WO2014001274A1 - Procede de separation d'au moins un premier element chimique e1 d'au moins un deuxieme element chimique e2 impliquant l'utilisation d'un milieu comprenant un sel fondu specifique - Google Patents
Procede de separation d'au moins un premier element chimique e1 d'au moins un deuxieme element chimique e2 impliquant l'utilisation d'un milieu comprenant un sel fondu specifique Download PDFInfo
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- WO2014001274A1 WO2014001274A1 PCT/EP2013/063179 EP2013063179W WO2014001274A1 WO 2014001274 A1 WO2014001274 A1 WO 2014001274A1 EP 2013063179 W EP2013063179 W EP 2013063179W WO 2014001274 A1 WO2014001274 A1 WO 2014001274A1
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B60/00—Obtaining metals of atomic number 87 or higher, i.e. radioactive metals
- C22B60/02—Obtaining thorium, uranium, or other actinides
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- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C19/00—Arrangements for treating, for handling, or for facilitating the handling of, fuel or other materials which are used within the reactor, e.g. within its pressure vessel
- G21C19/42—Reprocessing of irradiated fuel
- G21C19/44—Reprocessing of irradiated fuel of irradiated solid fuel
- G21C19/48—Non-aqueous processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Definitions
- the present invention relates to a method of separating at least a first chemical element Ei from at least a second chemical element E 2 involving the use of a medium comprising a specific molten salt.
- This process may be particularly applicable in the field of reprocessing of spent nuclear fuels, in particular for separating actinide elements from fission products (such as lanthanides, transition elements, such as molybdenum, zirconium, etc.). , yttrium, noble metals, such as ruthenium, rhodium).
- an organic phase comprising uranium and plutonium; and an aqueous phase comprising minor actinides (such as americium and curium) and fission products, which is also called "PUREX raffinate".
- the organic phase comprising uranium and plutonium undergoes an extraction step, so as to isolate uranium from plutonium, which can be reused to make uranium-based and / or plutonium-based fuels.
- the PUREX process is now used in high-capacity commercial plants, typically with a reprocessing rate of around 1000 t / year. In particular, it has benefited from numerous improvements, which have made it a reliable, robust process that produces little secondary waste.
- the organic solvent used as extractant is sensitive to irradiation, which imposes for high burnup fuels, long cooling times before reprocessing;
- the fuel must be dissolved beforehand in nitric acid, which is a problem in the case of refractory fuels insoluble in nitric acid.
- molten salts can dissolve the fuels, dedicated targets and refractory matrices quite easily for the reactors of the future. They use radiation-insensitive and neutron-transparent reagents, which makes it possible to reprocess fuels with a low burnup rate, without criticality constraints. Finally, they do not make it possible to obtain a pure plutonium flux directly and can therefore be considered as less proliferating than the PUREX process.
- the molten salt medium based on a generally alkaline chloride (s) was mainly chosen as a solvent with respect to the fluoride-based molten salt medium ( s), because it poses less technological problems of implementation, lower working temperatures and corrosion problems easier to manage allowing the use of stainless steel.
- Fluoride-based molten salt medium produces fluoride-type waste streams which, unlike chlorides, are directly compatible with the glass containment matrix used in the reprocessing of spent fuels.
- the elements derived from the spent fuels must be separated selectively (for example, actinides with respect to the fission products), this selective separation being able to take two different technical routes (which does not exclude that they can be combined):
- the first step consists of a selective reductive extraction of the actinides by a phase comprising liquid aluminum in contact with the molten fluoride salt containing the dissolved fuel in the form of a fluoride.
- Aluminum acts both as a reducing agent and a solvent for actinides.
- the oxidation-reduction reaction can thus be described by the following equation (1): AnF 3 (if
- the second step consists of extracting the actinides from the metal phase comprising aluminum, for example by oxidative de-extraction.
- the metal phase comprising aluminum is brought into contact with a chloride salt containing an oxidizing agent, for example AICI 3 , in order to extract the actinides in the saline phase in the form of chlorides, this de-extraction reaction possibly being represented by the following equation (2):
- the actinide chlorides thus formed can be converted into oxide (s) and used again as fuel.
- spent fuel reprocessing processes employing a molten salt medium based on fluoride (s) therefore require that the elements that form the fuel are previously converted into fluorides and then introduced into the salt.
