WO2016169345A1 - 防雾清洁布 - Google Patents

防雾清洁布 Download PDF

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Publication number
WO2016169345A1
WO2016169345A1 PCT/CN2016/075821 CN2016075821W WO2016169345A1 WO 2016169345 A1 WO2016169345 A1 WO 2016169345A1 CN 2016075821 W CN2016075821 W CN 2016075821W WO 2016169345 A1 WO2016169345 A1 WO 2016169345A1
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Prior art keywords
parts
cleaning cloth
agent
fogging
fog
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PCT/CN2016/075821
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English (en)
French (fr)
Inventor
陈善栋
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无锡市豪雅微纤科技有限公司
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Filing date
Publication date
Priority claimed from CN201510185608.0A external-priority patent/CN106137002A/zh
Priority claimed from CN201510951676.3A external-priority patent/CN105544197B/zh
Application filed by 无锡市豪雅微纤科技有限公司 filed Critical 无锡市豪雅微纤科技有限公司
Publication of WO2016169345A1 publication Critical patent/WO2016169345A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid

Definitions

  • the invention relates to the field of anti-fog technology, in particular to an anti-fog cleaning cloth.
  • the application of glass with air-proof and light-transmissive effect is more and more extensive.
  • the phenomenon of fogging on the glass surface often occurs, which affects its normal function. If the window is foggy during rainy or winter driving, the driver will not be able to see the road ahead and the rearview mirror. It is easy to cause traffic accidents; such as the fog of architectural glass windows, bathroom mirrors, and spectacle lenses. It will bring great inconvenience to life.
  • the anti-fog cleaning cloth currently used has a short anti-fog time and a short shelf life, which is not convenient to use.
  • the technical problem to be solved by the present invention is to provide an anti-fog cleaning cloth which has good dispersibility and adhesion, long anti-fog time, non-toxicity and low cost, and is convenient to use and has a long shelf life.
  • an anti-fog cleaning cloth comprising: a cleaning cloth body made of ultra-fine fibers and an anti-fogging agent, wherein the cleaning cloth body is dip coated with
  • the anti-fogging agent is prepared from the following raw materials by weight: 2 to 5 parts of the sustained release agent, 3 to 7 parts of the nano rare earth oxide particles, and 40 to 50 parts of the polyol type nonionic surfactant. , triethanolamine lauric acid monoester 5 to 10 parts, solvent 15 to 25 parts, hydrophilic finishing agent 5 to 10 parts, distilled water 50 to 60 parts.
  • the sustained release agent is talc, diatomaceous earth or kaolin.
  • the nano rare earth oxide particles are nano cerium oxide particles.
  • the polyol type nonionic surfactant is sorbitan monolaurate, sorbitan monostearate or sorbitan monooleate.
  • the nano rare earth oxide particles have a particle diameter of 30 to 100 nm.
  • the solvent is isopropanol.
  • the hydrophilic finishing agent is a polyester polyether copolymer type hydrophilic finishing agent.
  • the sustained release agent is diatomaceous earth having a particle size of 150 to 230 nm.
  • the nano rare earth oxide particles have a particle size of 30 to 50 nm.
  • the invention has the beneficial effects that the invention has good dispersibility and adhesion, long anti-fog time, non-toxicity and low cost, and is convenient to use and has a long shelf life.
  • An anti-fog cleaning cloth comprising: a cleaning cloth body made of ultra-fine fibers and an anti-fogging agent, wherein the cleaning cloth body is immersed with an anti-fogging agent, and the anti-fogging agent is composed of the following parts by weight
  • the raw material is prepared: 2 parts of talc powder sustained-release agent, 3 parts of nanometer cerium oxide particles having a particle diameter of 50 nm, 40 parts of sorbitan monooleate, 5 parts of triethanolamine lauric acid monoester, and 15 parts of isopropyl alcohol solvent. 5 parts of polyester polyether copolymer type hydrophilic finishing agent and 50 parts of distilled water.
  • An anti-fog cleaning cloth comprising: a cleaning cloth body made of ultra-fine fibers and an anti-fogging agent, wherein the cleaning cloth body is immersed with an anti-fogging agent, and the anti-fogging agent is composed of the following parts by weight Made of raw materials: 5 parts of 150 nm diatomaceous earth slow release agent, 7 parts of nanometer cerium oxide particles with a particle size of 30 nm, 50 parts of sorbitan monolaurate, 10 parts of triethanolamine lauric acid monoester, isopropyl 25 parts of alcohol solvent, 10 parts of polyester polyether copolymer type hydrophilic finishing agent, and 60 parts of distilled water.
  • An anti-fog cleaning cloth comprising: a cleaning cloth body made of ultra-fine fibers and an anti-fogging agent, wherein the cleaning cloth body is immersed with an anti-fogging agent, and the anti-fogging agent is composed of the following parts by weight
  • the raw material is prepared: 3 parts of kaolin slow release agent, 5 parts of nanometer cerium oxide particles having a particle diameter of 40 nm, 45 parts of sorbitan monostearate, 7 parts of triethanolamine lauric acid monoester, and 20 parts of isopropyl alcohol solvent. 8 parts of polyester polyether copolymer type hydrophilic finishing agent and 55 parts of distilled water.
  • Example 1 The anti-fog performance and long-term storage stability of the anti-fog cleaning cloth prepared in Example 1 - Example 3 are shown in Table 1.
  • the anti-fog cleaning cloth of the invention has the beneficial effects that the invention has good dispersibility and adhesion, long anti-fog time, non-toxicity and low cost, and is convenient to use and has a long storage period.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

