WO2014199936A1 - 毛髪処理剤組成物 - Google Patents

毛髪処理剤組成物 Download PDF

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Publication number
WO2014199936A1
WO2014199936A1 PCT/JP2014/065189 JP2014065189W WO2014199936A1 WO 2014199936 A1 WO2014199936 A1 WO 2014199936A1 JP 2014065189 W JP2014065189 W JP 2014065189W WO 2014199936 A1 WO2014199936 A1 WO 2014199936A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
amodimethicone
treatment composition
hair treatment
treatment
Prior art date
Application number
PCT/JP2014/065189
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
堅 林
賢二 野田
Original Assignee
株式会社 資生堂
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社 資生堂 filed Critical 株式会社 資生堂
Priority to KR1020157024482A priority Critical patent/KR102241232B1/ko
Priority to JP2015522762A priority patent/JP6685726B2/ja
Priority to CN201480032744.XA priority patent/CN105377231B/zh
Publication of WO2014199936A1 publication Critical patent/WO2014199936A1/ja
Priority to HK16103710.5A priority patent/HK1215684A1/zh

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/068—Microemulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the present invention relates to a hair treatment composition. More specifically, the present invention relates to a hair treatment composition that can efficiently remove calcium ions accumulated in hair.
  • Hair is damaged by chemical treatments such as ultraviolet rays and other stimuli from the natural environment, permanent wave treatment, coloring treatment, and decolorization treatment, resulting in “squeaking” and “pasty”. Furthermore, it is said that the metal ions are adsorbed on the hair that has been hydrophilized due to damage, resulting in a loss of smoothness and a stiff feeling. That is, even if shampooing or treatment treatment is performed for the purpose of caring for damaged hair, there is a problem that “stiffness” is promoted by the influence of metal ions contained in the water that is washed away.
  • Patent Document 1 includes a chelating agent that selectively chelates copper ions, such as diamine-N, N′-dipolyacid or monoamine monoamide-N, N′-dipolyacid, focusing on copper ions among metal ions.
  • the described hair treatment is described as being useful in reducing damage.
  • Patent Document 2 discloses a hair cosmetic that removes alkaline earth metals such as calcium from damaged hair, improves the softness of the hair, improves pain in the hair, and gives a smooth feel.
  • the cosmetic is characterized by containing an ⁇ -hydroxy acid compound and a gallic acid compound and having a pH of 2 to 4.
  • the ⁇ -hydroxy acid compound is blended as a calcium chelating agent (for example, paragraph 0019) and treated with a hair cosmetic blended with a specific oil agent and a nitrogen-containing modified silicone. It is described that the strength of hair can be increased and the surface can be hydrophobized to reduce the frictional resistance of the hair.
  • Patent Documents 1 and 2 copper ions and calcium ions accumulated on the surface or inside of the hair are removed using a chelating agent, but there is a treatment effect that imparts smoothness to the hair. I can't get it.
  • Patent Document 3 a specific oil agent and nitrogen-containing modified silicone are co-blended to give strength and smoothness to hair, but a chelating agent ( ⁇ -hydroxy acid) is essential to remove calcium ions. It is.
  • the present invention is a hair treatment composition that can effectively remove polyvalent metal ions such as calcium ions without containing a chelating agent, and also exhibits a treatment effect on hair.
  • the purpose is to provide.
  • the present inventors have conducted intensive research. As a result, by treating with a composition containing a micro emulsion of amodimethicone, calcium ions can be effectively removed without adding a chelating agent. As a result, the present invention has been completed.
  • the present invention provides a hair treatment composition for removing calcium from hair, which includes a micro emulsion of amodimethicone.
  • the hair treatment composition of the present invention can effectively remove polyvalent metal ions such as calcium ions accumulated in damaged hair without containing a chelating agent, and also exhibits a treatment effect on hair. .
  • the hair treated with the hair treatment composition of the present invention maintains the hydrophobic surface of the hair even after shampooing treatment, and maintains a smooth and soft feel.
  • the hair treatment composition of the present invention is characterized by containing a microemulsion of amodimethicone.
  • the microemulsion of amodimethicone in the present specification is an oil-in-water emulsion in which amodimethicone is dispersed in an aqueous medium, and has an average emulsion particle size of about 1 to about 50 nm.
  • a compound in which R 1 is all a methyl group, a is 3 in the R 2 group, and b is 2 is particularly preferable.
  • the micro emulsion of amodimethicone in the present invention is a micro emulsion having the above-mentioned amodimethicone as a dispersed phase and an aqueous medium as a continuous phase.
  • the microemulsion may contain components such as an ionic (anionic, cationic or amphoteric) or nonionic surfactant, an emulsion stabilizer such as a polyhydric alcohol such as glycerin or a thickener, and a pH adjuster. Good.
  • the amount of amodimethicone contained in the microemulsion is not particularly limited as long as a stable microemulsion is formed. For example, 1 to 30% by mass, preferably 5 to 25% by mass, more preferably It is about 10 to 20% by mass.
  • BY22-079 manufactured by Toray Dow Corning Co., Ltd.
