WO2016045279A1 - 一种封装层、电子封装器件及显示装置 - Google Patents
一种封装层、电子封装器件及显示装置 Download PDFInfo
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- WO2016045279A1 WO2016045279A1 PCT/CN2015/071328 CN2015071328W WO2016045279A1 WO 2016045279 A1 WO2016045279 A1 WO 2016045279A1 CN 2015071328 W CN2015071328 W CN 2015071328W WO 2016045279 A1 WO2016045279 A1 WO 2016045279A1
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- layer
- substrate
- organic coating
- encapsulating
- acrylate
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Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/87—Passivation; Containers; Encapsulations
- H10K59/873—Encapsulations
- H10K59/8731—Encapsulations multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/84—Passivation; Containers; Encapsulations
- H10K50/844—Encapsulations
- H10K50/8445—Encapsulations multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/10—Organic polymers or oligomers
- H10K85/151—Copolymers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
- H10K2102/311—Flexible OLED
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
- H10K2102/351—Thickness
Definitions
- the present invention relates to the field of electronic technologies, and in particular, to an encapsulation layer, an electronic package device, and a display device.
- OLED Organic Light Emitting Diode
- CCD Charge-coupled Device
- the inorganic passivation layer 301 and the water-oxygen barrier film 303, or the encapsulation film 302 and the water-oxygen barrier film 303 may be passed through in the prior art.
- the OLED display device is packaged.
- the water-oxygen barrier film 303 is usually prepared by a high-molecular polymer material by an extrusion molding process; limited to the preparation process, the thickness of the water-oxygen barrier film 303 needs to be controlled at about 50 ⁇ m to ensure uniformity thereof.
- the conventional packaging technology uses the water-oxygen barrier film 303 and the inorganic passivation layer 301 or the encapsulating film 302 to be bonded by means of an adhesive, which is disadvantageous for realizing lightness and thinning of the electronic device.
- the invention provides an encapsulation layer, an electronic packaging device and a display device, which can reduce the thickness of the encapsulation layer, thereby realizing the thinning and thinning of the electronic packaging device.
- an encapsulation layer comprising an encapsulating barrier layer and an organic coating formed directly on the encapsulating barrier layer; wherein the organic coating is a polymerizable organic coating; the polymerizable organic coating
- the layer comprises an unsaturated acrylate based organic coating.
- the organic coating has a thickness of 5 ⁇ m to 10 ⁇ m.
- the unsaturated acrylate organic coating comprises a urethane acrylate organic coating or an epoxy acrylate organic coating.
- the unsaturated acrylate organic coating layer is added with a cationic surfactant; wherein the cationic surfactant comprises a hydrophilic quaternary ammonium salt.
- the unsaturated acrylate-based organic coating comprises a first coating adjacent to the encapsulating barrier layer and a second coating remote from the encapsulating barrier layer; wherein the first coating has a refractive index greater than The refractive index of the second coating.
- the first coating layer comprises one or more of a silane-modified unsaturated acrylate-based polymer, an unsaturated urethane acrylate-based polymer, and an unsaturated fluorine-containing acrylate-based polymer;
- the second coating layer includes an unsaturated acrylate-based polymer doped with inorganic particles; the inorganic particles include one or more of titanium oxide, titanium oxide, zinc oxide, copper copper titanate, and barium titanate.
- the unsaturated acrylate organic coating layer comprises an unsaturated acrylate organic coating doped with hard particles; wherein the hard particles include graphene oxide, transparent graphite, glass fiber, diamond particles One or more of them.
- the encapsulating barrier layer comprises a plurality of layers of overlapping packaging films.
- an electronic package device comprising a substrate substrate and an encapsulation layer, and an electronic device therebetween; the encapsulation layer being the encapsulation layer described above.
- the electronic package device is an OLED display device, and the electronic device is an organic material functional layer between the substrate substrate and the encapsulation layer; wherein the encapsulation barrier layer of the encapsulation layer is adjacent to the lining a base substrate, the organic coating of the encapsulation layer being away from the substrate substrate.
