EP2654667A1 - Composition cosmétique émulsifiante contenant des agents moussants pour le soin de la peau et du corps - Google Patents

Composition cosmétique émulsifiante contenant des agents moussants pour le soin de la peau et du corps

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Publication number
EP2654667A1
EP2654667A1 EP11802402.5A EP11802402A EP2654667A1 EP 2654667 A1 EP2654667 A1 EP 2654667A1 EP 11802402 A EP11802402 A EP 11802402A EP 2654667 A1 EP2654667 A1 EP 2654667A1
Authority
EP
European Patent Office
Prior art keywords
chf
chcf
cfcf
acid
esters
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11802402.5A
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German (de)
English (en)
Inventor
Bernhard Banowski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
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Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP2654667A1 publication Critical patent/EP2654667A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A61K8/70—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine containing perfluoro groups, e.g. perfluoroethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q9/00—Preparations for removing hair or for aiding hair removal
    • A61Q9/02—Shaving preparations

Definitions

  • the present application relates to foamable cosmetic compositions for skin and body care, which are foamed with selected fluorocarbons or fluorocarbons as blowing agents.
  • Typical hydrocarbon blowing agents such as propane, n-butane and isobutane
  • propane, n-butane and isobutane have a low solubility in water
  • a polar blowing agent such as dimethyl ether
  • the foams produced with these blowing agents are in their quality, especially in terms of the stability or the rate of breakage, on the fine bubbles and the sensory properties in need of further improvement.
  • the present application was based on the object of providing a propellant-containing foamable cosmetic composition for skin and body care, which has improved properties compared to the compositions of the prior art, in particular with regard to the foam stability, the fine bubbles and the sensory properties.
  • a propellant selected from unsaturated fluorocarbons and unsaturated fluorohydrocarbons, as well as mixtures thereof, the prior art mousse compositions can be optimized, particularly with regard to foam stability, fine bubbles and sensory properties.
  • the present application relates to foamable cosmetic compositions containing
  • conditioning agents from different conditioning agent groups c) i. to c) v. are selected and
  • At least one blowing agent selected from at least one compound having 3 to 10 carbon atoms according to formula (I)
  • radicals R, R 2 , R 3 and R 4 independently of one another, denote a hydrogen atom, a bromine atom, a fluorine atom or a (CT - C 6 ) -alkyl group substituted by at least one fluorine atom,
  • R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom
  • R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom
  • At least one of the radicals R, R 2 , R 3 or R 4 is a substituted with at least one fluorine atom (C ⁇ to C 6 ) alkyl group.
  • normal conditions are a temperature of 20 ° C. and a pressure of 1013.25 mbar. Melting point data likewise relate to a pressure of 1013.25 mbar.
  • the surfactant content of the compositions according to the invention is 0.1 to 30% by weight, preferably 0.5 to 25% by weight, more preferably 1 to 20% by weight, most preferably 2 to 15% by weight, based in each case on the total weight of the blowing agent-free composition.
  • surfactant contents may also be preferred.
  • a surfactant content for cleansing compositions that only remain on the skin or hair during the cleansing process and are then rinsed off, may be a surfactant content of 6 to 30 wt .-%, moreover from 9 to 18 wt .-% or 1 1 - 14 wt .-%, each based on the total weight of the blowing agent-free composition, be preferred.
  • a surfactant content for cleansing compositions that only remain on the skin or hair during the cleansing process and are then rinsed off, may be a surfactant content of 6 to 30 wt .-%, moreover from 9 to 18 wt .-% or 1 1 - 14 wt .-%, each based on the total weight of the blowing agent-free composition, be preferred.
  • leave on compositions such as creams, lotions or facewashes
  • emulsifiers are also added to the surfactants.
  • Suitable anionic surfactants in compositions according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic Tensid- classes are, in each case in the form of the sodium, potassium and ammonium and the mono-, di- and Trialkanolammoniumsalze with 2 to 4 C-atoms in the alkanol group:
  • R6 OCH 2 CH 2
  • n -0-P-OR7 II in the R preferred for an aliphatic hydrocarbon radical having 8 to 30 carbon atoms
  • R 7 is hydrogen, a radical (CH 2 CH 2 0) n R 6 or X
  • n is from 1 to 10
  • X is hydrogen, an alkali or Alkaline earth metal or NR 8 R 9 R 0 R 11 , with R 8 to R
  • Protein hydrolyzate fatty acid condensates are prepared by condensation of C8 - C30 fatty acids, preferably fatty acids having 12 - 18 C atoms with amino acids, mono-, di- and water-soluble oligopeptides and mixtures of such products as obtained in the hydrolysis of proteins.
  • These protein hydrolyzate-fatty acid condensation products are neutralized with a base and are then preferably present as alkali, ammonium, mono-, di- or Trialkanolammoniumsalz;
  • Acylglutamates which are condensation products of glutamic acid and C 8 -C 30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms, and which are present in neutralized form as K, Na or ammonium salt, and
  • Acyl aspartates which condensation products of aspartic acid and C8 - C30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms and which are present in neutralized form as K, Na or ammonium salt.
  • Preferred anionic surfactant classes are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acid salts having 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfosuccinic acid mono- and dialkyl esters having 8 to 18 C atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups, citric acid esters with fatty alcohol ethoxylates, such as the product sold under the trade name "Plantapon LC-7"
  • Preferred surfactants of the class alkyl polyglycol ether sulfates are sodium trideceth sulfates, for example those sold under the trade name "Miracare SLB 365", “Genapol XRO" or "Rhodapex
  • Zwitterionic surfactants are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO () or -SO 3 () group in the molecule.