提供了一种防雾清洁布，包括：由超细纤维制成的清洁布本体和防雾剂，所述清洁布本体上浸涂有防雾剂，所述防雾剂由以下重量份数的原料制成：缓释剂2-5份，纳米稀土氧化物粒子3-7份，多元醇型非离子表面活性剂40-50份，三乙醇胺月桂酸单酯5-10份，溶剂15-25份，亲水整理剂5-10份，蒸馏水50-60份。所述防雾清洁布具有良好的分散性和附着性、防雾时间长、无毒、廉价的特点，且使用方便，保存期长。

Description

防雾清洁布 技术领域
本发明涉及防雾技术领域，特别是涉及一种防雾清洁布。
背景技术
随着人们生活水平的提高，具有隔风透光作用的玻璃应用也越来越广泛，但在温湿度发生变化时，常会发生玻璃表面起雾的现象，影响其正常功能。如雨天或冬天开车时常会发生的车窗起雾现象，会导致驾驶人员不能看清前方路况和后视镜的情况，很容易发生交通事故；如建筑玻璃窗、浴室镜子、眼镜镜片的雾化都会给生活带来很大的不便。然而，目前使用的防雾清洁布的防雾时间短，而且保存期也短，使用起来不太方便。
发明内容
本发明主要解决的技术问题是提供一种防雾清洁布，具有良好的分散性和附着性、防雾时间长、无毒、廉价特点，而且使用方便，保存期长。
为解决上述技术问题，本发明采用的一个技术方案是：提供一种防雾清洁布，包括：由超细纤维制成的清洁布本体和防雾剂，所述的清洁布本体上浸涂有防雾剂，所述的防雾剂由以下重量份数的原料制成：缓释剂2～5份，纳米稀土氧化物粒子3～7份，多元醇型非离子表面活性剂40～50份，三乙醇胺月桂酸单酯5～10份，溶剂15～25份，亲水整理剂5～10份，蒸馏水50～60份。
在本发明一个较佳实施例中，所述的缓释剂为滑石粉、硅藻土或高岭土。
在本发明一个较佳实施例中，所述的纳米稀土氧化物粒子为纳米氧化镧粒子。
在本发明一个较佳实施例中，所述的多元醇型非离子表面活性剂为山梨糖醇酐单月桂酸酯、山梨糖醇酐单硬脂酸酯或山梨糖醇酐单油酸酯。
在本发明一个较佳实施例中，所述的纳米稀土氧化物粒子的粒径为30～100nm。
在本发明一个较佳实施例中，所述的溶剂为异丙醇。
在本发明一个较佳实施例中，所述的亲水整理剂为聚酯聚醚共聚型亲水整理剂。
在本发明一个较佳实施例中，所述的缓释剂为硅藻土，其粒径为150～230nm。
在本发明一个较佳实施例中，所述的纳米稀土氧化物粒子的粒径为30～50nm。
本发明的有益效果是：本发明具有良好的分散性和附着性、防雾时间长、无毒、廉价特点，而且使用方便，保存期长。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅是本发明的一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
实施例1
一种防雾清洁布，包括：由超细纤维制成的清洁布本体和防雾剂，所述的清洁布本体上浸涂有防雾剂，所述的防雾剂由以下重量份数的原料制成：滑石粉缓释剂2份，粒径为50nm纳米氧化镧粒子3份，山梨糖醇酐单油酸酯40份，三乙醇胺月桂酸单酯5份，异丙醇溶剂15份，聚酯聚醚共聚型亲水整理剂5份，蒸馏水50份。
实施例2
一种防雾清洁布，包括：由超细纤维制成的清洁布本体和防雾剂，所述的清洁布本体上浸涂有防雾剂，所述的防雾剂由以下重量份数的原料制成：粒径为150nm硅藻土缓释剂5份，粒径为30nm纳米氧化镧粒子7份，山梨糖醇酐单月桂酸酯50份，三乙醇胺月桂酸单酯10份，异丙醇溶剂25份，聚酯聚醚共聚型亲水整理剂10份，蒸馏水60份。
实施例3
一种防雾清洁布，包括：由超细纤维制成的清洁布本体和防雾剂，所述的清洁布本体上浸涂有防雾剂，所述的防雾剂由以下重量份数的原料制成：高岭土缓释剂3份，粒径为40nm纳米氧化镧粒子5份，山梨糖醇酐单硬脂酸酯45份，三乙醇胺月桂酸单酯7份，异丙醇溶剂20份，聚酯聚醚共聚型亲水整理剂8份，蒸馏水55份。
实施例1-实施例3制得的防雾清洁布的防雾性能和长周期储存稳定性如表1所示。
表1
Figure PCTCN2016075821-appb-000001
本发明防雾清洁布的有益效果是：本发明具有良好的分散性和附着性、防雾时间长、无毒、廉价特点，而且使用方便，保存期长。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其它相关的技术领域，均同理包括在本发明的专利保护范围内。

