WO2016161852A1 - 一种增深染发组合物 - Google Patents

一种增深染发组合物 Download PDF

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Publication number
WO2016161852A1
WO2016161852A1 PCT/CN2016/074428 CN2016074428W WO2016161852A1 WO 2016161852 A1 WO2016161852 A1 WO 2016161852A1 CN 2016074428 W CN2016074428 W CN 2016074428W WO 2016161852 A1 WO2016161852 A1 WO 2016161852A1
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Prior art keywords
weight
agent
parts
hair dye
hair
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PCT/CN2016/074428
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English (en)
French (fr)
Inventor
宋子奎
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宋子奎
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Application filed by 宋子奎 filed Critical 宋子奎
Priority to RU2017121623A priority Critical patent/RU2677288C2/ru
Priority to KR1020177025155A priority patent/KR20170118779A/ko
Priority to US15/536,654 priority patent/US10252087B2/en
Priority to EP16776027.1A priority patent/EP3281621A4/en
Priority to JP2017534720A priority patent/JP2018504396A/ja
Publication of WO2016161852A1 publication Critical patent/WO2016161852A1/zh

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35—Ketones, e.g. benzophenone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/736—Chitin; Chitosan; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the invention relates to the technical field of hair dyeing, in particular to a deepening hair dyeing composition.
  • the most used ones are oxidative hair dyes, which contain more than 20 chemical components such as p-phenylenediamine.
  • p-phenylenediamine is often used in excess of the formulation; when used, the amount of hair dye is also increased by 2 to 3 times, and the dyeing time is increased and the dyeing temperature is increased. In this way, too much hair dye is heated after being exposed to the skin, and it is easy to cause benzene organic substances to enter the body through the skin, and long-term repeated action is not good for health.
  • the natural hair dye has the advantage of not harming the body.
  • the disadvantage is that the coloring rate is low, and the color depth of the dyed hair is not full enough. Even if the dyeing is repeated several times, it is difficult to dye the saturated color, which limits the purity to a large extent. Wide use of natural hair dyes.
  • the object of the present invention is to provide a deepening hair dyeing composition, and the deepening hair dyeing composition provided by the invention has the deepening property, and can deepen the unsaturated color dyed by the pure natural hair dye to a saturated color.
  • Chemical hair dyes are dyed to a saturated color at lower levels.
  • the present invention provides a darkening hair dye composition
  • a darkening hair dye composition comprising:
  • a deepening agent selected from one or more of chitin, chitosan, gelatin, silicone oil and resin, and the relative molecules of chitin, chitosan and gelatin
  • a deepening agent selected from one or more of chitin, chitosan, gelatin, silicone oil and resin, and the relative molecules of chitin, chitosan and gelatin
  • the masses are all below 2.7 ⁇ 10 4 , and the refractive indices of the silicone oil and the resin are both below 1.55;
  • the crosslinking agent is selected from one or more of the group consisting of cyanoaldehyde, magnesium chloride, citric acid, glyoxal, crosslinker EH, polyethylene glycol, and antistatic agent A-2ST.
  • it comprises 4 to 45 parts by weight of a deepening agent.
  • the deepening agent is selected from the group consisting of chitin, chitosan or gelatin;
  • the deepening agent is obtained by degradation of a degradation agent selected from the group consisting of an acid degradation agent, an oxidative degradation agent or an enzyme degradation agent.
  • the pH adjusting agent is selected from the group consisting of organic acids, inorganic weak acids, organic bases or inorganic weak bases.
  • the hair dye is selected from the group consisting of a pure natural hair dye or a chemical hair dye.
  • the dyeing agent is selected from the group consisting of salt, Yuanming powder, white peony, saponin, cholesteric acid, acetic acid, sodium carbonate or sodium hydrogencarbonate.
  • the darkening hair dyeing composition further comprises 2 to 98 parts by weight of an additive
  • the additive is selected from one or more of a leveling agent, an antistatic agent, an antiseptic antibacterial agent, and a fragrance.
  • the deepening hair dyeing composition provided by the present invention is mainly composed of the following raw materials: 2 to 98 parts by weight of hair dye; 1 to 99 parts by weight of a deepening agent; 2 to 98 parts by weight of a crosslinking agent.
  • the deepening agent is selected from the group consisting of chitin, chitosan, gelatin, silicone oil And one or more of the resins, the relative molecular masses of the chitin, chitosan and gelatin are all below 2.7 ⁇ 10 4 , and the refractive indices of the silicone oil and the resin are both 1.55 or less.
  • the deepening hair dyeing composition provided by the invention has the effect of deepening and fixing the color, so that the unsaturated color dyed by the natural hair dyeing agent is deepened to a saturated color, so that the chemical hair dye is less. Saturated color is obtained at the dosage.
  • the present invention provides a darkening hair dye composition
  • a darkening hair dye composition comprising:
  • a deepening agent selected from one or more of chitin, chitosan, gelatin, silicone oil and resin, and the relative molecules of chitin, chitosan and gelatin
  • a deepening agent selected from one or more of chitin, chitosan, gelatin, silicone oil and resin, and the relative molecules of chitin, chitosan and gelatin
  • the masses are all below 2.7 ⁇ 10 4 , and the refractive indices of the silicone oil and the resin are both below 1.55;
  • the invention adds a certain amount of a specific deepening agent to the hair dye, and adds a raw material such as a crosslinking agent and a pH adjusting agent, so that the deepening hair dyeing composition provided by the invention achieves the deepening effect when dyeing hair, and the use amount is small, which is favorable for the hair dye. widely used.
  • the darkening hair dye composition provided by the present invention comprises 2 to 98 parts by weight of a hair dye, preferably 2 to 60 parts by weight of a hair dye, in a small amount.
  • the hair coloring agent is preferably a natural hair coloring agent or a chemical hair coloring agent, more preferably a natural hair coloring agent; the natural hair coloring agent generally comprises a plant hair coloring agent, a mineral hair coloring agent and an animal hair coloring agent.
  • the plant hair dye comprises carotenoids, anthraquinones, naphthoquinones, flavonoids, curcumin, indigo and chlorophyll, such as grass, valerian, amaranth, clove , valerian, Susong, Yusong, white peony, indigo, algae, comfrey, purple, hematoxylin, indigo, safflower, pomegranate, scutellaria, mugwort, rhubarb, schisandra, radix isatidis, bluegrass, ginger Gold, glutinous rice, frozen green, soap, ebony, gallnut, oak bucket, millet shell, lotus seed shell, persimmon, avocado, polygonum multiflorum, yam, indigo, perilla, ink tree, red wine, coffee, tea , barley, beer, lemon, Chrysanthemum.
  • carotenoids such as grass, valerian, amaranth, clove , va
  • the mineral hair dye comprises various inorganic metal salts and metal oxides and ores, such as cinnabar, orpiment, vermiculite, lapis lazuli, malachite, turquoise, carbon black, gold and silver foil.
  • the animal hair dyes include, but are not limited to, insect shellac and carmine.
  • the chemical hair dye includes black dye 401, red dye 102, acid sexual brown RH, orange yellow, brown RH, trioxobenzene azoquinoline, p-phenylenediamine powder.
