WO2013003991A8 - 一种基于金属co的抛光工艺的抛光液及其应用 - Google Patents
一种基于金属co的抛光工艺的抛光液及其应用 Download PDFInfo
- Publication number
- WO2013003991A8 WO2013003991A8 PCT/CN2011/002027 CN2011002027W WO2013003991A8 WO 2013003991 A8 WO2013003991 A8 WO 2013003991A8 CN 2011002027 W CN2011002027 W CN 2011002027W WO 2013003991 A8 WO2013003991 A8 WO 2013003991A8
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- metal
- polishing
- polishing liquid
- process based
- oxidant
- Prior art date
Links
- 238000005498 polishing Methods 0.000 title abstract 7
- 239000007788 liquid Substances 0.000 title abstract 5
- 229910052751 metal Inorganic materials 0.000 title abstract 5
- 239000002184 metal Substances 0.000 title abstract 5
- 238000007517 polishing process Methods 0.000 title abstract 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000002738 chelating agent Substances 0.000 abstract 2
- 238000005260 corrosion Methods 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 2
- 230000001105 regulatory effect Effects 0.000 abstract 2
- MLIWQXBKMZNZNF-KUHOPJCQSA-N (2e)-2,6-bis[(4-azidophenyl)methylidene]-4-methylcyclohexan-1-one Chemical compound O=C1\C(=C\C=2C=CC(=CC=2)N=[N+]=[N-])CC(C)CC1=CC1=CC=C(N=[N+]=[N-])C=C1 MLIWQXBKMZNZNF-KUHOPJCQSA-N 0.000 abstract 1
- 239000004160 Ammonium persulphate Substances 0.000 abstract 1
- 125000003275 alpha amino acid group Chemical group 0.000 abstract 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 abstract 1
- 235000019395 ammonium persulphate Nutrition 0.000 abstract 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 abstract 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 1
- 229910001487 potassium perchlorate Inorganic materials 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/10—Etching compositions
- C23F1/14—Aqueous compositions
- C23F1/16—Acidic compositions
- C23F1/28—Acidic compositions for etching iron group metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/32115—Planarisation
- H01L21/3212—Planarisation by chemical mechanical polishing [CMP]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013523470A JP2014509064A (ja) | 2011-07-05 | 2011-12-05 | コバルトの化学機械研磨用スラリー |
US13/813,699 US20130140273A1 (en) | 2011-07-05 | 2011-12-05 | Slurry for chemical mechanical polishing of cobalt |
EP11867101.5A EP2592122A4 (en) | 2011-07-05 | 2011-12-05 | CLEANING LIQUID FOR METAL-CO-BASED CLEANING PROCESSES AND USE THEREOF |
KR1020137002473A KR101439797B1 (ko) | 2011-07-05 | 2011-12-05 | 코발트(Co)의 화학적 기계적 연마용 슬러리 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110186116A CN102304327A (zh) | 2011-07-05 | 2011-07-05 | 一种基于金属Co的抛光工艺的抛光液 |
CN201110186116.5 | 2011-07-05 | ||
CN201110372757.XA CN102516875B (zh) | 2011-07-05 | 2011-11-22 | 一种基于金属Co的抛光工艺的抛光液及其应用 |
CN201110372757.X | 2011-11-22 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2013003991A1 WO2013003991A1 (zh) | 2013-01-10 |
WO2013003991A8 true WO2013003991A8 (zh) | 2013-04-04 |
Family
ID=45378248
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2011/002027 WO2013003991A1 (zh) | 2011-07-05 | 2011-12-05 | 一种基于金属co的抛光工艺的抛光液及其应用 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20130140273A1 (zh) |
EP (1) | EP2592122A4 (zh) |
JP (1) | JP2014509064A (zh) |
