WO2014168451A1 - 연성인쇄회로기판의 제조방법 및 이에 의해 제조된 연성인쇄회로기판 - Google Patents
연성인쇄회로기판의 제조방법 및 이에 의해 제조된 연성인쇄회로기판 Download PDFInfo
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- WO2014168451A1 WO2014168451A1 PCT/KR2014/003151 KR2014003151W WO2014168451A1 WO 2014168451 A1 WO2014168451 A1 WO 2014168451A1 KR 2014003151 W KR2014003151 W KR 2014003151W WO 2014168451 A1 WO2014168451 A1 WO 2014168451A1
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- substrate
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- protective coating
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/10—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern
- H05K3/12—Apparatus or processes for manufacturing printed circuits in which conductive material is applied to the insulating support in such a manner as to form the desired conductive pattern using thick film techniques, e.g. printing techniques to apply the conductive material or similar techniques for applying conductive paste or ink patterns
- H05K3/1208—Pretreatment of the circuit board, e.g. modifying wetting properties; Patterning by using affinity patterns
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/22—Secondary treatment of printed circuits
- H05K3/28—Applying non-metallic protective coatings
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/38—Improvement of the adhesion between the insulating substrate and the metal
- H05K3/381—Improvement of the adhesion between the insulating substrate and the metal by special treatment of the substrate
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/46—Manufacturing multilayer circuits
- H05K3/4644—Manufacturing multilayer circuits by building the multilayer layer by layer, i.e. build-up multilayer circuits
- H05K3/4664—Adding a circuit layer by thick film methods, e.g. printing techniques or by other techniques for making conductive patterns by using pastes, inks or powders
Definitions
- the present invention relates to a method for manufacturing a flexible printed circuit board and a flexible printed circuit board manufactured by the same, and more particularly, to a flexible printed circuit board for forming a circuit pattern by printing at a low temperature after printing with a conductive paste and a method of manufacturing the same. will be.
- the present invention is Korean Patent Application No. 10-2013-0040465 filed April 12, 2013, Korea Patent Application No. 10-2013-0040466 filed April 12, 2013 and Korea Patent Application filed April 10, 2014 Claiming the benefit of No. 10-2014-0043073, the entire contents of which are incorporated herein.
- a flexible printed circuit board is a substrate that can be flexibly formed by forming a circuit pattern on a thin insulating film, and is widely used in an automated device or a display product that requires bending and flexibility when using portable electronic devices and mounting.
- the flexible printed circuit board has been widely used in portable terminals such as smart phones and the like, where demand is exploding in recent years.
- flexible printed circuit boards are frequently used in near field communication (NFC) antennas and digitizers of portable terminals.
- NFC near field communication
- the digitizer is applied to a display panel of an electronic device such as a mobile phone, a PDA, a notebook, and the like to recognize and display coordinates of a point where a touch is generated, thereby enabling natural handwriting recognition on the display panel.
- an electronic device such as a mobile phone, a PDA, a notebook, and the like to recognize and display coordinates of a point where a touch is generated, thereby enabling natural handwriting recognition on the display panel.
- the digitizer has recently increased in size in accordance with the size of the display panel because the size of the display panel of a smartphone is gradually increased, and is applied to the development of a tablet PC, a display for outdoor advertising, and the like.
- a flexible printed circuit board is manufactured by etching copper foil laminated on a flexible substrate, or by printing a circuit pattern on a flexible insulating film with a conductive paste or a conductive ink and then plating the circuit pattern.
- the present invention has been made in view of the above, and provides a method for manufacturing a flexible printed circuit board which ensures dimensional stability through the line heat treatment of the substrate and improves the reliability of the operation, and a flexible printed circuit board manufactured thereby. There is a purpose.
- Another object of the present invention is to ensure that the filling amount of the via hole is secured to a stable level so that one surface pattern and the other surface pattern of the substrate can be electrically connected, and to increase the adhesion between the substrate and the conductive paste to solve the problem of peeling the pattern A method of manufacturing a substrate and a flexible printed circuit board manufactured thereby.
- a method of manufacturing a flexible printed circuit board comprising: heating a substrate and performing thermal deformation;
- the substrate may be a polyimide (PI) film or a PET film.
- PI polyimide
- the conductive paste may be a silver paste including silver powder, polymer resin, and solvent.
- the step of firing the circuit pattern may be baked at 200 ° C to 450 ° C.
- the linear thermal deformation may heat the substrate to a temperature higher than or equal to the firing temperature of the firing of the circuit pattern.
- the step of heating the line-deformed substrate by removing the moisture in the substrate by heating the line-deformed substrate before the step of forming the circuit pattern with the conductive paste after the step of thermal deformation may further include.
- the method of manufacturing a flexible printed circuit board according to an embodiment of the present invention further includes forming a protective coating layer protecting the circuit pattern by applying a coating solution to one surface of the substrate which has been subjected to the step of firing the circuit pattern. can do.
- the protective coating layer in the present invention by applying a coating solution on one surface of the substrate to form a protective coating layer, it may be dried to form the protective coating layer.
- the protective coating layer may be formed to cover the circuit pattern to a thickness of at least 9 ⁇ m.
- the forming of the protective coating layer may be performed by screen printing the coating liquid on one surface of the substrate and adjusting the coating thickness of the coating liquid by the mesh size of the screen.
- Method of manufacturing a flexible printed circuit board according to an embodiment of the present invention, forming a circuit pattern with a conductive paste on the protective coating layer; And firing the other circuit pattern.
- a method of manufacturing a flexible printed circuit board comprising: forming a via hole in the linearly deformed substrate by performing the linear thermal deformation; And filling the via hole with a conductive paste.
- the method of manufacturing a flexible printed circuit board according to an embodiment of the present invention may further include laminating a carrier on the other surface of the substrate between the forming of the via hole and the filling of the via hole.
- the method of manufacturing a flexible printed circuit board according to an embodiment of the present invention may further include a corona treatment step for modifying the surface of the substrate before the forming of the circuit pattern with the conductive paste.
