WO2014086859A1 - Article de maquillage d'ongles pouvant être enlevé à froid - Google Patents

Article de maquillage d'ongles pouvant être enlevé à froid Download PDF

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Publication number
WO2014086859A1
WO2014086859A1 PCT/EP2013/075533 EP2013075533W WO2014086859A1 WO 2014086859 A1 WO2014086859 A1 WO 2014086859A1 EP 2013075533 W EP2013075533 W EP 2013075533W WO 2014086859 A1 WO2014086859 A1 WO 2014086859A1
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WO
WIPO (PCT)
Prior art keywords
nails
adhesive article
adhesive
false
copolymers
Prior art date
Application number
PCT/EP2013/075533
Other languages
English (en)
Inventor
Guillaume Kergosien
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal filed Critical L'oreal
Publication of WO2014086859A1 publication Critical patent/WO2014086859A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/90—Block copolymers
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D29/00—Manicuring or pedicuring implements
    • A45D29/001—Self adhesive nail coating blanks
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A61Q3/02—Nail coatings

Definitions

  • the present invention relates to a make-up and/or care article for nails and/or false nails, which is cold removable.
  • the present invention also relates to cosmetic uses of said article, notably for application on nails and/or false nails.
  • the object of the present invention is to provide an adhesive article for nails or false nails which may be removed under cold conditions.
  • an adhesive article for make-up and/or care of nails and/or false nails comprising an adhesive layer with a thickness ranging from 100 ⁇ to 500 ⁇ , preferably from 200 ⁇ to 500 ⁇ , said layer comprising:
  • the present invention therefore relates to an adhesive article intended to be applied on nails and/or false nails via said adhesive layer.
  • said adhesive layer is put into direct contact with the nail and/or with the false nail.
  • the thickness of the adhesive layer of the article according to the invention is preferably comprised between 200 ⁇ and 500 ⁇ , most preferably between 200 ⁇ and 300 ⁇ , and preferentially equal to 250 ⁇ .
  • This adhesive layer has a certain tackiness defined by its viscoelastic properties. Viscoelastic properties
  • the adhesive materials which may be used according to the present invention have viscoelastic properties which are measured at a reference temperature of 35 °C and in a certain range of frequencies.
  • the viscoelastic properties of this material are measured under conditions in which it has a volatile solvent content of less than 30%, and in particular a volatile solvent content of less than 20%.
  • a volatile solvent such as water, a short-chain ester, a short-chain alcohol, acetone, etc.
  • the elastic modulus of the material is measured at three different frequencies:
  • said adhesive material fits the following conditions:
  • - G'(35°C) is the elastic shear modulus of said adhesive material measured at a temperature of 35°C, for any frequency comprised between 2.10 "2 and 2 Hz,
  • the adhesive material also fits the following condition:
  • - G'(0.2 Hz, 35°C) is the elastic shear modulus of said adhesive material measured at a frequency of 0.2 Hz and at a temperature of 35°C.
  • the adhesive materials according to the invention fit the four following conditions:
  • the block copolymers are solid at ambient temperature.
  • the adhesive layer of the adhesive article of the invention comprises a mixture of at least two block copolymers.
  • copolymer is meant to designate a polymer stemming from at least two types of monomers.
  • block copolymer designates a copolymer consisting of blocks of different compositions, connected together in linear sequences. These copolymers may also be designated as “sequenced copolymers”. Thus, these block or sequenced copolymers are polymers comprising at least two distinct sequences or blocks.
  • block copolymers also encompass diblock, triblock, multiblock, radial or star copolymers.
  • block copolymers consist of at least two blocks, preferably two or three blocks. These copolymers are therefore preferably selected from diblock copolymers or triblock copolymers.
  • multiblock copolymers designate copolymers comprising more than three blocks.