KR (1) | KR101439797B1 (zh) |
CN (2) | CN102304327A (zh) |
WO (1) | WO2013003991A1 (zh) |
Families Citing this family (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102786879B (zh) * | 2012-07-17 | 2014-04-23 | 清华大学 | 钛酸钡化学机械抛光水性组合物及其应用 |
JP6156630B2 (ja) * | 2013-05-24 | 2017-07-05 | Jsr株式会社 | 化学機械研磨用水系分散体および化学機械研磨方法 |
CN103265893B (zh) * | 2013-06-04 | 2015-12-09 | 复旦大学 | 一种基于金属Mo的抛光工艺的抛光液、其制备方法及应用 |
CN104745085B (zh) * | 2013-12-25 | 2018-08-21 | 安集微电子(上海)有限公司 | 一种用于钴阻挡层抛光的化学机械抛光液 |
EP3112436A4 (en) * | 2014-02-26 | 2017-02-22 | Fujimi Incorporated | Polishing composition |
KR102458648B1 (ko) * | 2014-07-09 | 2022-10-26 | 쇼와덴코머티리얼즈가부시끼가이샤 | Cmp용 연마액 및 연마 방법 |
JP6379764B2 (ja) * | 2014-07-10 | 2018-08-29 | 日立化成株式会社 | 研磨液及び研磨方法 |
WO2016008896A1 (en) * | 2014-07-15 | 2016-01-21 | Basf Se | A chemical mechanical polishing (cmp) composition |
EP3169737B1 (en) * | 2014-07-15 | 2018-10-10 | Basf Se | A chemical mechanical polishing (cmp) composition |
US10217645B2 (en) * | 2014-07-25 | 2019-02-26 | Versum Materials Us, Llc | Chemical mechanical polishing (CMP) of cobalt-containing substrate |
US9735030B2 (en) * | 2014-09-05 | 2017-08-15 | Fujifilm Planar Solutions, LLC | Polishing compositions and methods for polishing cobalt films |
JP2016056254A (ja) * | 2014-09-08 | 2016-04-21 | 株式会社フジミインコーポレーテッド | 研磨用組成物 |
JP6723995B2 (ja) * | 2014-10-21 | 2020-07-15 | キャボット マイクロエレクトロニクス コーポレイション | コバルトディッシング制御剤 |
WO2016065060A1 (en) * | 2014-10-21 | 2016-04-28 | Cabot Microelectronics Corporation | Cobalt polishing accelerators |
US9944828B2 (en) * | 2014-10-21 | 2018-04-17 | Cabot Microelectronics Corporation | Slurry for chemical mechanical polishing of cobalt |
KR102477843B1 (ko) * | 2014-10-21 | 2022-12-16 | 씨엠씨 머티리얼즈, 인코포레이티드 | 부식 억제제 및 관련 조성물 및 방법 |
WO2016102279A1 (en) | 2014-12-22 | 2016-06-30 | Basf Se | Use of a chemical mechanical polishing (cmp) composition for polishing of cobalt and / or co-balt alloy comprising substrates |
KR101733162B1 (ko) * | 2015-03-20 | 2017-05-08 | 유비머트리얼즈주식회사 | 연마 슬러리 및 이를 이용한 기판 연마 방법 |
CN104830235B (zh) * | 2015-04-29 | 2017-06-23 | 清华大学 | 用于钴阻挡层结构化学机械抛光的抛光液及其应用 |
US10032644B2 (en) * | 2015-06-05 | 2018-07-24 | Versum Materials Us, Llc | Barrier chemical mechanical planarization slurries using ceria-coated silica abrasives |
US9528030B1 (en) * | 2015-10-21 | 2016-12-27 | Cabot Microelectronics Corporation | Cobalt inhibitor combination for improved dishing |
US9534148B1 (en) | 2015-12-21 | 2017-01-03 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | Method of polishing semiconductor substrate |
JP6641980B2 (ja) * | 2015-12-22 | 2020-02-05 | 日立化成株式会社 | 研磨液及び研磨方法 |
US10745589B2 (en) | 2016-06-16 | 2020-08-18 | Versum Materials Us, Llc | Chemical mechanical polishing (CMP) of cobalt-containing substrate |
US10570315B2 (en) | 2016-11-08 | 2020-02-25 | Fujimi Incorporated | Buffered slurry formulation for cobalt CMP |
US10233356B2 (en) | 2017-03-06 | 2019-03-19 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | Polishing slurry for cobalt-containing substrate |
US10077382B1 (en) | 2017-03-06 | 2018-09-18 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | Method for polishing cobalt-containing substrate |