- the base substrate is a flexible substrate; wherein the flexible substrate comprises a polyimide substrate, a polyethylene substrate, a polypropylene substrate, and a polystyrene substrate. Any one of a polyethylene terephthalate base substrate and a polyethylene naphthalate base substrate.
- a display device comprising the electronic package device described above.
- Embodiments of the present invention provide an encapsulation layer, an electronic package device, and a display device, the encapsulation layer including an encapsulation barrier layer and an organic coating layer formed directly on the encapsulation barrier layer; wherein the organic coating layer is a polymeric organic coating; the polymerizable organic coating comprises an unsaturated acrylate organic coating.
- the encapsulation layer provided by the embodiment of the present invention may be composed of the encapsulation barrier layer and the organic coating layer; wherein the encapsulation barrier layer has a certain water and oxygen barrier effect, and the organic coating layer The effect of water and oxygen barrier can be further improved.
- the organic coating is used instead of the water-oxygen barrier film, bonding can be achieved without using an adhesive, and the thickness of the organic coating is significantly smaller than the water-oxide barrier film. Therefore, under the premise of ensuring the water-oxygen barrier effect of the encapsulation layer, the thickness of the encapsulation layer can be significantly reduced, thereby achieving thinning of the electronic package device.
- FIG. 1(a) and 1(b) are schematic structural views of an OLED display device in the prior art
- FIG. 2 is a schematic structural diagram of an encapsulation layer according to an embodiment of the present invention.
- FIG. 3 is a schematic structural diagram 1 of an electronic package device (OLED display device) according to an embodiment of the present invention
- FIG. 4 is a schematic structural diagram 2 of an electronic package device (OLED display device) according to an embodiment of the present invention
- FIG. 5 is a flow chart of preparing an electronic package device (OLED display device) according to an embodiment of the present invention.
- 10-(flexible) substrate 20-electronic device/organic material functional layer; 30-encapsulation layer; 301-inorganic passivation layer; 302-package film; 303-water oxygen barrier film; 304-package barrier layer; - organic coating; 40-thin film transistor.
- An embodiment of the present invention provides an encapsulation layer 30, as shown in FIG. 2, including a package barrier layer 304 and an organic coating layer 305 formed directly on the encapsulation barrier layer 304; wherein the organic coating layer 305 is A polymeric organic coating, which may comprise an unsaturated acrylate based organic coating.
- the encapsulating barrier layer 304 may adopt an inorganic passivation layer 301 as shown in FIG. 1 , such as a silicon nitride film; or the package blocking layer 304 may also be packaged as shown in FIG. 2 .
- the film 302 is, for example, an organic film and an inorganic film which are alternately deposited.
- the formation of the organic coating layer 305 may include two stages of organic solution coating and solidification film formation; wherein the coating method of the organic solution may include spin coating, spray coating, flat wiper film, inkjet printing, Any one of slit coating; the method of curing the film formation may include any one of ultraviolet curing, visible light curing, thermal curing, and chemical decomposition curing.
- the encapsulation layer 30 provided by the embodiment of the present invention is mainly used for encapsulating an electronic device, so the encapsulation layer 30 needs to be formed on a specific substrate surface; wherein the substrate surface may specifically be needed The surface of the packaged electronic device.
- An embodiment of the present invention provides an encapsulation layer 30 including a package barrier layer 304 and an organic coating layer 305 formed directly on the encapsulation barrier layer 304; wherein the organic coating layer 305 is a polymerizable organic coating layer,
- the polymerizable organic coating comprises an unsaturated acrylate based organic coating.
- the encapsulation layer 30 provided by the embodiment of the present invention may be composed of the encapsulation barrier layer 304 and the organic coating layer 305; wherein the encapsulation barrier layer 304 has a certain water and oxygen barrier function.
- the organic coating 305 can further improve the effect of water oxygen barrier.
