WO2013041372A1 - Verfahren zur herstellung von synthesegas durch vergasung einer biomasse in einer wirbelschicht - Google Patents

Verfahren zur herstellung von synthesegas durch vergasung einer biomasse in einer wirbelschicht Download PDF

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Publication number
WO2013041372A1
WO2013041372A1 PCT/EP2012/067277 EP2012067277W WO2013041372A1 WO 2013041372 A1 WO2013041372 A1 WO 2013041372A1 EP 2012067277 W EP2012067277 W EP 2012067277W WO 2013041372 A1 WO2013041372 A1 WO 2013041372A1
Authority
WO
WIPO (PCT)
Prior art keywords
bed gasifier
fluidized
fluidized bed
synthesis gas
biomass
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2012/067277
Other languages
German (de)
English (en)
French (fr)
Inventor
Max Heinritz-Adrian
Ralf Abraham
Domenico Pavone
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Industrial Solutions AG
Original Assignee
ThyssenKrupp Uhde GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to IN2331CHN2014 priority Critical patent/IN2014CN02331A/en
Priority to US14/345,583 priority patent/US20140374661A1/en
Priority to ES12756178T priority patent/ES2918574T3/es
Priority to DK12756178.5T priority patent/DK2758496T3/da
Priority to PL12756178T priority patent/PL2758496T3/pl
Priority to CA2849101A priority patent/CA2849101C/en
Priority to RU2014110634A priority patent/RU2639911C2/ru
Priority to MX2014003274A priority patent/MX2014003274A/es
Application filed by ThyssenKrupp Uhde GmbH filed Critical ThyssenKrupp Uhde GmbH
Priority to EP12756178.5A priority patent/EP2758496B1/de
Priority to BR112014006436A priority patent/BR112014006436A2/pt
Publication of WO2013041372A1 publication Critical patent/WO2013041372A1/de
Anticipated expiration legal-status Critical
Priority to ZA2014/02815A priority patent/ZA201402815B/en
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/50—Fuel charging devices
    • C10J3/503—Fuel charging devices for gasifiers with stationary fluidised bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/32—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with introduction into the fluidised bed of more than one kind of moving particles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/007—Removal of contaminants of metal compounds
    • C10K1/008—Alkali metal compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/20—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/304—Composition or microstructure of the elements
    • B01J2219/30416—Ceramic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/30—Details relating to random packing elements
    • B01J2219/308—Details relating to random packing elements filling or discharging the elements into or from packed columns
    • B01J2219/3086—Filling of the packing elements into the column or vessel, e.g. using a tube
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0272—Processes for making hydrogen or synthesis gas containing a decomposition step containing a non-catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/15—Details of feeding means
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0916—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Definitions

  • the invention relates to a process for the production of synthesis gas by gasification of a biomass in a fluidized bed, wherein the biomass is fed to a fluidized bed gasifier.
  • the invention relates to a system for carrying out the method.
  • a problem of the previously known technology for the gasification of biomass in a fluidized bed is the not small alkali content in the biomass. These alkalis vaporize at temperatures above 800 ° C during gasification and partially diffuse into the pores of the lining of the fluidized bed gasifier. The incorporation of the alkalis destroys the structure of the lining. This phenomenon is known as so-called alkali bursting. Another part of the resulting in the gasification of a biomass in a fluidized bed vapor
  • Alkali enters a colder system area downstream of the fluidized-bed gasifier, in which condensation and clogging as well as bonding and decomposition, for example, of the heat exchangers and hot gas filters can occur.
  • this object is achieved according to the invention in that the synthesis gas with gettering ceramics in contact is brought.
  • getter ceramics or alkali binders are substances that can incorporate alkalis in their structure by physical or chemical sorption. Getter ceramics are thus alkali binders.
  • getter ceramics are thus alkali binders.
  • Suitable getter ceramics or alkali binders are, for example, the following substances:
  • alkali binders or getter ceramics can be used individually or as a mixture.
  • a practicable variant of the invention provides that the getter ceramics are brought into contact with the biomass with a device upstream of the fluidized bed gasifier.
  • Upstream devices are, for example, a weighing container, an entry lock or a storage container.
  • the getter ceramics can also be passed directly into the fluidized bed gasifier where they are brought into contact with the synthesis gas.
  • An advantageous embodiment of the invention therefore provides that contained in the synthesis gas vaporous alkalis are brought into contact with water vapor.
  • a discontinuous addition of the getter ceramics is ensured within the scope of the invention.
  • the getter cermets which are located downstream of the hot gas filter in the fluidized-bed gasifier are returned to the fluidized-bed gasifier.
  • the getter ceramics are separated to saturation in the warm gas filter together with the dust and circulated, ie. led back into the carburetor. Investigations have shown that a considerable cost saving can be achieved by this type of discontinuous addition of the getter ceramics.
  • the invention also provides a system for carrying out the method, wherein the system storage possibilities for the getter ceramics, d .h. a getter ceramic silo.
  • the plant generally designated 1 for the gasification of a biomass 2 in a fluidized bed of a fluidized bed gasifier 3 is essentially formed by the contact elements described below:
  • a storage device 4 stores the biomass 2. About a lock, z. B. a rotary valve 5, the material to be processed is first fed to a weighing container 6, then an entry lock 7 and finally a storage container 8.
  • the material from the storage container 8 is again shown via a rotary valve 9 and at least one screw 10, in the illustrated embodiments, two screws 10 are shown, fed to the fluidized bed gasifier 3 and gasified there in the fluidized bed process.
  • the biomass 2 is reacted in the fluidized bed gasifier 3 to a synthesis gas loaded with alkalis.
  • the synthesis gas is freed from the alkalis by being brought into contact with gettering ceramics 11 in the fluidized-bed gasifier 3.
  • the getter ceramics 11 are first stored in a getter ceramic silo 12 and via a feed line in the form of controllable rotary valves 13 and via a further rotary valve 14 and screw 15a, d .h. in the entry system of the fluidized bed gasifier 3 and thus passed into the fluidized bed gasifier 3.
  • the synthesis gas liberated from alka Ii is fed to a recycle cyclone 14, whereby the circulation of the solid particles suitable for the fluidized bed back into the fluidized bed gasifier 3 is ensured. From the recycle cyclone 14, the synthesis gas is finally fed to the raw gas cooler 15 and via the warm gas filter 16 for further use.
  • a dust silo for partial removal of the dust is disposed behind the hot gas filter 16, which is provided with the reference numeral 17.
  • the hot gas filter 16 and the entry system performs a return line 18 through which the dust from the hot gas filter 16 can be fed back to the fluidized bed gasifier 3 by gravity, wherein the return line 18 may be in the form of a screw.
  • the getter ceramics 11 can be led to saturation in the hot gas filter 16 and separated there with the methods of dust separation together with the dust and can be fed back via the return line 18 in the fluidized bed gasifier 3.
  • a measuring probe 19 is connected, with the aid of which the alkali content of the synthesis gas and thus the quality of the synthesis gas can be detected.
  • reference numeral 20 denotes the bottom discharge from the fluidized-bed gasifier 3, the products accumulating there being supplied in turn via a worm 21 corresponding to receptacles 22.
  • the described embodiment of the invention is still to be modified in many ways, without departing from the spirit of the invention, in particular as regards the return of the dust or Getterkeramiken from the hot gas filter 16.
  • the hot gas filter 16 for example, candle filters can be used to separate the dust or Getterkeramiken 11.
  • the getter ceramics 11 may be supplied to the torrefaction apparatus or the pellet press.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Processing Of Solid Wastes (AREA)
  • Industrial Gases (AREA)
PCT/EP2012/067277 2011-09-19 2012-09-05 Verfahren zur herstellung von synthesegas durch vergasung einer biomasse in einer wirbelschicht Ceased WO2013041372A1 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
RU2014110634A RU2639911C2 (ru) 2011-09-19 2012-09-05 Способ и установка для производства синтез-газа посредством газификации биомассы в псевдоожиженном слое
ES12756178T ES2918574T3 (es) 2011-09-19 2012-09-05 Método para producir gas de síntesis mediante la gasificación de biomasa en un lecho fluidizado
DK12756178.5T DK2758496T3 (da) 2011-09-19 2012-09-05 Fremgangsmåde til fremstilling af syntesegas ved forgasning af en biomasse i en fluid bed
PL12756178T PL2758496T3 (pl) 2011-09-19 2012-09-05 Sposób wytwarzania gazu syntezowego przez zgazowanie biomasy w złożu fluidalnym
CA2849101A CA2849101C (en) 2011-09-19 2012-09-05 Method for producing synthesis gas by gasifying a biomass in a fluidized bed
IN2331CHN2014 IN2014CN02331A (enExample) 2011-09-19 2012-09-05
BR112014006436A BR112014006436A2 (pt) 2011-09-19 2012-09-05 processo para a produção de gás de síntese por gaseificação de uma biomassa em um leito fluidizado e aparelho para a realização do mesmo
MX2014003274A MX2014003274A (es) 2011-09-19 2012-09-05 Metodo para producir gas de sintesis al gasificar una biomasa en una cama fluidizada.
EP12756178.5A EP2758496B1 (de) 2011-09-19 2012-09-05 Verfahren zur herstellung von synthesegas durch vergasung einer biomasse in einer wirbelschicht
US14/345,583 US20140374661A1 (en) 2011-09-19 2012-09-05 Method for producing synthesis gas by gasifying a biomass in a fluidized bed
ZA2014/02815A ZA201402815B (en) 2011-09-19 2014-04-16 Method for producing synthesis gas by gasifying a biomass in a fluidized bed

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011114171.9 2011-09-19
DE102011114171A DE102011114171A1 (de) 2011-09-19 2011-09-19 Verfahren zur Herstellung von Synthesegas durch Vergasung einer Biomasse in einer Wirbelschicht

Publications (1)

Publication Number Publication Date
WO2013041372A1 true WO2013041372A1 (de) 2013-03-28

Family

ID=46801496

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2012/067277 Ceased WO2013041372A1 (de) 2011-09-19 2012-09-05 Verfahren zur herstellung von synthesegas durch vergasung einer biomasse in einer wirbelschicht

Country Status (16)

Country Link
US (1) US20140374661A1 (enExample)
EP (1) EP2758496B1 (enExample)
BR (1) BR112014006436A2 (enExample)
CA (1) CA2849101C (enExample)
CL (1) CL2014000674A1 (enExample)
DE (1) DE102011114171A1 (enExample)
DK (1) DK2758496T3 (enExample)
ES (1) ES2918574T3 (enExample)
IN (1) IN2014CN02331A (enExample)
MX (1) MX2014003274A (enExample)
PL (1) PL2758496T3 (enExample)
PT (1) PT2758496T (enExample)
RU (1) RU2639911C2 (enExample)
TW (1) TW201319243A (enExample)
WO (1) WO2013041372A1 (enExample)
ZA (1) ZA201402815B (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3074501A1 (de) * 2013-11-28 2016-10-05 Peter Gallersdörfer Energiegewinnungssystem zur gewinnung erneuerbarer energie sowie biomassesammelsystem und komponenten dieser systeme
DE102017219786A1 (de) * 2017-11-07 2019-05-09 Thyssenkrupp Ag Verfahrenstechnische Anordnung und Verfahren zum Bereitstellen von Alkali-reduziertem Synthesegas sowie Steuerungseinrichtung und Verwendung
RU2723865C1 (ru) * 2019-08-12 2020-06-17 Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный технологический университет" (ФГБОУ ВО "КубГТУ") Способ получения синтез-газа из биомассы растительного происхождения

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US4280893A (en) * 1977-12-06 1981-07-28 Leas Arnold M Integrated coal conversion process
US5173263A (en) * 1991-01-22 1992-12-22 The United States Of America As Represented By The United States Department Of Energy Regenerable activated bauxite adsorbent alkali monitor probe
WO2000043468A1 (en) * 1999-01-25 2000-07-27 Valtion Teknillinen Tutkimuskeskus Process for the gasification of carbonaceous fuel in a fluidized bed gasifier
WO2003029389A1 (en) * 2001-10-02 2003-04-10 Valtion Teknillinen Tutkimuskeskus Method and apparatus for the gasification of fuel on a fluidised bed reactor
DE102006005626B4 (de) 2006-02-06 2008-02-28 Rwe Power Ag Verfahren und Vergasungsreaktor zur Vergasung verschiedenster Brennstoffe mit breitem Körnungsband mit Flüssigschlackeabzug
US20100040527A1 (en) * 2008-08-18 2010-02-18 Randhava Sarabjit S Process for producing ammonia from biomass
DE102010006192A1 (de) 2010-01-29 2011-08-04 Uhde GmbH, 44141 Verfahren zur Biomasse-Vergasung in einer Wirbelschicht

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DE10162398A1 (de) * 2001-12-13 2003-07-24 Moeller Materials Handling Gmb Anlage zum Beschicken einer Mehrzahl von Verbrauchern, z. B. von Zellen von Aluminiumschmelzöfen mit Schüttgut, z. B. pulverförmigem Aluminiumoxid
RU2336296C2 (ru) * 2003-09-16 2008-10-20 Анкер Ярл ЯКОБСЕН Способ и устройство для получения синтез-газа из биомассы
DE102008013179A1 (de) * 2007-12-22 2009-06-25 Uhde Gmbh Entfernung von Flüssigasche und Alkalien aus einem Synthesegas
RU76424U1 (ru) * 2008-04-02 2008-09-20 Институт катализа им. Г.К. Борескова Сибирского отделения Российской Акдемии наук Установка для утилизации биомассы
DE102008026267A1 (de) * 2008-06-02 2009-12-03 Uhde Gmbh Modifizierter Gas- und Dampfturbinenprozess mit integrierter Kohledruckvergasung

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4280893A (en) * 1977-12-06 1981-07-28 Leas Arnold M Integrated coal conversion process
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WO2000043468A1 (en) * 1999-01-25 2000-07-27 Valtion Teknillinen Tutkimuskeskus Process for the gasification of carbonaceous fuel in a fluidized bed gasifier
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ES2918574T3 (es) 2022-07-19
CA2849101A1 (en) 2013-03-28
PT2758496T (pt) 2022-06-24
US20140374661A1 (en) 2014-12-25
EP2758496A1 (de) 2014-07-30
IN2014CN02331A (enExample) 2015-06-19
PL2758496T3 (pl) 2022-07-11
RU2639911C2 (ru) 2017-12-25
TW201319243A (zh) 2013-05-16
EP2758496B1 (de) 2022-05-11
DK2758496T3 (da) 2022-06-27
MX2014003274A (es) 2015-03-03
BR112014006436A2 (pt) 2017-04-04
RU2014110634A (ru) 2015-10-27
ZA201402815B (en) 2022-08-31
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