WO2013039360A2 - Solution aqueuse de calcium ionisé et son procédé de production - Google Patents

Solution aqueuse de calcium ionisé et son procédé de production Download PDF

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Publication number
WO2013039360A2
WO2013039360A2 PCT/KR2012/007406 KR2012007406W WO2013039360A2 WO 2013039360 A2 WO2013039360 A2 WO 2013039360A2 KR 2012007406 W KR2012007406 W KR 2012007406W WO 2013039360 A2 WO2013039360 A2 WO 2013039360A2
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WO
WIPO (PCT)
Prior art keywords
calcium
solution
calcium oxide
aqueous solution
container
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PCT/KR2012/007406
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English (en)
Korean (ko)
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WO2013039360A3 (fr
Inventor
김미영
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주식회사 시로미
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Publication of WO2013039360A2 publication Critical patent/WO2013039360A2/fr
Publication of WO2013039360A3 publication Critical patent/WO2013039360A3/fr

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    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K50/00—Feeding-stuffs specially adapted for particular animals
    • A23K50/80—Feeding-stuffs specially adapted for particular animals for aquatic animals, e.g. fish, crustaceans or molluscs
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/20—Inorganic substances, e.g. oligoelements
    • A23K20/24—Compounds of alkaline earth metals, e.g. magnesium
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K50/00—Feeding-stuffs specially adapted for particular animals
    • A23K50/10—Feeding-stuffs specially adapted for particular animals for ruminants