- bonding can be achieved without using an adhesive, and the organic
- the thickness of the coating layer 305 is significantly smaller than the thickness of the water-oxygen barrier film 303, so that the thickness of the encapsulation layer 30 can be significantly reduced under the premise of ensuring the water-oxygen barrier effect of the encapsulation layer 30, thereby realizing electronic packaging.
- the device is light and thin.
- the encapsulating barrier layer 304 may be an inorganic passivation layer 301 or a package film 302 having a thickness of about 1 ⁇ m; the organic coating layer 305 is preferably an unsaturated acrylate organic coating layer having a thickness of 1 ⁇ 10 ⁇ m, preferably 2.5 to 10 ⁇ m, more preferably 5 to 7.5 ⁇ m.
- the encapsulating barrier layer 304 preferably employs a multi-layered overlying encapsulating film 302, such as an alternating organic film and an inorganic film.
- the encapsulation film 302 has a better water and oxygen barrier effect than the inorganic passivation layer 301.
- the unsaturated acrylate organic coating layer may specifically include a urethane acrylate organic coating or an epoxy acrylate organic coating.
- the unsaturated acrylate may be selected from unsaturated acrylates commonly used in the art to form a film layer when cured by ultraviolet light, visible light, heat, chemical reaction, etc., and specific examples thereof include: hydroxyethyl acrylate, Amino acrylate, epoxy acrylate, alicyclic epoxy methacrylate, methyl methacrylate, and the like.
- the unsaturated acrylate is a urethane acrylate or an epoxy acrylate.
- the urethane acrylate may be selected from one or more of the following: urethane acrylate, silicone-acrylate modified polyurethane, epoxy modified urethane acrylate, aliphatic modified urethane acrylate Classes, etc.
- the epoxy acrylate may be bisphenol A epoxy acrylate.
- the unsaturated acrylate has a weight average molecular weight of from 5,000 to 100,000, preferably from 10,000 to 50,000, and more preferably from 10,000 to 25,000, for the purpose of achieving sufficient crosslinking to avoid the need to use a binder and provide sufficient water oxygen barrier effect.
- the organic coating layer in the encapsulating layer according to the present invention may further contain various functional additives, such as an antifogging agent, an antireflection agent, a scratch resistant agent, etc., and the content in the organic coating layer may be determined according to the Need performance to choose properly.
- the organic coating may be an organic coating doped with anti-fogging particles or a surfactant, or may be a water-absorbing anti-fog organic coating.
- the doped anti-fog particles include: titanium dioxide, zinc oxide, nano-silica, super-hydrophobic silicon material, male/anionic/zwitterionic surfactant, modified polymer, etc.; water-absorbing organic coating includes high water absorption Polyol urethane resin and the like.
- the anti-reflection function achieves anti-reflection by adding particles of different refractive indices, and the low refractive index coating is mainly fluoridated by adding low refractive index.
- Low refractive index is achieved by one or more of a fluorine-containing acrylate, a silane-modified unsaturated acrylate polymer, an unsaturated urethane acrylate polymer, and an unsaturated fluorine-containing acrylate polymer;
- the coating of the refractive index is generally added by adding inorganic nano-oxides such as titanium dioxide, titanium oxide, acicular zinc oxide, calcium nano-titanium titanate, barium titanate to the photocurable acrylate or epoxy coating.
- the scratch-resistant hard particles are added to the organic coating or mixed with a hard monomer to form a film, which can improve scratch resistance.
- the scratch-resistant agent is, for example, one or more selected from the group consisting of glass fibers, celluloses, silica particles, or silicon-containing particles, alumina particles, graphene oxide, transparent graphite, glass fibers, and diamond particles.
- the organic coating layer 305 can have other properties such as anti-fog while having a water-oxygen barrier effect. Sex, anti-reflective, and scratch resistant.
- a cationic surfactant may be added to the unsaturated acrylate organic coating.