  • Particularly suitable zwitterionic surfactant classes are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkylbenzenesulfonate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.
  • Amphoteric surfactants are understood as meaning those surface-active compounds which, apart from a C 8 -C 24 -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and are capable of forming internal salts
  • Examples of preferred ampholytic surfactant classes are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, amphoacetates, in particular cocoamphoacetates, lauroamphoacetates, olivamphoacetates, amphopropionates, in particular cocoamphopropionates, Amphodiacetates, in particular cocoamphodiacetates, lauroamphodiacetates, capryloamphodiacetates, amphodipropionates, in particular cocoampho
  • Phosphatidylcholines having the general structural formula shown below are the main constituent of lecithin.
  • the substituents R and R 2 in the structural formula below represent linear aliphatic alkyl radicals having from 7 to 21 carbon atoms, preferably from 1 to 19 carbon atoms, more preferably from 15 to 17 carbon atoms, which may have up to four Z-configured double bonds. More preferably, R CO and R 2 CO are independently selected from palmitoyl, stearoyl, oleoyl, linoloyl and linolenoyl.
  • ampholytic surfactants are cocoamphoacetates, lauroamphoacetates, cocoamphodiacetates, lauroamphodiacetates and capryloamphodiacetates.
  • amphoteric and / or zwitterionic surfactants are in the compositions of the invention - based on the total weight of the propellant-free composition - in a total amount of 0.01 to 20 wt .-%, preferably in a total amount of 0.05 to 18 wt .-%, particularly preferably used in a total amount of 0.1 to 15 wt .-% and in particular in a total amount of 0.5 to 10 wt .-%.
  • Hydroxy mixed ethers as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and addition products of ethylene oxide onto sorbitan fatty acid esters, for example the polysorbates,
  • Alkyl polyglycosides having x values of 1.1 to 2.0 are preferred. Very particular preference is given to alkyl glycosides in which x is 1: 1 to 1, 8.
  • the alkoxylated homologs of said alkylpolyglycosides can also be used according to the invention. These homologs may contain on average up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.
  • Preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83.
  • the alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.
  • compositions according to the invention contain at least the following surfactant class mixture: alkylpolyglycol ether sulfate / betaine, alkylpolyglycol ether sulfate / sulfosuccinic acid monoalkylpolyoxyethyl ester, alkylpolyglycol ether sulfate / alkylpolyglycoside as aforesaid, alkylpolyglycol ether sulfate / amphoacetate, alkylpolyglycol ether sulfate / amphodiacetate, alkylpolyglycol ether sulfate / adduct of from 5 to 60 moles of ethylene oxide hydrogenated castor oil, sulfosuccinic acid mono-alkyl polyoxyethyl
  • compositions according to the invention preferably contain as surfactant at least one nonionic oil-in-water emulsifier having an HLB value of more than 7.
  • HLB (100-L): 5 where L is the weight fraction of the lipophilic groups, that is, the fatty alkyl or fatty acyl groups, in the ethylene oxide adducts, expressed in weight percent.
  • nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to optimally adjust the properties of compositions according to the invention.
  • compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols with an average of 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 - 100 moles of ethylene oxide per mole, silicone copolyols having ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs, ethoxylated sterols, partial esters of polyglycerols having 2 to 10 glycerol units and esterified with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues, provided that they have an HLB value of more than 7, and mixtures of the a
  • the ethoxylated C 8 -C 24 alkanols have the formula R 0 (CH 2 CH 2 0) n H, where R is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide Units per molecule, for numbers from 10 to 100, preferably 10 to 30, moles of ethylene oxide to 1 mole of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol , Arachylalkohol, Gadoleylalkhol, behenyl, erucyl alcohol and brassidyl alcohol and their technical mixtures. Also, adducts of 10-100 mo
  • the ethoxylated C 8 -C 24 carboxylic acids have the formula R (OCH 2 CH 2 ) n OH, where R is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide units per Molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, gadoleic acid, Behenic acid, erucic acid and brassidic acid as well as their technical mixtures.
  • Adducts of 10 to 100 moles of ethylene oxide with technical fatty acids containing 12 to 18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are also suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.
  • C 8 -C 22 -alkyl mono- and -oligoglycosides preference is given to using C 8 -C 22 -alkyl mono- and -oligoglycosides.
  • C 8 -C 22 -alkylmono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms.
  • the glycoside radical monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable.
  • the degree of oligomerization is a statistical mean, which is based on a homolog distribution typical for such technical products. Products which are obtainable under the trademark Plantacare ®, containing a glucosidic bond C 8 -C 6 - alkyl group at an oligoglucoside whose average degree of oligomerization at 1 - 2, in particular 1, 1 - 1, 4, is located.
  • Particularly preferred C 8 -C 22 alkyl mono- and oligoglycosides are selected from octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof.
  • the glucamine-derived acylglucamides are also suitable as nonionic oil-in-water emulsifiers.
  • Ethoxylated sterols, in particular ethoxylated soy sterols are also suitable oil-in-water emulsifiers according to the invention.
  • the degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7.
  • Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.
  • partial esters of polyglycerols having 2 to 10 glycerol units and having 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 -C 30 fatty acid radicals are preferably esterified, if they have an HLB value of more than 7 ,
  • Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol are rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetragly- cerinmonocaprylat, rinmonocaprat Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce-, hexa glycerol, Hexaglycerin
  • organosiloxane-oxyalkylene copolymers are selected from organosiloxane-oxyalkylene copolymers.