- This conversion is performed (after mechanical and thermal treatment of the fuel) during a step of hydrofluorination of the fuel by means of a chemical attack by gaseous hydrofluoric acid (dry fluorination).
- This operation is undoubtedly one of the most delicate and restrictive of the process, because it requires the implementation of a large use of toxic gas (HF), brought into contact with a highly active material.
- HF toxic gas
- the authors of the present invention have proposed to develop a method for separating at least one chemical element another chemical element both coexisting in oxide form involving the use of a molten salt medium based on fluoride (s) and not requiring a step of hydrofluorination of said oxides before contacting said oxides with said molten salt medium, this method being applicable to the reprocessing of spent fuel.
- the invention relates to a method for separating at least one first chemical element Ei from at least one second chemical element E 2 coexisting in a mixture in the form of oxides comprising the following steps:
- step b) a step of bringing the mixture resulting from step a) into contact with a medium comprising a metal in the liquid state, said metal being a reducing agent capable of reducing in a majority manner said at least one first chemical element Ei with respect to said at least one second chemical element E 2 , whereby it results, at the end of this step, a biphasic medium comprising a first phase, said metal phase, comprising said at least one first chemical element Ei in the oxidation state And a second phase, called the salt phase, comprising the molten salt of formula M F-AIF 3 mentioned above and a fluoride of the at least one second chemical element E 2 .
- the process of the invention makes it possible to separate at least one first chemical element Ei from at least one second chemical element E 2 initially coexisting in a mixture comprising one or more oxide forms of these elements while playing:
- a metal in the specific liquid state capable of reducing mainly the element Ei in a fluoride form to reduce the element Ei to its oxidation state 0 relative to the element E 2 in a fluoride form, said element Ei thus found in the metallic state and, concomitantly, embedded, in whole or in part, by chemical affinity, in the metal phase comprising the reducing metal in the liquid state, the element E 2 subsisting, in whole or in part, in the saline phase in a fluoride form.
- the element (s) Ei may be chosen from the group consisting of actinides (for example, uranium, plutonium and / or minor actinides, such as curium, americium and neptunium), transition elements (such as that zirconium or platinoid elements, such as rhodium, ruthenium, palladium), while the E 2 element or elements may be chosen from a group comprising no actinides, this group may comprise:
- lanthanides such as neodymium, europium, cerium
- alkaline or alkaline-earth elements such as strontium
- pnictogenic elements such as antimony
- the process of the invention can thus be part of the reprocessing of spent nuclear fuels, the transmutation targets used for the nuclear physics experiments or the refractory matrices. intended to enter the nuclear reactors, the elements E 2 can thus be considered as fission products.
- the process can be qualified as a DOS (DOS) process corresponding to the expression "Direct Oxide Solubilization”.
- the molten salt is a salt of formula MF-AIF 3 , in which M is an alkaline element.
- M is an element selected from Li, Na, K and mixtures thereof and more particularly Li.
- AIF 3 can play an important role in the mechanism of solubilization of oxides, solubilization of oxides being conventionally favored by increasing the molar content of AIF 3 salt.
- the efficiency of the reductive extraction (corresponding to the above-mentioned step b) can also depend on the AlF3 content of the salt, which can be promoted by the use of the least fluoroacid salt. i.e. the least rich salt in AIF 3 . It can, therefore, exist an antagonistic effect, between the solubilization efficiency of the oxides and the performance of the reductive extraction, which is directly related to the molar content of AIF 3 in the molten salt.
- the molar AIF 3 content of the molten salt can be in a range of 10% to 40% molar.
- the molar content of AIF 3 may range from 15% to 25% by mol, preferably from 25% to 35% by weight. molar%.
- the metal in the liquid state is a metal chosen for its reducing properties with respect to the element (s) Ei with respect to the element or elements E 2 that it is desired to separate.
- an effective metal is chosen from aluminum and its alloys.
- this metal may be in the form of an aluminum alloy and an element chosen from metal elements meeting the following criteria:
- a metallic element that responds favorably to these specificities is copper.
- the copper used in the constitution of the aluminum alloy does not contribute to the reduction as such but contributes to increasing the metal phase and, consequently, facilitates the separation by settling between the phase metallic and saline phase.
- Step a) can be implemented, in order to make it possible to optimize the solubilization of the oxides, in an atmosphere with the lowest oxygen partial pressure possible.
