WO2013136480A1 - Colorant capillaire et procédé de coloration des cheveux - Google Patents

Colorant capillaire et procédé de coloration des cheveux Download PDF

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Publication number
WO2013136480A1
WO2013136480A1 PCT/JP2012/056640 JP2012056640W WO2013136480A1 WO 2013136480 A1 WO2013136480 A1 WO 2013136480A1 JP 2012056640 W JP2012056640 W JP 2012056640W WO 2013136480 A1 WO2013136480 A1 WO 2013136480A1
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Prior art keywords
hair
component
hair dye
agent
dye
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PCT/JP2012/056640
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English (en)
Japanese (ja)
Inventor
順二 山形
奈那 市川
祐貴 笹尾
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ホーユー株式会社
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Priority to PCT/JP2012/056640 priority Critical patent/WO2013136480A1/fr
Publication of WO2013136480A1 publication Critical patent/WO2013136480A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a hair dye and a hair dyeing method. More specifically, the present invention relates to a multi-component hair dye comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent, and a viscous liquid mixture of each agent of the hair dye.
  • the present invention relates to a hair dyeing method in which hair is applied to the hair to perform hair dyeing treatment.
  • a hair dye that is applied to the hair using a hair color treatment and the like is provided.
  • such a hair dye has a high viscosity, for example, it is possible to effectively prevent the hair dye from dripping during the hair treatment time of about 30 minutes, but it is difficult to apply it uniformly to the entire hair. In particular, it is difficult for the user's own back of the head to perform a uniform application operation of the hair dye even if a mirror is used. Therefore, when applying a viscous liquid hair dye to the whole hair dyeing, it is easy to produce a partial dye residue and a non-uniform hair dyeing state.
  • Patent Documents 1 to 4 listed below disclose foam-like hair dyes that are applied to hair by discharging a mixture of hair dye agents in a foam form using an aerosol-type or non-aerosol-type former container. Has been. However, these foam-like hair dyes require a former container in order to mix each of the hair dyes and discharge them in the form of foam. Therefore, the cost increase for that is inevitable.
  • Patent Document 5 discloses a hair dyeing method in which a multi-component hair dye composition is impregnated into a soft sponge and foamed so as to rub the sponge, and the foam hair dye is applied to the hair. Yes.
  • the dyeing method of Patent Document 5 is a cumbersome and inefficient method because it is a round method in which a hair dye is foamed using a sponge and then applied to the hair.
  • the oxidized hair dye disclosed in Patent Document 6 Apart from the foamy hair dye described above, for example, the oxidized hair dye disclosed in Patent Document 6 below, after applying to the hair, lathering by hand on the hair and performing the hair dyeing treatment Hair dyes have been proposed. Since this hair dye does not require a foaming container such as a foam container or a sponge, it is possible to avoid the above-described cost increase and trouble in use.
  • JP-A-9-136818 Japanese Patent Laid-Open No. 10-287534 JP 2007-291015 A JP 2008-291020 A JP 2010-215576 A Japanese Patent Laid-Open No. 9-278637
  • the type of hair dye that is foamed and applied to the hair requires not only good foaming but also good foam retention.
  • Foam retention refers to suppressing defoaming and maintaining a good foaming state throughout the hair dyeing treatment time.
  • the hair dyes disclosed in Patent Documents 1 to 5 use a foaming device such as a former container, and thus easily meet such requirements.
  • the type of hair dye that foams on the hair it is required to show good foaming and foam retention by lathering with a hand on the hair.
  • the hair dye disclosed in Patent Document 6 does not disclose anything about the requirement of foaming and good foam retention at the time of foaming on the hair, and a solution to that requirement.
  • a surfactant is generally used as a foaming agent.
  • anionic surfactants are known to have high foaming power and good foaming. Therefore, it is preferable to use at least an anionic surfactant as a foaming agent in a hair dye that does not use a former container or the like. Furthermore, in order to improve foam retention, it is preferable to use an amphoteric surfactant in combination.
  • the contact area of the liquid portion of the foam with respect to the hair becomes insufficient, so that the hair coloring power becomes insufficient. More specifically, the hair dyeing is insufficient, and the hair is not dyed in a bright color due to insufficient bleaching power on the hair, resulting in low brightness after dyeing.
  • the viscosity in the foamed state or the defoamed state after that is lower than the viscous liquid mixture of each agent, and it becomes easy to flow. . Therefore, it is necessary to prevent the hair dye from dripping from the hair during the hair dyeing process after foaming.
  • This type of hair dye can be a first hair dyeing method in which a viscous liquid mixture of each agent is applied to the hair and then foamed on the hair to perform a hair dyeing process.
  • a second hair dyeing method is also possible in which hair treatment is carried out as it is without foaming after application to the hair.
  • the viscosity of the drug affects the spread of the hair. In general, the lower the viscosity, the better the spread, but there is concern over dripping when applied to the hair.
