WO2014133275A1 - 이차 전지 및 그 제조 방법 - Google Patents
이차 전지 및 그 제조 방법 Download PDFInfo
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- WO2014133275A1 WO2014133275A1 PCT/KR2014/001232 KR2014001232W WO2014133275A1 WO 2014133275 A1 WO2014133275 A1 WO 2014133275A1 KR 2014001232 W KR2014001232 W KR 2014001232W WO 2014133275 A1 WO2014133275 A1 WO 2014133275A1
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- WIPO (PCT)
- Prior art keywords
- electrode assembly
- secondary battery
- sealing member
- safety vent
- assembly
- Prior art date
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 238000007789 sealing Methods 0.000 claims abstract description 61
- 239000003792 electrolyte Substances 0.000 claims abstract description 10
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- 229910052744 lithium Inorganic materials 0.000 description 5
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Images
Classifications
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- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/107—Primary casings; Jackets or wrappings characterised by their shape or physical structure having curved cross-section, e.g. round or elliptic
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- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/148—Lids or covers characterised by their shape
- H01M50/152—Lids or covers characterised by their shape for cells having curved cross-section, e.g. round or elliptic
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- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/147—Lids or covers
- H01M50/166—Lids or covers characterised by the methods of assembling casings with lids
- H01M50/169—Lids or covers characterised by the methods of assembling casings with lids by welding, brazing or soldering
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/186—Sealing members characterised by the disposition of the sealing members
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
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- H01M50/574—Devices or arrangements for the interruption of current
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/4911—Electric battery cell making including sealing
Definitions
- the present invention relates to a technique for manufacturing a secondary battery, and more particularly, to a secondary battery and a method of manufacturing the same having improved capacity and safety by preventing welding of the cap assembly and the battery case without forming a bead portion.
- a secondary battery unlike a primary battery that cannot be charged, means a battery that can be charged and discharged, and is widely used in electronic devices such as mobile phones, notebook computers, camcorders, and electric vehicles.
- the lithium secondary battery has an operating voltage of about 3.6V, and has about three times the capacity of a nickel-cadmium battery or a nickel-hydrogen battery, which is widely used as a power source for electronic equipment, and has a high energy density per unit weight. The degree is increasing rapidly.
- Such lithium secondary batteries mainly use lithium-based oxides and carbon materials as positive electrode active materials and negative electrode active materials, respectively.
- the lithium secondary battery includes an electrode assembly in which a positive electrode plate and a negative electrode plate coated with such a positive electrode active material and a negative electrode active material are disposed with a separator interposed therebetween, and a battery case (external material) for sealingly storing the electrode assembly together with the electrolyte solution.
- the lithium secondary battery may be classified into a can type secondary battery in which an electrode assembly is embedded in a metal can and a pouch type secondary battery in which an electrode assembly is embedded in a pouch of an aluminum laminate sheet according to the type of battery case.
- the can-type secondary battery may be further classified into a cylindrical battery and a square battery according to the shape of the metal can.
- the rectangular or cylindrical secondary battery packaging material includes a battery case having an open end and a cap assembly sealingly coupled to the open end of the battery case.
- FIG. 1 is a schematic cross-sectional view of a conventional cylindrical secondary battery in which a beading portion is formed in a battery case.
- a cylindrical secondary battery generally includes a cylindrical battery case 20 sealed at a lower end thereof and an open upper end thereof, a jelly-roll electrode assembly 30 accommodated inside the battery case 20, and a battery case.
- the cap assembly 10 coupled to the upper portion of the 20, the beading portion 40 provided at the tip of the battery case 20 for mounting the cap assembly 10, and the crimping portion 50 for sealing the battery are provided. Equipped.
- the electrode assembly 30 is typically a structure in which a separator is sandwiched between a positive electrode plate and a negative electrode plate in a jelly-roll shape, and a positive electrode lead 31 is attached to the positive electrode plate and connected to the cap assembly 10.
- the negative lead 32 is attached to the lower end of the battery case 20.
- the cap assembly 10 includes a top cap 11 that forms a positive terminal, a safety vent 12 that blocks current when the pressure rises inside the cell and / or exhausts gas, and a safety vent 12 except for a specific portion.
