WO2012084970A1 - Composition cosmétique émulsifiante contenant des agents moussants pour le soin de la peau et du corps - Google Patents

Composition cosmétique émulsifiante contenant des agents moussants pour le soin de la peau et du corps Download PDF

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Publication number
WO2012084970A1
WO2012084970A1 PCT/EP2011/073436 EP2011073436W WO2012084970A1 WO 2012084970 A1 WO2012084970 A1 WO 2012084970A1 EP 2011073436 W EP2011073436 W EP 2011073436W WO 2012084970 A1 WO2012084970 A1 WO 2012084970A1
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chcf
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acid
esters
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PCT/EP2011/073436
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German (de)
English (en)
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Bernhard Banowski
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Henkel Ag & Co. Kgaa
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Priority to EP11802402.5A priority Critical patent/EP2654667A1/fr
Publication of WO2012084970A1 publication Critical patent/WO2012084970A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A61K8/70—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine containing perfluoro groups, e.g. perfluoroethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q9/00—Preparations for removing hair or for aiding hair removal
    • A61Q9/02—Shaving preparations

Definitions

  • the present application relates to foamable cosmetic compositions for skin and body care, which are foamed with selected fluorocarbons or fluorocarbons as blowing agents.
  • washing, cleansing and caring for one's own body is a fundamental human need, and modern industry is constantly trying to meet these needs of man in a variety of ways. Especially important for daily hygiene is the permanent elimination or at least reduction of body odor.
  • Numerous personal care products are known in the art which have been developed for cleansing and care. While in the past soaps were the most important cleansing agent, most consumers now use care products with a flowable consistency that are dispensed from a bottle or tube for hygienic and convenience reasons.
  • An interesting variant for the dosage of such composition are propellant-containing spray dispenser, which apply the composition as a mousse, that is, as a fine bubble foam. Depending on the field of application, both fast-breaking and stable foams can be produced.
  • the application saves as a mousse the foaming by hand. With care products such as creams that remain on the skin, the application gives as a mousse an interesting skin feel.
  • Typical hydrocarbon blowing agents such as propane, n-butane and isobutane
  • propane, n-butane and isobutane have a low solubility in water
  • a polar blowing agent such as dimethyl ether
  • the foams produced with these blowing agents are in their quality, especially in terms of the stability or the rate of breakage, on the fine bubbles and the sensory properties in need of further improvement.
  • the present application was based on the object of providing a propellant-containing foamable cosmetic composition for skin and body care, which has improved properties compared to the compositions of the prior art, in particular with regard to the foam stability, the fine bubbles and the sensory properties.
  • a propellant selected from unsaturated fluorocarbons and unsaturated fluorohydrocarbons, as well as mixtures thereof, the prior art mousse compositions can be optimized, particularly with regard to foam stability, fine bubbles and sensory properties.
  • the present application relates to foamable cosmetic compositions containing
  • conditioning agents from different conditioning agent groups c) i. to c) v. are selected and
  • At least one blowing agent selected from at least one compound having 3 to 10 carbon atoms according to formula (I)
  • radicals R, R 2 , R 3 and R 4 independently of one another, denote a hydrogen atom, a bromine atom, a fluorine atom or a (CT - C 6 ) -alkyl group substituted by at least one fluorine atom,
  • R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom
  • At least one of R, R 2 , R 3 or R 4 is a substituted with at least one fluorine atom (C- ⁇ to C 6 ) alkyl group or at least two of the radicals R, R 2 , R 3 and R 4 is a five or form a six-membered ring.
  • compositions are characterized by a propellant of formula (I) wherein R, R 2 , R 3 or R 4 of formula (I) independently represent a hydrogen atom, a fluorine atom or a (C 1 -C 6 ) -alkyl group substituted by at least one fluorine atom, with the proviso that:
  • R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom
  • At least one of the radicals R, R 2 , R 3 or R 4 is a substituted with at least one fluorine atom (C ⁇ to C 6 ) alkyl group.
  • compositions according to the invention are characterized in that blowing agent of the formula (I) is selected from at least one compound of the group which is formed
  • compositions according to the invention are not taken into account for the quantities which concern non-propellant ingredients. All amounts are therefore based on the total weight of the propellant-free composition, unless otherwise stated.
  • normal conditions are a temperature of 20 ° C. and a pressure of 1013.25 mbar. Melting point data likewise relate to a pressure of 1013.25 mbar.
  • the water content of the compositions according to the invention is 10 to 97% by weight, preferably 20 to 85% by weight, more preferably 30 to 75% by weight, most preferably 40 to 65% by weight, based in each case on the total weight of the blowing agent-free Composition.
  • the surfactant content of the compositions according to the invention is 0.1 to 30% by weight, preferably 0.5 to 25% by weight, more preferably 1 to 20% by weight, most preferably 2 to 15% by weight, based in each case on the total weight of the blowing agent-free composition.
  • surfactant contents may also be preferred.
  • a surfactant content for cleansing compositions that only remain on the skin or hair during the cleansing process and are then rinsed off, may be a surfactant content of 6 to 30 wt .-%, moreover from 9 to 18 wt .-% or 1 1 - 14 wt .-%, each based on the total weight of the blowing agent-free composition, be preferred.
  • a surfactant content for cleansing compositions that only remain on the skin or hair during the cleansing process and are then rinsed off, may be a surfactant content of 6 to 30 wt .-%, moreover from 9 to 18 wt .-% or 1 1 - 14 wt .-%, each based on the total weight of the blowing agent-free composition, be preferred.
  • leave on compositions such as creams, lotions or facewashes
  • emulsifiers are also added to the surfactants.
  • Suitable anionic surfactants in compositions according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic Tensid- classes are, in each case in the form of the sodium, potassium and ammonium and the mono-, di- and Trialkanolammoniumsalze with 2 to 4 C-atoms in the alkanol group:
  • Sulfobernsteinklamono- and -dialkylester having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethylester having 8 to 24 carbon atoms, preferably 10-14 C-atoms, more preferably 12 C-atoms in the alkyl group and each 1 to 6 oxyethyl groups .
  • linear alpha-olefin sulfonates having 8 to 24 carbon atoms
  • alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 carbon atoms alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 carbon atoms
  • R6 OCH 2 CH 2
  • n -0-P-OR7 II in the R preferred for an aliphatic hydrocarbon radical having 8 to 30 carbon atoms
  • R 7 is hydrogen, a radical (CH 2 CH 2 0) n R 6 or X
  • n is from 1 to 10
  • X is hydrogen, an alkali or Alkaline earth metal or NR 8 R 9 R 0 R 11 , with R 8 to R
  • R 2 CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, Alk for CH 2 CH 2 , CHCH 3 CH 2 and / or CH 2 CHCH 3 , n for numbers from 0.5 to 5 and M is a cation, as described in DE-OS 197 36 906.5,
  • R 3 CO is a linear or branched acyl radical having 6 to 22 carbon atoms
  • x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10
  • X is an alkali or alkaline earth metal.
  • monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. It is preferred to use monoglyceride sulfates of the formula (IV) in which R 3 CO is a linear acyl radical having 8 to 18 carbon atoms,
  • Protein hydrolyzate fatty acid condensates are prepared by condensation of C8 - C30 fatty acids, preferably fatty acids having 12 - 18 C atoms with amino acids, mono-, di- and water-soluble oligopeptides and mixtures of such products as obtained in the hydrolysis of proteins.
  • These protein hydrolyzate-fatty acid condensation products are neutralized with a base and are then preferably present as alkali, ammonium, mono-, di- or Trialkanolammoniumsalz;
  • Acylglutamates which are condensation products of glutamic acid and C 8 -C 30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms, and which are present in neutralized form as K, Na or ammonium salt, and
  • Acyl aspartates which condensation products of aspartic acid and C8 - C30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms and which are present in neutralized form as K, Na or ammonium salt.
  • Preferred anionic surfactant classes are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acid salts having 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfosuccinic acid mono- and dialkyl esters having 8 to 18 C atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups, citric acid esters with fatty alcohol ethoxylates, such as the product sold under the trade name "Plantapon LC-7"
  • Preferred surfactants of the class alkyl polyglycol ether sulfates are sodium trideceth sulfates, for example those sold under the trade name "Miracare SLB 365", “Genapol XRO" or "Rhodapex
  • Zwitterionic surfactants are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO () or -SO 3 () group in the molecule.
  • Particularly suitable zwitterionic surfactant classes are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkylbenzenesulfonate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.
  • Amphoteric surfactants are understood as meaning those surface-active compounds which, apart from a C 8 -C 24 -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and are capable of forming internal salts
  • Examples of preferred ampholytic surfactant classes are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, amphoacetates, in particular cocoamphoacetates, lauroamphoacetates, olivamphoacetates, amphopropionates, in particular cocoamphopropionates, Amphodiacetates, in particular cocoamphodiacetates, lauroamphodiacetates, capryloamphodiacetates, amphodipropionates, in particular cocoampho
  • Phosphatidylcholines having the general structural formula shown below are the main constituent of lecithin.
  • the substituents R and R 2 in the structural formula below represent linear aliphatic alkyl radicals having from 7 to 21 carbon atoms, preferably from 1 to 19 carbon atoms, more preferably from 15 to 17 carbon atoms, which may have up to four Z-configured double bonds. More preferably, R CO and R 2 CO are independently selected from palmitoyl, stearoyl, oleoyl, linoloyl and linolenoyl.
  • phosphatidylcholine also particularly preferred is phosphatidylcholine, partially hydrogenated phosphatidylcholine and fully hydrogenated phosphatidylcholine, each derived from soya lecithin.
  • Phosphatidylcholines belong to the phospholipids, but are calculated in the present context only to the surfactants, not the lipids.
  • ampholytic surfactants are cocoamphoacetates, lauroamphoacetates, cocoamphodiacetates, lauroamphodiacetates and capryloamphodiacetates.
  • amphoteric and / or zwitterionic surfactants are in the compositions of the invention - based on the total weight of the propellant-free composition - in a total amount of 0.01 to 20 wt .-%, preferably in a total amount of 0.05 to 18 wt .-%, particularly preferably used in a total amount of 0.1 to 15 wt .-% and in particular in a total amount of 0.5 to 10 wt .-%.