  • the hair dye may sag after application to the hair from the standpoint that if the viscosity of the drug at rest is low, it will flow easily. Therefore, it is necessary to prevent the hair dye from dripping from the hair during application and during the subsequent hair dyeing treatment.
  • the 2WAY type hair dye must satisfy the following requirements (1a) to (1c) when used in the first hair dyeing method, and the second hair dyeing method described above.
  • First hair dyeing method (1a) Good foaming and foam retention
  • Second hair dyeing method (2a) Good spread to hair
  • Sufficient dyeing and lightness of hair Prevention of dripping of hair dye during application and subsequent hair dyeing treatment
  • the present invention provides a hair dye that uses a viscous liquid mixture of each of the hair dyes in the 2WAY type, and ensures foaming and foam retention when foamed on the hair, and spread to the hair. Good things are the first purpose.
  • a second object is to ensure sufficient dyeing and lightness of the hair by the hair dye.
  • a third object is to prevent the hair dye from dripping during application and during the hair dyeing process.
  • a first invention for achieving the above object is a multi-component hair dye comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent,
  • the following (A) component and (B) component are contained in the viscous mixture of each agent of the hair dye, and the mass ratio of the content of the (B) component to the content of the (A) component (B) / ( A hair dye in which A) is in the range of 0.2 to 3.
  • Component (A) An ionic surfactant containing at least one component (A1) that is at least one anionic surfactant and component (A2) that is at least one amphoteric surfactant.
  • Component (B) One or more oily components containing at least a higher alcohol and having a total content in the range of 1 to 10% by mass.
  • the hair dye according to the first invention is used for the hair dyeing treatment of one or both of the following (1) and (2).
  • (1) After the viscous liquid mixture is applied to the hair, the hair is foamed on the hair to perform a hair dyeing treatment.
  • (2) After applying the viscous liquid mixture to the hair, the hair is processed without foaming on the hair.
  • “used for both hair dyeing treatments (1) and (2)” means that the hair dyeing methods (1) and (2) for each specific part of the hair in the same hair dyeing treatment. Say to use the process properly.
  • the root part of hair and the hairline part suitable for hair dyeing treatment with a viscous liquid hair dye are subjected to the hair dyeing process of (2), and the other part of the whole hair ( The hair dyeing process of 1) can be performed. This also applies to the sixth invention described later.
  • the total content of the component (A) in the viscous liquid mixture of the hair dye according to the first invention or the second invention is in the range of 1 to 12% by mass. .
  • the component (A2) of the hair dye according to any one of the first to third inventions is a betaine-type amphoteric surfactant.
  • the (A1) component of the hair dye according to any one of the first to fourth inventions is a sulfate ester type anionic surfactant.
  • a sixth invention for achieving the above object is a hair dyeing method using a hair dye, A hair coloring method in which one or both of the following (3) and (4) is performed using the hair dye described in any one of the first to fifth inventions. (3) After the viscous liquid mixture is applied to the hair, the hair is foamed on the hair to perform a hair dyeing treatment. (4) After applying the viscous liquid mixture to the hair, the hair is treated without foaming on the hair.
  • the hair dye of the first invention when applying the viscous liquid mixture of each agent to the hair, and then lathering to the hair, (1a) good foaming and foaming, (1b) hair with the hair dye Sufficient dyeing and lightness can be secured, and (1c) it is possible to prevent dripping of the hair dye during the hair dyeing process after foaming.
  • the hair-dyeing treatment when the hair-dyeing treatment is applied to the hair after applying the viscous mixture of each agent to the hair, (2a) the hair spreads well, and (2b) the hair dyeing agent ensures sufficient dyeing and lightness. Furthermore, (2c) it is possible to prevent the hair dye from dripping down during application and during the subsequent hair dyeing treatment.
  • the effect of (2c) also means that the hair dye can be prevented from dripping at the time of application (before foaming) in the method of foaming hair on the hair.
  • the hair dye of the first invention contains an anionic surfactant as the component (A1) and an amphoteric surfactant as the component (A2) as the component (A). It is in the point. Component (A1) has high foaming power and good foaming. Further, the combined use of component (A2) improves foam retention. Due to the interaction between the component (A1) and the component (A2), both good foaming and good foam retention are achieved.
  • the hair dye of 1st invention contains (B) component which is an oil-based component.
  • the component (B) compensates for the shortage of the above-mentioned hair dyeing power by improving the affinity of the hair dye with respect to the hair. Therefore, even if the hair dye is well foamed, sufficient hair dyeing power can be secured, the hair is dyed well, and the lightness after dyeing is also good.
  • the content of the component (B) in the viscous liquid mixture of each agent of the hair dye is less than 1% by mass, the effect of ensuring the hair dyeing power and lightness cannot be substantially ensured.
  • the content of the component (B) exceeds 10% by mass, the ionic surfactant as the component (A) is taken in by the excess component (B) and defoamed, so that the hair dye is good. Foaming and foam retention are impeded.