  • the silicone oil is also called silicone oil, and is a polyorganosiloxane having different polymerization degree chain structure, and is preferably prepared according to the following method: hydrolyzing dimethyldichlorosilane with water to obtain a preliminary polycondensation ring, ring body After the cracking and rectification, a low ring body is obtained, and then the low ring body, the heading agent and the catalyst are mixed, and the low boiling material is distilled off under reduced pressure to obtain a silicone oil; and the modified silicone oil or the silicone oil derivative is also included.
  • the silicone oil includes but is not limited to alkyl silicone oil, hydroxy silicone oil, amino silicone oil, phenyl silicone oil, fluorine-containing silicone oil, cyanide-containing silicone oil, ternary block silicone oil, polyether modified silicone oil, such as methyl silicone oil, ethyl Silicone oil, methyl hydrogen silicone oil, methyl phenyl silicone oil, methyl chlorophenyl silicone oil, methyl ethoxy silicone oil, methyl trifluoropropyl silicone oil, long chain alkyl silicone oil, cationic reactive silicone oil and aldehyde free Silicone oil; the silicone oil is preferably dimethyl silicone oil, octamethyl silicone oil, decamethylpentasiloxane or fluorine-containing silicone oil.
  • the resin is preferably an organic fluororesin, a silicone resin, a polyamine resin or a urethane resin, and more preferably an organic fluororesin.
  • the refractive index of the silicone oil and the resin are all below 1.55; since the refractive index of the general natural fiber is about 1.62, the present invention uses a silicone oil having a refractive index of 1.55 or less and a resin as a deepening agent, so that the color of the dyed hair can be obtained. Deeper.
  • the refractive index of the silicone oil is preferably between 1.40 and 1.45.
  • the present invention is not particularly limited to the source of the silicone oil and resin; in the embodiment of the present invention, the silicone oil may be an amino silicone oil of the type SILANOL SF9188 or SILANOL SF9103.
  • the silicone oil or resin may also impart other effects to the dyed hair, such as to impart antistatic properties to the hair, increase stiffness, and the like.
  • the deepening agent is silicone oil, resin and chitosan, and the invention utilizes an elastic network structure of silicone oil and resin to impart high tensile strength and elasticity to the chitosan film and Washable.
  • the chitin is mainly derived from the outer shell of aquatic shellfish such as shrimps and crabs; and the chitosan is also called chitosan, which is hydrolyzed by chitin under alkaline conditions. Formed by the acetyl group.
  • the chitin and chitosan are high polymers of polysaccharides, and contain a large amount of hydroxyl groups and amino groups in a molecular structure; the gelatin is a substance obtained by degrading collagen in tissues such as animal skin and bone.
  • the invention utilizes the deepening property of chitin, chitosan and gelatin, and is used in other raw materials such as a crosslinking agent. Multi-functional synergy to overcome other deficiencies, so that the hair is darkened and other good effects in the dyeing process.
  • the present invention overcomes the disadvantages of low adsorption rates of chitin, chitosan and gelatin to hair protein fibers.
  • Hair belongs to protein fibers, which are amphoteric fibers containing acidic groups and basic groups.
  • the deepening agent of the invention such as chitosan molecule, contains a large amount of -NH 2 and -OH groups, has good affinity with hair fibers, can be dissolved into hair fibers, hair fibers and active groups -OH and —NH 2 is bonded by hydrogen bonding or covalent bonding.
  • chitin or chitosan must be degraded into oligosaccharides with a certain molecular weight to have good adsorption and durability.
  • the relative molecular masses of the chitin, chitosan and gelatin are all 2.7 ⁇ 10 4 or less, preferably 2.0 ⁇ 10 4 to 2.6 ⁇ 10 4 ; the present invention uses chitin, chitosan and gelatin. Commercial products are available.
  • the deepening agent is selected from the group consisting of chitin, chitosan or gelatin; the deepening agent is preferably produced by degradation of a degrading agent.
  • the degradation agent is preferably derived from an acid degradation agent, an oxidative degradation agent or an enzyme degradation agent; specifically, the degradation agent includes, but is not limited to, phosphoric acid (H 3 PO 4 ), hydrochloric acid (HCl), Hydrofluoric acid (HF), nitric acid (HNO 3 ), acetic acid (CH 3 COOH), hydrogen peroxide (H 2 O 2 ), ozone, sodium perborate, chitosanase, chitosanase (chitinase), Lysozyme, esterase, lipase, hemicellulase, cellulase, chymase, protease or pectinase.
  • a deepening agent is obtained by an acid degradation method, that is, degradation of chitosan or the like by an acid is the most basic and simple method.
  • chitosan can be severely degraded by the action of inorganic strong acids such as HCl, H 3 PO 4 , HF and HNO 3 , and it utilizes a large number of free amino groups in the chitosan molecule to bind to H + in the solution, causing the shell.
  • the hydrogen bond breaks between the molecules of the glycan and the inside of the molecule, so that the molecular structure is stretched, and the long-chain portion is prone to cleavage of the glycosidic bond, forming a plurality of molecular fragments having different degrees of polymerization.
  • a deepening agent is prepared by an oxidative degradation process.
  • H 2 O 2 is a highly oxidizing oxidizing agent, which has the advantages of non-toxic and non-byproducts for oxidative degradation of chitosan, and low molecular mass under acid, alkali and neutral conditions. Chitosan.
  • the H 2 O 2 degradation process is the formation of various free radicals HO 2 ⁇ , HO ⁇ and (O) formed by ionization of H 2 O 2 in aqueous solution, wherein the highly active HO ⁇ and the new ecological (O) are extremely strong.
  • Their oxidative properties which attack the ⁇ (1,4) glycosidic bonds on the chitosan with active NH 2+ , causing them to depolymerize.
  • a deepening agent is prepared by an enzymatic (down) solution.
  • the enzymatic degradation method has no side reaction, mild degradation conditions, and the degradation process and the relative molecular weight distribution of the degradation products are easy to control.
  • the prepared oligomeric chitosan has high biological activity and the product does not need to be desalted.
  • it is divided into specific enzymatic degradation (such as chitosanase, lysozyme) and non-specific enzyme degradation (such as lipase, protease and cellulase).
  • specific enzymatic degradation such as chitosanase, lysozyme
  • non-specific enzyme degradation such as lipase, protease and cellulase.
  • ozone, sodium perborate method, periodate method, hypo-lactate method, and physical methods such as microwave and radiation can be used to degrade chitin or chitosan, thereby obtaining the increase of the present invention. Deep agent.
  • the invention secondly overcomes the disadvantages of poor adsorption fastness and water-resistant washing of chitosan: the deepening agent such as chitosan is not dried, and the wet washing fastness is poor, and once rinsed, it is easy to fall off, and it can not reach Expected deepening and other effects.
  • the present invention employs a crosslinking agent to introduce a hydroxyl group into the chitosan film by electrostatic attraction and complexation with the hair fiber. Thereby increasing the adsorption fastness of chitosan.
  • the complex with good hygroscopicity is combined on the chitosan film to improve the hygroscopicity and temperature permeability of the chitosan film, so as to improve the moisture resistance and wet cleaning fastness of the chitosan film. Effects such as deepening have a certain durability.
  • the darkening hair dye composition provided by the present invention comprises 2 to 98 parts by weight of a crosslinking agent, preferably 5 to 40 parts by weight of a crosslinking agent.
