Classifications

• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
  • D21H27/30—Multi-ply
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
  • B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
  • B05C11/02—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
  • B05C11/04—Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface with blades
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
  • D21F7/00—Other details of machines for making continuous webs of paper
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H19/00—Coated paper; Coating material
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
  • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
  • D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
  • D21H23/20—Apparatus therefor
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
  • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
  • D21H23/22—Addition to the formed paper
  • D21H23/32—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper
  • D21H23/34—Knife or blade type coaters
  • D21H23/36—Knife or blade forming part of the fluid reservoir, e.g. puddle-type trailing blade or short-dwell coaters
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
  • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
  • D21H23/22—Addition to the formed paper
  • D21H23/32—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper
  • D21H23/40—Addition to the formed paper by contacting paper with an excess of material, e.g. from a reservoir or in a manner necessitating removal of applied excess material from the paper only one side of the paper being in contact with the material
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
  • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
  • D21H23/22—Addition to the formed paper
  • D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
  • D21H23/56—Rolls
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
  • D21H25/08—Rearranging applied substances, e.g. metering, smoothing; Removing excess material
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
  • D21H25/08—Rearranging applied substances, e.g. metering, smoothing; Removing excess material
  • D21H25/10—Rearranging applied substances, e.g. metering, smoothing; Removing excess material with blades
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
  • D21H25/08—Rearranging applied substances, e.g. metering, smoothing; Removing excess material
  • D21H25/12—Rearranging applied substances, e.g. metering, smoothing; Removing excess material with an essentially cylindrical body, e.g. roll or rod
• • D—TEXTILES; PAPER
  • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
  • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
  • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
  • D21H27/18—Paper- or board-based structures for surface covering
  • D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
  • D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M1/00—Inking and printing with a printer's forme
  • B41M1/26—Printing on other surfaces than ordinary paper
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M1/00—Inking and printing with a printer's forme
  • B41M1/26—Printing on other surfaces than ordinary paper
  • B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/0041—Digital printing on surfaces other than ordinary paper

