WO2014148153A1 - 燃料電池システム及び燃料電池システムの制御方法 - Google Patents
燃料電池システム及び燃料電池システムの制御方法 Download PDFInfo
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0432—Temperature; Ambient temperature
- H01M8/04373—Temperature; Ambient temperature of auxiliary devices, e.g. reformers, compressors, burners
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
- H01M8/04104—Regulation of differential pressures
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- H—ELECTRICITY
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0438—Pressure; Ambient pressure; Flow
- H01M8/04395—Pressure; Ambient pressure; Flow of cathode reactants at the inlet or inside the fuel cell
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04537—Electric variables
- H01M8/04604—Power, energy, capacity or load
- H01M8/04619—Power, energy, capacity or load of fuel cell stacks
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- H—ELECTRICITY
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- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04701—Temperature
- H01M8/04738—Temperature of auxiliary devices, e.g. reformer, compressor, burner
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04746—Pressure; Flow
- H01M8/04753—Pressure; Flow of fuel cell reactants
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04791—Concentration; Density
- H01M8/04798—Concentration; Density of fuel cell reactants
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04865—Voltage
- H01M8/0488—Voltage of fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04694—Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
- H01M8/04858—Electric variables
- H01M8/04895—Current
- H01M8/0491—Current of fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0432—Temperature; Ambient temperature
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0432—Temperature; Ambient temperature
- H01M8/04358—Temperature; Ambient temperature of the coolant
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/0438—Pressure; Ambient pressure; Flow
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04537—Electric variables
- H01M8/04544—Voltage
- H01M8/04559—Voltage of fuel cell stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04298—Processes for controlling fuel cells or fuel cell systems
- H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
- H01M8/04537—Electric variables
- H01M8/04574—Current
- H01M8/04589—Current of fuel cell stacks
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells
Definitions
- the present invention relates to a fuel cell system and a control method for the fuel cell system.
- JP2012-003957A describes a conventional fuel cell system in which the flow rate of cathode gas is controlled by a compressor provided in the cathode gas supply passage, and the pressure of the cathode gas is controlled by a pressure regulating valve provided in the cathode gas discharge passage. Has been.
- the cathode gas pressure and flow rate are individually set according to the target output current so that the oxygen partial pressure in the fuel cell stack does not fall below a predetermined oxygen partial pressure even if the target output current is taken out from the fuel cell stack.
- the target value calculated in the above is controlled.
- the cathode gas pressure may need to be temporarily reduced to lower the temperature downstream of the compressor. Then, as described above, it has been found that the following problems occur when the pressure and flow rate of the cathode gas are controlled to the target values calculated individually according to the target output current.
- the cathode gas flow rate is calculated according to the target output current. Therefore, the oxygen partial pressure in the fuel cell stack may fall below a predetermined oxygen partial pressure.
- the present invention has been made paying attention to such problems, and an object thereof is to suppress the oxygen partial pressure in the fuel cell stack from falling below a predetermined oxygen partial pressure.
- a fuel cell system that generates electricity by supplying an anode gas and a cathode gas to a fuel cell.
- the fuel cell system includes a compressor for adjusting the flow rate of the cathode gas supplied to the fuel cell, a pressure regulating valve for adjusting the pressure of the cathode gas supplied to the fuel cell, the load of the fuel cell, and the thermal protection of the fuel cell system.
- the target pressure calculating means for calculating the target pressure of the cathode gas supplied to the fuel cell in consideration of the requirements, and the target of the cathode gas supplied to the fuel cell according to the load of the fuel cell and the target pressure of the cathode gas
- Target flow rate calculating means for calculating the flow rate, and control means for controlling the compressor and the pressure regulating valve in accordance with the target pressure and the target flow rate of the cathode gas.
- FIG. 1 is a schematic view of a fuel cell system according to a first embodiment of the present invention.
- FIG. 2 is a control block diagram for explaining the control of the cathode system according to the first embodiment of the present invention.
- FIG. 3 is a map for calculating the stack required WRD inlet pressure.
- FIG. 4 is a map for calculating the stack required supply flow rate.
- FIG. 5 is a time chart for explaining the operation of controlling the cathode system according to the first embodiment of the present invention.
- FIG. 6 is a control block diagram showing a stack required supply flow rate calculation unit according to the second embodiment of the present invention.