Claims (9)

  1. 一种防雾清洁布，其特征在于，包括：由超细纤维制成的清洁布本体和防雾剂，所述的清洁布本体上浸涂有防雾剂，所述的防雾剂由以下重量份数的原料制成：缓释剂2～5份，纳米稀土氧化物粒子3～7份，多元醇型非离子表面活性剂40～50份，三乙醇胺月桂酸单酯5～10份，溶剂15～25份，亲水整理剂5～10份，蒸馏水50～60份。
  2. 根据权利要求1所述的防雾清洁布，其特征在于，所述的缓释剂为滑石粉、硅藻土或高岭土。
  3. 根据权利要求1所述的防雾清洁布，其特征在于，所述的纳米稀土氧化物粒子为纳米氧化镧粒子。
  4. 根据权利要求1所述的防雾清洁布，其特征在于，所述的多元醇型非离子表面活性剂为山梨糖醇酐单月桂酸酯、山梨糖醇酐单硬脂酸酯或山梨糖醇酐单油酸酯。
  5. 根据权利要求1所述的防雾清洁布，其特征在于，所述的纳米稀土氧化物粒子的粒径为30～100nm。
  6. 根据权利要求1所述的防雾清洁布，其特征在于，所述的溶剂为异丙醇。
  7. 根据权利要求1所述的防雾清洁布，其特征在于，所述的亲水整理剂为聚酯聚醚共聚型亲水整理剂。
  8. 根据权利要求2所述的防雾清洁布，其特征在于，所述的缓释剂为硅藻土，其粒径为150～230nm。
  9. 根据权利要求5所述的防雾清洁布，其特征在于，所述的纳米稀土氧化物粒子的粒径为30～50nm。
PCT/CN2016/075821 2015-04-20 2016-03-07 防雾清洁布 WO2016169345A1 (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
CN201510185608.0 2015-04-20
CN201510185608.0A CN106137002A (zh) 2015-04-20 2015-04-20 一种超细纤维防雾毛巾及其制备工艺
CN201510951676.3 2015-12-18
CN201510951676.3A CN105544197B (zh) 2015-12-18 2015-12-18 防雾清洁布

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050137302A1 (en) * 2003-11-28 2005-06-23 Seiko Epson Corporation Anti-fogging treatment liquid, production method therefor, anti-fogging article and production method therefor
JP2009195648A (ja) * 2008-02-25 2009-09-03 Soft99 Corporation ドライタイプの曇り止めクロス
CN101953660A (zh) * 2010-04-19 2011-01-26 铜陵洁雅生物科技股份有限公司 一种汽车玻璃防雾清洁湿巾及其制备方法
CN102516943A (zh) * 2011-12-08 2012-06-27 华北电力大学 一种防止眼镜片起雾的复合液
CN103160388A (zh) * 2013-03-13 2013-06-19 金红叶纸业集团有限公司 镜片清洁液及湿巾

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050137302A1 (en) * 2003-11-28 2005-06-23 Seiko Epson Corporation Anti-fogging treatment liquid, production method therefor, anti-fogging article and production method therefor
JP2009195648A (ja) * 2008-02-25 2009-09-03 Soft99 Corporation ドライタイプの曇り止めクロス
CN101953660A (zh) * 2010-04-19 2011-01-26 铜陵洁雅生物科技股份有限公司 一种汽车玻璃防雾清洁湿巾及其制备方法
CN102516943A (zh) * 2011-12-08 2012-06-27 华北电力大学 一种防止眼镜片起雾的复合液
CN103160388A (zh) * 2013-03-13 2013-06-19 金红叶纸业集团有限公司 镜片清洁液及湿巾

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WAN, PINGNAN ET AL.: "Study of a Novel Cerium Dioxide Anti-fogging Agent", JOURNAL OF EAST CHINA JIAOTONG UNIVERSITY, vol. 23, no. 1, 28 February 2006 (2006-02-28) *
XING, YING;: "The General Development Situation of Anti-fogging Agents Used in Agricultural Films", JIHUA TECHNOLOGY, 31 December 1997 (1997-12-31) *

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