- Forming the circuit pattern in the method of manufacturing a flexible printed circuit board according to an embodiment of the present invention the process of forming a first circuit pattern with a conductive paste on one surface of the substrate; And forming a second circuit pattern with a conductive paste on the other surface of the substrate.
- Method of manufacturing a flexible printed circuit board after forming the first circuit pattern on one surface of the substrate and removing the carrier from the other surface of the substrate; Laminating a carrier to one surface of the substrate before forming the second circuit pattern; And removing the carrier from one surface of the substrate after forming the second circuit pattern.
- the first circuit pattern is an X-axis coordinate recognition pattern unit having a plurality of spaced X-axis electrodes
- the second circuit pattern is a Y-axis coordinate recognition pattern unit having a plurality of Y-axis electrodes spaced apart Can be.
- the carrier may use wet paper.
- the method of manufacturing a flexible printed circuit board according to an embodiment of the present invention further includes forming a protective coating layer protecting the circuit pattern by applying a coating solution to one surface of the substrate which has been subjected to the step of firing the circuit pattern.
- the forming of the protective coating layer may include forming a first protective coating layer on one surface of the substrate by applying a coating solution to one surface of the substrate; And forming a second protective coating layer on the other surface of the substrate by applying a coating solution to the other surface of the substrate.
- the method of manufacturing a flexible printed circuit board according to an embodiment of the present invention may further include curing the first protective coating layer and the second protective coating layer by heating.
- the curing may include curing the first protective coating layer and the second protective coating layer at 200 ° C to 450 ° C.
- the method of manufacturing a flexible printed circuit board according to an embodiment of the present invention further includes a corona treatment step for modifying the surface of the substrate before the forming of the circuit pattern with the conductive paste, wherein the corona treatment step
- the method may include: corona-processing one surface of the substrate before the forming of the first circuit pattern; And corona treating the other surface of the substrate before the forming of the second circuit pattern.
- a flexible printed circuit board according to an embodiment of the present invention, the substrate; And a circuit pattern formed by firing the conductive paste on the substrate, wherein the substrate is thermally deformed so that the amount of shrinkage change before and after firing the conductive paste is zero.
- the flexible printed circuit board according to the exemplary embodiment of the present invention may further include a protective coating layer for protecting the circuit pattern formed on the substrate.
- the substrate is a PI film or PET film
- the protective coating layer may be a coating layer formed of a PI solution or a PAI solution.
- the flexible printed circuit board according to an embodiment of the present invention further includes other circuit patterns stacked sequentially on the protective coating layer, and the protective coating is interposed between the other circuit patterns, respectively, of each layer.
- the circuit patterns may be connected by vias formed in the protective coating layer.
- the circuit pattern may include a first circuit pattern formed on one surface of the substrate and a second circuit pattern formed on the other surface of the substrate.
- a flexible printed circuit board includes a first protective coating layer formed on one surface of the substrate; And a second protective coating layer formed on the other surface of the substrate.
- the first circuit pattern may be an X-axis coordinate recognition pattern unit having a plurality of spaced apart X-axis electrodes
- the second circuit pattern may be a Y-axis coordinate recognition pattern unit having a plurality of spaced Y-axis electrodes.
- the present invention can secure the dimensional stability when firing the circuit pattern printed with the conductive paste through the preheating treatment of the substrate, prevents the lowering of the adhesion force between the circuit pattern and the substrate due to the deformation of the film during firing and the adhesion of the circuit pattern It is effective to maintain a stable even after firing.
- the present invention has the effect of stably filling the conductive paste in the via hole to improve the operation reliability of the circuit pattern formed on both sides of the substrate.
- the present invention protects the circuit pattern with a coating layer to prevent damage to the circuit pattern by bending or bending during use, and has the effect of keeping the circuit pattern firmly attached to the substrate.
- FIG. 1 is a process diagram showing an embodiment of a method of manufacturing a flexible printed circuit board according to the present invention.
- Figure 2 is a schematic diagram showing an embodiment of a method of manufacturing a flexible printed circuit board according to the present invention
- FIG. 3 is a process diagram showing another embodiment of a method of manufacturing a flexible printed circuit board according to the present invention.
- Figure 4 is a schematic diagram showing another embodiment of a method of manufacturing a flexible printed circuit board according to the present invention
- Figure 5 is a cross-sectional view showing a via hole in the method of manufacturing a flexible printed circuit board according to the present invention.
- FIG. 6 is a process diagram showing another embodiment in the method of manufacturing a flexible printed circuit board according to the present invention.
- FIG. 10 is a cross-sectional view showing an example of a flexible printed circuit board according to the present invention.
- FIG. 11 is a cross-sectional view showing another example of a flexible printed circuit board according to the present invention.
- FIGS. 1 and 2 are process diagrams showing an example of a method of manufacturing a flexible printed circuit board according to the present invention. Referring to FIGS. 1 and 2, a method of manufacturing a flexible printed circuit board according to an embodiment of the present invention is described. Heating the substrate 10 to deform the line thermally (S100), forming a circuit pattern 20 using conductive paste on the linearly deformed substrate 10 (S200), and firing the circuit pattern 20. (S300).
- the substrate 10 may be a substrate 10, such as PI film, PET film, polyester film, it is preferably a polyimide (PI) film.
- PI polyimide
- the polyimide film is inexpensive, has excellent heat resistance, can be baked at a temperature of 200 ° C. to 450 ° C., and is thin and excellent in flexibility.
- the linear thermal deformation step (S100) improves the dimensional stability of the substrate 10 by thermal treatment to prevent deformation of the substrate 10 during the firing process.
- the circuit pattern 20 is formed on the one surface of the substrate 10 subjected to the linear thermal deformation in step S100 by using conductive paste.
- the circuit pattern 20 (S200) it is preferable to form the circuit pattern 20 on one surface of the substrate 10 by using a predetermined circuit through screen printing.
- Forming the circuit pattern 20 (S200) includes a process of drying the printed conductive paste, and the drying of the conductive paste may be performed at a temperature of 80 ° C. or less.
- the conductive paste includes a conductive metal powder and a binder.