- step a) can be carried out under an inert atmosphere, that is to say an atmosphere comprising an inert gas, such as argon, nitrogen. From a practical point of view, this may consist in setting up a system of constant gas circulation, in particular with a view to eliminating the oxygen possibly released by the solubilization of the oxides.
- this system may be equipped with at least one inert gas purification unit.
- the step a) can be carried out, advantageously, at a sufficiently high temperature to facilitate the solubilization in the molten salt of the oxides, this temperature being directly dependent on the oxides concerned.
- the temperature It can be set at a value of 760 and 860 ° C, knowing that it is preferable not to exceed 860 ° C to avoid significant evaporation of AIF 3 .
- step a) can be carried out with stirring, for example: by mechanical means, for example, by means of a rotary vane; by a countercurrent system, especially when the process is implemented continuously; and or
- step a) and step b) are carried out simultaneously, stirring will also concern the medium comprising the metal in the liquid state, which will allow:
- a step of readjustment of the molar composition of the molten salt can be provided.
- the amount of AIF 3 is subject to two variations during the implementation of the method of the invention.
- the solubilization of the oxides, during step a) leads to a consumption of AIF 3 , resulting in a depletion in AIF 3 of the molten salt.
- the implementation of step b) when the metal in the liquid state is aluminum or a mixture thereof, results in the formation of AIF 3 (hence an enrichment in AIF 3 molten salt). It may therefore be appropriate to establish a mass balance between consumption and production of AIF 3 in order to carry out, if necessary, a readjustment of the molar composition of salt.
- step a) a step of determining the quantity of alumina in the mixture of step a) (the formation of which may be caused by the solubilization of the oxides in the molten salt of step a)), so that the latter does not exceed 3% by weight relative to the total mass of the mixture, a value beyond which the solubilization of the oxides begins to decrease seriously.
- step a) it may be provided a step of withdrawing the mixture of step a) (the withdrawn portion can be conveyed to a purification unit, so as to eliminate the alumina) and replacing the portion withdrawn with a molten salt free of alumina.
- the process may comprise, before the implementation of step a), a step of preparing the mixture of powders for step a), this preparation step may consist of a step of converting this product into a mixture comprising a powder of one or more oxides of said at least one first chemical element Ei and a powder of one or more oxides of said at least one second chemical element E 2 .
- the above-mentioned preparation step can take two distinct ways:
- the first variant a route involving a mechanical treatment operation of the spent fuel to form an oxide powder and a volumetric heat treatment operation to eliminate the fission products
- a route involving a voloxidation operation hereinafter referred to as the second variant
- the method comprises a fuel grinding operation intended to obtain a sufficiently fine oxide powder, for example, having an average particle diameter ranging from 50 to ⁇ .
- a fuel grinding operation intended to obtain a sufficiently fine oxide powder, for example, having an average particle diameter ranging from 50 to ⁇ .
- all or part of the gaseous or volatile fission products Kr, Xe, I, Br
- the resulting powder will undergo a heat treatment operation to remove volatile fission products, which heat treatment operation may consist of a volarbreaking at a temperature ranging from 800 ° C to 1500 ° C in a controlled atmosphere (e.g. argon at 5% hydrogen).
- a controlled atmosphere e.g. argon at 5% hydrogen.
- the method comprises a mechanical and thermal treatment operation in a single step, this operation possibly consisting of a voloxidation by means of which the uranium oxide U0 2 is converted into uranium oxide U 3 0 8 .
- this operation may consist of a high temperature oxidation, for example, at a temperature ranging from 480 ° C. to 600 ° C., of fuel for converting U0 2 to U 3 0 8 .
- Oxidation causes fragmentation (by increasing the volume) of the fuel, which is thus reduced to a fine powder.
- gaseous and volatile fission products should be removed during this step and, if necessary, re-routed to a vitrification unit.
- the conversion of the fuel into a fine powder should greatly favor the kinetics of dissolution of the oxides in the salt (by increasing the specific surface area).
- the conversion step will advantageously be implemented according to the modalities of the second variant described above.
- step a) and step b) mentioned above may be performed successively (hereinafter, first embodiment) or simultaneously (said, below, second embodiment).
