WO2013108177A1 - Carburant solide sous forme d'une poudre comprenant un constituant lignocellulosique - Google Patents

Carburant solide sous forme d'une poudre comprenant un constituant lignocellulosique Download PDF

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Publication number
WO2013108177A1
WO2013108177A1 PCT/IB2013/050364 IB2013050364W WO2013108177A1 WO 2013108177 A1 WO2013108177 A1 WO 2013108177A1 IB 2013050364 W IB2013050364 W IB 2013050364W WO 2013108177 A1 WO2013108177 A1 WO 2013108177A1
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WO
WIPO (PCT)
Prior art keywords
powder
weight
fuel
particles
iii
Prior art date
Application number
PCT/IB2013/050364
Other languages
English (en)
French (fr)
Inventor
Bruno PIRIOU
Gilles VAITILINGOM
Xavier Rouau
Original Assignee
Centre De Cooperation Internationale En Recherche Agronomique Pour Le Developpement (Cirad)
Institut National De La Recherche Agronomique
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre De Cooperation Internationale En Recherche Agronomique Pour Le Developpement (Cirad), Institut National De La Recherche Agronomique filed Critical Centre De Cooperation Internationale En Recherche Agronomique Pour Le Developpement (Cirad)
Priority to BR112014017727A priority Critical patent/BR112014017727A8/pt
Priority to US14/372,915 priority patent/US20150007492A1/en
Priority to IN5941DEN2014 priority patent/IN2014DN05941A/en
Priority to CA2861243A priority patent/CA2861243A1/fr
Priority to EP13705589.3A priority patent/EP2804932A1/de
Publication of WO2013108177A1 publication Critical patent/WO2013108177A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00—Solid fuels
    • C10L5/40—Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44—Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2250/00—Structural features of fuel components or fuel compositions, either in solid, liquid or gaseous state
    • C10L2250/06—Particle, bubble or droplet size
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/04—Specifically adapted fuels for turbines, planes, power generation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/08—Drying or removing water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/28—Cutting, disintegrating, shredding or grinding
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • WO 01/98438 discloses a solid fuel containing predominantly at least one constituent, which contains mainly at least one compound selected from the group consisting of starch, lactose, cellulose and at least 15% by weight of carbohydrates by weight total component (s) being in the form of a powder whose mean diameter and the median diameter of the particles are greater than or equal to 150 pm, preferably between 150 and 500 ⁇ .
  • the exemplified powders are dehydrated chocolate powder, dehydrated milk powder, and the remolding fraction of a wheat flour.
  • the powders described in this application have the disadvantage of competing with the food chain. Moreover, being unable to operate in the conditions of self ignition, the powders described in this application can not be a suitable solution for many engine applications.
  • the moisture content of the particles of the powder (P) is at most 15% by weight, preferably at most 10% by weight, more preferably less than or equal to 5% by weight, still more preferably less than or equal to 2% by weight of water, relative to the total mass of the powder (P).
  • step (iii) is carried out for from 2 to 72 hours, preferably from 4 to 48 hours,
  • a selective sorting of the particles from step (iii) can be carried out by a sorting process as described above, in order to obtain different populations of powders in order to improve their qualities as a motor fuel. .
  • a population of sorted particles having a higher lignin content and thus a higher calorific value can be selected.
  • the process according to the invention is simple and economical.
  • the invention also relates to the use of a lignocellulosic constituent in the form of a powder (P) whose mean diameter and the median diameter (d 50 ) of the particles are less than or equal to 35 ⁇ , preferably included between 10 and 30 ⁇ , more preferably between 10 and 20 ⁇ , obtained according to the process of the invention, for the manufacture of a solid fuel intended for an internal combustion engine.
  • the fuel according to the invention can be used alone or mixed with other fuels. It can be used, for example, for the operation of internal combustion engines whether spark ignition or diesel, for the operation of turbines, boilers, industrial furnaces involving burners.
  • Particles having a mean diameter and a median diameter (d 50 ) of 20 microns were obtained with a feed rate of approximately 700 g / hour (ie 20 rpm for the hopper) and a speed of rotation of the selector. 6000 rpm.
  • lignin (Sigma-Aldrich), obtained by kraft process, with a high sodium content and about 3% sulfur, median diameter 100 microns (d 5 o);
  • Ultracarbofluid dry residue of vegetable charcoal used in slurry
  • bimodal particle size distribution probable agglomeration of particles of median diameter (d 50 ) 18 microns in clusters of 350 microns.
  • the fuel powders according to the invention do not compete with the food chain in terms of agricultural land use.
  • the conversion into energy of the fuel powders according to the invention in an internal combustion engine extends to high-speed applications and especially transport, unlike coal powders.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
PCT/IB2013/050364 2012-01-18 2013-01-15 Carburant solide sous forme d'une poudre comprenant un constituant lignocellulosique WO2013108177A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BR112014017727A BR112014017727A8 (pt) 2012-01-18 2013-01-15 Carburante sólido em forma de um pó, compreendendo um constituinte lignocelulósico
US14/372,915 US20150007492A1 (en) 2012-01-18 2013-01-15 Solid fuel in the form of a powder, including a lignocellulosic component
IN5941DEN2014 IN2014DN05941A (de) 2012-01-18 2013-01-15
CA2861243A CA2861243A1 (fr) 2012-01-18 2013-01-15 Carburant solide sous forme d'une poudre comprenant un constituant lignocellulosique
EP13705589.3A EP2804932A1 (de) 2012-01-18 2013-01-15 Festbrennstoff in pulverform, mit einer lignocellulose-komponente