  • Nonionic surfactants contain as hydrophilic group z.
  • a polyol group especially a polyglycerol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups.
  • Such classes of surfactants are, for example
  • Polyol fatty acid esters such as the commercial product Hydagen ® HSP (BASF) or
  • Hydroxy mixed ethers as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and addition products of ethylene oxide onto sorbitan fatty acid esters, for example the polysorbates,
  • the alkyl polyglycosides which can be used according to the invention can only contain one particular alkyl radical R. Usually, however, these compounds are prepared starting from natural fats and oils or mineral oils. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the particular work-up of these compounds. Particular preference is given to those alkylpolyglycosides in which R
  • sugar building block Z it is possible to use any desired mono- or oligosaccharides.
  • sugars with 5 or 6 carbon atoms and the corresponding oligosaccharides are used.
  • Such sugars are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, idose, talose and sucrose.
  • Preferred sugar building blocks are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.
  • the inventively preferred Alkylpolyglycoside contain in section 1, 1 to 5 sugar units.
  • Alkyl polyglycosides having x values of 1.1 to 2.0 are preferred. Very particular preference is given to alkyl glycosides in which x is 1: 1 to 1, 8.
  • the alkoxylated homologs of said alkylpolyglycosides can also be used according to the invention. These homologs may contain on average up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.
  • Preferred nonionic surfactants are the ethylene oxide adducts of saturated linear fatty alcohols and fatty acids having in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Compositions having excellent properties are also obtained when they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.
  • the nonionic surfactants are in the compositions of the invention - based on the total weight - in a total amount of 0.05 to 20 wt .-%, preferably in a total amount of 0.1 to 15 wt .-% and in particular in a total amount of 0, 5 to 10 wt .-% used.
  • compositions according to the invention may further comprise at least one cationic surfactant of the quaternary ammonium quaternary type, the esterquats and the amidoamines.
  • Preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83.
  • the alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.
  • Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element.
  • Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines.
  • the cationic surfactants are contained in the compositions according to the invention - based on their total weight - in a total amount of 0.05 to 10 wt .-%, particularly preferably 0.5 to 3 wt .-%.
  • compositions of the invention contain at least two surfactants belonging to different classes of surfactants.
  • preferred surfactant classes are:
  • Sulfosuccinic acid monoalkylpolyoxyethyl esters having 8 to 24 C atoms, preferably 10 to 14 C atoms, particularly preferably 12 C atoms in the alkyl group and in each case 1 to 6 oxyethyl groups, Sodium, potassium and ammonium salts and mono-, di- and trialkanolammonium salts having 2 to 4 C atoms in the alkanol group of linear or branched fatty acids having 8 to 30 C atoms (soaps),
  • Alkylpolyglycolethersulfate of the formula R-0 (CH 2 -CH 2 0) x -OS0 3 H, in which R is a preferably linear alkyl group having 8 to 18 carbon atoms, preferably 10 to 14 and particularly preferably 12 carbon atoms and x 1 - 12, more preferably 2 - 4, is
  • Ethercarbon Acid the formula R-0- (CH2-CH20) x-CH2-COOH, where R is a linear
  • Alkyl group having 8 to 30 C atoms and x 0 or 1 to 16,
  • N-acyl sarcosinates N-acyl sarcosinates
  • compositions according to the invention contain at least the following surfactant class mixture: alkylpolyglycol ether sulfate / betaine, alkylpolyglycol ether sulfate / sulfosuccinic acid monoalkylpolyoxyethyl ester, alkylpolyglycol ether sulfate / alkylpolyglycoside as aforesaid, alkylpolyglycol ether sulfate / amphoacetate, alkylpolyglycol ether sulfate / amphodiacetate, alkylpolyglycol ether sulfate / adduct of from 5 to 60 moles of ethylene oxide hydrogenated castor oil, sulfosuccinic acid mono-alkyl polyoxyethyl
  • compositions according to the invention preferably contain as surfactant at least one nonionic oil-in-water emulsifier having an HLB value of more than 7.
  • HLB (100-L): 5 where L is the weight fraction of the lipophilic groups, that is, the fatty alkyl or fatty acyl groups, in the ethylene oxide adducts, expressed in weight percent.
  • nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to optimally adjust the properties of compositions according to the invention.
  • compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols with an average of 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 - 100 moles of ethylene oxide per mole, silicone copolyols having ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs, ethoxylated sterols, partial esters of polyglycerols having 2 to 10 glycerol units and esterified with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues, provided that they have an HLB value of more than 7, and mixtures of the a
  • the ethoxylated C 8 -C 24 alkanols have the formula R 0 (CH 2 CH 2 0) n H, where R is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide Units per molecule, for numbers from 10 to 100, preferably 10 to 30, moles of ethylene oxide to 1 mole of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol , Arachylalkohol, Gadoleylalkhol, behenyl, erucyl alcohol and brassidyl alcohol and their technical mixtures. Also, adducts of 10-100 mo
  • the ethoxylated C 8 -C 24 carboxylic acids have the formula R (OCH 2 CH 2 ) n OH, where R is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide units per Molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, gadoleic acid, Behenic acid, erucic acid and brassidic acid as well as their technical mixtures.
  • Adducts of 10 to 100 moles of ethylene oxide with technical fatty acids containing 12 to 18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are also suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.
  • C 2 -C 8 -alkanols or the C 2 -C 8 -carboxylic acids with in each case 10 to 30 units of ethylene oxide per molecule and also mixtures of these substances, especially ceteth-12, ceteth-20, ceteth-30, isoceteth-20, steareth-12, steareth-20, steareth-21, steareth-30, ceteareth-12, ceteareth-20, ceteareth-30, laureth-12 and beheneth -20.
  • C 8 -C 22 -alkyl mono- and -oligoglycosides preference is given to using C 8 -C 22 -alkyl mono- and -oligoglycosides.
  • C 8 -C 22 -alkylmono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms.
  • the glycoside radical monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable.
  • the degree of oligomerization is a statistical mean, which is based on a homolog distribution typical for such technical products. Products which are obtainable under the trademark Plantacare ®, containing a glucosidic bond C 8 -C 6 - alkyl group at an oligoglucoside whose average degree of oligomerization at 1 - 2, in particular 1, 1 - 1, 4, is located.
  • Particularly preferred C 8 -C 22 alkyl mono- and oligoglycosides are selected from octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof.
  • the glucamine-derived acylglucamides are also suitable as nonionic oil-in-water emulsifiers.
  • Ethoxylated sterols, in particular ethoxylated soy sterols are also suitable oil-in-water emulsifiers according to the invention.
  • the degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7.
  • Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.
  • partial esters of polyglycerols having 2 to 10 glycerol units and having 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 -C 30 fatty acid radicals are preferably esterified, if they have an HLB value of more than 7 ,
  • Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol are rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetragly- cerinmonocaprylat, rinmonocaprat Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce-, hexa glycerol, Hexaglycerin
  • organosiloxane-oxyalkylene copolymers are selected from organosiloxane-oxyalkylene copolymers.
  • Particularly preferred organosiloxane-oxyalkylene copolymers according to the invention are selected from linear polysiloxane-polyoxyalkylene block copolymers, in particular from linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymers.
  • Extremely preferred according to the invention is a linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer having the INCI name PEG / PPG-22/24 dimethicones and CAS no. 64365-23-7.
  • Such a linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer is available, for example, under the trade name Mirasil DMCO (INCI: PEG / PPG-22/24 dimethicone) from Rhodia or Bluestar Silicones.
  • Mirasil DMCO INCI: PEG / PPG-22/24 dimethicone
  • Another preferred linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer of this type carries the INCI name PEG / PPG-10/2 Dimethicone. It is available, for example, under the trade name Mirasil DMCP 93 (INCI: PEG / PPG-10/2 Dimethicone) from Rhodia or Bluestar Silicones.
  • organosiloxane-oxyalkylene copolymer O / W emulsifiers are selected from compounds of the general structural formulas (I), (II), (III), (IV) and (V),
  • radicals R represent, independently of one another, a linear or branched C 5 -C 5 -alkyl group or an optionally substituted phenyl group,
  • radicals R 2 are independently of one another the groups -C c H 2 C- O- (C 2 H 4 O-) a (C 3 H 6 O-) b R 5 or -C c H 2c -O- (C 2 H 4 O -) represent a R 5 ,
  • radicals R 3 and R 4 independently of one another represent a linear or branched CC 6 -alkyl group and preferably methyl groups,
  • radicals R 5 independently of one another represent a hydrogen atom or a linear or branched one
  • C 1 -C 4 -alkyl group and preferably represent a hydrogen atom or a methyl group, m represents a number from 0-20,
  • n a number from 0 - 500
  • 0 represents a number from 0 - 20
  • p represents a number from 1 to 50
  • a represents a number from 0-50
  • b represents a number from 0-50
  • a + b are at least 1,
  • c is a number from 1 to 4, more preferably 3,
  • x represents a number from 1 to 100.
  • organosiloxane-oxyalkylene copolymer is, for example, under the trade name Dow Corning 190 (INCI: PEG / PPG-18/18 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is, for example available under the trade designation Dow Corning 193 (INCI: PEG-12 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Silwet L-77.
  • organosiloxane-oxyalkylene copolymer is, for example available under the trade designation Dow Corning Q2-5220 (INCI: PEG / PPG-17/18 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is, for example available under the trade name Abil B 88184 (INCI: PEG / PPG-20/6 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is, for example available under the trade name Abil B 8851 (INCI: PEG / PPG-14/4 Dimethicone).
  • compositions according to the invention are characterized in that at least one oil-in-water emulsifier, preferably at least one nonionic oil-in-water emulsifier, in a total amount of 0.5-10 wt.%, Preferably 1-9 wt %, more preferably 1.5-8.5% by weight, most preferably 2-8% by weight, and also 2.5, 3, 3.5, 4.0, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, and 8 wt .-%, based on the propellant-free total composition is included.
