含量为0.1-20重量份,压敏胶的含量为0.25-25重量份,固相载体的含量为0.05-10重量份,溶剂的含量为0.25-25重量份。The gel composition according to claim 1, wherein the gel composition has a methyl eugenol content of 0.1 to 20 parts by weight based on 1 part by weight of the ketamine, and the pressure sensitive adhesive is contained in an amount of 0.1 to 20 parts by weight. 0.25 to 25 parts by weight, the solid phase carrier is contained in an amount of 0.05 to 10 parts by weight, and the solvent is contained in an amount of 0.25 to 25 parts by weight.
  3. 根据权利要求2所述的胶状组合物,其中,该胶状组合物中,相对于1重量份的诱蝇酮,甲基丁香酚的含量为0.5-5重量份,压敏胶的含量为1-10重量份,固相载体的含量为0.4-4重量份,溶剂的含量为1-10重量份。The gel composition according to claim 2, wherein the gel composition has a methyl eugenol content of 0.5 to 5 parts by weight based on 1 part by weight of the ketamine, and the pressure sensitive adhesive is contained in an amount of 0.5 to 5 parts by weight. The content of the solid phase carrier is from 0.4 to 4 parts by weight, and the solvent is contained in an amount of from 1 to 10 parts by weight, based on 1 to 10 parts by weight.
  4. 根据权利要求1-3中任意一项所述的胶状组合物,其中,所述压敏胶包括乙烯丙烯共聚物、石油树脂和聚丁烯中的至少一种;所述固相载体包括沸石、白炭黑和活性炭中的至少一种;所述溶剂包括正己烷、环己烷和正辛烷中的至少一种。The gel composition according to any one of claims 1 to 3, wherein the pressure sensitive adhesive comprises at least one of an ethylene propylene copolymer, a petroleum resin, and a polybutene; the solid phase carrier comprises a zeolite At least one of white carbon black and activated carbon; the solvent comprising at least one of n-hexane, cyclohexane, and n-octane.
  5. 根据权利要求4所述的胶状组合物,其中,所述压敏胶的重均分子量为300-3000;所述沸石的比表面积为10-200m2/g,平均粒径10-50μm;所述白炭黑的比表面积为100-200m2/g,平均粒径为10-25nm。The gel composition according to claim 4, wherein the pressure sensitive adhesive has a weight average molecular weight of 300 to 3000; the zeolite has a specific surface area of 10 to 200 m 2 /g, and an average particle diameter of 10 to 50 μm; The white carbon has a specific surface area of 100 to 200 m 2 /g and an average particle diameter of 10 to 25 nm.
  6. 根据权利要求1-3和5中任意一项所述的胶状组合物,其中,所述胶状组合物还含有丁香复合精油和/或水解蛋白。The gel composition according to any one of claims 1 to 3, wherein the gel composition further contains a clove complex oil and/or a hydrolyzed protein.
  7. 根据权利要求6所述的胶状组合物,其中,所述胶状组合物中,相 对于1重量份的诱蝇酮,丁香复合精油的含量为0.05-20重量份,水解蛋白的含量为0.05-10重量份。The gel composition according to claim 6, wherein the gel composition has a phase The clown complex essential oil is contained in an amount of 0.05 to 20 parts by weight, and the hydrolyzed protein is contained in an amount of 0.05 to 10 parts by weight based on 1 part by weight of the fly ketone.
  8. 根据权利要求1-3、5和7中任意一项所述的胶状组合物,其中,所述胶状组合物还含有黄色色素。The gel composition according to any one of claims 1-3, 5 and 7, wherein the gel composition further contains a yellow pigment.
  9. 一种引诱昆虫的喷雾剂,所述喷雾剂包括引诱物和推进剂;其特征在于,所述引诱物为权利要求1-8中任意一项所述的胶状组合物。A spray for attracting insects, the spray comprising an attractant and a propellant; wherein the attractant is the gel composition of any one of claims 1-8.
  10. 根据权利要求9所述的喷雾剂,其中,所述喷雾剂中,所述推进剂的含量为30-60重量%。The spray according to claim 9, wherein the propellant is contained in an amount of from 30 to 60% by weight.
  11. 根据权利要求9或10所述的喷雾剂,其中,所述推进剂包括二甲醚、丙烷和丁烷;所述推进剂中,相对于1重量份的二甲醚,丙烷的含量为0.5-0.7重量份;丁烷的含量为1-2重量份。The spray according to claim 9 or 10, wherein the propellant comprises dimethyl ether, propane and butane; and the propellant has a propane content of 0.5 based on 1 part by weight of dimethyl ether. 0.7 parts by weight; the content of butane is 1-2 parts by weight.
  12. 一种引诱昆虫的胶带,所述胶带包括带状基体、涂布在所述带状基体的一面的黏附胶体层和涂布在所述带状基体的另一面的引诱胶体层;其特征在于,所述引诱胶体层含有权利要求1-8中任意一项所述的胶状组合物。An insect-inducing tape comprising a tape-shaped substrate, an adhesive colloid layer coated on one side of the tape-shaped substrate, and an attractant colloid layer coated on the other side of the tape-shaped substrate; The attractant colloid layer contains the gel composition of any one of claims 1-8.
  13. 根据权利要求12的胶带,其中,所述胶带还含有覆盖在所述引诱胶体层上的剥离膜。The adhesive tape according to claim 12, wherein said adhesive tape further comprises a release film covering said layer of the attractant colloid.
  14. 一种降低昆虫危害的方法,其特征在于,该方法包括在农作物种植地中使用权利要求1-8中任意一项所述的胶状组合物、权利要求9-11中任意一项所述的喷雾剂和权利要求12-13中任意一项所述的胶带中的至少一种来诱捕昆虫。 A method for reducing the hazard of an insect, the method comprising the use of the gel composition according to any one of claims 1 to 8 in the crop planting, the method according to any one of claims 9-11 The spray and at least one of the tapes of any of claims 12-13 are used to trap insects.
  15. 根据权利要求14所述的方法,其中,使用权利要求1-8中任意一项所述的胶状组合物、权利要求9-11中任意一项所述的喷雾剂和权利要求12-13中任意一项所述的胶带中的至少一种在农作物种植地中设置一个或多个诱捕点。The method according to claim 14, wherein the gel composition according to any one of claims 1 to 8, the spray according to any one of claims 9 to 11 and the claims 12-13 At least one of the tapes of any of the preceding articles provides one or more trapping points in the crop planting site.
  16. 根据权利要求15所述的方法,其中,多个所述诱捕点中,相邻两个诱捕点之间的间距为100-300米。The method of claim 15 wherein a spacing between adjacent two trapping points of said plurality of trapping points is between 100 and 300 meters.
  17. 根据权利要求14-16中任意一项所述的方法,其中,所述农作物包括柑橘、柚子、柿子、番石榴、龙眼、荔枝、芒果、莲雾、酪梨、人心果、杨桃、枇杷、木瓜、桃李、释迦果、西瓜、洋香瓜、胡瓜、丝瓜、苦瓜、南瓜、冬瓜、蕃茄、榄仁、月橘和无患子中的至少一种;所述昆虫包括瓜实蝇、果实蝇、黄条叶蚤、蚊虫、苍蝇、蓟马、白粉虱和飞蛾中的至少一种。 The method according to any one of claims 14-16, wherein the crop comprises citrus, grapefruit, persimmon, guava, longan, lychee, mango, lotus, avocado, sapodilla, carambola, alfalfa, papaya At least one of peach, plum, custard, watermelon, cantaloupe, courgette, loofah, bitter gourd, pumpkin, melon, tomato, terminal meringue, moon orange, and sorrel; the insect includes cucurbit fly, fruit fly, yellow At least one of spider mites, mosquitoes, flies, thrips, whitefly, and moths.
PCT/CN2016/102789 2015-12-30 2016-10-21 Gel composition, spray, and tape for attracting insects, and method of reducing insect pest damage WO2017113945A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201511019340.XA CN106922665A (en) 2015-12-30 2015-12-30 A kind of method lured the jelly composition and spray and adhesive tape of insect and reduce insect infestations
CN201511019340.X 2015-12-30