Definitions

  • the present invention relates to an aqueous calcium ion solution and a method for manufacturing the same, and more particularly, to an aqueous calcium ion solution and a method for producing the same, which maximize the absorption of calcium into the body of animals and promote metabolism and biological function of the animals. It is about.
  • Calcium ions (Ca 2+) derived from calcium carbonate contained in limestone, etc., require a long time to naturally exist in the groundwater, and limestone itself is hard rock and does not easily dissolve in water.
  • An object of the present invention is to provide a method for preparing an aqueous calcium ion solution to stabilize the content and specification of calcium ion and to thereby maintain an appropriate level of trace elements, and to maintain an appropriate pH.
  • Another object of the present invention is to increase the shelf life by inhibiting the alteration and bacterial generation of livestock feed, thereby minimizing the loss of nutrients, ionization that can be used as a livestock feed that can increase the body absorption rate of calcium It is to provide an aqueous solution of calcium.
  • the present invention provides the following specific problem solving means.
  • Method for producing an aqueous calcium ion solution washing step of removing foreign matter and impurities through the washing of shells;
  • a high temperature firing step of heating and calcining the dried shellfish to produce calcium oxide by removing organic substances and residual toxicity contained in the dried shellfish;
  • Grinding the calcium oxide to produce a calcium oxide powder A stirring step of preparing a calcium oxide solution by mixing and stirring the calcium oxide powder and water; Supplying saturated steam to the container containing the calcium oxide solution, inducing an ionic reaction by generating static electricity in the container to produce an ionized calcium solution;
  • a hydrogen ion concentration adjusting step of adding the soft water treated water or pure water to the ionized calcium aqueous solution to maintain the hydrogen ion concentration at pH 12-13.
  • the high temperature firing step it is preferable to heat and fire shellfish dried for 1 to 3 hours at a temperature of 1100 ⁇ 2000 °C. This is the temperature and time necessary to allow the dried shellfish to be completely fired, and thus the temperature and time can be adjusted according to the application.
  • the firing temperature is gradually increased gradually over 2 to 3 hours from the initial temperature of 1100 ° C to the final temperature of 1600 ° C. This is because when the calcium ionized aqueous solution is used as an additive for livestock animals for constant temperature animals, the effect can be seen even if the particles are somewhat large or the ionization degree is lower, and the sensitivity to the components is less than that of the fish.
  • the particle size of the calcium oxide powder pulverized in the crushing step is preferably 20 ⁇ m or less, the particle size can be adjusted depending on whether the aqueous solution of calcium ionization is used.
  • the particle size of the calcium oxide powder when added to aquaculture feed, it is desirable to limit the particle size of the calcium oxide powder to 10 ⁇ m or less in consideration of the sensitivity of the fish, which is a transgenic animal, but for feed additives of livestock such as mammals or birds, which are relatively less sensitive. This is because even if the particle size of the calcium oxide powder is set to 20 ⁇ m, it is not too much.
  • the stirring step it is preferable to mix and stir the calcium oxide powder at a ratio of 0.1 to 2 parts by weight with respect to 100 parts by weight of water, because the calcium oxide powder is best ionized in water when mixing and stirring at this weight ratio.
  • the stirring time in the stirring step is preferably stirred for 2 to 5 hours after mixing, when used as an additive for livestock feed for constant temperature animals such as mammals and birds, it is preferable to stir for 2 to 4 hours, and relatively When the particle size is small, it is preferable to stir for 3 to 5 hours because the degree of ionization should be increased by dispersing it evenly in water.
  • the pressure of the saturated steam supplied in the ion reaction step is preferably 1.4 ⁇ 5MPa.
  • the method for producing an aqueous calcium ion solution according to the present invention, the ion reaction step of each step constituting the calcium oxide solution injection step of injecting the calcium oxide solution into the container;
  • the aqueous solution of calcium ion which is another aspect of the present invention is characterized in that it is produced by the above production method.
  • the method for preparing an aqueous calcium ion solution reaches a high concentration such that the content of pure calcium reaches 94 to 97%, and provides a high purity stable alkaline ionized calcium aqueous solution having a hydrogen ion concentration of pH 12 to 13, thereby adding food additives and calcium.
  • the absorption rate in the body is high when used, thereby maximizing the effect of calcium.
  • the ionized calcium aqueous solution according to the present invention increases the shelf life by inhibiting the alteration and bacterial generation of animal feed when used in animal feed, minimizes the loss of nutrients, and increases the body absorption rate of calcium by absorbing calcium It is effective in reducing intestinal gas generated by deficiency, ascites caused by calcium metabolic disorder, lowering immunity due to calcium deficiency, and lowering skin mucus.
  • FIG. 1 is a process chart showing a manufacturing process of an aqueous calcium ion solution according to an embodiment of the present invention.
  • Figure 2 shows a graph showing the results for the growth experiments of the flounder fed with the feed added as an additive to the halibut calcium aqueous solution prepared in accordance with an embodiment of the flounder and the flounder fed with the general feed.
  • Figure 3 is the blood of the halibut fed the feed with the addition of the aqueous solution of ionized calcium prepared according to an embodiment of the present invention as a feed additive and the blood of the halibut fed the normal feed to measure the aspartic acid amino-transferase (AST)
  • AST aspartic acid amino-transferase
  • Figure 4 is a graph showing the results of measuring the glucose (Glucose) by collecting the blood of the olive flounder fed the feed and the general feed fed with the calcium ionized aqueous solution prepared according to an embodiment of the present invention as a feed additive .
  • Figure 5 shows the results of measuring the lysozyme activity by collecting the slime and the slime of the halibut fed the feed with the feed added to the ionized calcium aqueous solution prepared according to an embodiment of the present invention as a feed additive It is a graph.
  • FIG. 1 is a process chart showing a manufacturing process of an aqueous calcium ion solution according to an embodiment of the present invention.
  • Shell refers to the inorganic secretion formation to protect the molluscs in mollusks, where shells may be used such as oyster shells, shell shells.
  • the dried shellfish is heated and calcined in the high temperature baking step to remove organic matter and residual toxicity contained in the dried shellfish, thereby preparing calcium oxide.
  • calcium oxide may be prepared by heating and firing the dried shellfish at 1100 ° C. to 2000 ° C. for 1 to 3 hours.
  • calcium oxide may be prepared by heating and firing the dried shellfish at an initial temperature of 1100 ° C. and gradually raising the temperature to a final temperature of 2000 ° C.
  • CaCO 3 calcium carbonate (CaCO 3 ), which is a constituent of shellfish, is calcined and converted to calcium oxide (CaO) in solid state.
  • Calcium oxide powder is prepared by grinding the calcium oxide prepared in the high temperature firing step. At this time, it is preferable to grind using a wet ball mill.
  • the particle diameter of the pulverized calcium oxide powder may be 20 ⁇ m or less. If the particle size of the calcium oxide powder exceeds 20 ⁇ m is because there is a problem that is not well mixed when preparing a calcium oxide solution by mixing with water. On the other hand, in order to obtain an ionized calcium solution used as a fish feed additive, it is preferable to grind to have a particle diameter of 10 ⁇ m or less, because the calcium oxide powder of 10 ⁇ m or less size is better mixed with water.
  • the calcium oxide powder and water are mixed and stirred to prepare a calcium oxide solution.
  • the calcium oxide solution prepared here is strongly alkaline.
  • the mixed weight ratio of water and calcium oxide powder is preferably 0.1 to 2 parts by weight of calcium oxide powder based on 100 parts by weight of water. Because if the weight ratio of calcium oxide powder to 100 parts by weight of water exceeds 2 parts by weight may not be sufficiently mixed in water, if less than 0.1 parts by weight prepared aqueous solution of calcium ion may not supply enough calcium in the body Because. Therefore, when the weight ratio is maintained, the calcium oxide powder is well mixed with water, and when used as a feed additive as an aqueous solution of calcium ion, it exhibits the effect of supplying sufficient calcium in the body.
