WO2013172187A1 - Produit cosmétique de nettoyage à base d'huile - Google Patents

Produit cosmétique de nettoyage à base d'huile Download PDF

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Publication number
WO2013172187A1
WO2013172187A1 PCT/JP2013/062421 JP2013062421W WO2013172187A1 WO 2013172187 A1 WO2013172187 A1 WO 2013172187A1 JP 2013062421 W JP2013062421 W JP 2013062421W WO 2013172187 A1 WO2013172187 A1 WO 2013172187A1
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WIPO (PCT)
Prior art keywords
oil
acid
cleansing cosmetic
weight
based cleansing
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PCT/JP2013/062421
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English (en)
Japanese (ja)
Inventor
淳一 藤本
優 河合
祐子 矢部
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ロート製薬株式会社
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Publication of WO2013172187A1 publication Critical patent/WO2013172187A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers

Definitions

  • the present invention relates to an oil-based cleansing cosmetic. More specifically, the present invention relates to an oil-based cleansing cosmetic that can maintain high cleansing power and maintain excellent wash-off properties even when the skin is used in a state of being wet with a small amount of water. .
  • Oil-based cleansing cosmetics are mainly composed of a surfactant and a large amount of oil. A makeup cosmetic that is difficult to dissolve in water is dissolved in the oil, and the rinse water and the oil are emulsified with the surfactant. Cleansing ability is demonstrated by removing it.
  • cleansing cosmetics have been developed that are difficult to emulsify even if a small amount of water is mixed, and the cleansing ability is not easily lowered.
  • cleansing cosmetics have been reported in which an oily component is added to and mixed with a water phase containing a specific polyglycerin fatty acid ester, a trihydric or higher polyhydric alcohol and 30 to 70% water (patent) Reference 1).
  • a cosmetic containing a dextrin fatty acid ester and a branched fatty acid ester of polyglycerol has been reported (Patent Document 2).
  • PEG-20 glyceryl triisostearate which is a surfactant, is not easily reduced in cleansing ability even when mixed with water by blending with oil-based cleansing cosmetics (Patent Document 3).
  • an oil-based cleansing cosmetic that maintains a sufficient detergency even when a small amount of water is mixed and has a high appearance transparency is provided.
  • the purpose is to do.
  • the inventors of the present invention contain at least one polyoxyethylene-20 glyceryl triisostearate or polyoxyethylene-20 glyceryl trioleate and decaglyceryl monoisostearate
  • polyoxyethylene-20 glyceryl triisostearate or polyoxyethylene-20 glyceryl trioleate and decaglyceryl monoisostearate
  • the present invention includes the following components A and B: A. One or more polyoxyethylene-20 glyceryl triisostearate or polyoxyethylene-20 glyceryl trioleate, B.
  • the present invention relates to an oil-based cleansing cosmetic containing decaglyceryl monoisostearate.
  • the content of the component A may be 1 to 20% by weight based on the total weight of the oil-based cleansing cosmetic composition.
  • the content of the component B may be 1 to 20% by weight based on the total weight of the oil-based cleansing cosmetic.
  • the weight ratio A / B between the component A and the component B of the oil-based cleansing cosmetic composition can be 0.2-20.
  • the content of the component A is 1 to 20% by weight
  • the content of the component B is 1 to 20% by weight, based on the total weight of the oil-based cleansing cosmetic
  • the weight ratio A / B between component A and component B can be 0.2-20.
  • the oil-based cleansing cosmetic of the present invention may further contain one or more selected from the group consisting of fatty acid dextrin, hyaluronic acid, and derivatives of hyaluronic acid.
  • the fatty acid constituting the fatty acid dextrin may be one or more selected from the group consisting of arachidic acid, octanoic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, and behenic acid.
  • the hyaluronic acid derivative may be a pharmaceutically acceptable salt of hyaluronic acid, hydrolyzed hyaluronic acid, or chemically modified hyaluronic acid.
  • the pharmaceutically acceptable salt of hyaluronic acid may be a zinc salt, alkylammonium salt, ammonium salt, potassium salt, calcium salt, sodium salt, or magnesium salt.
  • the chemical modification of the hyaluronic acid can be acetylation, sulfation, sulfonylation, polyhydric alcoholation, alkylation, or cationization.
  • the oil-based cleansing cosmetic of the present invention may contain 0.001 to 10% by weight of the fatty acid dextrin based on the total weight of the oil-based cleansing cosmetic.
  • the oil-based cleansing cosmetic composition of the present invention may contain 0.00001 to 10% by weight of the hyaluronic acid and / or a derivative of hyaluronic acid based on the total weight of the oil-based cleansing cosmetic composition.
