Classifications

• • H—ELECTRICITY
  • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
  • H02B—BOARDS, SUBSTATIONS OR SWITCHING ARRANGEMENTS FOR THE SUPPLY OR DISTRIBUTION OF ELECTRIC POWER
  • H02B1/00—Frameworks, boards, panels, desks, casings; Details of substations or switching arrangements
  • H02B1/26—Casings; Parts thereof or accessories therefor
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
  • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
  • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
  • H01B3/56—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances gases
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
  • H01H33/00—High-tension or heavy-current switches with arc-extinguishing or arc-preventing means
  • H01H33/02—Details
  • H01H33/04—Means for extinguishing or preventing arc between current-carrying parts
  • H01H33/22—Selection of fluids for arc-extinguishing
• • H—ELECTRICITY
  • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
  • H02B—BOARDS, SUBSTATIONS OR SWITCHING ARRANGEMENTS FOR THE SUPPLY OR DISTRIBUTION OF ELECTRIC POWER
  • H02B13/00—Arrangement of switchgear in which switches are enclosed in, or structurally associated with, a casing, e.g. cubicle
  • H02B13/02—Arrangement of switchgear in which switches are enclosed in, or structurally associated with, a casing, e.g. cubicle with metal casing
  • H02B13/035—Gas-insulated switchgear
  • H02B13/055—Features relating to the gas
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
  • H01H33/00—High-tension or heavy-current switches with arc-extinguishing or arc-preventing means
  • H01H33/02—Details
  • H01H33/53—Cases; Reservoirs, tanks, piping or valves, for arc-extinguishing fluid; Accessories therefor, e.g. safety arrangements, pressure relief devices
  • H01H33/56—Gas reservoirs
  • H01H2033/566—Avoiding the use of SF6

Definitions

• the present invention relates to an electrical apparatus for the generation, transmission, distribution and/or usage of 5 electrical energy, according to the preamble of the independent claims, and to a method for determining an optimum amount of an adsorber for the adsorption of water and optionally further contaminants in such an electrical apparatus .
• electrical apparatuses such as switchgears, gas-insulated substations (GIS) , gas-insulated lines (GIL) or transformers, a dielectric insulation media in liquid or gaseous state is conventionally used for the insulation of the electrical component comprised therein.
• the electrical component is arranged in a housing, which encloses an insulating space, the insulation space comprising an insulation gas and separating the housing from the electrical component without letting electrical current0 to pass through and thereby providing dielectric insulation.
• the insulating gas further functions as an arc extinction gas (hereinafter also referred to as "quenching gas”) .
• sulphur hexafluoride has been used as5 an insulation medium or quenching gas, respectively.
• SF 6 is known for its high dielectric strength and thermal interruption capability.
• SFe might have some environmental impact when released into the atmosphere, in particular due to its high global warming potential (GWP) and0 its relatively long lifetime in the atmosphere. So far, the relatively high GWP of SF6 has been coped with by strict gas leakage control and by very careful gas handling. Nevertheless, there is an on-going effort in the development of alternative insulation media or quenching gases, respectively.
• CO2 is readily available, non-toxic and non ⁇ flammable.
• a circuit breaker using CO2 as a quenching gas for restraining its impact on global warming is e.g. described in US 7,816,618.
• EP-A-2284854 proposes a mixed gas mainly comprising CO2 and CH4 as an arc-extinguishing medium.
• the electrical apparatus can further be provided with a contamination- reducing component.
• a contamination-reducing component for example, adsorbers such as a zeolite are disclosed as contamination-reducing component.
• adsorbers such as a zeolite are disclosed as contamination-reducing component.
• a zeolite has a selectivity that is primarily driven, by its pore size. Therefore, the use of zeolite is only feasible, if the kinetic diameter of the insulation medium molecule (s) is significantly different from the one of the contaminant ( s ) . If the kinetic diameter of the insulation gas molecule (s) is similar, co-adsorption of the insulation gas molecules can occur .
• the problem of the present invention is thus to provide an electrical apparatus using a dielectric insulation medium comprising CO2 , said apparatus allowing a reduction or elimination of contaminants from the insulation medium without substantially interfering with its insulation and arc extinction performance.
• the present invention thus relates to an electrical apparatus for the generation, transmission, distribution and/or usage of electrical energy
• said electrical apparatus comprising a housing enclosing an electrical apparatus interior space, at least a portion of the electrical apparatus interior space forming at least one insulation space, in which an electrical component is arranged and which contains an insulation medium surrounding said electrical component, the insulation medium comprising carbon dioxide, the insulation space comprising, in particular being formed by, at least one insulation space compartment, in which an adsorber for reducing or eliminating the amount of water and optionally further contaminants from the insulation medium is arranged, the amount of adsorber m a ds arranged in at least one insulation space compartment, in particular in each insulation space compartment, complying with the following formula ( I ) : mads ⁇ kads,H— 2 0 with
• ⁇ 2 ⁇ being the amount of water present in the respective insulation space compartment
• k a ds,H2o being the adsorption capability of the adsorber towards water at a predetermined temperature To; wherein m a ds further complies with the following formula (II) m ads ⁇ 0.1 - ⁇ - (ii:
• the presence of at least some water in the at least one insulation space compartment is almost impossible to avoid.
