WO2014048279A1 - 水蒸气裂解催化剂及其制法和水蒸气裂解氢燃烧方法 - Google Patents
水蒸气裂解催化剂及其制法和水蒸气裂解氢燃烧方法 Download PDFInfo
- Publication number
- WO2014048279A1 WO2014048279A1 PCT/CN2013/083906 CN2013083906W WO2014048279A1 WO 2014048279 A1 WO2014048279 A1 WO 2014048279A1 CN 2013083906 W CN2013083906 W CN 2013083906W WO 2014048279 A1 WO2014048279 A1 WO 2014048279A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- water vapor
- steam
- steam cracking
- hydrogen
- cracking
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 84
- 239000001257 hydrogen Substances 0.000 title claims abstract description 81
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 81
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 79
- 238000004230 steam cracking Methods 0.000 title claims abstract description 77
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 45
- 238000000034 method Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 115
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 47
- 238000005336 cracking Methods 0.000 claims abstract description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 34
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 21
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 13
- 239000011733 molybdenum Substances 0.000 claims abstract description 13
- 229910052742 iron Inorganic materials 0.000 claims abstract description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 10
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 7
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 239000001301 oxygen Substances 0.000 claims abstract description 7
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 7
- 239000000853 adhesive Substances 0.000 claims abstract description 3
- 230000001070 adhesive effect Effects 0.000 claims abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 60
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical group [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 30
- 239000000843 powder Substances 0.000 claims description 24
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 21
- 229910052748 manganese Inorganic materials 0.000 claims description 21
- 239000011572 manganese Substances 0.000 claims description 21
- 238000009841 combustion method Methods 0.000 claims description 19
- 239000007789 gas Substances 0.000 claims description 16
- 229910052961 molybdenite Inorganic materials 0.000 claims description 14
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 14
- 239000011780 sodium chloride Substances 0.000 claims description 13
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- 235000019353 potassium silicate Nutrition 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 7
- 239000003345 natural gas Substances 0.000 claims description 5
- 238000010298 pulverizing process Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- 239000002826 coolant Substances 0.000 claims description 3
- 239000003502 gasoline Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 150000001339 alkali metal compounds Chemical class 0.000 claims description 2
- 150000002697 manganese compounds Chemical class 0.000 claims description 2
- 239000005078 molybdenum compound Substances 0.000 claims description 2
- 150000002752 molybdenum compounds Chemical class 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 10
- 239000000126 substance Substances 0.000 abstract description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract description 5
- 239000008246 gaseous mixture Substances 0.000 abstract 3
- 238000000748 compression moulding Methods 0.000 abstract 1
- 239000003245 coal Substances 0.000 description 11
- 238000004523 catalytic cracking Methods 0.000 description 6
- 230000005611 electricity Effects 0.000 description 5
- 238000004880 explosion Methods 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000003344 environmental pollutant Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005381 potential energy Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 235000015842 Hesperis Nutrition 0.000 description 1
- 235000012633 Iberis amara Nutrition 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- -1 hydrogen ions Chemical class 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/20—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
- F02C3/22—Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being gaseous at standard temperature and pressure
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/04—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of inorganic compounds, e.g. ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
- B01J27/051—Molybdenum
- B01J27/0515—Molybdenum with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- the present invention provides a steam cracking catalyst, characterized in that the catalyst comprises the following elements: iron, aluminum, molybdenum, platinum, manganese and an alkali metal; wherein the iron and the aluminum are each elemental substance, the molybdenum
- the platinum, the manganese, and the alkali metal are each a simple substance or a compound.
- the iron is 3-10% by weight
- the aluminum is 15-30% by weight
- the platinum element is 1-10% by weight
- the sodium chloride salt is 1- 10% by weight
- the molybdenum ore is 10-20% by weight
- the manganese ore is 10-40% by weight.
- the catalyst prepared by this formulation not only further reduces the cost, but also has a better catalytic effect.
- the combustion zone may be in various locations where heating is required, such as when the steamer is used to heat steam to produce steam, which is the furnace of the boiler.
- the boiler can be an existing boiler or a simpler boiler designed specifically for burning hydrogen.
- Water vapor for cracking Water vapor for cracking; water vapor from the cycle cracking enters the pressure vessel 1 from the inlet 7, and the pressure vessel is filled with the steam cracking catalyst provided by the present invention, and the water vapor is in the pressure vessel Catalytic cracking by a steam cracking catalyst; oxygen, hydrogen and uncracked water vapor outlet 8 produced by cracking are sent to a combustion station 9 through a pipe, here a nozzle placed in the boiler; the ignition agent 2 is also passed through another pipe It is sent to the burning place 9, and is ignited at the burning place.
- the number of the heads can be set to one or more as needed, for example, two, three or four.
- a steamer with a steaming pot of 0.5 tons (with one nozzle) as an example starts to use steam to produce steam, and about 8% by weight of water vapor of the generated steam is used for catalytic cracking, in a pressure vessel.