  • compositions according to the invention comprise at least one water-in-oil emulsifier having an HLB value greater than 1.0, and less than or equal to 7.0, preferably at least one nonionic water-in-oil emulsifier having an HLB value greater than 1, 0 and ⁇ 7.0.
  • compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.
  • Preferred water-in-oil emulsifiers with an HLB value greater than 1.0, and ⁇ 7.0 are selected from the mono- and diesters of ethylene glycol and the mono-, di-, tri- and tetra-esters of pentaerythritol with linear saturated fatty acids with 12-30, in particular 14-22, carbon atoms which may be hydroxylated, as well as mixtures thereof.
  • the mono- and diesters are preferred.
  • C 2 -C 30 fatty acid radicals which are preferred according to the invention are selected from lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid and Behenic radicals; particularly preferred is the stearic acid residue.
  • Particularly preferred nonionic water-in-oil emulsifiers according to the invention having an HLB value greater than 1.0, and ⁇ 7.0 are selected from pentaerythrityl monostearate, pentaerythrityl distearate, pentaerythrityl tristearate, pentaerythrityl tetrastearate, ethylene glycol monostearate, ethylene glycol distearate, and mixtures thereof.
  • particularly preferred water-in-oil emulsifiers having an HLB value greater than 1, 0 and ⁇ 7.0 are, for example, as commercial products Cutina ® PES (INCI: Pentaerythrityl distearate), Cutina ® AGS (INCI: Glycol distearate) or Cutina ® EGMS (INCI: Glycol stearate) available.
  • Cutina ® PES INCI: Pentaerythrityl distearate
  • Cutina ® AGS INCI: Glycol distearate
  • Cutina ® EGMS INCI: Glycol stearate
  • These commercial products are already mixtures of mono- and diesters (in the pentaerythrityl esters are also tri- and tetraesters contain). Under a technical mixture, for example, a commercial product such as Cutina ® understood PES.
  • linear saturated alkanols having 12-30 carbon atoms, in particular having 16-22 carbon atoms, in particular cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol and lanolin alcohol or mixtures of these alcohols, as obtainable in the industrial hydrogenation of vegetable and animal fatty acids,
  • Such esters or partial esters are, for.
  • Sterols ie steroids which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol) and from fungi and yeasts (mycosterols) which may be low ethoxylated (1-5 EO);
  • Alkanols and carboxylic acids each having 8-24 C atoms, in particular having 16-22 C atoms, in the alkyl group and 1-4 ethylene oxide units per molecule which have an HLB value of greater than 1.0, and less than or equal to 7.0 exhibit,
  • Partial esters of polyglycerols with n 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues esterified, if they have an HLB value of less than or equal to 7,
  • Particularly advantageously usable water-in-oil emulsifiers are stearyl alcohol, cetyl alcohol, glyceryl monostearate, glyceryl Glycerylmonocaprinat, glyceryl, glyceryl monolaurate, glyceryl monomyristate rylmonooleat, glyceryl, Glycerylmonohydroxystearat, glycerol, lenglycolmonostearat Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, glyceryl, propylene, propylene glycol , Sorbitan monocaprylate, sorbitan monolaurate, sorbitan monomyristate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquistearate, sorbitan tandearate, sorbitan dioleate, sorbitan
  • W / O emulsifiers are silicone-free polymeric water-in-oil emulsifiers, in particular PEG-30 dipolyhydroxystearate, available for. B. under the trade name Arlacel P 135 from Uniqema.
  • PEG / PPG-18/18 dimethicones z. B. in a 1: 9 mixture with Cyclomethicone under the name Dow Corning 3225 C or Dow Corning 5225 C is commercially available
  • PEG / PPG-18/18 Dimethicone the z. B. in a 1: 3 mixture with non-volatile dimethicone as Dow Corning ES 5227 DM Formulation Aid is commercially available
  • PEG / PPG-4/12 Dimethicone, the z. B. under the name Abil B 8852 is available
  • silicone-based W / O emulsifiers which are preferred according to the invention are poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1 Dimethicone (formerly: Cetyl Dimethicone Copolyol, available, for example as Abil EM 90 or in a mixture of polyglyceryl-4-isostearate, cetyl PEG / PPG-10/1 dimethicone and hexyl laurate under the trade name Abil WE 09), furthermore alkyl methicone copolyols and alkyl dimethicone ethoxy glucosides.
  • poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10
  • compositions contain at least one water-in-oil emulsifier in a total amount of 0.01 to 4 wt .-%, preferably 0.1 to 3 wt .-%, particularly preferably 0.5 to 1 wt .-% ,
  • compositions according to the invention comprise at least two conditioning agents, which consist of different conditioning agent groups of the cosmetic oils and waxes, the organic UV filter substances, the polyols, the cationic polymers and the vitamins, provitamins or compounds designated as vitamin precursors Vitamin groups A, B, C and E, and the esters, ethers and salts of these substances are selected.
  • conditioning agents consist of different conditioning agent groups of the cosmetic oils and waxes, the organic UV filter substances, the polyols, the cationic polymers and the vitamins, provitamins or compounds designated as vitamin precursors Vitamin groups A, B, C and E, and the esters, ethers and salts of these substances are selected.
  • phospholipids and lecithins are among the surfactants, not the conditioners.
  • Cosmetic oils preferred according to the invention are selected from silicone oils, to which z.
  • dialkyl and alkylaryl such as cyclopentasiloxane, cyclohexasiloxane, dimethylpolysiloxane and methylphenylpolysiloxane, but also hexamethyldisiloxane, octamethyltrisiloxane and decamethyltetrasiloxane include.
  • Particularly preferred are volatile silicone oils, which may be cyclic, such as. For example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane and mixtures thereof, as described, for. B.
  • volatile linear silicone oils in particular hexamethyldisiloxane (L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), dodecamethylpentasiloxane (L 5 ), as well as any two, three and four mixtures of L 2 , L 3 , L 4 and / or L 5 , as z.
  • Dow Corning® 200 (0.65 cSt) and Dow Corning® 200 (1.5 cSt) from Dow Corning, where the values of the kinematic viscosity are at a temperature of 25 ° C.
  • compositions of the invention are free of cyclomethicones.
  • volatile non-silicone oil In addition to or instead of the at least one volatile silicone oil, it is also possible for at least one volatile non-silicone oil to be present.
  • volatile non-silicone oils are selected from C 8 -C 6 -isoalkanes, in particular from isodecane, isododecane, isotetradecane and isohexadecane and mixtures thereof.
  • compositions according to the invention may further comprise at least one non-volatile cosmetic oil selected from non-volatile silicone oils and non-volatile non-silicone oils.
  • nonvolatile silicone oils are selected from higher molecular weight linear dimethyl polysiloxanes, commercially available for.
  • Nonvolatile silicone oils which are likewise preferred in accordance with the invention are selected from silicones selected from integers of 1 to 20, preferably 1 to 3.
  • a preferred silicone oil of formula (Sil-1) is available under the INCI name Phenyl Trimethicone.
  • Natural and synthetic hydrocarbons such as paraffin oils, C 8 -C 30 - isoalkanes, particularly isoeicosane, polyisobutenes or polydecenes, the ®, for example, under the designation Emery ® 3004, 3006, 3010 or under the name Ethylflo ® from Albemarle or Nexbase 2004G from Nestle are available, as well as 1, 3-di- (2-ethylhexyl) -cyclohexane (obtainable, for. example, under the trade name Cetiol ® S from BASF) also belong to the invention preferred non-volatile non-silicone oils.
  • paraffin oils C 8 -C 30 - isoalkanes, particularly isoeicosane, polyisobutenes or polydecenes
  • the ® for example, under the designation Emery ® 3004, 3006, 3010 or under the name Ethylflo ® from Albemarle or Nexbase 2004G from Nestle are
  • non-volatile non-silicone oils which are preferred according to the invention are selected from the benzoic acid esters of linear or branched C 8 . 22 -alkanols. Particularly preferred are benzoic C12-C15 alkyl esters, z. B. available as a commercial product Finsolv ® TN, benzoic isostearylester, z. B. available as a commercial product Finsolv ® SB, ethylhexyl benzoate, z. B. available as a commercial product Finsolv ® EB, and Benzoekladyldocecylester, z. B. available as a commercial product Finsolv ® BOD.
  • benzoic C12-C15 alkyl esters z. B. available as a commercial product Finsolv ® TN
  • benzoic isostearylester z. B. available as a commercial product Finsolv ® SB
  • ethylhexyl benzoate z. B. available
  • Such benzoic acid ester oils have a pleasant feel on the skin.
  • Further non-volatile non-silicone oils which are preferred according to the invention are selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms. These alcohols are also often referred to as Guerbet alcohols, as they are obtainable by the Guerbet reaction.
  • Preferred oils are alcohol 2-hexyldecanol (Eutanol ® G 16) 2-octyldodecanol (Eutanol ® G) and 2-ethylhexyl alcohol.
  • non-volatile non-silicone oils are chosen from mixtures of Guerbet alcohols and Guerbet alcohol esters, for example the commercial product Cetiol ® PGL (hexyldecanol and hexyldecyl laurate).
  • Further non-volatile non-silicone oils which are preferred according to the invention are selected from the triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 . 30- fatty acids.
  • Particularly suitable may be the use of natural oils, for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, rapeseed oil, olive oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like.
  • natural oils for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, rapeseed oil, olive oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like.
  • synthetic triglyceride oils in particular Capric / Caprylic triglycerides, with unbranched fatty acid residues and z.
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols, in particular diisopropyl adipate, di-n-butyl adipate, di (2-ethylhexyl) adipate, dioctyl adipate, diethyl / di-n- butyl / dioctyl sebacate, diisopropyl sebacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di (2-hexyldecyl) succinate.
  • dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols in particular diisopropyl adipate, di-n-but
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated.
  • these include hexyldecyl (z. B. Eutanol ® G 16 S), hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, and 2-ethylhexyl stearate, in particular 2-ethylhexyl palmitate.
  • non-volatile non-silicone oils are selected from the addition products of 1 to 5 propylene oxide units of mono- or polyhydric C 8 _ 22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (z. B. Wtconol ® APM).
  • mono- or polyhydric C 8 _ 22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (z. B. Wtconol ® APM).