• water is thus present in the at least one insulation space compartment.
• the amount of water present can be determined, the methods for which are well known to the person skilled in the art.
• each insulation space compartment is provided with an amount of adsorber specified to the actual needs.
• the lower limit of the amount of adsorber present in the insulation space compartment is defined by first formula (I), whereas the upper limit is defined by second formula (II). Accordingly, the amount of adsorber is on the one hand sufficient for removing water present in the insulation space compartment, and on the other hand is limited such that at most 10% of the carbon dioxide present in the insulation space compartment is adsorbed.
• the amount of adsorber m a ds is such that when introducing it into the insulation space compartment, the insulation medium undergoes a change in the partial pressure of CO 2 of less than 15%, preferably less than 10%, more preferably less than 5%, and most preferably less than 2%.
• the change in the density of CO2 is according to this embodiment less than 15%, preferably less than 10%, more preferably less than 5%, and most preferably less than 2%.
• the decrease in the insulation and arc extinction performance of the insulation medium is limited to an acceptable degree, and - if a gas mixture is used - the uniformity of the medium's composition is only affected unsubstantially.
• adsorption capability refers to the amount (in kilogram) of the respective adsorbate, in the specific case the respective contaminant (in particular water) , that can be adsorbed to a given amount (in kilogram) of adsorber.
• the "adsorption capability” refers to the amount of adsorbate the adsorber is capable to adsorb.
• an adsorption capability of 0.1 refers to 100 gram of adsorbate being adsorbed to 1 kilogram of adsorber.
• contaminants as used herein encompasses both water and decomposition products. Among the contaminants, the amount of water typically dominates over the amount of decomposition products.
• the adsorption capability is a characteristic specific to the material of the adsorber and in general is dependent on its temperature, as well as on the conditions the adsorber has been subjected to. As a rule, the adsorption capability is lower for an adsorber to which some adsorbate has already been adsorbed than for an adsorber which is free of adsorbate. For a given adsorber, the adsorption capability typically refers to the fresh material as received on the market.
• the respective information on the adsorption capability is known to the skilled person or is provided by the respective distributor.
• the adsorption capability is dependent on the temperature and thus refers to a predetermined temperature To, specifically room temperature.
• the term "predetermined temperature" as used in the context of the present invention relates to the relevant temperature, more specifically to the average gas temperature at the operating condition of the electrical apparatus. Even more specifically, the predetermined temperature To relates to room temperature and most specifically to standard ambient temperature, i.e. 298.15 K.
• the predetermined temperature To which relates to the temperature of the adsorber, can be chosen as follows .
• the adsorption capability k a ds,H2o typically decreases with increasing predetermined temperature To, and thus the minimal desired amount of adsorber m a ds typically increases with increasing predetermined temperature To.
• representative adsorber temperatures can lie between enclosure temperatures (e.g. 30°C in normal operation or 60°C in extreme operation) and gas temperatures or temperatures of current-carrying components (e.g. 50 °C in normal operation or 100 °C in extreme operation) and can thus for example be about 35-40°C (normal operation) or about 80°C (extreme operation).
• a predetermined temperature To shall be chosen to be lower than the representative adsorber temperature, i.e. surely lower than about 80°C and preferably lower than about 35-40°C and more preferably about room temperature or standard ambient temperature, i.e. 298.15 K.
• a predetermined temperature To shall be chosen to be lower than the representative adsorber temperature, i.e. surely lower than about 80°C and preferably lower than about 35-40°C and more preferably about room temperature or standard ambient temperature, i.e. 298.15 K.
• the actual amount of adsorber m a ds is preferably chosen closer to the upper limit than to the lower limit. This results in tolerating larger, but still permis- sible pressure swings in carbon dioxide partial pressure and to increase the water absorption capacity of the adsorber m a ds .
• the amount of adsorber m a ds arranged in the at least one insulation space compartment, in particular in each insulation space compartment complies with the following formula (I) : m ads ⁇ -—2— (I) with ⁇ 2 ⁇ being the amount of water present in the respective insulation space compartment, and kads,H2o being the adsorption capability of the adsorber towards water at a first predetermined temperature Ti; wherein m a ds further complies with the following formula (ID : m ads ⁇ 0.1 - ⁇ 2a_
• the first predetermined temperature Ti is chosen higher than the second predetermined temperature 2. This results in smaller ranges of permissible amounts of adsorber m a ds.
• the first predetermined temperature Ti is chosen in analogy to above-mentioned To to be lower than the representative adsorber temperature, i.e. surely lower than about 80 °C and preferably lower than about 35-40 °C and more preferably about room temperature or standard ambient temperature, i.e. 298.15 K.
• the first predetermined temperature Ti is chosen equal to or higher than the (sole or combined) predetermined temperature To.
• the second predetermined temperature Ti is chosen to be lower than the representative adsorber temperature, i.e. lower than about 35-40°C and more preferably lower than room temperature, and most preferred equal or approximately equal to the minimal operating temperature of the electrical apparatus, for example -5°C or -40°C.
• the second predetermined temperature T2 is chosen smaller than the (sole or combined) predetermined temperature To. This results in smaller ranges of permissible amounts of adsorber m a ds-
• first and second predetermined temperature Ti and T2 instead of the (sole or combined) predetermined temperature To.