  • the calcium oxide solution may be prepared by mixing the calcium oxide powder and water, followed by stirring for 2 to 5 hours. At this time, the calcium oxide powder is evenly mixed with water by stirring for 2 to 5 hours.
  • the calcium oxide solution when preparing an aqueous calcium ion solution used as additives for fish feed it is good to stir for about 3 to 5 hours to finely disperse the fine calcium oxide powder mixed in water well.
  • Saturated steam is supplied to a vessel containing the calcium oxide solution prepared in the stirring step (S400) to generate an electrostatic reaction in the vessel to prepare an ionized calcium aqueous solution.
  • saturated steam generated in a boiler generates some condensation due to the temperature drop in the vessel, which results in the formation of droplets.
  • the generated droplets collide or rub against each other, thereby generating static electricity.
  • the supplied air is expelled by the supplied saturated steam, and saturated steam also penetrates into the calcium oxide solution.
  • the static electricity accumulated in the droplets reaches the container either directly or through calcium oxide solution.
  • the portion where the static electricity flows in the calcium oxide solution is locally heated to rise in temperature and ion structure, but the current is not continuously flowing and the amount of power is small, so the temperature rise is small.
  • the average temperature in the container does not rise above the temperature of the saturated steam supplied, harmful components hardly occur.
  • the vessel and the stirring means are made of a chargeable material, ionization may be promoted according to the following mechanism.
  • the vessel and the stirring means When the vessel and the stirring means are charged and provided in an insulated state with respect to the base, the calcium oxide solution, the vessel and the stirring means have positive or negative charges (electrostatic) due to friction with the calcium oxide solution. Accumulates.
  • the saturated steam heated and pressurized is supplied in the container, and since this saturated vapor penetrates into the inside of the calcium oxide solution, the electrical resistance inside the calcium oxide solution decreases, so that electricity easily flows.
  • the charging property means that the electrical resistance is large and that the added calcium oxide solution can be positively or negatively charged.
  • the charging may be performed either positively or negatively.
  • the charge flows through the inside of the calcium oxide solution and into the vessel and the stirring means. Since the calcium oxide solution is agitated, the amount of charge collection varies with each part, and the path and time through which the charge flows also differ. In addition, since saturated steam is filled in the container, the electrical resistance is not too high or the static electricity is not collected too much. Therefore, the static electricity is discharged little by little, and instantaneously generates heat in the discharge path during discharge, while the calcium oxide solution is converted into a stable aqueous solution of calcium ionization. However, since discharge is not carried out continuously, it does not become a high temperature, the entire temperature in the container does not increase significantly at the set temperature by heating steam, and water suppresses the generation of harmful components.
  • the pressure of the saturated steam supplied to the container including the calcium oxide aqueous solution may be 1.4 to 5 MPa.
  • the ion reaction step (S500) is a calcium oxide solution injection step (S510) specifically injecting the calcium oxide solution into the container;
  • Hydrogen ion concentration is maintained at pH 12-13 by adding soft water or pure water to the calcium ionized solution.
  • soft water treated water refers to water whose hardness is adjusted to less than 0 to 60 mg / L
  • pure water treated water refers to water from which impurities including hardness components are removed.
  • the aqueous solution of calcium ion prepared according to the embodiment of the present invention can be used as additives of fish feed, additives of livestock feed, calcium ionized drinks and calcium fortification of plants, but is not limited thereto.
  • the dried shellfish was gradually heated up to 1300 to 2000 ° C. so that the total heating and calcining time was 2 to 3 hours.
  • the calcium oxide produced in the high temperature firing step was pulverized with a wet ball mill to have a particle size of 8 ⁇ m, and then mixed with water and stirred. At this time, the water and calcium oxide powder was mixed in a ratio of 1 weight ratio of calcium oxide powder to 100 parts by weight of water and then stirred for 5 hours to prepare a calcium oxide solution.
  • Saturated steam with a pressure of 4 MPa was supplied to the vessel containing the prepared calcium oxide solution to induce an ionic reaction to prepare a calcium ionized aqueous solution.
  • the prepared was added to the feed for the flounder and then fed to the flounder. In case of fry, 10 times diluted with water is used, but it is preferable to use it without diluting as it becomes adult.
  • the calcium ionized aqueous solution was used as an additive to the olive flounder for the entire period, it was used by adding 1 g of calcium ionized aqueous solution to 1 kg of olive flounder.
  • Table 1 below shows the hydrogen ion concentration according to the content ratio of the calcium oxide powder of the aqueous solution of calcium ionized according to Example 1 of the present invention.
  • the pH value gradually increases from 12.340 to 12.412.
  • the calcium oxide powder becomes more alkaline as it is dissolved in water.
  • Table 2 shows the results of disinfection, pH change and dissolution rate of the calcium ionized aqueous solution prepared according to Example 1 of the present invention.
  • Figure 2 is a graph showing the results for the growth experiments of the flounder (experimental group) and the flounder (control group) fed the feed supplemented with the additives to the flounder feed prepared by the aqueous solution of ionized calcium prepared according to Example 1 of the present invention It is shown.
  • the experimental group had an average body weight of 154 g and a control group of 144 g on May 14, the early stage of the experiment.
  • the final mean weight of the experimental group on July 13 was 283g and the control group was 254g.
  • Table 3 below shows the mean weight, survival rate and weight gain rate of the experimental and control groups.
  • the survival rate of the experimental group was 87.3%, higher than the 86.6% of the control group, the weight gain rate was 83.8% in the experimental group, 76.4% in the control group and the ion calcium aqueous solution prepared according to the embodiment of the present invention was used as a feed additive. It can be seen that the efficacy of.
  • FIG. 3 shows the blood of the flounder (experimental group) fed with the feed added with the aqueous calcium ionized solution prepared according to Example 1 as a feed additive and the blood of the flounder (control group) fed with the general feed, and aspartate amino group transfer.
  • the graph shows the result of measuring enzyme (AST).
  • the AST value was about 9U / L, whereas in the control group, the amount of aspartic acid aminotransferase was high in the experimental group.
  • the amount of glucose was high in the experimental group.
  • Figure 5 is a lysozyme (Lysozyme) by collecting the slime of the flounder (experimental group) and the halibut (control group) fed the feed with the feed added the calcium ionized aqueous solution prepared according to Example 1 of the present invention as a feed additive
  • This graph shows the result of measuring activity.
  • the experimental group was about 0.009 unit / mL, whereas the control group was measured at about 0.008 unit / mL, so the lysozyme activity was high in the experimental group.
  • the aqueous calcium ion solution prepared according to Example 1 of the present invention is easily absorbed into the cell body without the aid of an absorption promoter such as vitamin D3, thereby maximizing the efficacy of the calcium ion when absorbed into the cell body.
  • the present invention reaches a high concentration of pure calcium content of 94-97%, and provides a high purity stable alkaline ionized calcium aqueous solution in which hydrogen ion concentration is pH 12-13, food additives, calcium ion drink, animal feed, aquaculture It can be applied to fish feed, agricultural calcium ion, etc.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
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  • Animal Husbandry (AREA)
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  • Marine Sciences & Fisheries (AREA)
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Abstract