  • BY22-079 is an oil-in-water micro-container containing 14% by weight amodimethicone and 9.4% by weight nonionic surfactant (polyoxyethylene branched alkyl (C12-14) ether). It is an emulsion and can be particularly preferably used in the present invention.
  • the hair treatment composition of the present invention can effectively remove calcium ions from hair as long as it contains the amodimethicone microemulsion.
  • the blending amount of the amodimethicone microemulsion in the hair treatment composition is not particularly limited. However, the actual amount of amodimethicone is usually 0.01 to 5% by mass, preferably based on the whole composition. Is about 0.05 to 3% by mass, more preferably about 0.1 to 2% by mass. If the amount of amodimethicone is less than 0.01% by mass, the calcium ion removal effect may not be sufficiently obtained within a practical time. If it exceeds 5% by mass, the hair feels heavy and May cause stickiness.
  • the hair treatment composition of the present invention can be blended with other optional components as long as the effects of the present invention are not impaired.
  • the optional components that can be blended are not particularly limited, but include, for example, oils such as higher alcohols, hydrocarbon oils, ester oils, silicone oils, humectants, ionic polymers, nonionic polymers, ionic Surfactants, nonionic surfactants, pH adjusters, preservatives, colorants and the like can be mentioned.
  • the hair treatment composition of the present invention does not contain a chelating agent as described in Patent Documents 1 to 3 because amodimethicone in the form of a microemulsion alone exhibits the effect of removing calcium ions from hair. It does not have to be.
  • the ⁇ -hydroxy acid used as a chelating agent in Patent Documents 2 and 3 contains a pH adjuster widely used in cosmetics such as citric acid. Therefore, the composition of the present invention may contain an ⁇ -hydroxy acid such as citric acid as a pH adjuster.
  • the pH of the composition of the present invention is preferably weakly acidic or neutral to weakly alkaline, and is 4 to 8, preferably 6 to 8 in terms of pH value.
  • the hair treatment composition of the present invention can efficiently remove calcium ions accumulated in hair damaged by permanent wave treatment or coloring treatment. Therefore, the hair treatment composition of the present invention is preferably provided in the form of a conditioner or treatment applied to hair damaged by the chemical treatment as described above.
  • the hair treatment composition of the present invention is particularly suitable for use in a beauty salon, a beauty salon, a hair salon, or the like that is subjected to chemical treatment such as permanent wave treatment. That is, the present invention relates to a hair treatment method for removing calcium from hair, which comprises applying a hair treatment composition containing amodimethicone to shampooed and towel-dried hair in a salon or the like and leaving it for a predetermined time. Also provide. After leaving, the hair treatment composition may or may not be washed away.
  • the time for leaving the hair to which the hair treatment composition is applied is at least 30 minutes, preferably about 1 hour.
  • the heating temperature is at least 50 ° C., preferably 60 ° C. or higher.
  • the standing time is shortened to about 1/3.
  • Example 1 A hair treatment composition comprising an oil-in-water microemulsion containing 0.1% by mass of amodimethicone (actual part) was prepared, and the composition was applied to hair that was shampooed by decolorization and permanent wave treatment. After a predetermined time, the calcium concentration contained in the hair was measured. Specifically, the hair was treated with 50% hydrochloric acid at 90 ° C. for 1 hour to extract calcium, and the calcium concentration was measured by ICP emission analysis (Simultaneous Mode).
  • the graph of FIG. 1 shows the change in calcium concentration in the hair before and after applying the hair treatment composition of the present invention.
  • the calcium in the hair was removed by applying the hair treatment composition of the present invention.
  • the calcium reduction effect rate was accelerated three times.
  • Example 2 Samples having the composition shown in Table 1 below (the balance being water) were prepared. Each sample was applied to a bundle of hair that had been damaged and deteriorated by decolorization and permanent treatment, and the feel after drying with a dryer was evaluated. The evaluation was conducted by a specialized panel and evaluated based on the following criteria. [Evaluation criteria] X (1): Bad rough feel ⁇ (2): Rough feel but improved feeling ⁇ (3): Good feeling ⁇ (4): Slightly heavy but improved feeling ⁇ (5): It is sticky and feels bad
  • Example 3 The difference of the effect by the kind of silicone or the emulsified particle diameter was confirmed.
  • microemulsions compared to emulsions and microemulsions (samples A to C) containing dimethicone as silicone and emulsions (samples D and E) containing amodimethicone, microemulsions (sample F) containing amodimethicone are:
  • the calcium removal effect from hair was remarkably excellent.
  • the contact angle of the hair surface after the treatment with each sample was measured, the surface was all hydrophobized.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
PCT/JP2014/065189 2013-06-13 2014-06-09 毛髪処理剤組成物 WO2014199936A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020157024482A KR102241232B1 (ko) 2013-06-13 2014-06-09 모발 처리제 조성물
JP2015522762A JP6685726B2 (ja) 2013-06-13 2014-06-09 毛髪処理剤組成物
CN201480032744.XA CN105377231B (zh) 2013-06-13 2014-06-09 毛发处理剂组合物
HK16103710.5A HK1215684A1 (zh) 2013-06-13 2016-03-31 毛髮處理劑組合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2013-124332 2013-06-13
JP2013124332 2013-06-13