  • the crosslinking agent is preferably one or more selected from the group consisting of cyanuric acid, magnesium chloride, citric acid, glyoxal, crosslinking agent EH, polyethylene glycol, and antistatic agent A-2ST.
  • glyoxal is used as a crosslinking agent, and the stable mixed emulsion has strong adsorption force to the hair, and can impart good gas permeability, moisture permeability, moisture absorption and resistance to the chitosan film. Bending stiffness.
  • the darkening hair dye composition comprises from 2 to 98 parts by weight of an emulsifier, preferably from 10 to 80 parts by weight of an emulsifier.
  • the emulsifier mainly comprises a cationic emulsifier, an anionic emulsifier, a zwitterionic emulsifier and a nonionic emulsifier.
  • a zwitterionic emulsifier and/or a nonionic emulsifier is preferably used as an emulsifier.
  • the emulsifier is a silicone emulsifier such as an aminosilicone oil emulsifier and a dimethyl silicone oil emulsifier.
  • the darkening hair dye composition comprises 2 to 98 parts by weight of a dyeing aid, preferably 10 to 80 parts by weight.
  • Dyeing aid is preferably self-salt salt, Yuanming powder, white peony, saponin, cholesteric acid, acetic acid, sodium carbonate or sodium hydrogencarbonate.
  • the darkening hair dye composition comprises 0.1 to 40 parts by weight of a pH adjusting agent, preferably 1 to 30 parts by weight of a pH adjusting agent.
  • the pH adjusting agent is selected from the group consisting of organic acids, inorganic weak acids, organic bases or inorganic weak bases.
  • the pH adjusting agent can be further divided into an acid regulator and a basic regulator, wherein the acid regulators such as citric acid, sorbic acid, lactic acid, tartaric acid, malic acid, metatartaric acid, phosphoric acid, acetic acid (acetic acid), hydrochloric acid, Oxalic acid, fumaric acid; alkaline regulators such as sodium bicarbonate, disodium hydrogen phosphate, sodium carbonate, sodium citrate, potassium citrate, trisodium hydrogencarbonate (sodium sesquicarbonate), monosodium citrate.
  • the acid regulators such as citric acid, sorbic acid, lactic acid, tartaric acid, malic acid, metatartaric acid, phosphoric acid, acetic acid (acetic acid), hydrochloric acid, Oxalic acid, fumaric acid
  • alkaline regulators such as sodium bicarbonate, disodium hydrogen phosphate, sodium carbonate, sodium citrate, potassium citrate, trisodium hydrogencarbonate (sodium sesquicarbonate
  • the darkening hair dye composition preferably further comprises 2 to 98 parts by weight of an additive;
  • the additive may be selected from the group consisting of a leveling agent, a penetrating agent, an antistatic agent, an antiseptic antibacterial agent, and a fragrance.
  • One or more kinds of other functional additives may also be used.
  • the leveling agent includes, but is not limited to, a flattening plus O, a leveling agent OP, and a leveling agent 102.
  • the antistatic agent includes a friction coefficient type, a conductivity type, and an ionic type and a nonionic type, and the ionic type includes an anionic type, a cationic type, and a zwitterionic type; for example, polyethylene glycol, sorbitol, polyoxyethylene castor oil, Polyoxyethylene lauric acid, polyethylene glycol, sulfonate, acid phosphate, neutral phosphate, amine salt, quaternary ammonium salt, alkyl imidazoline, polyol, polyol ester, alkyl amine epoxy Ethane adduct.
  • the antiseptic antibacterial agent may be rare earth and its derivatives, nisin, natamycin, red yeast rice, lysozyme, protamine, propolis, agar oligosaccharide, eucommia, benzoic acid, sodium benzoate One or more of potassium sorbate, sodium dehydroacetate and sodium diacetate.
  • the darkening hair dye composition provided by the present invention can be prepared as follows:
  • a deepening agent selected from one or more of chitin, chitosan, gelatin, silicone oil and resin, and the relative molecules of chitin, chitosan and gelatin
  • a deepening agent selected from one or more of chitin, chitosan, gelatin, silicone oil and resin, and the relative molecules of chitin, chitosan and gelatin
  • the masses are all below 2.7 ⁇ 10 4 , and the refractive indices of the silicone oil and the resin are both below 1.55;
  • the raw materials are mixed at a temperature of 0 to 200 ° C to obtain a darkening hair dye composition.
  • the mixing specifically includes:
  • the emulsion is mixed with a pH-adjusted mixture to obtain a darkening hair dye composition.
  • the mixing, emulsification, and the like are technical means well known to those skilled in the art; the temperature of the mixing is preferably from 20 ° C to 100 ° C.
  • the hair dyeing method of the hair dyeing composition containing the pure natural hair dye comprises: one dose dyeing method: 1 hair dyeing composition dosage: short hair 20-30 grams, medium long hair 50-60 grams. 2 Method of operation: Apply the hair dye composition to the hair, wrap it in a hot towel for 30 to 40 minutes, then wash it with warm water.
  • Two-dose dyeing method 1 dyeing hair composition dosage: short hair 20 ⁇ 30 grams, medium long hair 50 ⁇ 60 grams. 2 Operation method: Mix the hair dyeing composition and the dyeing agent in a 1:1 ratio, stir evenly, and evenly spread on the hair. Wrap it in a hot towel. After 30 to 40 minutes, wash it with warm water.
  • the hair dyeing method of the hair dyeing composition containing the chemical hair dye comprises: 1 hair dyeing composition dosage: short hair 10-20 grams, medium long hair 20-30 grams. 2 Dyeing method: Apply the hair dyeing composition to the hair, leave it for 10 to 30 minutes, and wash it with warm water.
  • the deepening hair dye composition obtained by the present invention mainly comprises 2 to 98 parts by weight of a hair dye, 1 to 99 parts by weight of a deepening agent, 2 to 98 parts by weight of a crosslinking agent, 2 to 98 parts by weight of an emulsifier, 2 ⁇ 98 parts by weight of the dyeing agent and 0.1 to 40 parts by weight of the pH adjusting agent; in the present invention, the hair dye can dye the hair to a certain depth; under the action of the deepening agent and the crosslinking agent, The unsaturated color dyed by the natural hair dye can be deepened to finally obtain the saturated depth color, or the amount of the chemical hair dye can be greatly reduced; at the same time, the dyeing time can be shortened, the hair dyeing temperature can be reduced, and the damage to the human body can be relatively reduced.
  • the deepening hair dyeing composition provided by the invention has the effect of deepening and fixing the color, so that the unsaturated color dyed by the natural hair dyeing agent is deepened to a saturated color, so that the chemical hair dye is less. Saturated color under the dosage
  • the darkening hair dye composition of the present invention has the following other functions: the present invention overcomes the stiffening property of the deepening agent, etc., so that the darkening hair dyeing composition has the function of a hair comforting agent, and the dyed hair is dyed. It has the functions of moisturizing, suppleness and fluffiness.
  • the invention can utilize the excellent fixing effect of the deepening agent to improve the hair dyeing fastness of the deepening hair dyeing composition.
  • the invention can make the hair after dyeing hard to generate static electricity, can also give the dyed hair better anti-slip performance, and can also make the dyed hair have antibacterial, antibacterial and immune effects.