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the adducts of at least 6 ethylene oxide and / or propylene oxide units with monovalent or polyvalent C 3 . 22 -alkanols such as glycerol, butanol, butanediol, myristyl alcohol and stearyl alcohol, which may be esterified if desired, for.
  • PPG-14 butyl ether z. B. Ucon ® fluid AP
  • PPG-9-butyl ether z. B. Breox B25 ®
  • PPG-10 butanediol z. B. Macol ® 57
  • PPG 15- stearyl ether z. B. Arlamol ® e
  • Glycereth-7-diisononanoate As PPG-14 butyl ether (z. B. Ucon ® fluid AP), PPG-9-butyl ether (z. B. Bre
  • non-volatile non-silicone oils are selected from the C 2 -C 22 fatty alcohol esters of monohydric or polyhydric C 2 -C 7 hydroxycarboxylic acids, in particular the esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and Salicylic acid.
  • esters based on linear C 2 / i 5-alkanols and branched in 2-position C 2 / i 3-alkanols are preferably selected from C 2 -C 5 alkyl lactate, di-C 12-13 -alkyl malate and tri-C 12 -13 alkyl citrate, e.g. B. available under the trademark Cosmacol ® from Nordmann, Rassmann GmbH & Co, Hamburg.
  • Another such preferred oil component is triethyl citrate.
  • non-volatile non-silicone oils are selected from the symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, eg. B. dicaprylyl or the esters according to the teaching of DE 19756454 A1.
  • compositions according to the invention are characterized in that the conditional liquid conditioner is selected from volatile silicone oils, nonvolatile silicone oils, volatile hydrocarbon oils, branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 .
  • compositions according to the invention comprise at least one oil as conditioning agent in a total amount of from 0.1 to 35% by weight, preferably from 0.5 to 25% by weight, more preferably from 1 to 15% by weight and most preferably from 2 to 8% by weight .-%, in each case based on the total weight of the composition according to the invention.
  • solid wax components can be used as conditioners even under normal conditions.
  • Particularly preferred wax components are selected from coconut oil acid glycerol mono-, di- and triesters, Butyrospermum Parkii (Shea butter) and esters of saturated, monohydric C 8 -C 8 alcohols with saturated C 2 -C 8 monocarboxylic acids and mixtures of these substances.
  • Further preferred esters of saturated, monohydric C 2 -C 8 -alcohols with saturated C 2 -C 8 -monocarboxylic acids are stearyl laurate, cetearyl stearate, cetyl palmitate and myristyl myristate.
  • Conditioning agents which are preferred according to the invention are also vegetable waxes, eg. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. As beeswax, shellac wax and spermaceti, hydrogenated or hardened waxes, chemically modified waxes, especially the hard waxes, such as.
  • vegetable waxes eg. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. As beeswax, shellac wax and spermaceti, hydrogenated or hardened waxes, chemically modified waxes, especially the hard waxes, such as.
  • a particularly preferred wax component is selected from at least one ester of a saturated, monohydric C 6 -C 60 -alcohol and a saturated C 8 -C 36 -monocarboxylic acid.
  • lactides the cyclic double esters of alpha-hydroxycarboxylic acids of the corresponding chain length.
  • wax components are the triglycerides of saturated and optionally hydroxylated C 2 -3o fatty acids, such as hardened triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryltri-12-hydroxystearate, furthermore synthetic full esters of fatty acids and glycols or Polyols with 2-6 carbon atoms.
  • hydrogenated castor oil is particularly preferred as the wax component.
  • Further preferred wax components are the saturated linear C 4 -C 36 -fatty alcohols, in particular myristyl alcohol, palmityl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol and behenyl alcohol, and also mixtures of these compounds.
  • compositions according to the invention comprise at least one wax component as conditioning agent in a total amount of 0.1 to 5% by weight, preferably 0.2 to 4% by weight, more preferably 0.5 to 3% by weight and most preferably 1% 2 wt .-%, each based on the total weight of the composition according to the invention.
  • organic UV filter substance is poly silicone-15, also known as dimethicodiethylbenzalmalonate, Diethylbenzylidene malonates Dimethicone or Diethylmalonylbenzylidene referred Oxypropene Dimethicone and (under the trade name Parsol ® SLX INCI name Dimethicodiethylbenzal malonate (CAS no. 207574-74- 1)) available from DSM.
  • Further inventively suitable organic UV filter substances are selected from the derivatives of benzimidazole sulfonic acid.
  • benzimidazole sulfonic acid as the water-soluble organic UV filter substance (s) is or are the phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid (UV-A) and their salts, in particular the alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolamine and glucammonium salts, preferably the corresponding sodium, potassium, trialkylammonium or triethanolamine salts.
  • UV-A phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid
  • salts of this acid with amino-C C 6 -alkanols and Amino-C Ce-alkanediols in particular with 2-amino-2-methylpropan-1-ol, 2-amino-2-methylpropan-1, 3-diol, 2-aminopropan-1-ol, 3-aminopropane-1 -ol, 1-aminopropan-2-ol (MIPA) and 2-amino-2- (hydroxymethyl) propane-1, 3-diol (TRIS), wherein the salts with 2-amino-2-methylpropan-1-ol and 2-amino-2-methylpropane-1, 3-diol are particularly preferred.
  • phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid bis-sodium salt with the INCI name "Disodium Phenyl Dibenzimidazole Tetrasulfonate” (CAS no. 180898-37-7), which is available, for example, from Symrise under the trade name Neo Heliopan AP
  • Further preferred water-soluble organic UV filter substances are 2-phenylbenzimidazole-5-sulfonic acid (INCI name "phenylbenzimidazole sulfonic acid” (CAS. No.
  • salts in particular the alkali, alkaline earth, ammonium, alkylammonium, alkanolamine and glucammonium salts, preferably the corresponding sodium, potassium, trialkylammonium or triethanolamine salts, furthermore the Salts of this acid with amino-CrCe-alkanols and amino-C Ce-alkanediols, in particular with 2-amino-2-methylpropan-1-ol, 2-amino-2-methyl-propane-1, 3-diol, 2-aminopropane 1 -ol, 3-aminopropan-1-ol and 1-aminopropan-2-ol (MIPA), the salts with 2-amino-2-methylpropan-1 -o l and 2-amino-2-methylpropane-1, 3-diol are particularly preferred, but especially the salts of 2-phenylbenzimidazole-5-sulfonic acid with sodium ions and with 2-amino
  • organic UV filter substances are selected from alkyl- and / or alkoxy-substituted Dibenzoylmethanderivaten.
  • Alkyl and / or alkoxy-substituted dibenzoylmethane derivatives which are preferred according to the invention are characterized in that one of the phenyl radicals has at least one alkyl group selected from methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, n -Pentyl, isopentyl, neopentyl, 2-ethylhexyl, and the other phenyl radical having at least one alkoxy group selected from methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, sec-butoxy, tert-butoxy, n-pentoxy, Isopentoxy, neopentoxy, 2-ethylhex
  • substituents are isopropyl, tert-butyl and methoxy.
  • Alkyl- and / or alkoxy-substituted dibenzoylmethane derivatives which are preferred according to the invention are selected from 2-methyldibenzoylmethane, 4-methyldibenzoylmethane, 4-isopropyldibenzylmethane, 4-tert-butyldibenzoylmethane, 2,4-dimethyldibenzoylmethane, 2,5-dimethyldibenzoylmethane, 4 4'-diisopropyldibenzoylmethane, 4,4'-dimethoxydibenzoylmethane, 4-tert-butyl-4'-methoxydibenzoylmethane, 2-methyl-5-isopropyl-4'-methoxydibenzoylmethane, 2-methyl-5-tert-butyl-4'-methoxydi
  • 4-tert-butyl-4'-Methoxydibenzoyl- methane with the INCI name butyl methoxydibenzoylmethane (also as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1, 3-dione), an oil-soluble organic sunscreen.
  • Further inventively preferred organic UV filter substances are selected from s-triazine derivatives, which have the following structural motif
  • TRIAZIN-GROUND have.
  • s-triazine derivatives which have the structure motif TRIAZIN-GRUND above are known in the art, for example from EP 775698, EP 878469 and EP 1027881.
  • C 3 axis of the triazine basic body of these compounds both symmetrical substitution and unsymmetrical substitution are conceivable.
  • symmetrically substituted s-triazines have three identical substituents R, R 2 and R 3 , while asymmetrically substituted s-triazine derivatives consequently have different substituents, whereby the C 3 symmetry is destroyed.
  • asymmetrical is always understood to be asymmetrical with respect to the C 3 axis of the triazine main body, unless something else is expressly mentioned.
  • Corresponding symmetrical triazine derivatives are 4,4 ', 4 "- (1,3,5-triazine-2,4,6-triyltriimino) tris-benzoic acid tris (alkyl ester), in particular 4,4', 4" - (1 , 3,5-triazine-2,4,6-triyltriimino) tris-benzoic acid tris (2-ethylhexyl ester) [INCI: ethylhexyl triazone, formerly octyl triazone], which is sold as a single substance under the name UVINUL® T 150, but also available in various commercial UV filter blends.
  • Unsymmetrical triazine derivatives are, for example, those disclosed in EP 775,698:
  • R 4 and R 5 can be selected from the group of branched and unbranched alkyl groups of 1 to 18 carbon atoms. Also, the alkyl groups may in turn be substituted with silyloxy groups.
  • R 6 may represent a hydrogen atom or a branched or unbranched alkyl group having 1 to 10 carbon atoms.
  • An exemplary compound of the general formula (BIS-RESOR-TRIAZIN) -I in which R 4 and R 5 each represent a 2-ethylhexyl group and R 6 represents a methyl group, is 2,4-bis - ⁇ [4- (2 -ethyl-hexyloxy) -2-hydroxy] phenyl ⁇ -6- (4-methoxyphenyl) -1, 3,5-triazine (INCI: bis-Ethylhexyloxyphenol methoxyphenyl triazine), under the trade name Tinosorb S ® available from CIBA.
  • This UV filter a UV-A filter, is available under the trade name UVASORB HEB from Sigma 3V.
