WO2017012306A1 - 阵列基板的制备方法、阵列基板及显示装置 - Google Patents

阵列基板的制备方法、阵列基板及显示装置 Download PDF

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WO2017012306A1
WO2017012306A1 PCT/CN2016/070855 CN2016070855W WO2017012306A1 WO 2017012306 A1 WO2017012306 A1 WO 2017012306A1 CN 2016070855 W CN2016070855 W CN 2016070855W WO 2017012306 A1 WO2017012306 A1 WO 2017012306A1
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Prior art keywords
region
photoresist
array substrate
layer
drain
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PCT/CN2016/070855
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English (en)
French (fr)
Chinese (zh)
Inventor
刘正
郭总杰
陈曦
张小祥
张治超
刘明悬
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京东方科技集团股份有限公司
北京京东方显示技术有限公司
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Application filed by 京东方科技集团股份有限公司, 北京京东方显示技术有限公司 filed Critical 京东方科技集团股份有限公司
Priority to EP16727927.2A priority Critical patent/EP3327763B1/de
Priority to KR1020167031087A priority patent/KR101900170B1/ko
Priority to JP2016566218A priority patent/JP6818554B2/ja
Priority to US15/106,052 priority patent/US9761617B2/en
Publication of WO2017012306A1 publication Critical patent/WO2017012306A1/zh

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    • H01L27/12Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
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    • H01L2021/775Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate comprising a plurality of TFTs on a non-semiconducting substrate, e.g. driving circuits for AMLCDs

Definitions

  • the present invention belongs to the field of display technologies, and in particular, to a method for fabricating an array substrate, an array substrate, and a display device.
  • Thin Film Transistor Liquid Crystal Display is an important flat panel display device.
  • the thin film transistor liquid crystal display can be classified into a vertical electric field type and a horizontal electric field type according to the direction of the electric field driving the liquid crystal.
  • the vertical electric field type TFT-LCD needs to form a pixel electrode on the array substrate, and form a common electrode on the color filter substrate, such as a common TN mode; and the horizontal electric field type TFT-LCD needs to simultaneously form a pixel electrode and a common electrode on the array substrate.
  • ADS Advanced Super Dimension Switch
  • ADS technology refers to the planar electric field wide viewing angle core technology.
  • the main idea is to form a multi-dimensional electric field by the electric field generated by the edge of the slit electrode in the same plane and the electric field generated between the slit electrode layer and the plate electrode layer, so that the inside of the liquid crystal cell All of the aligned liquid crystal molecules between the slit electrodes and directly above the electrodes can be rotated, thereby improving the liquid crystal working efficiency and increasing the light transmission efficiency.
  • ADS technology can improve the picture quality of TFT-LCD products, with high resolution, high transmittance, low power consumption, wide viewing angle, high aperture ratio, low chromatic aberration, and no push mura.
  • ADS technology has improved high-transmission I-ADS technology, high aperture ratio H-ADS and high-resolution S-ADS technology.
  • the array substrate of the I-ADS mode will be described in conjunction with the following preparation method.
  • Step 1 Form a first transparent conductive layer on the substrate, and form a pattern including a pixel electrode (plate electrode) by a patterning process.
  • Step 2 forming a gate metal film on the substrate on which the above steps are completed, and forming a pattern including a gate electrode of the thin film transistor by a patterning process.
  • Step 3 Form a gate insulating layer on the substrate on which the above steps are completed.
  • Step 4 forming an active layer film on the substrate on which the above steps are completed, and forming a pattern including the active layer by a patterning process.
  • Step 5 Form a source/drain metal film on the substrate on which the above steps are completed, and form a pattern including a source and a drain by a patterning process.
  • Step 6 Form a passivation layer on the substrate on which the above steps are completed, and form a pattern including a main via hole penetrating the passivation layer and the gate insulating layer by a patterning process.
