WO2012081130A1 - Composition de nettoyage en poudre pour machines de nettoyage automatisées - Google Patents

Composition de nettoyage en poudre pour machines de nettoyage automatisées Download PDF

Info

Publication number
WO2012081130A1
WO2012081130A1 PCT/JP2010/073074 JP2010073074W WO2012081130A1 WO 2012081130 A1 WO2012081130 A1 WO 2012081130A1 JP 2010073074 W JP2010073074 W JP 2010073074W WO 2012081130 A1 WO2012081130 A1 WO 2012081130A1
Authority
WO
WIPO (PCT)
Prior art keywords
mass
component
acid
automatic
cleaning composition
Prior art date
Application number
PCT/JP2010/073074
Other languages
English (en)
Japanese (ja)
Inventor
斉藤慎也
吉川清章
鈴木信行
Original Assignee
花王株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 花王株式会社 filed Critical 花王株式会社
Publication of WO2012081130A1 publication Critical patent/WO2012081130A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/12—Carbonates bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/02—Inorganic compounds
    • C11D7/04—Water-soluble compounds
    • C11D7/10—Salts
    • C11D7/14—Silicates

Definitions

  • the present invention relates to a powder cleaning composition used in an automatic cleaning machine for cleaning hard articles. More particularly, the present invention relates to a powder cleaning composition for an automatic cleaning machine used for cleaning hard articles such as kitchen utensils and plastic containers for food and beverage processing. Background art
  • Automatic washing machines are used for washing dishes such as dirty dishes, glasses and cooking utensils in kitchens such as homes, restaurants, and coffee shops, and washing plastic containers for foodstuffs and products used in food and beverage factories.
  • Main target soils include food-derived proteins, starches, oils and fats, and these soils are combined and adhered to dishes, glasses, tableware such as cooking utensils, and plastic containers.
  • these stains may be heat-denatured to become strong stains and be fixed.
  • heat-denatured oil is a difficult-to-clean stain, and there is a need for a cleaning agent that removes this stain.
  • the washing process using an automatic washing machine is performed in the order of washing and rinsing.
  • the time required for these processes is as short as 40 to 60 seconds for the washing process and 5 to 20 seconds for the rinsing process. It is.
  • alkali metal hydroxides, carbonates, and silicate alkali agents are used in powder detergent compositions for automatic washing machines in order to efficiently wash these strong stains in a short time.
  • alkali metal hydroxides are preferably used from the viewpoint of detergency.
  • alkali metal hydroxides have deliquescent properties, so that handling properties are inferior, and when mixed with 5% or more, they are handled as deleterious substances, so there are restrictions on their use.
  • tap water and well water containing hardness components such as Ca ions and Mg ions are often used for washing, and these hardness components and detergent-derived carbonate radicals, silicate radicals, and carbonates in the atmosphere are used.
  • the gas reacts to form products such as calcium carbonate, magnesium carbonate, calcium silicate, magnesium silicate. Since this product is insoluble in water, it adheres to tableware, tanks of automatic washing machines, tank walls, etc., and forms a strong film called scale. As a result, it causes troubles such as a decrease in thermal efficiency of the heat exchange unit, blockage of the circulation pump, malfunction of the concentration sensor, and the like.
  • a detergent composition for an automatic dishwasher containing one or more alkali agents, a polymer substance having a metal ion scavenging ability, and a bleaching agent is disclosed (for example, Japanese Patent Laid-Open No. Hei 8). -199194). Summary of invention
  • the present invention relates to a polymer selected from (a) polyacrylic acid or a salt thereof, and a copolymer of acrylic acid and maleic acid or a salt thereof (hereinafter referred to as component (a)) of 8% by mass or more, (b) metasilicic acid Containing 10 to 90% by mass of a silicate selected from a salt and an orthosilicate (hereinafter referred to as component (b)), and (c) a carbonate (hereinafter referred to as component (c)), and (b) (C)
  • component (a)) of 8% by mass or more 8% by mass or more
  • component (b) metasilicic acid Containing 10 to 90% by mass of a silicate selected from a salt and an orthosilicate
  • component (c) a carbonate
  • the present invention relates to a powder detergent composition for automatic washing machine for hard articles, wherein the total amount of carbonate is 35 to 92% by mass.