  • UV filter substances based on s-triazine compounds are:
  • UV filter substance is 2,2'-methylenebis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol) (INCI: Methylene Bis Benzotriazolyl tetramethylbutylphenol, MBBT) having the following structural formula
  • Tinosorb M available under the trade name Tinosorb M from CIBA. This is a so-called broadband filter that absorbs both UVA and UVB radiation.
  • Another preferred broadband UV UV optional filter substance is 2- (2H-benzotriazol-2-yl) -4-methyl-6- [2-methyl-3- [1,3,3,3-tetramethyl-1 - (( trimethylsilyl) oxy] disiloxanyl] propyl] phenol (CAS No .: 155633-54-8) with the INCI name Drometrizole Trisiloxane.
  • benzotriazole filters are 2,2'-methyl-bis- [6 (2H-benzotriazol-2-yl) -4- (methyl) phenol] (MIXXIM BB / 200 from Fairmount Chemical), 2- (2 '-Hydroxy-3', 5'-di-t-amyl-phenyl) benzotriazole (CAS No .: 025973-551), 2- (2'-hydroxy-5'-octylphenyl) benzotriazole (CAS-No. 003147-75-9), 2- (2'-hydroxy-5'-methylphenyl) benzotriazole (CAS No.
  • UV filter substances are mentioned below: - the camphor derivatives, particularly 3-benzylidenecamphor derivatives, which may have no ionizable functional groups in the molecule, preferably 3- (4-methyl-benzylidene) -D, L-camphor [INCI: 4-Methylbenzylidene Camphor];
  • camphor which may have ionizable functional groups in the molecule, preferably sulfonic acid derivatives of 3-Benzylidencamphers, such as.
  • 4-aminobenzoic acid derivatives preferably 4- (dimethylamino) benzoic acid (2-ethylhexyl) ester, 4- (dimethylamino) benzoic acid amyl ester;
  • benzophenone which have no ionizable functional groups in the molecule, preferably 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2 -Hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone; 2- (4'-diethylamino-2'-hydroxybenzoyl) benzoic acid hexyl ester (also: aminobenzophenone, available under the name Uvinul A Plus from BASF),
  • benzophenone having ionizable functional groups in the molecule preferably sulfonic acid derivatives of benzophenones, more preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts,
  • Esters of benzalmalonic acid preferably di-2-ethylhexyl 4-methoxybenzalmalonate,
  • polymeric-bound UV filters other than polysilicone-15 are polymeric-bound UV filters other than polysilicone-15;
  • Dibenzoxazoyl naphthalenes Dibenzoxazoyl naphthalenes
  • 2,4-bis [5-1 (di-methylpropyl) benzoxazol-2-yl- (4-phenyl) -imino] -6- (2-ethylhexyl) -imino-1,3,5- triazine Uvasorb K2A ® from 3V Sigma, INCI: ethylhexyl bis Isopentylbenzoxazolylphenyl melamines.
  • the benzoxazole derivatives are preferably in soluble form. ter form in the cosmetic compositions of the invention. However, it may also be advantageous if the benzoxazole derivatives are present in a pigmentary, ie undissolved form, for example in particle sizes of from 10 nm to 300 nm.
  • UV filter substances which can be used as conditioning agents in the context of the present invention should of course not be limiting.
  • the total amount of the at least one oil-soluble organic UV filter substance in the compositions according to the invention is preferably 0.1-25% by weight, more preferably 1-15% by weight, most preferably 2-10% by weight, based in each case on the total weight of the composition of the invention.
  • Further conditioning agents preferred according to the invention are selected from polyols. Surprisingly, it has been found that these substances, in interaction with a fluorocarbon or fluorohydrocarbon propellant according to the invention, can lead to a sensory particularly attractive foam.
  • Preferred polyols are water-soluble polyhydric C 2 -C 12 alkanols having 2 to 6 hydroxyl groups and water-soluble polyethylene glycols having 3 to 20 ethylene oxide units.
  • Water solubility according to the invention is understood to mean a solubility of at least 5% by weight at 20 ° C., that is to say amounts of at least 5 g of the polyol in 95 g of water are soluble at 20 ° C.
  • compositions according to the invention contain at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units and mixtures thereof.
  • These components are preferably selected from 1,2-propylene glycol, 1,3-propylene glycol, 2-methyl-1,3-propanediol, glycerol, 1,2-butylene glycol, 1,3-butylene glycol and 1,4-butylene glycol, Pentylene glycols such as 1, 2-pentanediol and 1, 5-pentanediol, hexanediols such as 1, 2-hexanediol and 1, 6-hexanediol, hexanetriols such as 1, 2,6-hexanetriol, 1, 2-octanediol, 1, 8-octanediol, Dipropylene glycol, tripropylene glycol, diglycerol, triglycerol, erythritol, sorbitol, cis-1,4-dimethylol-cyclohexane, trans-1,4-dimethylolcyclohexan
  • Suitable water-soluble polyethylene glycols are selected from PEG-3, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18 and PEG-20 and mixtures thereof, with PEG-3 to PEG-8 being preferred.
  • compositions according to the invention are characterized in that the at least one water-soluble polyvalent C 2 -C 9 -alkanol with 2-6 hydroxyl groups and / or at least one water-soluble polyethylene glycol with 3-20 ethylene oxide units in total in amounts of 0.5-30 wt .-%, preferably 3 - 20 wt .-%, particularly preferably 5 - 10 wt .-%, each based on the total composition is included.
  • Further conditioning agents preferred according to the invention are selected from cationic polymers. It has surprisingly been found that a cationic polymer in combination with a fluorocarbon or fluorohydrocarbon blowing agent according to the invention can lead to a particularly stable foam.
  • Cationic polymers preferred according to the invention are selected from quaternized hydroxyethyl cellulose polymers which contain cationic trimethylammonium and dimethyldodecylammonium groups as substituents. Such polymers preferably contain a grouping of the following formula:
  • Preferred polymers of this type have a cationic degree of substitution of 0.15 to 0.25 and a hydrophobic degree of substitution (HS) of HS ⁇ 0.01.
  • Such polymers are known under the INCI designation Polyquaternium-67 and are commercially available, for example, by the company Amerchol under the designations SL ® polymer or polymer ® SK.
  • cationic polymers are selected from homopolymers or copolymers, wherein the quaternary nitrogen groups are contained either in the polymer chain or preferably as a substituent on one or more of the monomers.
  • the ammonium group-containing monomers may be copolymerized with cationic monomers.
  • Suitable cationic monomers are unsaturated, free-radically polymerizable compounds which carry at least one cationic group, in particular ammonium-substituted vinyl monomers such as trialkylmethacryloxyalkylammonium, trialkylacryloxyalkylammonium, dialkyldiallylammonium and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups such as pyridinium, imidazolium or quaternary pyrrolidones, e.g. Alkylvinylimidazolium, alkylvinylpyridinium, or alkylvinylpyrrolidone salts.
  • the alkyl groups of these monomers are preferably lower alkyl groups such as C1 to C7 alkyl groups, more preferably C1 to C3 alkyl groups.
  • ammonium group-containing monomers may also be copolymerized with non-cationic monomers.
  • Suitable comonomers are, for example, acrylamide, methacrylamide; Alkyl and dialkylacrylamide, alkyl and dialkylmethacrylamide, alkyl acrylate, alkyl methacrylate, vinylcaprolactone, vinylcaprolactam, vinylpyrrolidone, vinyl esters, for example vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, where the alkyl groups of these monomers are preferably C 1 - to C 7 -alkyl groups, more preferably C1 to C3 alkyl groups.
  • Preferred polymers with quaternary Examples of ternary amine groups are the polymers described under the names Polyquaternium in the CTFA Cosmetic Ingredient Dictionary, such as methylvinylimidazolium chloride / vinylpyrrolidone copolymer (Polyquaternium-16) or quaternized vinylpyrrolidone / dimethylaminoethyl methacrylate copolymer (Polyquaternium-11). Polyquaternium-1 1 is particularly preferred according to the invention.
  • cationic polymers are, for example, copolymers of polyvinylpyrrolidone and Imidazoliminmethochlorid, such as those sold by BASF under the trade name Luviquat ® HM 550, terpolymers of dimethyldiallyl ammonium chloride, sodium acrylate and acrylamide with the INCI name Polyquaternium-39, z. B.
  • a particularly suitable homopolymer is, if desired crosslinked, poly (methacryloyl oxyethyltrimethylammoniumchlorid) with the INCI name Polyquaternium-37.
  • Such products are available, for example under the names Rheocare ® CTH (Cosmetic Rheologies) and Synthalen® ® CR (3V Sigma) in trade.
  • mineral oil (INCI name: mineral oil) and tridecyl polyoxypropylene polyoxyethylene ether (INCI name: PPG-1 -Trideceth-6) are further polymer dispersions under the names Salcare ® SC 95 ) and Salcare ® SC 96 (about 50% polymer content, additional components: mixture of diesters of propylene glycol (with a mixture of caprylic and capric acid INCI name: propylene glycol Dicaprylate / Dicaprate) and tridecyl polyoxypropylene poly- oxyethylene ether (INCI name: PPG-1 -Trideceth-6)) commercially available.
  • a further preferred copolymer according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium chloride copolymer with the INCI name Polyquaternium-32.
  • Such copolymers in which the monomers are present in a weight ratio of about 20:80, are commercially available as approximately 50% non-aqueous polymer dispersion 92 under the name Salcare ® SC.
  • cationic polymers derived from natural polymers are cationic derivatives of polysaccharides, for example, cationic derivatives of cellulose, starch or guar. Also preferred are chitosan and chitosan derivatives, in particular the salts of chitosan, such as chitosan lactate and chitosan glycolate.
  • a particularly preferred cationic cellulose has the INCI name Polyquaternium-10.
  • Another particularly preferred cationic cellulose bears the INCI name Polyquaternium-24.
  • Preferred cationic guar derivatives have the INCI name Guar Hydroxypropyltrimonium Chloride. Further preferred cationic polymers are, for example
  • cationic alkyl polyglycosides polymeric dimethyldiallylammonium salts and their copolymers with esters and amides of acrylic acid and methacrylic acid.