Cette invention concerne une solution aqueuse de calcium ionisé et son procédé de production. Plus spécifiquement, cette invention concerne : une solution aqueuse de calcium ionisé qui a pour effets de maximiser l'absorption du calcium dans le corps du bétail et de favoriser le métabolisme et les fonctions vitales chez le bétail ; et son procédé de production. Le procédé de production de la solution aqueuse de calcium ionisé constituant la présente invention donne une solution aqueuse de calcium ionisé alcaline, stable et de pureté élevée qui offre une concentration élevée avec une teneur en calcium pur entre 94 et 97 % et une concentration d'ions hydrogène allant de pH 12 à 13, ayant par conséquent pour effet d'augmenter l'absorption et ce faisant, de maximiser l'efficacité du calcium quand elle est utilisée dans des additifs alimentaires, des boissons à l'ion calcium, la nourriture animale, la nourriture des poissons d'élevage, le calcium ionisé à visée agricole et autres. De plus, quand la solution aqueuse de calcium ionisé constituant une autre facette de la présente invention est donnée au bétail sous forme d'additif alimentaire, elle a pour effet d'augmenter la période de stockage par suppression de la croissance dénaturante et microbienne dans la nourriture destinée au bétail, de réduire au minimum la perte de nutriments résultante, et d'augmenter l'absorption du calcium par le corps.
PCT/KR2012/007406 2011-09-16 2012-09-17 Solution aqueuse de calcium ionisé et son procédé de production WO2013039360A2 (fr)

