WO2012063157A1 - A tack free decorative ink composition comprising an aziridine derivative and a polyethylene / paraffin wax mixture, process and use thereof - Google Patents
A tack free decorative ink composition comprising an aziridine derivative and a polyethylene / paraffin wax mixture, process and use thereof Download PDFInfo
- Publication number
- WO2012063157A1 WO2012063157A1 PCT/IB2011/054796 IB2011054796W WO2012063157A1 WO 2012063157 A1 WO2012063157 A1 WO 2012063157A1 IB 2011054796 W IB2011054796 W IB 2011054796W WO 2012063157 A1 WO2012063157 A1 WO 2012063157A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- dispersion
- acrylic resin
- composition
- aziridine
- aqueous
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 71
- 238000000034 method Methods 0.000 title claims abstract description 10
- -1 polyethylene Polymers 0.000 title claims description 45
- 239000004698 Polyethylene Substances 0.000 title claims description 33
- 229920000573 polyethylene Polymers 0.000 title claims description 33
- 239000012188 paraffin wax Substances 0.000 title claims description 32
- 150000001541 aziridines Chemical class 0.000 title 1
- 239000001913 cellulose Substances 0.000 claims abstract description 16
- 229920002678 cellulose Polymers 0.000 claims abstract description 16
- 229920003023 plastic Polymers 0.000 claims abstract description 11
- 239000004033 plastic Substances 0.000 claims abstract description 11
- 239000006185 dispersion Substances 0.000 claims description 93
- 239000004925 Acrylic resin Substances 0.000 claims description 58
- 229920000178 Acrylic resin Polymers 0.000 claims description 58
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 35
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 claims description 32
- 235000019809 paraffin wax Nutrition 0.000 claims description 31
- 235000019271 petrolatum Nutrition 0.000 claims description 31
- 239000001993 wax Substances 0.000 claims description 30
- 239000000126 substance Substances 0.000 claims description 27
- 229920003015 aliphatic polyurethane dispersion Polymers 0.000 claims description 21
- 239000000049 pigment Substances 0.000 claims description 21
- 239000000758 substrate Substances 0.000 claims description 21
- 239000004408 titanium dioxide Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 11
- 239000004815 dispersion polymer Substances 0.000 claims description 11
- 229920000728 polyester Polymers 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 10
- 229920002125 Sokalan® Polymers 0.000 claims description 9
- 239000004584 polyacrylic acid Substances 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 239000004814 polyurethane Substances 0.000 claims description 8
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 claims description 6
- 229920006243 acrylic copolymer Polymers 0.000 claims description 6
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 6
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 6
- 230000002209 hydrophobic effect Effects 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 235000010755 mineral Nutrition 0.000 claims description 6
- 239000012860 organic pigment Substances 0.000 claims description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 6
- 229920000151 polyglycol Polymers 0.000 claims description 6
- 239000010695 polyglycol Substances 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- 229910052844 willemite Inorganic materials 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 5
- 239000004202 carbamide Substances 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- 229920005862 polyol Polymers 0.000 claims description 4
- 150000003077 polyols Chemical class 0.000 claims description 4
- 239000011686 zinc sulphate Substances 0.000 claims description 4
- 235000009529 zinc sulphate Nutrition 0.000 claims description 4
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- DKNPRRRKHAEUMW-UHFFFAOYSA-N Iodine aqueous Chemical compound [K+].I[I-]I DKNPRRRKHAEUMW-UHFFFAOYSA-N 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 238000007647 flexography Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000000976 ink Substances 0.000 description 13
- 230000000007 visual effect Effects 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000011111 cardboard Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/12—Printing inks based on waxes or bitumen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
Definitions
- the present invention relates to a composition of a decorative ink used on sheets and/or reels of cellulose and/or plastic in the field of the graphic arts.
- the present invention also relates to a process for obtaining such composition and its use.