  • the mass ratio (B) / (A) of the content of the component (B) to the content of the component (A) in the viscous mixture of the hair dye is inappropriate, the above effect cannot be obtained.
  • the mass ratio (B) / (A) is within an appropriate range of 0.2 to 3, the effect of the first invention is ensured.
  • the mass ratio (B) / (A) is less than 0.2, the blending effect of the component (B) cannot be substantially obtained due to the relative shortage of the component (B).
  • the mass ratio (B) / (A) exceeds 3, the foaming and foam retention of the hair dye become insufficient due to the relative excess of the component (B).
  • the oil component (B) higher oil is blended as the oil component (B).
  • Higher alcohol as an oily component, exhibits an effect of ensuring hair dyeing power and brightness in a hair dye having good foaming, and at the same time imparts an appropriate viscosity to the 2WAY type hair dye. Therefore, dripping of the hair dye is prevented when the viscous liquid mixture of each agent of the hair dye is applied to the hair. Furthermore, in the first hair dyeing method in which the hair is processed by foaming on the hair after that, the hair dye is prevented from dripping during the hair processing after the foaming, and the hair is not foamed on the hair. Even in the second hair dyeing method in which the hair dyeing treatment is performed, dripping of the hair dye during the hair dyeing treatment after application to the hair is prevented.
  • the hair dye of the present invention has a suitable use as a 2WAY type hair dye.
  • the effect of the first invention is particularly remarkable.
  • the total content of the component (A) in the viscous liquid mixture is less than 1% by mass, it is difficult to obtain the good foaming and foam retention when the hair dye is foamed on the hair.
  • the total content exceeds 12% by mass, the hair dye is sufficiently foamed, and the contact area of the liquid part of the foam with respect to the hair is insufficient, so that it is difficult to ensure sufficient dyeing and lightness of the hair.
  • the amphoteric surfactant as the component (A2) is a betaine-type amphoteric surfactant
  • the hair dye composition is compared with the case where an amphoteric surfactant other than the betaine-type surfactant is blended.
  • the foam retention during foaming is particularly good.
  • the anionic surfactant as the component (A1) is a sulfate ester type anionic surfactant, it is compared with the case where an anionic surfactant other than the sulfate ester type is added. Thus, the foaming of the hair dye is particularly good.
  • the hair dye of the present invention can be suitably used as a 2WAY type hair dye as defined in the sixth invention.
  • the hair dye of the present invention is a multi-component hair dye comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent. And it is a multi-component hair dye which applies the viscous liquid mixture of each agent which comprises a hair dye to hair.
  • the 2WAY type can be used as described later.
  • the “multi-component hair dye” means a third agent containing an oxidation aid for the first agent and the second agent, for example, in addition to the two-component hair dye composed of the first agent and the second agent.
  • a hair dye such as a three-part hair dye to which an agent is added is also included.
  • the type of the hair dye is not limited as long as it includes the first agent containing the alkaline agent and the second agent containing the oxidizing agent.
  • the oxidizing hair dye, the hair bleaching agent, A hair destaining agent is mentioned.
  • the hair dye of the present invention contains the following component (A) as an essential component in the viscous mixture of the hair dye. And (B) component is contained.
  • component (A) An ionic surfactant containing at least one component (A1) that is at least one anionic surfactant and component (A2) that is at least one amphoteric surfactant.
  • component (B) One or more oily components containing at least a higher alcohol and having a total content in the range of 1 to 10% by mass.
  • the mass ratio (B) / (A) of the content of the component (B) to the content of the component (A) in the viscous liquid mixture is in the range of 0.2 to 3. More preferably, the mass ratio (B) / (A) is in the range of 0.3 to 2.5.
  • the component (A1) as the component (A) is a sulfate ester type anionic surfactant
  • the component (A2) is a betaine type amphoteric surfactant.
  • the cationic surfactant which is an ionic surfactant other than the component (A1) and the component (A2) may or may not be contained as the component (A).
  • component (A1) component, (A2) component, cationic surfactant contained as component (A), and each component of component (B) are the first agent, the second agent or the second agent in the multi-component hair dye, respectively.
  • the mixture of each agent is a viscous liquid.
  • “Viscous liquid” means a liquid having a viscosity that does not cause dripping from the hair when applied to the hair as it is. Examples of viscous liquids include gels, creams, and emulsions. Gels or creams are particularly preferable.
  • each agent before mixing may be a viscous liquid, and some of the agents in each agent It may be a non-viscous liquid or powder.
  • a method for preparing a viscous mixture of each agent of the hair dye is not limited, and can be performed manually or using a simple tool, for example.
  • the method of applying the viscous liquid mixture to the hair is not limited, but for example, a comb or a brush may be used, or the viscous liquid mixture may be discharged from an appropriate applicator.