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KR10-2011-0093496 2011-09-16
KR1020110093496A KR101347276B1 (ko) 2011-09-16 2011-09-16 이온화칼슘 수용액의 제조 방법 및 그 제조 방법에 의해 제조된 어류사료첨가제용 이온화칼슘 수용액

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110574888A (zh) * 2018-06-09 2019-12-17 时海棋 一种调节酸碱平衡的多种微量元素离子化产品的加工方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102036125B1 (ko) * 2019-05-29 2019-10-24 송성은 저분자 저밀도 이온화 미네랄 복합체 및 이의 제조방법
KR102177415B1 (ko) * 2020-05-11 2020-11-12 (주)듀라핌 패각 소성분말을 이용한 천연 항균용액 제조방법, 이에 의해 제조된 마스크 살균용 천연 항균용액

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KR950000567A (ko) * 1993-06-08 1995-01-03 양인석 이온칼슘(CaO)수액 제조방법
KR960000499B1 (ko) * 1993-01-07 1996-01-08 김상범 패각류를 직접소성하여 이온화칼슘을 제조하는 방법
KR100455245B1 (ko) * 2001-07-26 2004-11-12 양인석 이온 칼슘의 제조방법
KR20050013912A (ko) * 2004-02-04 2005-02-05 최희욱 섭취가 가능한 고농축 칼슘수용액 제조방법 및 이를이용한 칼슘이온음료
KR20060083282A (ko) * 2005-01-14 2006-07-20 최희욱 섭취가 가능한 고농축 칼슘수용액 제조방법 및 이를이용한 칼슘이온음료
KR20080015167A (ko) * 2006-08-14 2008-02-19 김문재 고 순도 산화칼슘의 제조 방법

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Publication number Priority date Publication date Assignee Title
KR960000499B1 (ko) * 1993-01-07 1996-01-08 김상범 패각류를 직접소성하여 이온화칼슘을 제조하는 방법
KR950000567A (ko) * 1993-06-08 1995-01-03 양인석 이온칼슘(CaO)수액 제조방법
KR100455245B1 (ko) * 2001-07-26 2004-11-12 양인석 이온 칼슘의 제조방법
KR20050013912A (ko) * 2004-02-04 2005-02-05 최희욱 섭취가 가능한 고농축 칼슘수용액 제조방법 및 이를이용한 칼슘이온음료
KR20060083282A (ko) * 2005-01-14 2006-07-20 최희욱 섭취가 가능한 고농축 칼슘수용액 제조방법 및 이를이용한 칼슘이온음료
KR20080015167A (ko) * 2006-08-14 2008-02-19 김문재 고 순도 산화칼슘의 제조 방법

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110574888A (zh) * 2018-06-09 2019-12-17 时海棋 一种调节酸碱平衡的多种微量元素离子化产品的加工方法

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