  • Step 7 Form a second transparent conductive layer on the substrate on which the above steps are completed, and form a connection electrode connecting the drain electrode and the pixel electrode through the main via hole by a patterning process, and form a common electrode (slit electrode) by a patterning process Graphics.
  • the inventors have found that at least the following problems exist in the prior art: since dry etching is usually used in the process of forming the main via hole in step 6, the source/drain metal film is not etched away, and the active layer is The material is polysilicon, amorphous silicon, etc., which will be etched away, so there will be a problem of undercut under the drain. It is not difficult to understand that the second transparent conductive layer formed thereafter is easily broken at a floating position due to the phenomenon of dangling below the drain.
  • the present invention provides a method for fabricating an array substrate, an array substrate, and a display device, which effectively eliminate the problem of floating under the drain.
  • Embodiments of the present invention provide a method of fabricating an array substrate, the method comprising the steps of:
  • step S2 after step S1, forming a pattern including a gate of the thin film transistor on the substrate;
  • step S3 after step S2, forming a gate insulating layer on the substrate;
  • step S3 After step S3, forming an active layer including a thin film transistor by a patterning process on the substrate, and forming a source and a drain on the active layer shape;
  • step S5 after step S4, forming a passivation layer on the substrate;
  • step S6 after step S5, forming a main via extending through the gate insulating layer and the passivation layer and a main via extension under a partial region of the drain by a patterning process on the substrate a pattern in which the main via is continuous with the main via extension;
  • step S7 after step S6, removing a portion of the drain protruding from the main via extension to form a pattern including a final via;
  • step S8 After step S7, forming a pattern including a connection electrode and a common electrode on the substrate, wherein the connection electrode electrically connects the drain and the pixel electrode through the final via.
  • the array substrate includes: a thin film transistor region, a common electrode region, and a via region between the thin film transistor region and the common electrode region; and the step S6 includes the following steps:
  • the remaining photoresist is removed.
  • the first photoresist layer may have a thickness of 2.2 to 2.5 ⁇ m.
  • the step of removing portions of the passivation layer and the gate insulating layer under the first photoresist completely removed region by an etching process and removing the passivation layer by an etching process The etching process used in the step of the active layer and the portion of the gate insulating layer under the first photoresist portion remaining region is dry etching.
  • step S7 includes the following steps:
  • a portion of the drain protruding from the via extension is removed by a patterning process on a substrate formed with a pattern including the main via and the main via extension to form the final including A pattern of vias.
  • step S8 includes the following steps:
  • a transparent conductive film is formed, and a pattern including the connection electrode and the common electrode is formed by one patterning process.
  • the common electrode region includes a first region and a second region that are alternately arranged;
  • step S8 includes the following steps:
  • the remaining photoresist is removed using a step strip process and a pattern of the common electrode and the connection electrode is formed.
  • the second photoresist layer may have a thickness of 2.5 to 3.0 ⁇ m.
  • step S4 includes the following steps:
  • a pattern including the active layer of the thin film transistor and the source and the drain on the active layer is formed by a patterning process using a gray scale mask or a halftone mask.
  • step S4 comprises the following steps:
  • a source/drain metal film is deposited, and a pattern including a source and a drain of the thin film transistor is formed by another patterning process.
  • Embodiments of the present invention also provide an array substrate prepared by the above preparation method.
  • Embodiments of the present invention also provide a display device including the above array substrate.
  • a pattern including a main via extending through the gate insulating layer and the passivation layer and a main via extension located under a partial region of the drain is formed by a patterning process, and thereafter
  • the drain metal protruding above the main via extension is effectively removed, thereby solving the problem of floating under the drain in the prior art, and the performance of the formed array substrate is better without increasing the process steps.
  • the rate is higher.