  • the hair dye of the present invention has a 2WAY type application, or a 2WAY type usage method is possible. That is, after applying a viscous liquid mixture of hair dye to the hair, it can also be used in the first hair dyeing method in which foaming is performed on the hair to perform the hair dyeing process. It can also be used in a second hair dyeing method in which hair is treated without foaming on the hair after application to the hair. Furthermore, in the same hair dyeing process, the first hair dyeing method and the second hair dyeing method can be simultaneously performed for each hair portion.
  • the method of foaming the viscous mixture applied to the hair is not limited, but preferably the foam can be foamed by swallowing the viscous mixture on the hair.
  • the hair dyeing method After applying a viscous liquid mixture of hair dye to the hair, it is usually immediately foamed on the hair and then left for about 3 to 60 minutes for hair dyeing treatment.
  • the hair In the second hair dyeing method described above, after applying a viscous liquid mixture of hair dyes to the hair, the hair is treated by leaving it for about 3 to 60 minutes without foaming.
  • the component (A) is an ionic surfactant containing at least one component (A1) that is an anionic surfactant and one component (A2) that is at least one amphoteric surfactant.
  • a cationic surfactant that is one type of ionic surfactant may or may not be contained in the hair dye of the present invention as the component (A).
  • the nonionic surfactant is not the component (A), but may be contained in the hair dye of the present invention.
  • the total content of the component (A) in the hair dye of the present invention is not limited, but is preferably in the range of 1 to 12% by mass in the viscous mixture of the hair dye.
  • the total content of component (A) needs to be set so that the mass ratio (B) / (A) is within the range of 0.2 to 3 in relation to the content of component (B). is there.
  • This mass ratio can preferably be set to be within the range of 0.3 to 2.5.
  • the contents of the components (A1) and (A2) in the hair dye of the present invention are not particularly limited, but preferably, assuming that the mass ratio (B) / (A) is within the above range,
  • the component (A1) is in the range of 0.5 to 10% by mass in the viscous mixture of the hair dye
  • the component (A2) is in the range of 0.2 to 6% by mass in the viscous mixture of the hair dye.
  • the mass ratio (A1) / (A2) of the content of the components (A1) and (A2) in the viscous mixture of the hair dye is not particularly limited.
  • the mass ratio (A1) / (A2) A range of 1 to 5 is preferred.
  • the nonionic surfactant is not the component (A), but may be contained in the hair dye of the present invention.
  • the hair dye contains a nonionic surfactant, the content thereof can be arbitrarily selected. For example, it can be about 0.2 to 8% by mass in the viscous liquid mixture of the hair dye.
  • Component anionic surfactant includes sulfate ester salt type, phosphate ester salt type, carboxylate salt type, sulfonate salt type, fatty acid salt type, lactate salt type, sarcosine salt type, glutamate salt type , Alanine salt type, taurine salt type, ⁇ -sulfo fatty acid methyl ester salt, sulfosuccinate and isethionate are all included. Among these, a sulfate ester type anionic surfactant is particularly preferable.
  • anionic surfactant examples include sodium lauryl sulfate, sodium myristyl sulfate, potassium lauryl sulfate, ammonium lauryl sulfate, triethanolamine lauryl sulfate, sodium cetyl sulfate, sodium stearyl sulfate, and polyoxyethylene (hereinafter referred to as “POE”).
  • the amphoteric surfactant as component (A2) includes all amphoteric surfactants of alkyl betaine type, fatty acid amide propyl betaine type, alkyl imidazole type, and amino acid type.
  • betaine-type amphoteric surfactants that is, alkylbetaine-type and fatty acid amidopropylbetaine-type amphoteric surfactants are particularly preferable.
  • amphoteric surfactants include lauryl betaine, lauryl dimethylaminoacetic acid betaine, stearyl dimethylaminoacetic acid betaine, imidazoline, amide betaine, carbobetaine, sulfobetaine, hydroxysulfobetaine, amidosulfobetaine, 2-alkyl-N-.
  • Carboxymethyl-N-hydroxyethylimidazolinium betaine 2-undecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine sodium, cocoamidopropylbetaine, cocoamidopropylhydroxysultain, lauryldimethylaminoacetic acid betaine, lauroyl Arginine etc. are illustrated.
  • the type of the cationic surfactant included in the component (A) is not limited, and examples thereof include quaternary ammonium salt type, alkylamine salt type, pyridinium-based cationic surfactants.
  • Specific examples of cationic surfactants include lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride (steartrimonium chloride), distearyl dimethyl ammonium chloride, behenyl trimethyl ammonium chloride (behentrimonium chloride), odor Examples thereof include cetyltrimethylammonium bromide, stearyltrimethylammonium bromide, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, stearyltrimethylammonium saccharin, cetyltrimethylammonium saccharin, and methyl behenyltrimethylammonium sulfate.
  • the nonionic surfactant is not the component (A), but includes nonionic surfactants such as ester type, ether type, ester ether type, and alkanolamide type.
  • nonionic surfactants such as ester type, ether type, ester ether type, and alkanolamide type.