- the insulating member 13 for electrically separating the current blocking member 15 from the current blocking member 15 and the current blocking member 14 to which the positive electrode lead 31 connected to the positive electrode plate is connected are sequentially stacked.
- the cap assembly 10 is mounted to the beading part 40 of the battery case 20 while being mounted on the gasket 15. Therefore, under normal operating conditions, the anode of the electrode assembly 30 is connected to the top cap 11 via the anode lead 31, the current blocking member 14, and the safety vent 12 to conduct electricity.
- the beading portion 40 should be formed in the battery case 20 in order to couple and fix the cap assembly 10. Since the storage capacity of the electrode assembly 30 is reduced by the portion, there is a problem that the battery capacity is eventually reduced. Therefore, in order to solve this problem, a secondary battery in which the beading portion 40 is not formed in the battery case 20 has recently been proposed.
- FIG. 2 is a schematic cross-sectional view of a conventional cylindrical secondary battery in which no beading portion is formed in the battery case 20.
- the beading part is not formed in the battery case 20.
- the cap assembly 10 is coupled at the top of the battery case 20, such as a portion indicated by L, by laser welding or the like to seal the battery case 20.
- the cover 16 is typically provided at the outermost portion of the cap assembly 10. Since the cover 16 is a component for welding the battery case 20, the cover 16 may be made of a material that can be welded with the battery case 20, for example, a metal material.
- cap assembly 10 heat may be generated during welding of the cap assembly 10 and the battery case 20, which may damage various components of the cap assembly 10.
- the cap assembly 10 since the cap assembly 10 must be separately provided with a cover 16 made of a material such as metal for welding with the battery case 20, the structure of the cap assembly 10 may be more complicated and manufacturing costs may increase. And, the weight of the secondary battery can be increased.
- An object of the present invention is to provide a secondary battery capable of preventing damage and improving productivity and a method of manufacturing the same.
- a secondary battery according to the present invention for achieving the above object is a secondary battery that does not have a beading portion, the electrode assembly having a positive electrode plate and a negative electrode plate disposed between the separator;
- a battery case accommodating the electrode assembly and the electrolyte in an inner space, the battery case including an upper can and an open bottom and an upper can bent in an inward direction and a lower sealing member coupled to a lower end of the upper can to seal a lower end thereof;
- a top cap disposed protruding from the top to form a positive electrode terminal, a safety vent that is deformed when the internal pressure of the battery case increases in a lower portion of the top cap, and a gasket surrounding edges of the top cap and the safety vent. It includes a cap assembly comprising a.
- the gasket has an upper end contacting an inner surface of an upper bent portion of the upper can and a lower end contacting an upper surface of the electrode assembly.
- the gasket has an upper end contacting an inner surface of an upper bent portion of the upper can, and a lower end contacting an upper surface of the upper insulating plate.
- the upper can and the lower sealing member are coupled by laser welding.
- the lower sealing member is provided with a groove, and the upper can is inserted into the groove of the lower sealing member.
- the battery pack according to the present invention for achieving the above object includes the above-described secondary battery.
- a secondary battery manufacturing method for achieving the above object, a method for manufacturing a secondary battery without a beading portion, comprising the steps of preparing an electrode assembly, the positive electrode plate and the negative electrode plate disposed between the separator; Preparing a battery case including an upper space is formed in the inner space to accommodate the electrode assembly and the electrolyte, and the upper and lower ends are bent in the inward direction and the lower sealing member separated from the upper can; A top cap disposed protruding from the top to form a positive electrode terminal, a safety vent that is deformed when the internal pressure of the battery case increases from a lower portion of the top cap, and a gasket surrounding edges of the top cap and the safety vent Preparing a cap assembly comprising a; Inserting the cap assembly upwardly through the lower opening of the upper can such that the upper end of the gasket contacts the bent upper inner surface of the upper can; Inserting the electrode assembly in an upward direction through the lower opening of the upper can to be positioned below the cap assembly; And
- the step of inserting the electrode assembly the electrode assembly is inserted such that the upper surface of the electrode assembly is in contact with the lower end of the gasket.
- the preparing of the electrode assembly may further include an upper insulating plate on the upper part of the electrode assembly, and the inserting of the electrode assembly may include the electrode assembly such that an upper surface of the upper insulating plate contacts the lower end of the gasket. Insert
- the lower sealing member is coupled to the lower end of the upper can by laser welding.