  • Merquat ® 100 Poly (dimethyldi- allylammonium chloride)
  • Merquat ® 550 dimethyldiallylammonium chloride-acrylamide copolymer
  • commercially available products are examples of such cationic polymers, vinyl pyrrolidone-vinyl imidazolium methochloride copolymers, as are sold under the names Luviquat ® FC 370, FC 550, FC 905 and HM 552 are offered,
  • Vinylpyrrolidone-Vinylcaprolactam-acrylate terpolymers such as those with acrylic acid esters and acrylic acid amides as a third monomer unit commercially available, for example, under the name Aquaflex ® SF 40.
  • copolymers of vinylpyrrolidone as commercial products copoly mer 845 (manufactured by ISP), are Gaffix ® VC 713 (manufactured by ISP), Gafquat ® ASCP 101 1, Gafquat ® HS 1 10, Luviquat ® 8155 and Luviquat ® MS 370 are available.
  • Homopolymers or copolymers containing quaternary nitrogen groups either in the polymer chain or, preferably, as a substituent on one or more of the monomers, Homopolymers or copolymers of monomers containing ammonium groups, copolymers of monomers containing ammonium groups with cationic monomers different therefrom, which are preferably selected from ammonium-substituted vinyl monomers and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups such as pyridinium, imidazolium or quaternary pyrrolidones,
  • Copolymers of ammonium group-containing monomers with non-cationic monomers which are preferably selected from acrylamide, methacrylamide; Alkyl and dialkylacrylamide, alkyl and dialkylmethacrylamide, alkylacrylate, alkylmethacrylate, vinylcaprolactone, vinylcaprolactam, vinylpyrrolidone, vinyl esters, e.g. Vinyl acetate, vinyl alcohol, propylene glycol or ethylene glycol, the alkyl groups of these monomers preferably being C 1 - to C 7 -alkyl groups, more preferably C 1 - to C 3 -alkyl groups,
  • cationic derivatives of polysaccharides preferably cationic derivatives of cellulose, starch or guar,
  • Chitosan and chitosan derivatives in particular the salts of chitosan, such as chitosan lactate and
  • compositions according to the invention are characterized in that the at least one cationic polymer in a total amount of 0.02 to 4 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.5 to 1 wt .-% , in each case based on the total weight of the composition according to the invention.
  • Further conditioning agents preferred according to the invention are selected from anionic polymers. It has surprisingly been found that an anionic polymer in combination with a fluorocarbon or fluorohydrocarbon blowing agent according to the invention can lead to a particularly stable foam.
  • preferred anionic polymers are selected from xanthan gum, sclerotium gum, succinoglucans, polygalactomannans, in particular furthermore pectins, agar, carrageenan, tragacanth, gum arabic, karaya gum, gellan, propylene glycol alginate, alginic acids and their salts, in particular sodium alginate, Potassium alginate and calcium alginate, further comprising, physically (eg, by pre-gelatinizing) and / or chemically modified starches, in particular hydroxypropylated starch phosphates and octenyl starch succinates and their aluminum, calcium or sodium salts, furthermore the homopolymers of acrylic acid, Copolymers of acrylic acid, furthermore the homopolymers of methacrylic acid, the copolymers of methacrylic acid, acrylic acid-acrylate copolymers, acrylic acid-acrylamide copolymers, acrylic acid-vinylpyrrolidone copo
  • compositions according to the invention are characterized in that the at least one anionic polymer in a total amount of 0.01 to 3.5 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.5 to 1 wt. -%, in each case based on the total weight of the composition according to the invention is included.
  • Further conditioning agents preferred according to the invention are selected from amphoteric polymers. It has surprisingly been found that an amphoteric polymer in combination with a fluorocarbon or fluorohydrocarbon blowing agent according to the invention can lead to a particularly stable foam.
  • amphoteric polymers includes both those polymers which contain in the molecule both free amino groups and free -COOH or S0 3 H groups and which are capable of forming internal salts, as well as zwitterionic polymers which in the molecule have quaternary ammonium groups and -COO contain " - or -S0 3 " groups, and summarized those polymers containing -COOH or S0 3 H groups and quaternary ammonium groups.
  • amphopolymer is the acrylic resin commercially available as Amphomer ®, which is a copolymer of tert-butylaminoethyl methacrylate, N- (1, 1, 3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group of acrylic acid, Represents methacrylic acid and its simple esters.
  • amphoteric polymers which are preferred according to the invention are the compounds mentioned in British Patent Application 2,104,091, European Published Application 47,714, European Published Application 217,274, European Offenlegungsschrift 283,817 and German Offenlegungsschrift 28 17 369.
  • Preferred amphoteric polymers are those polymers which consist essentially of one another
  • R 22 -CH CR 23 -CO-Z- (C n H 2n ) -N (+) R 24 R 25 R 26 A () (IV)
  • R 22 and R 23 independently of one another are hydrogen or a methyl group and R 24 , R 25 and R 26 independently of one another are alkyl groups having 1 to 4 carbon atoms, Z is an NH group or an oxygen atom, n is an integer from 2 to 5 and A (_) is the anion of an organic or inorganic acid
  • R 27 and R 28 are independently hydrogen or methyl groups.
  • These compounds can be used both directly and in salt form, which is obtained by neutralization of the polymers, for example with an alkali metal hydroxide, according to the invention.
  • alkali metal hydroxide an alkali metal hydroxide
  • R 27 and R 28 are independently hydrogen or methyl groups.
  • These compounds can be used both directly and in salt form, which is obtained by neutralization of the polymers, for example with an alkali metal hydroxide, according to the invention.
  • a (_) is a halide, methoxysulfate or ethoxysulfate Ion is; Acrylamidopropyl trimethyl ammonium chloride is a particularly preferred monomer (a).
  • Acrylic acid is preferably used as monomer (b) for the stated polymers.
  • compositions according to the invention are characterized in that the at least one amphoteric polymer in a total amount of 0.01 to 3.5 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.2 - 0.8 % By weight, based in each case on the total weight of the composition according to the invention.
  • Further conditioning agents preferred according to the invention are selected from nonionic polymers. It has surprisingly been found that a nonionic polymer in combination with a fluorocarbon or fluorohydrocarbon blowing agent according to the invention can lead to a particularly stable foam.
  • preferred nonionic polymers are selected from cellulose ethers, especially hydroxyalkylcelluloses, in particular hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, gelatin, casein, guar gums and locust bean gum, in particular guar gum.
  • hydroxyalkylcelluloses in particular hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, gelatin, casein, guar gums and locust bean gum, in particular guar gum.
  • Gum and Locust Bean Gum themselves and the nonionic Hydroxyalkylguarderivaten and locust bean gum derivatives such as Hydroxyproppylguar, Carboxymethylhydroxypropylguar, Hydroxypropylmethylguar, Hydroxyethylguar and Carboxymethylguar, Taragummi, polyvinylpyrrolidones, polyvinyl alcohols, polyacrylamides, polyurethanes, polyurethane copolymers and vinylpyrrolidone / vinyl ester copolymers.
  • Hydroxyalkylguarderivaten and locust bean gum derivatives such as Hydroxyproppylguar, Carboxymethylhydroxypropylguar, Hydroxypropylmethylguar, Hydroxyethylguar and Carboxymethylguar, Taragummi, polyvinylpyrrolidones, polyvinyl alcohols, polyacrylamides, polyurethanes, polyurethane copolymers and vinylpyrrolidone
  • compositions according to the invention are characterized in that the at least one nonionic polymer in a total amount of 0.01 to 3.5 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.2 - 1, 2 % By weight, based in each case on the total weight of the composition according to the invention.
  • Further conditioning agents preferred according to the invention are selected from at least one vitamin, provitamin or a compound designated as vitamin precursor from the vitamin groups A, B, C and E and the esters, ethers and salts of these aforementioned substances.
  • the group of substances designated as vitamin A includes retinol (vitamin A and 3,4-didehydroretinol (vitamin A 2 ) .beta.-carotene is the provitamin of retinol.)
  • the vitamin A component is, for example, vitamin A acid and their esters, vitamin A aldehyde and vitamin A alcohol, and also esters thereof, such as retinyl palmitate and retinyl acetate.
  • the compositions according to the invention contain at least one vitamin A component preferably in a total amount of 0.01 to 1 wt .-%, based on the total composition.
  • the vitamin B group or the vitamin B complex include, among others
  • Vitamin B ⁇ trivial name thiamine, chemical name 3 - [(4 '-amino-2' -methyl-5 '-pyrimidi- nyl) methyl] -5- (2-hydroxyethyl) -4-methylthiazolium chloride.
  • Thiamine hydrochloride is preferably used in amounts of from 0.01 to 1% by weight, based on the total composition.
  • Vitamin B 2 common name riboflavin, chemical name 7,8-dimethyl-10- (1-D-ribityl) - benzo [g] pteridine-2,4 (3 / - /, 10 / - /) - dione.
  • riboflavin or its derivatives are used in a total amount of 0.01 to 1 wt .-%, based on the total composition.
  • Vitamin B 3 the compounds nicotinic acid and nicotinamide (niacinamide) are performed.
  • Preferred according to the invention is the nicotinic acid amide, which is preferably present in the compositions according to the invention in amounts of from 0.01 to 1% by weight, based on the total composition.
  • Vitamin B 5 pantothenic acid and panthenol.
  • Panthenol is preferably used.
  • Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and also cationically derivatized panthenols.
  • derivatives of 2-furanone instead of and in addition to pantothenic acid or panthenol, it is also possible to use derivatives of 2-furanone having the general structural formula (VIT-I).
  • the 2-furanone derivatives in which the substituents R to R 6 independently of one another are a hydrogen atom, a hydroxyl radical, a methyl, methoxy, aminomethyl or hydroxymethyl radical, a saturated or mono- or diunsaturated, linear or branched C C 2 -C 4 -hydrocarbon radical, a saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy-C 2 -C 4 -hydrocarbon radical or a saturated or mono- or diunsaturated, branched or linear mono-, Di- or triamino-C 2 -C 4 - hydrocarbon radical represent.