- the cationic surfactant may be selected from one or more of the group consisting of alkylbenzenesulfonic acid, alkylbetaine, alanine, fatty alkanesulfonate, and other polyol fatty acid salts, and the like.
- the cationic surfactant comprises a hydrophilic quaternary ammonium salt.
- the hydrophilic quaternary ammonium salt is selected from long chain quaternary ammonium salts containing a curable double bond structure, such as ethyl bromide.
- the hydrophilic quaternary ammonium salt is preferably a quaternary ammonium salt which can be subjected to ultraviolet photopolymerization, and the quaternary ammonium salt can be reacted by adding brominated alkane and acrylate having different chain lengths to obtain low molecular quaternary ammonium having different chain lengths. salt.
- the cationic surfactant to the unsaturated acrylate organic coating layer, the wettability of the organic solution and the surface of the substrate can be effectively improved, so that the organic solution can be tiled in the The surface of the substrate eliminates the diffuse reflection of light and achieves an anti-fog effect.
- the additive material in the unsaturated acrylate-based organic coating layer is not limited to the cationic surfactant, and may also be other super-hydrophilicity. Materials, or superhydrophobic materials, or amphiphilic materials.
- the unsaturated acrylate organic coating may include close to the package a first coating of the barrier layer 304 and a second coating remote from the encapsulating barrier layer 304; wherein the first coating has a refractive index greater than a refractive index of the second coating.
- the first coating layer may include one or more of a silane-modified unsaturated acrylate-based polymer, an unsaturated urethane acrylate-based polymer, and an unsaturated fluorine-containing acrylate-based polymer;
- the polymer may be a monofunctional polymer or a polyfunctional polymer, which is not limited herein.
- the first coating layer has a thickness of from 1 to 10 ⁇ m, preferably from 2.5 to 10 ⁇ m, and more preferably from 2.5 to 7.5 ⁇ m.
- the second coating layer may include an unsaturated acrylate-based polymer doped with inorganic particles; specifically, the material of the second coating layer may be the same as or different from the material of the first coating layer, The addition of the inorganic particles to the material of the second coating allows the second coating to have a relatively high refractive power.
- the inorganic particles may include one or more of titanium dioxide, titanium oxide, acicular zinc oxide, calcium nano titanate, and barium titanate.
- the second coating layer has a thickness of from 1 to 10 ⁇ m, preferably from 2.5 to 10 ⁇ m, and more preferably from 2.5 to 7.5 ⁇ m.
- the particle diameter of the inorganic particles is preferably from 20 to 1000 nm, more preferably from 30 to 500 nm and most preferably from 50 to 250 nm.
- the reflective effect of the encapsulating layer 30 can be improved, making it low-reflective or even Anti-reflective.
- the unsaturated acrylate organic coating layer may further include an unsaturated acrylate organic coating doped with hard particles; wherein the hard particles may specifically include graphene oxide, transparent graphite, One or more of glass fibers and diamond particles.
- the hard particles have a relatively high hardness, and by doping the above-described hard particles in the unsaturated acrylate-based organic coating layer, the scratch resistance of the encapsulating layer 30 can be effectively improved.
- the organic coating for the encapsulating layer according to the present invention may be prepared from a composition comprising an unsaturated acrylate, an additive, and a solvent.
- the unsaturated acrylate is preferably a urethane acrylate or an epoxy acrylate.
- the content of the unsaturated acrylate is from 10 to 85% by weight, preferably from 20 to 60% by weight, more preferably from 20 to 40% by weight, based on the total weight of the composition.
- the unsaturated acrylate may be selected from those commonly used in the art for passing ultraviolet light, An unsaturated acrylate which forms a film layer upon curing by visible light, heat, chemical reaction, etc., and specific examples thereof include: hydroxyethyl acrylate, amino acrylate, epoxy acrylate, alicyclic epoxy methacrylate, Methyl methacrylate and the like.
- the unsaturated acrylate is a urethane acrylate or an epoxy acrylate.
