Classifications

• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
  • H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
  • H01J37/30—Electron-beam or ion-beam tubes for localised treatment of objects
  • H01J37/317—Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation
  • H01J37/3171—Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation for ion implantation
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
  • H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
  • H01J37/02—Details
  • H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
  • H01J37/08—Ion sources; Ion guns
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
  • H01J37/00—Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
  • H01J37/02—Details
  • H01J37/04—Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement or ion-optical arrangement
  • H01J37/10—Lenses
  • H01J37/12—Lenses electrostatic
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
  • H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
  • H01J2237/02—Details
  • H01J2237/022—Avoiding or removing foreign or contaminating particles, debris or deposits on sample or tube
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
  • H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
  • H01J2237/06—Sources
  • H01J2237/061—Construction
• • H—ELECTRICITY
  • H01—ELECTRIC ELEMENTS
  • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
  • H01J2237/00—Discharge tubes exposing object to beam, e.g. for analysis treatment, etching, imaging
  • H01J2237/06—Sources
  • H01J2237/083—Beam forming

Definitions

• FIELD This invention relates to ion implantation and, more particularly, to reducing contaminants generated in an ion implanter .
• Ion implantation is a standard technique for introducing conductivity-altering impurities into a workpiece.
• a desired impurity material is ionized in an ion source, the ions are accelerated to form an ion beam of prescribed energy, and the ion beam is directed at the surface of the workpiece.
• the energetic ions in the ion beam penetrate into the bulk of the workpiece material and are embedded into the crystalline lattice of the workpiece material to form a region of desired conductivity.
• Ion implantation has been demonstrated as a viable method to dope solar cells.
• Use of ion implantation removes process steps needed for existing technology, such as diffusion furnaces. For example, a laser edge isolation step may be removed if ion implantation is used instead of furnace diffusion because ion implantation will only dope the desired surface. Besides removal of process steps, higher cell efficiencies have been demonstrated using ion implantation.
• Ion implantation also offers the ability to perform a blanket implant of an entire surface of a solar cell or a selective (or patterned) implant of only part of the solar cell. Selective implantation at high throughputs using ion implantation avoids the costly and time-consuming lithography or patterning steps used for furnace diffusion. Selective implantation also enables new solar cell designs.
• One issue associated with ion implantation may be the introduction of undesirable contaminants. These contaminants may decrease the efficiency or operation of the solar cell. Therefore, any technique or system that reduces the generation of these contaminants may be advantageous. This may accelerate the adoption of solar cells as an alternative energy source.
• An ion implanter has a coating of low resistivity silicon carbide on one or more of the conductive surfaces that are exposed to ions. For example, ions are generated in an ion source chamber, and the interior surfaces of the walls are coated with low resistivity silicon carbide. Since silicon carbide is hard and resistant to sputtering, this may reduce the amount of contaminant ions that are introduced into the ion beam that is extracted from the ion source chamber. In some embodiments, the extraction electrodes are also coated with silicon carbide to reduce the contaminant ions introduced by these components.
• an ion implanter comprising an ion source comprising an ion source chamber having a first wall, an opposite conductive second wall and a plurality of conductive side walls, where an extraction aperture is disposed in the second wall; and an extraction electrode assembly disposed proximate the extraction aperture and outside the ion source chamber, the extraction electrode assembly comprising one or more conductive electrodes; wherein at least one conductive component is coated with low resistivity silicon carbide.
• an ion implanter comprising an ion source comprising an ion source chamber having a first wall, an opposite conductive second wall and a plurality of conductive side walls, where an extraction aperture is disposed in the second wall; a plurality of conductive liners, each disposed against and in electrically communication with a respective interior surface of the conductive side walls; and an extraction electrode assembly disposed proximate the extraction aperture and outside the ion source chamber, the extraction electrode assembly comprising one or more conductive electrodes; wherein at least one of the conductive liners, an interior surface of the second wall and the extraction electrode assembly is coated with low resistivity silicon carbide.
