WO2016153230A1 - Agent de nano-revêtement hydrofuge et antimicrobien pour dépôt sous vide et procédé de revêtement l'utilisant - Google Patents

Agent de nano-revêtement hydrofuge et antimicrobien pour dépôt sous vide et procédé de revêtement l'utilisant Download PDF

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WO2016153230A1
WO2016153230A1 PCT/KR2016/002765 KR2016002765W WO2016153230A1 WO 2016153230 A1 WO2016153230 A1 WO 2016153230A1 KR 2016002765 W KR2016002765 W KR 2016002765W WO 2016153230 A1 WO2016153230 A1 WO 2016153230A1
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Prior art keywords
antimicrobial
vacuum deposition
polymer
silane
dry
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PCT/KR2016/002765
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English (en)
Korean (ko)
Inventor
김현중
김홍철
김정래
신미애
이한나
이수연
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주식회사 쎄코
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Priority to JP2018500258A priority Critical patent/JP6691206B2/ja
Priority to DE112016001303.5T priority patent/DE112016001303T5/de
Priority to CN201680016858.4A priority patent/CN107406968B/zh
Publication of WO2016153230A1 publication Critical patent/WO2016153230A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/12—Organic material
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • A01N25/10—Macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/60—Deposition of organic layers from vapour phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • G—PHYSICS
    • G06—COMPUTING; CALCULATING OR COUNTING
    • G06F—ELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2203/00—Other substrates
    • B05D2203/30—Other inorganic substrates, e.g. ceramics, silicon
    • B05D2203/35—Glass
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2350/00—Pretreatment of the substrate
    • B05D2350/60—Adding a layer before coating
    • B05D2350/63—Adding a layer before coating ceramic layer
    • G—PHYSICS
    • G06—COMPUTING; CALCULATING OR COUNTING
    • G06F—ELECTRIC DIGITAL DATA PROCESSING
    • G06F2203/00—Indexing scheme relating to G06F3/00 - G06F3/048
    • G06F2203/041—Indexing scheme relating to G06F3/041 - G06F3/045
    • G06F2203/04103—Manufacturing, i.e. details related to manufacturing processes specially suited for touch sensitive devices

Definitions

  • the present invention relates to a functional coating agent that realizes antimicrobial properties and water / oil repellency at the same time, a manufacturing method thereof, and a coating method using the same.
  • the present invention relates to an antimicrobial effect on water / oil repellent nano coatings for hygienic use of smart devices such as touch displays.
  • the present invention relates to a coating method using a vacuum deposition apparatus and to prepare a coating agent.
  • the anti-fingerprint coating gives the surface water / oil repellent properties by using a fluorine-based compound, which reduces the surface energy and reduces the contact area between fingerprints and external contaminants and the coated surface, minimizing the staining of contaminants and It has a wiping characteristic.
  • vacuum deposition In order to form such a thin film, a coating method called “vacuum deposition” is used in most cases.
  • the coating process using vacuum deposition (surface modification) is performed by applying a high temperature heat source to a target (coating agent) in a very short time. This very good, low chemical loss and nano-size thin film coating without compromising optical properties is possible.
  • the present invention relates to a technology for developing and utilizing a vacuum deposition system using nanotechnology that has antimicrobial activity.
  • wood wood, elm, plum, etc.
  • the sustainability is difficult to maintain, and also there is a problem that the functionality such as water repellency / oil repellency and slipping is not implemented.
  • U.S. Patent Publication No. US 2011/0025933 (Applicant: VIZIO INC., TELEVISION WITH ANTIMICROBIAL COATING) discloses a technique for inhibiting the growth of microorganisms by coating and coating a coating containing an antimicrobial agent on the outer surface of a television. There is a problem that functionality such as water / oil repellency and slipperiness is not implemented.
  • Japanese Patent Application No. 2007-322624 (Applicant: ZNO LAB, Antibacterial material and method for producing the same) is a vacuum deposition on glass substrates, plastics, etc. that can be used on the surface of touch panels or mobile phones, It discloses an antimicrobial material and a method of manufacturing the same, characterized in that the zinc oxide thin film is formed by a method such as sputtering, this also has a problem that the functionality such as water repellency / oil repellency and slip properties are not implemented, and also due to the metal thin film There is a problem that the optical properties are lowered.
  • the present invention provides a coating composition capable of simultaneously implementing water repellency / oil repellency and antimicrobial properties and satisfy both durability and optical properties while applying the vacuum deposition method of the touch-type display coating method, smart When using electronic devices and home appliances, it has a soft touch feeling and can easily remove contamination such as fingerprints, and at the same time, it can be used with confidence from contamination with germs.
  • the first aspect of the present invention provides a dry antimicrobial coating agent for vacuum deposition, comprising a polycondensation reaction product of a fluorine-based polymer and a functional organic-inorganic silane compound, and an antimicrobial material.
  • the fluorine-based polymer and the functional organic-inorganic silane compound are polycondensed in the presence of the antimicrobial material.
  • the antimicrobial material is introduced into the polycondensation reaction product of the fluoropolymer and the functional organic-inorganic silane compound, dispersed and mixed with each other.
  • a method for producing a mixture comprising: a) preparing a mixture comprising a fluorine-based polymer, a functional organic-inorganic silane compound, and an antimicrobial material; And b) polycondensing the mixture.
  • a method for preparing a dry antimicrobial coating agent for vacuum deposition is provided.
  • a third aspect of the invention i) preparing a mixture comprising a fluorine-based polymer and a functional organic-inorganic silane compound; ii) polycondensation the mixture; And iii) injecting and dispersing the antimicrobial substance into the resultant of the polycondensation reaction, and mixing the same.
  • a method for producing a substrate comprising the steps of: 1) providing a substrate to be coated; And 2) vacuum depositing the dry antimicrobial coating agent of the present invention on the surface of the substrate.
  • a coated article characterized in that it has a vacuum deposition coating layer of the dry antimicrobial coating of the present invention.
  • the dry antimicrobial coating agent for vacuum deposition of the present invention exhibits excellent water and oil repellency with a surface water contact angle of 115 ° or more, excellent anti-fingerprint (AF), durability and optical properties (transmittance), and excellent antibacterial properties. Indicates a function. In particular, it shows excellent abrasion resistance (in the eraser abrasion test, the contact angle change after the test compared to the initial contact angle within 15 °), and shows an excellent antibacterial effect with an initial antibacterial activity of 99.9%, and can be applied to various materials such as glass, plastic, and metal.
  • the present invention can be particularly suitably used for surface coating of smart devices having a touch type display such as mobile phones, tablet PCs, household appliances and other electronic products, or parts thereof.