- the upper can is inserted into the groove of the lower sealing member.
- the storage space of the electrode assembly is increased, the capacity of the secondary battery can be improved.
- the battery case and the cap assembly are not welded, it is possible to prevent the short from occurring in the secondary battery due to the welding residue generated during the welding.
- heat generated during the welding process can be transferred to the cap assembly to prevent damage to the cap assembly.
- the cap assembly since the cap assembly does not need to include a cover for welding the battery case separately, this can prevent the structure of the cap assembly from being complicated and reduce manufacturing cost and time.
- the productivity and quality of the secondary battery can be improved, and the weight reduction of the secondary battery can be easily achieved.
- FIG. 1 is a schematic cross-sectional view of a conventional cylindrical secondary battery in which a beading portion is formed in a battery case.
- FIG. 2 is a schematic cross-sectional view of a conventional cylindrical secondary battery in which no beading portion is formed in the battery case.
- FIG 3 is a cross-sectional view schematically showing the configuration of a secondary battery according to an embodiment of the present invention.
- FIG. 4 is a view schematically showing a coupling configuration of an upper can and a lower sealing member according to an embodiment of the present invention.
- FIG 5 and 6 are views schematically showing a coupling configuration of the upper can and the lower sealing member according to another embodiment of the present invention.
- FIG. 7 is a view schematically showing a coupling configuration of an upper can and a lower sealing member according to still another embodiment of the present invention.
- FIG. 8 is a flowchart schematically illustrating a method of manufacturing a secondary battery in which the beading portion is not formed according to an embodiment of the present invention.
- FIG 3 is a cross-sectional view schematically showing the configuration of a secondary battery according to an embodiment of the present invention.
- the secondary battery according to the present invention includes an electrode assembly 300, a battery case 200, and a cap assembly 100.
- the electrode assembly 300 may have a form in which a positive electrode plate and a negative electrode plate are disposed with a separator interposed therebetween and accommodated in the battery case 200.
- the electrode assembly 300 may be wound and disposed in the form of a jelly roll, in which case it is also called a jelly roll.
- the electrode plates of the electrode assembly 300 are formed as a structure in which an active material slurry is applied to a current collector, and the slurry may be formed by stirring a granular active material, an auxiliary conductor, a binder, a plasticizer, and the like in a state where a solvent is added. .
- the electrode plates In the direction in which the electrode plates are wound, there may be a non-coating portion in which the slurry is not coated at the beginning and the end of the current collector, and an electrode lead corresponding to each electrode plate may be attached to the non-coating portion.
- the anode lead 310 is attached to the top of the electrode assembly 300 to be electrically connected to the cap assembly 100
- the cathode lead 320 is attached to the bottom of the electrode assembly 300 to be connected to the battery case 200. Is connected to the bottom of the.
- the battery case 200 may be made of a lightweight conductive metal material such as aluminum, stainless steel, or an alloy thereof, and may have an internal space formed therein to accommodate the electrode assembly 300 and the electrolyte in the internal space.
- the battery case 200 may be composed of an upper can 210 and a lower sealing member 220.
- the upper can 210 constitutes an upper portion and a side portion of the battery case 200 as a configuration that occupies most of the battery case 200, and provides an inner space for accommodating the electrode assembly 300 and the electrolyte.
- the upper and lower ends of the upper can 210 are open. Accordingly, the upper portion of the cap assembly 100 may be exposed to the outside of the secondary battery through the upper opening of the upper can 210 to be electrically connected to the external device.
- the top opening of the upper can 210 has a size such that the cap assembly 100 and the electrode assembly 300 cannot pass, while the bottom opening of the upper can 210 has the cap assembly 100 and the electrode.
- the assembly 300 is sized enough to pass through. Therefore, the cap assembly 100 and the electrode assembly 300 may be inserted into the battery case 200 through the lower opening of the upper can 210.
- the upper end of the upper can 210 may be bent in the inner direction. That is, the upper can 210 may have a bent portion 211 at an upper end thereof.
- the upper bent portion 211 may prevent the cap assembly 100 from escaping in the upper direction of the upper can 210.