- an electrolyte membrane is sandwiched between an anode electrode (fuel electrode) and a cathode electrode (oxidant electrode), an anode gas containing hydrogen in the anode electrode (fuel gas), and a cathode gas containing oxygen in the cathode electrode (oxidant) Electricity is generated by supplying gas.
- the electrode reaction that proceeds in both the anode electrode and the cathode electrode is as follows.
- Anode electrode 2H 2 ⁇ 4H + + 4e ⁇ (1)
- Cathode electrode 4H + + 4e ⁇ + O 2 ⁇ 2H 2 O (2)
- the fuel cell generates an electromotive force of about 1 volt by the electrode reactions (1) and (2).
- a fuel cell When a fuel cell is used as a power source for automobiles, it requires a large amount of power, so it is used as a fuel cell stack in which several hundred fuel cells are stacked. Then, a fuel cell system that supplies anode gas and cathode gas to the fuel cell stack is configured, and electric power for driving the vehicle is taken out.
- FIG. 1 is a schematic diagram of a fuel cell system 100 according to a first embodiment of the present invention.
- the fuel cell system 100 includes a fuel cell stack 1, a cathode gas supply / discharge device 2, an anode gas supply / discharge device 3, and a controller 4.
- the fuel cell stack 1 is formed by stacking several hundred fuel cells, and receives the supply of anode gas and cathode gas to generate electric power necessary for driving the vehicle.
- the cathode gas supply / discharge device 2 supplies the cathode gas to the fuel cell stack 1 and discharges the cathode off-gas discharged from the fuel cell stack 1 to the outside air.
- the cathode gas supply / discharge device 2 is referred to as a cathode gas supply passage 21, a cathode gas discharge passage 22, a filter 23, a cathode compressor 24, an intercooler 25, and a water recovery device (hereinafter referred to as "WRD").
- WRD water recovery device
- the cathode gas supply passage 21 is a passage through which the cathode gas supplied to the fuel cell stack 1 flows.
- the cathode gas supply passage 21 has one end connected to the filter 23 and the other end connected to the cathode gas inlet hole of the fuel cell stack 1.
- the cathode gas discharge passage 22 is a passage through which the cathode off gas discharged from the fuel cell stack 1 flows. One end of the cathode gas discharge passage 22 is connected to the cathode gas outlet hole of the fuel cell stack 1, and the other end is an open end.
- the cathode off gas is a mixed gas of the cathode gas and water vapor generated by the electrode reaction.
- the filter 23 removes foreign matters in the cathode gas taken into the cathode gas supply passage 21.
- the cathode compressor 24 is provided in the cathode gas supply passage 21.
- the cathode compressor 24 takes air (outside air) as cathode gas through the filter 23 into the cathode gas supply passage 21 and supplies it to the fuel cell stack 1.
- the cathode compressor 24 is driven by a compressor driving motor 241.
- the compressor driving motor 241 is connected to a compressor driving inverter 242 that converts DC power supplied from the fuel cell stack 1 into AC power. By controlling the compressor driving inverter 242 with the controller, the compressor driving motor 241 and, consequently, the cathode compressor 24 are controlled.
- the intercooler 25 is provided in the cathode gas supply passage 21 downstream from the cathode compressor 24.
- the intercooler 25 cools the cathode gas discharged from the cathode compressor 24.
- the WRD 26 is connected to each of the cathode gas supply passage 21 and the cathode gas discharge passage 22, collects moisture in the cathode off-gas flowing through the cathode gas discharge passage 22, and cathode that flows through the cathode gas supply passage 21 with the collected moisture. Humidify the gas.
- the cathode pressure regulating valve 27 is provided in the cathode gas discharge passage 22 downstream of the WRD 26.
- the cathode pressure regulating valve 27 is controlled to be opened and closed by the controller 4 to adjust the pressure of the cathode gas supplied to the fuel cell stack 11 to a desired pressure.
- the air flow sensor 41 is provided in the cathode gas supply passage 21 upstream of the cathode compressor 24.
- the air flow sensor 41 detects the flow rate of the cathode gas supplied to the cathode compressor 24 and finally supplied to the fuel cell stack 1 (hereinafter referred to as “stack supply flow rate”).
- the temperature sensor 42 is provided in the cathode gas supply passage 21 between the intercooler 25 and the WRD 26.