  • oil-based cleansing cosmetic of the present invention can have a viscosity of 1 to 10000 mPa ⁇ s.
  • the oil-based cleansing cosmetic of the present invention may further contain water.
  • oil-based cleansing cosmetic of the present invention can be used for hands and skin wet with water.
  • the oil-based cleansing cosmetic of the present invention can be transparent.
  • “transparent” means that when an oil-based cleansing cosmetic excluding colorants such as dyes and pigments is observed from one side, it does not show turbidity and transmits light to the extent that the rear side can be recognized. It means doing.
  • the oil-based cleansing cosmetic composition of the present invention contains component A.
  • component A One or more polyoxyethylene-20 glyceryl triisostearate or polyoxyethylene-20 glyceryl trioleate
  • component B By containing decaglyceryl monoisostearate, the detergency is maintained even when a small amount of water is mixed, compared with the case where each surfactant is used alone, the storage stability is high, and the rinsing property is high. Excellent feel when washed with water.
  • the oil-based cleansing cosmetic composition of the present invention contains one or more polyoxyethylene-20 glyceryl triisostearate or polyoxyethylene-20 glyceryl trioleate as component A.
  • cleansing means that the cleansing cosmetic dissolves oily dirt such as makeup cosmetics, sebum, old keratin, or a complex thereof, and rinses with water or hot water, so that it is oily together with the cleansing cosmetic.
  • oily dirt such as makeup cosmetics, sebum, old keratin, or a complex thereof
  • the oil-based cleansing cosmetic means a cleansing cosmetic containing a surfactant and an oil as components contained in the cleansing cosmetic, and refers to a liquid, paste, or solid at room temperature.
  • Component A polyoxyethylene-20 glyceryl triisostearate or polyoxyethylene-20 glyceryl trioleate, is in the form of a liquid or paste at room temperature and is generally used in the pharmaceutical, quasi-drug or cosmetic fields. If there is no particular limitation.
  • polyoxyethylene-20 glyceryl triisostearate for example, a commercially available product can be used, and trade names “Emalex GWIS-320EX, Emalex GWIS-320 (display name: PEG-20 glyceryl triisostearate)” (NIKKOL TGI-20 (display name: PEG-20 glyceryl triisostearate)) (manufactured by Nikko Chemicals Co., Ltd.) and the like.
  • polyoxyethylene-20 glyceryl trioleate for example, a commercially available product can be used, and the trade name “Emalex GWO-320 (display name: PEG-20 glyceryl trioleate)” (manufactured by Nippon Emulsion Co., Ltd.) It is done.
  • PEG in the display name means polyoxyethylene glyceryl.
  • the description of PEG-20 glyceryl means that the added mole number of oxyethylene group is 20.
  • the content of the component A of the present invention is preferably 1% by weight or more, more preferably 3% by weight or more, further preferably 5% by weight or more from the viewpoint of cleansing power, based on the total weight of the oil-based cleansing cosmetic. From the viewpoint of skin irritation, it is preferably 20% by weight or less, more preferably 15% by weight or less, and still more preferably 12% by weight or less.
  • the content of Component A of the present invention is about 1 to 20% by weight, about 1 to 15% by weight, about 1 to 12% by weight, about 3 to 20% by weight, about 3 to 15% by weight, about 3%. -12 wt%, about 5-20 wt%, about 5-15 wt%, about 5-12 wt%.
  • the oil-based cleansing cosmetic composition of the present invention contains decaglyceryl monoisostearate as component B.
  • Component B used in the present invention is not particularly limited as long as it is generally used in the field of pharmaceuticals, quasi drugs or cosmetics.
  • commercially available products can be used, and the trade name “IS-1001P (display name) : Polyglyceryl isostearate-10) "(manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.),” NIKKOL Decaglyn 1-ISV (display name: polyglyceryl-10 isostearate) "(manufactured by Nikko Chemicals Co., Ltd.), and the like.
  • the content of component B of the present invention is preferably 1% by weight or more, more preferably 3% by weight or more, still more preferably 5% by weight or more from the viewpoint of cleansing power, based on the total weight of the oil-based cleansing cosmetic. From the viewpoint of skin irritation, it is preferably 20% by weight or less, more preferably 15% by weight or less, and still more preferably 10% by weight or less.
  • the content of Component B of the present invention is about 1 to 20% by weight, about 1 to 15% by weight, about 1 to 10% by weight, about 3 to 20% by weight, about 3 to 15% by weight, about 3%. -10 wt%, about 5-20 wt%, about 5-15 wt%, about 5-10 wt%.