- step a) and before step b) a digestion step , in the case where they are present in the mixture resulting from step a), the element or elements chosen from platinoid elements (such as Ru, Rh, Pd) and / or molybdenum (the latter being present when the the fuel is subjected to a prior vol-reduction step as mentioned above) or, if voloxidation / vol-reduction cycles are implemented, when the last cycle ends with a vol-reduction step.
- platinoid elements such as Ru, Rh, Pd
- molybdenum the element or elements chosen from platinoid elements (such as Ru, Rh, Pd) and / or molybdenum (the latter being present when the the fuel is subjected to a prior vol-reduction step as mentioned above) or, if voloxidation / vol-reduction cycles are implemented, when the last cycle ends with a vol-reduction step.
- this digestion step may consist in bringing the mixture resulting from step a) into contact with a medium comprising a metal in the liquid state, said metal being able to selectively adsorb the platinoid elements and / or molybdenum relative to the elements Ei (for example, actinides) and E 2 contained in the molten salt, this metal possibly being zinc alone or a zinc alloy, such as a zinc alloy with copper or a zinc alloy with nickel, whereby at the end of this step we obtain:
- step a which is now devoid of said platinoid element (s) and / or molybdenum; and a metal phase comprising the aforementioned liquid-state metal and said platinoid element (s) and / or molybdenum.
- this step is a function of the ability of the oxides, such as UO 2 , to solubilize in the salt in the absence of reducing agent, that is to say, the effectiveness of dissolving the oxides in a salt free of reducing metal phase.
- step b After the digestion step, it will follow a step of separation of said metal phase and said mixture of step a) now devoid of said platinoid element (s) and / or molybdenum, so that step b ) can be implemented.
- the metal phase resulting from said separation step may be subjected to a treatment step so as to recycle the zinc, for example, by simple vacuum evaporation, the platinoid element (s) and / or the molybdenum, when the zinc is initially alloyed. to copper and / or nickel, remaining in a mixture with copper and / or nickel, thus constituting a waste, which can be vitrified.
- a treatment step so as to recycle the zinc, for example, by simple vacuum evaporation, the platinoid element (s) and / or the molybdenum, when the zinc is initially alloyed. to copper and / or nickel, remaining in a mixture with copper and / or nickel, thus constituting a waste, which can be vitrified.
- the platinoid element (s) and / or molybdenum will then be extracted with the actinides during step b).
- This second embodiment does not allow the establishment of the digestion step as defined in the preceding paragraph, this role of digestion being assigned to the metal involved in step b).
- This second embodiment is, however, in the context of reprocessing, more advantageous than the first mode, in that it is easier to implement by reducing the number of steps.
- a first phase said metal phase comprising said at least one first chemical element Ei in oxidation state 0 and a second phase, so-called salt phase, comprising the molten salt of formula MF-AIF 3 and a fluoride of said at least one second chemical element E 2 .
- the metal phase may comprise:
- elements Ei actinides, certain transition elements such as zirconium, platinoid elements;
- transition elements such as those of E 1 (such as molybdenum, ytterbium);
- alkaline or alkaline-earth elements such as strontium
- pnictogenic elements such as antimony
- the method of the invention may comprise, after step b), a step c) of separating the metal phase from the salt phase.
- the metal phase, thus separated may be subjected to the following successive treatments:
- a molten chloride medium for example LiCl or LiCl-CaCl 2
- an oxidizing agent belonging to the chloride family for example, AICI 3
- actinide chloride (s) a step of converting the actinide chloride (s) into actinide oxide (s), for example, by oxidation with O 2 - ions generating the precipitation of said oxide (s); ) of actinide (s).
- the saline phase resulting from the separation step c) can be subjected to the following successive treatments:
- oxides of strategic interest more specifically, the oxides PuO 2 , UO 2 , U 3 O 8 , Nd 2 O 3 , Eu 2 0 3, Ce0 2, Zr0 2, Mo0 3, Y 2 0 3, SrO, Sb 2 0 3, PdO, Ru0 2 and Rh 2 0 3 in specific proportions
- oxides of strategic interest more specifically, the oxides PuO 2 , UO 2 , U 3 O 8 , Nd 2 O 3 , Eu 2 0 3, Ce0 2, Zr0 2, Mo0 3, Y 2 0 3, SrO, Sb 2 0 3, PdO, Ru0 2 and Rh 2 0 3 in specific proportions
- AIF 3 different molar compositions different molar compositions for Examples 1 to 3 explained below.