  • Japanese Patent Application Laid-Open No. 8-199194 discloses that an alkali metal hydroxide is not substantially used, that is, an alkali metal hydroxide is not used at all, or physical properties and product stability due to deliquescence, etc. Is not sufficient to achieve both a high cleaning property and a high scale adhesion inhibiting effect.
  • the powder cleaning composition for an automatic cleaning machine for hard articles means a powder cleaning composition used for cleaning hard articles such as dishes, cooking utensils, and plastic containers with an automatic cleaning machine.
  • the present invention substantially eliminates alkali metal hydroxides in washing dishes such as dirty dishes, glasses and cooking utensils in kitchens, washing food containers used in food and beverage factories, and plastic containers for products.
  • the powder cleaning composition for automatic washing machines of the hard article which has the high washing
  • the powder cleaning composition for an automatic cleaning machine of the present invention contains, as component (a), a polymer selected from polyacrylic acid or a salt thereof and a copolymer of acrylic acid and maleic acid or a salt thereof.
  • a polymer selected from polyacrylic acid or a salt thereof examples include polyacrylic acid, sodium polyacrylate, potassium polyacrylate, and the like. Sodium polyacrylate and potassium polyacrylate are preferred, and a copolymer of acrylic acid and maleic acid or a salt thereof.
  • the molar ratio of the copolymer of acrylic acid and maleic acid is preferably 99/1 to 1/99, more preferably 90/10 to 10/90, as the number of moles of acrylic acid / number of moles of maleic acid.
  • the component (a) of the present invention is a monomer other than acrylic acid and maleic acid and can be copolymerized with acrylic acid and / or maleic acid as long as the effects of the present invention are not hindered. It may be a copolymer.
  • monomers other than acrylic acid and maleic acid that can be copolymerized with acrylic acid and / or maleic acid include vinyl monomers, acrylic monomers, styrene monomers, and more specifically methacrylic monomers. Examples include acid, methyl acrylate, ethyl acrylate, methyl methacrylate, and styrene.
  • the molar ratio in the component (a) of the monomer other than acrylic acid and maleic acid, which can be copolymerized with acrylic acid and / or maleic acid, is the property of the present invention such as water solubility or the like of the present invention. Although it is not limited as long as it does not affect the expression of the effect, it is preferably 0 to 5 mol%, more preferably 0 to 3 mol%, and most preferably 0 mol% in the component (a). Therefore, the polyacrylic acid of the present invention or a salt thereof, and a copolymer of acrylic acid and maleic acid or a salt thereof are monomers other than acrylic acid and maleic acid among all constituent monomers, and are acrylic acid and / or maleic acid. It may be a polymer or copolymer containing a monomer copolymerizable with 0 to 5 mol%.
  • maleic anhydride is used as the maleic acid in the copolymerization reaction when the component (a) is produced. Therefore, the above molar ratios may be based on maleic anhydride.
  • the weight average molecular weight of the component (a) is preferably 1,000 to 100,000, more preferably 2,000 to 90,000, from the viewpoint of the scale adhesion inhibiting effect.
  • This weight average molecular weight is a polyacrylic acid (for example, sigma), which is a commercially available polymer standard reagent having a molecular weight known by gel permeation chromatography using a mixed solvent of acetonitrile and water (phosphate buffer solution) as a developing solvent. Aldrich molecular weight standard reagent) was obtained as a standard substance.
  • the powder detergent composition for automatic washing machines of the present invention contains an inorganic silicate selected from metasilicates and orthosilicates as the component (b).
  • the component (b) include alkali metal metasilicates and alkali metal orthosilicates, and further include sodium metasilicate, potassium metasilicate, sodium orthosilicate, potassium orthosilicate, and the like. Therefore, sodium orthosilicate and sodium metasilicate are preferred.
  • alkali metal metasilicates and alkali metal orthosilicates can be used as the component (b) of the present invention.
  • the molar ratio of the constituent silicic acid and the alkali metal oxide is the mol of silicic acid.
  • the number / number of moles of alkali metal oxide is preferably 0.3 to 1.2, and more preferably 0.5 to 1.0.
  • the number of moles of SiO 2 / number of moles of Na 2 O is preferably 0.3 to 1.2, and more preferably 0.5 to 1. 0.