- the urethane acrylate may be selected from one or more of the following: urethane acrylate, silicone-acrylate modified polyurethane, epoxy modified urethane acrylate, aliphatic modified urethane acrylate Classes, etc.
- the epoxy acrylate may be bisphenol A epoxy acrylate.
- the unsaturated acrylate has a weight average molecular weight of from 5,000 to 100,000, preferably from 10,000 to 50,000, and more preferably from 10,000 to 25,000, for the purpose of achieving sufficient crosslinking to avoid the need to use a binder and provide sufficient water oxygen barrier effect.
- the organic coating layer in the encapsulating layer according to the present invention may further contain various functional additives, such as an antifogging agent, an antireflection agent, a scratch resistant agent, etc., and the content in the organic coating layer may be determined according to the Need performance to choose properly.
- the organic coating may be an organic coating doped with anti-fogging particles or a surfactant, or may be a water-absorbing anti-fog organic coating.
- the doped anti-fog particles include: titanium dioxide, zinc oxide, nano-silica, super-hydrophobic silicon material, male/anionic/zwitterionic surfactant, modified polymer, etc.; water-absorbing organic coating includes high water absorption Polyol urethane resin and the like.
- the anti-reflection function achieves anti-reflection by adding particles of different refractive indices.
- the low refractive index coating mainly consists of adding low refractive fluoride, fluorine-containing acrylate, silane-modified unsaturated acrylate polymer, unsaturated urethane acrylic acid.
- High refractive is achieved by adding one or more of inorganic nano-oxides such as titanium dioxide, titanium oxide, acicular zinc oxide, calcium nano-titanate, and barium titanate.
- the scratch-resistant hard particles are added to the organic coating or mixed with a hard monomer to form a film, which can improve scratch resistance.
- the scratch-resistant agent is, for example, one or more selected from the group consisting of glass fibers, celluloses, silica particles, or silicon-containing particles, alumina particles, graphene oxide, transparent graphite, glass fibers, and diamond particles.
- the organic coating layer 305 can have other properties such as anti-fog while having a water-oxygen barrier effect. Sex, anti-reflective, and scratch resistant.
- An embodiment of the present invention further provides an electronic package device, as shown in FIG. 3, comprising a substrate substrate 10 and an encapsulation layer 30, and an electronic device 20 therebetween;
- the encapsulation layer 30 is the encapsulation layer provided by the above embodiments.
- the electronic package device may include an OLED display device, a CCD device, an electronic paper, a smart tag, and a smart card, and is not limited thereto.
- the core component of the electronic package device ie, the electronic device 20
- the electronic device 20 Since the core component of the electronic package device (ie, the electronic device 20) is very sensitive to moisture and oxygen in the atmospheric environment, in order to ensure the normal operation of the electronic device 20, it needs to be packaged to extend its service life. .
- the electronic device 20 can be packaged, which not only ensures good water-oxygen barrier effect, but also can realize thinning and thinning of the electronic package device. .
- the electronic package device may be an OLED display device, and the electronic device 20 may be an organic material functional layer 20 between the substrate substrate 10 and the encapsulation layer 30;
- the encapsulating barrier layer 304 of the encapsulation layer 30 is adjacent to the substrate substrate 10 , and the organic coating layer 305 of the encapsulation layer 30 is away from the substrate substrate 10 .
- the substrate substrate 10 may be a glass substrate or a flexible substrate, which is not specifically limited herein.
- the OLED display device can be divided into the passively driven OLED display device shown in FIG. 3 and the active driving OLED display device shown in FIG. 4 according to the driving manner thereof.
- the OLED display device may further include a thin film transistor 40 between the substrate substrate 10 and the organic material functional layer 20, Driving each of the light emitting units of the OLED display device.
- the encapsulation barrier layer 304 may be formed over the organic material functional layer 20, and the organic coating layer 305 may be formed on the surface of the encapsulation barrier layer 304.
- the package barrier layer 304 may include an inorganic passivation layer 301 or a package film 302.