  • FIG. 1 is a schematic view showing a step S1 of a method of fabricating an array substrate according to a first embodiment of the present invention
  • step S2 is a schematic diagram of step S2 of the method for fabricating the array substrate according to the first embodiment of the present invention
  • step S3 is a schematic diagram of step S3 of the method for fabricating the array substrate according to the first embodiment of the present invention
  • step S4 is a schematic diagram of step S4 of the method for fabricating the array substrate according to the first embodiment of the present invention
  • FIG. 5 is a schematic diagram of steps S5 and S6 of the method for fabricating the array substrate according to the first embodiment of the present invention
  • FIG. 6 is a schematic diagram of step S7 of the method for fabricating the array substrate according to the first embodiment of the present invention.
  • FIG. 7 is a schematic diagram of step S8 of the method for fabricating the array substrate according to the first embodiment of the present invention.
  • step S6 is a schematic view showing a specific preparation procedure of step S6 of the method for fabricating the array substrate according to the first embodiment of the present invention
  • FIG. 9 is a schematic view showing a specific preparation procedure of step S8 of the method for fabricating the array substrate according to the first embodiment of the present invention.
  • the present embodiment provides a method for fabricating an array substrate, which is an array substrate of an I-ADS mode, and includes at least a thin film transistor and a pixel electrode 1 , wherein the thin film transistor can be Top gate type thin film transistor or bottom gate type thin film transistor.
  • the top gate type thin film transistor The biggest difference from the bottom gate type thin film transistor is that the active layer 4 and the gate 2 are located at different positions. Specifically, a thin film transistor in which the active layer 4 is located under the gate 2 is referred to as a top gate type thin film transistor, and a thin film transistor in which the active layer 4 is located above the gate 2 is referred to as a bottom gate type thin film transistor.
  • the metal gate 2 of the bottom gate type thin film transistor can serve as a protective layer of the semiconductor active layer 4 to prevent the light emitted from the backlight from being irradiated to the amorphous silicon layer.
  • the generated photo-generated carriers break the electrical characteristics of the active layer 4. Therefore, a method of fabricating an array substrate having a bottom gate type thin film transistor will be described below as an example.
  • the preparation method does not constitute a limitation on the present embodiment, and the preparation method can also be applied to the preparation of an array substrate having a top gate type thin film transistor.
  • the patterning process may include only a photolithography process, or a photolithography process and an etching process, and may also include other processes for forming a predetermined pattern, such as printing, inkjet, and the like.
  • the photolithography process refers to a process of forming a pattern by using a photoresist, a mask, an exposure machine, or the like including a process of film formation, exposure, and development.
  • the corresponding patterning process can be selected according to the structure formed in this embodiment.
  • the method for preparing the array substrate in this embodiment specifically includes the following steps S1 to S8.
  • Step S1 a pattern including the pixel electrode 1 is formed on the substrate 10 by a patterning process.
  • the substrate 10 may be made of a transparent material such as glass, resin, sapphire, quartz or the like in this step and pre-cleaned.
  • a sputtering method a thermal evaporation method, a Plasma Enhanced Chemical Vapor Deposition (PECVD) method, a Low Pressure Chemical Vapor Deposition (LPCVD) method, and an atmospheric pressure chemistry may be employed.
  • PECVD Plasma Enhanced Chemical Vapor Deposition
  • LPCVD Low Pressure Chemical Vapor Deposition
  • a first transparent conductive film by an Atmospheric Pressure Chemical Vapor Deposition (APCVD) method or an Electron Cyclotron Resonance Chemical Vapor Deposition (ECR-CVD) method, and then performing the first transparent conductive film Photoresist coating, exposure, development, etching, photoresist stripping to form a pattern including the pixel electrode 1, as shown in FIG.
  • APCVD Atmospheric Pressure Chemical Vapor Deposition
  • ECR-CVD Electron Cyclotron Resonance Chemical Vapor Deposition
  • the first transparent conductive film has high reflectivity and meets certain work function requirements, and usually adopts a two-layer film or a three-layer film structure: such as ITO (indium tin oxide) / Ag (silver) / ITO or Ag / ITO structure;
  • ITO indium tin oxide
  • Ag silver
  • ITO indium tin oxide
  • IGZO indium gallium zinc oxide
  • InGaSnO indium gallium tin oxide
  • the inorganic metal oxide includes indium tin oxide or zinc oxide
  • the organic conductive polymer includes PEDOT: PSS, PANI. (Polyaniline)
  • the metal material includes one or more of gold, copper, silver, and platinum.