- the upper bent portion 211 of the upper can 210 is not formed after inserting the electrode assembly 300 and the cap assembly 100 into the battery case 200 like the conventional crimping portion of the secondary battery.
- the electrode assembly 300 and the cap assembly 100 are preformed before insertion. Therefore, there is no fear that the electrode assembly 300 or the cap assembly 100 may be damaged in the conventional crimping process for forming the crimping portion.
- the upper can 210 may be formed in a cylindrical shape. Therefore, the secondary battery according to the present invention can be applied to a cylindrical secondary battery.
- the present invention is not necessarily limited by the specific shape of the upper can 210, the upper can 210 may be formed in a shape other than a cylindrical shape, such as a rectangular cylinder.
- the lower sealing member 220 is coupled to the lower end of the upper can 210 serves to seal the lower end of the battery case 200. That is, in the secondary battery according to the present invention, the lower end of the upper can 210 is open, and the lower sealing member 220 is coupled to the lower end of the upper can 210 to prevent the lower opening. Therefore, the lower sealing member 220 may prevent the electrode assembly 300 and the electrolyte solution contained in the upper can 210 from leaking through the lower end of the upper can 210.
- the lower sealing member 220 is coupled to the upper can 210 after the cap assembly 100 and the electrode assembly 300 are inserted into the inner space of the upper can 210 through the lower opening.
- the electrolyte is injected through the lower end of the upper can 210 after the cap assembly 100 and the electrode assembly 300 are inserted and before the lower sealing member 220 is coupled with the upper can 210.
- the electrolyte may be inserted into the upper can 210 through the cap assembly 100 after the lower sealing member 220 is combined with the upper can 210.
- the upper can 210 and the lower sealing member 220 may be coupled by laser welding.
- FIG. 4 is a view schematically showing a coupling configuration of the upper can 210 and the lower sealing member 220 according to an embodiment of the present invention.
- FIG. 4 for convenience of description, the portion A of FIG. 3 will be mainly described.
- the lower end of the upper can 210 is open, and the lower sealing member 220 of the upper can 210 is inserted after the electrode assembly 300 is inserted. Will move to the bottom.
- the lower sealing member 220 is in close contact with the lower end of the upper can 210, as indicated by L in FIG. 4B, the lower end of the upper can 210 and the lower sealing member 220 are laser welded. These parts can be sealed by being joined to each other through a joining method such as.
- FIG. 4 illustrates the configuration of the lower left side of the battery case 200 of FIG. 3, but the coupling of the shape may be performed on the entire bottom of the battery case.
- the coupling form of the upper can 210 and the lower sealing member 220 shown in Figure 4 is only one example, the present invention is not necessarily limited to this coupling form, there may be a variety of coupling forms.
- the lower sealing member 220 is provided with a groove, and the upper can 210 is inserted into the groove of the lower sealing member 220, whereby the upper can 210 and the lower sealing member 220 are formed. Can be combined.
- FIGS. 5 and 6 are views schematically showing a coupling configuration of the upper can 210 and the lower sealing member 220 according to another embodiment of the present invention.
- FIGS. 5 and 6 for convenience of description, parts corresponding to part A of FIG. 3 will be mainly described.
- the lower sealing member 220 may have a groove 221, that is, a concave portion formed thereon.
- the groove 221 may be formed in a shape corresponding to the lower end of the upper can 210. Therefore, as indicated by the arrow in FIG. 5, when the lower sealing member 220 moves to the lower end of the upper can 210 to be in close contact, the lower end of the upper can 210 may be inserted into the groove 221. have.
- the groove 221 of the lower sealing member 220 may be formed in various ways.
- the inside of the protrusion 222 becomes a concave portion, such a portion may also be called a groove. . Therefore, as indicated by the arrows in FIG. 6, when the lower sealing member 220 moves to the lower end of the upper can 210 and is in close contact with each other, the lower end of the upper can 210 inside the groove, that is, the protrusion 222. You can let it be located.
- the upper can 210 and the lower sealing member 220 may be laser welded to each other. Can be.
- FIG. 7 is a view schematically showing a coupling configuration of the upper can 210 and the lower sealing member 220 according to another embodiment of the present invention.
- the lower sealing member 220 may be configured to be inserted into the lower inner surface of the upper can 210.