- the OLED display device provided by the embodiment of the present invention deposits a layer of encapsulating barrier layer 304 on the surface of the functional layer 20 of the organic material, and applies a layer of cured film forming on the surface of the encapsulating barrier layer 304.
- Organic coating 305 can be guaranteed Under the premise of the water-oxygen barrier effect of the encapsulation layer 30, the thickness of the OLED display device is effectively reduced, thereby achieving thinning of the OLED display device.
- the encapsulating barrier layer 304 preferably employs a multi-layered overlying encapsulating film 302, such as an alternating deposition of an organic film and an inorganic film.
- the encapsulation film 302 has a better water and oxygen barrier effect than the inorganic passivation layer 301.
- the substrate substrate 10 is preferably a flexible substrate substrate.
- the flexible substrate substrate 10 may include a polyimide (PI) substrate, polyethylene (PE). a base substrate, a polypropylene (PP) substrate, a polystyrene (PS) substrate, a polyethylene terephthalate (PET) substrate, And any one of a polyethylene naphthalate (PEN) base substrate.
- PI polyimide
- PE polyethylene
- PP polypropylene
- PS polystyrene
- PET polyethylene terephthalate
- PEN polyethylene naphthalate
- the OLED display device is a flexible OLED display device.
- the reduction in the thickness of the device can effectively reduce the internal stress of the flexible OLED display device, thereby improving the occurrence of bending cracks and poor separation of layers. Improving the bending performance of the OLED display device.
- the OLED display device preferably employs the flexible substrate substrate 10 and the encapsulation layer 30 provided by the embodiment of the present invention, and the organic material functional layer 20 therebetween to form a flexible OLED display device;
- the curved display characteristics of flexible OLED display devices provide users with a new visual experience.
- the OLED display device can also have anti-fog, low reflection, scratch resistance and the like, thereby expanding the application field thereof. Improve its display.
- composition of the organic coating layer 305 and the effect that can be achieved can be referred to the description of the portion of the encapsulation layer 30 provided by the embodiment of the present invention, and details are not described herein again.
- the illuminating manner of the OLED display device provided by the embodiment of the present invention may be a top emission or a bottom emission, and may also be a double-sided emission, which is not limited herein.
- the top emission refers to a side of the light emitting direction away from the substrate 10
- the bottom emission is The light-emitting direction is directed to the side of the base substrate 10, and the double-sided emission includes the above two cases.
- the encapsulation layer 30 provided by the embodiment of the present invention can effectively block moisture and oxygen in the atmospheric environment from entering the OLED display device. Internally, it is thereby possible to improve the illuminating performance of the flexible top emission type display device and extend the life of the device.
- Embodiments of the present invention also provide a display device including the above-described electronic package device.
- the display device may specifically include a device having a display function, such as a display, a mobile phone, or a digital camera, and is not specifically limited herein.
- the OLED display device may include a flexible substrate substrate 10, a thin film transistor 40 located above the flexible substrate substrate 10, and an organic material functional layer 20 located above the thin film transistor 40.
- the preparation process of the OLED display device may include the following steps:
- a flexible substrate substrate 10 is provided.
- the flexible base substrate 10 preferably employs a PI substrate having a thickness of about 10 ⁇ m.
- the thin film transistor may sequentially include a gate, a gate insulating layer above the gate, a semiconductor active layer above the gate insulating layer, and a source above the semiconductor active layer and in the same layer Pole and drain.
- the thin film transistor 40 may constitute an active driving control layer of the OLED display device, and has a thickness of about 4 ⁇ m.
- the organic material functional layer 20 may specifically include a red light emitting unit, a green light emitting unit, and a blue light emitting unit, and the light emitting unit may be in one-to-one correspondence with the thin film transistor 40.
- the organic material functional layer 20 has a thickness of about 500 nm.
- the material of the encapsulating barrier layer 304 may be an inorganic passivation material such as silicon nitride, and the silicon nitride has a thickness of about 1 ⁇ m.
