WO2017057887A1 - Composition transparente de maquillage pour les yeux de type phase liquide dispersible dans l'huile - Google Patents

Composition transparente de maquillage pour les yeux de type phase liquide dispersible dans l'huile Download PDF

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Publication number
WO2017057887A1
WO2017057887A1 PCT/KR2016/010788 KR2016010788W WO2017057887A1 WO 2017057887 A1 WO2017057887 A1 WO 2017057887A1 KR 2016010788 W KR2016010788 W KR 2016010788W WO 2017057887 A1 WO2017057887 A1 WO 2017057887A1
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WO
WIPO (PCT)
Prior art keywords
eye makeup
makeup composition
composition
viscosity
dispersion formulation
Prior art date
Application number
PCT/KR2016/010788
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English (en)
Korean (ko)
Inventor
장순희
한은실
Original Assignee
(주)아모레퍼시픽
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Application filed by (주)아모레퍼시픽 filed Critical (주)아모레퍼시픽
Priority to CN201680056649.2A priority Critical patent/CN108135828A/zh
Priority to JP2018516179A priority patent/JP6810137B2/ja
Publication of WO2017057887A1 publication Critical patent/WO2017057887A1/fr
Priority to HK18114989.4A priority patent/HK1255923A1/zh

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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/06Emulsions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31Hydrocarbons
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/88Polyamides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/10Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin

Definitions

  • the present invention relates to an eye makeup composition of a liquid oil-dispersed formulation that can simultaneously realize transparency and viscosity.
  • top coat' formulation adds a coating effect to existing mascara or eyeliner and improves the makeup's durability.
  • the top coat may be used as mascara itself or through a transparent mascara formulation to give only a curling effect without color to produce a lighter, more natural look.
  • topcoat formulations are required to have a transparent appearance so that the color of the right product or the feel of the applied area can be revealed as it is due to its use characteristics.
  • a liquid dispersion having a high sustained liquid form was considered suitable, but in this case, there were many limitations due to the characteristics of the top coat formulation. Specifically, make-up products must form an appropriate level of viscosity, and when preparing the eye makeup composition with the liquid oil-dispersed formulation, it is difficult to simultaneously realize viscosity and transparency through oil thickeners generally used. There was. For example, when using a wax thickener that is white at room temperature as one of the typical oily thickeners, the formulation becomes opaque when the viscosity of the composition is appropriate. It fell off and was inconvenient to use.
  • the inventors of the present invention have conducted various studies in order to solve the above-mentioned problems.
  • the eye makeup composition is prepared in a liquid oil-dispersion formulation. It was found that it is possible to provide an eye makeup composition that is transparent and has an appropriate viscosity.
  • an object of the present invention to provide an eye makeup composition capable of simultaneously implementing transparency and viscosity.
  • the present invention to achieve the above object
  • the thickener provides an eye makeup composition of a liquid oil dispersion formulation, which is at least one thickener selected from the group consisting of amide-based polymers and dextrin palmitate / ethylhexanoate.
  • the eye makeup composition of the liquid oil-dispersion formulation of the present invention can simultaneously realize the transparency and viscosity suitable for use.
  • the eye makeup composition of the present invention can reveal the color of the product applied as a base or the characteristics of the application site as it is, and can be appropriately adhered to the use site.
  • FIG. 2 is a graph showing K / S values of the eight types of thickeners measured using a color difference meter.
  • Figure 3 shows the transparency of the composition observed in appearance when added to the volatile oil by mixing the thickeners that appear to be transparent among the eight types of thickeners.
  • Volatile oils and thickeners wherein the thickener is selected from the group consisting of amide based polymers and dextrin palmitate / ethylhexanoate, which is one or more thickeners selected from the group consisting of liquid oil dispersion formulations.
  • An eye makeup composition is provided.
  • the eye makeup composition according to the present invention is a liquid oil-dispersion formulation that can be applied to eyebrows, eyelashes, etc., while having high sustainability, and simultaneously implementing transparency and proper viscosity suitable for use.
  • the most preferred application formulation of the eye makeup composition of the present invention may be a top coat formulation for eye makeup.
  • 'Top coat' is a formulation that is applied over a mascara, brow or eye line to improve the durability and gloss, and to prevent bleeding and smearing, and thus transparency is essential.
  • the eye makeup composition of the present invention can be applied to all eye makeup formulations that can utilize the same and similar effects of the present invention in addition to the top coat formulation, such as transparent mascara, brow, eyeliner, and the like without limitation.
  • the present invention is characterized in that a specific type of thickener is used in order to simultaneously realize a transparent appearance and an appropriate viscosity when increasing while having affinity with volatile oil.
  • the thickener of the present invention may be used alone or in combination of two or more thickeners selected from the group consisting of an amide polymer and dextrin palmitate / ethylhexanoate. do.
  • the amide-based polymer thickener is bis-stearyl ethylenediamine / neopentyl glycol / stearyl hydrogenated dimer dilinoleate copolymer, and bis-stearyl ethylenediamine / neopentyl glycol and stearyl hydrogenated dimer dilinoleate copolymer.
  • / or Ethylenediamine / Hydrogenated Dimer Dilinoleate Copolymer Bis-Di-C14-18 Alkyl Amide can be used.
  • amide-based polymers In contrast to the thickeners used in conventional eye makeup compositions, amide-based polymers have not typically been utilized as thickeners for eye makeup, especially mascara or topcoat formulations, and dextrin palmitate / ethylhexanoate has only viscosity control. While only used in combination with other conventional oil thickeners for the purpose, in the present invention, at least one mixture selected from the group consisting of the amide polymer and / or dextrin palmitate / ethylhexanoate is used as the thickener. By doing so, the appearance of the composition can be transparently formed, and at the same time, a suitable viscosity suitable for use can be realized.
  • the total content of the thickeners used in the present invention may depend on the amount of thickeners that may be conventionally added to prepare the eye makeup composition. Specifically, the content of the thickener may be 1 to 30% by weight, preferably 15 to 25% by weight, and more preferably 20% by weight, based on the total weight of the volatile oil. If the thickener is included in less than 1% by weight, the thickening effect is reduced to form a formulation that flows down like water, which may cause inconvenience in use, and when included in more than 30% by weight, an excessively sticky formulation may be formed.
  • the eye makeup composition of the present invention to which a specific thickener is added in the above range has a viscosity of 30,000 to 300,000 cps. At viscosity of less than 30,000 cps, it is unsuitable for use because it flows down like water, and at a viscosity of more than 300,000 cps, the composition is too stiff and difficult to apply to brows, eyelashes, etc., but in the present invention, an appropriate range of viscosities can be implemented to improve convenience. Preferably from 30,000 to 200,000cps, more preferably it can form a viscosity of about 100,000cps at 20% by weight, the optimum thickener content relative to the total weight of the volatile oil.
  • the most preferred viscosity range means the most suitable range to be utilized as a top coat formulation for mascara and the like. Since the viscosity of the mascara formulation is generally formed around 200,000 cps, the top coat applied thereto has a relatively lower viscosity to provide good applicability and usability.
  • the application example of the eye makeup composition of the present invention is not necessarily limited thereto, and may be appropriately adjusted and used to form the most suitable viscosity as necessary.
  • a thickener that forms a relatively high viscosity You can choose the combination.
  • the dextrin palmitate / ethylhexanoate compared to the amide polymer thickener tends to form a relatively high viscosity, it is also possible to adjust the viscosity to high. Even in this case, the viscosity of the composition does not exceed a maximum of 300,000 cps.
  • the conventional eye makeup composition includes a volatile oil for the purpose of drying quickly without smearing
  • the eye makeup composition of the present invention also includes a volatile oil.
  • Volatile oils having the highest compatibility with the specific thickeners described above include hydrocarbon-based volatile oils and / or silicon-based volatile oils.
  • it may be in the form of including a hydrocarbon-based volatile oil and optionally further comprises a silicone-based volatile oil.
  • silicone oil it is possible to secure the transparency of the composition, but because the tendency to increase less than the hydrocarbon-based oil.
  • hydrocarbon-based volatile oil at least one selected from the group consisting of C8 to C16 branched aliphatic hydrocarbon oils, and C8 to C16 branched aliphatic ester oils may be used. More preferably, one or more substances selected from the group consisting of isodecane, isododecane and isohexadecane can be used as isoalkanes.
  • the silicone-based volatile oil of the present invention may use a linear or cyclic silicone oil, preferably a silicone oil having a viscosity of 6 cSt or less at 25 ° C. and having 2 to 5 silicon (Si) atoms. More preferably dimethicone, trisiloxane or mixtures thereof can be used.
  • test examples to help understand the effects of the present invention are described.
  • the following test examples correspond to only one test examples regarding the configuration and effects of the present invention, and the scope and effects of the present invention are not limited thereto.
  • Each of the thickeners of Table 1 was added to 20% by weight of volatile oil isododecane and mixed to prepare eye makeup compositions of eight liquid oil dispersion formulations.
  • the transparency of the composition observed after the preparation can be confirmed through FIG. 1. 1, ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-18 alkylamide (No. 3), dextrin palmitate / ethylhexanoate (No. 4) and when the three thickeners of bis-stearyl ethylenediamine / neopentyl glycol / stearyl hydrogenated dimer dilinoleate copolymer (No. 7) are added, the composition forms a transparent appearance. You can check it.
  • the thickener concentration of the composition was prepared in 20% by weight as in (1).
  • the eye makeup composition prepared in (1) of Preparation Example 1 was applied on a black substrate with a predetermined thickness (100 um), respectively.
  • the background value before application and the value after application of the thickener composition were measured using a color difference meter (model name: Minolta CM5).
  • L represents color
  • dE can be interpreted as a difference from the L value of the target.
  • Figure 3 is a graph showing the K / S value of the eye makeup composition containing each thickener (denoted as Data No.) of the results of Table 2.
  • the thickener of the composition evaluated to be transparent with a dE value of 1.5 or less is ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-18 alkylamide (A2614V, No. 3)
  • C75V bis-stearyl ethylenediamine / neopentyl glycol / stearyl hydrogenated dimer dilinoleate copolymer
  • the three thickeners are identical to those of the three compositions that were observed to be transparent in appearance in FIG. 1.
  • Viscosity measurement was performed using a Brookfield Viscometer HA DV-III, repeated three times at room temperature (25 ° C) with spindle No. 29, and then the average value was derived to obtain a viscosity value. It was.
  • the thickener included in the composition satisfying the range of 30,000 to 300,000 cps corresponding to the proper viscosity range of the eye makeup composition is ethylene / acrylic acid copolymer (SC401, No. 1), ethylenediamine / hydro Generated dimer dilinoleate copolymer bis-di-C14-18 alkylamide (A2614V, No. 3), dextrin palmitate / ethylhexanoate (Rheopearl TT, No.
  • the thickener which satisfies the transparency and the viscosity of the composition at the same time is ethylenediamine / hydrogenated dimer dilinoleate copolymer bis-di-C14-18 alkylamide (A2614V, No. 3), dextrin palmitate / ethylhexanoate (Rheopearl TT, No. 4), bis-stearyl ethylenediamine / neopentyl glycol / stearyl hydrogenated dimer dilinoleate copolymer (C75V, No. 7) It is understood that it is three kinds of thickeners of).
  • the three types of thickeners correspond to the amide-based polymer and dextrin palmitate / ethylhexanoate, which are the thickeners of the present invention as exemplified herein, from which the effects of the present invention can be confirmed.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition transparente de maquillage pour les yeux de type phase liquide dispersable dans l'huile, et plus spécifiquement, une composition transparente de maquillage pour les yeux de type phase liquide dispersable dans l'huile comprenant une huile volatile et un épaississant, l'épaississant étant un type ou plus d'un épaississant sélectionné au sein du groupe constitué d'un polymère à base d'amide et du palmitate de dextrine/hexanoate d'éthyle. La composition de maquillage pour les yeux de la présente invention peut permettre d'obtenir simultanément la transparence et la viscosité, et peut ainsi être utilisée de manière efficace et de diverses façons.
PCT/KR2016/010788 2015-09-30 2016-09-26 Composition transparente de maquillage pour les yeux de type phase liquide dispersible dans l'huile WO2017057887A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201680056649.2A CN108135828A (zh) 2015-09-30 2016-09-26 透明的液状油分散剂型的眼部彩妆组成物
JP2018516179A JP6810137B2 (ja) 2015-09-30 2016-09-26 透明な液状油分散剤形のアイメイクアップ組成物
HK18114989.4A HK1255923A1 (zh) 2015-09-30 2018-11-23 透明的液狀油分散劑型的眼部彩妝組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2015-0137389 2015-09-30
KR1020150137389A KR102463230B1 (ko) 2015-09-30 2015-09-30 투명한 액상 유분산 제형의 아이메이크업 조성물