- the lower sealing member 220 and the upper can 210 may be bonded to each other by laser welding as indicated by L.
- the cap assembly 100 includes a top cap 110, a safety vent 120, and a gasket 150.
- the cap assembly 100 may be formed in various shapes, such as a circle or a square, according to the shape of the battery case 200.
- the top cap 110 is disposed in a shape protruding upward in the uppermost portion of the cap assembly 100 to form a positive electrode terminal.
- the top cap 110 allows the secondary battery to be electrically connected to the outside.
- a gas hole through which gas may be discharged may be formed in the top cap 110. Therefore, when gas is generated from the electrode assembly 300, the gas may be discharged to the outside of the battery case 200 through the gas hole.
- the top cap 110 may be formed of a metal material such as stainless steel or aluminum, for example.
- the safety vent 120 may be disposed such that the top cap 110 and the outer circumferential surface thereof, that is, the edge portion, contact the lower portion of the top cap 110.
- the safety vent 120 is configured to be deformed when the internal pressure of the secondary battery, that is, the internal pressure of the battery case 200 increases to a predetermined level or more.
- the safety vent 120 may be configured to deform and rupture when the internal pressure of the secondary battery is 12-25 kgf / cm 2 .
- the safety vent 120 as shown in the figure, the center portion is formed to protrude in the downward direction, a predetermined notch may be formed near the center. Therefore, when gas is generated from the inside of the secondary battery, that is, the electrode assembly 300, and the internal pressure increases, the safety vent 120 protrudes upward while its shape is reversed, and may be ruptured around the notches. . Therefore, the gas that has been filled inside the battery case 200 may be discharged to the outside through the ruptured portion of the safety vent 120.
- the gasket 150 is configured to surround the edges of the top cap 110 and the safety vent 120.
- the gasket 150 may be interposed between the upper can 210, the top cap 110, and the safety vent 120.
- the gasket 150 may be formed of a material having electrical insulation since the top cap 110 and the edge of the safety vent 120 may be insulated from the upper can 210.
- the gasket 150 may be made of a material having impact resistance, elasticity, and durability to support and protect the cap assembly 100.
- the gasket 150 may be made of, for example, polyolefine or polypropylene (PP).
- PP polypropylene
- the gasket 150 may be bent by mechanical processing rather than by heat treatment in order to prevent electrical insulation from being weakened.
- the gasket 150 may include a protrusion 151 supporting the lower edge of the safety vent 120 in an upward direction.
- the protrusion 151 of the gasket 150 may prevent the safety vent 120 and the top cap 110 from escaping downward.
- the gasket 150 may not include the protrusion 151, and in this case, the top cap 110 and the safety vent 120 may be supported upward through a bent form.
- the gasket 150 may be configured such that the lower end portion contacts the upper surface of the electrode assembly 300, as indicated in part B of FIG. 3.
- the gasket 150 may be configured such that an upper end thereof contacts the inner surface of the upper bent part 211 of the upper can 210. According to this embodiment, it is possible to prevent the electrode assembly 300 from flowing in the battery case 200, in particular, the electrode assembly 300 flows up and down by the gasket 150.
- the secondary battery according to the present invention may further include an upper insulating plate on the electrode assembly 300.
- the upper insulating plate is made of a material having electrical insulation, and may serve to insulate the electrode assembly 300 and the cap assembly 100.
- the gasket 150 may be configured such that a lower end thereof contacts the upper surface of the upper insulating plate. In addition, the gasket 150 may prevent the flow of the electrode assembly 300 by contacting the upper end portion with the inner surface of the upper bent portion 211 of the upper can 210.
- the cap assembly 100 of the secondary battery according to the present invention may further include a current blocking member 140, as shown in FIG.
- the current interrupting member 140 also called a CID (Current Interrupt Device) is located between the safety vent 120 and the electrode assembly 300, so that the electrode assembly 300 and the safety vent 120 are electrically connected. do. That is, at least a portion of the upper portion of the current blocking member 140 is connected to the lower end of the central protruding portion of the safety vent 120, and the lower portion thereof is connected to the electrode lead of the electrode assembly 300, such as the anode lead 310. Therefore, in the normal state, the current generated from the electrode assembly 300 flows through the anode lead 310 to the current blocking member 140, the safety vent 120, and the top cap 110, thereby discharging the secondary battery. have.