  • Block copolymers according to the invention may also be selected from star block copolymers or radial block copolymers. These copolymers have a single branching point from which emerge several blocks. In particular, such a star copolymer having n blocks bound to the branching point is called a star copolymer with n blocks (or radial copolymer).
  • Copolymers may have a linear structure or a non-linear structure such as for example, a copolymer with a branched, radial, star structure.
  • Block copolymers according to the invention may be random or alternating copolymers.
  • the block copolymers according to the invention are selected from olefin copolymers either amorphous or with controlled and moderate crystallization, and preferably from amorphous copolymers.
  • amorphous copolymers is meant a polymer which does not have any crystalline form.
  • the olefin copolymer may also be a film-forming copolymer, i.e. it is capable of forming a film upon its application on the skin.
  • olefin copolymers in the sense of the present application, is meant any copolymer formed by polymerization of at least one olefin and of one other additional monomer different from said olefin, such as for example a styrene monomer.
  • the olefin may notably be a monomer with ethylenic unsaturation.
  • ethylene carbide monomers notably having one or two ethylenic unsaturations (or alkenes) having from 2 to 5 carbon atoms such as ethylene, propylene, butadiene, isoprene.
  • at least one of the block copolymers of the invention comprises at least one styrene block.
  • the block copolymers stem from the polymerization of at least one olefin and of at least one styrene block.
  • At least one of the block copolymers of the invention comprises at least one block comprising at least one unit selected from butadiene, ethylene, propylene, butylene, isoprene or one of their mixtures.
  • each of the block copolymers of the invention comprises at least one styrene block.
  • each of the block copolymers of the invention comprises at least one block comprising at least one unit selected from butadiene, ethylene, propylene, butylene, isoprene, or one of their mixtures.
  • each of the block copolymers of the invention comprises at least one styrene block and at least one block comprising at least one unit selected from butadiene, ethylene, propylene, butylene, isoprene or one of their mixtures.
  • each of the block polymers of the invention comprises at least one styrene block and at least one block comprising at least one isoprene unit.
  • the styrene level in a block copolymer of the invention is less than 35%, preferably less than 25%.
  • the article is such that the block copolymers are selected from sequenced copolymers comprising at least one styrene block, notably present in a content of less than 35%, preferably less than 25%, and at least one block comprising at least one unit selected from butadiene, ethylene, propylene, butylene, isoprene or one of their mixtures.
  • a block copolymer according to the invention may be selected from a diblock, triblock, multiblock, radial or star copolymer.
  • the adhesive layer of the adhesive article of the invention comprises a mixture of two block copolymers (C1 ) and (C2).
  • the block copolymer (C1 ) is a diblock copolymer.
  • the block copolymer (C2) is selected from triblock, multiblock, radial or star copolymers as defined above.
  • the copolymer (C2) is selected from triblock copolymers.
  • Each of the copolymers (C1 ) and (C2) may also be in the form of mixtures of copolymers.
  • (C1 ) may be a mixture of diblock copolymers and (C2) may be a mixture of triblock copolymers.
  • the adhesive layer of the adhesive article of the invention comprises at least one diblock copolymer (C1 ) and at least one copolymer (C2) selected from copolymers of the triblock, multiblock, radial or star type.
  • the adhesive layer of the adhesive article of the invention comprises at least one diblock copolymer (C1 ) and at least one copolymer (C2) selected from triblock copolymers.
  • the adhesive article according to the present invention is such that the weight ratio (C2)/(C1 ) is less than or equal to 7, preferably less than 5.
  • This ratio corresponds to the ratio between the copolymer (C2) mass and the copolymer (C1 ) mass.
  • this ratio corresponds to the ratio between the mass of triblock copolymers and the mass of diblock copolymers.
  • block copolymers according to the invention are the copolymers of the styrene-butadiene-styrene, styrene-(ethylene-butylene)-styrene, styrene-isoprene-styrene type such as those sold under the trade names of "Kraton ® " from KRATON POLYMERS.