• first and second predetermined temperature Ti and 2 can be chosen to be identical to one another and thus to be the predetermined temperature To.
• the temperature of the adsorber is typically below the average temperature of the insulation medium, and in particular of the housing.
• the adsorption capability is also dependent on the pressure or partial pressure of the respective adsorbate .
• the respective information on the adsorption capability is known to the skilled person or is provided by the respective distributor.
• CO2 adsorption the pressure dependency for a typical adsorber, such as a zeolite, is very low, once the CO2 pressure is in the order of several bars, as is typically the case for the electrical apparatus according to the present invention.
• k a ds,co2 is dependent on the amount of e.g. water adsorbed, i.e. the adsorption capability of the adsorber towards carbon dioxide decreases with increasing amount of water adsorbed. Given the fact that with time more water is adsorbed, k a ds,co2 decreases with time. Thus, if initially the amount of adsorber m a ds is chosen such that it complies with formula (II), this formula (II) will also be complied with when kads,co2 decreases over time. According to an embodiment, k a ds,co2 thus relates to the initial kads,co2, i.e.
• the adsorption capability of the adsorber towards carbon dioxide at the predetermined temperature To at the time when placing the adsorber into the at least one insulation space compartment, in other words typically at the time when putting the electrical apparatus into operation or at the time of maintenance work on the electrical apparatus.
• m H 2o relates to the initial m H 2o, i.e. to the amount of water present in the insulation space compartment at the time when placing the adsorber into the insulation space compartment.
• mco2 relates to the amount of carbon dioxide present in the insulation space compartment at the time when placing the adsorber into the insulation space compartment .
• k a ds,H2o relates to the adsorption capability of the adsorber towards water at predetermined temperature To at the time when placing the adsorber into the insulation space compartment.
• the expression "the amount of water present in the insulation space compartment” encompasses water in any state and in particularly also encompasses water present in a solid material, such as in polymeric material, that is directly exposed to the insulation space compartment, since this water typically diffuses out of the material into the insulation space compartment over time.
• the term "the amount of water present in the insulation space compartment” thus also relates to water that is releasable into the insulation space compartment, in addition to the water already present in the insulation space compartment.
• the adsorber is a moisture- reducing component.
• moisture-reducing component is equivalent to the term “water-reducing component”.
• the adsorber is a molecular sieve, more preferably a zeolite, i.e. a micro-porous aluminosilicate mineral that has undergone cation exchange to achieve a desired pore size.
• Zeolites are inexpensive and allow a great range of different contaminants to be adsorbed, even at elevated temperatures, particularly in a range of 40° to 80 °C.
• Further preferred adsorbers enclose active charcoal and active alumina.
• the term "adsorption capability" shall encompass any adsorption processes, such as physisorption and/or chemi- sorption.
• Physisorption can, in particular, be determined or be influenced by the relationship between the size of molecules of the insulation medium and the pore size of the adsorber, specifically of the molecular sieve.
• Chemisorption can, in particular, be determined or be influenced by chemical, typically reversal, interactions between molecules of the insulation medium and the adsorber, specifically the molecular sieve.
• the molecular sieve particularly the zeolite, has an average pore size from 2 A to 13 A, preferably from 2 A to 10 A, even more preferably from 2 A to 8 A, most preferably from 2 A to 5 A.
• Molecular sieves having these pore sizes have been found to have a particularly high adsorption capacity and allow water and/or decomposition products, such as HF, to be efficiently adsorbed and thus to be removed from the insulation medium.
• the molecular sieve, and the zeolite in particular, having an average pore size of 5 A at most is particularly preferred, since in embodiments in which the insulation medium comprises a fluoroketone, which will be described in detail below, the latter is not adsorbed.
• the molecular sieve, and the zeolite in particular, having an average pore size of 3 A at most for its relatively low tendency to adsorb CO 2 .
• Suitable zeolites include e.g. ZEOCHEM® molecular sieve 3A (having a pore size of 3 A) , ZEOCHEM® molecular sieve 5A (having a pore size of 5 A) and ZEOCHEM® molecular sieve 13X (having a pore size of 9 A) .
• the term "adsorption” or “adsorbed” encompasses both physisorption and/or chemisorption .
• Physisorption can, in particular, be determined or be influenced by the relationship between the size of molecules of the insulation medium and the pore size of the molecular sieve.
• Chemisorption can, in particular, be determined or influenced by chemical interactions between molecules of the insulation medium and the molecular sieve.
• the advantages of the present invention are particularly pronounced in an embodiment, in which the insulation space is formed by at least two insulation space compartments separated from each other, because the invention allows to keep the influence of the adsorber on the insulation and arc- extinction performance of the insulation medium to a minimum, which is not the case if a standard amount is used for all compartments without taking into account the different needs present in the specific compartments.
• This is of particular relevance, if the compartments significantly differ from each other in the amount of water being present or released and/or the amount of decomposition products being generated.
• the feature that the at least two insulation space compartments are separated from each other means that they are not in fluid connection with each other.
• the volumes of the at least two insulation space compartments differ from one another by a factor of at least 1.5, more preferably at least 7, and most preferably at least 50.
• the at least one insulation space compartment comprises a volume-specific amount of less than 5 kg adsorber per cubic meter, preferably less than 1.25 kg adsorber per cubic meter, more preferably less than 0.25 kg adsorber per cubic meter, and most preferably less than 0.125 kg adsorber per cubic meter of the volume of the insulation space compartment.