  • the powder cleaning composition for an automatic cleaning machine of the present invention contains a carbonate as the component (c).
  • the component (c) include alkali metal carbonates, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate and the like. From the viewpoint of detergency, sodium carbonate and potassium carbonate are preferable, especially scale. From the viewpoints of adhesion suppression effect, detergency, solubility, and cost, the combined use of sodium carbonate and potassium carbonate is more preferable.
  • the mass ratio of sodium carbonate to potassium carbonate is not particularly limited, but is preferably 1 to 10 and more preferably 2 to 5 as the mass of sodium carbonate / the mass of potassium carbonate.
  • the powder cleaning composition for an automatic cleaning machine of the present invention preferably contains an organic chelating agent as the component (d) from the viewpoints of detergency and scale adhesion inhibiting effect.
  • component (d) aminocarboxylates such as tetrasodium ethylenediaminetetraacetate, trisodium methylglycine diacetate, tetrasodium L-glutamate diacetate, (d2) trisodium citrate, disodium malate, Examples thereof include hydroxycarboxylates such as sodium tartrate, and preferably at least one selected from the group consisting of tetrasodium ethylenediaminetetraacetate, trisodium methylglycine diacetate, tetrasodium L-glutamate diacetate, and trisodium citrate. .
  • the powder cleaning composition for an automatic cleaning machine of the present invention contains the above components (a) to (c) and, if necessary, the component (d), and may further contain other components.
  • the content of the component (a) in the powder cleaning composition for an automatic cleaning machine of the present invention is 8% by mass or more, 10% by mass or more, and further 20% by mass from the viewpoints of detergency and scale adhesion inhibiting effect.
  • the above is preferable.
  • an upper limit is not specifically limited, 40 mass% or less is preferable from a viewpoint of a scale adhesion inhibitory effect and cost, and 30 mass% or less is more preferable.
  • the content of the component (b) in the powder cleaning composition for an automatic cleaning machine of the present invention is 10 to 90% by mass.
  • the lower limit is 10% by mass or more, preferably 12% by mass or more, and more preferably 25% by mass or more from the viewpoint of detergency.
  • the upper limit is 90% by mass or less, preferably 70% by mass or less, and more preferably 60% by mass or less, from the viewpoint of the scale adhesion inhibiting effect.
  • the content of the component (c) in the powder cleaning composition for an automatic cleaning machine of the present invention is preferably 5% by mass or more from the viewpoint of detergency.
  • an upper limit is not specifically limited, From a viewpoint of the scale adhesion inhibitory effect, 50 mass% or less is preferable and 40 mass% or less is more preferable.
  • the total amount of the components (b) and (c) in the powder cleaning composition for an automatic cleaning machine of the present invention is 35 to 92% by mass from the viewpoint of detergency, and 35 to 90%. % By mass is preferable, 35 to 80% by mass is more preferable, and 40 to 80% by mass is still more preferable.
  • the mass ratio of the component (b) to the component (c) in the powder cleaning composition for an automatic cleaning machine of the present invention is the mass of the component (b) / (c )
  • the mass of the component is preferably 0.6 to 45, more preferably 0.6 to 7, and still more preferably 1 to 3.
  • the ratio of the mass of the component (b) and the total mass of the component (c) to the mass of the component (a) is the detergency and scale adhesion suppression.
  • the mass of [(b) component + (c) component] / (a) component is preferably 0.5-7, more preferably 1-6, and even more preferably 2-5. .
  • the content of the component (d) in the powder cleaning composition for an automatic cleaning machine of the present invention is preferably 1 to 50% by mass, more preferably 10 to 40% by mass, from the viewpoints of detergency and scale adhesion inhibiting effect. .
  • the powder cleaning composition for an automatic cleaning machine of the present invention includes, as necessary, mirabilite, surfactant, bleach, enzyme, antifoaming agent, preservative, Rusts, bactericides, antibacterial agents, pigments, fragrances, hydrotropes and the like can be blended.
  • a nonionic surfactant As the surfactant blended in the powder cleaning composition for an automatic cleaning machine of the present invention, a nonionic surfactant, an anionic surfactant, a cationic surfactant, or an amphoteric surfactant may be used depending on the purpose. However, a nonionic surfactant is preferable from the viewpoint of detergency.
