WO2013162080A3 - ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物、成形体、摺動性改良剤及び摺動部材 - Google Patents

ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物、成形体、摺動性改良剤及び摺動部材 Download PDF

Info

Publication number
WO2013162080A3
WO2013162080A3 PCT/JP2013/071890 JP2013071890W WO2013162080A3 WO 2013162080 A3 WO2013162080 A3 WO 2013162080A3 JP 2013071890 W JP2013071890 W JP 2013071890W WO 2013162080 A3 WO2013162080 A3 WO 2013162080A3
Authority
WO
WIPO (PCT)
Prior art keywords
polyorganosiloxane
graft copolymer
containing graft
sliding
rubber
Prior art date
Application number
PCT/JP2013/071890
Other languages
English (en)
French (fr)
Other versions
WO2013162080A2 (ja
Inventor
洋彰 音成
創平 上木
新治 松岡
Original Assignee
三菱レイヨン株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 三菱レイヨン株式会社 filed Critical 三菱レイヨン株式会社
Priority to CN201380080183.6A priority Critical patent/CN105636997B/zh
Priority to CN201810463096.3A priority patent/CN108641042B/zh
Priority to EP18170591.4A priority patent/EP3375800B1/en
Priority to EP13780989.3A priority patent/EP3034532B1/en
Priority to JP2013538385A priority patent/JP6221744B2/ja
Priority to PCT/JP2013/071890 priority patent/WO2013162080A2/ja
Priority to US14/911,940 priority patent/US9765170B2/en
Publication of WO2013162080A2 publication Critical patent/WO2013162080A2/ja
Publication of WO2013162080A3 publication Critical patent/WO2013162080A3/ja

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • C08F283/124Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to polysiloxanes having carbon-to-carbon double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

 熱可塑性樹脂の発色性及び難燃性を大きく損なうことなく、低温から高温までの幅広い環境条件において高い耐衝撃性、摺動性、耐薬品性を有する熱可塑性樹脂組成物を提供する。 ポリオルガノシロキサン(B1)及びポリアルキル(メタ)アクリレート(B2)を含む複合ゴムに1種以上のビニル単量体をグラフト重合したゴム含有グラフト共重合体であって、該ポリオルガノシロキサン(B1)中のビニル系重合性基含有シラン化合物に由来する成分の含有量が1~10質量%であり、該ゴム含有グラフト共重合体の体積平均粒子径が300~2000nmであり、該ゴム含有グラフト共重合体中の該ポリオルガノシロキサン(B1)の含有量が70~98質量%であり、かつアセトン可溶分が5.0質量%以上30.0質量%以下である、ゴム含有グラフト共重合体(GF2)。
PCT/JP2013/071890 2013-08-13 2013-08-13 ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物、成形体、摺動性改良剤及び摺動部材 WO2013162080A2 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CN201380080183.6A CN105636997B (zh) 2013-08-13 2013-08-13 含聚有机硅氧烷的接枝共聚物、树脂组合物、成形体、滑动性改良剂和滑动部件
CN201810463096.3A CN108641042B (zh) 2013-08-13 2013-08-13 含聚有机硅氧烷的接枝共聚物、树脂组合物、成形体、滑动性改良剂和滑动部件
EP18170591.4A EP3375800B1 (en) 2013-08-13 2013-08-13 Polyorganosiloxane-containing graft copolymer, resin composition, molded article, sliding-properties improvement agent, and sliding member
EP13780989.3A EP3034532B1 (en) 2013-08-13 2013-08-13 Polyorganosiloxane-containing graft copolymer, resin composition, molded article, sliding-properties improvement agent, and sliding member
JP2013538385A JP6221744B2 (ja) 2013-08-13 2013-08-13 ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物、成形体、摺動性改良剤及び摺動部材
PCT/JP2013/071890 WO2013162080A2 (ja) 2013-08-13 2013-08-13 ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物、成形体、摺動性改良剤及び摺動部材
US14/911,940 US9765170B2 (en) 2013-08-13 2013-08-13 Graft copolymer containing polyorganosiloxane, resin composition, molded article, slidability-improving agent, and sliding member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2013/071890 WO2013162080A2 (ja) 2013-08-13 2013-08-13 ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物、成形体、摺動性改良剤及び摺動部材

Publications (2)

Publication Number Publication Date
WO2013162080A2 WO2013162080A2 (ja) 2013-10-31
WO2013162080A3 true WO2013162080A3 (ja) 2014-01-23

Family

ID=49483994

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2013/071890 WO2013162080A2 (ja) 2013-08-13 2013-08-13 ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物、成形体、摺動性改良剤及び摺動部材

Country Status (5)

Country Link
US (1) US9765170B2 (ja)
EP (2) EP3375800B1 (ja)
JP (1) JP6221744B2 (ja)
CN (2) CN108641042B (ja)
WO (1) WO2013162080A2 (ja)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015196811A (ja) * 2014-04-03 2015-11-09 三菱レイヨン株式会社 ポリオレフィン樹脂用摺動性向上剤、ポリオレフィン樹脂組成物及びその成形体
JP6365116B2 (ja) * 2014-08-26 2018-08-01 三菱ケミカル株式会社 熱可塑性樹脂組成物及びその成形体。
JP2016079333A (ja) * 2014-10-20 2016-05-16 出光興産株式会社 リサイクル材を含むポリカーボネート系樹脂組成物及びその成形品
JP2016079334A (ja) * 2014-10-20 2016-05-16 出光興産株式会社 ポリカーボネート−ポリオルガノシロキサン共重合体を含むポリカーボネート系樹脂組成物及びその成形品
BR112018067763A2 (pt) * 2016-03-10 2019-01-15 Zeon Corp látex de uma borracha sintética, composição de látex, artigo moldado em película, substrato de formação de camada adesiva, e, método para produzir um látex de uma borracha sintética.
CN106519144B (zh) * 2016-08-31 2019-06-04 广州熵能创新材料股份有限公司 乙烯基系接枝共聚物和含有其的树脂组合物、及乙烯基系接枝共聚物的制备方法
KR102134856B1 (ko) * 2016-11-02 2020-07-16 주식회사 엘지화학 우수한 분산성을 갖는 알루미노실리케이트 입자의 제조 방법, 상기 알루미노실리케이트 입자를 포함한 고무 보강재 및 이를 포함한 타이어용 고무 조성물
EP4163313A1 (en) * 2017-06-06 2023-04-12 Mitsubishi Chemical Corporation Polyorganosiloxane-containing graft copolymer, thermoplastic resin composition, and molded article
EP3693402B1 (en) * 2017-10-04 2023-07-12 Mitsubishi Chemical Corporation Rubber-containing graft polymer, resin composition containing rubber-containing graft polymer, and shaped article thereof
WO2019103092A1 (ja) * 2017-11-27 2019-05-31 三菱ケミカル株式会社 ゴム含有グラフト重合体、ゴム含有グラフト重合体含有樹脂組成物およびその成形体
WO2020023815A1 (en) * 2018-07-27 2020-01-30 Rohm And Haas Company Silicone-acrylic polymer particles
JP7433283B2 (ja) 2018-07-27 2024-02-19 ローム アンド ハース カンパニー シリコーンモノマー及びアクリルモノマーの重合プロセス
JP7262984B2 (ja) * 2018-12-03 2023-04-24 日信化学工業株式会社 シリコーンアクリルグラフト共重合樹脂、その製造方法及びコーティング剤
EP4317325A1 (en) 2021-03-30 2024-02-07 Mitsubishi Chemical Corporation Resin composition and molded body
KR20230122135A (ko) 2021-03-30 2023-08-22 미쯔비시 케미컬 주식회사 폴리오르가노실록산 함유 중합체, 조성물 및 성형체
CN114478952A (zh) * 2022-01-25 2022-05-13 深圳市骏鼎达新材料股份有限公司 一种含环氧基团聚硅氧烷-丙烯酸酯弹性体的制备方法及其低温增韧尼龙管中的应用

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001055499A (ja) * 1999-08-17 2001-02-27 Mitsubishi Rayon Co Ltd 難燃性樹脂組成物
JP2010007045A (ja) * 2008-02-25 2010-01-14 Mitsubishi Rayon Co Ltd グラフト共重合体、それを含有する樹脂組成物及び成形体
JP2010275523A (ja) * 2009-04-28 2010-12-09 Mitsubishi Rayon Co Ltd グラフト共重合体及びその製造方法、熱可塑性樹脂組成物、並びに成形品
JP2011012241A (ja) * 2009-06-01 2011-01-20 Mitsubishi Rayon Co Ltd グラフト共重合体及びその製造方法、熱可塑性樹脂組成物、並びに成形物
JP2011046843A (ja) * 2009-08-27 2011-03-10 Fuji Xerox Co Ltd 複合ゴム系グラフト共重合体、熱可塑性樹脂組成物および樹脂成形体
JP2012007088A (ja) * 2010-06-25 2012-01-12 Mitsubishi Rayon Co Ltd ポリオルガノシロキサン系樹脂改質剤及びその製造方法、熱可塑性樹脂組成物、並びに成形体

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3168638B2 (ja) * 1991-02-15 2001-05-21 ジェイエスアール株式会社 摺動部材および耐汚染部材
JPH09309935A (ja) 1996-03-18 1997-12-02 Mitsubishi Rayon Co Ltd 複合ゴム系摺動性改質剤および軟質塩化ビニル系樹脂組成物
JPH10176017A (ja) 1996-12-17 1998-06-30 Techno Polymer Kk 塩化ビニル系樹脂用改質剤およびそれを用いた塩化ビニル系樹脂組成物
JPH10279642A (ja) 1997-03-31 1998-10-20 Techno Polymer Kk 複合ゴム系グラフト共重合体および熱可塑性樹脂組成物
JP3471225B2 (ja) 1998-06-29 2003-12-02 三菱レイヨン株式会社 難燃性熱可塑性樹脂組成物
ES2304067T3 (es) * 1998-12-07 2008-09-01 General Electric Company Modificadores de impacto basados en goma de silicona polimerizada en emulsion, procedimiento de fabricacion y mezclas de los mismos.
US20020147271A1 (en) * 2000-09-13 2002-10-10 Craig Daniel Horace Emulsion polymerized silicone rubber-based impact modifiers, method for making, and blends thereof
TWI317749B (en) 2002-02-15 2009-12-01 Kaneka Corp Graft copolymers and impact-resistant flame-retardant resin compositions containing the same
JP2004359889A (ja) 2003-06-06 2004-12-24 Mitsubishi Rayon Co Ltd シリコーン/アクリル複合ゴム系グラフト共重合体および熱可塑性樹脂組成物
JP2005112949A (ja) * 2003-10-06 2005-04-28 Mitsubishi Rayon Co Ltd 熱可塑性樹脂組成物
JP2005330467A (ja) * 2004-04-19 2005-12-02 Mitsubishi Rayon Co Ltd グラフト重合粉体の製造方法、および熱可塑性樹脂組成物。
WO2006011384A1 (ja) 2004-07-28 2006-02-02 Kaneka Corporation 熱可塑性樹脂組成物
EP1832613B9 (en) 2004-12-28 2012-08-29 Kaneka Corporation Graft copolymer, method for producing same and resin composition containing such graft copolymer
JP5560001B2 (ja) 2009-07-27 2014-07-23 出光興産株式会社 摺動性ポリカーボネート樹脂組成物および成形品
JP5522436B2 (ja) 2009-09-17 2014-06-18 三菱レイヨン株式会社 グラフト共重合体及びその製造方法、難燃剤、熱可塑性樹脂組成物、並びに成形体
EP2660256B1 (en) 2010-12-28 2018-07-25 Mitsubishi Chemical Corporation Graft copolymer and production method therefor, resin composition, and molded article
JP5765076B2 (ja) 2011-06-17 2015-08-19 三菱レイヨン株式会社 熱可塑性樹脂組成物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001055499A (ja) * 1999-08-17 2001-02-27 Mitsubishi Rayon Co Ltd 難燃性樹脂組成物
JP2010007045A (ja) * 2008-02-25 2010-01-14 Mitsubishi Rayon Co Ltd グラフト共重合体、それを含有する樹脂組成物及び成形体
JP2010275523A (ja) * 2009-04-28 2010-12-09 Mitsubishi Rayon Co Ltd グラフト共重合体及びその製造方法、熱可塑性樹脂組成物、並びに成形品
JP2011012241A (ja) * 2009-06-01 2011-01-20 Mitsubishi Rayon Co Ltd グラフト共重合体及びその製造方法、熱可塑性樹脂組成物、並びに成形物
JP2011046843A (ja) * 2009-08-27 2011-03-10 Fuji Xerox Co Ltd 複合ゴム系グラフト共重合体、熱可塑性樹脂組成物および樹脂成形体
JP2012007088A (ja) * 2010-06-25 2012-01-12 Mitsubishi Rayon Co Ltd ポリオルガノシロキサン系樹脂改質剤及びその製造方法、熱可塑性樹脂組成物、並びに成形体

Also Published As

Publication number Publication date
CN105636997B (zh) 2018-06-19
JPWO2013162080A1 (ja) 2016-06-02
US9765170B2 (en) 2017-09-19
CN105636997A (zh) 2016-06-01
CN108641042B (zh) 2020-09-11
EP3034532A2 (en) 2016-06-22
WO2013162080A2 (ja) 2013-10-31
JP6221744B2 (ja) 2017-11-01
EP3034532B1 (en) 2019-11-06
EP3034532A4 (en) 2016-11-30
CN108641042A (zh) 2018-10-12
EP3375800B1 (en) 2021-07-07
US20160194428A1 (en) 2016-07-07
EP3375800A1 (en) 2018-09-19

Similar Documents

Publication Publication Date Title
WO2013162080A3 (ja) ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物、成形体、摺動性改良剤及び摺動部材
WO2013129709A3 (ja) ポリオルガノシロキサン含有グラフト共重合体、樹脂組成物及び成形体
JP6457094B2 (ja) 熱可塑性樹脂組成物及びそれから製造される成形品
MX2017000265A (es) Composicion de resina termoplastica y articulo moldeado de la misma.
WO2017113269A8 (en) Anti-fog coating composition including functionalized silica nanoparticles and multifunctional (meth)acrylate monomers
MX2009012869A (es) Composicion de color con resistencia a la fisuracion por tension.
BR112013018415A2 (pt) composição ou compósito, material pré-impregnado, material termoplástico ou um produto moldado de resina de termocura modificado com termoplástico, poliaril sulfona, e, composto de benzoxazina
EP2520617A4 (en) POLYCARBONATE RESIN COMPOSITION AND MOLDING PRODUCTS
PL2178970T3 (pl) Tłoczywa termoplastyczne o zmniejszonej palności
WO2008080774A9 (de) Schnelldispergierbares, teilchenförmiges filmüberzugsmittel basierend auf polyvinylalkohol-polyether-pfropfcopolymeren
TW200621878A (en) Thermoplastic resin composition for refrigerator having improved environmental stress crack resistance
MY148143A (en) Resorcinol-blocked isocyanate compositions and their applications
WO2014049570A3 (en) Improved release polycarbonate compositions
MX368297B (es) Composicion curable formadora de pelicula que demuestra resistencia a pulido y poco brillo.
MX2016012526A (es) Composicion de resina termoplastica y articulo moldado de la misma.
MX2019003876A (es) Composicion de resina termoplastica y su articulo moldeado.
CA2862782A1 (en) Toughness modifier for curable resin, and curable resin composition
TR201821192T4 (tr) Poliorganosiloksan içeren graft kopolimer, termoplastik reçine bileşimi ve kalıplanmış ürün.
KR101444054B1 (ko) 무광택 열가소성 수지 조성물
EP3901190A3 (en) Polyorganosiloxane-containing graft copolymer, thermoplastic resin composition, and molded article
WO2007106186A3 (en) Resorcinol resin-blocked isocyanates and their applications
IN2015DN03278A (ja)
EP3733727A4 (en) GRAFT POLYMER INCLUDING A RUBBER, AND A RESIN COMPOSITION INCLUDING A GRAFT POLYMER WITH RUBBER CONTENT AND A MOLDED BODY OF THE SAME
MY182050A (en) Thermoplastic resin composition and resin molded article
WO2009091156A3 (en) Thermoplastic resin composition

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2013538385

Country of ref document: JP

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13780989

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 14911940

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2013780989

Country of ref document: EP