WO2017082356A1 - 長鎖アルキレン基含有エポキシ樹脂組成物 - Google Patents
長鎖アルキレン基含有エポキシ樹脂組成物 Download PDFInfo
- Publication number
- WO2017082356A1 WO2017082356A1 PCT/JP2016/083398 JP2016083398W WO2017082356A1 WO 2017082356 A1 WO2017082356 A1 WO 2017082356A1 JP 2016083398 W JP2016083398 W JP 2016083398W WO 2017082356 A1 WO2017082356 A1 WO 2017082356A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- epoxy resin
- resin composition
- epoxy
- group
- ether
- Prior art date
Links
- 0 CC1(OC1)I(*)N(C(N(C(N1I(C2(*I)OC2)I)=O)I*CC2(*)OC2)=O)C1=O Chemical compound CC1(OC1)I(*)N(C(N(C(N1I(C2(*I)OC2)I)=O)I*CC2(*)OC2)=O)C1=O 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
- C08G59/3236—Heterocylic compounds
- C08G59/3245—Heterocylic compounds containing only nitrogen as a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/32—Epoxy compounds containing three or more epoxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
- C08G59/4064—Curing agents not provided for by the groups C08G59/42 - C08G59/66 sulfur containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/44—Amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/66—Mercaptans
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/06—Triglycidylisocyanurates
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/032—Organic insulating material consisting of one material
- H05K1/0326—Organic insulating material consisting of one material containing O
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
Definitions
- the present invention relates to a long-chain alkylene group-containing epoxy resin composition.
- an epoxy resin is an epoxy resin composition combined with a curing agent or a curing catalyst, such as an adhesive, a high refractive index layer of an antireflection film (such as an antireflection film for a liquid crystal display), or an optical thin film (such as a reflection plate). It is widely used in the field of electronic materials such as encapsulants for electronic components, printed wiring boards, and interlayer insulating film materials (such as interlayer insulating film materials for build-up printed boards).
- an epoxy compound In order to obtain reliability such as heat resistance and light resistance required for such an electronic material, an epoxy compound needs a tough molecular skeleton.
- a compound having a rigid molecular skeleton and a high interaction between molecules tends to be a solid or a highly viscous liquid.
- the epoxy resin composition using an epoxy compound having a rigid molecular skeleton has a problem that the viscosity increases and the handling property is poor.
- a resin layer made of an epoxy resin or the like is coated on a fine concavo-convex structure formed by lithography or nanoimprint.
- the liquid viscosity of the epoxy resin composition to be used is high, the resin composition cannot embed a fine concavo-convex structure when applied, which adversely affects subsequent processes.
- the cured epoxy resin generally has a high polarity, and it has been difficult to achieve a sufficiently low dielectric constant.
- an epoxy compound having an isocyanuric acid skeleton has been known as a liquid epoxy compound from which an epoxy resin cured product having high heat resistance, high transparency and the like can be obtained (for example, Patent Document 1).
- Patent Document 1 an epoxy compound having an isocyanuric acid skeleton has been known as a liquid epoxy compound from which an epoxy resin cured product having high heat resistance, high transparency and the like can be obtained.
- Patent Document 2 an epoxy compound having an isocyanuric acid skeleton having high heat resistance, high transparency and the like can be obtained.
- a hollow particle is added to the epoxy resin composition, and the cured product obtained from the composition contains an air layer to lower the dielectric constant of the cured product.
- the method of making it known is known (for example, patent document 2).
- the epoxy compound used in Patent Document 1 is in a liquid state but has a viscosity of about 8,000 mPa ⁇ s. In consideration of the accuracy and workability required in the field of thin film formation and microfabrication in recent years, It cannot be said that the viscosity is sufficiently low.
- the present invention has a low viscosity and a low dielectric constant. Further, when added to a general-purpose epoxy resin composition, the viscosity of the composition is reduced and the epoxy resin cured product obtained from the composition has a sufficiently low dielectric constant. It is an object of the present invention to provide an epoxy resin composition containing an epoxy compound that can be converted into an epoxy resin.
- an epoxy compound having a specific structure is a liquid compound having a very low viscosity among the conventional liquid epoxy compounds, Moreover, it discovered that the hardened
- this invention relates to the epoxy resin composition containing the epoxy component which contains (a) the epoxy compound represented by Formula [1] at least as a 1st viewpoint, and (b) a hardening
- R 1 to R 3 each independently represent a hydrogen atom or a methyl group
- L 1 to L 3 each independently represent a pentamethylene group, a hexamethylene group, or a heptamethylene group.
- the present invention relates to the epoxy resin composition according to the first aspect, wherein R 1 to R 3 are hydrogen atoms.
- the (b) curing agent is at least one selected from the group consisting of acid anhydrides, amines, phenol resins, polyamide resins, imidazoles, and polymercaptans. It relates to the epoxy resin composition described.
- curing agent is related with the epoxy resin composition as described in a 3rd viewpoint which is an acid anhydride.
- any one of the first to fourth aspects includes 0.5 to 1.5 equivalents of the (b) curing agent with respect to 1 equivalent of the epoxy group of the (a) epoxy component. It relates to the epoxy resin composition according to item.
- the present invention relates to a metal wiring coating composition comprising the epoxy resin composition according to any one of the first aspect to the fifth aspect.
- the present invention relates to a cured product of the epoxy resin composition according to any one of the first aspect to the fifth aspect.
- the invention relates to a wiring board including the cured product of the epoxy resin composition according to any one of the first aspect to the fifth aspect, and a metal wiring, wherein the cured product and the metal wiring are in contact with each other. .
- the epoxy compound used in the present invention has a low viscosity because the bond part between the isocyanuric acid skeleton and the epoxy group is a linear alkylene group having 5 to 7 carbon atoms, and the epoxy compound is cured with A cured product having a low dielectric constant can be obtained from an epoxy resin composition containing an agent or a curing catalyst. Moreover, since the epoxy compound used by this invention reacts with the acid or base which generate
- the epoxy resin composition of the present invention includes (a) an epoxy component containing at least an epoxy compound represented by the formula [1], and (b) a curing agent.
- the epoxy component used in the present invention contains at least an epoxy compound represented by the following formula [1].
- R 1 to R 3 each independently represent a hydrogen atom or a methyl group
- L 1 to L 3 each independently represent a pentamethylene group, a hexamethylene group, or a heptamethylene group.
- R 1 to R 3 are preferably hydrogen atoms, and it is more preferable that R 1 to R 3 are all hydrogen atoms.
- L 1 to L 3 are preferably hexamethylene groups, and L 1 to L 3 are more preferably hexamethylene groups. Among them, it is preferable that R 1 to R 3 are all hydrogen atoms and L 1 to L 3 are all hexamethylene groups.
- the compound represented by the above formula [1] is conventionally known from, for example, an olefin compound having isocyanuric acid and a leaving group X (for example, International Publication No. 2010/092947 pamphlet, Japanese Patent Application Laid-Open No. 2012-25688). It can be produced by the method for synthesizing epoxides described in the publications and the like. Specifically, after reacting isocyanuric acid and an olefin compound represented by CH 2 ⁇ CR 1 -L 1 -X to produce a compound (intermediate) having an unsaturated bond, the compound (intermediate) ) And a peroxide can be reacted to produce an epoxy compound represented by the above formula [1].
- an olefin compound having isocyanuric acid and a leaving group X for example, International Publication No. 2010/092947 pamphlet, Japanese Patent Application Laid-Open No. 2012-25688. It can be produced by the method for synthesizing ep
- the leaving group X is not particularly limited as long as it is a group that reacts with the NH group of isocyanuric acid, but is not limited to hydroxy group, methanesulfonyloxy group, trifluoromethanesulfonyloxy group, toluenesulfonyloxy group, nitrobenzenesulfonyloxy group. , Acetoxy group, trifluoroacetoxy group, halogen atom and the like.
- R 1 , L 1 and X represent the same meaning as described above.
- the epoxy compound represented by the above formula [1] and other epoxy compounds can be used in combination.
- the epoxy compound represented by the above formula [1] and the other epoxy compounds can be used in a molar ratio of epoxy groups in the range of 1: 0 to 1:20.
- an epoxy compound other than the epoxy compound represented by the formula [1] various polyfunctional epoxy compounds that are commercially available can be used without any particular limitation.
- Examples of the epoxy compound that can be used in the present invention include 1,4-butanediol diglycidyl ether, 1,6-hexanediol diglycidyl ether, (poly) ethylene glycol diglycidyl ether, (poly) propylene glycol diglycidyl ether, Trimethylolethane triglycidyl ether, trimethylolpropane triglycidyl ether, 1,4-cyclohexanedimethanol diglycidyl ether, 1,2-epoxy-4- (epoxyethyl) cyclohexane, glycerol triglycidyl ether, diglycerol polyglycidyl ether, 2,6-diglycidylphenyl glycidyl ether, 1,1,3-tris (4-glycidyloxyphenyl) propane, diglycidyl 1,2-cyclohexanedicarboxylate, 4, '-Methylene
- the following commercial item can be mentioned as an example of the said epoxy compound.
- the solid epoxy compound include TEPIC (registered trademark) -G, S, L, and HP [all manufactured by Nissan Chemical Industries, Ltd.].
- Liquid epoxy compounds include TEPIC (registered trademark) -PAS B22, PAS B26, PAS B26L, VL, UC [all manufactured by Nissan Chemical Industries, Ltd.], jER (registered trademark) 828, and the like. 807, YX8000 [all manufactured by Mitsubishi Chemical Corporation], Guatemala Resin (registered trademark) DME100 [manufactured by Shin Nippon Rika Co., Ltd.], Celoxide 2021P [manufactured by Daicel Corporation], and the like.
- an acid anhydride, an amine, a phenol resin, a polyamide resin, an imidazole, or a polymercaptan can be used as the curing agent used in the present invention.
- acid anhydrides and amines are particularly preferable.
- curing agents are solid, they can be used by melt
- the curing agent itself is preferably liquid at normal temperature and normal pressure.
- the curing agent can be contained in a proportion of 0.5 to 1.5 equivalents, preferably 0.8 to 1.2 equivalents, relative to 1 equivalent of epoxy group of the epoxy component.