EP3631045A4 (en) | 2017-05-25 | 2021-01-27 | Fujifilm Electronic Materials U.S.A., Inc. | MECHANICAL-CHEMICAL POLISHING CONCENTRATE SUSPENSION FOR COBALT APPLICATIONS |
WO2019006668A1 (zh) * | 2017-07-04 | 2019-01-10 | 深圳市恒兆智科技有限公司 | 抛光剂、铜件及其抛光处理方法 |
US10522398B2 (en) | 2017-08-31 | 2019-12-31 | International Business Machines Corporation | Modulating metal interconnect surface topography |
US10170335B1 (en) | 2017-09-21 | 2019-01-01 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | Chemical mechanical polishing method for cobalt |
US10377921B2 (en) | 2017-09-21 | 2019-08-13 | Rohm and Haas Electronics Materials CMP Holdings, Inc. | Chemical mechanical polishing method for cobalt |
JP7507561B2 (ja) | 2017-09-29 | 2024-06-28 | 株式会社フジミインコーポレーテッド | 研磨用組成物 |
RU2687649C2 (ru) * | 2017-10-04 | 2019-05-15 | Общество с ограниченной ответственностью "КРОКУС НАНОЭЛЕКТРОНИКА" | Способ химико-механической полировки толстых слоев кобальтсодержащих сплавов |
US10727076B2 (en) * | 2018-10-25 | 2020-07-28 | Taiwan Semiconductor Manufacturing Company Ltd. | Slurry and manufacturing semiconductor using the slurry |
US10676647B1 (en) * | 2018-12-31 | 2020-06-09 | Cabot Microelectronics Corporation | Composition for tungsten CMP |
US20200263056A1 (en) | 2019-02-19 | 2020-08-20 | AGC Inc. | Polishing composition and polishing method |
CN113652317A (zh) * | 2021-07-16 | 2021-11-16 | 张家港安储科技有限公司 | 一种用于在半导体晶圆清洗过程中的化学机械研磨后的清洗组合物 |
CN115160933B (zh) * | 2022-07-27 | 2023-11-28 | 河北工业大学 | 一种用于钴互连集成电路钴cmp的碱性抛光液及其制备方法 |
CN115820127A (zh) * | 2022-11-07 | 2023-03-21 | 上海交通大学 | 一种适用于铜钴互连结构的化学机械抛光液及其制备方法 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3397501B2 (ja) * | 1994-07-12 | 2003-04-14 | 株式会社東芝 | 研磨剤および研磨方法 |
US6068879A (en) * | 1997-08-26 | 2000-05-30 | Lsi Logic Corporation | Use of corrosion inhibiting compounds to inhibit corrosion of metal plugs in chemical-mechanical polishing |
US6117795A (en) * | 1998-02-12 | 2000-09-12 | Lsi Logic Corporation | Use of corrosion inhibiting compounds in post-etch cleaning processes of an integrated circuit |
CN1209430C (zh) * | 1999-08-13 | 2005-07-06 | 卡伯特微电子公司 | 化学机械抛光系统及其使用方法 |
JP2002231666A (ja) * | 2001-01-31 | 2002-08-16 | Fujimi Inc | 研磨用組成物およびそれを用いた研磨方法 |
SG144688A1 (en) * | 2001-07-23 | 2008-08-28 | Fujimi Inc | Polishing composition and polishing method employing it |
US7300480B2 (en) * | 2003-09-25 | 2007-11-27 | Rohm And Haas Electronic Materials Cmp Holdings, Inc. | High-rate barrier polishing composition |
US20050076580A1 (en) * | 2003-10-10 | 2005-04-14 | Air Products And Chemicals, Inc. | Polishing composition and use thereof |
WO2005047410A1 (en) * | 2003-11-14 | 2005-05-26 | Showa Denko K.K. | Polishing composition and polishing method |
JP2008543060A (ja) * | 2005-05-26 | 2008-11-27 | アドバンスド テクノロジー マテリアルズ,インコーポレイテッド | 銅不活性化化学機械研磨後洗浄組成物及び使用方法 |
JP5317436B2 (ja) * | 2007-06-26 | 2013-10-16 | 富士フイルム株式会社 | 金属用研磨液及びそれを用いた研磨方法 |
CN101358107A (zh) * | 2007-08-03 | 2009-02-04 | 安集微电子(上海)有限公司 | 用于抛光半导体封盖层的抛光液 |
JP5428205B2 (ja) * | 2008-06-04 | 2014-02-26 | 日立化成株式会社 | 金属用研磨液 |
JP2011003665A (ja) * | 2009-06-17 | 2011-01-06 | Jsr Corp | 化学機械研磨用水系分散体およびそれを用いた化学機械研磨方法 |
CN102101982A (zh) * | 2009-12-18 | 2011-06-22 | 安集微电子(上海)有限公司 | 一种化学机械抛光液 |
-
2011