Publications (1)

Publication Number Publication Date
WO2017113945A1 true WO2017113945A1 (en) 2017-07-06

Family

ID=59224425

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2016/102789 WO2017113945A1 (en) 2015-12-30 2016-10-21 Gel composition, spray, and tape for attracting insects, and method of reducing insect pest damage

Country Status (2)

Country Link
CN (1) CN106922665A (en)
WO (1) WO2017113945A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107787835A (en) * 2017-10-26 2018-03-13 田东县八闽农业综合开发有限公司 A kind of method for luring honeybee to pollinate during the mango florescence
AU2018317246B2 (en) * 2017-08-15 2020-07-09 Institute of Zoology, Guangdong Academy of Sciences Agent capable of effectively repelling female imagoes of bactrocera minax and use thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109793011A (en) * 2018-12-29 2019-05-24 广州瑞丰生物科技有限公司 A kind of longicorn attractant and preparation method
CN112674087A (en) * 2021-01-06 2021-04-20 柳州市惠农化工有限公司 Insect-attracting composition, preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1997276A (en) * 2004-03-11 2007-07-11 巴伦西亚理工大学 Food bait comprising a specific attractant for combating tephritid insects
CN101703043A (en) * 2009-11-10 2010-05-12 杜进平 Preparation method of sexual attraction slow-release formulation for fruit flies
CN104349677A (en) * 2012-05-14 2015-02-11 陶氏益农公司 Insect attractant formulations and insect control