- the present inventors have previously developed a new product laminated with cellulose that overcame
- compositions as described in the above mentioned model, on sheets and reels of cellulose and/or plastic materials is especially designed for graphic arts as graphic finishes, for advertising in paper products with high added value, in which base materials are used, in particular cellulose or plasticized cellulose and/or plastic material, of high cost.
- a first object of the present invention is to provide a composition of a decorative ink overcoming the drawbacks indicated in the previous section.
- This composition of a decorative ink is one that comprises a compound derived from aziridine and a combination of polyethylene waxes and paraffin waxes, in which the compound derived from aziridine is between 0.1 and 1.5% by weight, preferably between 0.35 and 1.5% by weight, and said combination of polyethylene waxes and paraffin waxes is between 0.1 and 3% by weight, preferably between 0.5 and 2% by weight, with regard to the total weight of the composition.
- the solvent used is Said composition further comprises one or more of following components:
- Dispossion in the present invention refers to a fluid in whose mass a body in suspension or in colloidal state is evenly contained.
- said fluid is preferably water, but it can also be any other non aqueous solvent.
- Resin in the present invention refers to a complex organic substance with a melting point not defined in which the solvent solution forms the binding proportion of the flexographic ink.
- Compound derived from aziridine in the present invention refers to aziridine-based compounds which include a diluent and a moisturizing agent as dispersing agents .
- Polyethylene waxes in the present invention refers to polyethylene of very low molecular weight, slightly branched, with melting temperatures of 100 to 130°C. They are more effective than paraffin waxes.
- “Laminated polyester” in the present invention refers to cut polyester sheets.
- Acrylic resin polymer dispersion with a pigment in the present invention refers to a dispersion of acrylic-based resin in which a pigment has been dispersed (organic or inorganic) preferably in an aqueous medium.
- Polyacrylic acid dispersion in the present invention refers to a dispersion containing a solvent, preferably water, and polyacrylic acid.
- Aliphatic polyurethane dispersion in the present invention refers to a dispersion containing a solvent, preferably water, and aliphatic polyurethane, which is an acyclic organic compound with open-chain molecular structure .
- Woodemite mineral dispersion in acrylic resin dispersion refers to a dispersion containing a solvent, preferably water, and a Willemite mineral, which in turn is inside an acrylic resin .
- Acrylic resin dispersion of titanium dioxide in the present invention refers to a dispersion containing an acrylic resin and titanium dioxide.
- “Expanding product dispersion in an acrylic base” in the present invention refers to a dispersion of an expanding product in an acrylic base.
- Piglescent pigment dispersion in acrylic resin refers to a dispersion containing a pearlescent pigment, (a concept known in the industry and publications and also known as pearl sheen) and acrylic resin
- Tianium dioxide dispersion in the present invention refers to a dispersion containing a solvent, preferably water, and titanium dioxide.
- Organic pigment dispersion in the present invention refers to a dispersion containing a solvent, preferably water, and organic pigments.
- “Inflatable dispersion in acrylic resin” in the present invention refers to a dispersion of an inflatable product (flexible outer membrane structure containing a gas inside) in acrylic resin.
- Said components can be found in any proportion in the composition provided that the two essential components (a compound derived from aziridine and a combination of polyethylene waxes and paraffin waxes) are included and the total weight is 100%.
- composition disclosed herein for decorative inks is construed as that said composition is used itself as a decorative ink.
- a second object of the present invention relates to a process for the manufacture of said composition.
- This procedure comprises the step of mixing the compound derived from aziridine, the combination of polyethylene waxes and paraffin waxes and a solution comprising one or more of the following components:
- a third object of the present invention relates to a laminate and/or reeled product printed with a decorative layer comprising a first cellulose-based and/or plastic material substrate, and at least a second associated substrate, and is characterized in that the second substrate comprises a synthetic material layer bonded by an adhesive that is irreversible to the first substrate, said second substrate covering partially or completely said first substrate, and in that the composition of the present invention according to different embodiments is applied on said first cellulose-based and/or plastic substrate .