  • the pH of the mixture was adjusted to 4 to 5 with 1 part by weight of acetic acid.
  • the pH of the mixture was adjusted to 5 to 6 with 1 part by weight of acetic acid.
  • the mixture of the emulsion and the pH-adjusted value was mixed at 20 ° C to obtain a hair dye composition.
  • the pH of the mixture was adjusted to 7-8 with 1 part by weight of acetic acid.
  • amino silicone oil emulsifier AMM or AMH purchased from Hai'an Petrochemical Plant, Jiangsuzhou
  • a pH-adjusted mixture 50 parts by weight of an amino silicone oil emulsifier (amino silicone oil emulsifier AMM or AMH, purchased from Hai'an Petrochemical Plant, Jiangsuzhou) and a pH-adjusted mixture were mixed at 20 ° C to obtain a hair dye composition.
  • An organic fluororesin (purchased from Dalian Botai Co., Ltd.) having a refractive index of 1.38 was used as a deepening agent.
  • emulsifier dimethyl silicone oil emulsifier 1# or 2#, purchased from Hai'an Petrochemical Plant, Jiangsuzhou
  • 30 parts by weight of the deepening agent was emulsified into an emulsion.
  • the pH of the mixture was adjusted to 6 to 7 with 1 part by weight of acetic acid.
  • the mixture of the emulsion and the pH-adjusted mixture was mixed at 20 ° C to obtain a darkening hair dye composition.
  • the pH of the mixture was adjusted to 2 to 3 with 1 part by weight of acetic acid.
  • Gelatin (industrial gelatin, purchased from Shanghai Lubo Gelatin Co., Ltd.) was used as a deepening agent.
  • the pH of the mixture was adjusted to 4 to 5 with 1 part by weight of hydrochloric acid.
  • the mixture of the emulsion and the pH-adjusted mixture was mixed at 20 ° C to obtain a darkening hair dye composition.
  • the pH of the mixture was adjusted to 6 to 7 with 1 part by weight of hydrochloric acid.
  • emulsifier powder distribution environmental emulsifier GS-730 or GS-930, purchased from Shanghai Zhongyu Fine Chemical Co., Ltd.
  • pH-adjusted mixture 40 parts by weight of an emulsifier (narrow distribution environmental emulsifier GS-730 or GS-930, purchased from Shanghai Zhongyu Fine Chemical Co., Ltd.) and a pH-adjusted mixture were mixed at 20 ° C to obtain a hair dye composition.
  • Dimethyl silicone oil (purchased from Shandong Dayi Co., Ltd.) having a refractive index of 1.43 was used as a deepening agent.
  • the pH of the mixture was adjusted to 6 to 7 with 1 part by weight of sodium citrate.
  • the mixture of the emulsion and the pH-adjusted mixture was mixed at 20 ° C to obtain a darkening hair dye composition.
  • the pH of the mixture was adjusted to 5 to 6 with 1 part by weight of sodium citrate.
  • a hair dye composition was obtained by mixing 10 parts by weight of a nonionic emulsifier (Model NP-4, purchased from Hai'an Petrochemical Plant, Jiangsuzhou) and a pH-adjusted mixture at 20 °C.
  • a nonionic emulsifier Model NP-4, purchased from Hai'an Petrochemical Plant, Jiangsuzhou
  • a pH-adjusted mixture at 20 °C.
  • Amino silicone oil (purchased from Shandong Dayi Co., Ltd.) having a refractive index of 1.35 was used as a deepening agent.
  • an anionic emulsifier environmentally friendly anionic reactive emulsifier, purchased from Nanjing Xinhai Trading Co., Ltd.
  • 30 parts by weight of the deepening agent was emulsified into an emulsion.
  • the pH of the mixture was adjusted to 4 to 5 with 1 part by weight of tartaric acid.
  • the mixture of the emulsion and the pH-adjusted mixture was mixed at 20 ° C to obtain a darkening hair dye composition.
  • the pH of the mixture was adjusted to 8 to 9 with 1 part by weight of tartaric acid.
  • a mixture of 5 parts by weight of an anionic emulsifier (Model Dow DOWFAX 2A1, available from Guangzhou Fengshun Trading Co., Ltd.) and pH-adjusted was mixed at 20 ° C to obtain a hair dye composition.
  • the hair dyeing compositions obtained in Examples 1 to 6 and the hair dye compositions obtained in Comparative Examples 1 to 6 were dyed according to the method described above, and the color comparison of the hair after dyeing was shown in Table 1.
  • Table 1 is the present invention.
  • the hair dyeing results of the hair dye compositions provided in Examples 1 to 6 and Comparative Examples 1 to 6 were compared.
  • the deepening hair dyeing composition provided by the present invention is mainly composed of the following raw materials: 2 to 98 parts by weight of hair dye; 1 to 99 parts by weight of deepening agent; 2 to 98 parts by weight of a crosslinking agent; 2 to 98 parts by weight of an emulsifier; 2 to 98 parts by weight of a dyeing agent; 0.1 to 40 parts by weight of a pH adjusting agent; wherein the deepening agent is selected from the group consisting of chitin, chitosan, gelatin One or more of silicone oil and resin, the relative molecular mass of the chitin, chitosan and gelatin are all below 2.7 ⁇ 10 4 , and the refractive indices of the silicone oil and the resin are both 1.55 or less.
  • the deepening hair dyeing composition provided by the invention has the deepening performance under the synergistic combination of the raw materials, and the saturated deep color can be obtained by dyeing the hair with a small
  • the present invention overcomes the stiffening properties of the deepening agent, etc., so that the darkening hair dyeing composition has the function of a hair comforting agent, and has a moisturizing, supple and fluffy effect on the dyed hair.
  • the invention can utilize the excellent fixing effect of the deepening agent to improve the hair dyeing fastness of the deepening hair dyeing composition.
  • the invention can make the hair after dyeing hard to generate static electricity, can also give the dyed hair better anti-slip performance, and can also make the dyed hair have antibacterial, antibacterial and immune effects.