Definitions

• the invention relates to a method for producing a printable single-layer or multilayer material web according to the preamble of claim 1 and a material web produced therefrom according to claim 20 and to a system for producing such a material web according to claim 22.
• printed papers are used in the context of industrial production, namely so-called decorative films. These papers are usually printed by means of a gravure printing process.
• the print quality depends on different factors. In addition to the quality of the printing material used, for example the paper printing web used, the quality depends above all on the surface structure of the printing rollers.
• Such, often imitated with wood imitation decorative films are used for the production of printed or printable components of various kinds, namely in particular for the production of furniture applications, but also for the production of floor, ceiling and / or wall applications.
• furniture applications using wood decors are known.
• Corresponding decorative papers printed with imitations of wood and / or pre-impregnated decor papers are glued onto corresponding carrier plates, which may consist, for example, of a medium-density or high-density fiberboard, in particular fibreboard. Since appropriate plates provided with decor papers or pre-impregnated decor paper, for example, in
• a laminate floor as the topmost layer must have an additional protective layer, i. a corresponding plastic layer, which is also referred to as an overlay layer.
• preimpregnated paper VI paper
• the most uniform possible penetration of the resin into the paper layer should be ensured.
• Similar problems exist even when webs are to be used for example, comprise a plastic film layer as the top layer or consist of a plastic film.
• the mentioned webs to be printed can be not only one but also multi-layered, with the lowermost layer consisting for example of a decorative paper web and the layers of other materials located thereon, and can also comprise adhesive interlayers.
• the uppermost layer may consist of plastic.
• a generic method for producing a paper layer for a flat, printed or printable component, for example in the form of a floor, wall, ceiling and / or furniture panel has become known for example from WO 2009/097986 AI.
• the fibers or the fiber structure of the decor paper are to be encased by the ink receiving mass on the printing side and / or cavities between the fibers are wholly or partially coated. be filled wise, thereby improving the pressure.
• the printed decorative paper can then be doctored. This is usually done and preferred in that the printed decorative paper web is passed through a corresponding tub of resin and then dried under the action of heat.
• the thus treated resin-impregnated printed paper web can then be applied to wood panels by heating, and therefore, a heat-reactable resin such as aminoplast, melamine resin or the like is preferably proposed.
• non-resin decorative paper is to be used, which is coated on the printing side with ink receptive material, then printed and then impregnated by means of resin.
• the paper layer it should also be possible for the paper layer to be so defined from the underside before printing that the upper region of the fiber structure, with little or no resin content, preferably extends over a maximum of 30% of the thickness of the fiber structure.
• the printed decorative paper web is preferably only after completion of the printing process.
• the ink receiving composition used can be applied by different methods on the decorative paper web. It is mentioned that the ink receiving composition can be applied, for example, separately or together with a barrier liquid by rolling, spraying, knife coating, blade coating, air brushing, cast coating, film pressing, linen pressing, curtain coating and / or slot die application.
• doctor blades for paper, board, finishing or tissue machines can also be found, for example, in WO 2008/037850 A1 as known.
• doctor blade which has a specific structure in order to be used as long as possible.
• the doctor blade described in this prior publication is arranged so that the free leading end of the doctor rests against a surface of a roller or a cylinder.
• doctor blades described in document WO 2008/037850 A1 can be used differently.
• the doctor blades described can be used, for example, as doctor blades. In this case, the squeegee is directed against the direction of rotation of the roller.
• the doctor blade described in the document can also be used as a coating blade. In this case, the squeegee is directed in the direction of rotation of the roller.
• the present invention assumes that the material web to be printed is to be provided with a primer layer prior to printing.
• a certain pretreatment for a material web to be printed has to be carried out by adding a specific substance in a specific preselected and for the specific printing optimized layer thickness is applied to the later to be printed web.
• a primer layer with an excess amount is initially applied to the printing side of the material web in the context of the invention.
• a so-called doctor blade is used, which is also referred to below as a bladerack.
• This Bladerakel can be adjusted in their distance and preferably in their orientation relative to the passing material web, that the flowable or viscous material of the primer to be used runs on this doctor blade and adhesive only happen in the desired preset layer thickness of the doctor blade on the web to be printed can. The excess material is thus stripped and collected.
• the Bladerakel and especially its tip for example between two spaced rollers (ie generally between two spaced tineline- between which the material web is guided) is arranged so that the tip of the doctor blade lifts off the coated material web in the form of a hydrodynamic high-pressure zone which builds up between the doctor blade and the material web.
• a hydrodynamic high-pressure zone which builds up between the doctor blade and the material web.
• the doctor blade is arranged so that its tip is spaced from the possible deflection rollers, that is outside of the so-called Umschlingungs Kunststoffes on a roller on which the material web rests on the surface of a rotating roller.
• a primer material is used which still has properties defined in the context of the invention with respect to the solids content and with respect to the flow time.
• FIG. 1 shows a schematic side view of a system according to the invention for the pretreatment of a material web to be printed
• Figure 2 an enlarged detail of the doctor blade in its orientation to the material web passed by it.
• FIGS. 1 and 2 show diagrammatically how a material web 1 to be printed is provided with a flowable, i. at least viscous material can be coated.
• the material web 1 may be a film-like material web 1 in a predetermined width.
• the width is matched to the use of conventional printing cylinder of a printing system, not shown in the drawings. This may be, for example, a gravure printing process, an ink-jet printing process, or another common printing process.
• the section of the system shown in the drawings may be part of an entire printing system, since the method according to the invention is preferably carried out in a so-called on-line method, so the material to be printed web continuously and continuously coated first and then printed accordingly.
• the material web to be printed is first pretreated accordingly in the context of the invention and then wound, for example, on a winding station in order to be later printed in a second separate, temporally and optionally spatially separated step.
• the material web mentioned can be, for example, a prepreg paper web, namely preimpregnated decorative paper 1 '.
• a plastic film or plastic film web 1 " which may be monolayer or multilayer material webs, for example those of the decorative paper 1 'lying closer to the printing side 1 a or of a single layer Plastic film 1 "and the other layers of comparable or other materials may include or include.
• a multilayer decorative paper web can also comprise plastic film layers and conversely a plastic film on the side facing away from the pressure, at least one paper layer.
• adhesion promoters or adhesive layers may also be provided between the individual layers. There are no restrictions in this respect.
• Decorative papers are to be understood as meaning all pre-impregnates, film papers, thin foils in a wide variety of colors, etc.
• the material web 1, in particular in the form of decorative paper 1 1 be impregnated with a variety of resin solutions, such as malamine resins and urea resins in a variety of compositions, Kunststoffacrylattagenen (eg Acronal, Aerodur in admixture with various chemical aids), glued papers using starch sizing, AKD sizing or sizing agents in conjunction with acrylates, etc.
• resin solutions such as malamine resins and urea resins in a variety of compositions, Kunststoffacrylatucunane (eg Acronal, Aerodur in admixture with various chemical aids), glued papers using starch sizing, AKD sizing or sizing agents in conjunction with acrylates, etc.
• the preferred application rate of the abovementioned possibilities can be, for example, between 10% and 50% based on the basis weight of the material web 1, in particular the decorative paper web 1 ', the surface dimensions of this material web 1 and in particular the decorative paper web 1' usually between 30 g / m 2 and 100 g / m 2 usually lie or lie.
• Such a material web is moved by means of a suitable drive device using one or more driven rollers and rollers through the plant, wherein so-called tension, support and / or guide rollers are usually used, which are set accordingly in rotation, ie be actively driven.
• tension, support and / or guide rollers are usually used, which are set accordingly in rotation, ie be actively driven.
• idler rolls can also be provided, over which the material web 1 is guided past in a corresponding Umschlingungswinke1 predetermined according to the path of travel, while the corresponding actively non-driven rollers are set in rotation.
• an applicator roller 2 and a tension roller 3 are further provided in the system, between these two rollers 2 and 3 the scraper 4 provided within the scope of the invention, i. the so-called doctor blade or the Bladerakel 4 'is positioned.
• This scraper 4 for example in the form of Bladerakel 4 'is arranged directly in the withdrawal direction A of the material web 1 in front of the traction or drive roller 3, al so before the web 1 touches the peripheral wall 3a of the tension roller 3, ie outside the so-called wrap area on this drive roller 3.
• the application roller 2 is arranged via a primer pan 5, which is filled with the primer material 6 to be used.
• This primer tray 5 is thus located directly below the material web 1 in the withdrawal direction A in front of the doctor blade assembly.
• both tensile and application modules are provided with additional guide or support rollers.
• the mentioned scraper 4 is attached to an adjusting mechanism 7, by means of which a position and / or position adjustment of the scraper 4 and thus, above all, a corresponding adjustment of the doctor blade 44 with respect to the material web 1 can be made.
• Bladerakel 4 can thus by means of Einstellmecha- mechanism 7 against the material web 1, ie in particular the preimpregnated paper web 1' or paper layer 1 1 or a plastic film or plastic film 1 "are set at a suitable angle, ie at a suitable angle to the plane
• This angle ⁇ should preferably be between 25 ° and 75 ° C.
• the angle ⁇ should generally be smaller than 70 °, 65 °, 60 °, 55 °, 50 °, 45 ° or 40 °. In other words, optimum angle ranges are between 35 ° and 55 °, in particular between 40 ° and 50 °, especially around 45 °.
• the film web is supported between two rollers, here between a contact line (parallel to the axis of rotation) on the application roller 2 and on the draw roller 3.
• a corresponding pressure on the Bladerakel indirectly exerted on the web, since between the leading blade 44 and the web 1 still passes through the corresponding primer layer in appropriate thickness.
• the entire arrangement is such that the application roller 2 removes the corresponding primer material from the trough 5 during the rotational movement and deposits it on the printing side 1a of the material web 1, this application taking place on the underside of the material web 1, which in this region is at least is moved approximately horizontally between the rollers 2 and 3, so with at least predominantly horizontally oriented component of motion, so that the run on the Bladerakel 4 'and partially stripped excess primer material of gravity down to run down and collected by a pan collection section 55 and in the tub 5 can be returned.
• the described improved printing results have been achieved, for example, when a Blade 4 has been used, for example, made of stainless steel, plastic or other materials also coated and is designed plate or strip-shaped.
• the plate- or strip-shaped Bladerakel consisting of stainless steel extending perpendicular to the feed movement A of the material web, ie parallel to the respective axis of rotation of the rollers.
• the doctor blade thicknesses that is to say the thickness of the blade blades transversely to their longitudinal extent, can vary within wide ranges, for example between 0.1 mm and 15 mm. Preferred values are above 0.2 mm, 0.3 mm or 0.4 mm or 0.5 mm. Also, preferred values should be less than 15 mm, for example less than 12.5 mm, 10 mm, 7.5 mm or 5 mm. Corresponding values can also be present for the phase width D at the doctor blade cutting edge (FIG. 2).
• standard line speeds with which such decorative paper or decorative film is to be coated with the mentioned primer discussed below can be between 100 m / min to 350 m / min.
• optimum values can also be achieved in intermediate areas, ie even at line speeds greater than 100 m / min, namely, for example, 110 m / min, 120 m / min, 130 m / min, 140 m / min, 150 m / min, 160 m / min, 170 m / min, 180 m / min, 190 m / min, 200 m / min, 210 m / min, 220 m / min, 230 m / min, 240 m / min, 250 m / min.
• the line speeds are preferably not above 350 m / min, for many applications below this value, namely below 340 m / min, 330 m / min, 320 m / min, 310 m / min, 300 m / min, 290 m / min, 280 m / min, 270 m / min, 260 m / min, 250 m / min, 240 m / min, 230 m / min, 220 m / min, 210 m / min or less than 200 m / min.
• the primer solution which is to be used preferably as a layer to be applied.
• the primer material is a water-based synthetic resin or acrylate resin dispersion. In other words, the primer material is not a varnish. Rather, a paint-free primer material is used.
• the primer material should be chosen so that, for example, a viscosity (kinematic at 20 ° C) between 10 sec. to 30 sec. According to DIN standard 53211/4. In other words, the phasing out Time of the primer material (primer solution) from the DIN measuring cup 10 sec. To about 30 sec ..
• the primer material should have pH values which lie between 5 and 9, preferably between 6.5 and 8, in particular around 7.5.
• the primer material may also have a solids content of 20% or more, in particular of at least 25%, 30%, 35%, 40%, 45% or at least 50%. On the other hand, good and sufficient values are obtained even if the solids content is less than or equal to 70%, 65%, 60%, 55%, 50% or less than 45%. A value of 45% to 55% is optimal in many cases.
• the primer material used is miscible with water or soluble in water.
• a preferred primer material should be completely miscible with water or be soluble in water.
• the primer material should have a low solvent content of less than 3%, in particular less than 2%, 1% or even 0.5%.
• the primer material has a flash point above 100 ° C, there are usually no problems if the material should be subjected to a heat treatment before printing.
• a primer material By using such a primer material, it is possible to optimally print a printable web 1, in particular a printable preimpregnated paper layer or a so-called preimpregnated decorative paper, resulting in much better Print results can be achieved, in particular in a gravure printing process (although an ink-jet process o or other printing processes can be considered in principle).
• Water-based gravure inks having a solids content of from 5% to 35%, in particular from 10% to 30%, or from 15% to 25% are preferably used in the subsequent printing mentioned.
• the preferred water-based gravure inks should, for example, have a pH of between 7 and 9, in particular a value of 7.5 to 8.5. Particularly good results can be achieved if the printing inks have a flow speed of 13 sec. up to 30 sec. according to the already described with respect to the primer DIN standard 53211/4. Preferred values are, for example, between 18 sec. To 25 sec.
• the inks may further contain binders.
• the binder of the individual primary colors preferably consists of casein.
• the printing inks may be provided with an admixture of the binder casein or other binders customary in color production.
• the primer it has been explained that, by using the primer, the paper and / or film web to be printed can, above all, also be smoothed. It is also an unevenness in the decorative paper web smoothing layer, which is applied.
• the material used is also a kind of adhesion promoter which serves as a bonding agent for the printing ink to be applied. As a result, the significantly improved printing results can be achieved.