  • Nonionic surfactants that can be used in the present invention are not particularly limited.
  • polyoxyethylene alkyl ether polyoxyethylene polyoxypropylene alkyl ether, polyoxyalkylene dialkyl ether, polyoxyethylene alkenyl ether, polyoxyethylene Alkylene alkyl phenyl ether, Pluronic block polymer, Tetronic block polymer, Reverse pluronic block polymer, Reverse tetronic block polymer, Sucrose fatty acid ester, Sorbitan fatty acid ester, Polyethylene glycol fatty acid ester, Glycerin fatty acid ester, Polyglycerin fatty acid ester , Propylene glycol fatty acid ester, polypropylene glycol fatty acid ester, coconut fatty acid di Examples include: tanolamide, lauric acid diethanolamide, lauric acid mytilinic acid diethanolamide, myristylic acid diethanolamide, oleic acid diethanolamide, palm kernel fatty acid diethanolamide, al
  • polyoxyethylene polyoxypropylene alkyl ether pluronic block polymer, tetronic block polymer, reverse pluronic block polymer, and reverse tetronic block polymer are preferable.
  • nonionic surfactants may be used alone or in combination of two or more.
  • the content of the nonionic surfactant is 0.1 to 10% by mass, and 0.5 to 5% by mass is more preferable from the viewpoint of the balance between detergency and other components and economical efficiency.
  • the powder cleaning composition for an automatic cleaning machine of the present invention is used for an automatic cleaning machine for hard articles.
  • the hard article is an article mainly including a member having a hard surface, and includes an article having a size, shape, and material suitable for cleaning by an automatic washing machine.
  • the soft member may be partially contained.
  • Specific examples of the hard article include tableware, cooking utensils, and plastic containers.
  • the automatic washing machine can use suitably the apparatus suitable for the automatic washing
  • the automatic washing machine can use suitably the apparatus suitable for the automatic washing
  • the powder cleaning composition for an automatic cleaning machine of the present invention can be a so-called phosphorus-free composition that does not contain a phosphorus-containing compound.
  • the powder cleaning composition for an automatic cleaning machine of the present invention has a pH of 10 to 13, more preferably 11 to 12 at 25 ° C. in a 0.1% by weight aqueous solution from the viewpoint of cleaning properties and substrate damage properties. preferable.
  • a powder cleaning composition for an automatic cleaning machine having the composition shown in Tables 1 and 2 was prepared, and the scale adhesion inhibiting ability and the cleaning ability were evaluated by the following methods. The results are shown in Tables 1 and 2.
  • ⁇ Evaluation method> 62 g of the powder cleaning composition for automatic washing machines shown in Tables 1 and 2 is put into a washing tank (62 L) of an automatic dishwashing machine (SANIJET SD113EA6) manufactured by Nippon Washing Machine Co., Ltd., and dissolved in warm water at 65 ° C. It was.
  • SANIJET SD113EA6 automatic dishwashing machine manufactured by Nippon Washing Machine Co., Ltd.
  • Four polypropylene dishes coated with model dirt were set on a dedicated rack, washed with a cleaning solution at 65 ° C. for 45 seconds, and then rinsed with rinsing water at 85 ° C. for 10 seconds.
  • the polypropylene dish was taken out from the dedicated rack, and the washability was visually judged by 10 researchers according to the following criteria, and the score was averaged to give an evaluation score.
  • ⁇ Criteria for cleaning performance> 7 No staining marks are observed on any of the four polypropylene dishes, and the dirt is removed. 6: Most stains are observed only on one of the four polypropylene dishes. 5; Most of the stains are removed to the extent that a slight coloring mark is observed on two of the four polypropylene dishes. 4; A slight coloring mark is shown on three of the four polypropylene dishes. Most of the dirt has been removed 3); almost all the dirt has been removed to the extent that slight staining marks are observed on all four polypropylene dishes 2; all four polypropylene dishes have been removed Color marks are observed, and about half of the dirt remains; all four polypropylene dishes have color marks, and most of the dirt remains. If the score is 3 or more Good.
  • A-1 Sodium salt of polyacrylic acid (weight average molecular weight 4,000, Socaran PA25CL Granules (manufactured by BASF Japan Ltd.): raw material information from the product catalog of BASF Japan Ltd.)