• an ion implanter comprises an ion source comprising an ion source chamber having a first wall, an opposite conductive second wall and a plurality of conductive side walls, where an extraction aperture is disposed in the second wall; a plurality of conductive graphite liners, each disposed against and in electrically communication with a respective interior surface of the conductive side walls, each of the liners comprising a first surface facing an interior of the ion source chamber and an opposite second surface facing a respective sidewall, wherein the first surface is coated with low resistivity silicon carbide; and an extraction electrode assembly disposed proximate the extraction aperture and outside the ion source chamber, the extraction electrode assembly comprising one or more conductive electrodes, each having a respective aperture, wherein a portion of each electrode surrounding the respective aperture is coated with low resistivity silicon carbide; wherein the low resistivity silicon carbide has a resistivity of less than 1 ohm-cm.
• FIG. 1 is an ion implanter in accordance with a first embodiment .
• FIG. 1 shows a cross section of a representative ion implanter, which may be used to introduce dopant ions into a workpiece 150, such as a solar cell. These dopant ions are used to form the emitter region and p-n junction needed in a solar cell.
• the ion implanter 100 includes an ion source 110.
• the ion source 110 may comprise a first wall 111, and an opposite second wall 112.
• the first wall 111 and the second wall 112 may be joined together by a plurality of side walls 113, 114. Since the ion implanter is shown in cross section, only two side walls 113, 114 are shown. However, any number of side walls, such as four or more, may also be employed.
• These side walls 113, 114 are mechanically and electrically coupled to the second wall 112.
• These side walls 113, 114 are also mechanically coupled to the first wall 111.
• the interior surfaces of these sides 111-114 define an ion source chamber 115.
• the ion source 110 is illustrated as a box, having size planar walls, other configurations are also possible.
• the ion source 110 has a plasma generator
• the plasma generator is disposed proximate the first wall 111, on the outside of the ion source chamber 115.
• the first wall 111 may be constructed of a dielectric material, such as silicon oxide.
• the second wall 112 and the side walls 113, 114 may be constructed of a conductive material, such as a metal or graphite, such that a common bias voltage may be applied to these walls.
• the ion source chamber 115 may be made up of a first wall 111, an opposite conductive second wall 112, and conductive side walls 113, 114.
• a source gas is fed into the ion source 110.
• the plasma generator creates a plasma and creates ions of this source gas.
• An extraction aperture 117 may be disposed on the second wall 112, such that the ions generated within the ion source chamber 115 may be extracted through this extraction aperture 117.
• an extraction electrode assembly 130 Disposed outside the ion source chamber 115, proximate the extraction aperture 117, is an extraction electrode assembly 130, comprising one or more electrodes.
• an extraction electrode 130a and a suppression electrode 130b may be arranged proximate the extraction aperture 117.
• the extraction electrode assembly 130 may comprise any number of electrodes and is not limited to this embodiment.
• the electrodes that make up the extraction electrode assembly 130 may be conductive and are typically constructed from graphite.
• a negative bias voltage is applied to the extraction electrode 130a, which attracts positive ions from the ion source chamber 115.
• a different bias voltage is typically applied to the suppression electrode 130b.
• the extraction electrode 130a and the suppression electrode 130b each have a respective electrode aperture 131a, 131b disposed therein.
• the extraction electrode aperture 131a and the suppression electrode aperture 131b are each aligned with the extraction aperture 117, such that ions are attracted toward the extraction electrode assembly 130. These attracted ions then pass through the electrode apertures 131a, b disposed in the electrodes 130a, b. These ions form an ion beam 140 that impacts the workpiece 150.
• the ions that exit the ion source chamber 115 and form the ion beam 140 may be common not to mass analyze the ions that exit the ion source chamber 115 and form the ion beam 140.
• contaminants from the extraction electrode assembly 130 may also be contained in the ion beam 140.
• one or more interior surfaces of the ion source chamber 115 may be lined so as to reduce or eliminate the exposure of those interior surfaces to the plasma. These liners 120 may reduce the contaminants that are created by material sputtering from these interior surfaces.
• the energetic ions within the ion source chamber 115 may impact these interior surfaces and cause contaminants to become detached from these surfaces.
• the second wall 112 and the side walls 113, 114 of the ion source 110 may be made of a conductive material. Therefore, the liners 120 used to cover the interior surfaces of these walls may also be conductive. These liners 120 are disposed against and are in electrical communication with the interior surfaces of these walls, such as side walls 113, 114. In some embodiments, these liners 120 are constructed from graphite, which has a resistivity of about .001 ohm-cm. These liners 120 may be disposed against all of the interior surfaces of side walls 113, 114. In addition, a liner 120 may be disposed on a portion of the interior surface of second wall 112. If a liner 120 is disposed on the second wall 112, the liner 120 does not cover extraction aperture 117.
• contaminant ions may still impact the workpiece 150.
• these contaminant ions may comprise carbon. These carbon ions may be caused by the graphite liners 120, or the electrodes 130a, 130b.