- the conductive metal powder may be one selected from silver, copper, aluminum and nickel, or a mixture of two or more selected.
- the said conductive paste is silver paste containing silver powder, a polymer resin, and a solvent.
- the silver paste includes 73 wt% to 88 wt% of silver powder, 5.9 wt% to 9.5 wt% of polymer resin, and 5.7 wt% to 18.0 wt% of solvent.
- the silver paste may further include 0.35 wt% to 2.90 wt dispersant.
- the polymer resin includes a polyester-based resin and has an molecular weight of 25,000 as an example.
- the silver powder is an example that the particle size is 50nm ⁇ 5 ⁇ m, preferably 0.5 ⁇ 1.2 ⁇ m.
- the silver powder has a problem that it is difficult to achieve resistance of 30 ⁇ or less, preferably 23 ⁇ or less, in the silver powder of more than 5 ⁇ m because the silver powder has a small particle size to move well in printing and the silver powder adheres to each other during firing.
- the conductive paste may be a conductive powder, that is, one selected from silver, copper, aluminum, and nickel, or a mixture of two or more selected.
- the screen printing is suitable for the formation of a fine pattern because of the fast curing speed and excellent adhesion and flexibility, it is possible to form a pre-designed coordinate input circuit pattern at a low cost.
- the step of firing the circuit pattern 20 is to fire the circuit pattern 20 formed of the silver paste on the substrate 10 at 200 °C ⁇ 450 °C, preferably from 290 °C to 420 °C Fire.
- the firing temperature of 290 ° C to 420 ° C is a temperature range in which the circuit pattern 20 can be stably fired without deformation or damage to the synthetic resin film, ie, the polyimide film, which is the substrate 10 of the flexible printed circuit board. It is a temperature range in which the circuit pattern 20 printed and baked with a paste has a specific resistance value within a predetermined range, and the adhesion force of the circuit pattern 20 is higher than or equal to the reference.
- Firing is intended to improve electrical conductivity due to grain growth between silver powders, and to improve adhesion between the conductive material and the substrate 10 filled in the via holes to be described later.
- the conductive powder (silver powder) printed and dried on the substrate 10 may generate an interface separation with the substrate 10 or may cause cracks.
- the substrate 10 may be carbonized.
- firing is carried out in a temperature range of 300 ⁇ 450 °C.
- the circuit pattern 20 is formed to have a specific resistance value of 4.0 ⁇ ⁇ cm or more and 6.5 ⁇ ⁇ cm or less.
- the linear thermal deformation step S100 may be performed by linearly deforming the substrate 10, that is, the polyimide film, at a temperature higher than or equal to the firing temperature of the step S300 of firing the circuit pattern 20. In step S300 of firing the pattern 20, the deformation of the polyimide film is prevented.
- the firing temperature is preset by the type of the flexible printed circuit board to be manufactured in the step of firing the circuit pattern 20, the composition of the conductive paste, the specific resistance value required by the circuit pattern 20, and the like.
- the linear thermal deformation step S100 is to linearly deform the substrate 10 by heating the substrate 10 to a temperature higher than or equal to the firing temperature set in the step S300 of firing the circuit pattern 20.
- Tables 1 to 3 below show the shrinkage change rate after heat treating the polyimide film at 400 ° C. for 7 hours according to thickness and size, and heating the preheated polyimide film to 350 ° C., which is a firing temperature.
- Table 1 below is an example of a 1/2 mill thick polyimide film.
- Table 2 below is an example of 1 mill thick polyimide film.
- Table 3 below is an example of a 2 mill thick polyimide film.
- the polyimide film is linearly deformed before firing, thereby preventing shrinkage deformation of the polyimide film during firing of the circuit pattern 20. Accordingly, the dimensional stability of the substrate 10 is secured to accurately position the circuit pattern 20 at a predesigned position, and the circuit pattern 20 is deformed by the deformation of the substrate 10 generated during firing. The fall of the adhesion which adheres to (10) is prevented.
- the polyimide film wound and stored in a roll shape is heated in a box-type heating furnace to thermally treat a large amount of polyimide film at a time and in roll form. It is preferable to allow the step of forming the circuit pattern 20 through the roll-to-roll method of the wound and preheated polyimide film (S200), and the step of firing the circuit pattern 20 (S300).
- the method of manufacturing a flexible printed circuit board according to the present invention preferably further includes a baking step (S110) of heating the linearly deformed substrate 10 to remove moisture in the substrate 10.
- the baking step (S110) the moisture is absorbed into the substrate 10 during long-term storage after the substrate 10 is thermally deformed, so that the substrate 10 is heated in a temperature range of 80 °C ⁇ 150 °C the substrate Moisture contained in (10) is removed.
- the baking step (S110) is performed before the step (S200) of forming the circuit pattern 20, and baking the circuit pattern 20 by heating and removing moisture contained in the substrate 10 during storage.
- step S300 shrinkage deformation caused by moisture included in the substrate 10 is prevented.
- the polyimide film since the polyimide film has a property of absorbing moisture during storage, it is preferable to perform the step S200 of forming the circuit pattern 20 after the baking step S110.
- the protection of protecting the circuit pattern 20 by applying a coating solution to one surface of the substrate 10 through the step of firing the circuit pattern 20 (S300). It is preferable to further include forming a coating layer 30 (S400).
- the coating liquid is applied to one surface of the substrate 10 to form the protective coating layer 30, and dried to form the protective coating layer 30.
- the coating solution is a solution of PI (polyimide), PI is a solution containing 15 ⁇ 35wt%, the PI is dissolved in a solvent, the solvent is an example of dilution of NMP.
- the coating solution may be a PAI solution, and the protective coating layer 30 may be formed by applying the PAI solution.
- Forming the protective coating layer 30 (S400) is dried by heating the coating solution applied to one surface of the substrate 10 at 90 ⁇ 150 °C 5 to 25 minutes.
- the protective coating layer 30 is preferably formed to cover the circuit pattern 20 to a thickness of at least 9 ⁇ m, more preferably has a thickness of 10 ⁇ m or more. This is the minimum thickness that can serve as an insulating layer to insulate the circuit pattern 20.
- the coating liquid may be applied to one surface of the substrate 10 by screen printing, and the coating thickness of the coating liquid may be adjusted by the mesh size of the screen during screen printing.
- the protective coating layer 30 should be formed to have a thickness of at least 9 ⁇ m above the circuit pattern 20, when the thickness of the circuit pattern 20 is 10 ⁇ m more than 19 ⁇ m on one surface of the substrate 10 When the thickness of the circuit pattern 20 is 15 ⁇ m, the thickness of the circuit pattern 20 is preferably 24 ⁇ m or more.
- the protective coating layer 30 is preferably formed by one screen printing to simplify the process and reduce the manufacturing cost, the screen has a 40 ⁇ 70 mesh per unit area (inch 2 ). This means having 40 to 70 meshes per unit area (inch 2 ).
- the protective coating layer 30 protects the circuit pattern 20 formed on one surface of the substrate 10, and allows the circuit pattern 20 to be more firmly attached to the substrate 10, The circuit pattern 20 is prevented from being separated from the substrate 10 even in the bending deformation of the substrate 10.
- the protective coating layer 30 forms an insulating layer covering the circuit pattern 20 on one surface of the substrate 10 so as to easily form a multilayer circuit.
- Method of manufacturing a flexible printed circuit board according to the present invention comprises the steps of forming another circuit pattern (20a) with a conductive paste on one surface of the protective coating layer (30); And
- the method may further include firing the other circuit pattern 20a (S600).
- the step of forming the other circuit pattern 20a is the same as the embodiment of the step of forming the circuit pattern 20 (S200) and will be omitted as a redundant description.
- the step S600 of firing the other circuit pattern 20a is the same as the embodiment of the step S300 of firing the circuit pattern 20, and thus, a duplicate description thereof will be omitted.
- the protective coating layer 30 is cured together with the firing of the other circuit pattern 20a.
- the other circuit pattern 20a is electrically connected to the circuit pattern 20, and in step S400 of forming the protective coating layer 30, the other circuit pattern 20a and the circuit pattern 20 are electrically connected. Except for the portion connected to the protective coating layer 30, and forming the other circuit pattern (20a) (S500), while forming the other circuit pattern 20a with a conductive paste through screen printing For example, the other circuit pattern 20a and the protective coating layer 30 are electrically connected to each other. That is, when the other circuit pattern 20a is formed of the conductive paste, the conductive paste is filled with portions excluded from the protective coating layer 30 for electrical connection, so that the other circuit pattern 20a and the circuit pattern 20 are formed. ) Is electrically connected.
- a via hole may be formed in the protective coating layer 30 by drilling, and the conductive paste may be filled in the via hole to electrically connect the other circuit pattern 20a and the circuit pattern 20.
- a method of manufacturing a flexible printed circuit board according to the present invention includes: forming a via hole in the substrate 10 in which the thermal deformation is performed in step S100; Filling the via hole with a conductive paste (S140) further.
- the baking step (S110) may be performed, and the baking step (S110) is the same as the above embodiment, and thus the overlapping description will be omitted.
- the via hole is formed at a required portion of the substrate 10, that is, according to a predetermined circuit design, using a drill or a laser.
- the via hole is formed to electrically connect the first circuit pattern 21 formed on one surface of the substrate 10 and the second circuit pattern 22 formed on the other surface of the substrate 10.
- the conductive paste is filled in the via hole to electrically connect the first circuit pattern 21 and the second circuit pattern 22 formed on the other surface of the substrate 10.
- a via hole is formed in the substrate 10, the carrier 40 is laminated on the other surface of the substrate 10, and the via hole portion is printed by conductive paste on one surface of the substrate 10. Fill the paste.
- the carrier 40 allows the conductive paste to be stably filled in the via hole.
- the carrier 40 may block and absorb the conductive paste flowing through the via hole to the other surface side of the substrate 10 so that the conductive paste remains only up to the via hole. This prevents the conductive paste from being contaminated and the short caused by the conductive paste flowing out to the other surface side of the substrate 10.
- the carrier 40 may use an absorbent paper, preferably wet paper.
- the wet paper has a low density so that the conductive paste is well absorbed between the pores.
- An adhesive is attached to the carrier 40, so that the carrier 40 may be easily laminated with the substrate 10.
- the carrier 40 may be laminated or removed from the other surface or one surface of the substrate 10 in a roll to roll manner.
- the roll-to-roll method is a continuous process of forming a pattern by laminating the carrier 40 while unwinding the substrate 10 wound on the roll and printing a conductive paste on the opposite side of the carrier 40 on which the carrier 40 is laminated. .
- the roll-to-roll method is a method capable of mass production and reduce the production cost.
- Forming the circuit pattern 20 may include forming a first circuit pattern 21 with a conductive paste on one surface of the substrate 10 (S210); And
- the first circuit pattern 21 and the second circuit pattern 22 are electrically connected to each other through a conductive paste filled in the via hole.
- Forming the first circuit pattern 21 (S210) and forming the second circuit pattern 22 (S220) respectively include drying the conductive paste, and drying the conductive paste.
- the process can be carried out at temperatures of up to 80 ° C.
- the via hole is pre-filled with a conductive paste on one surface of the substrate 10 before the forming of the first circuit pattern 21. Allow the paste to be completely filled.
- the via hole may be filled with the conductive paste on one side of the substrate 10 in the filling of the via hole (S140), and the conductive paste may not be partially filled on the other side of the substrate 10. .
- the portion of the via hole which is not filled with the conductive paste on the other surface side of the substrate 10 is filled in the process of forming the second circuit pattern 22 (S220), and the inside of the via hole is filled with the conductive paste. Therefore, the first circuit pattern 21 and the second circuit pattern 22 are electrically and stably connected to improve operation reliability.
- the method may further include removing the carrier 40 from one surface of the substrate 10 (S221).
- the carrier 40 blocks the via hole on one surface of the substrate 10 so that the conductive paste is stably filled in the via hole.
- the conductive paste filled in the via hole is prevented from flowing out to one surface side of the substrate 10.
- the carrier 40 allows the conductive paste to be stably filled in the via hole.
- the carrier 40 may block and absorb the conductive paste flowing through the via hole to one side of the substrate 10 so that the conductive paste remains only up to the via hole. This prevents the conductive paste from being contaminated and the short caused by the conductive paste flowing out to one side of the substrate 10.
- the first circuit pattern 21 is an X-axis coordinate recognition pattern unit having a plurality of spaced X-axis electrodes
- the second circuit pattern 22 is a Y-axis coordinate recognition having a plurality of Y-axis electrodes spaced apart.
- the pattern part is taken as an example.
- the X-axis coordinate recognition pattern portion is formed on one surface, and the Y-axis coordinate recognition pattern portion is formed on the other surface. .
- the X-axis coordinate recognition pattern portion and the Y-axis coordinate recognition pattern portion are energized with each other through the via hole.
- the circuit pattern 20 may be formed in a grid shape having a plurality of X-Y coordinates on one surface and the other surface of the substrate 10.
- the step of firing the circuit pattern 20 is performed (S300).
- the first circuit pattern 21 and the second circuit pattern 22 are fired.
- a coating solution is applied to one surface of the substrate 10 to form a first protective coating layer 31, and then dried to form the first protective coating layer 31. To form.
- a coating solution is applied to one surface of the substrate 10 to form a first protective coating layer 31, and then dried to form the first protective coating layer 31. To form.
- the coating solution is a solution of PI (polyimide), PI is a solution containing 15 ⁇ 35wt%, the PI is dissolved in a solvent, the solvent is an example of dilution of NMP.
- the coating solution may be a PAI solution, and may be coated with the PAI solution to form the protective coating layer.
- the coating solution applied to one surface of the first substrate 10 and the other surface of the substrate 10 is dried by heating for 5 to 25 minutes at 90 to 150 °C, respectively, the first protective coating layer 31 and the second protective coating layer To form 32.
- the method of manufacturing a flexible printed circuit board according to the present invention further includes a step (S700) of heating and curing the first protective coating layer 31 and the second protective coating layer 32.
- the first protective coating layer 31 and the second protective coating layer 32 is cured by heating 20 to 50 minutes at 200 °C ⁇ 450 °C.
- the first protective coating layer 31 and the second protective coating layer 32 cured by the curing step (S700) is the first circuit pattern 21 and the second by the bending deformation of the substrate 10.
- the separation of the circuit pattern 22 is prevented, and the adhesion between the first circuit pattern 21 and the second circuit pattern 22 is enhanced.
- the method may further include a via hole filling step of filling the via hole on the other surface of the substrate 10 before forming the second circuit pattern 22.
- the drying of the conductive paste filled in the via hole may be performed at a temperature of 80 ° C. or less.
- the conductive paste filled in the via hole is in a state in which the top and bottom are concave by gravity during the drying process.
- One filling of the via hole may result in insufficient filling of the via hole, which may cause operational reliability problems when the first circuit pattern 21 and the second circuit pattern 22 are connected.
- the conductive paste is dried, the shape filled in the via hole by gravity changes to a concave shape. Therefore, the process of filling the via hole twice is necessary to secure the reliability of the via hole.
- the conductive paste is filled once in the via hole by filling the via hole before printing the first circuit pattern 21 on one surface of the substrate 10, and the second circuit pattern 22 on the other surface of the substrate 10.
- the via hole is filled twice before printing, and the conductive paste is filled into the via hole twice.
- the conductive paste is stably filled in the via hole 11, and the connection reliability of one surface pattern and the other surface pattern of the insulating film through the via hole is secured.
- the step of firing the circuit pattern 20 (S300), the process of firing the first circuit pattern 21 and the process of firing the second circuit pattern 22. can do.
- the second circuit pattern with the conductive paste on the other surface of the substrate 10. (22) is printed followed by the steps of Secondary Drying-Secondary Sintering. As a result, an amount of conductive paste filled in the via hole is secured, and operation reliability of the first circuit pattern 21 and the second circuit pattern 22 electrically connected through the via hole is secured.
- the process of firing the first circuit pattern 21 is for fixing the shape of the conductive paste in the insulating film from which the carrier 40 is dried and removed.
- the dried conductive paste is sintered, the shape in which the conductive paste is filled in the via hole is maintained and no further shrinkage occurs.
- the conductive paste is stably filled in the via hole, and interface separation with the substrate 10 and crack generation are prevented.
- the upper and lower portions of the conductive paste filled in the via holes are slightly recessed and concave than the primary drying.
- the sintered conductive paste does not cause any further shrinkage, and thus it is easy to secure the conductive paste filling amount of the via hole.
- the conductive paste is filled once in the via hole so that the conductive paste is filled in the via hole, and the second surface of the substrate 10 is filled in the second surface.
- the conductive paste is filled twice in the via hole so that the conductive paste 19 is filled in the via hole when printing the circuit pattern 22.
- the conductive paste is stably filled in the via hole, and electrically connects the first circuit pattern 21 and the second circuit pattern 22 of the substrate 10 through the via hole to be stable. Operational reliability of the pattern 21 and the second circuit pattern 22 is secured.
- the method of manufacturing a flexible printed circuit board according to the present invention further includes a corona treatment step (S131) for modifying the surface of the substrate 10 before the step of forming the circuit pattern 20.
- the corona processing step (S131) may include: corona-processing one surface of the substrate 10 before forming the first circuit pattern 21 (S132); And
- corona treatment of the other surface of the substrate 10 may be included (S213).
- the corona treatment step (S131) is for surface modification of the entire surface of the substrate 10 or a portion where the pattern is to be formed.
- the surface modification may be formed by any one of plasma treatment, corona treatment, laser treatment, etching treatment, and physical treatment. Of these, corona treatment having a short treatment time and excellent workability is most preferred.
- Corona treatment increases the adhesion between the substrate 10 and the conductive paste by performing modification of the surface of the substrate 10 without damaging the shrinkage, deformation, or the like of the substrate 10.
- Corona treatment of one surface of the substrate 10 may be performed after laminating the carrier 40 to the substrate 10 and filling the via hole (S140). After the conductive paste is filled in the via hole, a drying step for drying the conductive paste 15 filled in the via hole may be performed. If the drying is performed after the corona treatment, the effect of the corona treatment is halved. Therefore, it is most preferable to perform the first corona treatment after filling conductive vias in the via holes and to continuously print the conductive paste 15 on the substrate 10 to form a pattern, thereby improving the effect of the corona treatment. .
- the via hole is filled together when the second circuit pattern 22 is printed without the step of filling the via hole (S140). It is preferable to form the second circuit pattern 22 by laminating the carrier 40 on the other side of the substrate, and then corona treatment and printing the conductive paste.
- Corona treatment is most preferred in the case of the present invention, but instead of the corona treatment, plasma treatment may be performed on the entire surface or the pattern forming portion of the substrate 10 to form fine irregularities, thereby improving adhesion between the conductive paste and the substrate 10.
- a silver paste containing silver powder having a particle size of 50 nm to 5 ⁇ m and a polymer resin binder was printed on one side and via holes of the insulating film and the other side and via holes of the insulating film. Then, the insulating film printed with the conductive paste was dried at room temperature, and then heat-treated at a temperature range of less than 200 ° C and a temperature range of 300 to 450 ° C.
- the thermal analysis showed that the thermal decomposition temperature of the polymer resin binder present in the silver paste was completed at around 350 ° C., and only the polymer resin binder was analyzed after separating the silver powder from the silver paste. The same was true for the results.
- the adhesion strength between the insulating film and the silver paste is realized because the firing process is completed before the polymer resin is completely pyrolyzed. Able to know.
- the conductive paste for pattern printing was used including silver powder having a particle size of 200nm ⁇ 2 ⁇ m and a polymer resin binder, sintering was carried out at a temperature range of 200 ⁇ 450 °C.
- EDX analysis of the component after sintering the silver paste according to the present invention confirmed the pure silver (Ag) composition without the inorganic additives, and it was confirmed that particles between the silver powders grew after sintering, and the silver powder was spherical. .
- the conductive paste for printing the circuit pattern 20 used was one containing a silver powder and a polymer resin binder having a particle size of 50nm ⁇ 5 ⁇ m, sintering was carried out at a temperature range of 200 ⁇ 450 °C.
- silver powder is confirmed by the composition which the powder of about 1 micrometer and the powder of about 500 nm are mixed.
- the resistance value can be realized even in the sintering of 200 ⁇ 450 °C by using the powder around 500nm.
- the particle size of the silver powder distributed as a whole was found to be mixed at 200 to 300 nm, 400 to 500 nm, and 800 to 1500 nm.
- the resistance and specific resistance of the flexible printed circuit board manufactured according to the present invention were measured.
- Table 4 measures the specific resistance after sintering of the silver paste.
- Silver paste was used to include a silver powder and a polymer resin binder having a particle size of 200nm ⁇ 500nm, sintering was carried out at a temperature range of 330 °C.
- Table 5 measures the specific resistance after drying at room temperature of silver paste.
- the nano silver paste implements a resistance value close to the specific resistance in the solid state.
- the low resistance means that the coordinate recognition device having excellent electrical conductivity can be manufactured using only silver paste.
- the flexible printed circuit board according to the present invention, the substrate 10;
- a circuit pattern 20 is formed by baking a conductive paste on the substrate 10, and further includes a protective coating layer 30 for protecting the circuit pattern 20 formed on the substrate 10.
- the substrate 10 is used in which the shrinkage change amount is 0 before and after firing the conductive paste and is thermally treated at a temperature higher than the temperature at which the conductive paste is baked with a PI film or PET film. Yes.
- the circuit pattern 20 is baked by applying a conductive paste, that is, a silver face, and the protective coating layer 30 is formed by applying a coating solution, drying and curing.
- the substrate 10 and the conductive paste are the same as the above embodiment and are omitted as duplicated substrates.
- the protective coating layer 30 is preferably a coating layer formed of a PI solution or a PAI solution, which is for maximizing adhesion through integration with the PI film or PET film in using the PI film as the substrate 10. .
- the flexible printed circuit board according to the present invention preferably further includes another circuit pattern 20a formed on the protective coating layer 30.
- the other circuit pattern 20a is electrically connected to the circuit pattern 20 and forms a multilayer circuit structure.
- the other circuit pattern 20a is sequentially stacked on the protective coating layer 30, and the protective coating layer 30 is interposed between the other circuit patterns 20a, and the other circuit of each layer is formed.
- the pattern 20a is connected by vias formed in the protective coating layer 30.
- the circuit pattern 20 includes a first circuit pattern 21 formed on one surface of the substrate 10 and a second circuit pattern 22 formed on the other surface of the substrate 10. ).
- the protective coating layer 30 is a first protective coating layer 31 formed on one surface of the substrate 10; And a second protective coating layer 32 formed on the other surface of the substrate 10.
- the first circuit pattern 21 is an X-axis coordinate recognition pattern unit having a plurality of spaced X-axis electrodes
- the second circuit pattern 22 is a Y-axis coordinate recognition having a plurality of Y-axis electrodes spaced apart.
- the pattern part is taken as an example.
- a via hole is formed to electrically connect the first circuit pattern 21 and the second circuit pattern 22.
- a conductive paste is filled in the via hole to be fired to form the first circuit pattern ( 21 and the second circuit pattern 22 are electrically connected to each other.
- the present invention can secure the dimensional stability when firing the circuit pattern 20 printed with a conductive paste through the preheating treatment of the substrate 10, the circuit pattern 20 and the substrate (10) by deformation of the film during firing ) And the adhesion force of the circuit pattern 20 can be stably maintained even after firing.
- the conductive paste is stably filled in the via hole, thereby improving the operational reliability of the circuit pattern 20 formed on both surfaces of the substrate 10.
- the present invention protects the circuit pattern 20 with a coating layer to prevent the circuit pattern from being damaged by being bent or bent during use, and has the effect of keeping the circuit pattern firmly attached to the substrate 10.
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- Microelectronics & Electronic Packaging (AREA)
- Manufacturing Of Printed Wiring (AREA)
Abstract
Description
필름의 두께 | 필름크기(mm) | 선열처리후 필름 수축 변화량(400℃ 7시간) | 소성온도(350℃ 30분) 수축량 | 누적 수축 변화량 |
1/2밀(mill) | 287 | -1.8(0.63%) | 0 | -1.8(0.63%) |
309 | -1.5(0.49%) | 0 | -1.5(0.49%) | |
250 | -0.5(0.2%) | 0 | -0.5(0.2%) | |
229 | -1.0(0.44%) | 0 | -1.0(0.44%) |
필름의 두께 | 필름크기(mm) | 선열처리후 필름 수축 변화량(400℃ 7시간) | 소성온도(350℃ 30분) 수축량 | 누적 수축 변화량 |
1밀(mill) | 291 | -2.0(0.69%) | 0 | -2.0(0.69%) |
310 | -2.5(0.81%) | 0 | -2.5(0.81%) | |
250 | -1.5(0.60%) | 0 | -1.5(0.60%) | |
233 | -1.3(0.56%) | 0 | -1.3(0.56%) |
필름의 두께 | 필름크기(mm) | 선열처리후 필름 수축 변화량(400℃ 7시간) | 소성온도(350℃ 30분) 수축량 | 누적 수축 변화량 |
2밀(mill) | 286 | -2.5(0.87%) | 0 | -2.5(0.87%) |
306 | -3.7(1.21%) | 0 | -3.7(1.21%) | |
250 | -2.0(0.80%) | 0 | -2.0(0.80%) | |
227 | -2.0(0.88%) | 0 | -2.0(0.88%) |
구분 | 패턴(Line) | 측정저항 | 비저항 | ||
폭 | 두께 | 길이 | 18.5Ω | 5.69×10-6Ω㎝ | |
나노 은페이스트 | 204㎛ | 18㎛ | 1.2m |
구분 | 비저항 |
마이크로(Micro) 은페이스트 | 5.4×10-5Ω㎝ |
나노(Nano) 은페이스트 | 4.5×10-5Ω㎝ |
하이브리드(Micro+Nano) 은페이스트 | 2.5×10-5Ω㎝ |
Claims (30)
- 기재를 가열하여 선열변형시키는 단계;선열변형된 상기 기재에 도전성 페이스트로 회로패턴을 형성하는 단계; 및상기 회로패턴을 소성하는 단계를 포함한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제1항에 있어서,상기 기재는 폴리이미드(PI)필름 또는 PET필름인 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제1항에 있어서,상기 도전성 페이스트는 은분말과, 폴리머레진, 솔벤트를 포함한 은페이스트인 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제1항에 있어서,상기 회로패턴을 소성하는 단계는 200℃ ~ 450℃로 소성하는 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제1항에 있어서,상기 선열변형시키는 단계는 상기 회로패턴을 소성하는 단계의 소성 온도보다 높거나 동일한 온도로 상기 기재를 가열하는 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제1항에 있어서,상기 선열변형시키는 단계 후 상기 회로패턴을 형성하는 단계 전에 상기 선열변형된 기재를 가열하여 기재 내 수분을 제거하는 베이킹 단계를 더 포함하는 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제1항에 있어서,상기 회로패턴을 소성하는 단계를 거친 상기 기재의 일면에 코팅액을 도포하여 상기 회로패턴을 보호하는 보호코팅층을 형성하는 단계를 더 포함하는 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제7항에 있어서,상기 보호코팅층을 형성하는 단계는, 상기 기재의 일면에 코팅액을 도포하여 보호코팅층을 형성하고, 건조하여 상기 보호코팅층을 형성한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제7항에 있어서,상기 보호코팅층은 상기 회로패턴을 적어도 9㎛ 이상의 두께로 덮도록 형성되는 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제7항에 있어서,상기 보호코팅층을 형성하는 단계는 상기 기재의 일면에 코팅액을 스크린 인쇄로 도포하며, 스크린의 메쉬크기로 상기 코팅액의 도포 두께를 조절하는 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제7항에 있어서,상기 보호코팅층 위에 도전성 페이스트로 다른 회로패턴을 형성하는 단계; 및상기 다른 회로패턴을 소성하는 단계를 더 포함한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제1항에 있어서,상기 선열변형시키는 단계로 선열변형된 상기 기재에 비아홀을 형성하는 단계; 및도전성 페이스트로 상기 비아홀을 충진하는 단계를 더 포함한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제12항에 있어서,상기 비아홀을 형성하는 단계와 상기 비아홀을 충진하는 단계 사이에 상기 기재의 타면에 캐리어를 합지하는 단계를 더 포함하는 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제1항에 있어서,상기 회로패턴을 형성하는 단계 이전에 상기 기재의 표면을 개질하는 단계를 더 포함한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제13항에 있어서,상기 회로패턴을 형성하는 단계는,상기 기재의 일면에 도전성 페이스트로 제1회로패턴을 형성하는 과정; 및상기 기재의 타면에 도전성 페이스트로 제2회로패턴을 형성하는 과정을 포함한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제15항에 있어서,상기 기재의 일면에 상기 제1회로 패턴을 형성한 후 상기 기재의 타면에서 캐리어를 제거하는 단계;상기 제2회로 패턴을 형성하기 전 상기 기재의 일면에 캐리어를 합지하는 단계; 및상기 제2회로패턴을 형성한 후 상기 기재의 일면에서 캐리어를 제거하는 단계를 더 포함한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제15항에 있어서,상기 제1회로패턴은 이격된 복수의 X축 전극을 구비한 X축 좌표인식패턴부이고, 상기 제2회로패턴은 이격된 복수의 Y축 전극을 구비한 Y축 좌표인식패턴부인 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제16항에 있어서,상기 캐리어는 습자지를 사용하는 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제15항에 있어서,상기 회로패턴을 소성하는 단계를 거친 상기 기재의 일면에 코팅액을 도포하여 상기 회로패턴을 보호하는 보호코팅층을 형성하는 단계를 더 포함하며,상기 보호코팅층을 형성하는 단계는, 상기 기재의 일면에 코팅액을 도포하여 상기 기재의 일면에 제1보호코팅층을 형성하는 과정; 및상기 기재의 타면에 코팅액을 도포하여 상기 기재의 타면에 제2보호코팅층을 형성하는 과정을 포함한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제19항에 있어서,상기 제1보호코팅층과 상기 제2보호코팅층을 가열하여 경화시키는 단계를 더 포함한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제20항에 있어서,상기 경화시키는 단계는, 상기 제1보호코팅층과 상기 제2보호코팅층을 200℃ ~ 450℃에서 경화시킨 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제15항에 있어서,상기 회로패턴을 형성하는 단계 이전에 상기 기재의 표면을 개질하기 위한 코로나 처리 단계를 더 포함하며,상기 코로나 처리 단계는, 상기 제1회로패턴을 형성하는 단계 이전에 상기 기재의 일면을 코로나 처리하는 과정; 및상기 제2회로패턴을 형성하는 단계 이전에 상기 기재의 타면을 코로나 처리하는 과정을 포함한 것을 특징으로 하는 연성인쇄회로기판의 제조방법.
- 제1항 내지 제22항 중 어느 한 항의 방법으로 제조된 것을 특징으로 하는 연성인쇄회로기판.
- 기재;상기 기재의 일면에 도전성 페이스트를 소성하여 형성된 회로패턴을 포함하며,상기 기재는 선열변형되어 상기 도전성 페이스트를 소성하기 전과 소성된 후의 수축변화량이 0인 것을 특징으로 하는 연성인쇄회로기판.
- 제24항에 있어서,상기 기재에 형성된 회로패턴을 보호하기 위한 보호코팅층을 더 포함한 것을 특징으로 하는 연성인쇄회로기판.
- 제25항에 있어서,상기 기재는 PI필름 또는 PET필름이고, 상기 보호코팅층은 PI용액 또는 PAI용액으로 형성된 코팅층인 것을 특징으로 하는 연성인쇄회로기판.
- 제25항에 있어서,상기 보호코팅층의 위에 순차적으로 형성되는 다른 회로패턴을 더 포함하며, 상기 다른 회로패턴들 사이에는 각각 보호코팅층이 개재되며, 각 층의 회로패턴들은 보호코팅층에 형성되는 비아에 의해 연결되는 것을 특징으로 하는 연성인쇄회로기판.
- 제24항에 있어서,상기 회로패턴은 상기 기재의 일면에 형성되는 제1회로패턴과, 상기 기재의 타면에 형성되는 제2회로패턴을 포함한 것을 특징으로 하는 연성인쇄회로기판.
- 제28항에 있어서,상기 기재의 일면에 형성되는 제1보호코팅층; 및 상기 기재의 타면에 형성되는 제2보호코팅층을 더 포함한 것을 특징으로 하는 연성인쇄회로기판.
- 제28항에 있어서,상기 제1회로패턴은 이격된 복수의 X축 전극을 구비한 X축 좌표인식패턴부이고, 상기 제2회로패턴은 이격된 복수의 Y축 전극을 구비한 Y축 좌표인식패턴부인 것을 특징으로 하는 연성인쇄회로기판.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201480032626.9A CN105309052B (zh) | 2013-04-12 | 2014-04-11 | 柔性印刷电路板的制造方法及由其制造的柔性印刷电路板 |
US14/897,200 US10512175B2 (en) | 2013-04-12 | 2014-04-11 | Method for manufacturing flexible printed circuit board and flexible printed circuit board manufactured thereby |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
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KR10-2013-0040465 | 2013-04-12 | ||
KR20130040465 | 2013-04-12 | ||
KR20130040466 | 2013-04-12 | ||
KR10-2013-0040466 | 2013-04-12 | ||
KR1020140043073A KR101586812B1 (ko) | 2013-04-12 | 2014-04-10 | 연성인쇄회로기판의 제조방법 및 이에 의해 제조된 연성인쇄회로기판 |
KR10-2014-0043073 | 2014-04-10 |
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JPH0735106B2 (ja) * | 1988-11-15 | 1995-04-19 | 信越化学工業株式会社 | ポリイミドフィルム系フレキシブル印刷回路用基板の製造方法 |
JP2708598B2 (ja) * | 1990-02-22 | 1998-02-04 | 信越化学工業株式会社 | フレキシブル印刷配線用基板の製造方法 |
KR20050082450A (ko) * | 2004-02-19 | 2005-08-24 | 소프트픽셀(주) | 플라스틱 필름 lcd의 액정 주입을 위한 전처리 방법 |
US20100084168A1 (en) * | 2008-10-03 | 2010-04-08 | Po-Ju Chou | Manufacturing method of a flexible printed circuit board and a structure thereof |
KR20110052759A (ko) * | 2009-11-13 | 2011-05-19 | 최용묵 | 플렉서블 디스플레이 제조방법 |
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JPH0735106B2 (ja) * | 1988-11-15 | 1995-04-19 | 信越化学工業株式会社 | ポリイミドフィルム系フレキシブル印刷回路用基板の製造方法 |
JP2708598B2 (ja) * | 1990-02-22 | 1998-02-04 | 信越化学工業株式会社 | フレキシブル印刷配線用基板の製造方法 |
KR20050082450A (ko) * | 2004-02-19 | 2005-08-24 | 소프트픽셀(주) | 플라스틱 필름 lcd의 액정 주입을 위한 전처리 방법 |
US20100084168A1 (en) * | 2008-10-03 | 2010-04-08 | Po-Ju Chou | Manufacturing method of a flexible printed circuit board and a structure thereof |
KR20110052759A (ko) * | 2009-11-13 | 2011-05-19 | 최용묵 | 플렉서블 디스플레이 제조방법 |
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