WO2013038539A1 - Électrode pour dispositifs de conversion photoélectrique, et dispositif de conversion photoélectrique utilisant ladite électrode - Google Patents
Électrode pour dispositifs de conversion photoélectrique, et dispositif de conversion photoélectrique utilisant ladite électrode Download PDFInfo
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- WO2013038539A1 WO2013038539A1 PCT/JP2011/071053 JP2011071053W WO2013038539A1 WO 2013038539 A1 WO2013038539 A1 WO 2013038539A1 JP 2011071053 W JP2011071053 W JP 2011071053W WO 2013038539 A1 WO2013038539 A1 WO 2013038539A1
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- photoelectric conversion
- electrode
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- electrode part
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- 239000000463 material Substances 0.000 claims description 18
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Images
Classifications
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/20—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation comprising organic-organic junctions, e.g. donor-acceptor junctions
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/80—Constructional details
- H10K30/81—Electrodes
- H10K30/82—Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
- H10K30/83—Transparent electrodes, e.g. indium tin oxide [ITO] electrodes comprising arrangements for extracting the current from the cell, e.g. metal finger grid systems to reduce the serial resistance of transparent electrodes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/50—Photovoltaic [PV] devices
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to an electrode for a photoelectric conversion device used for a photoelectric conversion device and a photoelectric conversion device using the same.
- a photoelectric conversion device is a device that converts light into electrical energy and a device that converts electrical energy into light.
- Examples of the former include solar cells, and examples of the latter include light emitting diodes.
- the Si solar cell will be described by taking a single crystal Si solar cell as an example.
- a p-type single crystal wafer is converted into a pn junction by changing the surface layer of the wafer to an n-type semiconductor by vapor phase diffusion or implantation of n-type impurity ions.
- a pin junction is created.
- a solar cell having a sandwich structure is manufactured by forming a front electrode and a back electrode.
- a chalcopyrite solar cell will be described as an example. This is a solar cell provided with a CIGS layer made of a chalcopyrite compound (Cu (In + Ga) Se 2 ) containing elements of Group I, Group III and Group VI as constituent components as a p-type light absorption layer (for example, Patent Documents). 1).
- a CIGS layer made of a chalcopyrite compound (Cu (In + Ga) Se 2 ) containing elements of Group I, Group III and Group VI as constituent components as a p-type light absorption layer (for example, Patent Documents). 1).
- This solar cell with a CIGS layer generally prevents a back electrode layer, which is a positive electrode made of a Mo metal layer, on a glass substrate such as a soda lime glass (SLG) substrate, and Na unevenness caused by the SLG substrate.
- a back electrode layer which is a positive electrode made of a Mo metal layer
- SLG soda lime glass
- a back electrode layer which is a positive electrode made of a Mo metal layer
- a glass substrate such as a soda lime glass (SLG) substrate
- SLG soda lime glass
- the CIGS light absorbing layer is obtained by the following process. That is, the substrate itself provided with the In layer and the Cu—Ga layer as a precursor is accommodated in the annealing chamber and preheated. Thereafter, the precursor is converted into a CIGS layer by raising the temperature of the chamber to a temperature range of 500 to 520 ° C. while introducing H 2 Se gas through a gas introducing tube inserted into the annealing chamber.
- organic semiconductor thin film solar cells are attracting attention as solar cells suitable for mass production because they can be formed by a coating method.
- the organic solar cell has a so-called bulk heterojunction structure in which an organic donor material and an organic acceptor material are mixed.
- an organic thin-film solar cell capable of forming a cathode on a flexible substrate by coating and a low-temperature process has been developed (for example, Patent Document 2).
- an organic semiconductor thin film solar cell has a structure in which an anode, a photoelectric conversion layer having a bulk heterojunction structure, and a cathode are sequentially laminated on one surface of a substrate, and a silver oxide and a reducing agent
- a laminated structure in which an electron transport layer doped with an organic metal is applied in the vicinity of the cathode not only the cathode is formed at a low temperature, but also the bonding between the organic metal doped layer and the cathode is improved. It is said.
- the conventional structure it was necessary to provide a pair of electrodes across a region that becomes a pn junction. For this reason, the light irradiation side electrode is required to have good light transmittance and low electrical resistance. For this reason, the light irradiation side electrode needs to be formed by vapor deposition or plating of an expensive rare metal. In addition, the process steps are complicated accordingly. Further, the conventional solar cell has no flexibility, and when it is attached to the surface of a curved member, it must be divided and attached.