  • the weight ratio A / B of the component A and component B surfactants is preferably 0.2 to 20, more preferably 0, from the viewpoint of cleansing power. 0.5 to 5.0, more preferably 1.0 to 2.0.
  • the oil-based cleansing cosmetic of the present invention can further contain one or more selected from the group consisting of fatty acid dextrin, hyaluronic acid, and derivatives of hyaluronic acid.
  • fatty acid dextrin means an ester compound of dextrin and fatty acid.
  • hyaluronic acid refers to a polysaccharide having one or more structural units composed of glucuronic acid and N-acetylglucosamine.
  • the oil-based cleansing cosmetic of the present invention can improve rinsing properties by containing a fatty acid dextrin, and can improve stickiness after rinsing and washing away the oil-based cleansing cosmetic.
  • the oil-based cleansing cosmetic of the present invention can impart an excellent effect that it contains a fatty acid dextrin and is easy to apply to the target site without spilling the massage, cushioning, stability, and formulation. .
  • the fatty acid constituting the fatty acid dextrin is preferably one having 6 to 24 carbon atoms, and examples thereof include arachidic acid, octanoic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, and behenic acid.
  • the fatty acid dextrin can be composed of one or more fatty acids.
  • the fatty acid dextrin is not particularly limited as long as it is generally used in the field of pharmaceuticals, quasi drugs or cosmetics.
  • a commercially available product can be used, and the trade name “LEOPAL KL (display name: dextrin palmitate)” can be used.
  • Lion TL display name: dextrin palmitate
  • Lion TT trade name: (palmitic acid / octanoic acid) dextrin) " (Made by Chiba Flour Milling Co., Ltd.).
  • the content of the fatty acid dextrin is preferably 0.001% by weight or more, more preferably 0.01% by weight or more, and still more preferably 0, from the viewpoint of usability, based on the total weight of the oil-based cleansing cosmetic. From the viewpoint of compatibility with makeup stains, it is preferably 10% by weight or less, more preferably 8% by weight or less, and still more preferably 5% by weight or less.
  • the fatty acid dextrin content is about 0.001 to 10% by weight, about 0.001 to 8% by weight, about 0.001 to 5% by weight, about 0.01 to 10% by weight, about 0.01 -8 wt%, about 0.01-5 wt%, about 0.1-10 wt%, about 0.1-8 wt%, about 0.1-5 wt%.
  • the oil-based cleansing cosmetic of the present invention contains hyaluronic acid and / or a derivative of hyaluronic acid, so that the rinsing property can be improved, and the stickiness after rinsing and washing the oil-based cleansing cosmetic is improved. can do.
  • the oil-based cleansing cosmetic of the present invention contains hyaluronic acid and / or a derivative of hyaluronic acid, so that it is excellent in massage properties, cushioning properties, stability, and easy to apply to target areas without spilling from the hand. An effect can be imparted.
  • hyaluronic acid derivative examples include pharmaceutically acceptable salts of hyaluronic acid, hydrolyzed hyaluronic acid, and chemically modified hyaluronic acid.
  • Examples of pharmaceutically acceptable salts of hyaluronic acid include zinc salts, alkylammonium salts, ammonium salts, potassium salts, calcium salts, sodium salts, magnesium salts and the like.
  • Examples of the chemical modification of hyaluronic acid include acetylation, sulfation, sulfonylation, polyhydric alcoholation, alkylation, cationization and the like.
  • Hyaluronic acid or a derivative of hyaluronic acid is not particularly limited as long as it is generally used in the field of pharmaceuticals, quasi-drugs, or cosmetics.
  • a commercially available product can be used, and the trade name “Hyarobel (display name: Hyaluronic acid hydroxypropyltrimonium) (manufactured by QP Corporation), trade name “Hyarobel-MPF (display name: hydroxypropyltrimonium hyaluronate)” (manufactured by QP Corporation), trade name “hyaluronic sun HA-Q (display name) : Sodium hyaluronate) (manufactured by QP Corporation), trade name “Bio Sodium Hyaluronate HA9N (display name: sodium hyaluronate)” (manufactured by Shiseido Co., Ltd.), trade name “acetylated sodium hyaluronate (display name: acetyl)
  • the content of hyaluronic acid and / or a hyaluronic acid derivative is preferably 0.00001% by weight or more, more preferably 0.0001% by weight from the viewpoint of usability, based on the total weight of the oil-based cleansing cosmetic. % Or more, more preferably 0.001% by weight or more, and preferably 10% by weight or less, more preferably 8% by weight or less, and still more preferably 5% by weight from the viewpoint of compatibility with makeup stains. It is as follows.