  • the mixtures of block copolymers according to the invention may notably be selected from:
  • diblock copolymers adapted to the present invention mention may notably be made of diblock styrene-ethylene/butylene copolymers.
  • triblock copolymers adapted for the present invention, mention may notably be made of triblock styrene-ethylene/butylene-styrene copolymers.
  • the adhesive layer according to the invention comprises a mixture of diblock styrene-ethylene/butylene copolymers, and of linear triblock styrene-ethylene/butylene-styrene copolymers.
  • the adhesive article according to the invention comprises from 35% to 50%, and preferably from 40% to 45%, by weight of block copolymers based on the total weight of said article.
  • the adhesive articles according to the invention also comprise at least one tackifying resin.
  • the adhesive articles may comprise a tackifying resin or a mixture of several tackifying resins.
  • tackifying resin designates thermoplastic resins, with low molecular masses, entering the composition of the adhesives.
  • the tackifying resins according to the invention have a number average molecular mass (Mn) of less than or equal to 10,000 g.mol " .
  • this average molecular mass is comprised between 250 and 10,000 g.mol “1 , preferably less than or equal to 5,000 g.mol “1 , notably ranging from 250 to 5,000 g.mol “1 , better of less than or equal to 2,000 g.mol “1 , notably ranging from 250 to 2,000 g.mol “1 and even better of less than or equal to 1 ,000 g.mol “1 , notably ranging from 250 to 1 ,000 g.mol " .
  • the tackifying resins may be selected from the group consisting of rosins and hydrogenated or non-hydrogenated rosin esters, aliphatic and aromatic hydrocarbon resins, and terpene resins.
  • Rosin is a mixture in majority comprising organic acids called rosin acids (mainly acids of the abietic type and of the pimaric type).
  • rosin obtained by incision in living trees
  • wood rosin rosin obtained by incision in living trees
  • wood rosin rosin from wood
  • tall oil rosin obtained from a by-product stemming from papermaking.
  • Rosin derivatives may in particular stem from the polymerization, hydrogenation and/or esterification of rosin acids. Rosin derivatives may thus be selected from rosin esters, in particular stemming from polyhydric alcohols such as ethylene glycol, glycerol, pentaerythritol and more particularly stemming from glycerol and pentaerythritol. Mention may for example be made of rosin esters marketed under the reference FORAL 85, PENTALYN H and STAYBELITE ESTER 10 by HERCULES; SYLVATAC 95 and ZONESTER 85 by ARIZONA CHEMICAL or further UNIREZ 3013 by UNION CAMP.
  • hydrocarbon tackifying resin is meant a polymer or copolymer of olefins or a polymer or copolymer of aromatic hydrocarbon monomers.
  • Said polymer may be hydrogenated, partly hydrogenated, or non-hydrogenated, preferably the tackifying resin is hydrogenated.
  • the tackifying resin preferably has a softening temperature of less than 120 °C, preferably of less than 1 10 °C.
  • the measurement of the softening temperature is carried out according to the ring-and-ball method according to the ASTM D36 standard.
  • NBA 440 available from Normalab is used.
  • the fluid used for the measurement is glycerol.
  • the tackifying resins are selected from the group consisting of: indene hydrocarbon resins, pentanediene aliphatic resins, pentanediene and indene mixed resin, diene resins of cyclopentanediene dimers, diene resins of isoprene dimers, hydrogenated resins stemming from the polymerization of pentanediene, and mixtures thereof.
  • indene hydrocarbon resins mention may notably be made of resins stemming from the polymerization in a majority proportion of indene monomer and in a minority proportion of a monomer selected from styrene, methylindene, methylstyrene, and mixtures thereof. These resins may optionally be hydrogenated. These resins may have a molecular weight ranging from 290 to 1 ,150 g/mol.