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1250511A FR2985735B1 (fr) 2012-01-18 2012-01-18 Carburant solide sous forme d'une poudre comprenant un constituant lignocellulosique
FR1250511 2012-01-18

Publications (1)

Publication Number Publication Date
WO2013108177A1 true WO2013108177A1 (fr) 2013-07-25

Family

ID=47747728

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2013/050364 WO2013108177A1 (fr) 2012-01-18 2013-01-15 Carburant solide sous forme d'une poudre comprenant un constituant lignocellulosique

Country Status (8)

Country Link
US (1) US20150007492A1 (de)
EP (1) EP2804932A1 (de)
AR (1) AR090413A1 (de)
BR (1) BR112014017727A8 (de)
CA (1) CA2861243A1 (de)
FR (1) FR2985735B1 (de)
IN (1) IN2014DN05941A (de)
WO (1) WO2013108177A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105176622A (zh) * 2015-09-08 2015-12-23 吉林省一鑫生物质新能源发展有限公司 一种秸秆燃料固体成型方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3015312B1 (fr) * 2013-12-24 2016-01-01 Agronomique Inst Nat Rech Procede de fractionnement par voie seche de biomasse lignocellulosique
EP3050943A1 (de) * 2015-01-27 2016-08-03 Institut National De La Recherche Agronomique Verfahren zur thermochemischen Vorbehandlung einer Biomasse aus Holzzellulose im Trockenprozess
CN112646594B (zh) * 2020-11-10 2022-03-18 涉县清漳水泥制造有限公司 一种可阶梯利用生物质发电的热电联产系统
CN114798666A (zh) * 2022-03-28 2022-07-29 临泉县双军农业机械有限公司 一种大型秸秆粉碎揉丝一体机

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2079311A (en) * 1980-05-10 1982-01-20 Fischer Karl O P Process for recovery, treatment and refinement of coniferous substances
WO2001098438A1 (fr) 2000-06-20 2001-12-27 Guillaume Pourtout Carburant solide et melange combustible le contenant
WO2008063549A2 (en) 2006-11-17 2008-05-29 Summerhill Biomass Systems, Inc. Powdered fuels, dispersions thereof, and combustion devices related thereto
WO2009158709A2 (en) 2008-06-28 2009-12-30 White Ken W Powdered fuel production methods and systems useful in farm to flame systems

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US6468645B1 (en) * 1998-01-07 2002-10-22 Robert N. Clausi Molding finely powdered lignocellulosic fibers into high density materials
EA200801191A1 (ru) * 2005-10-26 2009-02-27 Деверо Холдингс Пти Лтд. Способ, система и установка для пассивирования углеродсодержащих материалов
JP2008013738A (ja) * 2006-07-06 2008-01-24 Biomass Products:Kk リグノセルロース系バイオマス微細粉燃料と、その製造方法
US8652222B2 (en) * 2008-02-29 2014-02-18 Greatpoint Energy, Inc. Biomass compositions for catalytic gasification
EP3568451A1 (de) * 2009-05-22 2019-11-20 KiOR, Inc. Verarbeitung von biomasse mit einer wasserstoffquelle
FI126842B (fi) * 2010-06-07 2017-06-15 Aalto Univ Found Uusi menetelmä mikroselluloosan valmistamiseksi
JP5967730B2 (ja) * 2011-05-04 2016-08-10 レンマティックス, インコーポレイテッドRenmatix, Inc. リグノセルロース系バイオマスからのリグニンの製造

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2079311A (en) * 1980-05-10 1982-01-20 Fischer Karl O P Process for recovery, treatment and refinement of coniferous substances
WO2001098438A1 (fr) 2000-06-20 2001-12-27 Guillaume Pourtout Carburant solide et melange combustible le contenant
WO2008063549A2 (en) 2006-11-17 2008-05-29 Summerhill Biomass Systems, Inc. Powdered fuels, dispersions thereof, and combustion devices related thereto
WO2009158709A2 (en) 2008-06-28 2009-12-30 White Ken W Powdered fuel production methods and systems useful in farm to flame systems

Non-Patent Citations (4)

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Title
ABBASI T. ET AL., JOURNAL OF HAZARDOUS MATERIALS, vol. 140, 2007, pages 7 - 44
AMYOTTE P.R. ET AL., JOURNAL OF CHEMICAL HEALTH AND SAFETY, 2010, pages 15 - 28
BELL S. R. ET AL., FUEL, vol. 67, 1988, pages 474 - 481
GABRIELA GHIZZI D SILVA ET AL: "Effects of grinding processes on enzymatic degradation of wheat straw", BIORESOURCE TECHNOLOGY, ELSEVIER BV, GB, vol. 103, no. 1, 16 September 2011 (2011-09-16), pages 192 - 200, XP028120862, ISSN: 0960-8524, [retrieved on 20110922], DOI: 10.1016/J.BIORTECH.2011.09.073 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105176622A (zh) * 2015-09-08 2015-12-23 吉林省一鑫生物质新能源发展有限公司 一种秸秆燃料固体成型方法

Also Published As

Publication number Publication date
BR112014017727A2 (de) 2017-06-20
CA2861243A1 (fr) 2013-07-25
US20150007492A1 (en) 2015-01-08
FR2985735A1 (fr) 2013-07-19
AR090413A1 (es) 2014-11-12
BR112014017727A8 (pt) 2017-07-11
FR2985735B1 (fr) 2014-09-12
IN2014DN05941A (de) 2015-06-26
EP2804932A1 (de) 2014-11-26

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