WO2015063388A1 - Procede de production d'esters (meth)acryliques legers - Google Patents

Procede de production d'esters (meth)acryliques legers Download PDF

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Publication number
WO2015063388A1
WO2015063388A1 PCT/FR2014/052667 FR2014052667W WO2015063388A1 WO 2015063388 A1 WO2015063388 A1 WO 2015063388A1 FR 2014052667 W FR2014052667 W FR 2014052667W WO 2015063388 A1 WO2015063388 A1 WO 2015063388A1
Authority
WO
WIPO (PCT)
Prior art keywords
meth
alcohol
stream
reactor
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR2014/052667
Other languages
English (en)
French (fr)
Inventor
Serge Tretjak
Stephane Denis
Lionel Delais
Anne MORELIERE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to EP14814915.6A priority Critical patent/EP3063123B1/fr
Priority to JP2016527415A priority patent/JP6804296B2/ja
Priority to US15/032,864 priority patent/US9908838B2/en
Publication of WO2015063388A1 publication Critical patent/WO2015063388A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/58—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Definitions

  • Ethyl acrylate synthesis tests were carried out using a reactor having a diameter of 2.5 cm, a height of 55 cm and a volume of 270 ml.
  • the reactor is filled with 330 ml of K1431 resin (LANXESS).
  • LANXESS K1431 resin

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
PCT/FR2014/052667 2013-10-29 2014-10-21 Procede de production d'esters (meth)acryliques legers Ceased WO2015063388A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP14814915.6A EP3063123B1 (fr) 2013-10-29 2014-10-21 Procede de production d'esters (meth)acryliques legers
JP2016527415A JP6804296B2 (ja) 2013-10-29 2014-10-21 軽質（メタ）アクリル酸エステルの製造方法
US15/032,864 US9908838B2 (en) 2013-10-29 2014-10-21 Process for producing light (meth)acrylic esters

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR1360541 2013-10-29
FR1360541A FR3012447B1 (fr) 2013-10-29 2013-10-29 Procede de production d'esters (meth)acryliques legers
FR1450994 2014-02-10
FR1450994A FR3012448B1 (fr) 2013-10-29 2014-02-10 Procede de production d'esters (meth)acryliques legers

Publications (1)

Publication Number Publication Date
WO2015063388A1 true WO2015063388A1 (fr) 2015-05-07

Family

ID=50069102

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2014/052667 Ceased WO2015063388A1 (fr) 2013-10-29 2014-10-21 Procede de production d'esters (meth)acryliques legers

Country Status (5)

Country Link
US (1) US9908838B2 (enExample)
EP (1) EP3063123B1 (enExample)
JP (2) JP6804296B2 (enExample)
FR (2) FR3012447B1 (enExample)
WO (1) WO2015063388A1 (enExample)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017153653A1 (fr) 2016-03-10 2017-09-14 Arkema France Procede de production d'esters (meth)acryliques
WO2020002830A1 (fr) 2018-06-27 2020-01-02 Arkema France Procede de purification d'acrylates legers
FR3146894A1 (fr) 2023-03-24 2024-09-27 Arkema France Procede de purification d’acrylates d’alkyle legers
WO2024241004A1 (fr) 2023-05-22 2024-11-28 Arkema France Procede de purification d'acrylates legers
FR3149895A1 (fr) 2023-06-19 2024-12-20 Arkema France Procede de purification d’acrylates legers

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109678711B (zh) * 2017-10-19 2021-08-27 山东开泰石化股份有限公司 一种从丙烯酸甲酯废油中提取甲氧基丙酸甲酯的系统和方法
KR102489174B1 (ko) * 2019-07-04 2023-01-18 주식회사 엘지화학 디에스터계 조성물의 제조 시스템 및 방법

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3776947A (en) 1972-10-10 1973-12-04 Nippon Catalytic Chem Ind Continuous esterification process
US3868410A (en) * 1972-08-03 1975-02-25 Celanese Corp Conversion of oligomeric acrylates to acrylate monomers
US3914290A (en) 1969-02-06 1975-10-21 Rohm & Haas Process for esterifying acrylic acid
GB2016461A (en) 1978-02-08 1979-09-26 Kyowa Yuka Kk Method for production of an ester and its recovery from the reaction mixture
US4435594A (en) 1978-10-31 1984-03-06 Minemet Recherche Process for the preparation of methacrylic acid esters
US4664229A (en) 1985-06-28 1987-05-12 Siecor Corporation Motion dampening compensating elevator cable
US6025520A (en) 1996-08-20 2000-02-15 Mitsubishi Chemical Corporation Method for preparing (meth)acrylic acid ester
US20050107629A1 (en) 2003-11-17 2005-05-19 Hershberger Brian L. Method for producing ethyl acrylate