  • indene resins mention may be made of those marketed under the reference ESCOREZ 7105 by Exxon Chem., NEVCHEM 100 and NEVEX 100 by Neville Chem., NORSOLENE S105 by Sartomer, PICCO 6100 by Hercules and
  • ARKON M-135 by Arakawa As an aliphatic pentanediene resin, mention may in particular be made of those stemming from the majority polymerization of 1 ,3-pentanediene (trans- or c/s-piperylene) monomers and of a minority monomer selected from isoprene, butane, 2-methyl-2-butene, pentene, 1 ,4-pentanediene, and mixtures thereof. These resins may have a molecular weight ranging from 1 ,000 to 2,500 g/mol.
  • Such resins of 1 ,3-pentanediene are for example marketed under the references PICCOTAC 95 by Eastman Chemical, ESCOREZ 1304 by Exxon Chemicals., NEVTAC 100 BY Neville Chem. or WINGTACK 95 by Goodyear.
  • mixed pentanediene and indene resins which stem from the polymerization of a mixture of pentanediene and indene monomers such as those described above, mention may be made of the resins marketed under reference ESCOREZ 21 01 by Exxon Chemicals, NEVPENE 9500 by Neville Chem., HERCOTAC 1 148 by Hercules., NORSOLENE A 100 by Cray Valley, resins marketed under reference NORSOLENE S1 25, NORSOLENE S1 35, NORSOLENE S145 and NORSOLENE S155 from Cray Valley, WINGTACK 86, WINGTACK
  • diene resins of cyclopentanediene dimers of those stemming from the polymerization of the first monomer selected from indene and styrene and of the second monomer selected from cyclopentanediene dimers such as dicyclopentanediene, methyldicyclopentanediene, other pentanediene dimers, and mixtures thereof.
  • These resins generally have a molecular weight ranging from 500 to 800 g/mol, such as for example those marketed under the reference BETAPRENE BR 1 00 by Arizona Chemical Co., NEVILLE LX-685-125 and NEVILLE LX-1 000 by Neville Chem., PICCODIENE 2215 by Hercules, PETRO-REZ 200 by Lawter, RESINALL
  • terpene resins stemming from the polymerization of at least one monomer selected from oc-pinene, ⁇ -pinene, limonene, and mixtures thereof. These resins may have a molecular weight ranging from 300 to 2,000 g/mol. Such resins are marketed for example under the names of PICCOLYTE A1 1 5 and S1 25 by Hercules, ZONAREZ 71 00 or ZONATAC 105 LITE by ARIZONA Chem.
  • the resin is selected from indene hydrocarbon resins in particular hydrogenated indene/methylstyrene/styrene copolymers marketed under the name of « REGALITE » by Eastman Chemical, such as REGALITE R 1 100, REGALITE R 1090, REGALITE S7125 REGALITE R- 7100, REGALITE R1010 HYDROCARBON RESIN, REGALITE R1 125 HYDROCARBON RESIN.
  • indene hydrocarbon resins in particular hydrogenated indene/methylstyrene/styrene copolymers marketed under the name of « REGALITE » by Eastman Chemical, such as REGALITE R 1 100, REGALITE R 1090, REGALITE S7125 REGALITE R- 7100, REGALITE R1010 HYDROCARBON RESIN, REGALITE R1 125 HYDROCARBON RESIN.
  • the adhesive article according to the invention preferably comprises between 45% and 55% by weight of tackifying resin(s) based on the total weight of said article.
  • the adhesive articles of the invention may comprise and preferentially further comprise one or several plasticizers.
  • these articles comprise less than 15% by weight of plasticizer based on the total weight of said article.
  • the mass content of plasticizer ranges from 0% to 15%, preferentially from 1 % to 10%, and still preferentially from 5% to 10%. Based on the total mass of the adhesive article.
  • plasticizers adapted for the present invention mention may notably be made of hydrocarbon plasticizers.