- an object of the present invention is to provide an electrode structure for a photoelectric conversion device that does not require light transmittance as an electrode material and a photoelectric conversion device using the same.
- the electrode for a photoelectric conversion device of the present invention is an electrode provided on both sides of a photoelectric conversion layer for converting light and electric energy, and is provided on the lower surface side of the photoelectric conversion layer.
- a side electrode portion and an upper electrode portion provided on the upper surface side of the photoelectric conversion layer, the lower electrode portion and the upper electrode portion include a plurality of warp yarns and a plurality of weft yarns,
- the warp is composed of a plurality of metal wires provided at a distance from each other
- the weft is composed of a plurality of insulating wires provided at a distance from each other
- one of the lower electrode portion and the upper electrode portion is p It functions as a mold electrode
- the other of the lower electrode part and the upper electrode part functions as an n-type electrode.
- At least one insulating wire may be provided between the metal wires constituting the upper electrode portion and the lower electrode portion.
- a p-layer organic semiconductor made of a hole transport material is provided on the P-type electrode with respect to the optoelectronic device electrode, and the n An n-layer organic semiconductor made of an electron transport material is provided on the mold electrode.
- the electrode provided on the surface of the photoelectric conversion layer on which light is incident is configured to have a plurality of gaps for passing light, it is not necessary to configure the electrode with a transparent electrode. Therefore, it is not necessary to use rare metals as materials. Therefore, an inexpensive electrode material such as Cu or Al can be used for the electrode for the photoelectric conversion device. Further, since the photoelectric conversion device is formed of a flexible net, the photoelectric conversion device can be attached to a curved surface after being formed in a flat shape. Furthermore, since light can be taken in from both surfaces of the photoelectric conversion layer, improvement in conversion efficiency can be expected.
- the photoelectric conversion device will be described assuming that a solar cell converts light into electric energy.
- the present invention can also be applied to a device that converts electric energy into light energy.
- FIG. 1 is a cross-sectional view of a photoelectric conversion device 1 according to an embodiment of the present invention
- FIG. 2 is a perspective view of the photoelectric conversion device 1.
- the photoelectric conversion device 1 includes an electrode 12 and a photoelectric conversion layer 13. In FIG. 2, the display of the photoelectric conversion layer 13 is omitted.
- the electrode 12 includes a lower electrode part 120 and an upper electrode part 220 provided to face the lower electrode part 120 at a predetermined distance.
- the lower electrode section 120 includes a plurality of warp threads 120A and a plurality of weft threads 120B.
- the warp yarn 120A and the weft yarn 120B are woven so as to intersect one by one. That is, the lower electrode portion 120 is formed in a plain weave net shape.
- first metal wire 121 and the first insulating wire 122 are used. As shown in FIG. 2, the first metal wire 121 and the first insulating wire 122 are alternately arranged. In addition, the 1st metal wire 121 and the 1st insulated wire 122 are arranged in parallel at predetermined intervals so that it may not contact.
- first metal wire 121 for example, a copper wire, a stainless wire, a wire obtained by performing metal plating on the surface of a chemical fiber, or the like can be used.
- One end 121E of each first metal wire 121 is connected to the first bus bar 121A as shown in FIG.
- the first insulating wire 122 is made of a flexible insulating resin such as a nylon resin, a silicone resin, a urethane resin, an epoxy resin, a polycarbonate resin, or a vinyl resin.
- a flexible insulating resin such as a nylon resin, a silicone resin, a urethane resin, an epoxy resin, a polycarbonate resin, or a vinyl resin.
- the second insulating wire is used as the weft 12B. Similar to the first insulating wire 122, the second insulating wire is made of a flexible insulating resin such as nylon resin, silicone resin, urethane resin, epoxy resin, polycarbonate resin, or vinyl resin.
- a flexible insulating resin such as nylon resin, silicone resin, urethane resin, epoxy resin, polycarbonate resin, or vinyl resin.
- the upper electrode portion 220 includes a plurality of warp yarns 220A and a plurality of weft yarns 220B.
- the warp yarn 220A and the weft yarn 220B are woven so as to intersect one by one. That is, the upper electrode portion 220 is formed in a plain weave net shape.
- Two types of wires are used as the warp yarn 220A. Specifically, the second metal wire 221 and the third insulating wire 222 are used. As shown in FIG. 2, the second metal wire 221 and the third insulating wire 222 are arranged alternately. The second metal wire 221 and the third insulating wire 222 are juxtaposed at a predetermined interval so as not to contact each other.