- the coating manner of the organic solution may include any one of spin coating, spray coating, flat wiper film, inkjet printing, and slit coating; the thickness of the formed organic coating 305 may be the same as the PI substrate.
- the thickness of the platform is about 10 ⁇ m.
- the organic coating layer 305 is preferably an organic coating layer having both water and oxygen barrier properties, antifogging properties, low reflectivity, and scratch resistance.
- a flexible OLED display device can be formed; the flexible OLED display device not only has the characteristics of lightness and thinness, but also has excellent characteristics of blocking water oxygen, anti-fog, low reflection, and scratch resistance, and can Effectively improving the display effect of the OLED display device.
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Abstract
Description
Claims (12)
- 一种封装层,其特征在于,包括封装阻隔层和直接在所述封装阻隔层上形成的有机涂层;其中,所述有机涂层为可聚合型有机涂层;所述可聚合型有机涂层包括不饱和丙烯酸酯类有机涂层。
- 根据权利要求1所述的封装层,其特征在于,所述有机涂层的厚度为5μm~10μm。
- 根据权利要求1所述的封装层,其特征在于,所述不饱和丙烯酸酯类有机涂层包括聚氨酯丙烯酸酯类有机涂层或者环氧丙烯酸酯类有机涂层。
- 根据权利要求3所述的封装层,其特征在于,所述不饱和丙烯酸酯类有机涂层中添加有阳离子表面活性剂;其中,所述阳离子表面活性剂包括亲水性季铵盐。
- 根据权利要求3所述的封装层,其特征在于,所述不饱和丙烯酸酯类有机涂层包括靠近所述封装阻隔层的第一涂层和远离所述封装阻隔层的第二涂层;其中,所述第一涂层的折射率大于所述第二涂层的折射率。
- 根据权利要求5所述的封装层,其特征在于,所述第一涂层包括硅烷改性不饱和丙烯酸酯类聚合物、不饱和聚氨酯丙烯酸酯类聚合物、不饱和含氟丙烯酸酯类聚合物中的一种或多种;所述第二涂层包括掺杂有无机颗粒的不饱和丙烯酸酯类聚合物;所述无机颗粒包括二氧化钛、一氧化钛、氧化锌、钛酸铜钙、钛酸锶颗粒中的一种或多种。
- 根据权利要求3所述的封装层,其特征在于,所述不饱和丙烯酸酯类有机涂层包括掺杂有硬质颗粒的不饱和丙烯酸酯类有机涂层;其中,所述硬质颗粒包括氧化石墨烯、透明石墨、玻璃纤维、金刚石粒子中的一种或多种。
- 根据权利要求1至7任一项所述的封装层,其特征在于,所述封装阻隔层包括多层交叠的封装薄膜。
- 一种电子封装器件,包括衬底基板和封装层,以及位于二者之间的电子器件;其特征在于,所述封装层为权利要求1至8任一项所述的封装层。
- 根据权利要求9所述的电子封装器件,其特征在于,所述电子封装器件为OLED显示器件,所述电子器件为所述衬底基板和所述封装层之间的有机材料功能层;其中,所述封装层的封装阻隔层靠近所述衬底基板,所述封装层的有机涂层远离所述衬底基板。
- 根据权利要求9或10所述的电子封装器件,其特征在于,所述衬底基板为柔性衬底基板;其中,所述柔性衬底基板包括聚酰亚胺衬底基板、聚乙烯衬底基板、聚丙烯衬底基板、聚苯乙烯衬底基板、聚对苯二甲酸乙二醇酯衬底基板、聚萘二甲酸乙二醇酯衬底基板中的任意一种。
- 一种显示装置,其特征在于,所述显示装置包括权利要求9-11任一项所述的电子封装器件。
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CN110335968A (zh) * | 2019-07-02 | 2019-10-15 | 深圳市华星光电技术有限公司 | 柔性基板及其制作方法与显示面板 |
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