  • Particularly preferred organosiloxane-oxyalkylene copolymers according to the invention are selected from linear polysiloxane-polyoxyalkylene block copolymers, in particular from linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymers.
  • Extremely preferred according to the invention is a linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer having the INCI name PEG / PPG-22/24 dimethicones and CAS no. 64365-23-7.
  • organosiloxane-oxyalkylene copolymer O / W emulsifiers are selected from compounds of the general structural formulas (I), (II), (III), (IV) and (V),
  • radicals R 3 and R 4 independently of one another represent a linear or branched CC 6 -alkyl group and preferably methyl groups,
  • C 1 -C 4 -alkyl group and preferably represent a hydrogen atom or a methyl group, m represents a number from 0-20,
  • n a number from 0 - 500
  • 0 represents a number from 0 - 20
  • p represents a number from 1 to 50
  • a represents a number from 0-50
  • b represents a number from 0-50
  • c is a number from 1 to 4, more preferably 3,
  • x represents a number from 1 to 100.
  • organosiloxane-oxyalkylene copolymer is, for example available under the trade designation Dow Corning 193 (INCI: PEG-12 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Silwet L-77.
  • organosiloxane-oxyalkylene copolymer is, for example available under the trade designation Dow Corning Q2-5220 (INCI: PEG / PPG-17/18 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is, for example available under the trade name Abil B 88184 (INCI: PEG / PPG-20/6 Dimethicone).
  • compositions according to the invention are characterized in that at least one oil-in-water emulsifier, preferably at least one nonionic oil-in-water emulsifier, in a total amount of 0.5-10 wt.%, Preferably 1-9 wt %, more preferably 1.5-8.5% by weight, most preferably 2-8% by weight, and also 2.5, 3, 3.5, 4.0, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, and 8 wt .-%, based on the propellant-free total composition is included.
  • compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.
  • Such esters or partial esters are, for.
  • Sterols ie steroids which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol) and from fungi and yeasts (mycosterols) which may be low ethoxylated (1-5 EO);
  • Alkanols and carboxylic acids each having 8-24 C atoms, in particular having 16-22 C atoms, in the alkyl group and 1-4 ethylene oxide units per molecule which have an HLB value of greater than 1.0, and less than or equal to 7.0 exhibit,
  • Partial esters of polyglycerols with n 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues esterified, if they have an HLB value of less than or equal to 7,
  • compositions contain at least one water-in-oil emulsifier in a total amount of 0.01 to 4 wt .-%, preferably 0.1 to 3 wt .-%, particularly preferably 0.5 to 1 wt .-% ,
  • phospholipids and lecithins are among the surfactants, not the conditioners.
  • compositions of the invention are free of cyclomethicones.
  • volatile non-silicone oil In addition to or instead of the at least one volatile silicone oil, it is also possible for at least one volatile non-silicone oil to be present.
  • volatile non-silicone oils are selected from C 8 -C 6 -isoalkanes, in particular from isodecane, isododecane, isotetradecane and isohexadecane and mixtures thereof.
  • non-volatile non-silicone oils which are preferred according to the invention are selected from the benzoic acid esters of linear or branched C 8 . 22 -alkanols. Particularly preferred are benzoic C12-C15 alkyl esters, z. B. available as a commercial product Finsolv ® TN, benzoic isostearylester, z. B. available as a commercial product Finsolv ® SB, ethylhexyl benzoate, z. B. available as a commercial product Finsolv ® EB, and Benzoekladyldocecylester, z. B. available as a commercial product Finsolv ® BOD.
  • benzoic C12-C15 alkyl esters z. B. available as a commercial product Finsolv ® TN
  • benzoic isostearylester z. B. available as a commercial product Finsolv ® SB
  • ethylhexyl benzoate z. B. available
  • Such benzoic acid ester oils have a pleasant feel on the skin.
  • Further non-volatile non-silicone oils which are preferred according to the invention are selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms. These alcohols are also often referred to as Guerbet alcohols, as they are obtainable by the Guerbet reaction.
  • Preferred oils are alcohol 2-hexyldecanol (Eutanol ® G 16) 2-octyldodecanol (Eutanol ® G) and 2-ethylhexyl alcohol.
  • non-volatile non-silicone oils are chosen from mixtures of Guerbet alcohols and Guerbet alcohol esters, for example the commercial product Cetiol ® PGL (hexyldecanol and hexyldecyl laurate).
  • Further non-volatile non-silicone oils which are preferred according to the invention are selected from the triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 . 30- fatty acids.
  • Particularly suitable may be the use of natural oils, for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, rapeseed oil, olive oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like.
  • natural oils for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, rapeseed oil, olive oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like.
  • synthetic triglyceride oils in particular Capric / Caprylic triglycerides, with unbranched fatty acid residues and z.
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated.
  • these include hexyldecyl (z. B. Eutanol ® G 16 S), hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, and 2-ethylhexyl stearate, in particular 2-ethylhexyl palmitate.
  • non-volatile non-silicone oils are selected from the addition products of 1 to 5 propylene oxide units of mono- or polyhydric C 8 _ 22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (z. B. Wtconol ® APM).
  • mono- or polyhydric C 8 _ 22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (z. B. Wtconol ® APM).
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the adducts of at least 6 ethylene oxide and / or propylene oxide units with monovalent or polyvalent C 3 . 22 -alkanols such as glycerol, butanol, butanediol, myristyl alcohol and stearyl alcohol, which may be esterified if desired, for.