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Abstract

一种增深染发组合物，包括：2～98重量份的染发剂；1～99重量份的增深剂、2～98重量份的交联剂、2～98重量份的乳化剂、2～98重量份的助染剂、0.1～40重量份的pH值调节剂。所述增深剂选自甲壳素、壳聚糖、明胶、硅油和树脂中的一种或多种，其中甲壳素、壳聚糖和明胶的相对分子质量均在2.7×10 4以下，所述硅油和树脂的折射率均在1.55以下。

Description

一种增深染发组合物
本申请要求于2015年04月09日提交中国专利局、申请号为201510166807.7、发明名称为“一种增深染发组合物”的中国专利申请的优先权，其全部内容通过引用结合在本申请中。
技术领域
本发明涉及毛发染色技术领域，尤其涉及一种增深染发组合物。
背景技术
化学染发剂中，目前用的最多的是氧化型染发剂，其含有20余种化学成分，如对苯二胺。为了达到饱满的染色深度效果，制剂时，往往会超限量使用对苯二胺；使用时，染发剂的用量也会增加2～3倍，同时还会成倍增加染色时间和提高染色温度。这样一来，过多染发剂接触到皮肤后被加热，容易使苯类有机物通过皮肤进入体内，长期反复作用不利于身体健康。
当今人们追求健康，崇尚自然，迫切需求安全无毒、不会引起皮肤过敏的染发剂，研发开发安全无毒染发剂成为染发剂的发展方向之一。纯天然染发剂则应运而生，其主要成分是从天然植物、矿物或动物中提取的纯天然元素，对人体无害无毒、对毛发不产生原发性刺激，也不会引起皮肤过敏。
纯天然染发剂的优点是不伤害身体，缺点是上色率较低，染后毛发的颜色深度不够饱满，即使重复数次染色，也难以染得饱和颜色，这在很大程度上限制了纯天然染发剂的广泛使用。
发明内容
有鉴于此，本发明的目的在于提供一种增深染发组合物，本发明提供的增深染发组合物具有增深性能，可使纯天然染发剂所染的不饱和颜色增深至饱和颜色，使化学染发剂在较少用量下染得饱和颜色。
本发明提供一种增深染发组合物，包括：
2～98重量份的染发剂；
1～99重量份的增深剂，所述增深剂选自甲壳素、壳聚糖、明胶、硅油和树脂中的一种或多种，所述甲壳素、壳聚糖和明胶的相对分子质量均在2.7×104以下，所述硅油和树脂的折射率均在1.55以下；
2～98重量份的交联剂；
2～98重量份的乳化剂；
2～98重量份的助染剂；
0.1～40重量份的pH值调节剂。
优选的，所述交联剂选自氰醛、氯化镁、柠檬酸、乙二醛、交联剂EH、聚乙二醇和抗静电剂A-2ST中的一种或多种。
优选的，包括5～40重量份的交联剂。
优选的，包括4～45重量份的增深剂。
优选的，所述增深剂选自甲壳素、壳聚糖或明胶；
所述增深剂通过降解剂降解制得，所述降解剂选自酸类降解剂、氧化类降解剂或酶类降解剂。
优选的，所述pH值调节剂选自有机酸、无机弱酸、有机碱或无机弱碱。
优选的，包括2～60重量份的染发剂；
所述染发剂选自纯天然染发剂或化学染发剂。
优选的，所述乳化剂选自两性离子型乳化剂和/或非离子型乳化剂。
优选的，所述助染剂选自食盐、元明粉、白矾、皂矾、胆矾、醋酸、碳酸钠或碳酸氢钠。
优选的，所述增深染发组合物还包括2～98重量份的添加剂；
所述添加剂选自匀染剂、抗静电剂、防腐抗菌剂和香精中的一种或多种。
与现有技术相比，本发明提供的增深染发组合物主要由以下原料构成：2～98重量份的染发剂；1～99重量份的增深剂；2～98重量份的交联剂；2～98重量份的乳化剂；2～98重量份的助染剂；0.1～40重量份的pH值调节剂；其中，所述增深剂选自甲壳素、壳聚糖、明胶、硅油和树脂中的一种或多种，所述甲壳素、壳聚糖和明胶的相对分子质量均在2.7×104以下，所述硅油和树脂的折射率均在1.55以下。在本发明中，染发剂可将毛发染成一定深度的颜色；在增深剂和交联剂等作用下，可将纯天然染发剂所染的不饱和颜色被增深，最终得到饱和深度颜色，或者可大大减少化学染发剂的用量；同时可以缩短染发时间，降低染发温度，从而相对减少对人体的伤害，且能提高染色牢度，延长染发间隔时间，减少重复染发次数。因此，在各原料协同综合作用下，本发明提 供的增深染发组合物具有增深固色性能，使纯天然染发剂所染的不饱和颜色增深至饱和颜色，使化学染发剂在较少用量下染得饱和颜色。
具体实施方式
本发明提供了一种增深染发组合物，包括：
2～98重量份的染发剂；
1～99重量份的增深剂，所述增深剂选自甲壳素、壳聚糖、明胶、硅油和树脂中的一种或多种，所述甲壳素、壳聚糖和明胶的相对分子质量均在2.7×104以下，所述硅油和树脂的折射率均在1.55以下；
2～98重量份的交联剂；
2～98重量份的乳化剂；
2～98重量份的助染剂；
0.1～40重量份的pH值调节剂。
本发明在染发剂中添加一定量特定的增深剂，并添加交联剂和pH值调节剂等原料，使本发明提供的增深染发组合物染发时达到增深效果，使用量少，利于广泛应用。
本发明提供的增深染发组合物包括2～98重量份的染发剂，优选包括2～60重量份的染发剂，用量较少。所述染发剂优选自纯天然染发剂或化学染发剂，更优选自纯天然染发剂；所述纯天然染发剂一般包括植物染发剂、矿物染发剂和动物染发剂。在本发明的实施例中，所述植物染发剂包括胡萝卜素类、蒽醌类、萘醌类、类黄酮类、姜黄素类、靛蓝类和叶绿素类，具体如甲草、茜草、苋菜、丁香、荩草、苏枋、于松、白芨、靛青、藻荷、紫草、紫色菜、苏木、靛蓝、红花、石榴、黄栀子、艾蒿、大黄、五味子、板蓝根、蓝草、姜金、槐米、冻绿、皂斗、乌柏、五倍子、橡斗、粟壳、莲子壳、柿子、油梨果、何首乌、薯莨、崧蓝、紫苏、墨水树、红酒、咖啡、茶、青黛、啤酒、柠檬、杭白菊。在本发明的实施例中，所述矿物染发剂包括各种无机金属盐和金属氧化物以及矿石类，具体如朱砂、雌黄、赭石、天青石、孔雀石、绿松石、炭黑、金银箔、珊瑚；所述动物染发剂包括但不限于虫紫胶和胭脂红虫。
在本申请的实施例中，所述化学染发剂包括黑染料401、红染料102、酸 性络褐RH、橙黄、棕RH、三氧苯甲烷偶氮喹啉、对苯二胺粉末。
所述增深染发组合物包括1～99重量份的增深剂，优选包括4～45重量份的增深剂；所述增深剂选自甲壳素、壳聚糖、明胶、硅油和树脂中的一种或多种，所述甲壳素、壳聚糖和明胶的相对分子质量均在2.7×104以下，所述硅油和树脂的折射率均在1.55以下。