  • plasticizers such as glycols and their derivatives, such as diethylene glycol ethylether, diethylene glycol methylether, diethylene glycol butylether or further diethylene glycol hexylether, ethylene glycol ethylether, ethylene glycol methylether, ethylene glycol butylether, ethylene glycol hexylether, glycol esters, derivatives of propylene glycol and in particular propylene glycol phenylether, propylene glycol diacetate, dipropylene glycol butylether, tripropylene glycol butylether, propylene glycol methylether, dipropylene glycol ethylether, tripropylene glycol methylether and diethylene glycol methylether, propylene glycol butylether, esters of notably carboxylic acids, such as citrates, notably trimethyl citrate, tributyl citrate, trimethyl acetylc
  • customary plasticizers such as glycols and
  • the adhesive articles of the invention may also further comprise one or several antioxidants.
  • antioxidant agents » it is meant to designate here the compounds commonly used by one skilled in the art for ensuring stability towards oxygen, heat, ozone and ultraviolet radiations, the compounds used, in particular tackifying resins and block copolymers. One or several of these associated antioxidant agents may be used.
  • antioxidant agents examples include phenolic antioxidants such as in particular the products marketed by BASF under the names of IRGANOX ® 1010, IRGANOX ® 565, IRGANOX ® 1076 and sulfur-containing antioxidants such as for example zinc dibutyl dithiocarbamate marketed by « Performance additives Italy S.p.A. » under the name of PERKACIT ZDBC.
  • phenolic antioxidants such as in particular the products marketed by BASF under the names of IRGANOX ® 1010, IRGANOX ® 565, IRGANOX ® 1076 and sulfur-containing antioxidants such as for example zinc dibutyl dithiocarbamate marketed by « Performance additives Italy S.p.A. » under the name of PERKACIT ZDBC.
  • the antioxidant mass content ranges from 0% to 5%, preferentially from 0.05% to 1 %.
  • the adhesive composition may further comprise other ingredients commonly used in cosmetic compositions and known to one skilled in the art as being able to be incorporated into an adhesive composition for a nail make-up article.
  • Such ingredients may be selected from pigments and coloring agents, plasticizers, coalescence agents, preservatives, oils, waxes, agents against free radicals, spreading agents, wetting agents, dispersant agents, antifoam agents, preservatives, surfactants, perfumes, neutralizers, stabilizers, antioxidants, thickeners, wherein the actives may be selected from essential oils, UV/solar screens, moisturizing agents, vitamins, proteins, ceramides, vegetable extracts, etc., and mixtures thereof.
  • composition according to the invention may further comprise as actives, nail care agents such as hardening agents for keratinic materials, actives acting on the growth of the nail such as for example methyl sulfonyl methane and/or actives for treating diverse affections localized at the nail, such as for example onichomycosis.
  • nail care agents such as hardening agents for keratinic materials
  • actives acting on the growth of the nail such as for example methyl sulfonyl methane and/or actives for treating diverse affections localized at the nail, such as for example onichomycosis.
  • the present invention also relates to a method for preparing an adhesive article as defined above, comprising the following steps:
  • step b) adding to the mixture obtained at the end of step a) of at least one block copolymer
  • step b) optionally coating a layer of the product obtained at the end of step b), with a thickness ranging from 100 ⁇ to 500 ⁇ , preferably from 200 ⁇ to 500 ⁇ , on a substrate, notably a silicone film, in order to obtain said adhesive article.
  • the first step according to this method consists of preparing a liquid and homogeneous mixture comprising the tackifying resin (or a mixture thereof if necessary) and an optional plasticizer. Preferably, this step comprises heating under stirring of said mixture.
  • the step a) is carried out at a temperature ranging from 120 °C to 180°C.
  • this step also comprises the heating of said mixture comprising the optional plasticizer, the tackifying resin and the block copolymer(s).