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4680574B2 (en) * 2004-11-17 2011-05-11 大日本除蟲菊株式会社 Gel-like flying insect attractant composition
BRPI0718585A2 (en) * 2006-11-07 2014-03-11 Dow Agrosciences Llc FORMULATION OF MALE ANTIQUILATION (MAT) TECHNIQUE, CONTROLLED, SPRAYABLE RELEASE AND INSECT CONTROL METHOD
CN101044850B (en) * 2007-04-30 2010-05-19 厦门大学 Insects adherbing glue used specially for tea-tree garden, and its preparing method
CN101328394A (en) * 2008-07-23 2008-12-24 东北师范大学 Preparation of insect sticker for agriculture and forestry
CN202059910U (en) * 2011-03-18 2011-12-07 北京中捷四方生物科技有限公司 Trap device for preventing ephestia and plodia

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1997276A (en) * 2004-03-11 2007-07-11 巴伦西亚理工大学 Food bait comprising a specific attractant for combating tephritid insects
CN101703043A (en) * 2009-11-10 2010-05-12 杜进平 Preparation method of sexual attraction slow-release formulation for fruit flies
CN104349677A (en) * 2012-05-14 2015-02-11 陶氏益农公司 Insect attractant formulations and insect control

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
GUO, XIAOHUI: "Preparation of Novel Environment-Friendly Sticky Insect Glue", MASTER'S DISSERTATION OF NORTHEAST NORMAL UNIVERSITY, 1 May 2011 (2011-05-01), pages 18,19,28 *
LI, YUEHONG ET AL.: "Analysis on Trapping and Killing of Different Attractants like ''So Sticky'' on Citrus Fruit Flies", SOUTH CHINA FRUITS, vol. 40, 20 July 2011 (2011-07-20) *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2018317246B2 (en) * 2017-08-15 2020-07-09 Institute of Zoology, Guangdong Academy of Sciences Agent capable of effectively repelling female imagoes of bactrocera minax and use thereof
CN107787835A (en) * 2017-10-26 2018-03-13 田东县八闽农业综合开发有限公司 A kind of method for luring honeybee to pollinate during the mango florescence

Also Published As

Publication number Publication date
CN106922665A (en) 2017-07-07

Similar Documents

Publication Publication Date Title
US20200329716A1 (en) Insect control formulations
WO2017113945A1 (en) Gel composition, spray, and tape for attracting insects, and method of reducing insect pest damage
CN103548826B (en) Citrus fruit fly sex attraction agent and its preparation method and application
US20070065476A1 (en) Pest control agent carrier
CN105994213A (en) Insect trapping device and insect trapping method
CN106973897B (en) Viscose for trapping and killing fruit flies and preparation method thereof
CN107494536B (en) Medicament capable of effectively repelling female bactrocera minax imagoes and application thereof
CN108575992A (en) Glue spraying type attracting pests agent
EP3310164B1 (en) Method and system for attracting lepidopterous insects
CN102653669A (en) Preparation and using method of pest-killing and pest-sticking glue
KR101468450B1 (en) Non woven fabric-type pheromone dispenser for controlling harmful insect and uses thereof
CN106614577B (en) Citrus fruit fly attractant
CN112931539B (en) Rice composite insect-resist agent and preparation method and application thereof
US20120039979A1 (en) Insect control substance that can be applied to a surface
CN108719282B (en) Special attractant for preventing and controlling oriental fruit moth and preventing and controlling method
EP3791723A1 (en) Repulsive composition and associated method
CN105104422A (en) Micro-capsule suspending agent containing fosthiazate and pyraclostrobin
JPH0148242B2 (en)
DK3139742T3 (en) PEST DEPENDENTS AND USE THEREOF
CN110292043B (en) Sex attractant for tuber moth with optimized system and application thereof
CN109315398A (en) A kind of pheromones analogue improving Xestia c nigrum gyplure attractant effect
TWI484911B (en) Lure formulation for flies with reduced active ingredient amount
KR20120072894A (en) Sex pheromone composition for attraction synanthedon bicingulata and manufacturing thereof
CN109258650B (en) Sea-buckthorn fruit fly trapping and killing agent
CN102177879B (en) Method for manufacturing Apriona germari poisoning wood pegs

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16880737

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16880737

Country of ref document: EP

Kind code of ref document: A1