  • the substituents R to R 6 independently of one another are a hydrogen atom, a hydroxyl radical, a methyl, methoxy, aminomethyl or hydroxymethyl radical, a saturated or mono- or diunsaturated, linear or branched C C 2 -C 4 -hydrocarbon radical, a saturated or mono- or diunsatur
  • Particularly preferred derivatives are the commercially available substances dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone with the trivial name pantolactone (Merck), 4-hydroxymethyl- ⁇ -butyrolactone (Merck), 3,3 Dimethyl 2-hydroxy- ⁇ -butyrolactone (Aldrich) and 2,5-dihydro-5- methoxy-2-furanone (Merck), expressly including all stereoisomers.
  • the inventively extraordinarily preferred 2-furanone derivative is pantolactone (dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone), wherein in formula (VIT-I) R is a hydroxyl group, R 2 is is a hydrogen atom, R 3 and R 4 are a methyl group, and R 5 and R 6 are a hydrogen atom.
  • the stereoisomer (R) -pantolactone is formed during the degradation of pantothenic acid.
  • the said compounds of the vitamin B 5 type as well as the 2-furanone derivatives are preferably in the compositions according to the invention in a total amount of 0.01 to 5 wt .-%, particularly preferably 0.1 to 3 wt .-%, most preferably 0, 5 to 2 wt .-%, each based on the total composition.
  • Vitamin B 6 which is understood hereunder no uniform substance, but the known under the common names pyridoxine, pyridoxamine and pyridoxal derivatives of 5-hydroxymethyl-2-methylpyridin-3-ols.
  • Vitamin B 6 is contained in the compositions according to the invention preferably in amounts of 0.0001 to 1, 0 wt .-%, in particular in amounts of 0.001 to 0.01 wt .-%.
  • Biotin also known as vitamin H or "skin vitamin”.
  • Biotin is (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] imidazole-4-valeric acid.
  • Biotin is preferably present in the compositions according to the invention in amounts of from 0.0001 to 1.0% by weight, in particular in amounts of from 0.001 to 0.01% by weight.
  • Folic acid (Vitamin B 9 , Vitamin B c ). International generic name for N- [4- (2-amino-3,4-dihydro-4-oxo-6-pteridinylmethylamino) -benzoyl] -L-glutamic acid (N-pteroyl-L-glutamic acid, PteGlu). Folate is used synonymously with pteroylglutamate. Folate is the generic term for all folic acid-active compounds and refers to a class of compounds containing a pteridine ring linked to 4-aminobenzoic acid and L-glutamic acid.
  • Folic acid is a growth factor for various microorganisms and a compound with vitamin character, which is usually found in nature as polyglutamate and in reduced form (7,8-dihydrofolic acid, H 2 folate, DHF, tetrahydrofolic acid, H 4 folate, THF, 5'-methyl Tetrahydrofolic acid, CH 3 -H 4 folate, MeTHF).
  • Particularly preferred compositions according to the invention are characterized in that they contain at least one component selected from folic acid, folates and their esters, in a total amount of 0.0001 to 1.0% by weight, in particular 0.01 to 0.5% by weight. %, based on the composition.
  • Orotic acid (vitamin B 3 , 1, 2,3,6-tetrahydro-2,6-dioxo-4-pyrimidine-carboxylic acid, uracil-6-carboxylic acid, molar acid).
  • Orotic acid, its choline ester or orotic acid metal salts (orotates of Ca, Cr, Fe, K, Co, Cu, Li, Mg, Mn, Na, Zn, Sn) are particularly preferred according to the invention.
  • Particularly preferred compositions according to the invention are characterized in that they contain at least one component selected from orotic acid, orotates and their esters, in a total amount of 0.0001-1.0% by weight, in particular 0.01-0.5% by weight. %, based on the composition.
  • the vitamin C group includes vitamin C (ascorbic acid) and its derivatives, in particular the esters of ascorbic acid with organic and inorganic acids and their salts, and the acetals with glucose or other sugars, in particular ascorbyl glucoside.
  • Vitamin C and / or at least one of its derivatives is preferably used in a total amount of 0.01 to 3 wt .-%, based on the total composition.
  • the use of the derivatives ascorbyl palmitate, stearate, dipalmitate, acetate, Mg ascorbyl phosphate, Na ascorbyl phosphate, sodium and magnesium ascorbate, disodium ascorbyl phosphate and sulfate, potassium ascorbyl tocopheryl phosphate, chitosan ascorbate or ascorbyl glucoside may be preferred.
  • the use of at least one member of the vitamin C group in combination with tocopherols and / or other members of the vitamin E group may also be preferred.
  • the vitamin E group includes tocopherol, especially ⁇ -tocopherol, and its derivatives.
  • Preferred derivatives are in particular the esters, such as tocopheryl acetate, tocopheryl nicotinate, phosphate, succinate, linoleate, oleate, tocophereth-5, tocophereth-10, tocophereth-12, tocophereth-18, tocophereth-50 and tocopherol.
  • Tocopherol and its derivatives are preferably contained in a total amount of 0.01 - 1 wt .-%, based on the total composition.
  • Vitamin A palmitate (retinyl palmitate), panthenol, pantolactone, nicotinamide, pyridoxine, pyridoxamine, pyridoxal, biotin, ascorbyl palmitate, acetate, Mg ascorbyl phosphate, Na ascorbyl phosphate, sodium and magnesium ascorbate and the tocopherol esters, especially tocopheryl acetate, are in accordance with the invention particularly preferred vitamin conditioners.
  • compositions according to the invention comprise at least one substance which is selected from the vitamins, provitamins and vitamin precursors of the group B 1 -B 2 , B 3 , B 6 , B 7 , B 9 , B 3 and their esters and / or Salts and from pantolactone.
  • compositions according to the invention contain as conditioning agents at least one vitamin, provitamin or a compound designated as vitamin precursor from the vitamin groups A, B, C and E and the esters, ethers and salts of these substances in a total amount of 0.01 to 5 Wt .-%, preferably from 0.25 to 4 wt .-% and in particular from 0.5 to 2.5 wt .-%, each based on the total weight of the composition according to the invention.
  • compositions according to the invention comprise at least two conditioning agents of mutually different conditioning agent groups c) i. to c) v.
  • Preferred mixtures of conditioning agents are
  • At least one oil and at least one cationic polymer at least one oil and at least one cationic polymer; at least one oil and at least one substance selected from vitamins, provitamins or compounds designated as vitamin precursors from the vitamin groups A, B, C and E and the esters, ethers and salts of these substances;
  • At least one polyol and at least one substance selected from vitamins, provitamins or compounds called vitamin precursors from the vitamin groups A, B, C and E and the esters, ethers and salts of these substances.
  • compositions preferred according to the invention furthermore contain at least one propellant selected from
  • CHF 2 CF CFCF 2 CF 3
  • CF 3 CF CFCF 2 CHF 2
  • CF 3 CF CFCHFCF 3
  • CHF CFCF (CF 3 ) 2
  • CHF CF (CF 2 ) 2 CHF 2
  • CH 2 C (CF 3 ) C 2 F 5
  • CF 2 CHCH (CF 3 ) 2
  • CHF CHCF (CF 3 ) 2
  • CH 2 CFCH (CF 3 ) 2
  • CHF CHCH (CF 3 ) 2
  • CH 2 FCH C (CF 3 ) 2
  • CH 3 CF C (CF 3 ) 2
  • CH 2 CHCF 2 CHFCF 3
  • CH 2 C (CF 3 ) CH 2 CF 3
  • (CF 3 ) 2 C CHC 2 F 5
  • CH 2 CHC (CF 3 ) 3
  • CF 3 CH CFCF 2 CF 2 CF 2 CF 3
  • CF 3 CF CHCF 2 CF 2 CF 2 CF 3
  • C 2 F 5 CH CFCF 2 CF 2 CF 3
  • CH 2 CBrCF 2 CF 2 CF 3
  • CF 2 C (CH 2 Br) CF 3
  • CH 2 C (CBrF 2 ) CF 3
  • CHCH CHBr
  • the amount of blowing agent is not taken into account in the weight data for the other components of the compositions according to the invention.
  • the propellant-free composition according to the invention is mixed with the entire propellant (propellant according to formula (I), in particular fluorocarbon or fluorohydrocarbon d) i) or d) ii) and optionally further propellants) in a composition / propellant weight ratio from 5/95 to 95/5, preferably 10/90 to 90/10, more preferably 15/85 to 85/15, most preferably 20/80 to 80/20, further preferably 30/70 to 70/30 and also 40/60 to 60/40 and 50 / 50, filled in a suitable aerosol spray can.
  • propellant propellant according to formula (I), in particular fluorocarbon or fluorohydrocarbon d) i) or d) ii) and optionally further propellants
  • the E-CF 3 CH CHF (E-1,3,3,3-tetrafluoropropene-1) is particularly preferably contained as sole blowing agent.
  • the fluorocarbon (s) or the fluorocarbon (s) d) i) or d) ii) in combination with at least one further blowing agent selected from propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, iso-pentane, iso-pentene, methane, ethane, dimethyl ether, nitrogen, air, oxygen, nitrous oxide, 1, 1, 1, 3-tetrafluoroethane, heptafluoro-n-propane, perfluoroethane, monochlorodifluoromethane, 1, 1 -difluoroethane, and mixtures of these blowing agents to use.
  • compositions of the invention are packaged with the propellant in a suitable pressure vessel.
  • a suitable pressure vessel As Druckg hereer come vessels made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is externally coated with plastic in question, in their selection pressure and fracture resistance, corrosion resistance, easy filling and aesthetic Aspects, handiness, printability etc. play a role.
  • Special internal protective lacquers ensure the corrosion resistance with respect to the suspension according to the invention.
  • An inner protective lacquer which is preferred according to the invention is a Epoxy Phenollack, as it is available, inter alia, under the name Hoba 7407 P.
  • valve plates can be internally z.
  • B. be coated with Micoflex paint. If tinplate valves are used according to the invention, their valve disks can be internally z. B. be coated with PET (polyethylene terephthalate).
  • compositions of the invention may also be packaged in a multi-chamber dispenser.
  • the multi-chamber dispenser can also be used so that one chamber is filled with the composition according to the invention, while another chamber contains the compressed propellant.