  • PPG-14 butyl ether z. B. Ucon ® fluid AP
  • PPG-9-butyl ether z. B. Breox B25 ®
  • PPG-10 butanediol z. B. Macol ® 57
  • PPG 15- stearyl ether z. B. Arlamol ® e
  • Glycereth-7-diisononanoate As PPG-14 butyl ether (z. B. Ucon ® fluid AP), PPG-9-butyl ether (z. B. Bre
  • non-volatile non-silicone oils are selected from the C 2 -C 22 fatty alcohol esters of monohydric or polyhydric C 2 -C 7 hydroxycarboxylic acids, in particular the esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and Salicylic acid.
  • esters based on linear C 2 / i 5-alkanols and branched in 2-position C 2 / i 3-alkanols are preferably selected from C 2 -C 5 alkyl lactate, di-C 12-13 -alkyl malate and tri-C 12 -13 alkyl citrate, e.g. B. available under the trademark Cosmacol ® from Nordmann, Rassmann GmbH & Co, Hamburg.
  • Another such preferred oil component is triethyl citrate.
  • non-volatile non-silicone oils are selected from the symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, eg. B. dicaprylyl or the esters according to the teaching of DE 19756454 A1.
  • compositions according to the invention are characterized in that the conditional liquid conditioner is selected from volatile silicone oils, nonvolatile silicone oils, volatile hydrocarbon oils, branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 .
  • compositions according to the invention comprise at least one oil as conditioning agent in a total amount of from 0.1 to 35% by weight, preferably from 0.5 to 25% by weight, more preferably from 1 to 15% by weight and most preferably from 2 to 8% by weight .-%, in each case based on the total weight of the composition according to the invention.
  • solid wax components can be used as conditioners even under normal conditions.
  • Particularly preferred wax components are selected from coconut oil acid glycerol mono-, di- and triesters, Butyrospermum Parkii (Shea butter) and esters of saturated, monohydric C 8 -C 8 alcohols with saturated C 2 -C 8 monocarboxylic acids and mixtures of these substances.
  • Further preferred esters of saturated, monohydric C 2 -C 8 -alcohols with saturated C 2 -C 8 -monocarboxylic acids are stearyl laurate, cetearyl stearate, cetyl palmitate and myristyl myristate.
  • Conditioning agents which are preferred according to the invention are also vegetable waxes, eg. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. As beeswax, shellac wax and spermaceti, hydrogenated or hardened waxes, chemically modified waxes, especially the hard waxes, such as.
  • vegetable waxes eg. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. As beeswax, shellac wax and spermaceti, hydrogenated or hardened waxes, chemically modified waxes, especially the hard waxes, such as.
  • a particularly preferred wax component is selected from at least one ester of a saturated, monohydric C 6 -C 60 -alcohol and a saturated C 8 -C 36 -monocarboxylic acid.
  • lactides the cyclic double esters of alpha-hydroxycarboxylic acids of the corresponding chain length.
  • wax components are the triglycerides of saturated and optionally hydroxylated C 2 -3o fatty acids, such as hardened triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryltri-12-hydroxystearate, furthermore synthetic full esters of fatty acids and glycols or Polyols with 2-6 carbon atoms.
  • hydrogenated castor oil is particularly preferred as the wax component.
  • Further preferred wax components are the saturated linear C 4 -C 36 -fatty alcohols, in particular myristyl alcohol, palmityl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol and behenyl alcohol, and also mixtures of these compounds.
  • organic UV filter substance is poly silicone-15, also known as dimethicodiethylbenzalmalonate, Diethylbenzylidene malonates Dimethicone or Diethylmalonylbenzylidene referred Oxypropene Dimethicone and (under the trade name Parsol ® SLX INCI name Dimethicodiethylbenzal malonate (CAS no. 207574-74- 1)) available from DSM.
  • Further inventively suitable organic UV filter substances are selected from the derivatives of benzimidazole sulfonic acid.
  • salts in particular the alkali, alkaline earth, ammonium, alkylammonium, alkanolamine and glucammonium salts, preferably the corresponding sodium, potassium, trialkylammonium or triethanolamine salts, furthermore the Salts of this acid with amino-CrCe-alkanols and amino-C Ce-alkanediols, in particular with 2-amino-2-methylpropan-1-ol, 2-amino-2-methyl-propane-1, 3-diol, 2-aminopropane 1 -ol, 3-aminopropan-1-ol and 1-aminopropan-2-ol (MIPA), the salts with 2-amino-2-methylpropan-1 -o l and 2-amino-2-methylpropane-1, 3-diol are particularly preferred, but especially the salts of 2-phenylbenzimidazole-5-sulfonic acid with sodium ions and with 2-amino
  • organic UV filter substances are selected from alkyl- and / or alkoxy-substituted Dibenzoylmethanderivaten.
  • Alkyl and / or alkoxy-substituted dibenzoylmethane derivatives which are preferred according to the invention are characterized in that one of the phenyl radicals has at least one alkyl group selected from methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, n -Pentyl, isopentyl, neopentyl, 2-ethylhexyl, and the other phenyl radical having at least one alkoxy group selected from methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, sec-butoxy, tert-butoxy, n-pentoxy, Isopentoxy, neopentoxy, 2-ethylhex
  • 4-tert-butyl-4'-Methoxydibenzoyl- methane with the INCI name butyl methoxydibenzoylmethane (also as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1, 3-dione), an oil-soluble organic sunscreen.