其中，所述硅油也称有机硅油，是一种不同聚合度链状结构的聚有机硅氧烷，优选按照如下方法制备：将二甲基二氯硅烷加水水解制得初缩聚环体，环体经裂解、精馏制得低环体，然后将低环体、封头剂与催化剂混合，减压蒸馏除去低沸物得到有机硅油；也包括改性硅油或有机硅油衍生物。所述硅油包括但不限于烷基硅油、羟基硅油、氨基硅油、苯基硅油、含氟硅油、含氰硅油、三元嵌段有机硅油、聚醚改性硅油，具体如甲基硅油、乙基硅油、甲基含氢硅油、甲基苯基硅油、甲基氯苯基硅油、甲基乙氧基硅油、甲基三氟丙基硅油、长链烷基硅油、阳离子反应型有机硅油和无醛有机硅油；所述硅油优选为二甲基硅油、八甲基硅油、十甲基五硅氧烷或含氟硅油。所述树脂优选为有机氟树脂、有机硅树脂、聚胺类树脂或聚氨酯树脂，更优选为有机氟树脂。所述硅油和树脂的折射率均在1.55以下；由于一般的天然纤维折射率在1.62左右，本发明采用折射率均在1.55以下的硅油和树脂为增深剂，能使染后的毛发的色泽变深。在本发明的实施例中，所述硅油的折射率优选在1.40～1.45之间。本发明对所述硅油和树脂的来源没有特殊限制；在本发明的实施例中，所述硅油可为型号为SILANOL SF9188或SILANOL SF9103的氨基硅油。
另外，所述硅油或树脂还可赋予染后的毛发其他效果，如还能使毛发具有抗静电性，增加硬挺度等。在本发明的优选实施例中，所述增深剂为硅油、树脂和壳聚糖，本发明利用有机硅油和树脂的弹性网状结构，赋予壳聚糖薄膜很高的抗拉强度和弹以及耐水洗性。
在本发明所述增深剂中，所述甲壳素主要来源于虾、蟹等水生贝壳动物的外壳；所述壳聚糖又称脱乙酰甲壳素，是由甲壳素在碱性条件下水解脱掉乙酰基而形成的。所述甲壳素和壳聚糖是多糖的高聚物，在分子结构中含有大量的羟基和氨基；所述明胶是由动物皮肤和骨等组织中的胶原部分降解而成的物质。本发明利用甲壳素、壳聚糖和明胶的增深属性，并在交联剂等其他原料的 多功能协同作用下克服其他不足属性，使毛发在染色过程中获得颜色被增深以及其他良好效果。
首先，本发明要克服甲壳素、壳聚糖和明胶对毛发这种蛋白质纤维吸附率低的不足。毛发属于蛋白质纤维，蛋白质纤维都是含有酸性基团和碱性基团的两性纤维。本发明增深剂如壳聚糖分子中含有大量的—NH2及—OH基团，与毛发纤维的亲和性较好，可以溶入到毛发纤维内部，毛发纤维与活性基团—OH及—NH2以氢键或共价键结合。但是，壳聚糖分子在酸性浴中与毛发纤维上已电离的羧基结合，使毛发纤维带有正电荷，这样会阻碍壳聚糖的继续吸附和大量吸附。由于吸附量太小，因而影响成膜厚度，很难达到预期的增深等效果。申请人研究发现，像甲壳素或壳聚糖这样的增深剂相对分子量越小，越有利于促进其在毛发纤维中的扩散，使其吸附率增大，从而使毛发得到较好的增深效果。因此，甲壳素或壳聚糖必须降解为具有一定分子量的低聚糖后才有良好的吸附性和耐久性。在本发明中，所述甲壳素、壳聚糖和明胶的相对分子质量均在2.7×104以下，优选为2.0×104～2.6×104；本发明采用甲壳素、壳聚糖和明胶的市售商品即可。
在本发明的优选实施例中，所述增深剂选自甲壳素、壳聚糖或明胶；所述增深剂优选通过降解剂降解制得。在本发明中，所述降解剂优选自酸类降解剂、氧化类降解剂或酶类降解剂；具体的，所述降解剂包括但不限于磷酸(H3PO4)、盐酸(HCl)、氢氟酸(HF)、硝酸(HNO3)、醋酸(CH3COOH)、双氧水(H2O2)、臭氧、过硼酸钠、壳聚糖酶、脱乙酰甲壳素酶(甲壳素酶)、溶菌酶、酯酶、脂肪酶、半纤维素酶、纤维素酶、糠酶、蛋白酶或果胶酶。
在本发明的一个实施例中，采用酸降解法制得增深剂，即利用酸对壳聚糖等进行降解，这是最基本和简单的方法。具体的，壳聚糖能在HCl、H3PO4、HF和HNO3等无机强酸作用下发生剧烈降解，它是利用壳聚糖分子中存在众多的游离氨基与溶液中H+结合，引起壳聚糖分子间与分子内部的氢键断裂，使分子结构舒展，而长链部分易发生糖苷键断裂，形成许多聚合度不等的分子片段。
在本发明的另一个实施例中，采用氧化降解法制得增深剂。比如，H2O2是一种氧化能力很强的氧化剂，用它对壳聚糖氧化降解具有无毒、无副产物的 优点，并且在酸、碱和中性条件下都可得到低分子质量壳聚糖。H2O2降解过程是利用H2O2在水溶液中电离形成的各种游离基团HO2·、HO·及(O)，其中高活性的HO·和新生态的(O)具有极强的氧化性能，它们攻击壳聚糖上那些带有活泼NH2+的β(1,4)糖苷键，致使其解聚。
在本发明的另一个实施例中，采用酶(降)解法制得增深剂。与其它降解方法相比，酶降解法具有无副反应、降解条件温和、降解过程及降解产物相对分子量分布容易控制、制备的低聚壳聚糖生物活性高，产物不用除盐等优势。根据使用的酶不同，又分为专一性酶降解(如壳聚糖酶、溶菌酶)和非专一性酶降解(如脂肪酶、蛋白酶和纤维素酶等)。另外，还可采用臭氧法、过硼酸钠法、高碘酸盐法、次乳酸盐法以及微波、射线辐射等物理方法进行甲壳素或壳聚糖的降解，从而制得本发明所述增深剂。
本发明其次要克服壳聚糖等吸附牢度差和不耐水洗的不足：壳聚糖等增深剂不经烘干，湿洗牢度较差，一经漂洗，极易脱落，也达不到预期的增深等效果。为了提高壳聚糖增深效果的耐久性、尤其是湿膜耐水洗牢度，本发明采用交联剂，通过与毛发纤维发生静电吸引和络合作用，在壳聚糖薄膜中引入了羟基，从而增加壳聚糖的吸附牢度。同时，将具有良好吸湿性的络合物结合在壳聚糖薄膜之上，可提高壳聚糖薄膜的吸湿性和透温性，以提高壳聚糖薄膜的耐湿性和湿洗牢度，使增深等效果具有一定的耐久性。
本发明提供的增深染发组合物包括2～98重量份的交联剂，优选包括5～40重量份的交联剂。在本发明中，所述交联剂优选自氰醛、氯化镁、柠檬酸、乙二醛、交联剂EH、聚乙二醇和抗静电剂A-2ST中的一种或多种。在本发明的一个实施例中，采用乙二醛做交联剂，其稳定的混合乳液对毛发有很强的吸附力，并能赋予壳聚糖薄膜良好的透气、透湿、吸湿性和抗弯刚度。
所述增深染发组合物包括2～98重量份的乳化剂，优选包括10～80重量份的乳化剂。所述乳化剂主要包括阳离子型乳化剂、阴离子型乳化剂、两性离子型乳化剂和非离子型乳化剂，本发明优选采用两性离子型乳化剂和/或非离子型乳化剂为乳化剂，在本发明的一个实施例中，所述乳化剂为有机硅乳化剂，如氨基硅油乳化剂和二甲基硅油乳化剂。
所述增深染发组合物包括2～98重量份的助染剂，优选包括10～80重量份 的助染剂。在本发明中，所述助染剂优选自食盐、元明粉、白矾、皂矾、胆矾、醋酸、碳酸钠或碳酸氢钠。