  • a higher alcohol is included in the nonionic surfactant, but in the present invention, the higher alcohol is positioned as one type of the oil component (B).
  • ether type nonionic surfactants such as POE (2) lauryl ether, POE (2) stearyl ether, POE (50) oleyl ether, POE (20) behenyl ether, etc.
  • POE alkyl ethers may be mentioned.
  • Other examples include POE alkylphenyl ethers and POE polyoxypropylene (POP) alkyl ethers.
  • ester type nonionic surfactant include glycerin fatty acid ester, POE glycerin fatty acid ester, POE sorbitan fatty acid ester, POE propylene glycol fatty acid ester, and sucrose fatty acid ester.
  • the component (B) is at least one oily component containing at least a higher alcohol and having a total content of 1 to 10% by mass in the viscous liquid mixture of each agent of the hair dye.
  • the total content of the component (B) is particularly preferably in the range of 1.5 to 9% by mass, and the higher alcohol is preferably in the range of 1 to 8% by mass.
  • the total content of the component (B) can be set so that the mass ratio (B) / (A) is in the range of 0.2 to 3, particularly in the range of 0.3 to 2.5. preferable.
  • the oil component as the component includes at least higher alcohols, fats and oils, waxes, higher fatty acids, alkyl glyceryl ethers, esters, silicones, and hydrocarbons. Of these, higher alcohols are essential as the component (B).
  • Higher alcohol is an alcohol having a carbon chain with 6 or more carbon atoms.
  • An alcohol having a carbon chain having 12 or more carbon atoms is more preferable.
  • the carbon chain may be saturated or unsaturated.
  • a higher alcohol such as 2-octyldodecanol having a branched carbon chain can also be used.
  • higher alcohols having a linear carbon chain are preferred in terms of “ensuring hair dyeing power and lightness” and “providing appropriate viscosity to the hair dye”.
  • Aromatic alcohols are not included in the higher alcohols of the present invention.
  • higher alcohols include lauryl alcohol, myristyl alcohol, cetyl alcohol (cetanol), stearyl alcohol, cetostearyl alcohol, aralkyl alcohol, behenyl alcohol, 2-hexyldecanol, isostearyl alcohol, 2-octyldodecanol, decyltetradecanol Oleyl alcohol, linoleyl alcohol, linolenyl alcohol, lanolin alcohol and the like.
  • Oils include olive oil, rosehip oil, camellia oil, shea fat, macadamia nut oil, almond oil, tea seed oil, sasanqua oil, safflower oil, sunflower oil, soybean oil, cottonseed oil, sesame oil, beef fat, cocoa butter, corn oil , Peanut oil, rapeseed oil, rice bran oil, rice germ oil, wheat germ oil, pearl barley oil, grape seed oil, avocado oil, carrot oil, macadamia nut oil, castor oil, linseed oil, palm oil, mink oil, egg yolk oil, etc. Is mentioned.
  • waxes examples include beeswax, candelilla wax, carnauba wax, jojoba oil, lanolin, whale wax, rice bran wax, sugar cane wax, palm wax, montan wax, cotton wax, bayberry wax, ibota wax, kapok wax, shellac wax, and the like.
  • higher fatty acids examples include palmitic acid, stearic acid, behenic acid, isostearic acid, hydroxystearic acid, 12-hydroxystearic acid, oleic acid, undecylenic acid, linoleic acid, ricinoleic acid, and lanolin fatty acid.
  • alkyl glyceryl ether examples include batyl alcohol (monostearyl glyceryl ether), chimyl alcohol (monocetyl glyceryl ether), ceralkyl alcohol (monooleyl glyceryl ether), and isostearyl glyceryl ether.
  • Esters include diisopropyl adipate, isopropyl myristate, cetyl octanoate, isononyl isononanoate, isopropyl palmitate, butyl stearate, hexyl laurate, decyl oleate, octyldodecyl ricinoleate, lanolin acetate, isocetyl isostearate, diester Examples include pentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, cetyl caprate, and lanolin derivatives.
  • Silicones include dimethylpolysiloxane (INCI name: dimethicone), dimethylpolysiloxane having hydroxy end groups (INCI name: dimethiconol), methylphenylpolysiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and polyether-modified.
  • Examples include silicone, highly polymerized silicone having an average polymerization degree of 650 to 10,000, amino-modified silicone, betaine-modified silicone, alkyl-modified silicone, alkoxy-modified silicone, mercapto-modified silicone, carboxy-modified silicone, and the like.
  • amino-modified silicones include aminopropylmethylsiloxane / dimethylsiloxane copolymer (INCI name: aminopropyl dimethicone), aminoethylaminopropylsiloxane / dimethylsiloxane copolymer (INCI name: amodimethicone), aminoethyl. And aminopropylmethylsiloxane / dimethylsiloxane copolymer (INCI name: trimethylsilylamodimethicone).
  • hydrocarbon examples include ⁇ -olefin oligomer, light isoparaffin, light liquid isoparaffin, liquid isoparaffin, liquid paraffin, squalane, polybutene, paraffin, polyethylene powder, microcrystalline wax, petrolatum and the like.