- the temperature sensor 42 detects the temperature on the cathode gas inlet side of the WRD 26 (hereinafter referred to as “WRD inlet temperature”).
- the pressure sensor 43 is provided in the cathode gas supply passage 21 between the intercooler 25 and the WRD 26.
- the pressure sensor 43 detects the pressure on the cathode gas inlet side of the WRD 26 (hereinafter referred to as “WRD inlet pressure”).
- the anode gas supply / discharge device 3 supplies anode gas to the fuel cell stack 1 and discharges anode off-gas discharged from the fuel cell stack 1 to the cathode gas discharge passage 22.
- the anode gas supply / discharge device 3 includes a high-pressure tank 31, an anode gas supply passage 32, an anode pressure regulating valve 33, an anode gas discharge passage 34, and a purge valve 35.
- the high pressure tank 31 stores the anode gas supplied to the fuel cell stack 1 in a high pressure state.
- the anode gas supply passage 32 is a passage for supplying the anode gas discharged from the high-pressure tank 31 to the fuel cell stack 1.
- the anode gas supply passage 32 has one end connected to the high pressure tank 31 and the other end connected to the anode gas inlet hole of the fuel cell stack 1.
- the anode pressure regulating valve 33 is provided in the anode gas supply passage 32.
- the anode pressure regulating valve 34 is controlled to be opened and closed by the controller 4 to adjust the pressure of the anode gas supplied to the fuel cell stack 1 to a desired pressure.
- the anode gas discharge passage 34 is a passage through which the anode off gas discharged from the fuel cell stack 1 flows.
- the anode gas discharge passage 35 has one end connected to the anode gas outlet hole of the fuel cell stack 1 and the other end connected to the cathode gas discharge passage 22.
- the anode off gas discharged to the cathode gas discharge passage 22 via the anode gas discharge passage 34 is mixed with the cathode off gas in the cathode gas discharge passage 22 and discharged to the outside of the fuel cell system 100. Since the anode off gas contains surplus anode gas (hydrogen) that has not been used for the electrode reaction, the anode off gas is mixed with the cathode off gas and discharged outside the fuel cell system 100, whereby hydrogen in the exhaust gas is discharged.
- the density is set to be equal to or lower than a predetermined density.
- the purge valve 35 is provided in the anode gas discharge passage 34.
- the purge valve 35 is controlled to be opened and closed by the controller 4 and controls the flow rate of the anode off gas discharged from the anode gas discharge passage 34 to the cathode gas discharge passage 22.
- the controller 4 includes a microcomputer having a central processing unit (CPU), a read only memory (ROM), a random access memory (RAM), and an input / output interface (I / O interface).
- the controller 4 includes a current sensor 44 that detects a current (output current) extracted from the fuel cell stack 1, and an output voltage of the fuel cell stack 1.
- a temperature sensor 46 for detecting the temperature of the cooling water for cooling the fuel cell stack 1 (hereinafter referred to as “cooling water temperature”)
- a rotational speed sensor 47 for detecting the rotational speed of the cathode compressor 24, and atmospheric pressure.
- Signals from various sensors such as an atmospheric pressure sensor 48 for detecting the outside air temperature and an outside air temperature sensor 49 for detecting the outside air temperature are input.
- the controller 4 calculates a target value (hereinafter referred to as “target output current”) of current to be extracted from the fuel cell stack 1 based on detection signals of these various sensors.
- the WRD inlet pressure and the stack supply flow rate are appropriately set so that the oxygen partial pressure in the fuel cell stack 1 does not fall below a predetermined oxygen partial pressure. Control to value. This is because when the oxygen partial pressure becomes lower than the predetermined oxygen partial pressure, the oxygen necessary for power generation becomes insufficient, and the IV characteristics (current / voltage characteristics) of the fuel cell stack 1 deteriorate, and the target output from the fuel cell stack 1 is reduced. This is because if the current is taken out, the output voltage of the fuel cell stack 1 may be lower than the minimum output voltage necessary for driving the drive motor of the vehicle.
- the oxygen partial pressure in the fuel cell stack 1 is a predetermined oxygen for each output current of the fuel cell stack 1. Based on the target output current, the WRD inlet pressure and the stack supply flow rate that do not fall below the partial pressure are obtained in advance through experiments. There is a method for individually calculating the target value of the stack supply flow rate.