  • Step S2 on the substrate 10 on which the step S1 is completed, a pattern including the gate electrode 2 of the thin film transistor is formed by a patterning process, as shown in FIG.
  • a gate metal film may be formed by sputtering, thermal evaporation, plasma enhanced chemical vapor deposition, low pressure chemical vapor deposition, atmospheric pressure chemical vapor deposition or electron cyclotron resonance chemical vapor deposition, and then The gate metal film is coated with a photoresist, exposed, developed, etched, and stripped to form a pattern of the gate electrode 2 including the thin film transistor.
  • the material for forming the gate metal film (gate 2) may be molybdenum (Mo), molybdenum-niobium alloy (MoNb), aluminum (Al), aluminum-niobium alloy (AlNd), titanium (Ti), and copper (Cu).
  • Step S3 on the substrate 10 on which the step S2 is completed, the gate insulating layer 3 is formed.
  • the gate insulating layer 3 may be formed by a thermal growth, atmospheric pressure chemical vapor deposition, low pressure chemical vapor deposition, plasma assisted chemical vapor deposition, sputtering, or the like, as shown in FIG.
  • the material forming the gate insulating layer 3 may be silicon oxide (SiOx), silicon nitride (SiNx), germanium oxide (HfOx), silicon oxynitride (SiON) or aluminum oxide ( AlOx), etc., or from silicon oxide (SiOx), silicon nitride (SiNx), germanium oxide (HfOx), silicon oxynitride (SiON), and aluminum oxide (AlOx)
  • SiOx silicon oxide
  • SiNx silicon nitride
  • SiON germanium oxide
  • AlOx aluminum oxide
  • Step S4 sequentially depositing an active layer film on the substrate 10 on which step S3 is completed And a source/drain metal film, and a pattern including the active layer 4 of the thin film transistor and the source 51 and the drain 52 is formed by a patterning process.
  • the active layer film may be first deposited by plasma enhanced chemical vapor deposition or low pressure chemical vapor deposition; then sputtering, thermal evaporation, plasma enhanced chemical vapor deposition, low pressure may be employed.
  • a source/drain metal film is formed by chemical vapor deposition, atmospheric pressure chemical vapor deposition or electron cyclotron resonance chemical vapor deposition; followed by using a Half Tone Mask (HTM) or a Gray Tone Mask (Gray Tone Mask). GTM), through the first patterning process (film formation, exposure, development, wet etching or dry etching), simultaneously forming a pattern including the source 51, the drain 52 and the active layer 4, as shown in FIG. Show.
  • the material forming the active layer film may be an amorphous silicon film (a-Si) or a polysilicon film (p-Si); and the material forming the source/drain metal film (source 51 and drain 52) may be molybdenum (Mo) , a single-layer or multi-layer composite laminate formed of one or a plurality of materials of molybdenum-niobium alloy (MoNb), aluminum (Al), aluminum-niobium alloy (AlNd), titanium (Ti), and copper (Cu) It is preferably a single layer or a multilayer composite film composed of Mo and/or Al or a single layer or multilayer composite film composed of an alloy containing Mo and Al.
  • Mo molybdenum
  • MoNb molybdenum-niobium alloy
  • AlNd aluminum-niobium alloy
  • Ti titanium
  • Cu copper
  • the active layer 4, the source 51 and the drain 52 formed in the step S4 can also be formed by two patterning processes, that is, the active layer 4 is formed by one patterning process, and the source 51 and the drain 52 are formed. Formed by another patterning process.
  • Step S5 on the substrate 10 on which step S4 is completed, a passivation layer 6 is formed.