Publications (1)

Publication Number Publication Date
WO2014199936A1 true WO2014199936A1 (ja) 2014-12-18

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2014/065189 WO2014199936A1 (ja) 2013-06-13 2014-06-09 毛髪処理剤組成物

Country Status (5)

Country Link
JP (2) JP6685726B2 (zh)
KR (1) KR102241232B1 (zh)
CN (1) CN105377231B (zh)
HK (1) HK1215684A1 (zh)
WO (1) WO2014199936A1 (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10881596B2 (en) * 2016-12-05 2021-01-05 Kao Germany Gmbh Cosmetic composition for enhancing properties of pre-colored keratin fibers
US11141367B2 (en) * 2016-10-19 2021-10-12 Kao Germany Gmbh Cosmetic composition comprising two optical brighteners, method, use, and kit-of-parts thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020090951A1 (ja) * 2018-11-02 2020-05-07 株式会社 資生堂 毛髪処理方法
CN115317407B (zh) * 2022-09-13 2023-08-22 广州品尚生物科技发展有限公司 一种液态护发素及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008297246A (ja) * 2007-05-31 2008-12-11 Lion Corp 化粧料組成物及び化粧料組成物の保存安定化方法
JP2009078992A (ja) * 2007-09-25 2009-04-16 Shiseido Co Ltd 毛髪化粧料
JP2010150175A (ja) * 2008-12-25 2010-07-08 Milbon Co Ltd シャンプー組成物
WO2011059063A1 (ja) * 2009-11-12 2011-05-19 花王株式会社 毛髪化粧料
JP2012092040A (ja) * 2010-10-27 2012-05-17 Milbon Co Ltd 毛髪処理剤

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2437170C (en) * 2001-03-20 2009-10-27 The Procter & Gamble Company Compositions suitable for the treatment of hair comprising chelants and methods for reducing oxidative hair damage
JP2005179198A (ja) 2003-12-16 2005-07-07 Lion Corp 毛髪化粧料
JP4129645B2 (ja) * 2004-08-30 2008-08-06 ライオン株式会社 シャンプー組成物
KR20070078569A (ko) * 2006-01-27 2007-08-01 주식회사 엘지생활건강 투명 샴푸 조성물
JP5111628B2 (ja) 2011-01-28 2013-01-09 ライオン株式会社 毛髪化粧料
JP2012176996A (ja) * 2012-06-22 2012-09-13 Momentive Performance Materials Inc 毛髪化粧料組成物

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008297246A (ja) * 2007-05-31 2008-12-11 Lion Corp 化粧料組成物及び化粧料組成物の保存安定化方法
JP2009078992A (ja) * 2007-09-25 2009-04-16 Shiseido Co Ltd 毛髪化粧料
JP2010150175A (ja) * 2008-12-25 2010-07-08 Milbon Co Ltd シャンプー組成物
WO2011059063A1 (ja) * 2009-11-12 2011-05-19 花王株式会社 毛髪化粧料
JP2012092040A (ja) * 2010-10-27 2012-05-17 Milbon Co Ltd 毛髪処理剤

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11141367B2 (en) * 2016-10-19 2021-10-12 Kao Germany Gmbh Cosmetic composition comprising two optical brighteners, method, use, and kit-of-parts thereof
US10881596B2 (en) * 2016-12-05 2021-01-05 Kao Germany Gmbh Cosmetic composition for enhancing properties of pre-colored keratin fibers

Also Published As

Publication number Publication date
KR20160018453A (ko) 2016-02-17
CN105377231B (zh) 2018-06-22
JP2019069975A (ja) 2019-05-09
KR102241232B1 (ko) 2021-04-16
JP6685726B2 (ja) 2020-04-22
CN105377231A (zh) 2016-03-02
JPWO2014199936A1 (ja) 2017-02-23
HK1215684A1 (zh) 2016-09-09

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