- the equivalent of the curing agent to the epoxy component is indicated by an equivalent ratio of the curable group of the curing agent to the epoxy group.
- the equivalent with respect to the epoxy group of these all epoxy compounds becomes the said range.
- the acid anhydride is preferably an anhydride of a compound having a plurality of carboxyl groups in one molecule.
- these acid anhydrides include phthalic anhydride, trimellitic anhydride, pyromellitic anhydride, benzophenone tetracarboxylic anhydride, ethylene glycol bistrimellitate, glycerol tris trimellitate, maleic anhydride, 1,2, 3,6-tetrahydrophthalic anhydride (tetrahydrophthalic anhydride), 4-methyl-1,2,3,6-tetrahydrophthalic anhydride (methyltetrahydrophthalic anhydride), 3,6-endomethylene-1,2, 3,6-tetrahydrophthalic anhydride (endomethylenetetrahydrophthalic anhydride), 4-methyl-3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride (methylendomethylenetetrahydrophthalic anhydride, 5 -Methylnorborna-5-
- 4-methyl-1,2,3,6-tetrahydrophthalic anhydride (methyltetrahydrophthalic anhydride), 4-methyl-3,6-endomethylene-1,2, which are liquid at normal temperature and normal pressure 3,6-tetrahydrophthalic anhydride (methylendomethylenetetrahydrophthalic anhydride, 5-methylnorborna-5-ene-2,3-dicarboxylic acid anhydride, methylnadic acid anhydride, methylhymic anhydride), 5-methyl Bicyclo [2.2.1] heptane-2,3-dicarboxylic acid anhydride (hydrogenated methylnadic acid anhydride), 3- (2-methylbut-2-en-1-yl) -1,2,3 6-tetrahydrophthalic anhydride (methylbutenyltetrahydrophthalic anhydride), dodecenyl succinic anhydride, 4-methylhexahydrophthalic anhydride (methylhexahydro Water phthalate), a mixture
- amines examples include piperidine, N, N-dimethylpiperazine, triethylenediamine, 2,4,6-tris (dimethylaminomethyl) phenol, benzyldimethylamine, 2- (dimethylaminomethyl) phenol, diethylenetriamine, and triethylenetetramine.
- liquid diethylenetriamine, triethylenetetramine, tetraethylenepentamine, diethylaminopropylamine, N-aminoethylpiperazine, di (1-methyl-2-aminocyclohexyl) methane, menthanediamine, isophoronediamine, diaminodicyclohexylmethane Etc. can be preferably used.
- phenol resin examples include phenol novolac resin and cresol novolac resin.
- the polyamide resin is produced by condensation of dimer acid and polyamine, and is a polyamide amine having a primary amine and a secondary amine in the molecule.
- imidazoles examples include 2-methylimidazole, 2-ethyl-4-methylimidazole, 1-cyanoethyl-2-undecylimidazolium trimellitate, epoxy imidazole adduct, and the like.
- Polymercaptan is, for example, one having a mercaptan group at the end of a polypropylene glycol chain or one having a mercaptan group at the end of a polyethylene glycol chain, and is preferably in a liquid form.
- a hardening accelerator (it is also mentioned a hardening adjuvant) may be used together suitably.
- Curing accelerators include organophosphorus compounds such as triphenylphosphine and tributylphosphine; quaternary phosphonium salts such as ethyltriphenylphosphonium bromide and tetrabutylphosphonium O, O-diethylphosphorodithioate; 1,8-diazabicyclo [ 5.4.0] Undec-7-ene, 1,8-diazabicyclo [5.4.0] undec-7-ene and octyl acid, quaternary ammonium such as zinc octylate, tetrabutylammonium bromide Examples include salt.
- imidazoles such as 2-methylimidazole and 2-ethyl-4-methylimidazole mentioned above as curing agents
- amines such as 2,4,6-tris (dimethylaminomethyl) phenol and benzyldimethylamine are also included. It can be used as a curing accelerator for these types of curing agents.
- These curing accelerators can be used at a ratio of 0.001 to 0.1 parts by mass with respect to 1 part by mass of the curing agent.
- the epoxy resin composition of the present invention may contain (c) a curing catalyst instead of (b) the curing agent or in addition to (b) the curing agent.
- the curing catalyst comprises (c1) an acid generator and / or (c2) a base generator.
- a photoacid generator or a thermal acid generator can be used as the acid generator.
- the photo acid generator or thermal acid generator is not particularly limited as long as it generates an acid (Lewis acid or Bronsted acid) directly or indirectly by light irradiation or heating.
- the epoxy resin composition containing the thermal acid generator can be cured in a short time by heating. Moreover, since the epoxy resin composition which mix
- the photoacid generator include onium salts such as iodonium salts, sulfonium salts, phosphonium salts, selenium salts, metallocene complex compounds, iron arene complex compounds, disulfone compounds, sulfonic acid derivative compounds, triazine compounds, acetophenone derivatives. Compounds, diazomethane compounds, and the like.
- iodonium salt examples include diphenyliodonium, 4,4′-dichlorodiphenyliodonium, 4,4′-dimethoxydiphenyliodonium, 4,4′-di-tert-butyldiphenyliodonium, 4-methylphenyl (4- ( 2-methylpropyl) phenyl) iodonium, 3,3′-dinitrophenyliodonium, 4- (1-ethoxycarbonylethoxy) phenyl (2,4,6-trimethylphenyl) iodonium, 4-methoxyphenyl (phenyl) iodonium, etc.
- Iodonium chloride, bromide, mesylate, tosylate, trifluoromethanesulfonate, tetrafluoroborate, tetrakis (pentafluorophenyl) borate, hexafluorophosphate, hexafluoroarsene DOO, diaryliodonium salts such as hexafluoroantimonate, and the like.
- sulfonium salt examples include triphenylsulfonium, diphenyl (4-tert-butylphenyl) sulfonium, tris (4-tert-butylphenyl) sulfonium, diphenyl (4-methoxyphenyl) sulfonium, tris (4-methylphenyl) Sulfonium chloride, bromide, sulfonium such as sulfonium, tris (4-methoxyphenyl) sulfonium, tris (4-ethoxyphenyl) sulfonium, diphenyl (4- (phenylthio) phenyl) sulfonium, tris (4- (phenylthio) phenyl) sulfonium, Triarylsulfonium such as trifluoromethanesulfonate, tetrafluoroborate, hexafluorophosphate, hexafluoroarsen
- Examples of the phosphonium salt include chloride, bromide, tetrafluoro of phosphonium such as tetraphenylphosphonium, ethyltriphenylphosphonium, tetra (p-methoxyphenyl) phosphonium, ethyltri (p-methoxyphenyl) phosphonium, benzyltriphenylphosphonium.
- Examples thereof include arylphosphonium salts such as borate, hexafluorophosphate, and hexafluoroantimonate.
- selenium salt examples include triaryl selenium salts such as triphenyl selenium hexafluorophosphate.
- iron arene complex compound examples include bis ( ⁇ 5 -cyclopentadienyl) ( ⁇ 6 -isopropylbenzene) iron (II) hexafluorophosphate.
- photoacid generators can be used alone or in combination of two or more.
- thermal acid generator examples include sulfonium salts and phosphonium salts, and sulfonium salts are preferably used.
- thermal acid generators examples include the compounds mentioned as examples of various onium salts in the above-mentioned photoacid generator. These thermal acid generators can be used alone or in combination of two or more.
- the acid generator (c1) a sulfonium salt compound or an iodonium salt compound is preferable.
- a compound having an anionic species such as hexafluorophosphate or hexafluoroantimonate showing strong acidity is preferable.
- the content of the acid generator (c1) in the epoxy resin composition of the present invention is preferably 0.1 to 20 parts by mass, or 0.1 to 10 parts by mass, more preferably 100 parts by mass of the (a) epoxy component. May be 0.5 to 10 parts by mass.
- the epoxy compound represented by the said Formula [1] and another epoxy compound, content with respect to 100 mass parts of all those epoxy compounds becomes the said range.
- a photobase generator or a thermal base generator can be used as the base generator.
- the photobase acid generator or the heat base generator is not particularly limited as long as it generates a base (Lewis base or Bronsted base) directly or indirectly by light irradiation or heating.
- An epoxy resin composition containing a thermal base generator can be cured in a short time by heating.
- blended the photobase generator hardens
- photobase generators can be used singly or in combination of two or more.
- the photobase generator is available as a commercial product.
- the photobase generator WPBG series WPBG-018, 027, 082, 140, 266, manufactured by Wako Pure Chemical Industries, Ltd. 300
- WPBG-018, 027, 082, 140, 266, manufactured by Wako Pure Chemical Industries, Ltd. 300 can be preferably used.
- thermal base generator examples include carbamates such as 1-methyl-1- (4-biphenylyl) ethyl carbamate and 2-cyano-1,1-dimethylethyl carbamate; urea, N, N-dimethyl-N′— Ureas such as methylurea; guanidines such as guanidine trichloroacetate, guanidine phenylsulfonylacetate and guanidine phenylpropiolate; dihydropyridines such as 1,4-dihydronicotinamide; N- (isopropoxycarbonyl) -2,6-dimethyl Dimethylpiperidines such as piperidine, N- (tert-butoxycarbonyl) -2,6-dimethylpiperidine, N- (benzyloxycarbonyl) -2,6-dimethylpiperidine; tetramethylammonium phenylsulfonylacetate, tetramethylphenylpropiolate Ann
- U-CAT registered trademark
- SA810 SA831, SA841, and SA851 which are salts of 1,8-diazabicyclo [5.4.0] undec-7-ene (DBU) [San Apro Corporation ) Made] and the like.
- DBU 1,8-diazabicyclo [5.4.0] undec-7-ene
- the content of the base generator (c2) in the epoxy resin composition of the present invention is preferably 0.1 to 20 parts by mass, or 0.1 to 10 parts by mass, more preferably 100 parts by mass of the epoxy component (a). May be 0.5 to 10 parts by mass.
- content with respect to 100 mass parts of all those epoxy compounds becomes the said range.
