WO2014184970A1 - 整髪剤組成物 - Google Patents
整髪剤組成物 Download PDFInfo
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- WO2014184970A1 WO2014184970A1 PCT/JP2013/076257 JP2013076257W WO2014184970A1 WO 2014184970 A1 WO2014184970 A1 WO 2014184970A1 JP 2013076257 W JP2013076257 W JP 2013076257W WO 2014184970 A1 WO2014184970 A1 WO 2014184970A1
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- hair styling
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
Definitions
- the present invention relates to a hair styling composition that is suitably used for a hair styling agent for preparing hair.
- a film-forming polymer is often used for imparting hair-styling power, which is a main function, to a hair-styling composition.
- a hairdressing composition using a film-forming polymer a film is formed on the surface of the hair after hair styling, derived from the film-forming polymer.
- the initial hair styling power immediately after hair styling is increased, while it is difficult to condition the hair in a natural state, or after hair styling, it is applied to the hair with a hand or a comb.
- the film peels off from the surface of the hair, so-called flaking occurs, and there is a problem that the appearance deteriorates.
- a method different from the method using a film-forming polymer has been studied. Specifically, it has been studied to impart hair-styling power to a hair-styling composition using a powder.
- a hair cosmetic (hairdressing composition) containing 0.1 to 10% by mass of fine particle powder having a specific surface area of 50 m 2 / g or more is known (see Patent Document 1).
- Patent Document 1 by using the specific fine particle powder at a specific content, a good feel can be obtained, an excellent hair styling power can be obtained, a good feel can be maintained for a long time, and an excellent It describes that hair styling properties can be obtained.
- An object of the present invention is to provide a hair styling composition capable of suppressing the occurrence of flaking and stickiness and improving the initial hair styling power and the hair styling holding power when hair is stipulated.
- the hairdressing composition according to the present invention includes the following component (A) and the following component (B), and the content of the component (A) is 0.1% by mass or more and 10% by mass or less.
- Agent composition Component (A): Particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide
- Component (B) Pantothenyl alcohol
- the content of the component (B) is preferably 0.1% by mass or more and 20% by mass or less.
- the hairdressing composition according to the present invention preferably further comprises the following component (C).
- component (C) Compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester
- the hairdressing composition according to the present invention preferably further contains the following component (D).
- the hairdressing composition according to the present invention preferably further contains the following component (E).
- the mass ratio of the content of the component (D) and the content of the component (E) is preferably 2: 1 to 10: 1.
- the total content of the component (D) and the component (E) is preferably 0.3% by mass or more and 5% by mass or less.
- the hairdressing composition according to the present invention preferably further contains the following component (F).
- the hair styling composition according to the present invention contains a specific component (A) and a specific component (B), and the content of the component (A) is within a specific range. Generation of king and stickiness can be suppressed, and initial hair styling power and hair styling holding power can be increased.
- the hairdressing composition according to the present invention was selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. At least particles and pantothenyl alcohol.
- the above-mentioned “particles selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide” May be referred to as “component (A)”.
- the “pantothenyl alcohol” may be referred to as “component (B)”.
- the hair styling composition according to the present invention preferably further contains a compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester.
- a compound selected from the group consisting of polyoxyalkylene alkyl glucoside and polyoxyalkylene glycerin fatty acid ester may be referred to as “component (C)”.
- component (C1) the “polyoxyalkylene alkyl glucoside”
- component (C2) the “polyoxyalkylene glycerin fatty acid ester”
- the hair styling composition according to the present invention preferably further contains a clay mineral.
- a clay mineral may be referred to as “component (D)”.
- the hair styling composition according to the present invention preferably further contains a polysaccharide compound.
- a polysaccharide compound may be referred to as “component (E)”.
- the hairdressing composition according to the present invention preferably further contains polyethylene glycol.
- polyethylene glycol may be referred to as “component (F)”.
- the hairdressing composition according to the present invention includes at least a component (A) and a component (B).
- the hairdressing composition according to the present invention preferably further comprises a component (at least one component) selected from the group consisting of component (C), component (D), component (E) and component (F).
- the component (D) and the component (E) are preferably used in combination.
- the hairdressing composition which concerns on this invention contains all of a component (A), a component (B), a component (C), a component (D), a component (E), and a component (F).
- the hairdressing composition according to the present invention may further contain other components. Only one type of each of the above components, for example, the component (A), the component (B), the component (C), the component (D), the component (E), the component (F), and the like is used. Two or more kinds may be used.
- the component (C) is a compound (at least one compound) selected from the group consisting of the component (C1) and the component (C2).
- component (C1) and component (C2) only 1 type may be used respectively and 2 or more types may be used.
- the component (A) is at least one selected from the group consisting of silica, calcium carbonate, magnesium carbonate, hydroxyapatite, titanium oxide, zinc oxide, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide. Particles.
- the said component (A) has a role which mainly suppresses stickiness and raises initial hair-setting power and hair-styling retention power. Further, by using the component (A), it is possible to facilitate hair styling again after hair styling once and to improve re-hair styling, as compared with the case where a film-forming polymer is used.
- silica, magnesium carbonate, hydroxyapatite, calcium silicate, magnesium silicate, aluminum silicate, and magnesium hydroxide are preferable, and silica, magnesium silicate, and hydroxide are preferable from the viewpoint of hair styling performance. Magnesium is more preferred.
- silica, magnesium silicate, and hydroxide are preferable from the viewpoint of hair styling performance. Magnesium is more preferred.
- the said component (A) only 1 type may be used and 2 or more types may be used.
- silica known and commonly used silica (anhydrous silicic acid) can be used.
- the silica may be silicic anhydride (hydrophilic silica) that has not been hydrophobized or may be hydrophobized silicic anhydride. Further, the silica may be silica surface-treated with amino acid, ester, lecithin or the like. The silica may be so-called easily disintegrating silica particles. As for the said silica, only 1 type may be used and 2 or more types may be used.
- the hydrophobized silicic anhydride is a substance obtained by hydrophobizing silicic anhydride (for example, untreated silicic anhydride).
- the treating agent used for the hydrophobizing treatment include organic silyl compounds and silicone compounds.
- the organic silyl compound include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyldialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyltrichlorosilane, long Examples include chain alkyltrichlorosilane, ethyltrialkoxysilane, propyltrialkoxysilane, hexyltrialkoxysilane, long chain alkyltrialkoxysilane, methacryl silane, fluoroalky
- silicone compound examples include dimethylpolysiloxane (silicone oil), methylphenylpolysiloxane, methylhydrogenpolysiloxane, and amino-modified silicone.
- the method for the hydrophobic treatment is not particularly limited, and a known method can be used. Examples of the hydrophobic treatment method include a liquid phase method, a gas phase method, and an autoclave method.
- hydrophobic silicic anhydride examples include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, silicone oil treated silicic anhydride and methacrylsiloxylated silicic anhydride. Etc.
- the above easily disintegratable silica particles are particles formed by aggregating a plurality of silica primary particles. Although it does not specifically limit as said silica primary particle, For example, a spherical silica particle, a scaly silica particle, an amorphous silica particle, etc. are mentioned.
- the average particle diameter of the silica primary particles is not particularly limited.
- the easily disintegratable silica particles may contain components other than silica.