- each second metal wire 221 for example, a copper wire, a stainless wire, a wire obtained by performing a metal plating process on the surface of a chemical fiber, or the like can be used.
- One end 221E of each second metal wire 221 is connected to the second bus bar 221A as shown in FIG.
- the third insulating wire 222 is made of a flexible insulating resin such as a nylon resin, a silicone resin, a urethane resin, an epoxy resin, a polycarbonate resin, or a vinyl resin.
- a flexible insulating resin such as a nylon resin, a silicone resin, a urethane resin, an epoxy resin, a polycarbonate resin, or a vinyl resin.
- a fourth insulating wire is used as the weft 220B. Similar to the third insulating wire 222, the fourth insulating wire is made of a flexible insulating resin such as nylon resin, silicone resin, urethane resin, epoxy resin, polycarbonate resin, or vinyl resin.
- a flexible insulating resin such as nylon resin, silicone resin, urethane resin, epoxy resin, polycarbonate resin, or vinyl resin.
- the first metal wire 121, the second metal wire 221, the first insulating wire 122, the third insulating wire 222, etc. are set to a thickness of about 20 ⁇ m to 30 ⁇ m.
- FIG. 3 is a schematic enlarged view of a circle A region in FIG.
- the photoelectric conversion layer 13 is provided on one electrode, that is, the lower electrode portion 120, and the p-layer organic semiconductor 13A serving as a hole transport material, and on the other electrode, that is, the upper electrode portion 220, and is transported by electrons.
- n-layer organic semiconductor 13B as a material.
- the organic semiconductor 13B is provided on the organic semiconductor 13A. Therefore, the lower electrode part 120 functions as a p-type electrode, and the upper electrode part 220 functions as an n-type electrode.
- the p-layer organic semiconductor 13A and the n-layer organic semiconductor 13B form a pn junction.
- the p-layer organic semiconductor 13A is formed of a hole transport material.
- a hole transport material in addition to triphenylamine (TAPC) represented by the chemical formula (1), TPD and other aromatic amines which are dimers of triphenylamine represented by the chemical formula (2), the chemical formula (3) ⁇ -NPD represented by formula (4), (DTP) DPPD represented by formula (4), m-MTDATA represented by formula (5), HTM1 represented by formula (6), 2-TNATA represented by formula (7), TPTE1 represented by the chemical formula (8), TCTA represented by the chemical formula (9), NTPA represented by the chemical formula (10), spiro TAD represented by the chemical formula (11), TFREL represented by the chemical formula (12), and the like are used.
- TAPC triphenylamine
- the n-layer organic semiconductor 13B is formed of an electron transport material.
- the electron transport material include Alq 3 represented by the chemical formula (13), BCP represented by the chemical formula (14), an oxadiazole derivative represented by the chemical formula (15), and an oxadiazole dimer represented by the chemical formula (16).
- a method for producing the photoelectric conversion device 1 shown in FIG. First, the first metal wire 121, the first insulating wire 122, and the second insulating wire are prepared and plain weave to produce the lower electrode portion 120. Similarly, the upper electrode part 220 is produced. Thereafter, a hole transport material to be the p-layer organic semiconductor 13A is applied to a predetermined portion, for example, one electrode, that is, the lower electrode portion 120. For the application, for example, a printing method using an inkjet printer can be applied.
- an electron transport material to be the n-layer organic semiconductor 13B is applied on the p-layer.
- the same printing technique by an ink jet printer as in the case of the p-layer organic semiconductor 13A may be used.
- a pn junction is formed by the p-layer organic semiconductor 13A and the n-layer organic semiconductor 13B.
- the n-layer organic semiconductor 13B may be applied, and then the p-layer organic semiconductor 13A may be applied.
- the lower electrode portion 120 is overlaid on the n layer. Thereby, the photoelectric conversion device 1 is produced. Note that the method is not limited to the above-described method as long as the photoelectric conversion device 1 illustrated in FIG. 1 is manufactured.
- the photoelectric conversion device 1 configured as described above, for example, when light is incident on the photoelectric conversion layer 13 from the upper electrode portion 220 side, the light L and the second metal wire 221 constituting the upper electrode portion 220 It passes between the three insulated wires 222 and enters the inner region from the upper surface of the photoelectric conversion layer 13. As shown in FIG. 3, the light L ′ can enter the inner region also from the lower surface of the photoelectric conversion layer 13.