- the epoxy resin composition of the present invention can be obtained by mixing an epoxy component containing at least the epoxy compound represented by the above formula [1], the curing agent, and optionally a curing accelerator. Alternatively, it is obtained by mixing an epoxy component containing at least the epoxy compound represented by the formula [1] and the curing catalyst.
- the mixing is not particularly limited as long as it can be uniformly mixed, but can be performed using, for example, a reaction flask and a stirring blade or a mixer. The mixing is performed under heating as necessary in consideration of the viscosity, and is performed at a temperature of 10 to 100 ° C. for 0.5 to 1 hour.
- the solid content concentration in the epoxy resin composition of the present invention can be 1 to 100% by mass, or 5 to 100% by mass, or 50 to 100% by mass, or 80 to 100% by mass.
- solid content means all components other than the solvent in an epoxy resin composition.
- an epoxy resin composition can be prepared by dissolving a solid curing catalyst in a solvent such as propylene carbonate and then mixing it with a liquid epoxy compound. Even when the curing catalyst is dissolved in the liquid epoxy compound, a general solvent may be added to adjust the viscosity of the resulting epoxy resin composition.
- the obtained epoxy resin composition has an appropriate viscosity for use as a liquid sealing material.
- the epoxy resin composition of the present invention can be adjusted to an arbitrary viscosity, and is used as a transparent sealing material such as an LED by a casting method, a potting method, a dispenser method, a screen printing method, a flexographic printing method, an inkjet printing method, or the like. For this reason, partial sealing can be performed at an arbitrary position.
- the epoxy resin composition is directly mounted in an LED or the like in the liquid state by the above-described method, and then dried and cured to obtain a cured epoxy resin.
- the cured product obtained from the epoxy resin composition is pre-cured at a temperature of 100 to 120 ° C. by applying the epoxy resin composition to a base plate or pouring it onto a casting plate coated with a release agent, and 120 to It is obtained by carrying out main curing (post-curing) at a temperature of 200 ° C.
- the heating time is 1 to 12 hours, for example, about 2 to 5 hours for both preliminary curing and main curing.
- the thickness of the coating film obtained from the epoxy resin composition of the present invention can be selected from the range of about 0.01 ⁇ m to 10 mm depending on the use of the cured product.
- an epoxy component containing at least the epoxy compound represented by the above formula [1] and an epoxy resin composition containing a photoacid generator or a photobase generator are applied onto a substrate and cured by light irradiation. be able to. Moreover, it can also heat before and after light irradiation. Moreover, in this invention, the epoxy component containing at least the epoxy compound represented by the said Formula [1], and the epoxy resin composition containing a thermal acid generator or a thermal base generator are apply
- an epoxy component containing at least an epoxy compound represented by the above formula [1] and an epoxy resin composition containing a thermal acid generator and a photoacid generator or a thermal base generator and a photobase generator on a substrate It can be applied to and cured by light irradiation after heating.
- Examples of the method for applying the epoxy resin composition of the present invention on a substrate include a flow coating method, a spin coating method, a spray coating method, a screen printing method, a flexographic printing method, an ink jet printing method, a casting method, and a bar coating method. , Curtain coating method, roll coating method, gravure coating method, dipping method, slit method and the like.
- the thickness of the coating film formed from the epoxy resin composition of the present invention can be selected from a range of about 0.01 ⁇ m to 10 mm depending on the use of the cured product. For example, when used for a photoresist, 0.05 to 10 ⁇ m. (Especially 0.1 to 5 ⁇ m), about 10 ⁇ m to 5 mm (particularly 100 ⁇ m to 1 mm) when used for a printed wiring board, and 0.1 to 100 ⁇ m (particularly when used for an optical thin film) In particular, it can be about 0.3 to 50 ⁇ m.
- Examples of light to be irradiated or exposed in the case of using a photoacid generator or a photobase generator include gamma rays, X-rays, ultraviolet rays, and visible rays, and usually visible rays or ultraviolet rays, particularly ultraviolet rays are used. There are many cases.
- the wavelength of light is, for example, about 150 to 800 nm, preferably about 150 to 600 nm, more preferably about 200 to 400 nm, and particularly about 300 to 400 nm.
- Irradiation dose may vary depending on the thickness of the coating film, for example, 2 ⁇ 20,000mJ / cm 2, preferably to the 5 ⁇ 5,000mJ / cm 2 approximately.
- the light source can be selected according to the type of light to be exposed.
- a low-pressure mercury lamp for example, in the case of ultraviolet rays, a low-pressure mercury lamp, a high-pressure mercury lamp, an ultrahigh-pressure mercury lamp, a deuterium lamp, a halogen lamp, laser light (helium-cadmium laser, excimer) Laser, etc.), UV-LED, etc. can be used. By such light irradiation, the curing reaction of the composition proceeds.
- the coating film is heated, for example, at room temperature (approximately 23 ° C.) to 250 ° C. Performed at about °C.
- the heating time can be selected from a range of 3 seconds or more (for example, about 3 seconds to 5 hours), for example, about 5 seconds to 2 hours.
- the coating film formed on the base material may be subjected to pattern exposure.
- This pattern exposure may be performed by scanning with a laser beam or by irradiating light through a photomask.
- a pattern or an image can be formed by developing (or dissolving) a non-irradiated region (unexposed portion) generated by such pattern exposure with a developer.
- an alkaline aqueous solution or an organic solvent can be used as the developer.
- the alkaline aqueous solution include aqueous solutions of alkali metal hydroxides such as potassium hydroxide, sodium hydroxide, potassium carbonate and sodium carbonate; quaternary ammonium hydroxides such as tetramethylammonium hydroxide, tetraethylammonium hydroxide and choline.
- Aqueous solution An aqueous amine solution such as ethanolamine, propylamine, and ethylenediamine can be used.
- the alkali developer is generally an aqueous solution of 10% by mass or less, and preferably an aqueous solution of 0.1 to 3% by mass is used. Further, alcohols and surfactants may be added to the developer and used, and the amount of these added is preferably 0.05 to 10 parts by mass with respect to 100 parts by mass of the developer. Specifically, a 0.1 to 2.38 mass% tetramethylammonium hydroxide aqueous solution or the like can be used.
- the organic solvent as a developing solution can use a common organic solvent, for example, aromatic hydrocarbons, such as toluene; ethyl lactate, propylene glycol monomethyl ether acetate (PGMEA), propylene glycol monoethyl Esters such as ether acetate, propylene glycol monopropyl ether acetate and propylene glycol monobutyl ether acetate; Amides such as N, N-dimethylformamide (DMF); Nitriles such as acetonitrile; Ketones such as acetone and cyclohexanone; Methanol, Ethanol, 2-propanol, propylene glycol monomethyl ether (PGME), propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol And alcohols such as chromatography mono butyl ether.
- aromatic hydrocarbons such as toluene
- PMEA propylene glycol monomethyl ether a
- ethyl lactate propylene glycol monomethyl ether acetate (PGMEA), propylene glycol monomethyl ether (PGME) and the like can be preferably used.
- PGMEA propylene glycol monomethyl ether acetate
- PGME propylene glycol monomethyl ether
- the epoxy resin composition of the present invention may contain a solvent if necessary.
- the solvent that can be used in the present invention include aromatic hydrocarbons such as toluene and xylene; esters such as methyl acetate, ethyl acetate, propyl acetate, and butyl acetate; methyl hydroxyacetate, ethyl hydroxyacetate, butyl hydroxyacetate, Methyl lactate, ethyl lactate, propyl lactate, butyl lactate, methyl 3-hydroxypropionate, ethyl 3-hydroxypropionate, propyl 3-hydroxypropionate, butyl 3-hydroxypropionate, methyl 2-hydroxy-2-methylpropionate Hydroxy esters such as ethyl 2-hydroxy-2-methylpropionate and methyl 2-hydroxy-3-methylbutanoate; methyl methoxyacetate, ethyl methoxyacetate, propyl methoxyacetate, butyl methoxyacetate, methyl
- the epoxy resin composition of the present invention may contain a vinyl group-containing compound, an oxetanyl group-containing compound and the like as a cationic curable monomer for the purpose of adjusting the viscosity of the curable composition and improving the curability.
- the vinyl group-containing compound is not particularly limited as long as it is a compound having a vinyl group.
- HEVE 2-hydroxyethyl vinyl ether
- DEGV diethylene glycol monovinyl ether
- HBVE 2-hydroxybutyl vinyl ether
- triethylene glycol And vinyl ether compounds such as divinyl ether.
- a vinyl compound having a substituent such as an alkyl group or an allyl group at the ⁇ -position and / or ⁇ -position can be used.
- a vinyl ether compound containing a cyclic ether group such as an epoxy group and / or an oxetanyl group can be used, and examples thereof include oxynorbornene divinyl ether and 3,3-dimethanol oxetane divinyl ether.
- a compound having a vinyl group and a (meth) acryl group can be used, and examples thereof include 2- (2-vinyloxyethoxy) ethyl (meth) acrylate.
- the oxetanyl group-containing compound is not particularly limited as long as it is a compound having an oxetanyl group, and 3-ethyl-3- (hydroxymethyl) oxetane (OXA), 3-ethyl-3- (phenoxymethyl) oxetane (POX), Bis ((3-ethyl-3-oxetanyl) methyl) ether (DOX), 1,4-bis (((3-ethyl-3-oxetanyl) methoxy) methyl) benzene (XDO), 3-ethyl-3- ( 2-ethylhexyloxymethyl) oxetane (EHOX), 3-ethyl-3-((3-triethoxysilylpropoxy) methyl) oxetane (TESOX), oxetanylsilsesquioxane (OX-SQ), phenol novolac oxetane (PNOX- 100
- a compound having an oxetanyl group and a (meth) acryl group can be used, and examples thereof include (3-ethyl-3-oxetanyl) methyl (meth) acrylate.
- These oxetanyl group-containing compounds can be used alone or in combination of two or more.
- the epoxy resin composition of this invention may contain the conventional additive as needed.
- additives include surfactants, adhesion promoters, sensitizers, thickeners, antifoaming agents, leveling agents, coatability improvers, lubricants, stabilizers (antioxidants, thermal stability). Agents, light stabilizers, etc.), plasticizers, dissolution accelerators, antistatic agents, fillers, pigments, colorants and the like. These additives may be used alone or in combination of two or more.
- a surfactant may be added to the epoxy resin composition of the present invention for the purpose of improving coating properties.
- surfactants include, but are not limited to, fluorine-based surfactants, silicone-based surfactants, and nonionic surfactants.
- the said surfactant can be used individually or in combination of 2 or more types.
- a fluorosurfactant is preferable because of its high coating property improving effect.
- fluorosurfactant examples include, for example, EFTOP (registered trademark) EF-301, EF-303, and EF-352 [all manufactured by Mitsubishi Materials & Chemicals Co., Ltd.], MegaFuck (registered trademark) ) F-171, F-173, F-482, R-08, R-30, R-90, BL-20 [all made by DIC Corporation], Florard FC-430, FC-431 [all manufactured by 3M Japan Co., Ltd.], Asahi Guard (registered trademark) AG-710 (manufactured by Asahi Glass Co., Ltd.), Surflon S-382, SC-101, SC-102, SC-103 SC-104, SC-105, SC-106 [all manufactured by AGC Seimi Chemical Co., Ltd.], etc., but are not limited thereto.
- the addition amount of the surfactant in the epoxy resin composition of the present invention is 0.01 to 5% by mass, preferably 0.01 to 3% by mass, based on the solid content of the epoxy resin composition.
- An adhesion promoter may be added to the epoxy resin composition of the present invention, for example, for the purpose of improving the adhesion to the substrate after development.
- adhesion promoters include chlorosilanes such as chlorotrimethylsilane, trichloro (vinyl) silane, chloro (dimethyl) (vinyl) silane, chloro (methyl) (diphenyl) silane, and chloro (chloromethyl) (dimethyl) silane.
- adhesion promoters can be used alone or in combination of two or more.
- the addition amount of the adhesion promoter in the epoxy resin composition of the present invention is usually 20% by mass or less, preferably 0.01 to 10% by mass, more preferably based on the solid content of the epoxy resin composition. 0.05 to 5% by mass.
- sensitizer may be added to the epoxy resin composition of the present invention.
- sensitizers that can be used include anthracene, phenothiazene, perylene, thioxanthone, and benzophenone thioxanthone.
- sensitizing dyes include thiopyrylium salt dyes, merocyanine dyes, quinoline dyes, styrylquinoline dyes, ketocoumarin dyes, thioxanthene dyes, xanthene dyes, oxonol dyes, cyanine dyes, rhodamine dyes. And pyrylium salt pigments.
- anthracene-based sensitizer when used in combination with a cationic curing catalyst (radiation sensitive cationic polymerization initiator), the sensitivity is drastically improved and also has a radical polymerization initiation function.
- a cationic curing catalyst radiation sensitive cationic polymerization initiator
- the catalyst species can be simplified.
- anthracene compounds dibutoxyanthracene, dipropoxyanthraquinone and the like are effective.
- Examples of the sensitizer when using a base generator as a curing catalyst include acetophenones, benzoins, benzophenones, anthraquinones, xanthones, thioxanthones, ketals, and tertiary amines. it can.
- the addition amount of the sensitizer in the epoxy resin composition of the present invention is 0.01 to 20% by mass, preferably 0.01 to 10% by mass, based on the solid content of the epoxy resin composition. .
- a metal wiring coating composition comprising the epoxy resin composition is also an object of the present invention.
- the metal wiring in the present invention is usually used for metal wiring, such as aluminum, nickel, copper, platinum, gold, palladium, silver, tin, etc., or antimony-added tin oxide (ATO), aluminum-added zinc oxide (AZO).
- ATO antimony-added tin oxide
- AZO aluminum-added zinc oxide
- FTO fluorine-added tin oxide
- GZO gallium-added zinc oxide
- ITO tin-added indium oxide
- a wiring substrate in which the cured product of the epoxy resin composition and the metal wiring are in contact can be obtained.
- coating and hardening method of the said epoxy resin composition it is as above-mentioned.
- the wiring board thus obtained is also an object of the present invention.
- Viscosity Equipment TVE-22L, TVE-25H manufactured by Toki Sangyo Co., Ltd.
- Melting point Apparatus Diamond DSC manufactured by PerkinElmer Japan
- Epoxy equivalent apparatus Kyoto Denshi Kogyo Co., Ltd.
- potentiometric automatic titrator AT-510 Dielectric constant Device: E4980A Precision LCR meter manufactured by Keysight Technologies, Inc.
- Sample holder 12962 type room temperature sample holder, manufactured by Toyo Technica Co., Ltd.
- OEO 7-octen-1-ol [Kuraray Co., Ltd., purity 95%]
- DEO 9-decen-1-ol [manufactured by Tokyo Chemical Industry Co., Ltd.]
- UdEO 10-Undecen-1-ol [manufactured by Tokyo Chemical Industry Co., Ltd.]
- TEA Triethylamine [Pure Chemical Co., Ltd.]
- MsCl Methanesulfonic acid chloride [manufactured by Tokyo Chemical Industry Co., Ltd.]
- ICA isocyanuric acid [manufactured by Nissan Chemical Industries, Ltd.]
- mCPBA m-chloroperbenzoic acid [manufactured by Wako Pure Chemical Industries, Ltd., purity 70%]
- CEL 3,4-epoxycyclohexanecarboxylic acid (3,4-epoxycyclohexyl) methyl [Celoxide 2021P manufactured by Daicel Corporation]
- TEOIC tris (7,8-epoxyoctyl) isocyanurate
- TEDIC tris (9,10-epoxydecyl) isocyanurate
- the obtained TEDIC had a melting point of 26 ° C. and an epoxy equivalent of 196.
- the reaction flask was charged with 34.1 g (0.058 mol) of TUdEIC and 500 g of chloroform. To this solution, 55.9 g (net 0.23 mol) of mCPBA was added with stirring, and the mixture was stirred at room temperature (approximately 23 ° C.) for 30 hours. To this reaction solution, 300 mL of a 10% by mass aqueous sodium thiosulfate solution was added to decompose mCPBA. The organic layer was washed with 5% by mass aqueous sodium bicarbonate solution and 5% by mass saline solution, and then the solvent was distilled off.
- TEUDIC had a melting point of 43 ° C. and an epoxy equivalent of 211.
- Table 1 shows the viscosities at 25 ° C for the epoxy compounds produced in Production Example 1 and Comparative Production Examples 1 and 2, and TEPeIC, which is a general-purpose low-viscosity epoxy compound.
- the epoxy compound (TEOIC) used in the present invention has a viscosity much lower than that of a general-purpose low-viscosity epoxy compound (TEPeIC), and not only is excellent in handling properties but also has applicability and embedding properties. It was suggested that the characteristics were excellent. On the other hand, it was confirmed that epoxy compounds (TEDIC, TEUDIC) in which L 1 to L 3 are longer chain (C8, C9) alkylene groups, although having the same skeleton, are not liquid but solid. .
- Examples 1 to 3 Comparative Examples 1 to 3
- MH700 was added as an equimolar amount with the epoxy group of the epoxy compound as a curing agent, and 1 part by mass of PX4ET as a curing accelerator.
- the mixture was degassed by stirring at room temperature (approximately 23 ° C.) for 30 minutes under reduced pressure to prepare epoxy resin compositions 1-6.
- Each epoxy resin composition was sandwiched between two glass substrates that had been release-treated with Optool (registered trademark) DSX (manufactured by Daikin Industries, Ltd.) together with a U-shaped silicone rubber spacer having a thickness of 3 mm. This was heated in an oven at 100 ° C.
- the cured product obtained from the epoxy resin composition of the present invention showed an extremely low relative dielectric constant compared to the cured product obtained using TEPeIC, which is a general-purpose low-viscosity epoxy compound. (Example 1 and Comparative Example 1). Moreover, it was confirmed that the specific dielectric constant of the hardened
- the epoxy resin composition of the present invention has light and thermosetting properties, and has an adhesive, a high refractive index layer of an antireflection film (such as an antireflection film for a liquid crystal display), an optical thin film (such as a reflection plate), and an electronic component. It can be widely used in the field of electronic materials such as sealing materials for printed circuit boards, printed wiring boards, and interlayer insulating film materials (interlayer insulating film materials for build-up printed circuit boards, etc.). In particular, it can be widely used as an electronic material that is required to have a low dielectric constant, such as a printed wiring board and an interlayer insulating film material.
- the epoxy resin composition of the present invention includes a semiconductor sealing material, a transparent sealing agent, an adhesive for electronic materials, an optical adhesive, a printed wiring board material, an interlayer insulating film material, a fiber reinforced plastic, an ink for optical modeling, and a paint.
- a semiconductor sealing material a transparent sealing agent
- an adhesive for electronic materials an optical adhesive
- a printed wiring board material an interlayer insulating film material
- a fiber reinforced plastic an ink for optical modeling
- a paint e.g., a paint
- various materials such as inks, water repellent coating materials, water slidable coating materials, lipophilic coating materials, self-healing materials, biocompatible materials, birefringence control materials, pigment dispersants, filler dispersants, rubber modifiers, etc.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Epoxy Resins (AREA)
Abstract
Description
特に、近年微細化が進行している半導体、液晶等の分野では、リソグラフィーやナノインプリントにより形成した微細な凹凸構造の上層に、エポキシ樹脂等からなる樹脂層をコーティングする場面が多くみられる。しかしながら、使用するエポキシ樹脂組成物の液粘度が高い場合には、塗布した際に該樹脂組成物が微細な凹凸構造を埋め込むことができず、その後の工程に悪影響を及ぼすこととなる。
また、エポキシ樹脂硬化物の誘電率を低下させる方法として、エポキシ樹脂組成物中に中空粒子を添加し、該組成物から得られる硬化物に空気層を含ませることで硬化物を低誘電率化させる方法が知られている(例えば特許文献2)。
また、特許文献2に記載の方法では、組成物中に中空粒子を添加するためベース樹脂の光学物性、力学物性、熱物性などが変化してしまい、材料設計に悪影響を与える虞があった。
本発明は、低粘度かつ低誘電率であり、さらに汎用のエポキシ樹脂組成物に添加したときに、該組成物の低粘度化及び該組成物から得られるエポキシ樹脂硬化物の十分な低誘電率化が達成できるエポキシ化合物を含む、エポキシ樹脂組成物を提供することを目的とする。
第2観点として、前記R1乃至R3が水素原子である、第1観点に記載のエポキシ樹脂組成物に関する。
第3観点として、前記(b)硬化剤が、酸無水物、アミン、フェノール樹脂、ポリアミド樹脂、イミダゾール類、及びポリメルカプタンからなる群から選ばれる少なくとも一種である、第1観点又は第2観点に記載のエポキシ樹脂組成物に関する。
第4観点として、前記(b)硬化剤が酸無水物である、第3観点に記載のエポキシ樹脂組成物に関する。
第5観点として、前記(a)エポキシ成分のエポキシ基1当量に対して、0.5~1.5当量の前記(b)硬化剤を含む、第1観点乃至第4観点のうち何れか一項に記載のエポキシ樹脂組成物に関する。
第6観点として、第1観点乃至第5観点のうち何れか一項に記載のエポキシ樹脂組成物からなる、金属配線被覆用組成物に関する。
第7観点として、第1観点乃至第5観点のうち何れか一項に記載のエポキシ樹脂組成物の硬化物に関する。
第8観点として、第1観点乃至第5観点のうち何れか一項に記載のエポキシ樹脂組成物の硬化物、及び金属配線を含み、前記硬化物と前記金属配線が接している、配線基板に関する。
また、本発明で使用するエポキシ化合物は、従来の硬化剤、又は硬化触媒から発生した酸又は塩基と反応して硬化するので、汎用のエポキシ樹脂組成物に添加することができる。そして、本発明で使用するエポキシ化合物は、エポキシ樹脂組成物に添加することで、該組成物を低粘度化し、また該組成物から得られるエポキシ樹脂硬化物の誘電率を、該エポキシ化合物を添加していないエポキシ樹脂組成物から得られるエポキシ樹脂硬化物の誘電率よりも低下させることができる。
本発明のエポキシ樹脂組成物は、(a)前記式[1]で表されるエポキシ化合物を少なくとも含むエポキシ成分、及び(b)硬化剤を含む。
本発明で使用するエポキシ成分は、少なくとも下記式[1]で表されるエポキシ化合物を含む。
また上記L1乃至L3は、好ましくはヘキサメチレン基であり、L1乃至L3が何れもヘキサメチレン基であることがより好ましい。
中でも、R1乃至R3が何れも水素原子であり、L1乃至L3が何れもヘキサメチレン基であることが好ましい。
具体的には、イソシアヌル酸と、CH2=CR1-L1-Xで表されるオレフィン化合物とを反応させて不飽和結合を有する化合物(中間体)を製造した後、該化合物(中間体)と過酸化物を反応させて、上記式[1]で表されるエポキシ化合物を製造することができる。一例として、合成スキームを以下に示す。
なお、脱離基Xは、イソシアヌル酸のN-H基と反応する基であれば特に限定されないが、ヒドロキシ基、メタンスルホニルオキシ基、トリフルオロメタンスルホニルオキシ基、トルエンスルホニルオキシ基、ニトロベンゼンスルホニルオキシ基、アセトキシ基、トリフルオロアセトキシ基、ハロゲン原子等が挙げられる。
上記式[1]で表されるエポキシ化合物以外のエポキシ化合物としては、特に限定されることなく市販されている種々の多官能のエポキシ化合物を使用することができる。
これらのエポキシ化合物は単独で又は二種以上の混合物として使用することができる。
固体エポキシ化合物としては、TEPIC(登録商標)-G、同S、同L、同HP[何れも日産化学工業(株)製]等が挙げられる。
また、液状エポキシ化合物としては、TEPIC(登録商標)-PAS B22、同PAS B26、同PAS B26L、同VL、同UC[何れも日産化学工業(株)製]、jER(登録商標)828、同807、同YX8000[何れも三菱化学(株)製]、リカレジン(登録商標)DME100[新日本理化(株)製]、セロキサイド2021P[(株)ダイセル製]等が挙げられる。
本発明で使用する硬化剤としては、酸無水物、アミン、フェノール樹脂、ポリアミド樹脂、イミダゾール類、又はポリメルカプタンを用いることができる。これらの中でも、特に酸無水物及びアミンが好ましい。これら硬化剤は、固体であっても溶剤に溶解することによって使用することができる。しかし、溶剤の蒸発により硬化物の密度低下や細孔の生成により強度低下、耐水性の低下を生ずる虞があるため、硬化剤自体が常温、常圧下で液状のものが好ましい。
硬化剤は、エポキシ成分のエポキシ基1当量に対して0.5~1.5当量、好ましくは0.8~1.2当量の割合で含有することができる。エポキシ成分に対する硬化剤の当量は、エポキシ基に対する硬化剤の硬化性基の当量比で示される。なお、上記式[1]で表されるエポキシ化合物と、それ以外のエポキシ化合物を併用する場合には、それら全エポキシ化合物のエポキシ基に対する当量が前記範囲となる。
これらの中でも常温、常圧で液状である4-メチル-1,2,3,6-テトラヒドロ無水フタル酸(メチルテトラヒドロ無水フタル酸)、4-メチル-3,6-エンドメチレン-1,2,3,6-テトラヒドロ無水フタル酸(メチルエンドメチレンテトラヒドロ無水フタル酸、5-メチルノルボルナ-5-エン-2,3-ジカルボン酸無水物、メチルナジック酸無水物、無水メチルハイミック酸)、5-メチルビシクロ[2.2.1]ヘプタン-2,3-ジカルボン酸無水物(水素化メチルナジック酸無水物)、3-(2-メチルブタ-2-エン-1-イル)-1,2,3,6-テトラヒドロ無水フタル酸(メチルブテニルテトラヒドロ無水フタル酸)、ドデセニル無水コハク酸、4-メチルヘキサヒドロ無水フタル酸(メチルヘキサヒドロ無水フタル酸)、4-メチルヘキサヒドロ無水フタル酸(メチルヘキサヒドロ無水フタル酸)とヘキサヒドロ無水フタル酸との混合物が好ましい。これら液状の酸無水物は粘度が25℃での測定で10~1,000mPa・s程度である。酸無水物基において、1つの酸無水物基は1当量として計算される。
硬化促進剤としては、トリフェニルホスフィン、トリブチルホスフィン等の有機リン化合物;エチルトリフェニルホスホニウムブロミド、テトラブチルホスホニウムO,O-ジエチルホスホロジチオエート等の第4級ホスホニウム塩;1,8-ジアザビシクロ[5.4.0]ウンデカ-7-エン、1,8-ジアザビシクロ[5.4.0]ウンデカ-7-エンとオクチル酸との塩、オクチル酸亜鉛、テトラブチルアンモニウムブロミド等の第4級アンモニウム塩などが挙げられる。また前述の硬化剤として挙げた2-メチルイミダゾール、2-エチル-4-メチルイミダゾール等のイミダゾール類や、2,4,6-トリス(ジメチルアミノメチル)フェノール、ベンジルジメチルアミン等のアミン類も他の種類の硬化剤に対する硬化促進剤として用いることができる。
これらの硬化促進剤は、硬化剤1質量部に対して、0.001~0.1質量部の割合で用いることができる。
本発明のエポキシ樹脂組成物は、上記(b)硬化剤に替えて、又は(b)硬化剤に加えて、(c)硬化触媒を含むことができる。硬化触媒は、(c1)酸発生剤及び/又は(c2)塩基発生剤からなる。これにより、本発明で使用するエポキシ成分と硬化触媒とを混合しても直ちに硬化が生じないため、保存安定性に優れ、また十分な作業時間が得られる。
(c1)酸発生剤としては、光酸発生剤又は熱酸発生剤を用いることができる。光酸発生剤又は熱酸発生剤は、光照射又は加熱により直接又は間接的に酸(ルイス酸あるいはブレンステッド酸)を発生するものであれば特に限定されない。熱酸発生剤を配合したエポキシ樹脂組成物は、加熱により短時間で硬化させることができる。また、光酸発生剤を配合したエポキシ樹脂組成物は、加熱によらず、光照射で硬化するので、耐熱性の低い基板及び部位に使用することができる。
これらの例示化合物としては、上述の光酸発生剤において各種オニウム塩の例示として挙げた化合物を挙げることができる。
これらの熱酸発生剤は単独で、又は二種以上を組み合わせて用いることができる。
本発明のエポキシ樹脂組成物における(c1)酸発生剤の含有量は、(a)エポキシ成分100質量部に対して、0.1~20質量部、又は0.1~10質量部、さらに好ましくは0.5~10質量部とすることができる。なお、上記式[1]で表されるエポキシ化合物と、それ以外のエポキシ化合物を併用する場合には、それら全エポキシ化合物100質量部に対する含有量が前記範囲となる。
(c2)塩基発生剤としては、光塩基発生剤又は熱塩基発生剤を用いることができる。光塩基酸発生剤又は熱塩基発生剤は、光照射又は加熱により直接又は間接的に塩基(ルイス塩基あるいはブレンステッド塩基)を発生するものであれば特に限定されない。熱塩基発生剤を配合したエポキシ樹脂組成物は、加熱により短時間で硬化させることができる。また、光塩基発生剤を配合したエポキシ樹脂組成物は、加熱によらず、光照射で硬化するので、耐熱性の低い基板及び部位に使用することができる。
これら光塩基発生剤は、一種を単独で、又は二種以上を組み合わせて用いることができる。
また、光塩基発生剤は市販品として入手可能であり、例えば、和光純薬工業(株)製の光塩基発生剤WPBGシリーズ(WPBG-018、同027、同082、同140、同266、同300など)等を好適に用いることができる。
これら熱塩基発生剤は、一種を単独で、又は二種以上を組み合わせて用いることができる。
本発明のエポキシ樹脂組成物は、上記式[1]で表されるエポキシ化合物を少なくとも含むエポキシ成分と、上記硬化剤と所望により硬化促進剤とを混合することにより得られる。または、上記式[1]で表されるエポキシ化合物を少なくとも含むエポキシ成分と、上記硬化触媒とを混合することにより得られる。
これら混合は、均一に混合できれば特に限定されるものではないが、例えば反応フラスコと撹拌羽根若しくはミキサー等を用いて行うことができる。
混合は粘度を考慮して必要に応じて加熱下で行われ、10~100℃の温度で0.5~1時間行われる。
本発明では液状エポキシ化合物を用い、それに硬化剤又は硬化触媒を混合するため、基本的に溶剤を用いる必要はないが、必要により溶剤を添加してもよい。例えば、固体の硬化触媒を炭酸プロピレン等の溶剤に溶解した後、液状エポキシ化合物と混合してエポキシ樹脂組成物を調製することができる。また、液状エポキシ化合物に硬化触媒を溶解させる場合でも、得られるエポキシ樹脂組成物の粘度調整のために一般的な溶剤を添加してもよい。
エポキシ樹脂組成物から得られる硬化物は、該エポキシ樹脂組成物を基材に塗布、若しくは離型剤を塗布した注型板に注ぎ込んで、100~120℃の温度で予備硬化し、そして120~200℃の温度で本硬化(後硬化)することにより得られる。
加熱時間は、1~12時間、例えば予備硬化及び本硬化ともにそれぞれ2~5時間程度である。
本発明のエポキシ樹脂組成物から得られる塗膜の厚みは、硬化物の用途に応じて、0.01μm~10mm程度の範囲から選択できる。
また、本発明では、上記式[1]で表されるエポキシ化合物を少なくとも含むエポキシ成分、及び熱酸発生剤又は熱塩基発生剤を含むエポキシ樹脂組成物を、基材上に塗布し加熱により硬化することができる。
さらに、上記式[1]で表されるエポキシ化合物を少なくとも含むエポキシ成分、及び熱酸発生剤と光酸発生剤若しくは熱塩基発生剤と光塩基発生剤を含むエポキシ樹脂組成物を、基材上に塗布し加熱後に光照射により硬化することができる。
光の波長は、例えば、150~800nm、好ましくは150~600nm、さらに好ましくは200~400nm、特に300~400nm程度である。
照射光量は、塗膜の厚みにより異なるが、例えば、2~20,000mJ/cm2、好ましくは5~5,000mJ/cm2程度とすることができる。
光源としては、露光する光線の種類に応じて選択でき、例えば、紫外線の場合は低圧水銀ランプ、高圧水銀ランプ、超高圧水銀ランプ、重水素ランプ、ハロゲンランプ、レーザー光(ヘリウム-カドミウムレーザー、エキシマレーザーなど)、UV-LEDなどを用いることができる。このような光照射により、前記組成物の硬化反応が進行する。
アルカリ水溶液としては、例えば、水酸化カリウム、水酸化ナトリウム、炭酸カリウム、炭酸ナトリウム等のアルカリ金属水酸化物の水溶液;水酸化テトラメチルアンモニウム、水酸化テトラエチルアンモニウム、コリン等の水酸化四級アンモニウムの水溶液;エタノールアミン、プロピルアミン、エチレンジアミン等のアミン水溶液などを挙げることができる。
中でも、乳酸エチル、プロピレングリコールモノメチルエーテルアセテート(PGMEA)、プロピレングリコールモノメチルエーテル(PGME)等を好ましく使用することができる。
本発明のエポキシ樹脂組成物は、必要により溶剤を含んでいてもよい。
本発明で使用できる溶剤としては、例えば、トルエン、キシレン等の芳香族炭化水素類;酢酸メチル、酢酸エチル、酢酸プロピル、酢酸ブチル等のエステル類;ヒドロキシ酢酸メチル、ヒドロキシ酢酸エチル、ヒドロキシ酢酸ブチル、乳酸メチル、乳酸エチル、乳酸プロピル、乳酸ブチル、3-ヒドロキシプロピオン酸メチル、3-ヒドロキシプロピオン酸エチル、3-ヒドロキシプロピオン酸プロピル、3-ヒドロキシプロピオン酸ブチル、2-ヒドロキシ-2-メチルプロピオン酸メチル、2-ヒドロキシ-2-メチルプロピオン酸エチル、2-ヒドロキシ-3-メチルブタン酸メチル等のヒドロキシエステル類;メトキシ酢酸メチル、メトキシ酢酸エチル、メトキシ酢酸プロピル、メトキシ酢酸ブチル、エトキシ酢酸メチル、エトキシ酢酸エチル、エトキシ酢酸プロピル、エトキシ酢酸ブチル、プロポキシ酢酸メチル、プロポキシ酢酸エチル、プロポキシ酢酸プロピル、プロポキシ酢酸ブチル、ブトキシ酢酸メチル、ブトキシ酢酸エチル、ブトキシ酢酸プロピル、ブトキシ酢酸ブチル、2-メトキシプロピオン酸メチル、2-メトキシプロピオン酸エチル、2-メトキシプロピオン酸プロピル、2-メトキシプロピオン酸ブチル、2-エトキシプロピオン酸メチル、2-エトキシプロピオン酸エチル、2-エトキシプロピオン酸プロピル、2-エトキシプロピオン酸ブチル、2-ブトキシプロピオン酸メチル、2-ブトキシプロピオン酸エチル、2-ブトキシプロピオン酸プロピル、2-ブトキシプロピオン酸ブチル、3-メトキシプロピオン酸メチル、3-メトキシプロピオン酸エチル、3-メトキシプロピオン酸プロピル、3-メトキシプロピオン酸ブチル、3-エトキシプロピオン酸メチル、3-エトキシプロピオン酸エチル、3-エトキシプロピオン酸プロピル、3-エトキシプロピオン酸ブチル、3-プロポキシプロピオン酸メチル、3-プロポキシプロピオン酸エチル、3-プロポキシプロピオン酸プロピル、3-プロポキシプロピオン酸ブチル、3-ブトキシプロピオン酸メチル、3-ブトキシプロピオン酸エチル、3-ブトキシプロピオン酸プロピル、3-ブトキシプロピオン酸ブチル、メチルセロソルブアセテート、エチルセロソルブアセテート、プロピレングリコールモノメチルエーテルアセテート(PGMEA)、プロピレングリコールモノエチルエーテルアセテート、プロピレングリコールモノプロピルエーテルアセテート、プロピレングリコールモノブチルエーテルアセテート、プロピレングリコールモノメチルエーテルプロピオネート、プロピレングリコールモノエチルエーテルプロピオネート、プロピレングリコールモノプロピルエーテルプロピオネート、プロピレングリコールモノブチルエーテルプロピオネート等のエーテルエステル類;メチルエチルケトン(MEK)、4-ヒドロキシ-4-メチル-2-ペンタノン、シクロヘキサノン等のケトン類;エチレングリコールモノメチルエーテル、エチレングリコールモノエチルエーテル、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノエチルエーテル、プロピレングリコールモノメチルエーテル(PGME)、プロピレングリコールモノエチルエーテル、プロピレングリコールモノプロピルエーテル、プロピレングリコールモノブチルエーテル等のアルコール類;テトラヒドロフラン(THF)、ジエチレングリコールジメチルエーテル、ジエチレングリコールジエチルエーテル、ジエチレングリコールエチルメチルエーテル等のエーテル類などが挙げられる。
本発明のエポキシ樹脂組成物は、硬化性組成物の粘度調整や硬化性の向上を目的として、カチオン硬化性モノマーとして、ビニル基含有化合物、オキセタニル基含有化合物等を含んでもいてもよい。
また、ビニル基と(メタ)アクリル基を有する化合物を使用することができ、例えば、(メタ)アクリル酸2-(2-ビニルオキシエトキシ)エチル等が挙げられる。
これらビニル基含有化合物は、単独で又は二種以上を組み合わせて使用することができる。
また、オキセタニル基と(メタ)アクリル基を有する化合物を使用することができ、例えば、(3-エチル-3-オキセタニル)メチル(メタ)アクリレート等が挙げられる。
これらのオキセタニル基含有化合物は、単独で又は二種以上を組み合わせて使用することができる。
本発明のエポキシ樹脂組成物は、必要に応じて慣用の添加剤を含んでいてもよい。このような添加剤としては、例えば、界面活性剤、密着促進剤、増感剤、増粘剤、消泡剤、レベリング剤、塗布性改良剤、潤滑剤、安定剤(酸化防止剤、熱安定剤、耐光安定剤など)、可塑剤、溶解促進剤、帯電防止剤、充填材、顔料、着色剤などが挙げられる。これらの添加剤は単独で又は二種以上組み合わせてもよい。
これらの界面活性剤の中で、塗布性改善効果の高さからフッ素系界面活性剤が好ましい。フッ素系界面活性剤の具体例としては、例えば、エフトップ(登録商標)EF-301、同EF-303、同EF-352[何れも三菱マテリアル電子化成(株)製]、メガファック(登録商標)F-171、同F-173、同F-482、同R-08、同R-30、同R-90、同BL-20[何れもDIC(株)製]、フロラードFC-430、同FC-431[何れもスリーエムジャパン(株)製]、アサヒガード(登録商標)AG-710[旭硝子(株)製]、サーフロンS-382、同SC-101、同SC-102、同SC-103、同SC-104、同SC-105、同SC-106[何れもAGCセイミケミカル(株)製]等が挙げられるが、これらに限定されるものではない。
本発明のエポキシ樹脂組成物における界面活性剤の添加量は、該エポキシ樹脂組成物の固形分の含有量に基づいて、0.01~5質量%、好ましくは0.01~3質量%、より好ましくは0.01~2質量%である。
本発明のエポキシ樹脂組成物における密着促進剤の添加量は、該エポキシ樹脂組成物の固形分の含有量に基づいて、通常20質量%以下、好ましくは0.01~10質量%、より好ましくは0.05~5質量%である。
また、硬化触媒として塩基発生剤を用いる場合の増感剤としては、例えば、アセトフェノン類、ベンゾイン類、ベンゾフェノン類、アントラキノン類、キサントン類、チオキサントン類、ケタール類、3級アミン類等を挙げることができる。
本発明のエポキシ樹脂組成物における増感剤の添加量は、該エポキシ樹脂組成物の固形分の含有量に基づいて、0.01~20質量%、好ましくは0.01~10質量%である。
前記エポキシ樹脂組成物からなる金属配線被覆用組成物も本発明の対象である。
本発明における金属配線は、通常金属配線に使用される、アルミニウム、ニッケル、銅、白金、金、パラジウム、銀、スズ等の金属、又はアンチモン添加酸化スズ(ATO)、アルミニウム添加酸化亜鉛(AZO)、フッ素添加酸化スズ(FTO)、ガリウム添加酸化亜鉛(GZO)、スズ添加酸化インジウム(ITO)等の金属酸化物で形成された配線であれば、特に限定されない。
上記金属配線を具備した基板に、前記エポキシ樹脂組成物を塗布し硬化させることで、エポキシ樹脂組成物の硬化物と金属配線とが接している配線基板を得ることができる。なお、前記エポキシ樹脂組成物の塗布、硬化方法については前述のとおりである。こうして得られた配線基板も本発明の対象である。
なお、実施例において、試料の調製及び物性の分析に用いた装置及び条件は、以下のとおりである。
装置:東機産業(株)製 TVE-22L、TVE-25H
(2)融点
装置:(株)パーキンエルマージャパン製 Diamond DSC
(3)エポキシ当量
装置:京都電子工業(株)製 電位差自動滴定装置AT-510
(4)比誘電率
装置:キーサイト・テクノロジーズ社製 E4980A プレシジョンLCRメータ
サンプルホルダー:(株)東陽テクニカ製 12962型室温サンプルホルダー
(5)オーブン
装置:ヤマト科学(株)製 送風低温恒温器DNF400
OEO:7-オクテン-1-オール[(株)クラレ製、純度95%]
DEO:9-デセン-1-オール[東京化成工業(株)製]
UdEO:10-ウンデセン-1-オール[東京化成工業(株)製]
TEA:トリエチルアミン[純正化学(株)製]
MsCl:メタンスルホン酸クロリド[東京化成工業(株)製]
ICA:イソシアヌル酸[日産化学工業(株)製]
mCPBA:m-クロロ過安息香酸[和光純薬工業(株)製、純度70%]
CEL:3,4-エポキシシクロヘキサンカルボン酸(3,4-エポキシシクロヘキシル)メチル[(株)ダイセル製 セロキサイド2021P]
TEPeIC:トリス(4,5-エポキシペンチル)イソシアヌレート[日産化学工業(株)製 TEPIC(登録商標)-VL]
TGIC:トリグリシジルイソシアヌレート[日産化学工業(株)製 TEPIC(登録商標)-L]
MH700:4-メチルヘキサヒドロ無水フタル酸/ヘキサヒドロ無水フタル酸混合物(モル比70:30)[新日本理化(株)製 リカシッド(登録商標)MH-700]
PX4ET:テトラブチルホスホニウムO,O-ジエチルホスホロジチオエート[日本化学工業(株)製 ヒシコーリン(登録商標)PX-4ET]
DMSO:ジメチルスルホキシド
反応フラスコに、OEO 100.0g(正味0.74mol)、TEA 94.7g(0.94mol)、及びクロロホルム400gを仕込んだ。この溶液を氷浴中で撹拌しながら、MsCl 107.21g(0.94mol)をゆっくり滴下し、さらに1時間撹拌した。
この反応液を、5質量%重曹水及びイオン交換水でそれぞれ洗浄した後、溶媒を留去した。得られた残渣を、シリカゲルクロマトグラフィー(ヘキサン:酢酸エチル=75:25(体積比))で精製することで、7-オクテニルメタンスルホネート(OEOMs)146.1gを得た。
この反応液に、ヘプタン140g及び酢酸30.6g(0.51mol)を加え、イオン交換水300gで2回洗浄した後、溶媒を留去した。得られた残渣を、シリカゲルクロマトグラフィー(ヘキサン:酢酸エチル=95:5(体積比))で精製することで、トリス(7-オクテニル)イソシアヌレート(TOEIC)35.6gを得た。
この反応液に、10質量%チオ硫酸ナトリウム水溶液300mLを加えてmCPBAを分解した。この有機層を、5質量%重曹水溶液及び5質量%食塩水でそれぞれ洗浄した後、溶媒を留去した。得られた残渣を、シリカゲルクロマトグラフィー(ヘキサン:酢酸エチル=80:20(体積比))で精製することで、目的物であるトリス(7,8-エポキシオクチル)イソシアヌレート(TEOIC)22.8gを無色透明液体として得た。得られたTEOICの、粘度は680mPa・s(25℃)、JIS K7236:2009に準じて測定したエポキシ当量は171であった。
反応フラスコに、DEO 100.0g(0.64mol)、TEA 77.8g(0.77mol)、及びクロロホルム400gを仕込んだ。この溶液を氷浴中で撹拌しながら、MsCl 88.1g(0.77mol)をゆっくり滴下し、さらに1時間撹拌した。
この反応液を、5質量%重曹水及びイオン交換水でそれぞれ洗浄した後、溶媒を留去した。得られた残渣を、シリカゲルクロマトグラフィー(ヘキサン:酢酸エチル=75:25(体積比))で精製することで、9-デセニルメタンスルホネート(DEOMs)143.9gを得た。
この反応液に、ヘプタン132g及び酢酸25.4g(0.42mol)を加え、イオン交換水300gで2回洗浄した後、溶媒を留去した。得られた残渣を、シリカゲルクロマトグラフィー(ヘキサン:酢酸エチル=90:10(体積比))で精製することで、トリス(9-デセニル)イソシアヌレート(TDEIC)23.1gを得た。
この反応液に、10質量%チオ硫酸ナトリウム水溶液300mLを加えてmCPBAを分解した。この有機層を、5質量%重曹水溶液及び5質量%食塩水でそれぞれ洗浄した後、溶媒を留去した。得られた残渣を、シリカゲルクロマトグラフィー(ヘキサン:酢酸エチル=85:15(体積比))で精製することで、目的物であるトリス(9,10-エポキシデシル)イソシアヌレート(TEDIC)22.0gを白色固体として得た。得られたTEDICの、融点は26℃、エポキシ当量は196であった。
反応フラスコに、UdEO 100.0g(0.59mol)、TEA 77.3g(0.76mol)、及びクロロホルム590gを仕込んだ。この溶液を氷浴中で撹拌しながら、MsCl 80.7g(0.70mol)をゆっくり滴下し、さらに1時間撹拌した。
この反応液を、5質量%重曹水及びイオン交換水でそれぞれ洗浄した後、溶媒を留去することで、10-ウンデセニルメタンスルホネート(UdEOMs)145.9gを得た。
反応液をろ過し、不溶物を除去した。このろ液に、ヘキサン250gを加え、5質量%食塩水250g、5質量%食塩水500gでそれぞれ洗浄した後、溶媒を留去した。得られた残渣を、シリカゲルクロマトグラフィー(ヘキサン:酢酸エチル=90:10(体積比))で精製することで、トリス(10-ウンデセニル)イソシアヌレート(TUdEIC)34.1gを得た。
この反応液に、10質量%チオ硫酸ナトリウム水溶液300mLを加えてmCPBAを分解した。この有機層を、5質量%重曹水溶液及び5質量%食塩水でそれぞれ洗浄した後、溶媒を留去した。得られた残渣を、シリカゲルクロマトグラフィー(ヘキサン:酢酸エチル=75:25(体積比))で精製することで、目的物であるトリス(10,11-エポキシウンデシル)イソシアヌレート(TEUdIC)23.1gを白色固体として得た。得られたTEUdICの、融点は43℃、エポキシ当量は211であった。
一方、同様の骨格を持ちながらも、L1乃至L3がより長鎖(C8、C9)のアルキレン基であるエポキシ化合物(TEDIC、TEUdIC)は、液状とならず固体となることが確認された。
表2に記載のエポキシ成分100質量部に、硬化剤としてMH700をエポキシ化合物のエポキシ基と等モル量、及び硬化促進剤としてPX4ET 1質量部を加えた。この混合物を、減圧下、室温(およそ23℃)で30分間撹拌することで脱泡し、エポキシ樹脂組成物1~6を調製した。
各エポキシ樹脂組成物を、厚さ3mmのコの字型のシリコーンゴム製スペーサーとともに、予めオプツール(登録商標)DSX[ダイキン工業(株)製]で離型処理したガラス基板2枚で挟み込んだ。これを、100℃のオーブンで2時間加熱(予備硬化)し、その後150℃まで昇温して5時間加熱(本硬化)した。徐冷した後、ガラス基板を取り去り、厚さ3mmの各硬化物を得た。
得られた硬化物について、比誘電率を評価した。比誘電率は、ホルダーの電極間に挟み込んだ試験片に、1V、1MHzの電圧を印加した際の静電容量Cpを測定し、同条件で測定した空気の静電容量C0で除して算出した。結果を表2に併せて示す。
また、本発明のエポキシ樹脂組成物を構成する特定のエポキシ化合物を含むことで、汎用のエポキシ化合物の硬化物の比誘電率を低減できることが確認された(実施例2及び比較例2、実施例3及び比較例3)。
Claims (8)
- 前記R1乃至R3が水素原子である、請求項1に記載のエポキシ樹脂組成物。
- 前記(b)硬化剤が、酸無水物、アミン、フェノール樹脂、ポリアミド樹脂、イミダゾール類、及びポリメルカプタンからなる群から選ばれる少なくとも一種である、請求項1又は請求項2に記載のエポキシ樹脂組成物。
- 前記(b)硬化剤が酸無水物である、請求項3に記載のエポキシ樹脂組成物。
- 前記(a)エポキシ成分のエポキシ基1当量に対して、0.5~1.5当量の前記(b)硬化剤を含む、請求項1乃至請求項4のうち何れか一項に記載のエポキシ樹脂組成物。
- 請求項1乃至請求項5のうち何れか一項に記載のエポキシ樹脂組成物からなる、金属配線被覆用組成物。
- 請求項1乃至請求項5のうち何れか一項に記載のエポキシ樹脂組成物の硬化物。
- 請求項1乃至請求項5のうち何れか一項に記載のエポキシ樹脂組成物の硬化物、及び金属配線を含み、前記硬化物と前記金属配線が接している、配線基板。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017550393A JP6931199B2 (ja) | 2015-11-10 | 2016-11-10 | 長鎖アルキレン基含有エポキシ樹脂組成物 |
KR1020187008539A KR102494437B1 (ko) | 2015-11-10 | 2016-11-10 | 장쇄 알킬렌기함유 에폭시 수지 조성물 |
EP16864317.9A EP3375804B1 (en) | 2015-11-10 | 2016-11-10 | Long-chain alkylene group-containing epoxy resin composition |
US15/775,132 US10669369B2 (en) | 2015-11-10 | 2016-11-10 | Long-chain alkylene group-containing epoxy resin composition |
CN201680065273.1A CN108350146B (zh) | 2015-11-10 | 2016-11-10 | 含长链伸烷基的环氧树脂组合物 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015220569 | 2015-11-10 | ||
JP2015-220569 | 2015-11-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2017082356A1 true WO2017082356A1 (ja) | 2017-05-18 |
Family
ID=58695540
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2016/083398 WO2017082356A1 (ja) | 2015-11-10 | 2016-11-10 | 長鎖アルキレン基含有エポキシ樹脂組成物 |
Country Status (7)
Country | Link |
---|---|
US (1) | US10669369B2 (ja) |
EP (1) | EP3375804B1 (ja) |
JP (1) | JP6931199B2 (ja) |
KR (1) | KR102494437B1 (ja) |
CN (1) | CN108350146B (ja) |
TW (1) | TWI715664B (ja) |
WO (1) | WO2017082356A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019216321A1 (ja) * | 2018-05-07 | 2019-11-14 | 学校法人東京理科大学 | 光反応性組成物、反応生成物及び反応生成物の製造方法 |
WO2020184324A1 (ja) * | 2019-03-08 | 2020-09-17 | 株式会社Adeka | 繊維強化プラスチック用樹脂組成物、及び該組成物を含有する繊維強化プラスチック |
WO2024010059A1 (ja) * | 2022-07-07 | 2024-01-11 | 積水化学工業株式会社 | 硬化性樹脂組成物及び有機el表示素子用封止剤 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN116655888B (zh) * | 2023-08-01 | 2023-10-31 | 南京海关工业产品检测中心 | 一种自修复材料及其制备和回收利用方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008007782A (ja) * | 2006-06-27 | 2008-01-17 | Lumination Llc | オプトエレクトロニックデバイス |
WO2010092947A1 (ja) * | 2009-02-10 | 2010-08-19 | 日産化学工業株式会社 | 長鎖アルキレン基含有エポキシ化合物 |
JP2012025688A (ja) * | 2010-07-22 | 2012-02-09 | National Institute Of Advanced Industrial Science & Technology | エポキシ化合物の製造方法 |
WO2016027735A1 (ja) * | 2014-08-20 | 2016-02-25 | 日産化学工業株式会社 | 過酸化水素の安定化剤を含有するエポキシ化合物の製造方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000226432A (ja) * | 1999-02-08 | 2000-08-15 | Hitachi Chem Co Ltd | 樹脂ペースト組成物及びこれを用いた半導体装置 |
JP5423602B2 (ja) | 2004-07-27 | 2014-02-19 | 日立化成株式会社 | 低誘電率絶縁性樹脂組成物 |
US20070295956A1 (en) * | 2006-06-27 | 2007-12-27 | Gelcore Llc | Optoelectronic device |
WO2009107699A1 (ja) * | 2008-02-28 | 2009-09-03 | 積水化学工業株式会社 | 硬化性エポキシ組成物、異方性導電材料及び接続構造体 |
KR101821573B1 (ko) * | 2010-01-26 | 2018-01-25 | 닛산 가가쿠 고교 가부시키 가이샤 | 장쇄 알킬렌기 함유하는 경화성 에폭시 수지 조성물 |
US20130172522A1 (en) * | 2010-08-05 | 2013-07-04 | Nissan Chemical Industries, Ltd. | Epoxy compound with nitrogen-containing ring |
KR101897097B1 (ko) * | 2012-05-31 | 2018-09-11 | 엘지이노텍 주식회사 | 에폭시 수지 조성물 및 발광장치 |
KR102226349B1 (ko) * | 2013-10-30 | 2021-03-10 | 세키스이가가쿠 고교가부시키가이샤 | 유기 el 표시 소자용 밀봉제 |
KR102350408B1 (ko) * | 2016-03-29 | 2022-01-11 | 닛산 가가쿠 가부시키가이샤 | 액정 배향제, 액정 배향막, 및 액정 표시 소자 |
TWI753959B (zh) * | 2016-10-18 | 2022-02-01 | 日商日產化學工業股份有限公司 | 印刷配線板形成用環氧樹脂組成物 |
-
2016
- 2016-11-10 US US15/775,132 patent/US10669369B2/en active Active
- 2016-11-10 TW TW105136707A patent/TWI715664B/zh active
- 2016-11-10 WO PCT/JP2016/083398 patent/WO2017082356A1/ja active Application Filing
- 2016-11-10 KR KR1020187008539A patent/KR102494437B1/ko active IP Right Grant
- 2016-11-10 EP EP16864317.9A patent/EP3375804B1/en active Active
- 2016-11-10 JP JP2017550393A patent/JP6931199B2/ja active Active
- 2016-11-10 CN CN201680065273.1A patent/CN108350146B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008007782A (ja) * | 2006-06-27 | 2008-01-17 | Lumination Llc | オプトエレクトロニックデバイス |
WO2010092947A1 (ja) * | 2009-02-10 | 2010-08-19 | 日産化学工業株式会社 | 長鎖アルキレン基含有エポキシ化合物 |
JP2012025688A (ja) * | 2010-07-22 | 2012-02-09 | National Institute Of Advanced Industrial Science & Technology | エポキシ化合物の製造方法 |
WO2016027735A1 (ja) * | 2014-08-20 | 2016-02-25 | 日産化学工業株式会社 | 過酸化水素の安定化剤を含有するエポキシ化合物の製造方法 |
Non-Patent Citations (2)
Title |
---|
KENTARO OMORI: "The High Reliability Optical Material Based on the Isocyanuric Acid", KOBUNSHI, vol. 64, no. 7, 1 July 2015 (2015-07-01), pages 435 - 436, XP009511106 * |
See also references of EP3375804A4 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019216321A1 (ja) * | 2018-05-07 | 2019-11-14 | 学校法人東京理科大学 | 光反応性組成物、反応生成物及び反応生成物の製造方法 |
KR20200143427A (ko) * | 2018-05-07 | 2020-12-23 | 갓코호우징 도쿄리카다이가쿠 | 광반응성 조성물, 반응 생성물 및 반응 생성물의 제조방법 |
TWI718531B (zh) * | 2018-05-07 | 2021-02-11 | 學校法人東京理科大學 | 光反應性組成物、反應產物及反應產物的製造方法 |
JPWO2019216321A1 (ja) * | 2018-05-07 | 2021-06-17 | 学校法人東京理科大学 | 光反応性組成物、反応生成物及び反応生成物の製造方法 |
KR102474260B1 (ko) | 2018-05-07 | 2022-12-05 | 갓코호우징 도쿄리카다이가쿠 | 광반응성 조성물, 반응 생성물 및 반응 생성물의 제조방법 |
JP7224054B2 (ja) | 2018-05-07 | 2023-02-17 | 学校法人東京理科大学 | 光反応性組成物、反応生成物及び反応生成物の製造方法 |
WO2020184324A1 (ja) * | 2019-03-08 | 2020-09-17 | 株式会社Adeka | 繊維強化プラスチック用樹脂組成物、及び該組成物を含有する繊維強化プラスチック |
WO2024010059A1 (ja) * | 2022-07-07 | 2024-01-11 | 積水化学工業株式会社 | 硬化性樹脂組成物及び有機el表示素子用封止剤 |
Also Published As
Publication number | Publication date |
---|---|
TWI715664B (zh) | 2021-01-11 |
JP6931199B2 (ja) | 2021-09-01 |
CN108350146A (zh) | 2018-07-31 |
KR20180081038A (ko) | 2018-07-13 |
EP3375804A4 (en) | 2019-07-31 |
EP3375804B1 (en) | 2020-10-14 |
EP3375804A1 (en) | 2018-09-19 |
US10669369B2 (en) | 2020-06-02 |
TW201728664A (zh) | 2017-08-16 |
US20180340040A1 (en) | 2018-11-29 |
JPWO2017082356A1 (ja) | 2018-08-30 |
CN108350146B (zh) | 2021-03-16 |
KR102494437B1 (ko) | 2023-02-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6823294B2 (ja) | エポキシ系反応性希釈剤及びそれを含むエポキシ樹脂組成物 | |
JP5741860B2 (ja) | 硬化性長鎖アルキレン基含有エポキシ樹脂組成物 | |
JP6898596B2 (ja) | 多官能エポキシ化合物及びそれを含む硬化性組成物 | |
JP5867749B2 (ja) | 多官能エポキシ化合物 | |
JP6931199B2 (ja) | 長鎖アルキレン基含有エポキシ樹脂組成物 | |
JP6893921B2 (ja) | エポキシ化合物、これを含む硬化性組成物および硬化性組成物を硬化させた硬化物 | |
KR101886060B1 (ko) | 다관능 에폭시 화합물 | |
JP7004181B2 (ja) | プリント配線板形成用エポキシ樹脂組成物 | |
JP6954898B2 (ja) | エポキシ化合物、これを含む硬化性組成物および硬化性組成物を硬化させた硬化物 | |
JP2020083954A (ja) | ジエポキシ化合物、これを含む硬化性組成物および硬化性組成物を硬化させた硬化物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 16864317 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2017550393 Country of ref document: JP Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 20187008539 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 15775132 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2016864317 Country of ref document: EP |