  • Further conditioning agents preferred according to the invention are selected from cationic polymers. It has surprisingly been found that a cationic polymer in combination with a fluorocarbon or fluorohydrocarbon blowing agent according to the invention can lead to a particularly stable foam.
  • Cationic polymers preferred according to the invention are selected from quaternized hydroxyethyl cellulose polymers which contain cationic trimethylammonium and dimethyldodecylammonium groups as substituents. Such polymers preferably contain a grouping of the following formula:
  • a particularly suitable homopolymer is, if desired crosslinked, poly (methacryloyl oxyethyltrimethylammoniumchlorid) with the INCI name Polyquaternium-37.
  • Such products are available, for example under the names Rheocare ® CTH (Cosmetic Rheologies) and Synthalen® ® CR (3V Sigma) in trade.
  • copolymers of vinylpyrrolidone as commercial products copoly mer 845 (manufactured by ISP), are Gaffix ® VC 713 (manufactured by ISP), Gafquat ® ASCP 101 1, Gafquat ® HS 1 10, Luviquat ® 8155 and Luviquat ® MS 370 are available.
  • Homopolymers or copolymers containing quaternary nitrogen groups either in the polymer chain or, preferably, as a substituent on one or more of the monomers, Homopolymers or copolymers of monomers containing ammonium groups, copolymers of monomers containing ammonium groups with cationic monomers different therefrom, which are preferably selected from ammonium-substituted vinyl monomers and quaternary vinylammonium monomers with cyclic, cationic nitrogen-containing groups such as pyridinium, imidazolium or quaternary pyrrolidones,
  • cationic derivatives of polysaccharides preferably cationic derivatives of cellulose, starch or guar,
  • Chitosan and chitosan derivatives in particular the salts of chitosan, such as chitosan lactate and
  • compositions according to the invention are characterized in that the at least one cationic polymer in a total amount of 0.02 to 4 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.5 to 1 wt .-% , in each case based on the total weight of the composition according to the invention.
  • Further conditioning agents preferred according to the invention are selected from anionic polymers. It has surprisingly been found that an anionic polymer in combination with a fluorocarbon or fluorohydrocarbon blowing agent according to the invention can lead to a particularly stable foam.
  • Further conditioning agents preferred according to the invention are selected from amphoteric polymers. It has surprisingly been found that an amphoteric polymer in combination with a fluorocarbon or fluorohydrocarbon blowing agent according to the invention can lead to a particularly stable foam.
  • amphoteric polymers includes both those polymers which contain in the molecule both free amino groups and free -COOH or S0 3 H groups and which are capable of forming internal salts, as well as zwitterionic polymers which in the molecule have quaternary ammonium groups and -COO contain " - or -S0 3 " groups, and summarized those polymers containing -COOH or S0 3 H groups and quaternary ammonium groups.
  • amphopolymer is the acrylic resin commercially available as Amphomer ®, which is a copolymer of tert-butylaminoethyl methacrylate, N- (1, 1, 3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group of acrylic acid, Represents methacrylic acid and its simple esters.
  • amphoteric polymers which are preferred according to the invention are the compounds mentioned in British Patent Application 2,104,091, European Published Application 47,714, European Published Application 217,274, European Offenlegungsschrift 283,817 and German Offenlegungsschrift 28 17 369.
  • Preferred amphoteric polymers are those polymers which consist essentially of one another
  • R 22 -CH CR 23 -CO-Z- (C n H 2n ) -N (+) R 24 R 25 R 26 A () (IV)
  • R 22 and R 23 independently of one another are hydrogen or a methyl group and R 24 , R 25 and R 26 independently of one another are alkyl groups having 1 to 4 carbon atoms, Z is an NH group or an oxygen atom, n is an integer from 2 to 5 and A (_) is the anion of an organic or inorganic acid
  • R 27 and R 28 are independently hydrogen or methyl groups.
  • These compounds can be used both directly and in salt form, which is obtained by neutralization of the polymers, for example with an alkali metal hydroxide, according to the invention.
  • alkali metal hydroxide an alkali metal hydroxide
  • R 27 and R 28 are independently hydrogen or methyl groups.
  • These compounds can be used both directly and in salt form, which is obtained by neutralization of the polymers, for example with an alkali metal hydroxide, according to the invention.
  • a (_) is a halide, methoxysulfate or ethoxysulfate Ion is; Acrylamidopropyl trimethyl ammonium chloride is a particularly preferred monomer (a).
  • Acrylic acid is preferably used as monomer (b) for the stated polymers.
  • compositions according to the invention are characterized in that the at least one amphoteric polymer in a total amount of 0.01 to 3.5 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.2 - 0.8 % By weight, based in each case on the total weight of the composition according to the invention.
  • Further conditioning agents preferred according to the invention are selected from nonionic polymers. It has surprisingly been found that a nonionic polymer in combination with a fluorocarbon or fluorohydrocarbon blowing agent according to the invention can lead to a particularly stable foam.
  • preferred nonionic polymers are selected from cellulose ethers, especially hydroxyalkylcelluloses, in particular hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, gelatin, casein, guar gums and locust bean gum, in particular guar gum.
  • hydroxyalkylcelluloses in particular hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, gelatin, casein, guar gums and locust bean gum, in particular guar gum.
  • Gum and Locust Bean Gum themselves and the nonionic Hydroxyalkylguarderivaten and locust bean gum derivatives such as Hydroxyproppylguar, Carboxymethylhydroxypropylguar, Hydroxypropylmethylguar, Hydroxyethylguar and Carboxymethylguar, Taragummi, polyvinylpyrrolidones, polyvinyl alcohols, polyacrylamides, polyurethanes, polyurethane copolymers and vinylpyrrolidone / vinyl ester copolymers.