  • Figure 1 schematically shows the cross-section of the substrate coated with the antimicrobial coating of the present invention, the left side is the antimicrobial AF coating layer is formed directly on the substrate (right), the right side is the inorganic or oxide between the substrate and the antimicrobial AF coating layer The layers are interposed.
  • Figure 2 is a photograph showing the results of the antimicrobial test for each of (a) uncoated samples, (b) AF coating sample without the antimicrobial agent and (c) antimicrobial AF coating sample coated with the antimicrobial coating agent of the present invention.
  • a first aspect of the present invention provides a dry antimicrobial coating for vacuum deposition, comprising a polycondensation reaction product of a fluorine-based polymer and a functional organic-inorganic silane compound, and an antimicrobial material.
  • the fluorine-based polymer and the functional organic-inorganic silane compound are polycondensed in the presence of the antimicrobial material.
  • the antimicrobial material is introduced into the polycondensation reaction product of the fluoropolymer and the functional organic-inorganic silane compound, dispersed and mixed with each other.
  • the fluorine-based polymer usable in the present invention may be a perfluorinated polymer.
  • the fluorine-based polymer is a perfluoropolyether, a vinylidene fluoride (Vinylidene fluoride) polymer, a tetrafluoroethylene polymer, a hexafluoropropylene polymer, a chlorotrifluoroethylene polymer and It may be selected from a combination of these, preferably perfluorinated polyether.
  • the functional organic-inorganic silane compound usable in the present invention includes at least one functional group (eg, an amino group, a vinyl group, an epoxy group, an alkoxy group, a halogen group, a mercapto group, a sulfide group, etc.) that performs a polycondensation reaction with the fluorine-based polymer. It may be an organic-inorganic silane compound having.
  • the functional organic-inorganic silane compound is aminopropyltriethoxysilane, aminopropyltrimethoxysilane, amino-methoxysilane, phenylaminopropyltrimethoxysilane, N- (2-aminoethyl) -3-aminopropyl Trimethoxysilane, N- ( ⁇ -aminoethyl) - ⁇ -aminopropylmethyldimethoxysilane, ⁇ -aminopropyltridimethoxysilane, ⁇ -aminopropyldimethoxysilane, ⁇ -aminopropyltriethoxysilane, ⁇ -Aminopropyl diethoxysilane, vinyl triethoxysilane, vinyl trimethoxysilane, vinyl tri (methoxyethoxy) silane, di-, tri- or tetraalkoxysilane, vinylmethoxysilane, vinyltrimethoxysi
  • the antimicrobial material usable in the present invention may be selected from natural materials or extracts thereof, antimicrobial polymer compounds and combinations thereof.
  • Examples of the natural material or extract thereof include crab, shell of shrimp or extract thereof (e.g. chitosan), green tea or extract thereof (e.g. catechin), bark or extract thereof (e.g. Paeonol, Paeoniflorin, Paeonolide, sitosterol, Gallic acid, Methyl gallate, Tannic acid, Quercetin, etc., grapefruit or extracts thereof (e.g. naringin), citral, licorice or extracts thereof (e.g. flavonoids), cypress Trees or extracts thereof (e.g. phytoncide), bamboo or extracts thereof (e.g. polyphenols), germinated beans or extracts thereof (e.g.
  • crab, shell of shrimp or extract thereof e.g. chitosan
  • green tea or extract thereof e.g. catechin
  • bark or extract thereof e.g. Paeonol, Paeoniflorin, Paeonolide, sitosterol, Gallic acid,
  • glyceollins gold or extracts thereof (e.g. tyrosinase), horseradish or extracts thereof (e.g. Eg isothiocyanate), mustard or extracts thereof, hinokitol And combinations thereof.
  • the extracts may be prepared by known extraction methods.
  • antimicrobial polymer compound examples include at least one polymer compound selected from aromatic or heterocyclic polymers, acrylic or methacryl polymers, cationic conjugated polymer electrolytes, polysiloxane polymers, natural polymer mimic polymers, and phenol or benzoic acid derivative polymers, Or those having at least one functional group selected from ammonium base, phosphonium base, sulfonium base or other onium base, phenylamide group and diguanamid group attached to the branched polymer chain.
  • polymer compound selected from aromatic or heterocyclic polymers, acrylic or methacryl polymers, cationic conjugated polymer electrolytes, polysiloxane polymers, natural polymer mimic polymers, and phenol or benzoic acid derivative polymers, Or those having at least one functional group selected from ammonium base, phosphonium base, sulfonium base or other onium base, phenylamide group and diguanamid group attached to the branched polymer chain.
  • the antimicrobial material is harmless to the human body and has an initial antibacterial activity of 99.9% by coating an antimicrobial coating agent prepared using the natural material or its extract, or an antimicrobial polymer compound having stability and persistence. Excellent antibacterial effect can be obtained.
  • chitosan chitosan
  • peonol peonol: 1- (2-hydroxy-4-methoxyphenyl) ethanone
  • a combination thereof may be used as the antimicrobial material.
  • the content of the polycondensation reaction product of the fluorine-based polymer and the functional organic-inorganic silane compound is preferably 50 to 99.9% by weight based on 100% by weight of the total weight of the coating agent, and is 80 to 95% by weight. It is more preferable.
  • the content of the antimicrobial material is preferably 0.1 to 50% by weight, more preferably 5 to 20% by weight, based on 100% by weight of the total weight of the coating agent.
  • a method for producing a mixture comprising: a) preparing a mixture comprising a fluorine-based polymer, a functional organic-inorganic silane compound, and an antimicrobial material; And b) polycondensing the mixture.