  • the first agent contains an alkaline agent
  • the second agent contains an oxidizing agent.
  • This hair dye is, for example, an oxidative hair dye.
  • the oxidative hair dye swells the hair with the alkaline agent in the first agent, and allows the oxidative dye intermediate and the oxidant in the second agent to penetrate into the hair. Further, the action of the oxidizing agent is promoted by the pH change based on the alkaline agent. Examples of the action of the oxidizing agent include decomposing and decolorizing melanin contained in the hair, and, at the same time, oxidative polymerization of the oxidative dye intermediate compounded in the first agent to develop a color. Oxidative dye intermediates consist of major intermediates or consist of major intermediates and couplers. In order to adjust the hair color tone, the oxidative hair dye may be further blended with a direct dye.
  • Alkaline agents include ammonia, alkanolamines (monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2- Methyl-1,3-propanediol, etc.), ammonium salts, organic amines (guanidine, etc.), inorganic alkalis (sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, etc.), basic amino acids (arginine, lysine, etc.) And salts thereof.
  • alkanolamines monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, triisopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2- Methyl-1,3-propanediol, etc.
  • hydrogen peroxide is particularly preferable, but other examples include potassium bromate, sodium bromate, sodium perborate, and peroxide.
  • Peroxides include urea peroxide, melamine peroxide, sodium percarbonate, potassium percarbonate, sodium perborate, potassium perborate, ammonium persulfate, sodium peroxide, potassium peroxide, magnesium peroxide, barium peroxide. , Calcium peroxide, strontium peroxide, sulfate hydrogen peroxide adduct, phosphate hydrogen peroxide adduct, pyrophosphate hydrogen peroxide adduct, and the like.
  • main intermediates include colored dye precursors that are mainly o- or p-phenylenediamines or aminophenols.
  • Couplers mainly include m-diamines, aminophenols or diphenols, and specifically include resorcin, catechol, pyrogallol, phloroglucin, gallic acid, hydroquinone, 5-amino-o-cresol, m-amino.
  • Phenol 5- (2-hydroxyethylamino) -2-methylphenol, m-phenylenediamine, 2,4-diaminophenoxyethanol, toluene-3,4-diamine, ⁇ -naphthol, 2,6-diaminopyridine, diphenylamine, Examples thereof include 3,3′-iminodiphenyl, 1,5-dihydroxynaphthalene and tannic acid and their salts.
  • Examples of direct dyes include various acid dyes, basic dyes, nitro dyes, natural dyes, and disperse dyes.
  • polyhydric alcohol examples include glycols and glycerins. Specific examples of glycols include ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, 1,3-butylene glycol and the like. Examples of glycerins include glycerin, diglycerin, and polyglycerin.
  • Peptides and amino acid components include animal proteins such as collagen, keratin, elastin, fibroin, silk, casein, and gelatin, proteins obtained from plants such as wheat, barley, oats, soybeans, almonds, and the like. Examples thereof include those hydrolyzed by alkali, enzyme, and the like.
  • polymer compound examples include cationized cellulose derivatives, cationic starch, cationized guar gum, diallyl quaternary ammonium salt polymers or copolymers, quaternized polyvinylpyrrolidone, and the like.
  • a polymer of a quaternary ammonium salt obtained by adding glycidyltrimethylammonium chloride to hydroxyethyl cellulose POLYQUATERNIUM-10, for example, LEOGARD G, GP; Lion Corporation ], Hydroxyethylcellulose dimethyldiallylammonium chloride [POLYQUATERNIUM-4, eg, Cellcoat H-100 (National Starch and Chemical Co.), O- [2-hydroxy-3- (lauryldimethyl) Examples include ammonio) propyl] hydroxyethylcellulose and the like.
  • diallyl quaternary ammonium salt examples include dimethyldiallylammonium chloride polymer (polydimethylmethylenepiperidinium chloride) [POLYQUATERNIUM-6], for example, MERQUAT 100; Nalco ], Dimethyldiallylammonium chloride / acrylic acid copolymer [POLYQUATERNIUM-22, such as MERQUAT 280; Nalco, Inc.], acrylic acid / diallyl quaternary ammonium salt / acrylamide copolymer [polyquaternium -39 (POLYQUATERNIUM-39), such as MERQUAT PLUS 3331 (Nalco), etc.
  • quaternized polyvinylpyrrolidone quaternary ammonium salt obtained from a copolymer of vinylpyrrolidone (VP) and dimethylaminoethyl methacrylate and diethyl sulfate [POLYQUATERNIUM-11, for example, GAFQUAT 734] , 755; IS Japan Co., Ltd.].
  • polymer compound examples include anionic polymers such as carboxyvinyl polymer, water-soluble polymers, and the like.