Abstract

L'invention porte sur une composition de nettoyage en poudre pour des machines automatisées qui nettoient des articles durs, qui contient (a) 8 % en masse ou plus d'un polymère choisi parmi le poly(acide acrylique) et les sels de celui-ci et les copolymères de l'acide acrylique avec l'acide maléique et les sels de celui-ci, (b) 10-90 % en masse d'un silicate choisi parmi les métasilicates et les orthosilicates et (c) un carbonate, le total du silicate (b) et du carbonate (c) étant de 35-92 % en masse.
PCT/JP2010/073074 2010-12-17 2010-12-22 Composition de nettoyage en poudre pour machines de nettoyage automatisées WO2012081130A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2010281228A JP5788671B2 (ja) 2010-12-17 2010-12-17 自動洗浄機用粉末洗浄剤組成物
JP2010-281228 2010-12-17

Publications (1)

Publication Number Publication Date
WO2012081130A1 true WO2012081130A1 (fr) 2012-06-21

Family

ID=46244256

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2010/073074 WO2012081130A1 (fr) 2010-12-17 2010-12-22 Composition de nettoyage en poudre pour machines de nettoyage automatisées

Country Status (3)

Country Link
JP (1) JP5788671B2 (fr)
TW (1) TW201226554A (fr)
WO (1) WO2012081130A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109652236A (zh) * 2019-01-21 2019-04-19 广州森波化工科技有限公司 一种玻璃清洗粉剂及其制备方法和使用方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50151906A (fr) * 1974-03-06 1975-12-06
EP0504091A1 (fr) * 1991-03-15 1992-09-16 Cleantabs A/S Composition pour le lavage machinal de la vaisselle sans phosphate
JP2004204055A (ja) * 2002-12-25 2004-07-22 Adeka Clean Aid Co Ltd 洗浄剤組成物
JP2006183026A (ja) * 2004-11-30 2006-07-13 Kumano Yushi Kk 固形洗浄剤
JP2007522922A (ja) * 2004-01-22 2007-08-16 ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン 洗剤、漂白剤、ならびに食器洗い機および食器手洗い用洗剤のための水沈殿軟化系
JP2008050410A (ja) * 2006-08-22 2008-03-06 Diversey Ip Internatl Bv 自動食器洗浄機用粒状洗浄剤組成物およびその製法、並びにその使用方法
WO2008048537A1 (fr) * 2006-10-16 2008-04-24 Danisco Us, Inc. Genencor Division Détergents de vaisselle sans phosphate