  • Such a multi-chamber dispenser is for example a so-called bag-in-can packaging.
  • compositions of the invention may contain other additives such as pH regulators, buffering agents, electrolytes, preservatives, chelating agents, antioxidants, thickeners, pigments, dyes, anti-wrinkle agents, active ingredients which increase skin moisture, e.g. As urea, alkyl-substituted ureas, betaine, or carnitine, plant extracts, alpha-hydroxycarboxylic acids, cooling agents such as menthol, menthyl lactate or isopulegol, fragrances and perfumes.
  • additives such as pH regulators, buffering agents, electrolytes, preservatives, chelating agents, antioxidants, thickeners, pigments, dyes, anti-wrinkle agents, active ingredients which increase skin moisture, e.g. As urea, alkyl-substituted ureas, betaine, or carnitine, plant extracts, alpha-hydroxycarboxylic acids, cooling agents such as menthol, menthyl lactate or iso
  • compositions according to the invention are cleaning foams, cleansing mousses, care foams, care mousses, creams, shaving foams, shaving gels, sun protection foams, sun protection mousses or so-called crackling foams, that is to say foams which break with noise.
  • compositions according to the invention are particularly preferred.
  • conditioning agents from different conditioning agent groups c) i. to c) v. are selected and
  • the shower and cleaning composition was in the weight ratio 94/6 with
  • Post-foaming shaving gels (in% by weight, without propellant)
  • Neosorb 70/70 B sorbitol (70% in water) Roquette Polyox WSR 301 PEG-90 M Amerchol
  • Sunscreen mousse water-in-oil emulsion
  • Sunscreen mousse water-in-oil emulsion
  • Phenonip® ME phenoxyethanol, methylparaben, ethylparaben (Clariant) 1, 0
  • Tego Betain® 810 Capryl / Capramidopropyl Betaine (Goldschmidt) 2.0
  • Citric acid 10% citric acid q.s.
  • Thistle oil 1, 0% by weight
  • Xanthan gum 1% by weight aqueous solution Water 49.0% by weight
  • a foam is formed which breaks with a clearly audible crackling, crackling noise when rubbed.
  • Facial care mousse no. 1 (leave on, quantities in% by weight)
  • Cutina MD (glycerol mono-adistearate, ex BASF / BASF) 1, 0
  • Facial care mousse No. (leave on, quantities in% by weight)

Abstract

L'invention concerne des compositions cosmétiques émulsifiantes pour le soin de la peau et du corps, qui se transforment en mousses sous l'action de fluorocarbures ou d'hydrocarbures fluorés sélectionnés comme agents moussants.
PCT/EP2011/073436 2010-12-23 2011-12-20 Composition cosmétique émulsifiante contenant des agents moussants pour le soin de la peau et du corps WO2012084970A1 (fr)

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EP11802402.5A EP2654667A1 (fr) 2010-12-23 2011-12-20 Composition cosmétique émulsifiante contenant des agents moussants pour le soin de la peau et du corps

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE201010055817 DE102010055817A1 (de) 2010-12-23 2010-12-23 Treibmittelhaltige verschäumbare kosmetische Zusammensetzung zur Haut- und Körperpflege
DE102010055817.6 2010-12-23

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WO2012084970A1 true WO2012084970A1 (fr) 2012-06-28

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EP (1) EP2654667A1 (fr)
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WO2016154275A1 (fr) 2015-03-23 2016-09-29 Edgewell Personal Care Brands Llc Compositions de rasage non-aérosol
US9949914B2 (en) 2015-04-23 2018-04-24 The Procter & Gamble Company Low viscosity hair care composition
US9949901B2 (en) 2015-04-23 2018-04-24 The Procter & Gamble Company Low viscosity hair care composition
WO2018075846A1 (fr) * 2016-10-21 2018-04-26 The Procter & Gamble Company Dosage de shampooing concentré de mousse désignant des avantages de conditionnement des cheveux
WO2018075850A1 (fr) * 2016-10-21 2018-04-26 The Procter & Gamble Company Dosage de mousse destiné à distribuer un volume de dosage et une quantité de tensioactif souhaités par un consommateur dans un espace de formulation optimal
WO2018075831A1 (fr) * 2016-10-21 2018-04-26 The Procter & Gamble Company Compositions de soins capillaires aérosol comprenant un agent moussant hfo et des solvants hydromiscibles
WO2018075845A1 (fr) * 2016-10-21 2018-04-26 The Procter & Gamble Company Shampooing à dosage concentrée de mousse pour améliorer le conditionnement des cheveux
US10311575B2 (en) 2016-03-23 2019-06-04 The Procter And Gamble Company Imaging method for determining stray fibers
CN109952131A (zh) * 2016-10-21 2019-06-28 宝洁公司 用于递送组合物和泡沫剂型特性有益效果的包含氢氟烯烃或氢氯氟烯烃的浓缩型洗发剂
CN110087733A (zh) * 2016-12-16 2019-08-02 宝洁公司 调理毛发的方法
US10426713B2 (en) 2017-10-10 2019-10-01 The Procter And Gamble Company Method of treating hair or skin with a personal care composition in a foam form
US10441519B2 (en) 2016-10-21 2019-10-15 The Procter And Gamble Company Low viscosity hair care composition comprising a branched anionic/linear anionic surfactant mixture
US10653590B2 (en) 2016-10-21 2020-05-19 The Procter And Gamble Company Concentrated shampoo dosage of foam for providing hair care benefits comprising an anionic/zwitterionic surfactant mixture
US10799434B2 (en) 2016-10-21 2020-10-13 The Procter & Gamble Company Concentrated shampoo dosage of foam for providing hair care benefits
JP2020536959A (ja) * 2017-10-10 2020-12-17 ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ コンパクトなシャンプー組成物
US10888505B2 (en) 2016-10-21 2021-01-12 The Procter And Gamble Company Dosage of foam for delivering consumer desired dosage volume, surfactant amount, and scalp health agent amount in an optimal formulation space
US10912732B2 (en) 2017-12-20 2021-02-09 The Procter And Gamble Company Clear shampoo composition containing silicone polymers
US11116705B2 (en) 2017-10-10 2021-09-14 The Procter And Gamble Company Compact shampoo composition containing sulfate-free surfactants
US11116703B2 (en) 2017-10-10 2021-09-14 The Procter And Gamble Company Compact shampoo composition containing sulfate-free surfactants
US11129783B2 (en) 2016-10-21 2021-09-28 The Procter And Gamble Plaza Stable compact shampoo products with low viscosity and viscosity reducing agent
US11141361B2 (en) 2016-10-21 2021-10-12 The Procter And Gamble Plaza Concentrated shampoo dosage of foam designating hair volume benefits
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US11224567B2 (en) 2017-06-06 2022-01-18 The Procter And Gamble Company Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel
US11291616B2 (en) 2015-04-23 2022-04-05 The Procter And Gamble Company Delivery of surfactant soluble anti-dandruff agent
US11318073B2 (en) 2018-06-29 2022-05-03 The Procter And Gamble Company Low surfactant aerosol antidandruff composition
US11357714B2 (en) 2020-07-21 2022-06-14 Chembeau LLC Diester cosmetic formulations and uses thereof
US11446217B2 (en) 2016-03-03 2022-09-20 The Procter & Gamble Company Aerosol antidandruff composition
US11464724B2 (en) 2018-11-08 2022-10-11 The Procter & Gamble Company Low shear stress conditioner composition with spherical gel network vesicles
US11679073B2 (en) 2017-06-06 2023-06-20 The Procter & Gamble Company Hair compositions providing improved in-use wet feel
US11679065B2 (en) 2020-02-27 2023-06-20 The Procter & Gamble Company Compositions with sulfur having enhanced efficacy and aesthetics
US11771635B2 (en) 2021-05-14 2023-10-03 The Procter & Gamble Company Shampoo composition
US11819474B2 (en) 2020-12-04 2023-11-21 The Procter & Gamble Company Hair care compositions comprising malodor reduction materials

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EP3491093A4 (fr) * 2016-07-28 2020-04-15 Honeywell International Inc. Agents propulseurs et compositions d'émulsification
WO2022156877A1 (fr) 2021-01-19 2022-07-28 Beiersdorf Ag Formulation de protéines

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US10864149B2 (en) 2015-03-23 2020-12-15 Edgewell Personal Care Brands, Llc Non-aerosol shaving compositions
US9949914B2 (en) 2015-04-23 2018-04-24 The Procter & Gamble Company Low viscosity hair care composition
US9949901B2 (en) 2015-04-23 2018-04-24 The Procter & Gamble Company Low viscosity hair care composition
US11291616B2 (en) 2015-04-23 2022-04-05 The Procter And Gamble Company Delivery of surfactant soluble anti-dandruff agent
US11446217B2 (en) 2016-03-03 2022-09-20 The Procter & Gamble Company Aerosol antidandruff composition
US10311575B2 (en) 2016-03-23 2019-06-04 The Procter And Gamble Company Imaging method for determining stray fibers
US11202740B2 (en) 2016-10-21 2021-12-21 The Procter And Gamble Company Concentrated shampoo dosage of foam for providing hair care benefits
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CN109952131A (zh) * 2016-10-21 2019-06-28 宝洁公司 用于递送组合物和泡沫剂型特性有益效果的包含氢氟烯烃或氢氯氟烯烃的浓缩型洗发剂
US11141361B2 (en) 2016-10-21 2021-10-12 The Procter And Gamble Plaza Concentrated shampoo dosage of foam designating hair volume benefits
US11129783B2 (en) 2016-10-21 2021-09-28 The Procter And Gamble Plaza Stable compact shampoo products with low viscosity and viscosity reducing agent
US10441519B2 (en) 2016-10-21 2019-10-15 The Procter And Gamble Company Low viscosity hair care composition comprising a branched anionic/linear anionic surfactant mixture
JP2019532964A (ja) * 2016-10-21 2019-11-14 ザ プロクター アンド ギャンブルカンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ 組成物及び泡用量の特性利点を送達するためのヒドロフルオロオレフィン又はヒドロクロロフルオロオレフィンを含む濃縮シャンプー
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