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WO2017057887A1 true WO2017057887A1 (fr) 2017-04-06

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PCT/KR2016/010788 WO2017057887A1 (fr) 2015-09-30 2016-09-26 Composition transparente de maquillage pour les yeux de type phase liquide dispersible dans l'huile

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JP (1) JP6810137B2 (fr)
KR (1) KR102463230B1 (fr)
CN (1) CN108135828A (fr)
HK (1) HK1255923A1 (fr)
WO (1) WO2017057887A1 (fr)

Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN112437686A (zh) * 2018-07-02 2021-03-02 莱雅公司 包含酯-封端的聚(酯-酰胺)聚合物、挥发性烷烃、一元醇和至少一种颜料的流体组合物

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* Cited by examiner, † Cited by third party
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KR102529099B1 (ko) * 2020-10-21 2023-05-08 코스맥스 주식회사 폴리에틸렌 테레프탈레이트를 포함하는 건식 아이메이크업 화장료 조성물

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JP2006213679A (ja) * 2005-02-07 2006-08-17 Kao Corp 化粧料
KR20120059673A (ko) * 2010-11-30 2012-06-11 (주)아모레퍼시픽 아마이드계 폴리머를 함유하는 메이크업 화장료 조성물
KR20150014279A (ko) * 2013-07-29 2015-02-06 주식회사 엘지생활건강 투명 또는 반투명 겔 형상의 클렌징 화장료 조성물
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112437686A (zh) * 2018-07-02 2021-03-02 莱雅公司 包含酯-封端的聚(酯-酰胺)聚合物、挥发性烷烃、一元醇和至少一种颜料的流体组合物

Also Published As

Publication number Publication date
JP6810137B2 (ja) 2021-01-06
KR20170038269A (ko) 2017-04-07
HK1255923A1 (zh) 2019-09-06
KR102463230B1 (ko) 2022-11-04
JP2018530544A (ja) 2018-10-18
CN108135828A (zh) 2018-06-08

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