- About 1 kg of the steam cracking catalyst prepared in Example 3 was charged, and the ignition agent was ethanol.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015533428A JP6309528B2 (ja) | 2012-09-27 | 2013-09-22 | 水蒸気分解用触媒、及びその製造方法、並びに水蒸気分解で得られた水素ガスの燃焼方法 |
US14/431,671 US10006362B2 (en) | 2012-09-27 | 2013-09-22 | Vapor cracking catalyst, preparation method thereof, and combustion method of hydrogen obtained by vapor cracking |
EP13840352.2A EP2902359A4 (en) | 2012-09-27 | 2013-09-22 | STEAM CRACKING CATALYST, PROCESS FOR PREPARING THE SAME, AND METHOD OF COMBUSTING HYDROGEN OBTAINED BY STEAM CRACKING |
EA201590639A EA029250B1 (ru) | 2012-09-27 | 2013-09-22 | Катализатор парофазного крекинга, способ его приготовления и способ сжигания водорода, полученного парофазным крекингом |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210364826.7 | 2012-09-27 | ||
CN201210364826.7A CN103691459B (zh) | 2012-09-27 | 2012-09-27 | 水蒸汽裂解催化剂及其制法和水蒸汽裂解氢燃烧方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2014048279A1 true WO2014048279A1 (zh) | 2014-04-03 |
Family
ID=50353218
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2013/083906 WO2014048279A1 (zh) | 2012-09-27 | 2013-09-22 | 水蒸气裂解催化剂及其制法和水蒸气裂解氢燃烧方法 |
Country Status (6)
Country | Link |
---|---|
US (1) | US10006362B2 (zh) |
EP (1) | EP2902359A4 (zh) |
JP (1) | JP6309528B2 (zh) |
CN (1) | CN103691459B (zh) |
EA (1) | EA029250B1 (zh) |
WO (1) | WO2014048279A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10006362B2 (en) | 2012-09-27 | 2018-06-26 | Huaichao Chen | Vapor cracking catalyst, preparation method thereof, and combustion method of hydrogen obtained by vapor cracking |
CN115818568A (zh) * | 2022-11-25 | 2023-03-21 | 王凯 | 一种裂解水蒸汽制氢的裂解剂、制备、使用及其复活方法 |
Families Citing this family (8)
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CN105986902A (zh) * | 2015-03-02 | 2016-10-05 | 袁志平 | 燃水涡轮发动机 |
CN104807013B (zh) * | 2015-05-08 | 2017-12-19 | 陈怀超 | 燃烧器喷头及具有它的燃烧器和水蒸汽裂解氢气燃烧方法 |
CN105645352A (zh) * | 2015-12-26 | 2016-06-08 | 杜善骥 | 核能激光炭的镍铁氧体(cnf)制氢氧方法 |
CN106185802A (zh) * | 2016-07-02 | 2016-12-07 | 关笑天 | 水解氢能燃烧方法及装置 |
CN110857404A (zh) * | 2018-08-24 | 2020-03-03 | 重庆奥图美腾环保科技有限公司 | 车用助燃添加剂及使用方法 |
CN111001421A (zh) * | 2019-04-28 | 2020-04-14 | 蔡勇梅 | 一种水蒸气制氢催化剂及其制法、应用和燃烧装置 |
CN110360591A (zh) * | 2019-08-23 | 2019-10-22 | 蔡勇梅 | 一种天然气加氢低氮燃烧装置 |
CN115010086B (zh) * | 2022-05-20 | 2024-01-26 | 泰州中和氢能源科技有限公司 | 一种制氢用裂解剂、其制备方法及使用其制备氢气的方法 |
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US1401927A (en) * | 1920-07-09 | 1921-12-27 | George W Sargent | Process of recovering molybdenum from molybdenite |
US2462499A (en) * | 1947-09-27 | 1949-02-22 | Mellon Inst Of Ind Res | Process for recovering manganese values from manganese ores |
US3661555A (en) * | 1969-06-24 | 1972-05-09 | Showa Denko Kk | Pelletized chromium addition agents for ferro alloys production and method therefor |
US3617497A (en) * | 1969-06-25 | 1971-11-02 | Gulf Research Development Co | Fluid catalytic cracking process with a segregated feed charged to the reactor |
US4640221A (en) * | 1985-10-30 | 1987-02-03 | International Business Machines Corporation | Vacuum deposition system with improved mass flow control |
GB8617831D0 (en) * | 1986-07-22 | 1986-08-28 | British Petroleum Co Plc | Production of porous shaped articles |
DE4026351A1 (de) * | 1990-08-21 | 1992-02-27 | Bayer Ag | Verfahren und vorrichtung zur herstellung von tabletten aus metallpulver und deren verwendung als katalysatoren |
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JP2002069558A (ja) * | 2000-09-05 | 2002-03-08 | Mitsubishi Heavy Ind Ltd | 水素発生用燃料及び水素発生装置及び水素発生方法 |
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Publication number | Publication date |
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EP2902359A1 (en) | 2015-08-05 |
CN103691459A (zh) | 2014-04-02 |
JP2015532195A (ja) | 2015-11-09 |
EA029250B1 (ru) | 2018-02-28 |
EP2902359A4 (en) | 2016-10-12 |
JP6309528B2 (ja) | 2018-04-11 |
CN103691459B (zh) | 2016-06-29 |
EA201590639A1 (ru) | 2015-07-30 |
US10006362B2 (en) | 2018-06-26 |
US20150275754A1 (en) | 2015-10-01 |
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