  • the passivation layer 6 may be formed by a thermal growth, atmospheric pressure chemical vapor deposition, low pressure chemical vapor deposition, plasma assisted chemical vapor deposition, or sputtering.
  • the material forming the passivation layer 6 may be an oxide of silicon (SiOx), a nitride of silicon (SiNx), an oxide of hafnium (HfOx), an oxide of silicon (SiON) or an oxide of aluminum (AlOx). Or etc., or two or three of silicon oxide (SiOx), silicon nitride (SiNx), germanium oxide (HfOx), silicon oxynitride (SiON), and aluminum oxide (AlOx) The composition of the multilayer film composition.
  • Step S6 forming a package by the patterning process on the substrate 10 completing the step S5
  • a pattern of the main via 71 and the main via extension 72 extending through the gate insulating layer 3 and the passivation layer 6 is formed, wherein the main via 71 and the main via extension 72 are penetrated as shown in FIG.
  • the main via extension portion 72 refers to inevitably etching the active layer 4 and the gate insulating layer 3 under the drain 52 in the process of forming the main via 71 by a patterning process.
  • the via hole that is, the portion defined by the lower surface of the drain electrode 52, the right side surface of the active layer 4 and the gate insulating layer 3, the upper surface of the substrate 10, and the broken line in FIG. 5 in FIG.
  • step S6 specifically includes the following steps S61 to S66.
  • Step S61 on the passivation layer 6, a first photoresist layer is formed.
  • Step S62 exposing and developing the first photoresist layer by using a halftone mask or a gray scale mask, so that the first photoresist layer forms a first photoresist completely removed region (not shown), first The photoresist completely retains the region 91 and the first photoresist portion retention region 92.
  • a first photoresist completely removed region corresponding to an intermediate region of the via region a first photoresist portion reserved region 92 corresponding to a portion of the thin film transistor region near the via region and the portion a peripheral region of the via region adjacent to the thin film transistor region, a first photoresist completely remaining region 91 and a first region including a common electrode region other than the above region (a region corresponding to a position of the common electrode 81 formed later) Corresponds to a portion of the thin film transistor region.
  • the photoresist thickness of the first photoresist completely remaining region 91 is not changed, the photoresist of the first photoresist completely removed region is completely removed, and the photoresist of the first photoresist portion retaining region 92 is completely removed.
  • the thickness is reduced.
  • the thickness of the first photoresist layer is 2.2 to 2.5 ⁇ m, and after the development process, the thickness of the photoresist of the first photoresist portion remaining region 92 is 1 to 1.5 ⁇ m.
  • Step S63 through the etching process, specifically, the portion of the passivation layer 6 and the gate insulating layer 3 under the first photoresist completely removed region may be removed by dry etching.
  • Step S64 removing the photoresist of the first photoresist portion remaining region 92 by an ashing process to expose a portion of the passivation layer 6 under the first photoresist portion remaining region 92 and the via region. Near the peripheral region of the thin film transistor region.
  • Step S65 through the etching process, specifically, the portion of the passivation layer 6, the active layer 4, and the gate insulating layer 3 under the first photoresist portion remaining region 92 may be sequentially removed by dry etching to form A pattern including the main via 71 and the main via extension 72 is included. At this time, the drain 52 will protrude from the main via extension 72.
  • Step S66 removing the remaining photoresist.
  • the formation of the main via extension portion 72 is not intentionally formed, but because the material of the active layer 4 is polysilicon or amorphous silicon, etc., in the passivation layer 6 and the gate insulating layer. 3
  • the etching is performed, the portion of the active layer 4 that is in contact with the etched passivation layer 6 and the gate insulating layer 3 is inevitably etched, resulting in the occurrence of the main via extension 72 under the drain 52.
  • the main via extension portion 72 formed by the exposure mode using the gray scale mask or the halftone mask in the above steps will be small, and the floating phenomenon under the drain 52 is improved to some extent, but it cannot be improved. Completely eliminate this defect.