  • the content of hyaluronic acid and / or a derivative of hyaluronic acid is about 0.00001 to 10% by weight, about 0.00001 to 8% by weight, about 0.00001 to 5% by weight, about 0.0001 to 10%. Wt%, about 0.0001-8 wt%, about 0.0001-5 wt%, about 0.001-10 wt%, about 0.001-8 wt%, about 0.001-5 wt%. .
  • the oil-based cleansing cosmetic of the present invention is mainly composed of oil, and the oil generally used in the pharmaceutical, quasi-drug or cosmetic field is within a quantitative and qualitative range that does not impair the effects of the present invention. Can be contained.
  • oils examples include natural animal and vegetable oils, hydrocarbon oils, ester oils, silicone oils, higher alcohols, higher fatty acids, animals and plants, and synthetic essential oils.
  • oils and fats examples include avocado oil, linseed oil, almond oil, olive oil, cacao oil, beef tallow, giraffe oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, safflower oil, soybean oil, evening primrose oil , Camellia oil, corn oil, rapeseed oil, horse fat, persic oil, palm oil, palm kernel oil, castor oil, sunflower oil, pork fat, grape oil, jojoba oil, macadamia nut oil, mink oil, cottonseed oil, molasses, palm oil , Hardened coconut oil, peanut oil, lanolin, egg yolk oil, rosehip oil and the like.
  • paraffinic hydrocarbons and olefinic hydrocarbons are used, and examples include squalane, squalene, ceresin, paraffin, pristane, microcrystalline wax, liquid paraffin, and petroleum jelly.
  • ester oils include synthetic esters, esters of higher alcohols and higher fatty acids, such as diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, isostearyl isostearate, Trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, neopentyl glycol di-2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octanoate, Oleyl oleate, octyldodecyl oleate, decyl oleate, neopentyl glycol dicaprate, 2-ethylhexyl succinate, isocetyl stearate, butyl steary
  • silicone oil examples include higher alkoxy-modified silicones such as dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane, octamethylcyclotetrasiloxane, octamethylcyclopentasiloxane, decamethylcyclohexasiloxane, stearoxysilicone, Examples include alkyl-modified silicones and higher fatty acid ester-modified silicones.
  • higher alcohols examples include octyldodecanol, isostearyl alcohol, oleyl alcohol, and the like.
  • a saturated or unsaturated linear or branched fatty acid having 12 to 22 carbon atoms can be used.
  • isostearic acid, oxystearic acid, oleic acid, stearic acid, palmitic acid, behenic acid examples include myristic acid, lauric acid, lanolinic acid, linoleic acid, and linolenic acid.
  • the oil content is preferably 25% by weight or more, more preferably 30% by weight or more, and still more preferably 40% by weight from the viewpoint of the cleansing effect, based on the total weight of the oil-based cleansing cosmetic. From the viewpoint of washability, it is preferably 95% by weight or less, more preferably 90% by weight or less, and still more preferably 85% by weight or less.
  • the oil-based cleansing cosmetic composition of the present invention can contain water.
  • the water content is preferably 0.1% by weight or more, more preferably 1% by weight or more, still more preferably 2% by weight or more from the viewpoint of stability, based on the total weight of the oil-based cleansing cosmetic. It is.
  • the water content is preferably 30% by weight or less, more preferably 20% by weight or less.
  • the water content is about 0.1 to 30% by weight, about 0.1 to 20% by weight, about 1 to 30% by weight, about 1 to 20% by weight, about 2 to 30% by weight, about 2%. Up to 20% by weight.
  • the oil-based cleansing cosmetic composition of the present invention includes various components generally used in the pharmaceutical, quasi-drug or cosmetic field as required, for example, within the quantitative and qualitative ranges that do not impair the effects of the present invention, for example, Surfactants other than Component A and Component B, moisturizers other than hyaluronic acid or hyaluronic acid derivatives, stabilizers, irritation reducers, blood circulation promoters, scrub agents, thickeners, preservatives, antioxidants, Coloring agent, pearl luster imparting agent, dispersing agent, chelating agent, pH adjusting agent, fragrance, UV absorbing component, UV scattering component, cleaning component, antibacterial component, anti-inflammatory component, astringent component, vitamins, peptide or derivative thereof, amino acid Alternatively, a derivative thereof, a keratin soft component, a cell activation component, and the like can be blended.
  • Surfactants other than Component A and Component B moisturizers other than hyaluronic acid or hyaluronic acid derivatives
  • these components can be mix
  • these components can be mixed with a known base or carrier and blended in an oily cleansing cosmetic.
  • the oil-based cleansing cosmetic composition of the present invention can also be produced by treating these components according to a conventional method.