- the oxides mentioned above, in terms of the concentration introduced into the medium of the molten salt type correspond to the specificities mentioned in the following table.
- the concentration of the elements is determined in the two phases mentioned above:
- the percentage of unsolubilized oxide can be estimated from the following relation:
- : -xm met represents the percentage of the element m present in the metallic phase
- This coefficient of distribution indicates the quantity of the element m, present at the end of experimentation in the metal, relative to the initial amount introduced in oxide form into the crucible.
- actinides are very predominantly present in the aluminum phase.
- This example illustrates a campaign of studies conducted on the behavior of oxides of strategic interest as defined above according to the above procedure in a specific molten salt-type medium LiF-AIF 3 (having 35 mol% of AIF 3 ).
- the first of these two causes is perfectly illustrated for the platinoid elements (Ru and Rh). Indeed, they have positive log D m values, which means that these elements, once solubilized in L1F-AIF 3 , are mainly extracted by the metal phase. As shown in the table above, they are very little present in the metal phase, because of the very low solubility of these elements in L1F-AIF 3 (it is almost zero if the reducing metal is not present).
- the second of these causes is, for its part, perfectly illustrated for lanthanide elements as well as for yttrium and strontium. Indeed, these elements have Log D m and Log E m values very close, which shows that their respective oxides solubilize well in LiF-AIF 3 . These elements are very little extracted in the metal phase during the reductive extraction.
- Example 1 shows a recovery of 90% of the plutonium initially introduced into the crucible and a near-quantitative recovery of uranium in one step. It shows that the initial form of uranium oxide is compatible with the various heat treatments envisaged for the fuel.
- Example 1 is a perfect illustration of the feasibility of separating actinides / fission products in the context of a DOS process.
- This example illustrates a campaign of studies carried out on the behavior of oxides of strategic interest (more precisely, Pu0 2 , U0 2 , Nd 2 0 3 , Zr0 2 , Mo0 3 , PdO, Ru0 2 and Rh 2 0 3 ) according to the above-mentioned procedure in a molten salt-specific medium LiF-AIF 3 (having 15 mol% AIF 3 ).
- This example illustrates a campaign of studies conducted on the behavior of oxides of strategic interest (more precisely, Pu0 2 , Nd 2 0 3 , Zr0 2 , Mo0 3 , PdO, Ru0 2 and Rh 2 0 3 ) according to the mode above-mentioned procedure in a LiF-AIF-type molten salt-type medium 3 (having 25 mol% AIF 3 ).
- the distribution coefficients D An and E An obtained at the end of the experiments have values (Log E An > 0 or ⁇ 1) perfectly compatible with the implementation of the method of the invention for separation of actinides / fission products in the framework of spent fuel reprocessing.
- composition L1F-AIF 3 (comprising 35 mole% AlF 3 ), which is preferred to the others for facilitating the solubilization of the oxides, is well suited.
- the yields E m obtained after the experimental validation shows that it would be possible to recover more than 99% of the actinides setting up two extraction stages. After extraction, the separation factors between actinides and Fissions are sufficient to consider efficient fuel reprocessing. The addition of a washing stage, before the oxidative desextraction, should further increase the decontamination rates of actinide fission products.
- the actinides present in the irradiated fuel (U, Np, Pu, Am and Cm) remain grouped in the same flow, which gives the process a good resistance to proliferation and meets the objectives of the generation IV reactors. reduction of the harmfulness of long-lived waste.
- This process scheme is applicable to oxide fuels but also to carburized fuels (by applying an appropriate heat treatment).
- the scope of this process can be extended to the reprocessing of any irradiated fuels (such as nitrides), or target, since it is possible to convert them to the oxide at the head of the process, which confers on the process a great flexibility.