  • water-soluble polymers include vegetable polymers such as gum arabic, xanthan gum, carrageenan, pectin, agar, starch, and alge colloid (brown algae extract), microbial polymers such as dextran and pullulan, carboxymethyl starch, methyl
  • starch polymers such as hydroxypropyl starch
  • cellulose polymers such as methylcellulose, ethylcellulose, nitrocellulose, and hydroxyethylcellulose
  • alginic acid polymers such as sodium alginate
  • vinyl polymers such as carboxyvinyl polymer.
  • the pH buffer component comprises an acid component that is an inorganic acid or an organic acid, and an alkali component that is an inorganic alkali or an organic alkali. In particular, those composed of an organic acid and an organic alkali are preferred.
  • organic acids examples include hydroxycarboxylic acids (glycolic acid, lactic acid, malic acid, citric acid, tartaric acid, etc.) and dicarboxylic acids (succinic acid, etc.).
  • Organic alkali includes volatile alkali components such as morpholine, alkanolamines such as monoethanolamine, amino alcohols such as 2-amino-2-methyl-1-propanol, L-arginine, L-lysine, L- Examples include basic amino acids such as histidine.
  • cationic compound examples include acid neutralized tertiary amidoamines.
  • the hair dye of the present invention may optionally contain preservatives such as water, methylparaben, phenoxyethanol, chelating agents such as EDTA-2Na, ceramides, vitamins, plant extracts, ultraviolet absorbers, and fragrances. Can be contained.
  • preservatives such as water, methylparaben, phenoxyethanol, chelating agents such as EDTA-2Na, ceramides, vitamins, plant extracts, ultraviolet absorbers, and fragrances.
  • the cationic surfactant is indicated as “(Ac)” on the left side of the component name
  • the component (A1) For certain anionic surfactants, “(A1)” is written on the left side of the component name, and for the amphoteric surfactants that are component (A2), “(A2)” is written on the left side of the component name, (B The oily component which is a component) is indicated by “(B)” on the left side of the component name.
  • the total content (% by mass) of the ionic surfactant in the first agent and the second agent is respectively expressed as “(A) Total (one agent)”. "And” (A) Total (2 agents) ". Further, for each of the Examples and Comparative Examples, the total content (mass%) of the oily component in the first agent and the second agent is set in the “(B) Total (one agent)” column and “(B) Total ( 2 agents) ”.
  • the mass ratio (B) / (A) of the total content of the component (B) to the total content of the component (A) in these viscous liquid mixtures is shown in the column “B / A” in the table.
  • the numerical values are rounded off to the third decimal place.
  • the evaluation results of each example and each comparative example are shown in the “bubble” column of Tables 1 to 3 by numbers representing the goodness of evaluation.
  • the number “6” indicates that “It is very easy to foam and the bubbles did not disappear at all”.
  • the number “5” indicates that “It was very easy to foam and the foam hardly disappeared” or “It was easy to foam and the foam did not disappear at all”.
  • the number “4” indicates that “foaming is easy and the foam hardly disappears”.
  • the number “3” indicates that “foaming is easy and the foam has disappeared slightly” or “slightly foaming is almost possible and the foam has hardly disappeared”.
  • the number “2” indicates “slightly difficult to foam and bubbles disappeared” or “difficult to foam and bubbles slightly disappeared”.
  • the number “1” indicates “no bubbling”.
  • the evaluation results of each example and each comparative example are shown in the “brightness” column of Tables 1 to 3 by numbers representing good evaluation.
  • the number “5” indicates “very good”.
  • the number “4” indicates “excellent”.
  • the number “3” indicates “good”.
  • the number “2” indicates “somewhat bad”.
  • the number “1” indicates “bad”.
  • the evaluation results of each example and each comparative example are shown in the “Sagging (2)” section of the “Evaluation” column of Tables 1 to 3 by a number indicating the goodness of evaluation.
  • the number “3” indicates that “no dripping was observed even when 20 g of the viscous liquid mixture was applied”.
  • the number “2” indicates that “no dripping was observed even when 10 g of the viscous liquid mixture was applied”.
  • the number “1” indicates that “sagging was observed when 10 g of the viscous liquid mixture was applied”.
  • a 2WAY type hair dye that has good foaming and foam retention when foamed on the hair, has good hair dyeing and lightness, and does not cause dripping of the hair dye during hair dyeing treatment.