  • a method for preparing a dry antimicrobial coating agent for vacuum deposition is provided.
  • a third aspect of the invention i) preparing a mixture comprising a fluorine-based polymer and a functional organic-inorganic silane compound; ii) polycondensation the mixture; And iii) injecting and dispersing the antimicrobial substance into the resultant of the polycondensation reaction, and mixing the same.
  • the conditions of the polycondensation reaction in the polycondensation reaction step is not particularly limited, for example, it may be carried out by reflux reaction at 100 ⁇ 200 °C temperature under an inert gas (for example, argon, nitrogen).
  • the reaction mixture may be irradiated with ultrasonic waves and / or UV while the reaction is performed.
  • the result of the polycondensation reaction may optionally go through a stabilization step.
  • a stabilization step There are no particular limitations to the stabilization conditions, and for example, the result of the polycondensation reaction can be stabilized by leaving it at room temperature for 24 hours.
  • a method for producing a substrate comprising the steps of: 1) providing a substrate to be coated; And 2) vacuum depositing the dry antimicrobial coating agent of the present invention on the surface of the substrate.
  • the substrate to be coated is not particularly limited as long as it can be coated by vacuum deposition, and substrates of various materials such as glass, plastic, and metal may be coated by the method of the present invention.
  • the dry antimicrobial coating may be vacuum deposited directly on the substrate surface or alternatively vacuum deposited on a layer of inorganic or oxide (eg SiO 2 ) preformed on the substrate surface.
  • inorganic or oxide eg SiO 2
  • vacuum deposition there is no particular limitation on the method of vacuum deposition, and it can be carried out using conventional vacuum deposition methods and equipment. According to one embodiment of the present invention, it is possible to perform vacuum deposition coating using a 2050 ⁇ vacuum deposition equipment (Electron-beam evaporation, Thermal evaporation, Thermal sputter, etc.) by PVD (Physical Vapor Deposition) method.
  • the advantage of vacuum deposition is that various materials can be easily applied to the coating, there is little loss of coating chemicals, and a clean and uniform thin film can be formed.
  • the overall configuration of the device is relatively simple, and since the thermal and electrical complexity of the thin film is small, it is suitable for the study of the physical properties of the film during thin film formation.
  • a coated article characterized in that it has a vacuum deposition coating layer of the dry antimicrobial coating of the present invention.
  • the article may be a smart device having a touch type display such as a mobile phone or a tablet PC of various materials such as glass, plastic and metal, a home appliance, a vending machine, a common interactive information device, an external electronic device that can be touched by hand, or a part thereof. It is preferably a smart device having a touch type display or a part thereof.
  • the antimicrobial material is arranged at the base of the coating layer to exhibit fouling resistance, water / oil repellency, surface lubrication activity, anti-fingerprint, etc., while maintaining the life of the coating, and at the same time exhibiting antibacterial activity.
  • a dry antimicrobial coating agent was prepared in the same manner as in Example 1, except that 8 g of peonol was further added as an antimicrobial material.
  • perfluoropolyether 50 g is added to 50 g of aminopropyltriethoxysilane and subjected to a polycondensation reaction at about 150 ° C. under an inert argon gas atmosphere, followed by paeonol as an antimicrobial substance. 8 g was added and uniformly dispersed and mixed to prepare a dry antimicrobial coating.
  • Example 1 Using the dry antimicrobial coating agent prepared in Examples 1 to 3 was coated with tempered glass by E / B (Electron-beam) evaporation method in a 2050 ⁇ vacuum deposition equipment. In order to smooth the coating, the tempered glass was wet cleaned with a 5 wt% alkali cleaner (cleaning agent for tempered glass) in a 10 bath washer before coating. Vacuum deposition conditions, the initial etching: 300 seconds, SiO 2 thickness: 120 ⁇ Temperature was 80 °C.
  • the contact angle of the coated surface was measured using a contact angle measuring device.
  • the size of one droplet was 3 ⁇ l and in order to confirm the uniformity of the coating, the contact angle of 5 points per coated sample was measured and averaged.
  • Examples 1 and 2 were commissioned by the Korea Institute of Construction and Environmental Testing (KCL) using E. coli (ATCC 8739), Staphylococcus aureus (ATCC 6538P), and Pseudomonas aeruginosa (ATCC 15442) JIS Z 2801 standard.
  • KCL Korean Institute of Construction and Environmental Testing
  • E. coli ATCC 8739
  • Staphylococcus aureus ATCC 6538P
  • Pseudomonas aeruginosa ATCC 15442 JIS Z 2801 standard.
  • the antibacterial test was carried out, and Example 3 was carried out in the same standard using E. coli (ATCC 8739) in the KOLAS accredited test laboratory. 400 ⁇ l of the diluted bacterial solution was inoculated on the surface of the coated sample and incubated in a constant temperature and humidity environment for 24 hours, and then desorption was performed to confirm the antibacterial result.
  • Test Example 2 Comparison of the antimicrobial activity and coating that does not contain non-coated sample, and the sample biocide