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Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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KR1020157002140A KR20150027259A (ko) | 2012-06-26 | 2013-06-25 | 특정 용융염을 함유하는 매질의 사용을 포함하는, 적어도 하나의 제2 화학원소 e2로부터 적어도 하나의 제1 화학원소 e1을 분리하는 방법 |
CN201380033651.4A CN104428429B (zh) | 2012-06-26 | 2013-06-25 | 使用含特殊熔盐介质的、将至少一种第一化学元素e1与至少一种第二化学元素e2分离的方法 |
US14/410,501 US9677156B2 (en) | 2012-06-26 | 2013-06-25 | Process for separating at least one first chemical element E1 from at least one second chemical element E2, involving the use of a medium comprising a specific molten salt |
RU2015102096A RU2015102096A (ru) | 2012-06-26 | 2013-06-25 | Способ отделения, по меньшей мере, одного первого химического элемента e1, по меньшей мере, от одного второго химического элемента e2, включающий использование среды, включающей определённую расплавленную соль |
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FR1256034 | 2012-06-26 | ||
FR1256034A FR2992330B1 (fr) | 2012-06-26 | 2012-06-26 | Procede de separation d'au moins un premier element chimique e1 d'au moins un deuxieme element chimique e2 impliquant l'utilisation d'un milieu comprenant un sel fondu specifique |
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PCT/EP2013/063179 WO2014001274A1 (fr) | 2012-06-26 | 2013-06-25 | Procede de separation d'au moins un premier element chimique e1 d'au moins un deuxieme element chimique e2 impliquant l'utilisation d'un milieu comprenant un sel fondu specifique |
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US (1) | US9677156B2 (fr) |
KR (1) | KR20150027259A (fr) |
CN (1) | CN104428429B (fr) |
FR (1) | FR2992330B1 (fr) |
RU (1) | RU2015102096A (fr) |
WO (1) | WO2014001274A1 (fr) |
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JP2015230170A (ja) * | 2014-06-03 | 2015-12-21 | 株式会社東芝 | 複合酸化物分離方法 |
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CN108504867B (zh) * | 2018-04-28 | 2019-08-27 | 长江师范学院 | 从钌废料中回收钌的碱性熔剂和钌的回收方法 |
GB2602339A (en) * | 2020-12-23 | 2022-06-29 | Richard Scott Ian | Molten salt coolant for nuclear reactor |
CA3192159A1 (fr) * | 2020-09-09 | 2022-03-17 | Ian Richard Scott | Fluide de refrodissement a sels fondus pour reacteur nucleaire |
CN113881862A (zh) * | 2021-09-08 | 2022-01-04 | 中国科学院上海应用物理研究所 | 氟化挥发技术分离铀和镎的方法 |
Citations (1)
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US20020005357A1 (en) * | 1998-09-11 | 2002-01-17 | Naruhito Kondo | Method of treating waste from nuclear fuel handling facility and apparatus for carrying out the same |
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NL250195A (fr) * | 1959-04-06 | 1900-01-01 | ||
GB0113749D0 (en) * | 2001-06-06 | 2001-07-25 | British Nuclear Fuels Plc | Actinide production |
JP5193687B2 (ja) * | 2008-05-30 | 2013-05-08 | 株式会社東芝 | 使用済み燃料再処理方法 |
FR2948126B1 (fr) * | 2009-07-17 | 2011-09-16 | Commissariat Energie Atomique | Procede d'extraction d'au moins un element chimique d'un milieu sel fondu |
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- 2013-06-25 RU RU2015102096A patent/RU2015102096A/ru not_active Application Discontinuation
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US20020005357A1 (en) * | 1998-09-11 | 2002-01-17 | Naruhito Kondo | Method of treating waste from nuclear fuel handling facility and apparatus for carrying out the same |
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CONOCAR O ET AL: "Distribution of actinides and lanthanides in a molten fluoride/liquid aluminum alloy system", JOURNAL OF ALLOYS AND COMPOUNDS, ELSEVIER SEQUOIA, LAUSANNE, CH, vol. 389, no. 1-2, 8 March 2005 (2005-03-08), pages 29 - 33, XP027812577, ISSN: 0925-8388, [retrieved on 20050308] * |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2015230170A (ja) * | 2014-06-03 | 2015-12-21 | 株式会社東芝 | 複合酸化物分離方法 |
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US9677156B2 (en) | 2017-06-13 |
RU2015102096A (ru) | 2016-08-10 |
FR2992330A1 (fr) | 2013-12-27 |
US20150340109A1 (en) | 2015-11-26 |
CN104428429B (zh) | 2017-12-05 |
FR2992330B1 (fr) | 2014-08-08 |
KR20150027259A (ko) | 2015-03-11 |
CN104428429A (zh) | 2015-03-18 |
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