  • surfactant other than the component A and the component B examples include, for example, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, diglycerol sorbitan penta-2-ethylhexylate, tetra Sorbitan fatty acid esters, such as diglycerol sorbitan 2-ethylhexylate; propylene glycol fatty acid esters, such as propylene glycol monostearate; polyoxyethylene hydrogenated castor oil 40 (HCO-40), polyoxyethylene hydrogenated castor oil 50 Cured castor oil derivatives such as (HCO-50), polyoxyethylene hydrogenated castor oil 60 (HCO-60), polyoxyethylene hydrogenated castor oil 80; polyoxyethylene (20) sorbitan monolaurate ( Polyoxyethylene sorbitan such as resorbate 20), polyoxyethylene (20) sorbitan monostearate (polysorbate 60), polyoxyethylene (20) sorbitan
  • moisturizing ingredients include polyhydric alcohols such as glycerin, 1,3-butylene glycol, propylene glycol, polyethylene glycol, and diglycerin trehalose; sodium hyaluronate, heparin analog, chondroitin sulfate sodium, collagen, elastin, keratin, Polymer compounds such as chitin and chitosan; amino acids such as glycine, aspartic acid and arginine; natural moisturizing factors such as sodium lactate, urea and sodium pyrrolidonecarboxylate; lipids such as ceramide, cholesterol and phospholipid; chamomile extract , Plant extract extracts such as hamamelis extract, tea extract and perilla extract.
  • polyhydric alcohols such as glycerin, 1,3-butylene glycol, propylene glycol, polyethylene glycol, and diglycerin trehalose
  • sodium hyaluronate heparin analog, chondroitin
  • stabilizer examples include sodium polyacrylate, dibutylhydroxytoluene, butylhydroxyanisole and the like.
  • irritation reducing agent examples include gum arabic, polyvinyl pyrrolidone, licorice extract, sodium alginate and the like.
  • Examples of the blood circulation promoter include acetylcholine, ictamol, caffeine, capsaicin, cantalis tincture, gamma oryzanol, ginger tincture, gingeron, cephalanthin, assembly extract, tannic acid, red pepper tincture, trazoline, tocopherol nicotinate, benzyl nicotinate Examples include esters.
  • scrubbing agents include apricot kernel powder, almond shell powder, apricot kernel powder, sodium chloride granules, olive kernel powder, dried seawater granules, candelilla wax, walnut shell powder, cherries kernel powder, coral powder, charcoal powder, Examples include hasp shell powder, polyethylene powder, and silicic anhydride.
  • thickeners examples include guar gum, locust bean gum, carrageenan, xanthan gum, carboxymethylcellulose, hydroxymethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymer, alkyl methacrylate methacrylate.
  • Copolymers polyethylene glycol, bentonite, (hydroxyethyl acrylate / acryloyldimethyltaurine sodium) copolymer, (acryloyldimethyltaurine ammonium / vinylpyrrolidone) copolymer, and the like.
  • Preservatives include, for example, benzoic acid, sodium benzoate, dehydroacetic acid, sodium dehydroacetate, isobutyl paraoxybenzoate, isopropyl paraoxybenzoate, butyl paraoxybenzoate, ethyl paraoxybenzoate, propyl paraoxybenzoate, benzyl paraoxybenzoate , Methyl paraoxybenzoate, phenoxyethanol and the like.
  • antioxidants examples include dibutylhydroxytoluene, butylhydroxyanisole, sorbic acid, sodium sulfite, ascorbic acid, erythorbic acid, L-cysteine hydrochloride and the like.
  • colorants include inorganic pigments and natural pigments.
  • pearl luster imparting agent examples include ethylene glycol distearate, ethylene glycol monostearate, and triethylene glycol distearate.
  • dispersant examples include sodium pyrophosphate, sodium hexametaphosphate, polyvinyl alcohol, polyvinyl pyrrolidone, methyl vinyl ether / maleic anhydride crosslinked copolymer, and organic acid.
  • Examples of the chelating agent include EDTA ⁇ disodium salt and EDTA ⁇ calcium disodium salt.
  • pH adjusters examples include inorganic acids (hydrochloric acid, sulfuric acid, etc.), organic acids (lactic acid, sodium lactate, citric acid, sodium citrate, succinic acid, sodium succinate, etc.), inorganic bases (potassium hydroxide, hydroxide) Sodium), organic bases (triethanolamine, diisopropanolamine, triisopropanolamine, etc.).