• the at least one insulation space compartment comprises a volume-specific amount of less than 2 kg adsorber per cubic meter, preferably less than 0.5 kg adsorber per cubic meter, more preferably less than 0.1 kg adsorber per cubic meter, and most preferably less than 0.05 adsorber per kg per cubic meter of the volume of the insulation space compartment.
• the electrical apparatus can comprise a desiccant selected from the group consisting of: calcium, calcium sulphate, in particular drierite, calcium carbonate, calcium hydride, calcium chloride, potassium carbonate, potassium hydroxide, copper (II) sulphate, calcium oxide, magnesium, magnesium oxide, magnesium sulphate, magnesium perchlorate, sodium, sodium sulphate, aluminium, lithium aluminium hydride, aluminium oxide, activated alumina, montmorrilonite, phosphorpentoxide, silica gel and a cellulose filter, as well as mixtures thereof.
• a desiccant selected from the group consisting of: calcium, calcium sulphate, in particular drierite, calcium carbonate, calcium hydride, calcium chloride, potassium carbonate, potassium hydroxide, copper (II) sulphate, calcium oxide, magnesium, magnesium oxide, magnesium sulphate, magnesium perchlorate, sodium, sodium sulphate, aluminium, lithium aluminium hydride, aluminium oxide, activated
• the insulation medium comprises carbon dioxide (C0 2 ) .
• the insulation medium consists or essentially consists of carbon dioxide.
• carbon dioxide is thus the sole component of the insulation medium.
• the insulation medium can comprise carbon dioxide apart from other constituents and thus form a gas mixture, which is an often preferred embodiment. It is particularly preferred that the insulation medium comprises - apart from carbon dioxide - air or at least one air component, in particular selected from the group consisting of oxygen and nitrogen and mixtures thereof.
• the insulation medium comprises a mixture of carbon dioxide and oxygen.
• the ratio of the amount of carbon dioxide to the amount of oxygen can thereby range from 50:50 to 100:1.
• the ratio of the amount of carbon dioxide to the amount of oxygen ranges from 80:20 to 95:5, more preferably from 85:15 to 92:8, even more preferably from 87:13 to less than 90:10, and in particular is about 89:11.
• oxygen being present in a molar fraction of at least 5% cannot sufficiently suppress soot formation which is to be prevented even after repeated current interruption events with high current arcing.
• the insulation medium additionally comprises an organofluorine compound, since it has been found that these contribute to very high insulation capabilities, in particular a high dielectric strength (or breakdown field strength) , and at the same time have a low GWP and low toxicity.
• organofluorine compound since it has been found that these contribute to very high insulation capabilities, in particular a high dielectric strength (or breakdown field strength) , and at the same time have a low GWP and low toxicity.
• the advantages achievable by the present invention are of particular relevance in this embodiment, since water is efficiently removed, which might otherwise open reaction pathways with the organofluorine compound to generate decomposition products. The generation of e.g. hydrogen fluoride, which is extremely toxic and corrosive, can thus efficiently be avoided.
• the organofluorine compound is selected from the group consisting of: fluoroethers , in particular hydro- fluoromonoethers, fluoroketones , in particular perfluoro- ketones, fluoroolefins , in particular hydrofluoroolefins , fluoronitriles , in particular perfluoronitriles , and mixtures thereof, since these classes of compounds have been found to have very high insulation capabilities, in particular a high dielectric strength (or breakdown field strength) and at the same time a low GWP and low toxicity.
• the invention encompasses both embodiments in which the dielectric insulation gas comprises either one of a fluoro- ether, in particular a hydrofluoromonoether, a fluoroketone and a fluoroolefin, in particular a hydrofluoroolefin, as well as embodiments in which it comprises a mixture of at least two of these compounds.
• fluoroether as used in the context of the present invention encompasses both perfluoroethers , i.e. fully fluorinated ethers, and hydrofluoroethers , i.e. ethers that are only partially fluorinated.
• fluoroether further encompasses saturated compounds as well as unsaturated compounds, i.e. compounds including double and/or triple bonds between carbon atoms.
• the at least partially fluorinated alkyl chains attached to the oxygen atom of the fluoroether can, independently of each other, be linear or branched .
• fluoroether further encompasses both non-cyclic and cyclic ethers.
• the two alkyl chains attached to the oxygen atom can optionally form a ring.
• the term encompasses fluorooxiranes .
• the organofluorine compound according to the present invention is a perfluorooxirane or a hydrofluorooxirane, more specifically a perfluorooxirane or hydrofluorooxirane comprising from three to fifteen carbon atoms.
• the dielectric insulation gas comprises a hydrofluoromonoether containing at least three carbon atoms.
• these hydrofluoromonoethers are chemically and thermally stable up to temperatures above 140 °C. They are further non-toxic or have a low toxicity level. In addition, they are non- corrosive and non-explosive.
• the term "hydrofluoromonoether” as used herein refers to a compound having one and only one ether group, said ether group linking two alkyl groups, which can be, independently from each other, linear or branched, and which can optionally form a ring. The compound is thus in clear contrast to the compounds disclosed in e.g. US-B-7128133, which relates to the use of compounds containing two ether groups, i.e. hydrofluorodiethers, in heat-transfer fluids.
• hydrofluoromonoether as used herein is further to be understood such that the monoether is partially hydrogenated and partially fluorinated. It is further to be understood such that it may comprise a mixture of differently structured hydrofluoromonoethers .
• structurally different shall broadly encompass any difference in sum formula or structural formula of the hydrofluoromonoether .
• hydrofluoromonoethers containing at least three carbon atoms have been found to have a relatively high dielectric strength. Specifically, the ratio of the dielectric strength of the hydrofluoromonoethers according to the present invention to the dielectric strength of SF 6 is greater than about 0.4.
• the GWP of the hydrofluoromonoethers is low.
• the GWP is less than l'OOO over 100 years, more specifically less than 700 over 100 years.
• the hydrofluoromonoethers mentioned herein have a relatively low atmospheric lifetime and in addition are devoid of halogen atoms that play a role in the ozone destruction catalytic cycle, namely CI, Br or I. Their Ozone Depletion Potential (ODP) is zero, which is very favourable from an environmental perspective.
• ODP Ozone Depletion Potential
• the preference for a hydrofluoromonoether containing at least three carbon atoms and thus having a relatively high boiling point of more than -20°C is based on the finding that a higher boiling point of the hydrofluoromonoether generally goes along with a higher dielectric strength.
• the hydrofluoromonoether contains exactly three or four or five or six carbon atoms, in particular exactly three or four carbon atoms, most preferably exactly three carbon atoms .
• the hydrofluoromonoether is thus at least one compound selected from the group consisting of the compounds defined by the following structural formulae in which a part of the hydrogen atoms is each substituted by a fluorine atom:
• the ratio of the number of fluorine atoms to the total number of fluorine and hydrogen atoms, here briefly called "F-rate", of the hydrofluoromonoether is at least 5:8. It has been found that compounds falling within this definition are generally non-flammable and thus result in an insulation medium complying with highest safety requirements. Thus, safety requirements of the electrical insulator and the method of its production can readily be fulfilled by using a corresponding hydrofluoromonoether .
• the ratio of the number of fluorine atoms to the number of carbon atoms ranges from 1.5:1 to 2:1.
• Such compounds generally have a GWP of less than l'OOO over 100 years and are thus very environment-friendly. It is particularly preferred that the hydrofluoromonoether has a GWP of less than 700 over 100 years.
• the hydrofluoromonoether has the general structure (0)
• exactly one of c and f in the general structure (0) is 0.
• the corresponding grouping of fluorines on one side of the ether linkage, with the other side remaining unsubstituted, is called "segregation". Segregation has been found to reduce the boiling point compared to unsegregated compounds of the same chain length. This feature is thus of particular interest, because compounds with longer chain lengths allowing for higher dielectric strength can be used without risk of liquefaction under operational conditions.
• the hydrofluoromonoether is selected from the group consisting of pentafluoro-ethyl-methyl ether (C3 ⁇ 4- O-CF2C F3 ) and 2, 2, 2-trifluoroethyl-trifluoromethyl ether ( CF3-O-CH2C F3 ) .
• Pentafluoro-ethyl-methyl ether has a boiling point of +5.25°C and a GWP of 697 over 100 years, the F-rate being 0.625
• 2 , 2 , 2-trifluoroethyl-trifluoromethyl ether has a boiling point of +11°C and a GWP of 487 over 100 years, the F-rate being 0.75. They both have an ODP of 0 and are thus environmentally fully acceptable.
• pentafluoro-ethyl-methyl ether has been found to be thermally stable at a temperature of 175°C for 30 days and therefore to be fully suitable for the operational conditions given in the apparatus. Since thermal stability studies of hydrofluoromonoethers of higher molecular weight have shown that ethers containing fully hydrogenated methyl or ethyl groups have a lower thermal stability compared to those having partially hydrogenated groups, it can be assumed that the thermal stability of 2 , 2 , 2-trifluoroethyl-trifluoromethyl ether is even higher.
• hydrofluoromonoethers and in particular pentafluoro-ethyl- methyl ether as well as 2 , 2 , 2-trifluoroethyl-trifluoromethyl ether, have a lethal concentration LC 50 of higher than 10' 000 ppm, rendering them suitable also from a toxicological point of view.
• hydrofluoromonoethers mentioned have a higher dielectric strength than air.
• pentafluoro-ethyl-methyl ether at 1 bar has a dielectric strength about 2. times higher than that of air at 1 bar.
• the hydrofluoromonoethers mentioned are normally in the gaseous state at operational conditions.
• a dielectric insulation medium in which every component is in the gaseous state at operational conditions of the apparatus can be achieved, which is advantageous.
• the dielectric insulation gas comprises a fluoroketone containing from four to twelve carbon atoms.
• fluoroketone as used in this application shall be interpreted broadly and shall encompass both perfluoroketones and hydrofluoroketones, and shall further encompass both saturated compounds and unsaturated compounds, i.e. compounds including double and/or triple bonds between carbon atoms.
• the at least partially fluorinated alkyl chain of the fluoroketones can be linear or branched, or can form a ring, which optionally is substituted by one or more alkyl groups.
• the fluoroketone is a perfluoro- ketone.
• the fluoroketone has a branched alkyl chain, in particular an at least partially fluorinated alkyl chain.
• the fluoroketone is a fully saturated compound.
• the present invention also relates to a dielectric insulation medium comprising a fluoroketone having from 4 to 12 carbon atoms, the at least partially fluorinated alkyl chain of the fluoroketone forming a ring, which is optionally substituted by one or more alkyl groups .
• the insulation medium comprises a fluoroketone containing exactly five or exactly six carbon atoms or mixtures thereof.
• fluoroketones containing five or six carbon atoms have the advantage of a relatively low boiling point. Thus, problems which might go along with liquefaction can be avoided, even when the apparatus is used at low temperatures .
• the fluoroketone is at least one compound selected from the group consisting of the compounds defined by the following structural formulae in which at least one hydrogen atom is substituted with a fluorine atom:
• Fluoroketones containing five or more carbon atoms are further advantageous, because they are generally non-toxic with outstanding margins for human safety. This is in contrast to fluoroketones having less than four carbon atoms, such as hexafluoroacetone (or hexafluoropropanone) , which are toxic and very reactive.
• fluoroketones containing exactly five carbon atoms herein briefly named fluoroketones a)
• fluoroketones containing exactly six carbon atoms are thermally stable up to 500 °C.
• the fluoroketones in particular fluoroketones a) , having a branched alkyl chain are preferred, because their boiling points are lower than the boiling points of the corresponding compounds (i.e. compounds with same molecular formula) having a straight alkyl chain.
• the fluoroketone a) is a perfluoro- ketone, in particular has the molecular formula C 5 F1 0 O, i.e. is fully saturated without double or triple bonds between carbon atoms.
• the fluoroketone a) may more preferably be selected from the group consisting of 1,1,1,3,4,4,4- heptafluoro-3- (trifluoromethyl) butan-2-one (also named decafluoro-2-methylbutan-3-one) , 1,1,1,3,3,4,4,5,5,5- decafluoropentan-2-one, 1,1,1,2,2,4,4,5,5, 5-decafluoropentan- 3-one and octafluorocylcopentanone, and most preferably is 1, 1, 1,3,4, 4, 4-heptafluoro-3- (trifluoromethyl) butan-2-one .
• C5-ketone 1,1,1,3,4,4, 4-heptafluoro-3- (trifluoromethyl ) butan-2-one, here briefly called "C5-ketone", with molecular formula CF 3 C (0) CF (CF 3 ) 2 or C5F10O, has been found to be particularly preferred for high and medium voltage insulation applica- tions, because it has the advantages of high dielectric insulation performance, in particular in mixtures with a dielectric carrier gas, has very low GWP and has a low boiling point. It has an ODP of 0 and is practically non-toxic.
• a fluoroketone containing exactly five carbon atoms, as described above and here briefly called fluoroketone a) , and a fluoroketone containing exactly six carbon atoms or exactly seven carbon atoms, here briefly named fluoroketone c) can favourably be part of the dielectric insulation at the same time.
• an insulation medium can be achieved having more than one fluoroketone, each contributing by itself to the dielectric strength of the insulation medium.
• the further fluoroketone c) is at least one compound selected from the group consisting of the compounds defined by the following structural formulae in which at least one hydrogen atom is substituted with a fluorine atom:
• any fluoroketone having exactly 6 carbon atoms in which the at least partially fluorinated alkyl chain of the fluoroketone forms a ring, which is substituted by one or more alkyl groups (Ilh) ; and/or is at least one compound selected from the group consisting of the compounds defined by the following structural formulae in which at least one hydrogen atom is substituted with a fluorine atom:
• the present invention encompasses, in particular, each combination of any of the compounds according to structural formulae (la) to (Id) with any of the compounds according to structural formulae (Ila) to (Ilg) and/or (Ilia) to (Illn) .
• the present invention encompasses each compound or each combination of compounds selected from the group consisting of the compounds according to structural formulae (la) to (Ii), (Ila) to (Ilh), (Ilia) to (IIIo), and mixtures thereof.
• the present invention relates to a dielectric insulation medium comprising a fluoroketone having exactly 6 carbon atoms, in which the at least partially fluorinated alkyl chain of the fluoroketone forms a ring, optionally substituted by one or more alkyl groups.
• dielectric insulation medium can comprise a background gas, in particular selected from the group consisting of: air, air component, nitrogen, oxygen, carbon dioxide, a nitrogen oxide (in particular - i.e. including but not limited to - NO2, NO, N2O) , and mixtures thereof.
• an electrical apparatus comprising such a dielectric insulation medium is disclosed.
• the present invention relates to a dielectric insulation medium comprising a fluoroketone having exactly 7 carbon atoms, in which the at least partially fluorinated alkyl chain of the fluoroketone forms a ring, optionally substituted by one or more alkyl groups.
• dielectric insulation medium can comprise a background gas, in particular selected from the group consisting of: air, air component, nitrogen, oxygen, carbon dioxide, a nitrogen oxide (including but not limited to NO2, NO, N2O) , and mixtures thereof.
• an electrical apparatus comprising such a dielectric insulation medium is disclosed.
• the present invention encompasses any dielectric insulation medium comprising each compound or each combination of compounds selected from the group consisting of the compounds according to structural formulae (la) to (Ii), (Ila) to (Ilg) or to (Ilh), (Ilia) to (Illn) or to (IIIo) , and mixtures thereof, and with the dielectric insulation medium further comprising a background gas, in particular selected from the group consisting of: air, air component, nitrogen, oxygen, carbon dioxide, a nitrogen oxide (including but not limited to NO2, NO, N2O) , and mixtures thereof.
• a background gas in particular selected from the group consisting of: air, air component, nitrogen, oxygen, carbon dioxide, a nitrogen oxide (including but not limited to NO2, NO, N2O) , and mixtures thereof.
• an electrical apparatus comprising such a dielectric insulation medium is disclosed.
• fluoroketone c) a fluoroketone containing exactly six carbon atoms (falling under the designation “fluoroketone c) " mentioned above) may be preferred; such a fluoroketone is non-toxic, with outstanding margins for human safety.
• fluoroketone c) alike fluoroketone a) , is a perfluoroketone, and/or has a branched alkyl chain, in particular an at least partially fluorinated alkyl chain, and/or the fluoroketone c) contains fully saturated compounds.
• the fluoroketone c) has the molecular formula C6F12O, i.e.
• the fluoroketone c) can be selected from the group consisting of 1,1,1,2,4,4,5,5, 5-nonafluoro-2- (trifluoromethyl ) pentan-3- one (also named dodecafluoro-2-methylpentan-3-one ) ,
• 1,1,1,3,4,4,5,5, 5-nonafluoro-3- (trifluoromethyl) pentan-2-one also named dodecafluoro-3-methylpentan-2-one ) , 1,1,1,4,4,4- hexafluoro-3 , 3-bis- (trifluoromethyl) butan-2-one (also named dodecafluoro-3 , 3- (dimethyl) butan-2-one) , dodecafluorohexan-2- one, dodecafluorohexan-3-one and decafluorocyclohexanone, and particularly is the mentioned 1 , 1 , 1 , 2 , 4 , 4 , 5 , 5, 5-nonafluoro-2- (trifluoromethyl ) pentan-3-one .
• 1,1,1,2,4,4,5,5, 5-Nonafluoro-2- (trifluoromethyl ) pentan-3-one can be represented by the
• the organofluorine compound can also be a fluoroolefin, in particular a hydrofluoroolefin . More particularly, the fluoroolefin or hydrofluorolefin, respectively, contains exactly three carbon atoms.
• the hydrofluoroolefin is thus selected from the group consisting of: 1,1,1,2- tetrafluoropropene (HFO-1234yf) , 1 , 2 , 3 , 3-tetrafluoro-2- propene (HFO-1234yc) , 1, 1, 3, 3-tetrafluoro-2-propene (HFO- 1234zc), 1, 1, 1, 1, 3-tetrafluoro-2-propene (HFO-1234ze) , 1,1,2,3- tetrafluoro-2-propene (HFO-1234ye) , 1 , 1 , 1 , 2 , 3-pentafluoropropene (HFO-1225ye) , 1 , 1 , 2 , 3 , 3-pentafluoropropene (HFO- 1225yc) , 1, 1, 1, 3, 3-pentafluoropropene (HFO-1225zc) ,
• the organofluorine compound can also be a fluoronitrile, in particular a perfluoronitrile .
• the organofluorine compound can be a fluoronitrile, specifically a perfluoronitrile, containing two carbon atoms, three carbon atoms or four carbon atoms.
• the fluoronitrile can be a perfluoroalkylnitrile, specifically perfluoroacetonitrile, perfluoropropionitrile (C2F5CN) and/or perfluorobutyronitrile (C3F-7CN) .
• the fluoronitrile can be perfluoro- isobutyronitrile (according to the formula (CF3)2CFC ) and/or perfluoro-2-methoxypropanenitrile (according to the formula CF 3 CF (OCF3) CN) .
• perfluoroisobutyronitrile is particularly preferred due to its low toxicity.
• the housing preferably encloses the insulation space in a gas-tight manner.
• the amount of adsorber m a ds arranged in the at least one insulation space compartment, in particular in each insulation space compartment complies with the following formula (Ii) :
• K ads,H2-.0 ⁇ ads.dPi with rridpi being the amount of a respective decomposition product dpi, dp2,... dp n present in the insulation medium, with i being an index for the i-th decomposition product, and kads,dpi being the adsorption capability of the adsorber towards the respective i-th decomposition product dpi, dp2, ... dp n at the predetermined temperature To (or first predetermined temperature Ti in embodiments mentioning first and second predetermined temperatures Ti, T2 instead of To) .
• At least one decomposition product is taken into account as further contaminant, in addition to the water present in the insulation space compartment.
• the at least one decomposition product is a decomposition product of the organofluorine compound optionally contained in the insulation medium, and more specifically the decomposition product of a fluoroketone .
• mdpi relates to the amount of the respective i-th decomposition product created in and/or released into the respective insulation space compartment, e.g. between gas maintenance or gas replacement intervals.
• the electrical apparatus is a high voltage or medium voltage apparatus.
• the electrical apparatus is a part of or is a: high voltage apparatus, medium voltage apparatus, low voltage apparatus, direct-current apparatus, switchgear, air- insulated switchgear, part or component of air-insulated switchgear, gas-insulated metal-encapsulated switchgear (GIS) , part or component of gas-insulated metal-encapsulated switchgear, air-insulated transmission line, gas-insulated transmission line (GIL) , bus bar, bushing, air-insulated insulator, gas-insulated metal-encapsulated insulator, cable, gas-insulated cable, cable joint, current transformer, voltage transformer, sensors, surge arrester, capacitor, inductance, resistor, current limiter, high voltage switch, earthing switch, disconnector, load-break switch, circuit breaker, gas circuit breaker, vacuum circuit breaker, generator circuit breaker, medium voltage switch, ring main unit, recloser, sectionalizer, low voltage switch, transformer, distribution transformer, power transformer, tap changer, transformer bushing, electrical rotating machine, generator, motor, drive, semiconducting device,
• the present invention independently also relates to an electrical apparatus for the generation, transmission, distribution and/or usage of electrical energy
• said electrical apparatus comprising a housing enclosing an electrical apparatus interior space, at least a portion of said electrical apparatus interior space forming at least one insulation space, in which an electrical component is arranged and which contains an insulation medium surrounding said electrical component, the insulation medium comprising carbon dioxide, the insulation space comprising, in particular being formed by, at least one insulation space compartment, in which an adsorber for reducing or eliminating an amount of water and optionally further contaminants from the insulation medium is arranged, wherein the at least one insulation space compartment comprises a volume-specific amount of less than 5 kg adsorber per cubic meter, preferably less than 1.25 kg adsorber per cubic meter, more preferably less than 0.25 kg adsorber per cubic meter, and most preferably less than 0.125 kg adsorber per cubic meter of the volume of the insulation space compartment .
• the at least one insulation space compartment comprises a volume-specific amount of less than 2 kg adsorber per cubic meter, preferably less than 0.5 kg adsorber per cubic meter, more preferably less than 0.1 kg adsorber per cubic meter, and most preferably less than 0.05 kg adsorber per cubic meter of the volume of the insulation space compartment, thus keeping the influence of the adsorber on the insulation performance of the insulation medium to a minimum.
• the present invention also relates to a method for determining an optimum amount of an adsorber for the adsorption of water and optionally further contaminants in an electrical apparatus for the generation, transmission, distribution and/or usage of electrical energy
• said electrical apparatus comprising a housing enclosing an electrical apparatus interior space, at least a portion of the electrical apparatus interior space forming at least one insulation space, in which an electrical component is arranged and which contains an insulation medium surrounding the electrical component, the insulation medium comprising carbon dioxide, the insulation space comprising at least one insulation space compartment, the method comprising the steps or method elements of a) determining for at least one insulation space compartment the amount of water m H 2o present in the insulation space compartment; b) determining for the at least one insulation space compartment the amount of carbon dioxide mco2 present in the insulation space compartment; c) determining for the at least one insulation space compartment the lower limit of the amount of adsorber m a ds by formula (I)
• m H 2o relates to the amount of water present in the insulation space compartment at the time of or immediately before placing the adsorber into the insulation space compartment and k a ds,co2 relates to the adsorption capability of the adsorber towards carbon dioxide at the predetermined temperature To at the time of or immediately before placing the adsorber into the insulation space compartment.
• the amount of adsorber m a ds is such that when introducing it into the insulation space compartment, the insulation medium undergoes a change in the partial pressure of CO2 of less than 15%, preferably less than 10%, more preferably less than 5%, and most preferably less than 2%.
• the change in the density of CO2 is according to this embodiment less than 15%, preferably less than 10%, more preferably less than 5%, and most preferably less than 2%.
• the lower limit of the amount of adsorber m a ds for the at least one insulation space compartment, in particular each insulation space compartment specifically complies with the following formula (Ii) :
• the amount of water in the insulation space compartment was calculated by multiplying the amount of polymeric material contained in the insulation space compartment with the amount of water contained in the polymeric material, adding 1 g of water per square meter directly exposed to the insulation medium and further adding 1 g of water relating to an empirical value for the diffusion of water through sealings over long term operation of the apparatus of up to 30 years. Since 10 kg of polymeric material containing 2 g of water per kg is contained in the insulation space compartment (approximately at the order of a cubic meter) , the total amount of water to be adsorbed is 22 g.
• H2o of the adsorber of about 0.147, the lower limit of the amount of adsorber defined by
• K ads,H 2 0 is thus 110 g.
• the upper limit was determined according to the formula
• the upper limit of zeolite is 4.4 kg.
• the optimum amount of zeolite to be introduced in the insulation space compartment is thus between 110 g and 4.4 kg.

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• Spectroscopy & Molecular Physics (AREA)
• Solid-Sorbent Or Filter-Aiding Compositions (AREA)
• Organic Insulating Materials (AREA)
• Drying Of Gases (AREA)
• Gas-Insulated Switchgears (AREA)

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• 2014
  • 2014-11-12 KR KR1020167015397A patent/KR102242307B1/ko active Active
  • 2014-11-12 JP JP2016529943A patent/JP6625053B2/ja active Active
  • 2014-11-12 HU HUE14798807A patent/HUE035818T2/hu unknown
  • 2014-11-12 CN CN201480072978.7A patent/CN105874665B/zh active Active
  • 2014-11-12 WO PCT/EP2014/074365 patent/WO2015071303A1/en not_active Ceased
• 2016
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