WO2013106017A2 - Compositions de zéolites de type x d'aminosilicates converties avec un liant - Google Patents

Compositions de zéolites de type x d'aminosilicates converties avec un liant Download PDF

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Publication number
WO2013106017A2
WO2013106017A2 PCT/US2012/032255 US2012032255W WO2013106017A2 WO 2013106017 A2 WO2013106017 A2 WO 2013106017A2 US 2012032255 W US2012032255 W US 2012032255W WO 2013106017 A2 WO2013106017 A2 WO 2013106017A2
Authority
WO
WIPO (PCT)
Prior art keywords
zeolite
composition
lta
binder
converted
Prior art date
Application number
PCT/US2012/032255
Other languages
English (en)
Other versions
WO2013106017A3 (fr
Inventor
Jack E. Hurst
Linda S. Cheng
Robert W. Broach
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc filed Critical Uop Llc
Priority to BR112013021043A priority Critical patent/BR112013021043A2/pt
Priority to RU2013147991/05A priority patent/RU2544673C1/ru
Priority to CN201280013151.XA priority patent/CN103517876A/zh
Priority to JP2014503971A priority patent/JP2014522357A/ja
Priority to KR1020137022035A priority patent/KR101504053B1/ko
Priority to SG2013057849A priority patent/SG192213A1/en
Priority to EP12864937.3A priority patent/EP2697166A4/fr
Publication of WO2013106017A2 publication Critical patent/WO2013106017A2/fr
Publication of WO2013106017A3 publication Critical patent/WO2013106017A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/22—Type X
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004—Sorbent size or size distribution, e.g. particle size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28011—Other properties, e.g. density, crush strength
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers

Abstract

L'invention concerne une composition zéolitique convertie avec un liant, laquelle comprend (a) une composition de zéolites X comprenant une première zéolite X présentant un diamètre moyen égal ou inférieur à 2,7 microns, et une seconde zéolite X, la seconde zéolite X étant obtenue par conversion d'un matériau liant en seconde zéolite X, le matériau liant représentant de 5 à 50% en poids de la composition de zéolites X; et (b) une teneur en matériau liant non converti, après conversion en seconde zéolite X, représentant de 0 à 3% en poids de la composition de zéolites X. La composition de zéolites X présente un rapport molaire de structure Si/Al allant de 1.0 à 1.5 et une intensité LTA relative égale ou inférieure à 1.0, tels que déterminés par diffraction des rayons X. La composition zéolitique convertie avec un liant est utile dans un processus consistant à séparer le paraxylène d'un mélange d'alkyles aromatiques C8.
PCT/US2012/032255 2011-04-13 2012-04-05 Compositions de zéolites de type x d'aminosilicates converties avec un liant WO2013106017A2 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
BR112013021043A BR112013021043A2 (pt) 2011-04-13 2012-04-05 composição zeolítica convertida em aglutinante, e. processo para a separação de para-xileno de uma mistura de alquil aromáticos
RU2013147991/05A RU2544673C1 (ru) 2011-04-13 2012-04-05 Включающие превращенное связующее алюмосиликатные цеолитные композиции типа х с низким содержанием цеолита типа lta
CN201280013151.XA CN103517876A (zh) 2011-04-13 2012-04-05 具有低lta型沸石的粘合剂转化铝硅酸盐x型沸石组合物
JP2014503971A JP2014522357A (ja) 2011-04-13 2012-04-05 少量のｌｔａ型ゼオライトを含む結合剤転化アルミノケイ酸塩ｘ型ゼオライト組成物
KR1020137022035A KR101504053B1 (ko) 2011-04-13 2012-04-05 적은 lta-유형 제올라이트를 갖는 결합제-전환 알루미노실리케이트 x-유형 제올라이트 조성물
SG2013057849A SG192213A1 (en) 2011-04-13 2012-04-05 Binder-converted aluminosilicate x-type zeolite compositions with low lta-type zeolite
EP12864937.3A EP2697166A4 (fr) 2011-04-13 2012-04-05 Compositions de zéolites de type x d'aminosilicates converties avec un liant

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US201161474923P 2011-04-13 2011-04-13
US201161474927P 2011-04-13 2011-04-13
US61/474,927 2011-04-13
US61/474,923 2011-04-13

Publications (2)

Publication Number Publication Date
WO2013106017A2 true WO2013106017A2 (fr) 2013-07-18
WO2013106017A3 WO2013106017A3 (fr) 2013-10-10

Family

ID=48139046

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/032255 WO2013106017A2 (fr) 2011-04-13 2012-04-05 Compositions de zéolites de type x d'aminosilicates converties avec un liant

Country Status (10)

Country Link
EP (1) EP2697166A4 (fr)
JP (1) JP2014522357A (fr)
KR (1) KR101504053B1 (fr)
CN (1) CN103517876A (fr)
BR (1) BR112013021043A2 (fr)
MY (1) MY168775A (fr)
RU (1) RU2544673C1 (fr)
SG (2) SG192213A1 (fr)
TW (1) TWI461239B (fr)
WO (1) WO2013106017A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018100318A1 (fr) 2016-12-02 2018-06-07 Arkema France Matériau adsorbant zéolithique, procédé de préparation et utilisation pour la séparation non-cryogénique des gaz industriels

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6743045B2 (ja) * 2015-04-09 2020-08-19 ビーエーエスエフ コーポレーション Ｚｓｍ−５触媒

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JPS5747713A (en) * 1980-09-05 1982-03-18 Kanto Kagaku Kk Manufacture of x-type zeolite
US4603040A (en) * 1985-03-27 1986-07-29 Air Products And Chemicals, Inc. Massive bodies of Maximum Aluminum X-type zeolite
JPS63260810A (ja) * 1988-03-18 1988-10-27 Kanebo Ltd 殺菌性ゼオライト組成物及びその製造法
AU7802198A (en) * 1997-05-29 1998-12-30 Exxon Chemical Patents Inc. Preparation of zeolite-bound fau structure type zeolite and use thereof
FR2767524B1 (fr) * 1997-08-21 1999-09-24 Ceca Sa Procede ameliore d'obtention de paraxylene a partir de coupes de c8 aromatiques
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US8283274B2 (en) * 2009-07-20 2012-10-09 Uop Llc Binderless zeolitic adsorbents, methods for producing binderless zeolitic adsorbents, and processes for adsorptive separation of para-xylene from mixed xylenes using the binderless zeolitic adsorbents

Non-Patent Citations (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018100318A1 (fr) 2016-12-02 2018-06-07 Arkema France Matériau adsorbant zéolithique, procédé de préparation et utilisation pour la séparation non-cryogénique des gaz industriels
US11007505B2 (en) 2016-12-02 2021-05-18 Arkema France Zeolite adsorbent material, method of preparation and use for non-cryogenic separation of industrial gases

Also Published As

Publication number Publication date
TWI461239B (zh) 2014-11-21
SG10201404109YA (en) 2014-09-26
CN103517876A (zh) 2014-01-15
RU2544673C1 (ru) 2015-03-20
WO2013106017A3 (fr) 2013-10-10
EP2697166A4 (fr) 2015-02-25
JP2014522357A (ja) 2014-09-04
KR101504053B1 (ko) 2015-03-18
BR112013021043A2 (pt) 2016-10-18
EP2697166A2 (fr) 2014-02-19
MY168775A (en) 2018-12-04
KR20130121162A (ko) 2013-11-05
TW201249532A (en) 2012-12-16
SG192213A1 (en) 2013-09-30

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