  • Examples of the ultraviolet absorbing component include octyl triazone, diethylaminohydroxybenzoyl hexyl benzoate, dimethoxybenzylidenedioxoimidazolidinepropionate octyl, paramethoxycinnamate 2-ethylhexyl, t-butylmethoxydibenzoylmethane, phenylbenzimidazolesulfonic acid, Etc.
  • ultraviolet scattering components include hydrous silicic acid, zinc silicate, cerium silicate, titanium silicate, zinc oxide, zirconium oxide, cerium oxide, titanium oxide, iron oxide, silicic anhydride, and other inorganic compounds.
  • inorganic powders such as hydrous silicic acid, aluminum hydroxide, mica and talc, compounded with resin powders such as polyamide, polyethylene, polyester, polystyrene and nylon, and with silicon oil and fatty acid aluminum salts, etc. Processed ones are listed.
  • Cleaning ingredients include soaps such as alkali metal salts such as potassium laurate, potassium myristate, potassium palmitate or potassium stearate, alkanolamide salts or amino acid salts, amino acid-based interfaces such as sodium cocoyl glutamate, sodium cocoyl methyl taurate, etc.
  • soaps such as alkali metal salts such as potassium laurate, potassium myristate, potassium palmitate or potassium stearate, alkanolamide salts or amino acid salts, amino acid-based interfaces such as sodium cocoyl glutamate, sodium cocoyl methyl taurate, etc.
  • ether sulfate ester salt such as sodium laureth sulfate, ether carboxylate salt such as sodium lauryl ether acetate, sulfosuccinate ester salt such as sodium alkylsulfosuccinate ester, coconut oil fatty acid monoethanolamide, coconut oil fatty acid ethanolamide
  • monoalkyl phosphates such as sodium lauryl phosphate, sodium polyoxyethylene lauryl ether phosphate, palm Fatty acid amidopropyldimethylaminoacetic acid betaine, lauryldimethylaminoacetic acid betaine, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, laurylhydroxysulfobetaine and lauroylamidoethylhydroxyethylcarboxymethylbetaine hydroxypropyl phosphate sodium Betaine type amphoteric surfactants such as amino acid type amphoteric surfactants
  • Antibacterial components include chlorhexidine, salicylic acid, benzalkonium chloride, acrinol, ethanol, benzethonium chloride, cresol, gluconic acid and its derivatives, popidone iodine, potassium iodide, iodine, isopropylmethylphenol, triclocarban, triclosan, photosensitizer 101
  • Photosensitive element 201 paraben, phenoxyethanol, 1,2-pentanediol, alkyldiaminoglycine hydrochloride, pyroctoolamine, miconazole and the like.
  • anti-inflammatory agents examples include glycyrrhetinic acid, glycyrrhizic acid derivatives, allantoin, azulene, aminocaproic acid and hydrocortisone.
  • astringent components include zinc oxide, zinc sulfate, allantoin hydroxyaluminum, aluminum chloride, zinc sulfocolate and tannic acid.
  • Vitamins such as dl- ⁇ -tocopherol, dl- ⁇ -tocopherol acetate, dl- ⁇ -tocopherol succinate, and dl- ⁇ -tocopherol calcium succinate; riboflavin, flavin mononucleotide, flavin adenine dinucleotide Vitamin B2 such as riboflavin butyrate, riboflavin tetrabutyrate, sodium riboflavin 5′-phosphate, riboflavin tetranicotinate; nicotinic acid dl- ⁇ -tocopherol, benzyl nicotinate, methyl nicotinate, ⁇ -nicotinic acid ⁇ - Nicotinic acids such as butoxyethyl and 1- (4-methylphenyl) ethyl nicotinate; ascorbigen-A, ascorbyl stearate, ascorbyl palmitate, dipalmitin Vitamin Cs such as L-as
  • Peptides or derivatives thereof include keratin-degrading peptide, hydrolyzed keratin, collagen, fish-derived collagen, atelocollagen, gelatin, elastin, elastin-degrading peptide, collagen-degrading peptide, hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin-degrading peptide , Conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soy proteolytic peptide, hydrolyzed soy protein, wheat protein, wheat proteolytic peptide, hydrolyzed wheat protein, casein degrading peptide Acylated peptides (palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetrapeptide, etc.).
  • Amino acids or derivatives thereof include betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, ⁇ -alanine, threonine, glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine Leucine, isoleucine, valine, histidine, taurine, ⁇ -aminobutyric acid, ⁇ -amino- ⁇ -hydroxybutyric acid, carnitine, carnosine, creatine and the like.
  • keratin soft component examples include lactic acid, salicylic acid, salicylic acid glycolic acid, gluconic acid, citric acid, malic acid, phytic acid, urea, and sulfur.
