WO2013155892A1 - 用于制造军队轮式战车、飞机特种安全轮胎橡胶的专用材料 - Google Patents

用于制造军队轮式战车、飞机特种安全轮胎橡胶的专用材料 Download PDF

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WO2013155892A1
WO2013155892A1 PCT/CN2013/071487 CN2013071487W WO2013155892A1 WO 2013155892 A1 WO2013155892 A1 WO 2013155892A1 CN 2013071487 W CN2013071487 W CN 2013071487W WO 2013155892 A1 WO2013155892 A1 WO 2013155892A1
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parts
rubber
material according
group
special material
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PCT/CN2013/071487
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English (en)
French (fr)
Inventor
夏华松
夏康凯
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Xia Huasong
Xia Kangkai
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Priority to EP13778006.0A priority Critical patent/EP2842995B1/en
Priority to US14/394,959 priority patent/US9365705B2/en
Priority to JP2015506082A priority patent/JP6105049B2/ja
Priority to KR1020147032033A priority patent/KR20150002827A/ko
Publication of WO2013155892A1 publication Critical patent/WO2013155892A1/zh

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016—Compositions of the tread
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0025—Compositions of the sidewalls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/01—Magnetic additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/28—Non-macromolecular organic substances
    • C08L2666/44—Silicon-containing compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/80—Technologies aiming to reduce greenhouse gasses emissions common to all road transportation technologies
    • Y02T10/86—Optimisation of rolling resistance, e.g. weight reduction 

Definitions

  • the invention discloses a special material which can be used for manufacturing rubber for an army wheeled vehicle and an aircraft special safety tire. Background technique
  • the purpose of this is to invent a special material for the manufacture of military wheeled vehicles, aircraft special safety tire rubber.
  • This special material is still made of ordinary rubber, higher than flame retardant rubber. It can be used to make radial tires, bias tires, solid tires, and can be directly vulcanized into molds. It has the characteristics of ordinary tire rubber at room temperature, and has the characteristics of high temperature resistance, combustion resistance, strong fire resistance and aging resistance. It can withstand high temperatures for a long time and burn for a long time. This material will not be deformed or damaged. Physical properties are basically the same as normal temperature. The material of the present invention can withstand temperatures of 800 1 200 ° C in a hot environment. Under high temperature ablation, the surface layer of the carcass will form a dense shell, the flame and combustion air will not invade, and the external temperature will last longer, and the fireproof layer formed will be denser.
  • the invention can be used for the special safety tire carcass material which is used in the unfavorable environment such as bad terrain, sharp foreign matter, high temperature open flame, etc., and thoroughly solves these concerns, and at the same time can make the combat vehicle and the aircraft tire have bulletproof and resistant
  • use Wheeled vehicles and special safety tires made of this material fill the gaps of similar products in China.
  • the tires prepared by this special material can be formed into three insurances if they are filled with nitrogen.
  • the invention has simple manufacturing process, lower cost and better manufacturing process than similar international products, and can be recycled and used without pollution. Specific way
  • the invention relates to a special material for manufacturing an army wheeled vehicle and an aircraft special safety tire rubber.
  • the special material is prepared from the following parts by weight of raw materials:
  • the polyisoprene is selected from the group consisting of polyisoprene rubber IR565, IR LHIR70, IR560, and IR2200;
  • the silicone rubber is selected from the group consisting of GM300, GM500, 110 2, TSE270-7U, 3150 in silicone rubber;
  • thermoplastic elastomer is selected from the group consisting of styrene-butadiene rubber 1778, SBR1500, SBS 792, and SBS796;
  • the paraffin oil is selected from the group consisting of DE 69, DY 36, HB, 300# in paraffin oil;
  • the toughening agent is selected from the group consisting of a non-polar polymer and an unsaturated acid or anhydride graft;
  • the silicone oil is selected from the group consisting of 22941-1, 201, 5036D in silicone oil, and the porcelain micropowder described in KF 96 1000 is selected from the group consisting of niobium, ZYBJ-1, JZA-1 03F, and XZS in porcelain powder;
  • the antioxidant is any one of a compound such as diphenylamine, p-phenylenediamine or dihydroquinoline, a derivative thereof or a polymer.
  • the invention also provides a method for manufacturing a special material for manufacturing an army wheeled vehicle and an aircraft special safety tire rubber, comprising the following steps:
  • the obtained premix is further added to an internal mixer for thorough mixing and mixing, and the heating temperature is 150 to 180 ' €, and the mixing time is 120 to 200 minutes.
  • the material obtained from the discharge port after mixing is the special material.
  • the heating temperature is 1 551 and the mixing time is 200 minutes.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)
  • Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)