- the manufacture of the laminate product comprises the steps of applying xerographically or by any other suitable method, for example, hollow engraving, flexography, stamping or inkjet, the composition of the present invention, according to different embodiments, on the first cellulose-based and/or plastic material substrate and the introduction of the product in a heat tunnel at a suitable temperature.
- the solvent used is water said temperature is between 80 and 160°C.
- a fourth object of the present invention relates to the use of the composition described herein to eliminate the phenomenon of tacking from the product, according to the third object of the invention, between the cellulose-based and/or plastic substrate and the substrate that covers it.
- compositions obtained in the examples are obtained by mixing the compound derived from aziridine, polyethylene waxes and paraffin waxes and a solution containing the other components. The mixtures are performed at room temperature.
- Example 16 polyethylene waxes and paraffin waxes 1.05%
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Laminated Bodies (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ESP201031649 | 2010-11-09 | ||
| ES201031649A ES2353293B1 (es) | 2010-11-09 | 2010-11-09 | Composición para el sector de las artes gráficas, procedimiento y utilización de la misma. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2012063157A1 true WO2012063157A1 (en) | 2012-05-18 |
Family
ID=43587009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/IB2011/054796 WO2012063157A1 (en) | 2010-11-09 | 2011-10-27 | A tack free decorative ink composition comprising an aziridine derivative and a polyethylene / paraffin wax mixture, process and use thereof |
Country Status (2)
| Country | Link |
|---|---|
| ES (1) | ES2353293B1 (es) |
| WO (1) | WO2012063157A1 (es) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449030A (zh) * | 2014-12-05 | 2015-03-25 | 徐州市华阳油墨化学有限公司 | 一种溶剂型凹印珠光油墨及其制备方法 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3926636A (en) * | 1972-08-29 | 1975-12-16 | Basf Ag | Photocurable compositions |
| EP0697295A2 (en) * | 1994-07-18 | 1996-02-21 | Toppan Printing Co., Ltd. | Printed decorative paper having a three dimensional pattern and a process for the production thereof |
| US5534049A (en) * | 1991-09-03 | 1996-07-09 | Girobank A?S | Flexographic printing ink |
| US20010031344A1 (en) | 1997-12-08 | 2001-10-18 | Nordeen Charles Kevin | Image transfer process for ink-jet generated images |
| WO2002062894A1 (en) | 2001-02-05 | 2002-08-15 | Avery Dennison Corporation | Topcoat compositions, substrates containing a topcoat derived therefrom, and methods of preparing the same |
| US20060019043A1 (en) | 2004-07-20 | 2006-01-26 | Kimberly-Clark Worldwide, Inc. | Heat transfer materials and method of use thereof |
| WO2008094863A1 (en) * | 2007-01-29 | 2008-08-07 | Sun Chemical Corporation | Lithographic printing ink |
| WO2008149067A1 (en) | 2007-06-04 | 2008-12-11 | Arjowiggins Licensing | Transfer sheet and method of manufacturing a transfer sheet |
| CN101717596A (zh) * | 2009-12-08 | 2010-06-02 | 杭华油墨化学有限公司 | 一种高附着力薄膜包装印刷用水性油墨及其制作方法 |
-
2010
- 2010-11-09 ES ES201031649A patent/ES2353293B1/es not_active Expired - Fee Related
-
2011