所述增深染发组合物包括0.1～40重量份的pH值调节剂，优选包括1～30重量份的pH值调节剂。在本发明的优选实施例中，所述pH值调节剂选自有机酸、无机弱酸、有机碱或无机弱碱。所述pH值调节剂又可分为酸性调节剂和碱性调节剂，其中，酸性调节剂如柠檬酸、山梨酸、乳酸、酒石酸、苹果酸、偏酒石酸、磷酸、乙酸(醋酸)、盐酸、乙二酸、富马酸；碱性调节剂如碳酸氢钠、磷酸氢二钠、碳酸钠、柠檬酸钠、柠檬酸钾、碳酸氢三钠(倍半碳酸钠)、柠檬酸一钠。
为了赋予更多的功能，所述增深染发组合物优选还包括2～98重量份的添加剂；所述添加剂可选自匀染剂、渗透剂、抗静电剂、防腐抗菌剂和香精中的一种或多种，也可以为更多种其他功能添加剂。
具体的，所述匀染剂包括但不限于平平加O、匀染剂OP、匀染剂102。所述抗静电剂包括降低摩擦系数型、导电型以及离子型和非离子型，离子型包括阴离子型、阳离子型和两性离子型；比如，聚乙烯二醇、山梨醇、聚氧乙烯蓖麻油、聚氧乙烯月桂酸脂、聚乙二醇、磺酸盐、酸性磷酸酯、中性磷酸酯、胺盐、季铵盐、烷基咪唑啉、多元醇、多元醇脂、烷基胺的环氧乙烷加合物。所述防腐抗菌剂可为稀土及其衍生物、乳酸链球菌素、那他霉素、红曲米素、溶菌酶、鱼精蛋白、蜂胶、琼脂低聚糖、杜仲素、苯甲酸、苯甲酸钠、山梨酸钾、脱氢乙酸纳和双乙酸钠中的一种或多种。
本发明提供的增深染发组合物可按照以下方法制备：
称取如下原料：
2～98重量份的染发剂；
1～99重量份的增深剂，所述增深剂选自甲壳素、壳聚糖、明胶、硅油和树脂中的一种或多种，所述甲壳素、壳聚糖和明胶的相对分子质量均在2.7×104以下，所述硅油和树脂的折射率均在1.55以下；
2～98重量份的交联剂；
2～98重量份的乳化剂；
2～98重量份的助染剂；
0.1～40重量份的pH值调节剂；
将所述原料在温度为0～200℃的条件下混合，得到增深染发组合物。
在本发明的优选实施例中，所述混合具体包括：
用乳化剂将增深剂乳化为乳液；
将染发剂、交联剂和助染剂混合，得到混合液；
用pH值调节剂将所述混合液的pH值调为1～10；
将所述乳液与调节pH值后的混合液混合，得到增深染发组合物。
在本发明中，所述混合、乳化等为本领域技术人员熟知的技术手段；所述混合的温度优选为20℃～100℃。
使用时，含有纯天然染发剂的染发组合物的染发方法包括：一剂染法：①染发组合物用量：短发20～30克，中长发50～60克。②操作方法：将染发组合物涂抹在头发上，可用热毛巾包裹30～40分钟后，用温水洗净。
两剂染法：①染发组合物用量：短发20～30克，中长发50～60克。②操作方法：将染发组合物与助染剂按照1:1比例混配，搅拌均匀，并均匀涂抹在头发上，可用热毛巾包裹，30～40分钟后，用温水洗净。
含有化学染发剂的染发组合物的染发方法包括：①染发组合物用量：短发10～20克，中长发20～30克。②染法：将染发组合物涂抹在头发上，停留10～30分钟后，用温水洗净。
本发明得到的增深染发组合物主要由2～98重量份的染发剂、1～99重量份的增深剂、2～98重量份的交联剂、2～98重量份的乳化剂、2～98重量份的助染剂和0.1～40重量份的pH值调节剂构成；在本发明中，染发剂可将毛发染成一定深度的颜色；在增深剂和交联剂等作用下，可将纯天然染发剂所染的不饱和颜色被增深，最终得到饱和深度颜色，或者可大大减少化学染发剂的用量；同时可以缩短染发时间，降低染发温度，从而相对减少对人体的伤害，且能提高染色牢度，延长染发间隔时间，减少重复染发次数。因此，在各原料协同综合作用下，本发明提供的增深染发组合物具有增深固色性能，使纯天然染发剂所染的不饱和颜色增深至饱和颜色，使化学染发剂在较少用量下染得饱和颜色
此外，本发明所述增深染发组合物还具有以下其他功能：本发明克服了增深剂的硬挺属性等，使增深染发组合物具有毛发舒适剂的功能，对染后的毛发 具有保湿、柔顺和蓬松等作用。本发明能利用增深剂的优良固色作用，提高增深染发组合物的染发牢度。本发明可以使染后的毛发难以产生静电，也可以赋予染后的毛发更好的活络滑爽性能，还可以使染后的毛发具有抑菌、抗菌和免疫作用。
为了进一步说明本发明，下面结合实施例对本发明提供的增深染发组合物进行详细地描述，但不能将它们理解为对本发明保护范围的限定。
实施例1
用10重量份的甲壳素酶，将20重量份的甲壳素(相对分子质量为3×105～7×105)降解至相对分子质量为2.7×104，得到增深剂。
用40重量份的乳化剂(型号为AEO9，购自吉化公司)，将20重量份的所述增深剂乳化成乳液。
称取50重量份的靛青、5重量份的交联剂EH和1重量份的白矾于20℃混合，得到混合液。
用1重量份的醋酸将所述混合液的pH值调为4～5。
将所述乳液与调节pH值后的混合液于20℃混合，即得到增深染发组合物。
比较例1
用30重量份的乳化剂(型号为AEO3，购自吉化公司)，将20重量份的甲壳素(相对分子质量为3×105～7×105)乳化成乳液。
称取50重量份的靛青和1重量份的白矾于20℃混合，得到混合液。
用1重量份的醋酸将所述混合液的pH值调为5～6。
将所述乳液与调节pH值后的混合液于20℃混合，即得到染发组合物。
实施例2
以折射率为1.3868的有机硅树脂(购自山东大易公司)为增深剂。
用35重量份的氨基硅油乳化剂(型号为EXG-101的环保乳化剂，购自上海忠诚精细化工有限公司)，将30重量份的所述增深剂乳化成乳液。
称取2重量份的红染料102、10重量份的交联剂和20重量份的助染剂于20℃混合，得到混合液。
用1重量份的醋酸将所述混合液的pH值调为3～4。
将所述乳液与调节pH值后的混合液于20℃混合，即得到增深染发组合物。
比较例2
称取2重量份的红染料102和10重量份的助染剂于20℃混合，得到混合液。
用1重量份的醋酸将所述混合液的pH值调为7～8。
将50重量份的氨基硅油乳化剂(氨基硅油乳化剂AMM或AMH，购自江苏省海安石油化工厂)与调节pH值后的混合液于20℃混合，即得到染发组合物。
实施例3
以折射率为1.38的有机氟树脂(购自大连博泰公司)为增深剂。
用55重量份的乳化剂(二甲基硅油乳化剂1#或2#，购自江苏省海安石油化工厂)，将30重量份的所述增深剂乳化成乳液。
称取2重量份的橙黄、10重量份的柠檬酸和40重量份的助染剂于20℃混合，得到混合液。
用1重量份的醋酸将所述混合液的pH值调为6～7。
将所述乳液与调节pH值后的混合液于20℃混合，即得到增深染发组合物。
比较例3
称取2重量份的橙黄和20重量份的助染剂于20℃混合，得到混合液。
用1重量份的醋酸将所述混合液的pH值调为2～3。
将36重量份的乳化剂(棕榈蜡乳化剂，购自江苏省海安石油化工厂)与调节pH值后的混合液于20℃混合，即得到染发组合物。