- the oxygen consumption also increases. Therefore, in order to ensure the oxygen partial pressure, it is necessary to increase the target values of the WRD inlet pressure and the stack supply flow rate. There is. Therefore, when the high load operation continues, the temperature downstream of the cathode compressor 24, that is, the outlet temperature of the cathode compressor 24 and the WRD inlet temperature rise, and in some cases, the heat resistance temperature of the cathode compressor 24 and WRD 26 may be exceeded.
- the WRD inlet pressure must be temporarily reduced according to the operating state of the cathode compressor 24 and the WRD inlet temperature, and the outlet temperature and WRD inlet temperature of the cathode compressor 24 must be reduced. There are times when it does not become. In other words, the target value of the WRD inlet pressure sometimes needs to be temporarily lower than the target value of the WRD inlet pressure calculated based on the target output current.
- the WRD inlet pressure is calculated based on the target output current. Even if it is controlled to be lower than the target value of the inlet pressure, the stack supply flow rate is controlled to the target value of the stack supply flow rate calculated based on the target output current. Therefore, there arises a problem that the oxygen partial pressure in the fuel cell stack 1 may be lower than a predetermined oxygen partial pressure.
- the target value of the stack supply flow rate for ensuring the oxygen partial pressure in the fuel cell stack 1 is corrected to be increased based on the target value of the WRD inlet pressure.
- the oxygen partial pressure is prevented from falling below a predetermined oxygen partial pressure by increasing the stack supply flow rate as the WRD inlet pressure is reduced.
- FIG. 2 is a control block diagram for explaining the control of the cathode system according to the present embodiment.
- the control block of the cathode system includes a stack required WRD inlet pressure calculation unit 51, a limit pressure setting unit 52, a first limit pressure output unit 53, a second limit pressure output unit 54, and a third limit pressure.
- a limit flow rate output unit 55, a target WRD inlet pressure setting unit 56, a target stack supply flow rate setting unit 57, a stack required supply flow rate calculation unit 58, and a feedback control unit 59 are provided.
- the stack required WRD inlet pressure calculation unit 51 refers to the map shown in FIG. 3 and calculates the stack required WRD inlet pressure based on the target output current of the fuel cell stack 1 and the atmospheric pressure.
- the stack required WRD inlet pressure is a target value of the WRD inlet pressure necessary for securing the oxygen partial pressure in the fuel cell stack 1 when the target output current is extracted from the fuel cell stack 1.
- the stack required WRD inlet pressure calculation unit 51 sets the optimum target value of the WRD inlet pressure according to the load of the fuel cell stack 1 as the stack required WRD inlet pressure.
- the limit pressure setting unit 52 sets an upper limit value (hereinafter referred to as “limit pressure”) of the WRD inlet pressure that needs to be protected in order to protect the cathode system for heat protection.
- the limit pressure setting unit 52 is a target of the WRD inlet pressure necessary to satisfy the thermal protection requirements of the entire fuel cell system such as the cathode compressor 24, the fuel cell stack 1, the WRD 26, and the compressor driving inverter 242.
- the limit pressure setting unit 52 receives the first limit pressure, the second limit pressure, and the third limit pressure, and the limit pressure setting unit 52 sets the smallest of these as the limit pressure.
- the first limit pressure output unit 53 outputs the first limit pressure.
- the first limit pressure is an upper limit value of the WRD inlet pressure for preventing the outlet temperature of the cathode compressor 24 from becoming higher than the heat resistant temperature of the cathode compressor 24.
- the first limit pressure is calculated according to, for example, the compressor rotation speed, the compressor torque, the outside air temperature (intake air temperature), and the atmospheric pressure. Basically, the higher the compressor rotation speed and the outside air temperature, the lower the compressor torque, The first limiting pressure is lowered. Note that the calculation method of the first limit pressure is not limited to this.
- the outlet temperature of the cathode compressor 24 may be detected and calculated based on the outlet temperature.
- the first limit pressure output unit 53 calculates the WRD inlet pressure such that the outlet temperature of the cathode compressor 24 does not become equal to or higher than the heat resistant temperature of the cathode compressor 24, and outputs it as the first limit pressure.
- the second limit pressure output unit 54 outputs the second limit pressure.
- the second limit pressure is the upper limit value of the WRD inlet pressure for preventing the downstream components of the cathode compressor 24 such as the WRD 26 and the fuel cell stack 1 from reaching the respective heat resistant temperatures.
- the second limit pressure is calculated according to, for example, the WRD inlet temperature, and basically decreases as the WRD inlet temperature increases. Note that the method for calculating the second limit pressure is not limited to this. For example, the temperature at a specific location downstream of the cathode compressor 24 may be detected and calculated based on the detected temperature. As described above, the second limit pressure output unit 54 calculates the WRD inlet pressure such that the temperature downstream of the cathode compressor 24 does not exceed the heat resistance temperature of the components disposed downstream, and outputs the calculated WRD as the second limit pressure. .
- the third limit pressure / limit flow rate output unit 55 outputs the WRD inlet pressure and the stack supply flow rate to prevent the temperature of the compressor drive inverter 242 from exceeding the heat-resistant temperature as the third limit pressure and limit flow rate, respectively.
- the third limiting pressure and the limiting flow rate are predetermined values determined in advance by experiments or the like, and when the temperature of the compressor driving inverter 242 becomes equal to or higher than a predetermined temperature lower than the heat resistant temperature, the compressor driving inverter 242 is used. Output for thermal protection.
- the third limit pressure and the limit flow rate are basically selected as a target WRD inlet pressure and a target stack supply flow rate, which will be described later, and the fuel cell stack 1
- An upper limit value is also set for the target output current so that the oxygen partial pressure can be secured.
- the temperature of the compressor driving inverter 242 may be estimated based on the power supplied to the compressor driving motor 241 or may be directly detected.
- the target WRD inlet pressure setting unit 56 sets the smaller one of the stack required WRD inlet pressure and the limit pressure as the target WRD inlet pressure.
- the stack required WRD inlet pressure is normally set as the target WRD inlet pressure.
- the limit pressure is set as the target WRD inlet pressure when it is necessary to provide thermal protection of the cathode system, such as when high load operation continues.
- the target WRD inlet pressure setting unit 56 sets the target WRD inlet pressure in consideration of the load of the fuel cell stack 1 and the thermal protection request of the fuel cell system 100.
- the target stack supply flow rate setting unit 57 sets the smaller one of the stack request supply flow rate and the limit flow rate calculated by the stack request supply flow rate calculation unit 58 described later as the target stack supply flow rate.
- the target stack supply flow rate setting unit 57 basically sets the required stack supply flow rate as the target stack supply flow rate except when the temperature of the compressor driving inverter 242 becomes equal to or higher than a predetermined temperature.
- the target stack supply flow rate setting unit 57 basically targets the cathode gas to be supplied to the fuel cell stack 1 according to the load of the fuel cell stack 1 and the target pressure of the cathode gas (target WRD inlet pressure). Set the flow rate (target stack supply flow rate).
- the stack required supply flow rate calculation unit 58 calculates the stack required supply flow rate based on the target output current (load) of the fuel cell stack 1 and the target WRD inlet pressure with reference to the map of FIG. As shown in the map of FIG. 4, the stack required supply flow rate is corrected so as to increase as the target WRD inlet pressure is lower. As a result, when the limit pressure (first limit pressure or second limit pressure) is selected as the target WRD inlet pressure, the target stack supply flow rate is set higher than when the stack required WRD inlet pressure is selected as the target WRD inlet pressure. Can be increased.
- the stack supply flow rate can be increased by the amount that the WRD inlet pressure has decreased from the stack required WRD inlet pressure to the limit pressure, the oxygen partial pressure in the fuel cell stack 1 is suppressed from falling below a predetermined oxygen partial pressure. Can do.
- the actual WRD inlet pressure detected by the pressure sensor 43, the target WRD inlet pressure, the actual stack supply flow rate detected by the airflow sensor 41, and the target stack supply flow rate are input to the feedback control unit 59.
- the feedback control unit 59 substitutes these input values into an arithmetic expression that models the system, so that the target value of the compressor torque for converging the actual WRD inlet pressure to the target WRD inlet pressure, and the actual stack supply flow rate Is calculated as a target value for the opening degree of the cathode pressure regulating valve 27 to converge to the target stack supply flow rate.
- FIG. 5 is a time chart for explaining the operation of controlling the cathode system according to the present embodiment.
- the cathode pressure regulating valve 27 When the target WRD inlet pressure is switched from the stack required WRD inlet pressure to the limiting pressure (first limiting pressure or second limiting pressure) at time t1, the cathode pressure regulating valve 27 is set so that the WRD inlet pressure decreases toward the limiting pressure. Is feedback-controlled (FIG. 5A). Then, as the target WRD inlet pressure is switched to the limit pressure, the stack required supply flow rate is corrected to increase, and the target stack supply flow rate increases. As a result, the cathode compressor 24 is feedback-controlled so that the stack supply flow rate increases toward the target stack supply flow rate (FIG. 5B).
- the target WRD inlet pressure before time t1 is obtained from the fuel cell stack 1. If the target output current before switching to the limit pressure is taken out, the oxygen partial pressure in the fuel cell stack 1 cannot be secured. Therefore, as shown by a broken line in FIG. 5C, in order to secure the oxygen partial pressure in the fuel cell stack 1, it is necessary to reduce the target output current, which causes a reduction in the output of the vehicle.
- the stack supply flow rate can be increased by the amount that the WRD inlet pressure has decreased from the stack required WRD inlet pressure to the limit pressure, so the oxygen partial pressure in the fuel cell stack 1 is predetermined. It is possible to suppress the lowering of the oxygen partial pressure.
- the target WRD inlet pressure setting unit 56 supplies the cathode to the fuel cell stack 1 in consideration of the load of the fuel cell stack 1 and the thermal protection requirement of the fuel cell system 100.
- the target gas pressure (target WRD inlet pressure) is set, and the target required flow rate calculation unit 58 supplies the target cathode gas supplied to the fuel cell stack 1 according to the load of the fuel cell stack 1 and the target pressure of the cathode gas. Set the flow rate (stack required supply flow rate).
- the feedback control unit 59 controls the cathode compressor 24 and the cathode pressure regulating valve 27 according to the target pressure and target flow rate of the cathode gas.
- the target flow rate of the cathode gas is calculated in consideration of the target pressure of the cathode gas. Will increase. Therefore, it is possible to suppress the oxygen partial pressure in the fuel cell stack 1 from falling below a predetermined oxygen partial pressure.
- FIG. 6 is a control block diagram showing the stack required supply flow rate calculation unit 58 according to the present embodiment.
- the correction coefficient is calculated based on the coolant temperature and the target WRD inlet pressure, and the stack required supply flow rate calculated based on the target output current of the fuel cell stack 1 and the target WRD inlet pressure is calculated.
- the stack required supply flow rate is corrected by multiplying the correction coefficient.
- the correction coefficient increases as the coolant temperature increases and the pressure in the fuel cell stack 1 decreases.
- the water temperature at the cooling water inlet side and the water temperature at the outlet side of the fuel cell stack are detected as the cooling water temperature, it is desirable to calculate the correction coefficient for the higher cooling water temperature.
- the stack required supply flow rate calculation unit 58 is configured to increase the target flow rate of the cathode gas (stack required supply flow rate) as the temperature in the fuel cell stack 1 is higher. .
- the same effects as those of the first embodiment can be obtained, and the stack required supply flow rate can be corrected according to the water vapor partial pressure in the fuel cell stack 1, so that the oxygen partial pressure in the fuel cell stack 1 is It can suppress more reliably that it is less than predetermined oxygen partial pressure.