  • Hydroxyalkylguarderivaten and locust bean gum derivatives such as Hydroxyproppylguar, Carboxymethylhydroxypropylguar, Hydroxypropylmethylguar, Hydroxyethylguar and Carboxymethylguar, Taragummi, polyvinylpyrrolidones, polyvinyl alcohols, polyacrylamides, polyurethanes, polyurethane copolymers and vinylpyrrolidone
  • compositions according to the invention are characterized in that the at least one nonionic polymer in a total amount of 0.01 to 3.5 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.2 - 1, 2 % By weight, based in each case on the total weight of the composition according to the invention.
  • Further conditioning agents preferred according to the invention are selected from at least one vitamin, provitamin or a compound designated as vitamin precursor from the vitamin groups A, B, C and E and the esters, ethers and salts of these aforementioned substances.
  • the group of substances designated as vitamin A includes retinol (vitamin A and 3,4-didehydroretinol (vitamin A 2 ) .beta.-carotene is the provitamin of retinol.)
  • the vitamin A component is, for example, vitamin A acid and their esters, vitamin A aldehyde and vitamin A alcohol, and also esters thereof, such as retinyl palmitate and retinyl acetate.
  • the compositions according to the invention contain at least one vitamin A component preferably in a total amount of 0.01 to 1 wt .-%, based on the total composition.
  • the vitamin B group or the vitamin B complex include, among others
  • Vitamin B ⁇ trivial name thiamine, chemical name 3 - [(4 '-amino-2' -methyl-5 '-pyrimidi- nyl) methyl] -5- (2-hydroxyethyl) -4-methylthiazolium chloride.
  • Thiamine hydrochloride is preferably used in amounts of from 0.01 to 1% by weight, based on the total composition.
  • Vitamin B 2 common name riboflavin, chemical name 7,8-dimethyl-10- (1-D-ribityl) - benzo [g] pteridine-2,4 (3 / - /, 10 / - /) - dione.
  • riboflavin or its derivatives are used in a total amount of 0.01 to 1 wt .-%, based on the total composition.
  • Vitamin B 3 the compounds nicotinic acid and nicotinamide (niacinamide) are performed.
  • Preferred according to the invention is the nicotinic acid amide, which is preferably present in the compositions according to the invention in amounts of from 0.01 to 1% by weight, based on the total composition.
  • Vitamin B 5 pantothenic acid and panthenol.
  • Panthenol is preferably used.
  • Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and also cationically derivatized panthenols.
  • derivatives of 2-furanone instead of and in addition to pantothenic acid or panthenol, it is also possible to use derivatives of 2-furanone having the general structural formula (VIT-I).
  • the 2-furanone derivatives in which the substituents R to R 6 independently of one another are a hydrogen atom, a hydroxyl radical, a methyl, methoxy, aminomethyl or hydroxymethyl radical, a saturated or mono- or diunsaturated, linear or branched C C 2 -C 4 -hydrocarbon radical, a saturated or mono- or diunsaturated, branched or linear mono-, di- or trihydroxy-C 2 -C 4 -hydrocarbon radical or a saturated or mono- or diunsaturated, branched or linear mono-, Di- or triamino-C 2 -C 4 - hydrocarbon radical represent.
  • the substituents R to R 6 independently of one another are a hydrogen atom, a hydroxyl radical, a methyl, methoxy, aminomethyl or hydroxymethyl radical, a saturated or mono- or diunsaturated, linear or branched C C 2 -C 4 -hydrocarbon radical, a saturated or mono- or diunsatur
  • Particularly preferred derivatives are the commercially available substances dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone with the trivial name pantolactone (Merck), 4-hydroxymethyl- ⁇ -butyrolactone (Merck), 3,3 Dimethyl 2-hydroxy- ⁇ -butyrolactone (Aldrich) and 2,5-dihydro-5- methoxy-2-furanone (Merck), expressly including all stereoisomers.
  • the inventively extraordinarily preferred 2-furanone derivative is pantolactone (dihydro-3-hydroxy-4,4-dimethyl-2 (3H) -furanone), wherein in formula (VIT-I) R is a hydroxyl group, R 2 is is a hydrogen atom, R 3 and R 4 are a methyl group, and R 5 and R 6 are a hydrogen atom.
  • the stereoisomer (R) -pantolactone is formed during the degradation of pantothenic acid.
  • the said compounds of the vitamin B 5 type as well as the 2-furanone derivatives are preferably in the compositions according to the invention in a total amount of 0.01 to 5 wt .-%, particularly preferably 0.1 to 3 wt .-%, most preferably 0, 5 to 2 wt .-%, each based on the total composition.
  • Vitamin B 6 which is understood hereunder no uniform substance, but the known under the common names pyridoxine, pyridoxamine and pyridoxal derivatives of 5-hydroxymethyl-2-methylpyridin-3-ols.
  • Vitamin B 6 is contained in the compositions according to the invention preferably in amounts of 0.0001 to 1, 0 wt .-%, in particular in amounts of 0.001 to 0.01 wt .-%.
  • Biotin also known as vitamin H or "skin vitamin”.
  • Biotin is (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] imidazole-4-valeric acid.
  • Biotin is preferably present in the compositions according to the invention in amounts of from 0.0001 to 1.0% by weight, in particular in amounts of from 0.001 to 0.01% by weight.