- the component other than the silica (hereinafter may be referred to as “encapsulated component”) is not particularly limited, and examples thereof include surfactants, polyhydric alcohols, higher alcohols, sugar alcohols, silicone oils, sequestering agents, Examples include antioxidants, plant extracts, dyes, pigments, fragrances, moisturizers, vitamins, amino acids, and refreshing agents. Of these, amino acids, silicone oils, and vitamins are preferable. Although it does not specifically limit as said amino acids, Dilauroyl glutamate ricin Na (For example, Asahi Kasei Chemicals make, brand name "Perisea”), a trimethylglycine, glutamic acid, etc.
- the easily disintegratable silica particles encapsulate the inclusion component
- the inclusion component is released when the easily disintegratable silica particles are disintegrated during hair styling, and an effect corresponding to the type of the inclusion component is exhibited.
- the easily disintegratable silica particles encapsulate amino acids, thereby exhibiting a hair damage care function.
- the method for producing the easily disintegratable silica particles is not particularly limited, and a known method can be used.
- the silica oil absorption is preferably 100 mL / 100 g or more, more preferably 150 mL / 100 g or more, still more preferably 200 mL / 100 g or more, preferably 1000 mL / 100 g or less, more preferably 800 mL / 100 g or less, more preferably 700 mL / 100 g or less.
- the oil absorption amount of the silica is not less than the above lower limit and not more than the above upper limit, the initial hair styling power, the hair styling holding power, and the re-hair styling property are further improved.
- the oil absorption is measured according to the method described in JIS K5101.
- silica silicic acid manufactured by Fuji Silysia Chemical Co., Ltd. trade name “Silicia 320”, trade name “Silisia 310P”, trade name “Silicia 250”, trade name “Silicia 250N”, Product name “Siricia 350”, Product name “Siricia 370”, Product name “Silicia 380”, Product name “Silicia 420”, Product name “Silicia 430”, Product name “Silicia 440”, Product name “Silicia 450”, and Product Name “Silicia 470”: Nippon Aerosil Co., Ltd., which is silicic anhydride, product name “AEROSIL 50”, product name “AEROSIL 90G”, product name “AEROSIL 130”, product name “AEROSIL 150”, product name “AEROSIL 200” ",Product name” EROSIL 300, product name “AEROSIL 380”, product name “AEROSIL 200V” and product name “AE
- the said calcium carbonate is represented by the INCI name "CALCIUM CARBONATE", for example.
- the said calcium carbonate only 1 type may be used and 2 or more types may be used.
- Sakai Chemical Industry Co., Ltd. product name "Karumaru SCS M5"; Shiraishi Calcium Co., Ltd. product name "Fuwakal” etc. are mentioned, for example.
- the magnesium carbonate is represented by, for example, the INCI name “MAGNESIUM CARBONATE”. As for the said magnesium carbonate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium carbonate, the Tomita Pharmaceutical Co., Ltd. make, brand name "light magnesium carbonate” etc. are mentioned, for example.
- the hydroxyapatite is represented by, for example, the INCI name “HYDROXYAPATITE”. As for the said hydroxyapatite, only 1 type may be used and 2 or more types may be used.
- the hydroxyapatite is not particularly limited, and examples thereof include spherical hydroxyapatite, plate-like hydroxyapatite, and amorphous hydroxyapatite. Among these, spherical hydroxyapatite is preferable from the viewpoint of high hair styling performance.
- Examples of commercially available products of hydroxyapatite include, for example, trade name “plate-shaped HAP”, trade name “spherical HAP”, trade name “HAP-100”, trade name “HAP-200”, trade name “HAP-300” ( All of them are manufactured by Taihei Chemical Industry Co., Ltd.
- the titanium oxide is represented by, for example, the INCI name “TITANIUM DIOXIDE”.
- the titanium oxide is not particularly limited, and may be fine particle titanium oxide or pigment titanium, for example. As for the said titanium oxide, only 1 type may be used and 2 or more types may be used. Examples of commercially available titanium oxide include Ishihara Sangyo Co., Ltd., trade name “TTO-55 (A)”, trade name “CR-50”, and the like.
- the zinc oxide is represented by, for example, the INCI name “ZINC OXIDE”. As for the said zinc oxide, only 1 type may be used and 2 or more types may be used. Examples of commercially available products of zinc oxide include trade name “FINEX-30S-LP2” manufactured by Sakai Chemical Industry Co., Ltd.
- the calcium silicate is represented, for example, by the INCI name “CALCIUM SILICATE”. As for the said calcium silicate, only 1 type may be used and 2 or more types may be used. Examples of commercially available products of the above calcium silicate include Tomita Pharmaceutical Co., Ltd., trade name “Calcium Silicate Fluorite R”; Nippon Insulation Co., Ltd., trade name “Zonotolite Powder XJ”, trade name “Tobermorite Powder TK”. Or the like.
- the magnesium silicate is represented by, for example, the INCI name “MAGNESIUM SILICATE”. As for the said magnesium silicate, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium silicate, the Tomita Pharmaceutical Co., Ltd. make, brand name "magnesium silicate (light)" etc. are mentioned, for example.
- the aluminum silicate is represented by, for example, the INCI name “ALUMINUM SILICATE”. As for the said aluminum silicate, only 1 type may be used and 2 or more types may be used. Although it does not specifically limit as an aluminum silicate, A synthetic aluminum silicate is preferable. Synthetic methods include, for example, a method of adding Na 2 SiO 3 to alum and drying the generated precipitate, a method of forming a silicate sol by electrodialysis, and generating a gel by this, or an aluminum salt in water glass A method of adding an aqueous solution of As a commercial item of the said aluminum silicate, the Tomita Pharmaceutical Co., Ltd. make, brand name "synthetic aluminum silicate (heavy)" etc. are mentioned, for example.
- the magnesium hydroxide is represented by, for example, the INCI name “MAGNESIUM HYDROXIDE”. As for the said magnesium hydroxide, only 1 type may be used and 2 or more types may be used. As a commercial item of the said magnesium hydroxide, the Tomita Pharmaceutical Co., Ltd. make, brand name "magnesium hydroxide (heavy)" etc. are mentioned, for example.
- the content of the component (A) is 0.1% by mass or more, preferably 0.4% by mass or more, more preferably 1% by mass or more and 10% by mass. Hereinafter, it is preferably 7% by mass or less, more preferably 5% by mass or less.
- the content of the component (A) is not less than the above lower limit, the initial styling power immediately after styling can be further increased, and the styling holding power can be further enhanced.
- content of the said component (A) is below the said upper limit, the effect which suppresses flaking and the wash-off property improve further.
- the content of the component (A) is the total content of all the components (A) in the hairdressing composition according to the present invention.
- the said component (B) is pantothenyl alcohol (panthenol).
- the component (B) mainly has a role of effectively increasing the initial hair styling power and the hair styling holding power. Moreover, by using the component (B), flaking can be suppressed and the above effect can be exhibited.
- the said component (B) only 1 type may be used and 2 or more types may be used.
- the pantothenyl alcohol may be any of D-form, L-form and racemate. Among these, D-form (that is, D-pantothenyl alcohol) is preferable from the viewpoint of availability.
- the content of the component (B) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, and further preferably 1% by mass or more. Preferably it is 20 mass% or less, More preferably, it is 10 mass% or less, More preferably, it is 5 mass% or less.
- the content of the component (B) is not less than the above lower limit, the hair styling power and its sustainability are further improved.