  • Cell activation components include amino acids such as ⁇ -aminobutyric acid and ⁇ -aminocaproic acid, vitamins such as retinol, thiamine, riboflavin, pyridoxine hydrochloride, pantothenic acids, ⁇ -hydroxy acids such as glycolic acid and lactic acid, tannins, Examples include flavonoids, saponins, allantoin, and photosensitizer 301.
  • the viscosity of the oil-based cleansing cosmetic of the present invention that is not solid is 1 mPa ⁇ s or more, preferably 10 mPa ⁇ s or more, more preferably 20 mPa ⁇ s or more, and is compatible with makeup stains. From the viewpoint, it is 10,000 mPa ⁇ s or less, preferably 1000 mPa ⁇ s or less, more preferably 500 mPa ⁇ s or less.
  • the viscosity of the oily cleansing cosmetic composition of the present invention which is not solid is about 1 to 10000 mPa ⁇ s, about 1 to 1000 mPa ⁇ s, about 1 to 500 mPa ⁇ s, about 10 to 10000 mPa ⁇ s, about 10 to 1000 mPa ⁇ s. s, about 10 to 500 mPa ⁇ s, about 20 to 10000 mPa ⁇ s, about 20 to 1000 mPa ⁇ s, and about 20 to 500 mPa ⁇ s.
  • the HLB value as a whole of the oil-based cleansing cosmetic of the present invention is 8 or more, more preferably 9 or more, more preferably 10 or more, from the viewpoint of washout properties, and 13 or less, more preferably 12 or less, from the viewpoint of cleansing power. More preferably, it is 11 or less.
  • oil-based cleansing cosmetic of the present invention When the oil-based cleansing cosmetic of the present invention is liquid or pasty, take an appropriate amount of the oil-based cleansing cosmetic, apply it to the face, and apply it to oil stains and makeup cosmetics. Can be washed away. When used with the hands and face slightly wet, the oil-based cleansing cosmetic of the present invention maintains a transparent or translucent appearance, becomes liquid or thick, and can continue cleansing.
  • oil-based cleansing cosmetic of the present invention When the oil-based cleansing cosmetic of the present invention is in a solid form, even if it is solid at the start of use, it is applied to the face in order to transfer it to a liquid having a moderate viscosity by picking it up and rubbing it. After it is thoroughly applied to oil stains and makeup cosmetics, it can be easily washed away with a large amount of water. Even when the oil-based cleansing cosmetic composition of the invention is solid, cleansing can be performed with the hands and face slightly wet.
  • each component is heated to 20 to 80 ° C. and dissolved while stirring.
  • a known method can be used.
  • a blade-type stirrer, a disper, a homomixer, or the like can be used.
  • the oil-based cleansing cosmetic of the present invention can be obtained by cooling the mixture that has been dissolved and made uniform to room temperature.
  • a liquid, paste-like, or solid oil-based cleansing cosmetic can be obtained upon cooling.
  • the oil-based cleansing cosmetic composition of the present invention is solid, it can be processed into shapes such as animals, fruits, characters, etc. by using a known molding method.
  • PEG-20 glyceryl triisostearate (GWIS-320EX, HLB: 8.0, manufactured by Nihon Emulsion Co., Ltd.)
  • PEG-10 glyceryl triisostearate (GWIS-310EX, HLB: 5.0, manufactured by Nihon Emulsion Co., Ltd.)
  • Triisostearin PEG-30 glyceryl acid (GWIS-330EX, HLB: 10.0, manufactured by Nihon Emulsion Co., Ltd.)
  • PEG-20 glyceryl diisostearate (GWIS-220EX, HLB: 10.0, manufactured by Nihon Emulsion Co., Ltd.)
  • Trioleic acid PEG- 20 glyceryl (GWO-320, HLB: 8.0, manufactured by Nippon Emulsion Co., Ltd.)
  • PEG-20 glyceryl tristearate (GWS-320, HLB: 8.0, manufactured by Japan Emulsion Co., Ltd.)
  • Polyglyceryl isostearate-10 (IS-1001P, HLB: 13.7, manufactured by Sakamoto Pharmaceutical Co., Ltd.) Polyglyceryl isostearate-6 (IS-601P, HLB: 10.8, manufactured by Sakamoto Pharmaceutical Co., Ltd.) Polyglyceryl laurate 10 (L-1001, HLB: 14.8, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) Polyglyceryl myristate-10 (M-1001, HLB: 14.8, manufactured by Sakamoto Yakuhin Kogyo Co., Ltd.) Polyglyceryl-10 diisostearate (IS- 1002P, HLB: 11.3, manufactured by Sakamoto Pharmaceutical Co., Ltd.) Polyglyceryl stearate-10 (S-1001P, HLB: 14.1, manufactured by Sakamoto Pharmaceutical Co., Ltd.)