Abstract

Cette invention concerne un colorant capillaire de type double action qui mousse bien et conserve bien sa mousse une fois mis en mousse sur les cheveux, tout en étant empêché de s'égoutter pendant le processus de coloration. Le colorant capillaire de type double action selon l'invention fait preuve d'une bonne performance de coloration des cheveux et confère aux cheveux une belle brillance. Cette invention concerne également un colorant capillaire de type multi-pack, qui est conçu pour contenir un premier agent qui contient un agent alcalin et un second agent qui contient un oxydant, le mélange liquide visqueux de chaque agent du colorant capillaire contenant le composant (A) et le composant (B) décrits ci-dessous, et le rapport en poids du composant (B) contenu au composant (A) contenu, à savoir (B)/(A) étant dans la plage de 0,2 à 3. Composant (A) : tensioactif ionique qui contient au moins le composant (A1) qui est constitué d'un ou de plusieurs types de tensioactifs anioniques et le composant (A2) qui est constitué d'un ou de plusieurs types de tensioactifs amphotères Composant (B) : un ou plusieurs types de composants huileux qui contiennent au moins un alcool supérieur, sa teneur totale étant dans la plage de 1 à 10 % en poids
PCT/JP2012/056640 2012-03-15 2012-03-15 Colorant capillaire et procédé de coloration des cheveux WO2013136480A1 (fr)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018081399A1 (fr) * 2016-10-31 2018-05-03 L'oreal Compositions pour cheveux traités chimiquement
US10231915B2 (en) 2015-05-01 2019-03-19 L'oreal Compositions for altering the color of hair
US10441518B2 (en) 2015-11-24 2019-10-15 L'oreal Compositions for treating the hair
US11083675B2 (en) 2015-11-24 2021-08-10 L'oreal Compositions for altering the color of hair
US11090249B2 (en) 2018-10-31 2021-08-17 L'oreal Hair treatment compositions, methods, and kits for treating hair
US11135150B2 (en) 2016-11-21 2021-10-05 L'oreal Compositions and methods for improving the quality of chemically treated hair
US11213470B2 (en) 2015-11-24 2022-01-04 L'oreal Compositions for treating the hair
US11419809B2 (en) 2019-06-27 2022-08-23 L'oreal Hair treatment compositions and methods for treating hair
US11433011B2 (en) 2017-05-24 2022-09-06 L'oreal Methods for treating chemically relaxed hair
US11596588B2 (en) 2017-12-29 2023-03-07 L'oreal Compositions for altering the color of hair
US11826451B2 (en) 2019-12-31 2023-11-28 L'oreal Compositions for treating hair

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0320209A (ja) * 1989-06-16 1991-01-29 Hoyu Co Ltd 染毛剤組成物
JPH0499711A (ja) * 1990-08-14 1992-03-31 Yamahatsu Sangyo Kk 染毛剤
JPH09278637A (ja) * 1996-02-10 1997-10-28 Wella Ag 酸化毛髪染色剤
JP2000290150A (ja) * 1999-04-02 2000-10-17 Hoyu Co Ltd 液状染毛剤組成物
JP2004339216A (ja) * 2003-04-25 2004-12-02 Kao Corp 毛髪化粧品
JP2010053103A (ja) * 2008-08-29 2010-03-11 Hoyu Co Ltd 酸化染毛剤組成物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0320209A (ja) * 1989-06-16 1991-01-29 Hoyu Co Ltd 染毛剤組成物
JPH0499711A (ja) * 1990-08-14 1992-03-31 Yamahatsu Sangyo Kk 染毛剤
JPH09278637A (ja) * 1996-02-10 1997-10-28 Wella Ag 酸化毛髪染色剤
JP2000290150A (ja) * 1999-04-02 2000-10-17 Hoyu Co Ltd 液状染毛剤組成物
JP2004339216A (ja) * 2003-04-25 2004-12-02 Kao Corp 毛髪化粧品
JP2010053103A (ja) * 2008-08-29 2010-03-11 Hoyu Co Ltd 酸化染毛剤組成物

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10993896B2 (en) 2015-05-01 2021-05-04 L'oreal Compositions for altering the color of hair
US10231915B2 (en) 2015-05-01 2019-03-19 L'oreal Compositions for altering the color of hair
US11213470B2 (en) 2015-11-24 2022-01-04 L'oreal Compositions for treating the hair
US10828244B2 (en) 2015-11-24 2020-11-10 L'oreal Compositions for treating the hair
US10441518B2 (en) 2015-11-24 2019-10-15 L'oreal Compositions for treating the hair
US11083675B2 (en) 2015-11-24 2021-08-10 L'oreal Compositions for altering the color of hair
US11191706B2 (en) 2015-11-24 2021-12-07 L'oreal Compositions for altering the color of hair
WO2018081399A1 (fr) * 2016-10-31 2018-05-03 L'oreal Compositions pour cheveux traités chimiquement
US11135150B2 (en) 2016-11-21 2021-10-05 L'oreal Compositions and methods for improving the quality of chemically treated hair
US11433011B2 (en) 2017-05-24 2022-09-06 L'oreal Methods for treating chemically relaxed hair
US11596588B2 (en) 2017-12-29 2023-03-07 L'oreal Compositions for altering the color of hair
US11090249B2 (en) 2018-10-31 2021-08-17 L'oreal Hair treatment compositions, methods, and kits for treating hair
US11419809B2 (en) 2019-06-27 2022-08-23 L'oreal Hair treatment compositions and methods for treating hair
US11826451B2 (en) 2019-12-31 2023-11-28 L'oreal Compositions for treating hair

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