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Abstract

La présente invention concerne un agent de revêtement fonctionnel présentant à la fois une activité antimicrobienne et un caractère hydrofuge/oléofuge, un procédé de préparation de celui-ci et un procédé de revêtement l'utilisant. La présente invention concerne plus particulièrement : un procédé de préparation d'un agent de revêtement qui fournit une activité antimicrobienne à un nano-revêtement hydrofuge/oléofuge permettant à des dispositifs intelligents, etc., tels que des écrans tactiles, d'être utilisés de manière hygiénique ; un procédé de revêtement utilisant un équipement de dépôt sous vide.
PCT/KR2016/002765 2015-03-20 2016-03-18 Agent de nano-revêtement hydrofuge et antimicrobien pour dépôt sous vide et procédé de revêtement l'utilisant WO2016153230A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2018500258A JP6691206B2 (ja) 2015-03-20 2016-03-18 抗菌力を有する真空蒸着用撥水型ナノコーティング剤及びそれを用いたコーティング方法
DE112016001303.5T DE112016001303T5 (de) 2015-03-20 2016-03-18 Wasserabweisendes Nanobeschichtungsmittel mit antimikrobieller Wirkung für die Vakuumabscheidung sowie Beschichtungsverfahren unter Verwendung desselben
CN201680016858.4A CN107406968B (zh) 2015-03-20 2016-03-18 具有抗菌能力的真空沉积用防水型纳米涂层剂及利用其的涂布方法

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Application Number Priority Date Filing Date Title
KR1020150038820A KR101677024B1 (ko) 2015-03-20 2015-03-20 항균력을 갖는 진공증착용 발수형 나노 코팅제 및 이를 이용한 코팅 방법
KR10-2015-0038820 2015-03-20

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WO2016153230A1 true WO2016153230A1 (fr) 2016-09-29

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JP (1) JP6691206B2 (fr)
KR (1) KR101677024B1 (fr)
CN (1) CN107406968B (fr)
DE (1) DE112016001303T5 (fr)
WO (1) WO2016153230A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108545958A (zh) * 2018-04-24 2018-09-18 新疆大学 一种聚合物涂层的制备方法
CN109295415A (zh) * 2017-07-24 2019-02-01 立得光电科技股份有限公司 功能性膜层的成膜方法、功能性膜层，及抗菌抗指纹元件
US10236328B2 (en) 2017-03-23 2019-03-19 Samsung Display Co., Ltd. Method of manufacturing organic light-emitting display device
EP3697860A4 (fr) * 2017-08-14 2021-08-25 Interphase Materials Inc. Traitement de surface
WO2022078767A1 (fr) 2020-10-14 2022-04-21 Solvay Specialty Polymers Italy S.P.A. Nouveaux polymères de (per)fluoropolyéther et leur utilisation
WO2022078766A1 (fr) 2020-10-14 2022-04-21 Solvay Specialty Polymers Italy S.P.A. Nouveaux polymères de (per)fluoropolyéther et leur utilisation

Families Citing this family (4)

* Cited by examiner, † Cited by third party
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KR101690091B1 (ko) * 2015-04-16 2016-12-27 주식회사 쎄코 진공증착용 항균성 프라이머 코팅제 및 이를 이용한 다중코팅 방법
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CN107406968A8 (zh) 2018-01-12
CN107406968A (zh) 2017-11-28
DE112016001303T5 (de) 2018-01-18
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