  • step b) is carried out at a temperature ranging from 140 °C to
  • an adhesive composition is obtained which may be coated according to a layer with a thickness ranging from 100 ⁇ to 500 ⁇ , preferably from 200 ⁇ to 500 ⁇ , on a suitable substrate, for example on a silicone film.
  • the present invention also relates to a method for make-up and/or care of nails and/or false nails consisting of applying on a nail and/or a false nail an adhesive article as described above.
  • the present invention is also directed to a method for make-up and/or care of nails and/or false nails comprising the following steps:
  • an adhesive article for make-up and/or care of nails and/or false nails comprising an adhesive layer, the glassy transition temperature of which (Tg) is comprised between -30 °C and 20 °C, preferably comprised between -10°C and 10 °C ;
  • said adhesive layer preferably comprises:
  • the make-up and/or care method for nails and/or for false nails as described above involves the use of an adhesive article according to the invention as defined above.
  • step b') consisting of cooling said adhesive article in order to remove it from the nail and/or false nail is carried out by means of a cooling aerosol comprising a liquefied gas such as dimethyl ether, C C 5 alkanes and hydrochlorofluoroalkanes.
  • a cooling aerosol comprising a liquefied gas such as dimethyl ether, C C 5 alkanes and hydrochlorofluoroalkanes.
  • Cooling aerosols based on dimethylether are notably marketed under the reference « Tensocold ® Spray cryogen » by BSN medical GmbH.
  • cooling aerosols based on hydrochlorofluoroalkanes are notably marketed under reference « Refrigerant -55°C » (Coolant -55°C) by Henkel Teifcinologies France.
  • the sequence of both steps a') and b') above forms a make-up/make-up removal cycle which may be repeated several times. These steps may be spaced out in time, these steps may thus be spaced out by several minutes, hours or even several days.
  • the user may thus carry out one, two, three, or up to about ten make-up/make-up removal cycles.
  • the present invention also relates to a method for make-up removal from nails and/or false nails obtained at the end of the make-up method as defined above, i.e. from nails and/or false nails on which an adhesive article has been applied, as described above, said make-up removal method comprising a step for reducing the temperature of the adhesive layer to below its glassy transition temperature for removing it from the nails and/or false nails.
  • the present invention also relates to a method for removing make-up from nails or false nails covered with adhesive layer, the glassy transition temperature (Tg) of which is comprised between -30 °C and 20 °C, said method consisting of removing from the nails and/or false nails said adhesive layer by reducing its temperature to below its glassy transition temperature.
  • Tg glassy transition temperature
  • this adhesive layer is as defined above.
  • the step for reducing the temperature of the adhesive layer is carried out as indicated above by means of a cooling aerosol.
  • weight percentages given in this application may be assimilated to the dry material weight percentage of the applied compounds.
  • « comprise(s) one » or « include(s) one » should be understood as « comprise(s) at least one » or « include(s) at least one » unless explicitly indicated otherwise.
  • Example 1 Preparation of an adhesive article according to the invention An adhesive article according to the invention was prepared on the basis of an adhesive layer, the composition of which is indicated in the table below.
  • the tackifying resin (Regalite R1090), the plasticizer (Primol 352), and the antioxidant were mixed and then heated with stirring to 170°C.
  • the mixture of block copolymers was gradually incorporated while maintaining stirring and the temperature to 170°C until a homogeneous mixture was obtained.
  • the obtained adhesive was then coated on a silicone film to a thickness of 250 microns. After cooling, the adhesive layer was applied under a false nail bearing the reference « EDGE FASHION NAILS » of the FING'RS ® brand.
  • Example 2 Make-up of false nails and make-up removal
  • the adhesive article of Example 1 was applied onto a nail. During the application, care was taken to remove the counter-adhesive silicone film beforehand. The thereby obtained article for the make-up of the nails was then removed by projecting a liquefied gas on the nails.