  • Folic acid (Vitamin B 9 , Vitamin B c ). International generic name for N- [4- (2-amino-3,4-dihydro-4-oxo-6-pteridinylmethylamino) -benzoyl] -L-glutamic acid (N-pteroyl-L-glutamic acid, PteGlu). Folate is used synonymously with pteroylglutamate. Folate is the generic term for all folic acid-active compounds and refers to a class of compounds containing a pteridine ring linked to 4-aminobenzoic acid and L-glutamic acid.
  • Folic acid is a growth factor for various microorganisms and a compound with vitamin character, which is usually found in nature as polyglutamate and in reduced form (7,8-dihydrofolic acid, H 2 folate, DHF, tetrahydrofolic acid, H 4 folate, THF, 5'-methyl Tetrahydrofolic acid, CH 3 -H 4 folate, MeTHF).
  • Particularly preferred compositions according to the invention are characterized in that they contain at least one component selected from folic acid, folates and their esters, in a total amount of 0.0001 to 1.0% by weight, in particular 0.01 to 0.5% by weight. %, based on the composition.
  • Orotic acid (vitamin B 3 , 1, 2,3,6-tetrahydro-2,6-dioxo-4-pyrimidine-carboxylic acid, uracil-6-carboxylic acid, molar acid).
  • Orotic acid, its choline ester or orotic acid metal salts (orotates of Ca, Cr, Fe, K, Co, Cu, Li, Mg, Mn, Na, Zn, Sn) are particularly preferred according to the invention.
  • Particularly preferred compositions according to the invention are characterized in that they contain at least one component selected from orotic acid, orotates and their esters, in a total amount of 0.0001-1.0% by weight, in particular 0.01-0.5% by weight. %, based on the composition.
  • the vitamin C group includes vitamin C (ascorbic acid) and its derivatives, in particular the esters of ascorbic acid with organic and inorganic acids and their salts, and the acetals with glucose or other sugars, in particular ascorbyl glucoside.
  • Vitamin C and / or at least one of its derivatives is preferably used in a total amount of 0.01 to 3 wt .-%, based on the total composition.
  • the use of the derivatives ascorbyl palmitate, stearate, dipalmitate, acetate, Mg ascorbyl phosphate, Na ascorbyl phosphate, sodium and magnesium ascorbate, disodium ascorbyl phosphate and sulfate, potassium ascorbyl tocopheryl phosphate, chitosan ascorbate or ascorbyl glucoside may be preferred.
  • the use of at least one member of the vitamin C group in combination with tocopherols and / or other members of the vitamin E group may also be preferred.
  • the vitamin E group includes tocopherol, especially ⁇ -tocopherol, and its derivatives.
  • Preferred derivatives are in particular the esters, such as tocopheryl acetate, tocopheryl nicotinate, phosphate, succinate, linoleate, oleate, tocophereth-5, tocophereth-10, tocophereth-12, tocophereth-18, tocophereth-50 and tocopherol.
  • Tocopherol and its derivatives are preferably contained in a total amount of 0.01 - 1 wt .-%, based on the total composition.
  • Vitamin A palmitate (retinyl palmitate), panthenol, pantolactone, nicotinamide, pyridoxine, pyridoxamine, pyridoxal, biotin, ascorbyl palmitate, acetate, Mg ascorbyl phosphate, Na ascorbyl phosphate, sodium and magnesium ascorbate and the tocopherol esters, especially tocopheryl acetate, are in accordance with the invention particularly preferred vitamin conditioners.
  • compositions according to the invention comprise at least one substance which is selected from the vitamins, provitamins and vitamin precursors of the group B 1 -B 2 , B 3 , B 6 , B 7 , B 9 , B 3 and their esters and / or Salts and from pantolactone.
  • compositions according to the invention contain as conditioning agents at least one vitamin, provitamin or a compound designated as vitamin precursor from the vitamin groups A, B, C and E and the esters, ethers and salts of these substances in a total amount of 0.01 to 5 Wt .-%, preferably from 0.25 to 4 wt .-% and in particular from 0.5 to 2.5 wt .-%, each based on the total weight of the composition according to the invention.
  • compositions according to the invention comprise at least two conditioning agents of mutually different conditioning agent groups c) i. to c) v.
  • Preferred mixtures of conditioning agents are
  • At least one oil and at least one cationic polymer at least one oil and at least one cationic polymer; at least one oil and at least one substance selected from vitamins, provitamins or compounds designated as vitamin precursors from the vitamin groups A, B, C and E and the esters, ethers and salts of these substances;
  • At least one polyol and at least one substance selected from vitamins, provitamins or compounds called vitamin precursors from the vitamin groups A, B, C and E and the esters, ethers and salts of these substances.
  • compositions preferred according to the invention furthermore contain at least one propellant selected from
  • CHF 2 CF CFCF 2 CF 3
  • CF 3 CF CFCF 2 CHF 2
  • CF 3 CF CFCHFCF 3
  • CHF CFCF (CF 3 ) 2
  • CHF CF (CF 2 ) 2 CHF 2
  • CH 2 C (CF 3 ) C 2 F 5
  • CF 2 CHCH (CF 3 ) 2
  • CHF CHCF (CF 3 ) 2
  • CH 2 CFCH (CF 3 ) 2
  • CHF CHCH (CF 3 ) 2
  • CH 2 FCH C (CF 3 ) 2
  • CH 3 CF C (CF 3 ) 2
  • CH 2 CHCF 2 CHFCF 3
  • CH 2 C (CF 3 ) CH 2 CF 3
  • (CF 3 ) 2 C CHC 2 F 5
  • CH 2 CHC (CF 3 ) 3
  • CF 3 CH CFCF 2 CF 2 CF 2 CF 3
  • CF 3 CF CHCF 2 CF 2 CF 2 CF 3
  • C 2 F 5 CH CFCF 2 CF 2 CF 3
  • CH 2 CBrCF 2 CF 2 CF 3
  • CF 2 C (CH 2 Br) CF 3
  • CH 2 C (CBrF 2 ) CF 3
  • CHCH CHBr
  • the amount of blowing agent is not taken into account in the weight data for the other components of the compositions according to the invention.