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Abstract
Description
燃料電池は電解質膜をアノード電極(燃料極)とカソード電極(酸化剤極)とによって挟み、アノード電極に水素を含有するアノードガス(燃料ガス)、カソード電極に酸素を含有するカソードガス(酸化剤ガス)を供給することによって発電する。アノード電極及びカソード電極の両電極において進行する電極反応は以下の通りである。
カソード電極 : 4H+ +4e- +O2 →2H2O …(2)
次に、本発明の第2実施形態について説明する。本実施形態は、燃料電池スタック1内の温度等に応じてスタック要求供給流量をさらに補正する点で第1実施形態と相違する。以下、その相違点を中心に説明する。なお、以下に示す各実施形態では前述した実施形態と同様の機能を果たす部分には、同一の符号を用いて重複する説明を適宜省略する。
Claims (7)
- アノードガス及びカソードガスを燃料電池に供給して発電する燃料電池システムであって、
前記燃料電池に供給するカソードガスの流量を調節するコンプレッサと、
前記燃料電池に供給するカソードガスの圧力を調節する調圧弁と、
前記燃料電池の負荷と前記燃料電池システムの熱保護要求とを考慮して、前記燃料電池に供給するカソードガスの目標圧力を算出する目標圧力算出手段と、
前記燃料電池の負荷と前記カソードガスの目標圧力とに応じて、前記燃料電池に供給するカソードガスの目標流量を算出する目標流量算出手段と、
前記カソードガスの目標圧力及び目標流量に応じて、前記コンプレッサ及び前記調圧弁を制御する制御手段と、
を備える燃料電池システム。 - 前記目標流量算出手段は、
前記カソードガスの目標圧力が低いときほど、前記カソードガスの目標流量を多くする、
請求項1に記載の燃料電池システム。 - 前記目標流量算出手段は、
前記燃料電池内の温度が高いときほど、前記カソードガスの目標流量を多くする、
請求項2に記載の燃料電池システム。 - 前記目標圧力算出手段は、
前記燃料電池の負荷に基づいて、前記燃料電池内の酸素分圧を所定以上に保持するために必要なカソードガスの圧力を燃料電池要求圧力として算出する燃料電池要求圧力算出手段と、
前記燃料電池システムの熱保護要求に基づいて、前記カソードガスの目標圧力の上限値を設定する上限値設定手段と、
を備え、
前記燃料電池要求圧力と前記上限値との小さいほうを前記カソードガスの目標圧力として算出する、
請求項1から請求項3までのいずれか1つに記載の燃料電池システム。 - 前記上限値設定手段は、
前記コンプレッサの出口温度が、前記コンプレッサを保護するための所定温度以上とならないように、前記上限値を設定する、
請求項4に記載の燃料電池システム。 - 前記上限値設定手段は、
前記コンプレッサと前記燃料電池との間の温度が、前記コンプレッサの下流部品を保護するための所定温度以上とならないように、前記上限値を設定する、
請求項4又は請求項5に記載の燃料電池システム。 - アノードガス及びカソードガスが供給される燃料電池と、
前記燃料電池に供給するカソードガスの流量を調節するコンプレッサと、
前記燃料電池に供給するカソードガスの圧力を調節する調圧弁と、
を備える燃料電池システムの制御方法であって、
前記燃料電池の負荷と前記燃料電池システムの熱保護要求とを考慮して、前記燃料電池に供給するカソードガスの目標圧力を算出する目標圧力算出工程と、
前記燃料電池の負荷と前記カソードガスの目標圧力とに応じて、前記燃料電池に供給するカソードガスの目標流量を算出する目標流量算出工程と、
前記カソードガスの目標圧力及び目標流量に応じて、前記コンプレッサ及び前記調圧弁を制御する制御工程と、
を備える燃料電池システムの制御方法。
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US14/778,917 US10181606B2 (en) | 2013-03-22 | 2014-02-12 | Fuel cell system and method of controlling fuel cell system |
EP14769953.2A EP2978055B1 (en) | 2013-03-22 | 2014-02-12 | Fuel-cell system and method for controlling fuel-cell system |
JP2015506648A JP5983862B2 (ja) | 2013-03-22 | 2014-02-12 | 燃料電池システム及び燃料電池システムの制御方法 |
CA2907902A CA2907902C (en) | 2013-03-22 | 2014-02-12 | Fuel cell system with cathode compressor regulation |
CN201480013547.3A CN105190976B (zh) | 2013-03-22 | 2014-02-12 | 燃料电池系统以及燃料电池系统的控制方法 |
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EP2978056B1 (en) * | 2013-03-22 | 2018-09-19 | Nissan Motor Co., Ltd | Fuel cell system and control method therefor |
JP6044620B2 (ja) * | 2014-11-13 | 2016-12-14 | トヨタ自動車株式会社 | 燃料電池車両 |
US11563222B1 (en) * | 2016-02-25 | 2023-01-24 | Ball Aerospace & Technologies Corp. | Systems and methods for passively controlling pressure within a cryogenic storage tank |
JP6330835B2 (ja) * | 2016-03-10 | 2018-05-30 | トヨタ自動車株式会社 | 燃料電池システム及びその制御方法 |
CN108177539B (zh) * | 2017-12-28 | 2020-10-30 | 潍柴动力股份有限公司 | 一种燃料电池电动汽车的空气压缩系统及控制方法 |
CN112751061B (zh) * | 2020-12-31 | 2022-02-25 | 吉林大学 | 一种燃料电池空气路测试系统及方法 |
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