Abstract

一种可用于制造军队轮式战车、飞机特种安全轮胎橡胶的专用材料，该材料的组成及质量比例为：聚异戊二烯28-40份，硅橡胶19-30份，热塑性弹性体15-25份，瓷微粉10-18份，石蜡油10-15份，增韧剂0.8-2份，硅油5-10份，抗氧剂0.5-2份，所述材料可作为地形恶劣、尖锐异物较多、高温明火等不利环境下行军作业的特种安全轮胎胎体材料，常温下具备普通轮胎橡胶的特性，酷热环境兼具耐高温，耐燃烧，隔火性强，耐老化等特点，并且具有耐扎、防弹、防暴功能，能承受轻量爆炸物的弹片袭击，制作工艺简单，可回收利用无污染。

Description

说 明 书
用于制造军队轮式战车、 飞机特种安全轮胎樣胶的专用材料 技术领域
本发明公开了一种可用于制造军队轮式战车、 飞机特种安全轮胎 橡胶的专用材料。 背景技术
轮式战车、 飞机在现代战争中的重要性毋庸多言， 灵活、 高效的 战车与飞机同时也极易受到由于地形、 危险源等元素的影响致使行动 受阻而使作业难以完成， 甚至危及人员生命安全。
本专用材料其性能有別于时下的一些安全轮胎——有充入防漏液 的安全轮胎， 其缺点： 易腐蚀轮辋、 行驶不舒适性、 动平衡性能差， 容易损坏母胎； 有骨架式缺气保用轮胎， 售价昂贵， 缺气时靠内置骨 架支撑进行行驶， 且安全性能一旦体现， 该产品即已作废。
' 本. ^明的目的是发明一种用于制造军队轮式战车， 飞机特种安全 轮胎橡胶的专用材料。
经长期的研制及反复实验， 发明一种新材料， 制造该材料使用的 原料的成分及质量比例为：
聚异戊二烯 28 40份， 硅橡胶 1 9 30份， 热塑性弹性体 1 5 2 5份， 瓷微粉 1 0-1 8 , 石蜡油 1 0 1 5份， 增韧剂 0. 8-2份, 硅油 5- 1 0份， 抗氧剂 0, 5 2份。
本专用材料犹于普通橡胶， 高于阻燃橡胶， 可以用作制造子午胎、 斜交胎、 实心胎， 可直接入模硫化， 与轮胎为一整体。 常温下具备普 通轮胎橡胶的特性， 兼具耐高温， 耐燃烧， 隔火性强， 耐老化等特点。 可以耐长时间高温， 长时间火烧。 本材料也不会变形， 损毁。 物理性 能和常温基本无异。 本发明的材料在酷热环境可以经受 800 1 200 °C的 高温。 在高温烧蚀下， 胎体表层会形成致密的壳体， 火焰及助燃空气 侵牲不进， 并且外界高温持续越久， 形成的防火层越致密。 本发明可 用于地形恶劣、 尖锐异物较多、 高温明火等不利环境下行军作业的特 种安全轮胎胎体材料， 较为彻底的解决了这些恍虑， 同时可使战车、 飞机轮胎具有防弹、 耐扎、 防暴的特性， 扎的透而扎不漏， 能承受轻 量爆炸物的弹片袭击， 有效的减少緩沖了外击能量所带来的危害。 用 该材料制造的轮式战车、飞机特种安全轮胎填补国内同类产品的空白。 本专用材料所制备的轮胎如充入氮气， 可形成三保险
本发明制作工艺简单， 较国际同类产品成本低廉制作工艺简单， 可回收利用无污染。 具体实 方式
本发明是一种用于制造军队轮式战车、 飞机特种安全轮胎橡胶的 专用材料， 该专用材料由以下重量份数的原料制备而成：
聚异戊二烯 28- 40份 硅橡胶 2 G 30份
热塑性弹性体 15-25份 瓷微粉 1 G 18份
石蜡油 10 15份 增韧剂 0, 8-2份
硅油 5 10份 抗氧剂 0, 5 2份
所述的聚异戊二烯选自聚异戊二烯橡胶 IR565、 IR LHIR70、 IR560、 IR2200中的一种；
所述的硅橡胶选自硅橡胶中的 GM300、 GM500 , 110 2、 TSE270-7U, 3150中的一种；
所述的热塑性弹性体选自丁苯橡胶 1778、SBR1500、SBS 792、SBS796 中的一种；
所述的石蜡油选自石蜡油中的 DE 69、 DY 36、 HB、 300#中的一种； 所述增韧剂选自非极性高分子与不饱和酸或酸酐的接枝物； 是 A 659HIPS、 A-608PP , TP- 165、 HR 189中的一种;
所述的硅油选自硅油中的 22941-1、 201、 5036D, KF 96 1000 中的 所述的瓷微粉选自瓷粉中的 ΝΑΐ、 ZYBJ-1、 JZA-1 03F , XZS中的一 种；
所述抗氧剂是二苯胺、 对苯二胺、 二氢喹啉等化合物及其衍生物 或聚合物中的任意一种。
本发明还提出一种用于制造军队轮式战车、 飞机特种安全轮胎橡 胶的专用材料的制作方法， 包括以下步骤：
(1)将上述重量份数的聚异戊二烯， 硅橡胶， 热塑性弹性体， 瓷微 粉， 石蜡油， 增韧剂， 硅油， 抗氧剂放入搅拌机中预拌 30-45分钟。
( 2 )再将所得预拌物加入密炼机中加以充分混合密炼， 加热温度为 150一 180 '€ , 混合时间 120- 200分钟。 混合充分后由出料口所得材料 即为本专用材料。 为取得较佳效果， 加热温度为 1 551， 混合时间 200 分钟。

Claims

1 , 一种用于制造军队轮式战车、 安全轮胎橡胶的专用 由以下重量份数原料组成：
聚异戊二婦 28 40份 硅橡胶 20 30份 热塑性弹性体 1 5 25份 瓷微粉 10 1 8份 石蜡油 10 15 增韧剂 0. 8 2份 硅油 5 10份 抗氧剂 0. 5 2份'
2、根据权利要求 1所述的专用材料， 所述的聚异戊二烯选自聚异 戊二烯撐、,晈 IR565、 IR LH IR70 , IR560、 I R2200中的一种
3、根据权利要求 1所述的专用材料， 橡胶选自硅橡胶' 的 GM300 , GM501 110 2、 TSE270-7U . 3150 的一种。
4、根据权利要求 1所述的专 .弹性体选自丁 苯橡胶 1778、 SBR1500、 SBS792、 SBS796中的 -种。
5、根据权利要求 1所述的专用材料， 所述的.石 4油选
的 DE 69、 DY 36、 HB、 300#中的一种。
6、根据权利要求 1所述的密封材料， 所述增韧剂选自非极性高分 子与不饱和酸或酸酐的接技物， 是 A 659HIPS、 A 608PP、 TP 165、 HR-189中的一种。
7、 根据权利要求 1 所述的专用材料， 所述的硅油选自硅油中的 229氣 201 , 5036D、 KF 96 1000中的一种。
8、根据权利要求 1所述的专用材料， 所述的瓷微粉选自陶瓷粉中 的 NAI、 ZYBJ- JZA 103F、 XZS中的一种。
9、 根据权利要求 1所述的专用材料， 所述抗氧剂是二笨胺、 对苯 二胺和二氢喹啉等化合物及其衍生物或聚合物中的任意一种。
1 0、 一种用于制造军队轮式战车、 飞机轮胎特种安全橡胶的专 用材料的制作方法包括以下步骤：
U)将聚异戊二烯， 硅橡胶， 热塑性弹性体， 瓷微粉， 石蜡油， 增韧剂， 硅油， 抗氧剂放入搅拌机中预拌 30 45分钟。
(2)再将所得预拌物加入密炼机中加以充分混合密炼， 温度 1 50-1801：, 混合时间 1 20 200分钟， 混合充分后由出料口 A 料即为本专用
PCT/CN2013/071487 2012-04-16 2013-02-07 用于制造军队轮式战车、飞机特种安全轮胎橡胶的专用材料 WO2013155892A1 (zh)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP13778006.0A EP2842995B1 (en) 2012-04-16 2013-02-07 Specific material for manufacturing special run-flat tire rubber for wheeled military combat vehicle and aeroplane
US14/394,959 US9365705B2 (en) 2012-04-16 2013-02-07 Dedicated material for manufacturing special safety tire rubber for wheeled combat vehicles and aircraft in the army
JP2015506082A JP6105049B2 (ja) 2012-04-16 2013-02-07 軍隊用の車輪型戦車、飛行機の特種で安全なタイヤゴムを製造することに用いられる専用材料
KR1020147032033A KR20150002827A (ko) 2012-04-16 2013-02-07 군용 차륜식 전투 차량 또는 비행기용 특수 런플랫 타이어 고무의 제조를 위한 전용 재료

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CN2012101087022A CN102627791A (zh) 2012-04-16 2012-04-16 用于制造军队轮式战车、飞机特种安全轮胎橡胶的专用材料
CN201210108702.2 2012-04-16

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EP (1) EP2842995B1 (zh)
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WO (1) WO2013155892A1 (zh)

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CN102627791A (zh) 2012-04-16 2012-08-08 夏华松 用于制造军队轮式战车、飞机特种安全轮胎橡胶的专用材料
FR3012148B1 (fr) * 2013-10-22 2015-12-04 Michelin & Cie Pneumatique d'avion dont la bande de roulement comprend une composition a base de silicone elastomerique
FR3135084A1 (fr) * 2022-04-27 2023-11-03 Nyco Utilisation d’un antioxydant pour réduire et/ou prévenir la toxicité d’une composition de caoutchouc
CN114918905B (zh) * 2022-06-06 2023-09-15 浙江大学 一种温致变色液气相变柔性驱动器及其制备方法

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JP2015520778A (ja) 2015-07-23
CN102627791A (zh) 2012-08-08
EP2842995A4 (en) 2016-01-20
EP2842995B1 (en) 2018-01-03
KR20150002827A (ko) 2015-01-07

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