  • the propellant-free composition according to the invention is mixed with the entire propellant (propellant according to formula (I), in particular fluorocarbon or fluorohydrocarbon d) i) or d) ii) and optionally further propellants) in a composition / propellant weight ratio from 5/95 to 95/5, preferably 10/90 to 90/10, more preferably 15/85 to 85/15, most preferably 20/80 to 80/20, further preferably 30/70 to 70/30 and also 40/60 to 60/40 and 50 / 50, filled in a suitable aerosol spray can.
  • propellant propellant according to formula (I), in particular fluorocarbon or fluorohydrocarbon d) i) or d) ii) and optionally further propellants
  • the E-CF 3 CH CHF (E-1,3,3,3-tetrafluoropropene-1) is particularly preferably contained as sole blowing agent.
  • the fluorocarbon (s) or the fluorocarbon (s) d) i) or d) ii) in combination with at least one further blowing agent selected from propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, iso-pentane, iso-pentene, methane, ethane, dimethyl ether, nitrogen, air, oxygen, nitrous oxide, 1, 1, 1, 3-tetrafluoroethane, heptafluoro-n-propane, perfluoroethane, monochlorodifluoromethane, 1, 1 -difluoroethane, and mixtures of these blowing agents to use.
  • compositions of the invention are packaged with the propellant in a suitable pressure vessel.
  • a suitable pressure vessel As Druckg hereer come vessels made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is externally coated with plastic in question, in their selection pressure and fracture resistance, corrosion resistance, easy filling and aesthetic Aspects, handiness, printability etc. play a role.
  • Special internal protective lacquers ensure the corrosion resistance with respect to the suspension according to the invention.
  • An inner protective lacquer which is preferred according to the invention is a Epoxy Phenollack, as it is available, inter alia, under the name Hoba 7407 P.
  • valve plates can be internally z.
  • B. be coated with Micoflex paint. If tinplate valves are used according to the invention, their valve disks can be internally z. B. be coated with PET (polyethylene terephthalate).
  • compositions of the invention may also be packaged in a multi-chamber dispenser.
  • the multi-chamber dispenser can also be used so that one chamber is filled with the composition according to the invention, while another chamber contains the compressed propellant.
  • Such a multi-chamber dispenser is for example a so-called bag-in-can packaging.
  • compositions of the invention may contain other additives such as pH regulators, buffering agents, electrolytes, preservatives, chelating agents, antioxidants, thickeners, pigments, dyes, anti-wrinkle agents, active ingredients which increase skin moisture, e.g. As urea, alkyl-substituted ureas, betaine, or carnitine, plant extracts, alpha-hydroxycarboxylic acids, cooling agents such as menthol, menthyl lactate or isopulegol, fragrances and perfumes.
  • additives such as pH regulators, buffering agents, electrolytes, preservatives, chelating agents, antioxidants, thickeners, pigments, dyes, anti-wrinkle agents, active ingredients which increase skin moisture, e.g. As urea, alkyl-substituted ureas, betaine, or carnitine, plant extracts, alpha-hydroxycarboxylic acids, cooling agents such as menthol, menthyl lactate or iso
  • compositions according to the invention are cleaning foams, cleansing mousses, care foams, care mousses, creams, shaving foams, shaving gels, sun protection foams, sun protection mousses or so-called crackling foams, that is to say foams which break with noise.
  • compositions according to the invention are particularly preferred.
  • conditioning agents from different conditioning agent groups c) i. to c) v. are selected and
  • the shower and cleaning composition was in the weight ratio 94/6 with
  • Sunscreen mousse water-in-oil emulsion
  • Xanthan gum 1% by weight aqueous solution Water 49.0% by weight

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Abstract

L'invention concerne des compositions cosmétiques émulsifiantes pour le soin de la peau et du corps, qui se transforment en mousses sous l'action de fluorocarbures ou d'hydrocarbures fluorés sélectionnés comme agents moussants.
EP11802402.5A 2010-12-23 2011-12-20 Composition cosmétique émulsifiante contenant des agents moussants pour le soin de la peau et du corps Withdrawn EP2654667A1 (fr)

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DE201010055817 DE102010055817A1 (de) 2010-12-23 2010-12-23 Treibmittelhaltige verschäumbare kosmetische Zusammensetzung zur Haut- und Körperpflege
PCT/EP2011/073436 WO2012084970A1 (fr) 2010-12-23 2011-12-20 Composition cosmétique émulsifiante contenant des agents moussants pour le soin de la peau et du corps

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US9949901B2 (en) 2015-04-23 2018-04-24 The Procter & Gamble Company Low viscosity hair care composition
WO2016172406A1 (fr) 2015-04-23 2016-10-27 The Procter & Gamble Company Composition de soins capillaires à faible viscosité
JP6813586B2 (ja) 2016-03-03 2021-01-13 ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ エアゾールフケ防止組成物
EP3432776B1 (fr) 2016-03-23 2023-03-29 The Procter & Gamble Company Procédé d'imagerie permettant de déterminer des fibres éparses
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