- the lower electrode portion 120 and the upper electrode portion 220 are made of a material that transmits light through a plurality of gaps S for passing light, that is, the areas of the gaps S.
- the electrode provided on the surface of the photoelectric conversion layer 13 on which light is incident is configured to have a plurality of gaps S for passing light, so that it is not necessary to configure the electrode with a transparent electrode. Therefore, it is not necessary to use a rare metal for the transparent electrode as a material. Therefore, Cu, Al, etc. can be used for the electrode 12 for photoelectric conversion devices. Moreover, since the electrode 12 is comprised with the net
- the upper electrode part 220 is comprised by the net shape with the wire which functions as an electrode, members, such as a bus bar, contact
- the present invention can be implemented with appropriate modifications within the scope of the present invention.
- the configuration in which one first insulating wire 122 and one third insulating wire 222 are provided between the first metal wires 121 and between the second metal wires 221 is described with reference to FIG. A plurality may be provided as shown in A).
- the photoelectric conversion device may be configured by omitting the first insulating wire 122 and the third insulating wire 222 as shown in FIG.
- Photoelectric conversion device 12 Electrode 120 for photoelectric conversion device: Lower electrode portion 120A: Warp yarn 120B of lower electrode portion: Weft yarn of lower electrode portion 121: First metal wire 122 of lower electrode portion: Lower side Second insulating wire 220 of electrode part: Upper electrode part 220A: Warp thread 220B of upper electrode part: Weft thread 221 of upper electrode part: Second metal wire 222 of upper electrode part: Second insulating wire 13 of upper electrode part: Photoelectric conversion Layer 13A: p-layer organic semiconductor 13B: n-layer organic semiconductor 14: protective layer
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Abstract
La présente invention concerne une électrode pour dispositifs de conversion photoélectrique, pourvue des éléments suivants : une partie électrode inférieure (120) qui est prévue du côté de la surface inférieure d'une couche de conversion photoélectrique (13) ; et une partie électrode supérieure (220) qui est prévue du côté de la surface supérieure de la couche de conversion photoélectrique. La partie électrode inférieure et la partie électrode supérieure comprennent respectivement une pluralité de fils de chaîne (120A, 220A) et une pluralité de fils de trame (120B, 220B). Les fils de chaîne sont composés d'une pluralité de fils métalliques (121, 221) qui sont agencés à intervalle les uns des autres, et les fils de trame sont composés d'une pluralité de fils isolants qui sont agencés à intervalle les uns des autres. Une première partie, parmi la partie électrode inférieure et la partie électrode supérieure, fonctionne comme une électrode de type p, et l'autre partie, parmi la partie électrode inférieure et la partie électrode supérieure, fonctionne comme une électrode de type n.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2011/071053 WO2013038539A1 (fr) | 2011-09-14 | 2011-09-14 | Électrode pour dispositifs de conversion photoélectrique, et dispositif de conversion photoélectrique utilisant ladite électrode |
PCT/JP2012/073000 WO2013039021A1 (fr) | 2011-09-14 | 2012-09-09 | Écran, électrode destinée à un dispositif de conversion photoélectrique, dispositif de conversion photoélectrique et procédé de fabrication de dispositif de conversion photoélectrique |
JP2013533650A JP6083675B2 (ja) | 2011-09-14 | 2012-09-09 | 表示装置、光電変換デバイス用電極、光電変換デバイス及び光電変換デバイスの製造方法 |
Applications Claiming Priority (1)
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PCT/JP2011/071053 WO2013038539A1 (fr) | 2011-09-14 | 2011-09-14 | Électrode pour dispositifs de conversion photoélectrique, et dispositif de conversion photoélectrique utilisant ladite électrode |
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WO2013038539A1 true WO2013038539A1 (fr) | 2013-03-21 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015083175A3 (fr) * | 2013-12-08 | 2015-07-30 | Solarpaint Ltd. | Matériau de peinture solaire et système de peinture utilisant ce dernier |
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WO2015083175A3 (fr) * | 2013-12-08 | 2015-07-30 | Solarpaint Ltd. | Matériau de peinture solaire et système de peinture utilisant ce dernier |
CN105900249A (zh) * | 2013-12-08 | 2016-08-24 | 太阳涂料有限公司 | 太阳能涂料材料和使用太阳能涂料材料的涂刷系统 |
US11978815B2 (en) | 2018-12-27 | 2024-05-07 | Solarpaint Ltd. | Flexible photovoltaic cell, and methods and systems of producing it |
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