- 2011-10-27 WO PCT/IB2011/054796 patent/WO2012063157A1/en active Application Filing
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3926636A (en) * | 1972-08-29 | 1975-12-16 | Basf Ag | Photocurable compositions |
| US5534049A (en) * | 1991-09-03 | 1996-07-09 | Girobank A?S | Flexographic printing ink |
| EP0697295A2 (en) * | 1994-07-18 | 1996-02-21 | Toppan Printing Co., Ltd. | Printed decorative paper having a three dimensional pattern and a process for the production thereof |
| US20010031344A1 (en) | 1997-12-08 | 2001-10-18 | Nordeen Charles Kevin | Image transfer process for ink-jet generated images |
| WO2002062894A1 (en) | 2001-02-05 | 2002-08-15 | Avery Dennison Corporation | Topcoat compositions, substrates containing a topcoat derived therefrom, and methods of preparing the same |
| US20060019043A1 (en) | 2004-07-20 | 2006-01-26 | Kimberly-Clark Worldwide, Inc. | Heat transfer materials and method of use thereof |
| WO2008094863A1 (en) * | 2007-01-29 | 2008-08-07 | Sun Chemical Corporation | Lithographic printing ink |
| WO2008149067A1 (en) | 2007-06-04 | 2008-12-11 | Arjowiggins Licensing | Transfer sheet and method of manufacturing a transfer sheet |
| CN101717596A (zh) * | 2009-12-08 | 2010-06-02 | 杭华油墨化学有限公司 | 一种高附着力薄膜包装印刷用水性油墨及其制作方法 |
Non-Patent Citations (1)
| Title |
|---|
| DATABASE WPI Week 201046, Derwent World Patents Index; AN 2010-G97023, XP002669907 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449030A (zh) * | 2014-12-05 | 2015-03-25 | 徐州市华阳油墨化学有限公司 | 一种溶剂型凹印珠光油墨及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2353293A1 (es) | 2011-03-01 |
| ES2353293B1 (es) | 2012-01-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5070718B2 (ja) | インサート成形用加飾シート | |
| US8349427B2 (en) | Dye migration-resistant heat transfer label | |
| JP3271022B2 (ja) | 化粧シート | |
| CN103342920A (zh) | 一种表印固化哑光油墨及其制备方法 | |
| KR101391622B1 (ko) | 네일 스티커 및 그 제조방법 | |
| JP2008087303A (ja) | インサート成形用加飾シート | |
| CN103865418B (zh) | 一种无彩虹纹化学处理双向拉伸聚酯预涂膜及其制备方法 | |
| CN1986211A (zh) | 具保护膜层的转印标签 | |
| WO2012063157A1 (en) | A tack free decorative ink composition comprising an aziridine derivative and a polyethylene / paraffin wax mixture, process and use thereof | |
| KR102253038B1 (ko) | 개선된 블록킹 방지 특성을 갖는 발포 열전사 필름 | |
| NO176832B (no) | Flerlags, fleksibelt overföringsbånd, fremgangsmåte for fremstilling av dette samt anvendelse av overföringsbåndet | |
| JP2008110532A (ja) | 化粧シート及び化粧材 | |
| JP6815409B2 (ja) | 発泡性紙製品に用いる原材料シート及び発泡性紙製容器 | |
| DE69737697T2 (de) | Elektronisch gesteuert schneidbare mehrlagige filme für bilddarstellungen | |
| JP2010202735A (ja) | 粘着シート | |
| US20110297311A1 (en) | Film for the lamination of graphic media and production method thereof | |
| JP4601065B2 (ja) | 感圧修正テープ | |
| JP3131358U (ja) | 感圧修正テープ | |
| JPH06198830A (ja) | 化粧シ−ト | |
| JP2007331136A (ja) | 化粧シート | |
| WO2021011340A1 (en) | Coatings and primers for metallized films | |
| KR101078087B1 (ko) | 표지 및 그 제조방법 | |
| CN206800068U (zh) | 一种无纺纸喷绘耗材 | |
| KR100553276B1 (ko) | 은 나노를 함유한 탑 코팅된 열전사 필름 및 그 제조방법 | |
| CN207659372U (zh) | 一种可uv打印的软性墙贴 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 11784786 Country of ref document: EP Kind code of ref document: A1 |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 11784786 Country of ref document: EP Kind code of ref document: A1 |