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54104612A (en) * 1978-02-02 1979-08-17 Japan Synthetic Rubber Co Ltd Sheet for construction
US4464229A (en) 1981-07-09 1984-08-07 Nippon Shokubai Kagaku Kogyo Co. Ltd. Process for producing acrylic or methacrylic esters
FR2727964B1 (fr) * 1994-12-12 1997-01-24 Atochem Elf Sa Procede de recuperation des produits nobles legers contenus dans les residus de distillation des procedes de fabrication de l'acide acrylique et de ses esters
JP4079480B2 (ja) * 1996-08-20 2008-04-23 三菱化学株式会社 （メタ）アクリル酸エステルの製造方法
JP4580120B2 (ja) * 2001-05-14 2010-11-10 株式会社日本触媒 不飽和カルボン酸エステルの製造方法
JP2003252825A (ja) * 2001-12-25 2003-09-10 Mitsubishi Chemicals Corp （メタ）アクリル酸類製造時の副生物の分解方法
FR2848208B1 (fr) * 2002-12-05 2005-01-14 Atofina Procede continu de preparation de lactate d'ethyle
JP4561137B2 (ja) * 2004-03-19 2010-10-13 三菱化学株式会社 （メタ）アクリル酸エステルの製造方法
FR2876375B1 (fr) * 2004-10-12 2007-02-02 Arkema Sa Procede de preparation d'esters ou d'anydrides (meth) acryliques
FR2940801B1 (fr) * 2009-01-06 2012-08-17 Arkema France Procede de fabrication d'un methacrylate de methyle derive de la biomasse
CA2918525C (en) * 2013-07-15 2019-10-15 Hills Inc. Spun-laid webs with at least one of lofty, elastic and high strength characteristics

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3914290A (en) 1969-02-06 1975-10-21 Rohm & Haas Process for esterifying acrylic acid
US3868410A (en) * 1972-08-03 1975-02-25 Celanese Corp Conversion of oligomeric acrylates to acrylate monomers
US3776947A (en) 1972-10-10 1973-12-04 Nippon Catalytic Chem Ind Continuous esterification process
GB2016461A (en) 1978-02-08 1979-09-26 Kyowa Yuka Kk Method for production of an ester and its recovery from the reaction mixture
US4435594A (en) 1978-10-31 1984-03-06 Minemet Recherche Process for the preparation of methacrylic acid esters
US4664229A (en) 1985-06-28 1987-05-12 Siecor Corporation Motion dampening compensating elevator cable
US6025520A (en) 1996-08-20 2000-02-15 Mitsubishi Chemical Corporation Method for preparing (meth)acrylic acid ester
US20050107629A1 (en) 2003-11-17 2005-05-19 Hershberger Brian L. Method for producing ethyl acrylate

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017153653A1 (fr) 2016-03-10 2017-09-14 Arkema France Procede de production d'esters (meth)acryliques
WO2020002830A1 (fr) 2018-06-27 2020-01-02 Arkema France Procede de purification d'acrylates legers
US11161799B2 (en) 2018-06-27 2021-11-02 Arkema France Method for purifying light acrylates
FR3146894A1 (fr) 2023-03-24 2024-09-27 Arkema France Procede de purification d’acrylates d’alkyle legers
WO2024200950A1 (fr) 2023-03-24 2024-10-03 Arkema France Procede de purification d'acrylates d'alkyle legers
WO2024241004A1 (fr) 2023-05-22 2024-11-28 Arkema France Procede de purification d'acrylates legers
FR3149008A1 (fr) 2023-05-22 2024-11-29 Arkema France Procede de purification d’acrylates legers
FR3149895A1 (fr) 2023-06-19 2024-12-20 Arkema France Procede de purification d’acrylates legers
WO2024261414A1 (fr) 2023-06-19 2024-12-26 Arkema France Procede de purification d'acrylates legers

Also Published As

Publication number Publication date
US9908838B2 (en) 2018-03-06
JP6804296B2 (ja) 2020-12-23
FR3012448B1 (fr) 2019-08-30
FR3012448A1 (fr) 2015-05-01
JP2019163294A (ja) 2019-09-26
EP3063123A1 (fr) 2016-09-07
FR3012447B1 (fr) 2017-01-20
EP3063123B1 (fr) 2018-05-30
US20160272570A1 (en) 2016-09-22
FR3012447A1 (fr) 2015-05-01
JP2016539104A (ja) 2016-12-15

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