- CID Current Interrupt Device
- the cap assembly 100 may include the current blocking member 140.
- the cap assembly 100 may further include an insulating member 130.
- the insulating member 130 is interposed between the safety vent 120 and the current blocking member 140, except for a portion where the central protruding portion of the safety vent 120 is in contact with the current blocking member 140.
- the blocking member 140 and the safety vent 120 are electrically insulated from each other.
- the shape of the cap assembly 100 shown in FIG. 3 is only one embodiment, and the present invention is not limited to the specific shape of the cap assembly 100.
- the cap assembly 100 of the secondary battery according to the present invention may further include a safety device (not shown).
- the safety device is disposed between the top cap 110 and the safety vent 120 to electrically connect the top cap 110 and the safety vent 120.
- a safety device may block a current flow inside the battery when the temperature of the secondary battery increases, for example, it may be formed of a positive temperature coefficient element (PTC) device.
- PTC positive temperature coefficient element
- the battery pack according to the present invention includes at least one secondary battery described above.
- the battery pack may include a battery management device such as a battery management system (BMS) to control the charge / discharge operation.
- BMS battery management system
- FIG. 8 is a flowchart schematically illustrating a method of manufacturing a secondary battery in which the beading portion is not formed according to an embodiment of the present invention.
- an electrode assembly 300 having a positive electrode plate and a negative electrode plate disposed therebetween is prepared (S110), and an upper can 210 and a lower sealing member.
- a battery case 200 including the 220 is prepared (S120).
- the cap assembly 100 including the top cap 110, the safety vent 120, and the gasket 150 is also prepared (S130).
- the upper can 210 has an internal space is formed to accommodate the electrode assembly 300 and the electrolyte, the top and bottom are open, especially the top It is bent inward.
- the lower sealing member 220 of the battery case 200 is provided in a state separate from the upper can 210.
- the upper can 210 may be cylindrical, but the present invention is not necessarily limited to the shape of the upper can 210.
- the top cap 110 is disposed in a form protruding on the top of the secondary battery to form a positive electrode terminal, the safety vent 120 of the top cap 110 The shape is changed when the internal pressure of the battery case 200 increases in the lower portion, and the gasket 150 is configured to surround the edges of the top cap 110 and the safety vent 120.
- steps S110, S120, and S130 are illustrated as being sequentially performed, but this is for convenience of description only, and steps S110, S120, and S130 may be reversed. It may be performed at the same time.
- the cap assembly eg, the upper end of the gasket 150 is in contact with the bent upper inner surface of the upper can 210.
- 100 is inserted through the lower opening of the upper can 210 (S140).
- the electrode assembly 300 is inserted into the upper can 210 through the lower opening of the upper can 210 so as to be positioned below the cap assembly 100 (S150).
- the lower sealing member 220 is coupled to the lower end of the upper can 210 so that the lower opening of the upper can 210 can be sealed (S160).
- the electrode assembly 300 may be inserted such that the upper surface of the electrode assembly 300 contacts the lower end of the gasket 150.
- the upper insulating plate may be further provided on the upper part of the electrode assembly 300.
- the electrode assembly (the upper surface of the upper insulating plate is in contact with the lower end of the gasket 150). It is preferred to insert 300).
- the step S160 may be performed such that the lower sealing member 220 is coupled to the lower end of the upper can 210 by laser welding.
- the step S160 may be performed in a form in which the upper can 210 is inserted into a groove of the lower sealing member 220.
- the battery case 200 having a groove formed in the lower sealing member 220 may be prepared so that the lower end of the upper can 210 may be inserted.
- the step S130 may include a current blocking member 140 and a safety vent 120 and a current blocking member having an upper portion connected to a lower end of the safety vent 120 and a lower portion connected to the electrode assembly 300.
- the cap assembly 100 may further include an insulation member 130 interposed between the portions 140 to electrically insulate the current blocking member 140 from the safety vent 120 except for a portion thereof.
- the step S130 may be disposed between the top cap 110 and the safety vent 120 to further include a safety element in the cap assembly 100 to block a current when the temperature rises.
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- Chemical & Material Sciences (AREA)
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- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Secondary Cells (AREA)
- Connection Of Batteries Or Terminals (AREA)
- Gas Exhaust Devices For Batteries (AREA)
Abstract
Description
Claims (17)
- 비딩부가 형성되지 않은 이차 전지에 있어서,양극판 및 음극판이 세퍼레이터를 사이에 두고 배치된 전극 조립체;내부 공간에 상기 전극 조립체 및 전해액을 수납하고 상단 및 하단이 개방되어 있으며 상단이 내측 방향으로 절곡된 상부 캔 및 상기 상부 캔의 하단에 결합되어 하단을 밀폐시키는 하부 밀폐부재를 포함하는 전지 케이스; 및최상부에 돌출된 형태로 배치되어 양극 단자를 형성하는 탑 캡, 상기 탑 캡의 하부에서 상기 전지 케이스의 내압 증가시 형태가 변형되는 안전 벤트, 및 상기 탑 캡 및 상기 안전 벤트의 테두리들을 감싸는 가스켓을 포함하는 캡 조립체를 포함하는 것을 특징으로 하는 이차 전지.
- 제1항에 있어서,상기 가스켓은, 상단부가 상기 상부 캔의 상단 절곡부 내면에 접촉되고, 하단부가 상기 전극 조립체의 상면에 접촉되는 것을 특징으로 하는 이차 전지.
- 제1항에 있어서,상기 전극 조립체의 상부에 상부 절연판을 더 포함하고,상기 가스켓은, 상단부가 상기 상부 캔의 상단 절곡부 내면에 접촉되고, 하단부가 상기 상부 절연판의 상면에 접촉되는 것을 특징으로 하는 이차 전지.
- 제1항에 있어서,상기 상부 캔과 상기 하부 밀폐부재는, 레이저 용접에 의해 결합된 것을 특징으로 하는 이차 전지.
- 제1항에 있어서,상기 하부 밀폐부재는 홈이 형성되어 있고, 상기 상부 캔은 상기 하부 밀폐부재의 홈에 삽입되는 것을 특징으로 하는 이차 전지.
- 제1항에 있어서,상부가 상기 안전 벤트의 하단에 연결되고, 하부가 전극 조립체와 연결될 수 있는 전류차단부재; 및 상기 안전 벤트와 상기 전류차단부재 사이에 개재되어 일부분을 제외하고는 상기 전류차단부재를 상기 안전 벤트와 전기적으로 절연시키는 절연부재를 더 포함하는 것을 특징으로 하는 이차 전지.
- 제1항에 있어서,상기 탑 캡과 상기 안전 벤트 사이에 배치되어, 온도 상승시 전류를 차단하는 안전 소자를 더 포함하는 것을 특징으로 하는 이차 전지.
- 제1항에 있어서,상기 상부 캔은, 원통형으로 형성된 것을 특징으로 하는 이차 전지.
- 제1항 내지 제8항 중 어느 한 항에 따른 이차 전지를 포함하는 배터리 팩.
- 비딩부가 형성되지 않은 이차 전지를 제조하는 방법에 있어서,양극판 및 음극판이 세퍼레이터를 사이에 두고 배치된 전극 조립체를 준비하는 단계;상기 전극 조립체 및 전해액을 수납 가능하도록 내부 공간이 형성되고 상단 및 하단이 개방되어 상단이 내측 방향으로 절곡된 상부 캔 및 상기 상부 캔과 분리된 하부 밀폐부재를 포함하는 전지 케이스를 준비하는 단계;상기 최상부에 돌출된 형태로 배치되어 양극 단자를 형성하는 탑 캡, 상기 탑 캡의 하부에서 상기 전지 케이스의 내압 증가시 형태가 변형되는 안전 벤트, 및 상기 탑 캡 및 상기 안전 벤트의 테두리들을 감싸는 가스켓을 포함하는 캡 조립체를 준비하는 단계;상기 가스켓의 상단부가 상기 상부 캔의 절곡된 상부 내면에 접촉되도록 상기 캡 조립체를 상기 상부 캔의 하단 개방부를 통하여 상부 방향으로 삽입하는 단계;상기 캡 조립체의 하부에 위치하도록 상기 전극 조립체를 상기 상부 캔의 하단 개방부를 통하여 상부 방향으로 삽입하는 단계; 및상기 상부 캔의 하단을 밀폐시키도록 상기 하부 밀폐부재를 상기 상부 캔의 하단에 결합하는 단계를 포함하는 것을 특징으로 하는 이차 전지 제조 방법.
- 제10항에 있어서,상기 전극 조립체의 삽입 단계는, 상기 전극 조립체의 상면이 상기 가스켓의 하단부에 접촉되도록 상기 전극 조립체를 삽입하는 것을 특징으로 하는 이차 전지 제조 방법.
- 제10항에 있어서,상기 전극 조립체의 준비 단계는, 상기 전극 조립체의 상부에 상부 절연판을 더 구비하고,상기 전극 조립체의 삽입 단계는, 상기 상부 절연판의 상면이 상기 가스켓의 하단부에 접촉되도록 상기 전극 조립체를 삽입하는 것을 특징으로 하는 이차 전지 제조 방법.
- 제10항에 있어서,상기 하부 밀폐부재와 상부 캔의 결합 단계에서, 상기 하부 밀폐부재는 레이저 용접에 의해 상기 상부 캔의 하단에 결합되는 것을 특징으로 하는 이차 전지 제조 방법.
- 제10항에 있어서,상기 하부 밀폐부재와 상부 캔의 결합 단계에서, 상기 상부 캔은 상기 하부 밀폐부재의 홈에 삽입되는 것을 특징으로 하는 이차 전지 제조 방법.
- 제10항에 있어서,상기 캡 조립체의 준비 단계는, 상기 캡 조립체에 상부가 상기 안전 벤트의 하단에 연결되고, 하부가 전극 조립체와 연결될 수 있는 전류차단부재 및 상기 안전 벤트와 상기 전류차단부재 사이에 개재되어 일부분을 제외하고는 상기 전류차단부재를 상기 안전 벤트와 전기적으로 절연시키는 절연부재가 더 포함되도록 하는 것을 특징으로 하는 이차 전지 제조 방법.
- 제10항에 있어서,상기 캡 조립체의 준비 단계는, 상기 캡 조립체에 상기 탑 캡과 상기 안전 벤트 사이에 배치되어, 온도 상승시 전류를 차단하는 안전 소자가 더 포함되도록 하는 것을 특징으로 하는 이차 전지 제조 방법.
- 제10항에 있어서,상기 상부 캔은, 원통형인 것을 특징으로 하는 이차 전지 제조 방법.
Priority Applications (4)
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JP2015534405A JP6022696B2 (ja) | 2013-02-26 | 2014-02-14 | 二次電池及びその製造方法 |
EP14757062.6A EP2822060B1 (en) | 2013-02-26 | 2014-02-14 | Secondary battery and manufacturing method therefor |
CN201480001073.0A CN104285314B (zh) | 2013-02-26 | 2014-02-14 | 二次电池和用于制造二次电池的方法 |
US14/491,023 US9843025B2 (en) | 2013-02-26 | 2014-09-19 | Secondary battery and method for manufacturing the same |
Applications Claiming Priority (2)
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KR10-2013-0020744 | 2013-02-26 | ||
KR1020130020744A KR101514827B1 (ko) | 2013-02-26 | 2013-02-26 | 이차 전지 및 그 제조 방법 |
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US14/491,023 Continuation US9843025B2 (en) | 2013-02-26 | 2014-09-19 | Secondary battery and method for manufacturing the same |
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CN (1) | CN104285314B (ko) |
TW (1) | TWI489676B (ko) |
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Also Published As
Publication number | Publication date |
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CN104285314A (zh) | 2015-01-14 |
TW201503467A (zh) | 2015-01-16 |
EP2822060A1 (en) | 2015-01-07 |
KR101514827B1 (ko) | 2015-04-23 |
CN104285314B (zh) | 2017-02-22 |
EP2822060A4 (en) | 2015-09-09 |
KR20140106327A (ko) | 2014-09-03 |
JP2015534232A (ja) | 2015-11-26 |
EP2822060B1 (en) | 2017-05-31 |
TWI489676B (zh) | 2015-06-21 |
US20150004446A1 (en) | 2015-01-01 |
JP6022696B2 (ja) | 2016-11-09 |
US9843025B2 (en) | 2017-12-12 |
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