- the content of the component (B) is less than or equal to the above upper limit, the sticking suppression effect, the spread at the time of application, and the familiarity are further improved.
- the content of the component (B) is the total content of all the components (B) in the hairdressing composition according to the present invention.
- the component (C) is at least one compound selected from the group consisting of the component (C1) and the component (C2).
- flaking can be further suppressed, washing off after hair styling is improved, and good hair feel can be imparted to the hair after styling while maintaining high initial hair styling power.
- the sense of discomfort to which the hair-styling composition is attached is suppressed, and hair can be styled in a natural state.
- the said component (C) only 1 type may be used and 2 or more types may be used.
- only 1 type may be used for said component (C1) and said component (C2), respectively, and 2 or more types may be used.
- component (C) only one of the component (C1) and the component (C2) may be used, or the component (C1) and the component (C2) may be used in combination. .
- the component (C1) is a polyoxyalkylene alkyl glucoside.
- the oxyalkylene group in the component (C1) include an oxyethylene group and an oxypropylene group.
- the average addition mole number of the oxyalkylene group in the component (C1) is not particularly limited, but is preferably 5 or more, and preferably 40 or less.
- the number of carbon atoms of the alkyl group in the component (C1) is preferably 1 to 4, more preferably 1 to 3.
- the alkyl group in the component (C1) is preferably a methyl group or an ethyl group.
- the component (C1) is not particularly limited, and examples thereof include polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, polyoxypropylene methyl glucoside, and polyoxypropylene ethyl glucoside. From the viewpoint of imparting a better touch to the hair after styling while maintaining high initial hair styling power, the component (C1) is preferably polyoxyethylene methyl glucoside.
- the component (C2) is a polyoxyalkylene glycerin fatty acid ester.
- the number of carbon atoms of the fatty acid in the component (C2) is preferably 8 or more, and preferably 22 or less.
- Examples of the oxyalkylene group in the component (C2) include an oxyethylene group and an oxypropylene group.
- the average added mole number of the oxyalkylene group in the component (C2) is preferably 5 or more, and preferably 40 or less.
- the fatty acid in the component (C2) is preferably a branched fatty acid, and the component (C2) is a polyoxyalkylene. It is preferably a glycerin branched fatty acid ester. From the viewpoint of imparting a better touch to the hair after styling while maintaining high initial hair styling power, the number of carbon atoms of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester is preferably 8 or more, and preferably 22 or less. .
- Examples of the branched fatty acid in the polyoxyalkylene glycerin branched fatty acid ester include 2-ethylhexanoic acid, isononanoic acid, isopalmitic acid, and isostearic acid.
- polyoxyalkylene glycerin branched fatty acid ester polyoxyethylene glyceryl isostearate is particularly preferable.
- component (C2) Commercially available products of the component (C2) include, for example, Daiichi Kogyo Seiyaku Co., Ltd., trade name “Neugen GIS-125”; Nihon Emulsion Co., Ltd., trade name “EMALEX GWIS-115”, trade name “EMALEX GWIS”. -120 ”, trade name“ EMALEX GWIS-125 ”, trade name“ EMALEX GWIS-130 ”, and the like.
- the content of the component (C) is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 20% by mass or less, more preferably. It is 10 mass% or less.
- the content of the component (C) is not less than the above lower limit, flaking is further suppressed, washing off after hair styling is further improved, and a better touch is imparted to the hair after hair styling.
- The is not more than the above upper limit, stickiness is further reduced.
- Content of the said component (C) is a total amount of content of all the components (C) in the hairdressing composition which concerns on this invention.
- the mass ratio between the content of the component (A) and the content of the component (C) is 1 : 0.2 to 1:20 is preferable, and 1: 1 to 1:10 is more preferable.
- content of the component (C) is relatively increased, the hair texture, flaking suppression effect, and wash-off properties are further improved.
- Component (D) The component (D) is a clay mineral. By using the component (D), the hair styling power and the storage stability of the hair styling composition are further improved. As for the said component (D), only 1 type may be used and 2 or more types may be used.
- the component (D) may be a natural product or a synthetic product. Although it does not specifically limit as said component (D), For example, kaolin group clay mineral, antigolite group clay mineral, pyrophyllite group clay mineral, mica group clay mineral, smectite group clay mineral, vermiculite group clay mineral, green mud Examples include stone group clay minerals and organically modified clay minerals.
- Examples of the kaolin group clay mineral include kaolin, nacrite, dickite, and halosite.
- examples of the antigolite group clay mineral include antigolite, amesite, and cronstedite.
- examples of the pyrophyllite clay mineral include pyrophyllite and talc (talc).
- examples of the mica group clay minerals include illite, sea chlorite, ceradonite, sericite, mica (mica), muscovite, chromium muscovite and biotite.
- Examples of the smectite clay mineral include bentonite, montmorillonite, beidellite, nontonite, saponite, hectorite, and lucentite. Vermiculite etc.
- vermiculite group clay mineral examples include chlorite.
- examples of the organic modified clay mineral include an organic modified clay mineral obtained by organically modifying a smectite group clay mineral or a vermiculite group clay mineral.
- a quaternary ammonium salt type cationic surfactant is preferably used for the organic modification treatment.
- examples of the quaternary ammonium salt type cationic surfactant include the above alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, and benzalkonium chloride.
- the component (D) is preferably a clay mineral selected from the group consisting of synthetic silicates and derivatives thereof.
- the above-mentioned synthetic silicate and its derivative are not a silicate mineral mainly composed of magnesium silicate or silicic acid (sodium / magnesium) derived from nature, which contains impurities, but silicic acid obtained by synthesis. Refers to salts and silicate derivatives.
- Examples of the synthetic silicate and derivatives thereof include, for example, an INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 3076): SODIUM MAGNESIUM SILICATE Acid (sodium / magnesium), INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 2, CTFA, 2012, p. 1793): MAGNESIUM FLUOROSILICATE Magnesium Fluorosilicate, INCI name Cosmetic gradient Dictary and Handbook, 14th edition, Volume 2, CTFA, 2012, p.
- SODIUM MAGNESIUM FLUOROSILICATE fluorosilicic acid (sodium / magnesium), INCI name (International CosmicHindoticIndigo 14th Edition, Volume 2, CTFA, 2012, p. 1799): MAGNESIUM POTASSIUM FLUOROSILIC Fluorosilicate (magnesium / potassium), INCI name (International Cosmetic Ingredient Dictionary and Han book, 14th edition, volume 2, CTFA, 2012, p. 1800): MAGNESIUM SODIUM FLUOROSILICATE, fluorosilicic acid (magnesium / sodium), INCI name (International Cosmetic Ingredient Dictionary, Handbook 14th edition) Volume 1, CTFA, 2012, p. 156): ALUMINUM, synthetic aluminum silicate represented by SILICATE.
- a clay mineral at least one selected from the group consisting of synthetic silicic acid (sodium / magnesium), fluorosilicic acid (sodium / magnesium), and fluorosilicic acid (sodium / magnesium) is used. Clay minerals are particularly preferred.
- the content of the component (D) is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and further preferably 0.5% by mass. As mentioned above, Preferably it is 10 mass% or less, More preferably, it is 5 mass% or less, More preferably, it is 3 mass% or less.
- the content of the component (D) is not less than the above lower limit, the hair styling property is further improved.
- the content of the component (D) is not more than the above upper limit, the storage stability of the hairdressing composition is further improved.
- the component (E) is a polysaccharide compound.
- the hairdressing composition is appropriately thickened, so that the dispersibility of the component (A) is further increased. It becomes much better, and water storage and separation of the composition are suppressed, and the storage stability is further improved. Moreover, the elongation at the time of application
- coating and familiarity can be improved by suppressing the viscosity increase of a hairdressing composition.
- the said component (E) only 1 type may be used and 2 or more types may be used.
- a polysaccharide, modified polysaccharide (for example, alkyl modified polysaccharide etc.) etc. are preferable, for example, alginic acid, carrageenan, agar, ferrerlan, guar gum, quince seed, konjac mannan, tamarind seed gum
- Plant-derived polysaccharide compounds such as tara gum, dextrin, starch, locust bean gum, gum arabic, gati gum, karaya gum, tragacanth gum, arabinogalactan, pectin and quince
- animal-derived polysaccharide compounds such as chitosan and hyaluronic acid
- Microbial-derived polysaccharide compounds such as xanthan gum, gellan gum, cyclodextrin, dextran, pullulan and hyaluronic acid
- microcrystalline cellulose methylcellulose, ethylcellulose, hydroxymethylcell
- Nonionic celluloses such as glucose
- xanthan gum guar gum, tamarind gum, and gellan gum are preferable.
- E examples include xanthan gum manufactured by Dainippon Sumitomo Pharma Co., Ltd., trade name “Echo Gum T”, trade name “Keldent”, and trade name “Monato Gum”; Product name “Inagel Guar Gum CS” manufactured by company; manufactured by DSP Gokyo Food & Chemical Co., Ltd., a tamarind gum, product name “Glyroid 6C”; CP Kelco U. S. , Inc. Manufactured and trade name "Kelcogel”.
- the content of the component (E) is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and preferably 3% by mass or less. Preferably it is 1 mass% or less.
- the content of the component (E) is not less than the above lower limit, water removal and separation of the hairdressing composition are suppressed, and the storage stability is further improved.
- the content of the component (E) is less than or equal to the above upper limit, the increase in viscosity is suppressed and the elongation and familiarity during application are further improved, and the hair styling power is further improved.
- Content of the said component (E) is a total amount of content of all the components (E) in the hairdressing composition which concerns on this invention.
- the total content of the component (D) and the component (E) is preferably 0.3% by mass or more, more preferably 0.4% by mass or more. More preferably, it is 0.6% by mass or more, preferably 5% by mass or less, more preferably 4% by mass or less.
- the total content of the component (D) and the component (E) is equal to or higher than the lower limit, the component (A) is prevented from settling, and the hair-styling composition is prevented from being separated or separated, thereby being stable. The property becomes even better.
- the total content of the component (D) and the component (E) is not more than the upper limit, an increase in the viscosity of the hairdressing composition is suppressed, and the elongation and familiarity at the time of application are further improved.
- the mass ratio of the content of the component (D) and the content of the component (E) is a hairdressing composition according to the present invention.
- 100% by mass it is preferably 2: 1 to 10: 1, more preferably 2.5: 1 to 8: 1.
- the mass ratio is satisfied, the initial hair styling power is further improved, and the storage stability of the hair styling composition is further improved, and an increase in the viscosity of the hair styling composition when stored for a long period of time can be suppressed. Elongation and familiarity during application become even better.
- the component (F) is polyethylene glycol.
- the component (F) mainly has a role of effectively increasing the initial hair styling power and the hair styling holding power. In addition, by using the component (F), it is possible to impart a better touch to the hair after styling while maintaining high initial styling power.
- the said component (F) only 1 type may be used and 2 or more types may be used.
- the number average molecular weight of the component (F) is preferably 150 or more, more preferably 200 or more, preferably 6000 or less, more preferably 4000 or less. Two or more components (F) having different number average molecular weights may be used.
- the content of the component (F) is preferably 1% by mass or more, more preferably 3% by mass or more, preferably 30% by mass or less, more preferably 25% by mass. % Or less, more preferably 10% by mass or less.
- the content of the component (F) is not less than the above lower limit, the initial hair styling power and the hair styling holding power can be further enhanced.
- the content of the component (F) is less than or equal to the above upper limit, the occurrence of flaking can be further suppressed, and the hair after styling can be imparted with a better touch by suppressing stiffness and squeaking.
- Content of the said component (F) is a total amount of content of all the components (F) in the hairdressing agent composition which concerns on this invention.
- the mass ratio between the content of the component (A) and the content of the component (F) (content of the component (A): content of the component (F)). Is preferably 1: 1 to 1:25, more preferably 1: 3 to 1:20.
- the content of the component (A) is relatively increased, the initial hair styling power is further improved.
- the content of the component (F) is relatively increased, the firmness and creaking are further improved.
- the hairdressing composition according to the present invention is not particularly limited, but preferably contains water. Although the said water will not be specifically limited if it is the water used for cosmetics, Purified water is preferable. In 100% by mass of the hairdressing composition according to the present invention, the content of water is preferably 30% by mass or more, more preferably 40% by mass or more, preferably 95% by mass or less, more preferably 90% by mass or less. .
- the hairdressing composition according to the present invention is not particularly limited, but preferably contains a lower alcohol having 2 to 5 carbon atoms (particularly ethanol).
- the content of the lower alcohol (particularly ethanol) is preferably 2% by mass or more, more preferably 5% by mass or more, preferably 50% by mass or less, more preferably. 30% by mass or less.
- the hairdressing composition according to the present invention can be used within the range not inhibiting the effects of the present invention, for example, surfactants such as nonionic surfactants, cationic surfactants and amphoteric surfactants; glycerin, 1,3-butylene glycol Polyhydric alcohols such as propylene glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol; lauryl alcohol, myristyl alcohol, C12-18 higher alcohols such as cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol and oleyl alcohol; sugar alcohols such as sorbitol, maltitol and trehalose; silicone oils; sequestering agents; antioxidants; Plant extract; dye; Fee; pH adjusting agents; perfumes; may contain a solvent such as, preservatives.
- the hairdressing composition according to the present invention is not particularly limited, but is a liquid at 25 ° C. and a polyoxyethylene / polyoxypropylene copolymer having a number average molecular weight of 10,000 to 20000, and a liquid at 25 ° C. And a compound selected from the group consisting of polyoxypropylene sorbites having a number average molecular weight of 300 or more and 1000 or less may be included.
- the “compound selected from the group consisting of polyoxypropylene sorbits having a molecular weight of 1000 or less” may be referred to as “component (G)”.
- the “polyoxyethylene / polyoxypropylene copolymer having a liquid state at 25 ° C. and having a number average molecular weight of 10,000 or more and 20,000 or less” may be referred to as “component (G1)”.
- a polyoxypropylene sorbit having a number average molecular weight of 300 or more and 1000 or less” may be referred to as “component (G2)”.
- the component (G) is at least one compound selected from the group consisting of the component (G1) and the component (G2).
- the component (G) mainly has a role of further enhancing the initial hair styling power and the hair styling holding power. Moreover, flaking can be further suppressed and the above effects can be exhibited.
- the said component (G) only 1 type may be used and 2 or more types may be used. In addition, only 1 type may be used for said component (G1) and said component (G2), respectively, and 2 or more types may be used.
- As the component (G), only one of the component (G1) and the component (G2) may be used, or the component (G1) and the component (G2) may be used in combination. Good. Especially, it is preferable that the said component (G1) and the said component (G2) are used together from a viewpoint of improving the sustainability of hairdressing power further.
- the component (G1) is a polyoxyethylene / polyoxypropylene copolymer. That is, the component (G1) is a copolymer having at least a plurality of oxyethylene units (ethylene oxide units) and a plurality of oxypropylene units (propylene oxide units).
- the component (G1) may be any of a block copolymer, a random copolymer, and an alternating copolymer, and the form of copolymerization in the component (G1) is not particularly limited.
- the average added mole number of oxyethylene in the component (G1) is not particularly limited, but is preferably 100 or more, more preferably 200 or more, preferably 400 or less, more preferably 350 or less.
- the average added mole number of oxypropylene in the component (G1) is not particularly limited, but is preferably 30 or more, more preferably 40 or more, preferably 150 or less, more preferably 100 or less.
- the component (G1) is in a liquid state at 25 ° C. from the viewpoint of further suppressing flaking, easy application of the hairdressing agent, and imparting gloss to the hair.
- the number average molecular weight of the component (G1) is 10,000 or more from the viewpoint of the effect of improving hairdressing properties and 20000 or less from the viewpoint of handling properties.
- the number average molecular weight of the component (G1) is preferably 12000 or more.
- the number average molecular weight of the component (G1) is preferably 18000 or less.
- the component (G2) is polyoxypropylene sorbit.
- the average added mole number of oxypropylene in the component (G2) is not particularly limited, but is preferably 4 or more, more preferably 8 or more, preferably 15 or less, more preferably 12 or less.
- the component (G2) is in a liquid state at 25 ° C. from the viewpoint of further suppressing flaking, easy application of the hairdressing agent, and imparting gloss to the hair.
- the number average molecular weight of the component (G2) is 300 or more and 1000 or less.
- the number average molecular weight of the component (G2) is preferably 400 or more.
- the number average molecular weight of the component (G2) is preferably 800 or less.
- the liquid state at 25 ° C. means that, for example, the viscosity ⁇ measured at 25 ° C. using a Brookfield type rotational viscometer is preferably 5000 mPa ⁇ s or less, more preferably 3000 mPa ⁇ s or less.
- the viscosity ⁇ is preferably 10 mPa ⁇ s or more, more preferably 100 mPa ⁇ s or more.
- Examples of commercially available components (G1) include Sanyo Chemical Industries, Ltd., trade name “New Paul 75H-90000”, and the like.
- Examples of commercially available components (G2) include Sanyo Chemical Industries, Ltd., trade name “New Pole SP-750”, trade name “Sannix SP-750”, and the like.
- the content of the component (G) is preferably 3% by mass or more, more preferably 5% by mass or more, and still more preferably, from the viewpoint of hair styling power and its sustainability. Is 8% by mass or more, and is preferably 40% by mass or less, more preferably 30% by mass or less, and still more preferably 20% by mass or less, from the viewpoint of stickiness suppressing effect, spreading during application, and familiarity.
- Content of the said component (G) is a total amount of content of all the components (G) in the hairdressing composition which concerns on this invention.
- the hairdressing composition according to the present invention is not particularly limited, but may contain a polymer selected from the group consisting of the following first polymer and the following second polymer.
- the first polymer is a polymer obtained by using two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters as essential monomer components.
- the second polymer includes, as essential monomer components, a monomer selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, (meth) acrylic acid polyoxyethylene alkyl ether, itaconic acid poly A polymer obtained using an oxyethylene alkyl ether and a monomer selected from the group consisting of vinyl neodecanoate.
- the “polymer selected from the group consisting of the first polymer and the second polymer” may be referred to as “component (H)”. Further, the “first polymer” may be referred to as “component (H1)”, and the “second polymer” may be referred to as “component (H2)”. “(Meth) acrylic acid” means one or both of acrylic acid and methacrylic acid.
- the component (H) is at least one polymer selected from the group consisting of the component (H1) and the component (H2).
- the hairdressing composition is moderately thickened. Therefore, the dispersibility of the component (A) is further improved, and the hairdressing composition is more difficult to separate, so that the storage stability is improved. Even better. In addition, the hair styling property is further improved.
- the component (H) may be used in place of the component (E) or together with the component (E).
- the said component (H) only 1 type may be used and 2 or more types may be used. In addition, only 1 type may be used for the said component (H1) and the said component (H2), respectively, and 2 or more types may be used.
- the monomer component used to obtain the polymer of the component (H1) includes at least two or more monomers selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl esters. That is, the component (H1) is a polymer containing at least two structural units selected from the group consisting of structural units derived from (meth) acrylic acid and structural units derived from (meth) acrylic acid alkyl esters. . In this specification, the polymer that can correspond to both the component (H1) and the component (H2) is not the component (H1) but the component (H2).
- H1 examples include Dow Chemical Co., Ltd., trade name “Aculin 33”, trade name “Aculin 33A”; SEPPIC, trade name “SepiMAX ZEN”, and the like.
- the component (H1) is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance.
- the basic substance include alkanolamines such as triethanolamine and monoethanolamine; inorganic bases such as ammonia, sodium hydroxide, and potassium hydroxide; basic amino acids such as arginine.
- the basic substance is added in an amount sufficient to neutralize the component (H1) or an amount sufficient to neutralize the component (H1).
- the type of the basic substance and the amount of the component (H1) used may be appropriately blended.
- the monomer component used to obtain the polymer of component (H2) is at least one monomer component (h2a) selected from the group consisting of (meth) acrylic acid and (meth) acrylic acid alkyl ester, and (meth) And at least one monomer component (h2b) selected from the group consisting of polyoxyethylene alkyl ether acrylate, polyoxyethylene alkyl ether itaconic acid and vinyl neodecanoate. That is, the component (H2) is a polymer including at least a structural unit derived from the monomer component (h2a) and a structural unit derived from the monomer component (h2b). As for the said monomer component (h2a) and the said monomer component (h2b), only 1 type may respectively be used and 2 or more types may be used.
- ACRYLATES / BEHENETH-25 METHACRYLATE COPOLYMER ((Acrylates / Beheneth-25 Methacrylate Copolymer)); INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, 20th edition, CT, 14th edition) 68-69) "ACRYLATES / VIN L NEODENONOATE CROSSPOLYMER ((Acrylates / vinyl neodecanoate) crosspolymer) ”; INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, Volume 1, CTFA, 2012, p.
- ACRYLATES / STEARETH-20 ITACONATE COPOLYMER ((Acrelate / Itaconic acid steareth-20) copolymer) ”; INCI name (International Cosmetic Ingredient Dictionary and Handbook, 14th edition, CT, 14th edition, 14th edition .60) “ACRYL A compound represented by “ATES / CETETH-20, ITACONATE COPOLYMER ((Acrelates / Ceteth-20 itaconate) copolymer)” is preferable.
- the component (H2) is not particularly limited, but is preferably neutralized with a basic substance or neutralized with a basic substance.
- Examples of the basic substance in this case include the basic substances described above.
- the basic substance is added in an amount sufficient to neutralize the component (H2) or an amount sufficient to neutralize the component (H2). ) And the type of the basic substance and the amount of the component (H2) used may be appropriately blended.
- the content of the component (H) is preferably 0.01% by mass or more from the viewpoint of the effect of imparting gloss and the storage stability of the hairdressing composition. More preferably, it is 0.1% by mass or more, and preferably 5% by mass or less, and more preferably 2% by mass or less, from the viewpoint of hair styling ability and hair touch.
- Content of the said component (H) is a total amount of content of all the components (H) in the hairdressing agent composition which concerns on this invention.
- the properties of the hairdressing composition according to the present invention are not particularly limited, but may be any of liquid, gel, cream and solid.
- the hair styling composition is preferably liquid or gel.
- particles such as silica are used in a liquid or gel hairdressing composition, the dispersibility of the particles tends to decrease because the hairdressing composition has high fluidity.
- the initial hairstyling power and the hairstyling holding power tend to be reduced, and stickiness and flaking tend to occur.
- the hairdressing composition according to the present invention even if it is a liquid or gel hairdressing composition, the occurrence of flaking and stickiness is suppressed, and the initial hairstyling power and hairstyling are achieved. Holding power can be increased.
- the viscosity at 25 ° C. of the hairdressing composition is preferably 1000 mPa ⁇ s or more, more preferably 2000 mPa ⁇ s or more, preferably 100,000 mPa ⁇ s or less, more preferably 50000 mPa ⁇ s or less.
- the viscosity is not less than the above lower limit and not more than the above upper limit, applicability is further enhanced, flaking and stickiness are further suppressed, and initial hair styling power and hair styling holding power are further enhanced.
- the viscosity is not more than the above upper limit and the fluidity is high, the occurrence of flaking and stickiness can be suppressed, and the initial hair styling power and hair styling holding power can be increased.
- the above viscosity was measured using a viscometer, No. It is measured under the conditions of a rotation speed of 12 rpm and a rotation time of 1 minute using a 4-rotor.
- a viscometer a TV-22 viscometer manufactured by Toki Sangyo Co., Ltd. can be used.
- the method for producing the hairdressing composition according to the present invention is not particularly limited, and a known method for producing a hairdressing composition can be used as the method for producing the hairdressing composition according to the present invention. Although it does not specifically limit as a manufacturing method of the hairdressing agent composition which concerns on this invention, For example, after stirring a component (A), a component (E), and water with a disper mixer, changing to a paddle mixer and stirring, The method of mix
- the hair styling composition according to the present invention includes at least a component (A) and a component (B) as main hair styling components. While only component (B) causes stickiness, the combined use of component (A) and component (B) can increase the initial hair-styling power immediately after hair styling while suppressing stickiness, and the hair-styling retention force. Can be increased. In addition, by using the component (B), it is possible to suppress the occurrence of flaking (a phenomenon in which white powder or a film appears to adhere to the hair) when the hair is arranged. Thereby, if the hair-styling agent composition according to the present invention is used, not only hair can be properly sculpted, but the state of shampooing can be favorably sustained for a long period of time.
- flaking a phenomenon in which white powder or a film appears to adhere to the hair
- the hair styling ability and the flaking suppression effect are further improved, and the wash-off is further improved.
- the hairdressing composition is moderately thickened, and the applicability of the hairdressing composition is improved. Furthermore, by setting the blending ratio of the component (D) and the component (E) to a specific preferable range, the component (A) is less likely to settle or aggregate, and the storage stability of the hairdressing composition is increased. (Stability over time) is improved.
- the hair styling composition according to the present invention is not particularly limited, but can be used, for example, in a form filled in a container.
- the container include a bottle container, a jar container, and a tube container.
- the container is preferably a bottle container or a tube container.
- surface was shown by the actual compounding quantity (composition quantity of goods).
- the obtained hairdressing composition was filled in a plastic container to obtain a hairdressing agent.
- the hairdressing composition obtained in Examples 1-1 to 1-12 and Examples 2-1 to 2-27 was filled in a transparent glass container having a volume of 60 mL and kept in a thermostatic bath maintained at 40 ° C. After storing for 1 month, the hair styling composition in the transparent glass container after 1 month storage was visually observed. As a result, neither generation of aggregates or sediments nor separation of the hairdressing composition was observed, and the hairdressing composition showed excellent storage stability.
- the hair styling composition according to the present invention is suitably used as a hair styling agent for preparing hair.
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Abstract
Description
成分(A):シリカ、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、酸化チタン、酸化亜鉛、ケイ酸カルシウム、ケイ酸マグネシウム、ケイ酸アルミニウム、及び水酸化マグネシウムからなる群より選ばれた粒子
成分(B):パントテニルアルコール
成分(C):ポリオキシアルキレンアルキルグルコシド及びポリオキシアルキレングリセリン脂肪酸エステルからなる群より選ばれた化合物
成分(D):粘土鉱物
成分(E):多糖系化合物
成分(E):多糖系化合物
成分(F):ポリエチレングリコール
上記成分(A)は、シリカ、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、酸化チタン、酸化亜鉛、ケイ酸カルシウム、ケイ酸マグネシウム、ケイ酸アルミニウム、及び水酸化マグネシウムからなる群より選ばれた少なくとも1の粒子である。上記成分(A)は、主として、べたつきを抑え、初期整髪力及び整髪保持力を高める役割を有する。また、上記成分(A)の使用により、皮膜形成ポリマーを用いた場合と比べて、一旦整髪した後に整髪を再度行うことを容易にし、再整髪性を高めることも可能である。
上記シリカとしては、公知慣用のシリカ(無水ケイ酸)を用いることができる。上記シリカは、疎水化処理されていない無水ケイ酸(親水性のシリカ)であってもよいし、疎水化無水ケイ酸であってもよい。また、上記シリカは、アミノ酸、エステル、レシチン等で表面処理されたシリカであってもよい。また、上記シリカは、所謂、易崩壊性シリカ粒子であってもよい。上記シリカは、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記炭酸カルシウムは、例えば、INCI名「CALCIUM CARBONATE」で表される。上記炭酸カルシウムは、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記炭酸カルシウムの市販品としては、例えば、堺化学工業株式会社製、商品名「かるまる SCS M5」;白石カルシウム株式会社製、商品名「ふわカル」などが挙げられる。
上記炭酸マグネシウムは、例えば、INCI名「MAGNESIUM CARBONATE」で表される。上記炭酸マグネシウムは、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記炭酸マグネシウムの市販品としては、例えば、富田製薬株式会社製、商品名「軽質炭酸マグネシウム」などが挙げられる。
上記ヒドロキシアパタイトは、例えば、INCI名「HYDROXYAPATITE」で表される。上記ヒドロキシアパタイトは、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記ヒドロキシアパタイトとしては、特に限定されず、例えば、球状のヒドロキシアパタイト、板状のヒドロキシアパタイト、非晶質のヒドロキシアパタイトなどが挙げられる。中でも、高い整髪性能を有する観点から、球状のヒドロキシアパタイトが好ましい。
上記ヒドロキシアパタイトの市販品としては、例えば、商品名「板状HAP」、商品名「球状HAP」、商品名「HAP-100」、商品名「HAP-200」、商品名「HAP-300」(いずれも太平化学産業株式会社製)などが挙げられる。
上記酸化チタンは、例えば、INCI名「TITANIUM DIOXIDE」で表される。上記酸化チタンは、特に限定されず、例えば、微粒子酸化チタンや、顔料チタンであってもよい。上記酸化チタンは、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記酸化チタンの市販品としては、例えば、石原産業株式会社製、商品名「TTO-55(A)」、商品名「CR-50」などが挙げられる。
上記酸化亜鉛は、例えば、INCI名「ZINC OXIDE」で表される。上記酸化亜鉛は、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記酸化亜鉛の市販品としては、例えば、堺化学工業株式会社製、商品名「FINEX-30S-LP2」などが挙げられる。
上記ケイ酸カルシウムは、例えば、INCI名「CALCIUM SILICATE」で表される。上記ケイ酸カルシウムは、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記ケイ酸カルシウムの市販品としては、例えば、富田製薬株式会社製、商品名「ケイ酸カルシウム フローライトR」;日本インシュレーション株式会社製、商品名「ゾノトライトパウダーXJ」、商品名「トバモライトパウダーTK」などが挙げられる。
上記ケイ酸マグネシウムは、例えば、INCI名「MAGNESIUM SILICATE」で表される。上記ケイ酸マグネシウムは、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記ケイ酸マグネシウムの市販品としては、例えば、富田製薬株式会社製、商品名「ケイ酸マグネシウム(軽質)」などが挙げられる。
上記ケイ酸アルミニウムは、例えば、INCI名「ALUMINUM SILICATE」で表される。上記ケイ酸アルミニウムは、1種のみが用いられてもよく、2種以上が用いられてもよい。ケイ酸アルミニウムとしては、特に限定されないが、合成ケイ酸アルミニウムが好ましい。合成方法としては、例えば、ミョウバンにNa2SiO3を加え、生成した沈殿を乾燥する方法や、電気透析法によりケイ酸ゾルを作り、これによりゲルを生成する方法、あるいは、水ガラスにアルミニウム塩の水溶液を加える方法などが挙げられる。
上記ケイ酸アルミニウムの市販品としては、例えば、富田製薬株式会社製、商品名「合成ケイ酸アルミニウム(重質)」などが挙げられる。
上記水酸化マグネシウムは、例えば、INCI名「MAGNESIUM HYDROXIDE」で表される。上記水酸化マグネシウムは、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記水酸化マグネシウムの市販品としては、例えば、富田製薬株式会社製、商品名「水酸化マグネシウム(重質)」などが挙げられる。
上記成分(B)は、パントテニルアルコール(パンテノール)である。上記成分(B)は、主として、初期整髪力及び整髪保持力を効果的に高める役割を有する。また、上記成分(B)の使用により、フレーキングを抑えて上記効果を発揮させることができる。上記成分(B)は、1種のみが用いられてもよく、2種以上が用いられてもよい。上記パントテニルアルコールは、D体、L体、ラセミ体のいずれであってもよい。中でも、入手の容易性からD体(即ち、D-パントテニルアルコール)が好ましい。
上記成分(C)は、上記成分(C1)及び上記成分(C2)からなる群より選ばれた少なくとも1の化合物である。上記成分(C)の使用により、フレーキングをより一層抑え、かつ整髪後の洗い落ちを良好にし、かつ高い初期整髪力を維持しつつ整髪後の髪に良好な手触りを付与することができる。また、毛髪に整髪剤組成物が付与され、毛髪が十分に整髪されている状態であっても、整髪剤組成物が付着している違和感が抑えられ、自然な状態で整髪することができる。上記成分(C)は、1種のみが用いられてもよく、2種以上が用いられてもよい。なお、上記成分(C1)、上記成分(C2)も、それぞれ、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記成分(D)は、粘土鉱物である。上記成分(D)の使用により、整髪力や整髪剤組成物の保存安定性がより一層良好になる。上記成分(D)は、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記成分(E)は、多糖系化合物である。上記成分(E)の使用により、特に上記成分(D)と上記成分(E)とを併用することにより、整髪剤組成物が適度に増粘するため、上記成分(A)の分散性がより一層良好になり、組成物の離水や分離が抑えられて保存安定性がより一層良好になる。また、整髪剤組成物の粘度上昇を抑えて塗布時の延び及び馴染みを高めることができる。上記成分(E)は、1種のみが用いられてもよく、2種以上が用いられてもよい。
上記成分(F)は、ポリエチレングリコールである。上記成分(F)は、主として、初期整髪力及び整髪保持力を効果的に高める役割を有する。また、上記成分(F)の使用により、高い初期整髪力を維持しつつ整髪後の髪により一層良好な手触りを付与することができる。上記成分(F)は、1種のみが用いられてもよく、2種以上が用いられてもよい。