  • oils used are as follows. Ethylhexyl palmitate (NIKKOL IOP, manufactured by Nikko Chemicals Co., Ltd.) Triethylexanoin (NIKKOL Trifat S-308, manufactured by Nikko Chemyls Co., Ltd.) Mineral oil (Silcol P-70, manufactured by Matsumura Oil Research Institute) Diphenylsiloxyphenyl trimethicone (silicone) KF-56, manufactured by Shin-Etsu Chemical)
  • the content of each component was prepared at the content ratio shown in Tables 1 to 4.
  • the obtained oil-based cleansing cosmetic had the appearance and shape shown in Tables 1 to 4. (Evaluation criteria for appearance) Transparent: No turbidity Translucent: Turbidity White turbidity: Emulsified
  • the apparent HLB value of the entire preparation is the apparent weight of the whole preparation, when two or more surfactants are contained, the weighted average of the HLB values of each surfactant and the HLB value calculated from the weight ratio. The above HLB value was used.
  • the oil-based cleansing cosmetic of Example 1 according to the present invention was prepared by mixing a small amount of water on the assumption that the cosmetic prepared as shown in Table 1 is used on wet skin. Both cosmetics had good appearance and properties, maintained cleanability, and had excellent viscosity and stability upon storage. Therefore, it was shown that the cleansing effect was high even when the skin was not wet with water or when the skin was wet with water.
  • the oil-based cleansing cosmetic of Example 2 according to the present invention had good appearance and properties even after a small amount of water was mixed in, was excellent in stability upon storage, and was excellent in viscosity and ease of washing.
  • the oil-based cleansing cosmetics of Examples 3 to 6 according to the present invention have all the appearance and properties, detergency, viscosity, stability upon storage, and ease of washing, before and after mixing a small amount of water. The evaluation results were excellent.
  • the oil-based cleansing cosmetics of Comparative Examples 1 to 14 are any of the appearance and properties, detergency, viscosity, stability upon storage, and ease of washing in any case before and after mixing a small amount of water. Or, all the evaluation results were insufficient.
  • the oily cleansing cosmetic was obtained according to the preparation example based on the following formulation.
  • this oil-based cleansing cosmetic the detergency was maintained regardless of whether the skin was not wet with water or the skin was wet with water. Moreover, it was excellent in the feel of the skin when it was washed away with water, and in addition, it was excellent in massage and conformability and low in irritation.
  • Oil-based cleansing cosmetic formulation example 1 Oil-based cleansing cosmetic formulation example 1
  • Oil-based cleansing cosmetic formulation example 2 is

Abstract

L'invention concerne un produit cosmétique de nettoyage à base d'huile qui se rince bien et qui peut être utilisé sans problèmes, tels qu'une turbidité ou un pouvoir nettoyant réduit, même sur mains ou peau mouillées. Ce produit cosmétique de nettoyage à base d'huile contient ce qui suit : (A) du triisostéarate de polyoxyéthylène (20) glycéryle et/ou du trioléate de polyoxyéthylène (20) glycéryle ; et (B) du monoisostéarate de décaglycéryle. Le pouvoir nettoyant de ce produit cosmétique de nettoyage à base d'huile est maintenu lorsque de l'eau y est mélangée. Egalement, ce produit cosmétique de nettoyage à base d'huile présente une bonne stabilité au stockage et conduit à une bonne sensation après avoir été rincé avec de l'eau.
PCT/JP2013/062421 2012-05-16 2013-04-26 Produit cosmétique de nettoyage à base d'huile WO2013172187A1 (fr)

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CN111000735A (zh) * 2019-12-27 2020-04-14 广州蜜妆生物科技有限公司 一种应用胶束科技的双层卸妆液

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WO2017159247A1 (fr) 2016-03-15 2017-09-21 株式会社マンダム Produit cosmétique de nettoyage à base d'huile
JP2019172652A (ja) * 2018-03-29 2019-10-10 株式会社マンダム 油性化粧料
JP6994563B2 (ja) * 2018-03-29 2022-01-14 株式会社マンダム 油性化粧料
JP7215377B2 (ja) 2018-10-24 2023-01-31 日油株式会社 クレンジング組成物
JP7155048B2 (ja) * 2019-03-08 2022-10-18 株式会社ノエビア 油性化粧料

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CN111000735A (zh) * 2019-12-27 2020-04-14 广州蜜妆生物科技有限公司 一种应用胶束科技的双层卸妆液

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