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10316999A (ja) * 1997-05-15 1998-12-02 Kao Corp 洗浄剤組成物
JP5331550B2 (ja) * 2009-04-10 2013-10-30 ライオン株式会社 高嵩密度粒状洗剤組成物およびその製造方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS50151906A (fr) * 1974-03-06 1975-12-06
EP0504091A1 (fr) * 1991-03-15 1992-09-16 Cleantabs A/S Composition pour le lavage machinal de la vaisselle sans phosphate
JP2004204055A (ja) * 2002-12-25 2004-07-22 Adeka Clean Aid Co Ltd 洗浄剤組成物
JP2007522922A (ja) * 2004-01-22 2007-08-16 ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチエン 洗剤、漂白剤、ならびに食器洗い機および食器手洗い用洗剤のための水沈殿軟化系
JP2006183026A (ja) * 2004-11-30 2006-07-13 Kumano Yushi Kk 固形洗浄剤
JP2008050410A (ja) * 2006-08-22 2008-03-06 Diversey Ip Internatl Bv 自動食器洗浄機用粒状洗浄剤組成物およびその製法、並びにその使用方法
WO2008048537A1 (fr) * 2006-10-16 2008-04-24 Danisco Us, Inc. Genencor Division Détergents de vaisselle sans phosphate

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109652236A (zh) * 2019-01-21 2019-04-19 广州森波化工科技有限公司 一种玻璃清洗粉剂及其制备方法和使用方法

Also Published As

Publication number Publication date
JP2012126857A (ja) 2012-07-05
JP5788671B2 (ja) 2015-10-07
TW201226554A (en) 2012-07-01

Similar Documents

Publication Publication Date Title
KR101952567B1 (ko) 제형, 식기세척용 세제로서의 또는 이를 제조하기 위한 이의 용도, 및 이의 제조
US8709990B2 (en) Formulations, their use as or for producing dishwashing detergents and their production
US9732309B2 (en) Formulations, their use as or for producing dishwashing detergents and their production
US9994797B2 (en) Formulations, preparation thereof, and use thereof as, or for preparing, dishwashing compositions
RU2629112C2 (ru) Композиции, их применение в качестве или для получения средств для мытья посуды и их получение
KR20160030256A (ko) 식기 세정 방법
MX2014013009A (es) Formulaciones, su uso como o para la producir detergentes lavavajillas y su produccion.
WO2013175659A1 (fr) Composition de détergent pour lave-vaisselle automatiques
JP5770465B2 (ja) 自動洗浄機用粉末洗浄剤組成物
JP6235120B2 (ja) 処方物、食器用洗剤としてのそれらの使用方法、又は食器用洗剤の製造のためのそれらの使用方法、及びそれらの製造
JP5719077B1 (ja) 食器洗浄機用液体洗浄剤組成物
JP5890193B2 (ja) 自動洗浄機用粉末洗浄剤組成物
JP5788671B2 (ja) 自動洗浄機用粉末洗浄剤組成物
JP5604337B2 (ja) 食器洗浄機用液体洗浄剤組成物
JP2010047730A (ja) 食器洗浄機用洗浄剤組成物
JP6570331B2 (ja) 食器洗浄機用液体洗浄剤組成物
JP2003171689A (ja) 粉末漂白洗浄剤組成物
BR112019011182A2 (pt) composição detergente de lavagem automática de louça.
JP5753412B2 (ja) 食器洗浄機用液体洗浄剤組成物
US9074162B1 (en) Detergent compositions comprising vinylidene diphosphonic acid polymers
JP2012111810A (ja) 自動洗浄機用粉末洗浄剤組成物
TW201321498A (zh) 調配物、其作為或用於製造洗碗精之用途及其製備

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10860652

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 10860652

Country of ref document: EP

Kind code of ref document: A1