本発明に係る整髪剤組成物は、特に限定されないが、水を含むことが好ましい。上記水は、化粧料に用いられる水であれば特に限定されないが、精製水が好ましい。本発明に係る整髪剤組成物100質量%中、水の含有量は、好ましくは30質量%以上、より好ましくは40質量%以上、好ましくは95質量%以下、より好ましくは90質量%以下である。
本発明に係る整髪剤組成物は、特に限定されないが、25℃で液状でありかつ数平均分子量が10000以上、20000以下であるポリオキシエチレン/ポリオキシプロピレン共重合体、及び25℃で液状でありかつ数平均分子量が300以上、1000以下であるポリオキシプロピレンソルビットからなる群より選ばれた化合物を含んでいてもよい。
本発明に係る整髪剤組成物は、特に限定されないが、下記第1のポリマー及び下記第2のポリマーからなる群より選ばれたポリマーを含んでいてもよい。第1のポリマーは、必須のモノマー成分として、(メタ)アクリル酸、及び(メタ)アクリル酸アルキルエステルからなる群より選ばれた2以上のモノマーを用いて得られるポリマーである。第2のポリマーは、必須のモノマー成分として、(メタ)アクリル酸、及び(メタ)アクリル酸アルキルエステルからなる群より選ばれたモノマーと、(メタ)アクリル酸ポリオキシエチレンアルキルエーテル、イタコン酸ポリオキシエチレンアルキルエーテル、及びネオデカン酸ビニルからなる群より選ばれたモノマーとを用いて得られるポリマーである。
本発明に係る整髪剤組成物の性状は、特に限定されないが、液状、ジェル状、クリーム状及び固形状のいずれであってもよい。上記整髪剤組成物は、液状又はジェル状であることが好ましい。一般に、液状又はジェル状の整髪剤組成物において、シリカ等の粒子を用いると、整髪剤組成物の流動性が高いために、粒子の分散性が低下する傾向がある。この結果、上記液状又はジェル状の整髪剤組成物では、初期整髪力及び整髪保持力が低下しやすくなったり、べたつき及びフレーキングが生じやすくなったりする傾向がある。これに対して、本発明に係る整髪剤組成物における上述した組成の採用によって、液状又はジェル状の整髪剤組成物であっても、フレーキングの発生及びべたつきを抑え、かつ初期整髪力及び整髪保持力を高めることができる。
商品名「サイリシア320」:シリカ、富士シリシア化学株式会社製
商品名「アエロジル200」:シリカ、日本アエロジル株式会社製
商品名「球状HAP」:ヒドロキシアパタイト、太平化学産業株式会社製
商品名「フローライトR」:ケイ酸カルシウム、富田製薬株式会社製
商品名「ケイ酸マグネシウム(軽質)」:ケイ酸マグネシウム、富田製薬株式会社製
商品名「合成ケイ酸アルミニウム(重質)」:ケイ酸アルミニウム、富田製薬株式会社製
商品名「D-Panthenol USP」:パントテニルアルコール、BASFジャパン株式会社製、液状
商品名「ノイゲン GIS-125」:イソステアリン酸ポリオキシエチレングリセリル、第一工業製薬株式会社製
商品名「マクビオブライド MG-10P」:ポリオキシプロピレンメチルグルコシド、日油株式会社製
商品名「ラポナイトXL21」:フルオロケイ酸(ナトリウム/マグネシウム)、ロックウッド社製
商品名「ラポナイトXLG」:合成ケイ酸(ナトリウム/マグネシウム)、ロックウッド社製
商品名「エコーガムT」:キサンタンガム、大日本住友製薬株式会社製
商品名「PEG-400」:ポリエチレングリコール、数平均分子量400(三洋化成工業株式会社製)
商品名「PEG#1000」:ポリエチレングリコール、数平均分子量1000(日油株式会社製)
商品名「PEG#4000」:ポリエチレングリコール、数平均分子量4000(日油株式会社製)
下記の表1~7に示す配合成分を配合(配合単位は質量%)し、整髪剤組成物を調製した。実施例1-1~1-12及び実施例2-1~2-27で得られた整髪剤組成物の性状はいずれもジェル状であった。なお、表中の配合量は、実配合量(商品の配合量)で示した。
得られた整髪剤組成物を、プラスチック製容器内に充填し、整髪剤を得た。
専門パネル20名が、上記整髪剤組成物をウィッグ(レッスンマネキン:株式会社ユーカリジャパン製)の毛髪上に均一に塗布し、ウィッグの形状に沿うように前方から後方へと髪を撫でつけるように整髪を施した後、べたつきの有無を回答した。上記回答から、下記の基準でべたつきを評価した。
<べたつきの評価基準>
○(かなり良好):20名中16名以上が、べたつきが無いと回答
△(良好):20名中10~15名が、べたつきが無いと回答
×(不良):20名中9名以下が、べたつきが無いと回答
専門パネル20名が、上記整髪剤組成物をウィッグ(レッスンマネキン:株式会社ユーカリジャパン製)の毛髪上に均一に塗布し、ウィッグの形状に沿うように前方から後方へと髪を撫でつけるように整髪を施した後、初期整髪力の有無を回答した。なお、整髪した髪の形状がくっきりと保持されているものを初期整髪力があると判定した。上記回答から、下記の基準で初期整髪力を評価した。
<初期整髪力の評価基準>
○(かなり良好):20名中16名以上が、初期整髪力があると回答
△(良好):20名中10~15名が、初期整髪力があると回答
×(不良):20名中9名以下が、初期整髪力があると回答
専門パネル20名が、上記試験例2(初期整髪力の評価)の後、6時間経過後に整髪を施したウィッグの毛髪を観察し、整髪保持力の有無を回答した。なお、試験例2の整髪した髪の形状が保持され続けている場合を整髪保持力があると判定した。上記回答から、下記の基準で整髪保持力を評価した。
<整髪保持力の評価基準>
○(かなり良好):20名中16名以上が、整髪保持力があると回答
△(良好):20名中10~15名が、整髪保持力があると回答
×(不良):20名中9名以下が、整髪保持力があると回答
専門パネル20名が、上記試験例3(整髪保持力の評価)の後、ウィッグの毛髪を、指先で毛髪の根元から毛先へ連続して5回コーミングし、フレーキングの有無を回答した。なお、毛髪上に白い粉が付着しているように見える場合に、フレーキングがあると判定した。上記回答から、下記の基準でフレーキングを評価した。
<フレーキングの評価基準>
○(かなり良好):20名中16名以上が、フレーキングが無いと回答
△(良好):20名中10~15名が、フレーキングが無いと回答
×(不良):20名中9名以下が、フレーキングが無いと回答
専門パネル20名が、上記試験例4(フレーキングの評価)の後、ウィッグの毛髪をシャンプー(商品名「ルシード シャンプー」、マンダム社製)を用いて、ぬるま湯にて洗髪した後に、乾燥し、洗い落ちの良否を回答した。なお、洗髪後の毛髪のきしみ感やべたつき感がない場合に、洗い落ちが良いとした。上記回答から、下記の基準で洗い落ちを評価した。
<洗い落ちの評価基準>
○(かなり良好):20名中16名以上が、洗い落ちが良いと回答
△(良好):20名中10~15名が、洗い落ちが良いと回答
×(不良):20名中9名以下が、洗い落ちが良いと回答
Claims (8)
- 下記成分(A)と、下記成分(B)とを含み、前記成分(A)の含有量が0.1質量%以上、10質量%以下である、整髪剤組成物。
成分(A):シリカ、炭酸カルシウム、炭酸マグネシウム、ヒドロキシアパタイト、酸化チタン、酸化亜鉛、ケイ酸カルシウム、ケイ酸マグネシウム、ケイ酸アルミニウム、及び水酸化マグネシウムからなる群より選ばれた粒子
成分(B):パントテニルアルコール - 前記成分(B)の含有量が0.1質量%以上、20質量%以下である、請求項1に記載の整髪剤組成物。
- さらに、下記成分(C)を含む、請求項1又は2に記載の整髪剤組成物。
成分(C):ポリオキシアルキレンアルキルグルコシド及びポリオキシアルキレングリセリン脂肪酸エステルからなる群より選ばれた化合物 - さらに、下記成分(D)を含む、請求項1~3のいずれか1項に記載の整髪剤組成物。
成分(D):粘土鉱物 - さらに、下記成分(E)を含む、請求項1~4のいずれか1項に記載の整髪剤組成物。
成分(E):多糖系化合物 - さらに、下記成分(E)を含み、
前記成分(D)の含有量と前記成分(E)の含有量との質量比が、2:1~10:1である、請求項4に記載の整髪剤組成物。
成分(E):多糖系化合物 - 前記成分(D)と前記成分(E)との合計の含有量が、0.3質量%以上、5質量%以下である、請求項6に記載の整髪剤組成物。
- さらに、下記成分(F)を含む、請求項1~7のいずれか1項に記載の整髪剤組成物。
成分(F):ポリエチレングリコール
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WO2015145821A1 (ja) * | 2014-03-28 | 2015-10-01 | 株式会社マンダム | 整髪剤組成物 |
JP2017019728A (ja) * | 2015-07-07 | 2017-01-26 | 株式会社マンダム | 整髪剤組成物及び整髪剤組成物の製造方法 |
JP2019142824A (ja) * | 2018-02-23 | 2019-08-29 | ホーユー株式会社 | 整髪剤組成物 |
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JPH11502872A (ja) * | 1996-01-16 | 1999-03-09 | ザ、プロクター、エンド、ギャンブル、カンパニー | 毛髪または皮膚を処置する組成物 |
JP2003342130A (ja) * | 2002-05-30 | 2003-12-03 | Shiseido Co Ltd | 毛髪化粧料 |
JP2004067572A (ja) * | 2002-08-06 | 2004-03-04 | Kanebo Ltd | 毛髪化粧料 |
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JP2017019728A (ja) * | 2015-07-07 | 2017-01-26 | 株式会社マンダム | 整髪剤組成物及び整髪剤組成物の製造方法 |
JP2019142824A (ja) * | 2018-02-23 | 2019-08-29 | ホーユー株式会社 | 整髪剤組成物 |
JP7178684B2 (ja) | 2018-02-23 | 2022-11-28 | ホーユー株式会社 | 整髪剤組成物 |
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