• silicon carbide has a resistivity of about 100 ohm-cm. In comparison, as stated above, the resistivity of graphite is about .001 ohm-cm. Therefore, traditional silicon carbide cannot be used in applications which require a conductive surface, such as the second wall 112 and side walls 113, 114 in the ion source chamber 115 and the electrodes in the extraction electrode assembly 130.
• this resistivity may be between .01 and 1 ohm-cm.
• this low resistivity silicon carbide may be used in some of the applications described herein.
• the graphite liners 120 may be coated with low resistivity silicon carbide.
• the low resistivity silicon carbide is applied to the graphite liners 120 using a chemical vapor deposition (CVD) process.
• the liner 120 has a first surface which faces the interior of the ion source chamber 115, and an opposite second side, which faces the side wall 113,114.
• the low resistivity silicon carbide may be applied to both surfaces of the liner 120.
• the low resistivity silicon carbide is only applied to the first surface of the liner 120 that faces the interior of the ion source chamber 115.
• the liners 120 are installed against the interior surface of side walls 113, 114 of the ion source chamber 115. Since the low resistivity silicon carbide has relatively good conductivity, the bias voltage can still be applied to these liners 120.
• the interior surface of second wall 112 of the ion source chamber 115 is also coated with the low resistivity silicon carbide.
• the second wall 112 may be coated with the low resistivity silicon carbide using CVD.
• both surfaces of the second wall 112 i.e. the interior surface which faces the ion source chamber 115 and the exterior surface
• the low resistivity silicon carbide is not applied to the outer border of the inner surface of the second wall 112. For example, an uncoated border of about 1 inch may be disposed about the interior surface of the second wall 112.
• the side walls 113, 114 are in direct contact with the second wall 112, without an intervening layer of silicon carbide. This may help improve the electrical connection between the second wall 112 and the side walls 113, 114.
• the side walls 113, 114 may extend beyond the second wall 112, such that a portion of the interior surface of the side walls 113, 114 mates with the end of the second surface 112 In this embodiment, the portion of the interior surface of the side walls 113, 114 may not be coated or lined.
• silicon carbide is not disposed in the regions where the second wall 112 and the side walls 113, 114 are attached.
• the exterior surface of the second wall 112 i.e. the side outside of ion source chamber 115
• the contaminants that originate from within the ion source chamber 115 may be reduced by the application of a low resistivity silicon carbide coating on one or more of the interior surfaces of the walls that make up the ion source chamber 115.
• a low resistivity silicon carbide coating on one or more of the interior surfaces of the walls that make up the ion source chamber 115.
• only the liners 120 are coated with low resistivity silicon carbide.
• only the interior side of the second wall 112 is coated.
• all interior surfaces, except the first wall are coated with low resistivity silicon carbide.
• liners 120 are not used in the ion source chamber 115. Instead, the low resistivity silicon carbide is applied directly to the interior surfaces of side walls 113, 114. However, in both embodiments, the surfaces that ultimately face the interior of the ion source chamber 115 (which may be either the first surface of the liners 120 or the interior surface of the walls 113,114) are coated with low resistivity silicon carbide. In some cases, these surfaces may be the liners 120. In other cases, these surfaces may be the interior surfaces of the side walls 113, 114.
• the extraction electrode 130a and the suppression electrode 130b may be coated with low resistivity silicon carbide.
• both surfaces of the electrodes 130a, 130b are coated using a CVD process.
• only the surface of each electrode 130a, 130b that faces the ion beam 140 is coated.
• a portion of both surfaces of the electrodes 130a, 130b is coated, however, this coating is limited to the region surrounding the electrode apertures 131a, 131b.
• FIG. 1 shows an electrode assembly 130 to direct the ion beam 140, other focusing elements may also be employed. These focusing elements may include electrodes or other structures. Although not shown, one or more surfaces of these focusing elements may be coated with low resistivity silicon carbide to reduce the amount of contaminants that strikes the workpiece 150.
• Silicon carbide is described as it is known for its hardness and resistance to etching or sputtering. However, the disclosure is not limited to this material. For example, other hard materials which may be modified so as to have a resistivity of 1 ohm-cm or less can be employed in order to perform in these applications. Thus, a higher purity ion beam may be produced by coating one or more conductive surfaces in the ion implanter using low resistivity silicon carbide. This low resistivity silicon carbide may be more resistant to sputtering, thereby producing fewer contaminant ions than the underlying surfaces would otherwise produce. In system without mass analysis, this reduction in contaminant ions may be highly beneficial.

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• Analytical Chemistry (AREA)
• Electron Sources, Ion Sources (AREA)
• Physical Vapour Deposition (AREA)

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• 2013
  • 2013-09-27 US US14/039,654 patent/US9384937B2/en active Active
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