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• Engineering & Computer Science (AREA)
• Manufacturing & Machinery (AREA)
• Application Of Or Painting With Fluid Materials (AREA)
• Laminated Bodies (AREA)
• Paper (AREA)
• Printing Methods (AREA)

Priority Applications (12)

Applications Claiming Priority (2)

Publications (1)

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Family Applications (1)

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Citations (4)

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• 2013
  • 2013-05-03 DE DE102013007602.1A patent/DE102013007602A1/de not_active Withdrawn
• 2014
  • 2014-04-24 ES ES14722551.0T patent/ES2637814T3/es active Active
  • 2014-04-24 WO PCT/EP2014/001100 patent/WO2014177258A1/de active Application Filing
  • 2014-04-24 CN CN201480025133.2A patent/CN105189867B/zh active Active
  • 2014-04-24 PT PT147225510T patent/PT2992142T/pt unknown
  • 2014-04-24 LT LTEP14722551.0T patent/LT2992142T/lt unknown
  • 2014-04-24 JP JP2016510961A patent/JP2016522741A/ja active Pending
  • 2014-04-24 PL PL14722551T patent/PL2992142T3/pl unknown
  • 2014-04-24 US US14/787,128 patent/US20160069028A1/en not_active Abandoned
  • 2014-04-24 BR BR112015026150-7A patent/BR112015026150B1/pt active IP Right Grant
  • 2014-04-24 CA CA2908175A patent/CA2908175A1/en not_active Abandoned
  • 2014-04-24 HU HUE14722551A patent/HUE033174T2/en unknown
  • 2014-04-24 SI SI201430318T patent/SI2992142T1/sl unknown
  • 2014-04-24 RU RU2015146996A patent/RU2661211C2/ru active
  • 2014-04-24 DK DK14722551.0T patent/DK2992142T3/en active
  • 2014-04-24 EP EP14722551.0A patent/EP2992142B1/de active Active

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