  • a cooling aerosol based on hydrochlorofluoroalkanes available from Henkel Technologies France under reference « Refrigerant -55 °C » was used.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

La présente invention porte sur un article adhésif pour le maquillage et/ou les soins des ongles et/ou de faux ongles comprenant une couche adhésive ayant une épaisseur allant de 200 µm à 500 µm, ladite couche comprenant de 30 % à 60 % en poids, par rapport au poids total dudit article, d'un copolymère séquencé ou d'un mélange de copolymères séquencés ; de 40 % à 60 % en poids, par rapport au poids total dudit article, d'au moins une résine donnant du collant ayant une masse moléculaire moyenne en nombre inférieure ou égale à 10 000 g.mol-1 ; et éventuellement, et de préférence, au moins un plastifiant.
PCT/EP2013/075533 2012-12-05 2013-12-04 Article de maquillage d'ongles pouvant être enlevé à froid WO2014086859A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1261669A FR2998767B1 (fr) 2012-12-05 2012-12-05 Article de maquillage des ongles demaquillable au froid
FR1261669 2012-12-05

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WO2014086859A1 true WO2014086859A1 (fr) 2014-06-12

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990013420A1 (fr) * 1989-05-11 1990-11-15 Landec Labs, Inc. Ensembles adhesifs actives par la temperature
WO2003027182A1 (fr) * 2001-09-25 2003-04-03 Exxonmobil Chemical Patents Inc. Copolymeres sequences radiaux et adhesifs a base de ces copolymeres presentant de meilleures caracteristiques de decoupage a la presse
WO2006041736A1 (fr) * 2004-10-08 2006-04-20 Exxonmobil Chemical Patents Inc. Combinaisons d'agent gluant et d'huile polyalphaolefinique
WO2006107763A2 (fr) * 2005-04-06 2006-10-12 Henkel Corporation Adhesifs thermofusibles sensibles a la pression a base de melanges de copolymeres de styrene/butadiene
WO2007078486A2 (fr) * 2005-12-21 2007-07-12 Avon Products, Inc. Adhesifs autocollants pour applications cosmetiques
WO2009097517A1 (fr) * 2008-01-30 2009-08-06 L'oreal S.A. Article adhésif contenant un colorant et/ou un agent actif
FR2949679A1 (fr) * 2009-09-08 2011-03-11 Oreal Procede de maquillage des ongles et article pour la mise en oeuvre du procede
FR2959918A1 (fr) * 2010-05-11 2011-11-18 Oreal Article souple pour les ongles a couche adhesive amelioree

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990013420A1 (fr) * 1989-05-11 1990-11-15 Landec Labs, Inc. Ensembles adhesifs actives par la temperature
WO2003027182A1 (fr) * 2001-09-25 2003-04-03 Exxonmobil Chemical Patents Inc. Copolymeres sequences radiaux et adhesifs a base de ces copolymeres presentant de meilleures caracteristiques de decoupage a la presse
WO2006041736A1 (fr) * 2004-10-08 2006-04-20 Exxonmobil Chemical Patents Inc. Combinaisons d'agent gluant et d'huile polyalphaolefinique
WO2006107763A2 (fr) * 2005-04-06 2006-10-12 Henkel Corporation Adhesifs thermofusibles sensibles a la pression a base de melanges de copolymeres de styrene/butadiene
WO2007078486A2 (fr) * 2005-12-21 2007-07-12 Avon Products, Inc. Adhesifs autocollants pour applications cosmetiques
WO2009097517A1 (fr) * 2008-01-30 2009-08-06 L'oreal S.A. Article adhésif contenant un colorant et/ou un agent actif
FR2949679A1 (fr) * 2009-09-08 2011-03-11 Oreal Procede de maquillage des ongles et article pour la mise en oeuvre du procede
FR2959918A1 (fr) * 2010-05-11 2011-11-18 Oreal Article souple pour les ongles a couche adhesive amelioree

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FR2998767B1 (fr) 2015-01-16

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