实施例4
以明胶(工业明胶，购自上海鲁博明胶有限公司)为增深剂。
用42重量份的乳化剂(反应性乳化剂NRS-1030，购自上海忠诚精细化工有限公司)，将10重量份的所述增深剂乳化成乳液。
称取30重量份的孔雀石、5重量份的聚乙二醇和1重量份的皂矾于20℃混合，得到混合液。
用1重量份的盐酸将所述混合液的pH值调为4～5。
将所述乳液与调节pH值后的混合液于20℃混合，即得到增深染发组合物。
比较例4
称取30重量份的孔雀石和1重量份的皂矾于20℃混合，得到混合液。
用1重量份的盐酸将所述混合液的pH值调为6～7。
将40重量份的乳化剂(窄分布环保乳化剂GS-730或GS-930，购自上海忠诚精细化工有限公司)与调节pH值后的混合液于20℃混合，即得到染发组合物。
实施例5
以折射率为1.43的二甲基硅油(购自山东大易公司)为增深剂。
用10重量份的非离子型乳化剂(型号为TX-40，购自江苏省海安石油化工厂)，将30重量份的所述增深剂乳化成乳液。
称取50重量份的冻绿、15重量份的交联剂和1重量份的白矾于20℃混合，得到混合液。
用1重量份的柠檬酸钠将所述混合液的pH值调为6～7。
将所述乳液与调节pH值后的混合液于20℃混合，即得到增深染发组合物。
比较例5
称取50重量份的冻绿和1重量份的白矾于20℃混合，得到混合液。
用1重量份的柠檬酸钠将所述混合液的pH值调为5～6。
将10重量份的非离子型乳化剂(型号为NP-4，购自江苏省海安石油化工厂)与调节pH值后的混合液于20℃混合，即得到染发组合物。
实施例6
以折射率为1.35的氨基硅油(购自山东大易公司)为增深剂。
用5重量份的阴离子型乳化剂(环保型阴离子反应型乳化剂，购自南京馨海商贸有限公司)，将30重量份的所述增深剂乳化成乳液。
称取40重量份的紫草、5重量份的乙二醛和1重量份的胆矾于20℃混合，得到混合液。
用1重量份的酒石酸将所述混合液的pH值调为4～5。
将所述乳液与调节pH值后的混合液于20℃混合，即得到增深染发组合物。
比较例6
称取40重量份的紫草和1重量份的胆矾于20℃混合，得到混合液。
用1重量份的酒石酸将所述混合液的pH值调为8～9。
将5重量份的阴离子型乳化剂(型号为陶氏DOWFAX 2A1，购自广州峰佰顺贸易有限公司)与调节pH值后的混合液于20℃混合，即得到染发组合物。
实施例7
采用实施例1～6得到的增深染发组合物和比较例1～6得到的染发组合物，按照上文所述的方法进行染发，染发后毛发的颜色对比参见表1，表1为本发明实施例1～6和比较例1～6提供的染发组合物的染发结果对比。
表1本发明实施例1～6和比较例1～6提供的染发组合物的染发结果对比
Figure PCTCN2016074428-appb-000001
并且，对实施例1和比较例1得到的染发组合物进行毛发舒适性的测试。测试方法和结果参见表2，表2为本发明实施例1和比较例1提供的染发组合物对毛发舒适性的影响。
表2本发明实施例1和比较例1提供的染发组合物对毛发舒适性的影响
Figure PCTCN2016074428-appb-000002
Figure PCTCN2016074428-appb-000003
由以上实施例和比较例可知，本发明提供的增深染发组合物主要由以下原料构成：2～98重量份的染发剂；1～99重量份的增深剂；2～98重量份的交联剂；2～98重量份的乳化剂；2～98重量份的助染剂；0.1～40重量份的pH值调节剂；其中，所述增深剂选自甲壳素、壳聚糖、明胶、硅油和树脂中的一种或多种，所述甲壳素、壳聚糖和明胶的相对分子质量均在2.7×104以下，所述硅油和树脂的折射率均在1.55以下。在各原料协同综合作用下，本发明提供的增深染发组合物具有增深性能，在较少用量下染发即可得饱和深度颜色。
此外，本发明克服了增深剂的硬挺属性等，使增深染发组合物具有毛发舒适剂的功能，对染后的毛发具有保湿、柔顺和蓬松等作用。本发明能利用增深剂的优良固色作用，提高增深染发组合物的染发牢度。本发明可以使染后的毛发难以产生静电，也可以赋予染后的毛发更好的活络滑爽性能，还可以使染后的毛发具有抑菌、抗菌和免疫作用。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (10)

  1. 一种增深染发组合物，包括：
    2～98重量份的染发剂；
    1～99重量份的增深剂，所述增深剂选自甲壳素、壳聚糖、明胶、硅油和树脂中的一种或多种，所述甲壳素、壳聚糖和明胶的相对分子质量均在2.7×104以下，所述硅油和树脂的折射率均在1.55以下；
    2～98重量份的交联剂；
    2～98重量份的乳化剂；
    2～98重量份的助染剂；
    0.1～40重量份的pH值调节剂。
  2. 根据权利要求1所述的增深染发组合物，其特征在于，所述交联剂选自氰醛、氯化镁、柠檬酸、乙二醛、交联剂EH、聚乙二醇和抗静电剂A-2ST中的一种或多种。
  3. 根据权利要求1所述的增深染发组合物，其特征在于，包括5～40重量份的交联剂。
  4. 根据权利要求1所述的增深染发组合物，其特征在于，包括4～45重量份的增深剂。
  5. 根据权利要求1所述的增深染发组合物，其特征在于，所述增深剂选自甲壳素、壳聚糖或明胶；
    所述增深剂通过降解剂降解制得，所述降解剂选自酸类降解剂、氧化类降解剂或酶类降解剂。
  6. 根据权利要求1所述的增深染发组合物，其特征在于，所述pH值调节剂选自有机酸、无机弱酸、有机碱或无机弱碱。
  7. 根据权利要求1所述的增深染发组合物，其特征在于，包括2～60重量份的染发剂；
    所述染发剂选自纯天然染发剂或化学染发剂。
  8. 根据权利要求1所述的增深染发组合物，其特征在于，所述乳化剂选自两性离子型乳化剂和/或非离子型乳化剂。
  9. 根据权利要求1所述的增深染发组合物，其特征在于，所述助染剂选自食盐、元明粉、白矾、皂矾、胆矾、醋酸、碳酸钠或碳酸氢钠。
  10. 根据权利要求1～9任一项所述的增深染发组合物，其特征在于，所述增深染发组合物还包括2～98重量份的添加剂；
    所述添加剂选自匀染剂、抗静电剂、防腐抗菌剂和香精中的一种或多种。
PCT/CN2016/074428 2015-04-09 2016-02-24 一种增深染发组合物 WO2016161852A1 (zh)

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