  • main via 71 can also be formed by a single etching process using an ordinary mask. At this time, the main via extension 72 will be large, and the floating under the drain 52 will be apparent.
  • Step S7 on the substrate 10 completing step S6, the portion of the drain electrode 52 protruding from the main via extension portion 72 is removed by a patterning process to form a final via hole including the main via hole 71 and the main via hole.
  • the pattern of the via extensions 72) is shown in FIG.
  • the portion of the drain electrode 52 that protrudes from the main via extension portion 72 means a portion of the drain electrode 52 that is suspended due to the underlying active layer 4 being partially etched.
  • a wet etching process is employed in step S7.
  • Step S8 on the substrate 10 completing the step S7, a pattern including the connection electrode 82 and the common electrode 81 is formed by one patterning process, wherein the connection electrode 82 electrically connects the drain electrode 52 and the pixel electrode 1 through the final via hole. , as shown in Figure 7.
  • the common electrode region includes a first region (a region corresponding to the position of the common electrode 81) and a second region (a region corresponding to the interval between the adjacent common electrodes 81) which are alternately arranged.
  • the step S8 specifically includes the following steps S81 to S86.
  • Step S81 forming a diagram including the main via 71 and the main via extension 72 On the shaped substrate 10, a second photoresist layer is formed.
  • Step S82 exposing and developing the second photoresist layer by using a gray scale mask or a halftone mask, so that the second photoresist layer forms a second photoresist completely removed region (not shown), and second The photoresist completely retains the region 94, the second photoresist portion retention region 95.
  • a second photoresist complete removal region corresponding to a source region of the thin film transistor region, the via region, and a second region of the common electrode region, the second photoresist portion retention region 95 corresponding to the The drain region of the thin film transistor region, the second photoresist completely remaining region 94 corresponds to a region other than the above region.
  • the thickness of the photoresist in the completely remaining region of the second photoresist is not changed, the photoresist in the completely removed region of the second photoresist is completely removed, and the thickness of the photoresist in the second photoresist portion remains in the region 95. Reduced.
  • the thickness of the second photoresist layer is 2.5 to 3.0 ⁇ m; after the development process, the thickness of the photoresist of the second photoresist portion remaining region 95 is 0.5 to 1.0 ⁇ m.
  • Step S83 removing a portion of the drain electrode 52 protruding above the main via extension portion 72 by an etching process, specifically by a wet etching process, to form a final via hole (the final via hole includes the main via hole 71 and The pattern of the main via extension 72).
  • Step S84 removing the photoresist of the second photoresist partial retention region 95 by an ashing process.
  • Step S85 depositing a transparent conductive film (second transparent conductive film) 80.
  • the material of the transparent conductive film 80 is any one of an ITO/Ag/ITO structure and an Ag/ITO structure; or, the ITO in the above structure is replaced with any one of IZO, IGZO, and InGaSnO.
  • Step S85 removing the remaining photoresist by a step stripping process, and forming a pattern including the common electrode 81 and the connection electrode 82.
  • the method for preparing the array substrate provided in this embodiment effectively solves the problem that the floating layer exists below the drain, and does not increase the process steps, and the formed array substrate has better performance and higher yield.
  • a second embodiment of the present invention provides an array substrate, the array
  • the substrate was prepared by the method of the first embodiment, and its performance was better.
  • a third embodiment of the present invention provides a display device including the array substrate of the second embodiment.
  • the display device may be any product or component having a display function such as a liquid crystal panel, an electronic paper, a mobile phone, a tablet computer, a television, a display, a notebook computer, a digital photo frame, a navigator, and the like.

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CN105070684A (zh) * 2015-07-17 2015-11-18 京东方科技集团股份有限公司 阵列基板的制备方法、阵列基板及显示装置

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CN105070684B (zh) 2018-01-05
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JP6818554B2 (ja) 2021-01-20
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