- 2011-07-05 CN CN201110186116A patent/CN102304327A/zh active Pending
- 2011-11-22 CN CN201110372757.XA patent/CN102516875B/zh not_active Expired - Fee Related
- 2011-12-05 US US13/813,699 patent/US20130140273A1/en not_active Abandoned
- 2011-12-05 WO PCT/CN2011/002027 patent/WO2013003991A1/zh active Application Filing
- 2011-12-05 JP JP2013523470A patent/JP2014509064A/ja active Pending
- 2011-12-05 EP EP11867101.5A patent/EP2592122A4/en not_active Withdrawn
- 2011-12-05 KR KR1020137002473A patent/KR101439797B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
EP2592122A4 (en) | 2014-01-22 |
CN102516875A (zh) | 2012-06-27 |
JP2014509064A (ja) | 2014-04-10 |
US20130140273A1 (en) | 2013-06-06 |
CN102304327A (zh) | 2012-01-04 |
EP2592122A1 (en) | 2013-05-15 |
KR20130132389A (ko) | 2013-12-04 |
WO2013003991A1 (zh) | 2013-01-10 |
CN102516875B (zh) | 2014-01-08 |
KR101439797B1 (ko) | 2014-09-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2013003991A8 (zh) | 一种基于金属co的抛光工艺的抛光液及其应用 | |
EP1950263A3 (en) | Polishing composition and polishing method | |
MY159149A (en) | Polishing composition | |
JP2016536785A5 (zh) | ||
BR0318293A (pt) | composição para revestir metais para proteger contra corrosão | |
WO2009025383A1 (ja) | 研磨組成物 | |
WO2011008770A3 (en) | Methods for inhibiting yellow color and peroxide formation in a composition | |
MY147273A (en) | Oxidation-stabilized cmp compositions and methods | |
EA201400745A1 (ru) | Композиция моющего средства, содержащая глутамин-n,n-диацетат, воду и отбеливатель | |
WO2009001829A1 (ja) | 安定性が改良されたトリフェニルボロン化合物含有防汚塗料組成物、それに用いる防汚剤セット、およびトリフェニルボロン化合物の分解抑制・制御方法 | |
MX2007011113A (es) | Composiciones que contienen micro-esferas expansibles y un compuesto ionico, asi como metodos para producir y utilizar las mismas. | |
MY148323A (en) | Stable, high rate silicon slurry | |
WO2009083547A3 (de) | Wasserfreie antitranspirant-sprays mit verbesserter wirkstofffreisetzung | |
TW200725726A (en) | Process for producing silicon wafer | |
MY155229A (en) | Polishing composition and polishing method using the same | |
MY165455A (en) | Silicon-nitride-containing separating layer having high hardness | |
AU2020258568A8 (en) | CD73 inhibitors | |
TW200940694A (en) | Polishing liquid and polishing method | |
TW200632156A (en) | Process for treating a semiconductor wafer with a gaseous medium, and semiconductor wafer treated by this process | |
TW200738714A (en) | New secondary amines | |
SG179405A1 (en) | Additive for polishing composition | |
TW200740968A (en) | Polishing composition for silicon wafer | |
TW200745316A (en) | Copper-based metal polishing compositions and polishing process | |
WO2008105799A3 (en) | Galfenol steel | |
CR20220308A (es) | Compuestos heterocíclicos como inhibidores de delta-5 desaturasa y métodos de uso |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 2011867101 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 20137002473 Country of ref document: KR Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2013523470 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 13813699 Country of ref document: US |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 11867101 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |