WO2012043437A1 - Procédé de volatilisation chimique et volatilisateur chimique - Google Patents

Procédé de volatilisation chimique et volatilisateur chimique Download PDF

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Publication number
WO2012043437A1
WO2012043437A1 PCT/JP2011/071807 JP2011071807W WO2012043437A1 WO 2012043437 A1 WO2012043437 A1 WO 2012043437A1 JP 2011071807 W JP2011071807 W JP 2011071807W WO 2012043437 A1 WO2012043437 A1 WO 2012043437A1
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Prior art keywords
chemical
glycol
chemical solution
solvent
ether
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PCT/JP2011/071807
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English (en)
Japanese (ja)
Inventor
毅 村木
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小林製薬株式会社
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Publication of WO2012043437A1 publication Critical patent/WO2012043437A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/02—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air by heating or combustion
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon

Definitions

  • the present invention relates to a chemical solution transpiration method and a chemical solution transpiration device used for carrying out the method. More specifically, the present invention relates to a chemical liquid transpiration method and a chemical liquid evaporator that heat and evaporate a chemical liquid in the form of smoke (aerosol state).
  • various evaporators such as a natural evaporating type, a spray type, and a heating type are known as devices for evaporating a chemical solution such as a fragrance, a deodorant, and an insect repellent into an indoor space.
  • the chemical solution is evaporated in the indoor space by natural evaporation of the chemical solution, so that the amount of the chemical solution is small and the desired effect of the chemical solution may not be sufficiently achieved in the indoor space. Further, when the chemical solution is evaporated by natural evaporation, the desired effect of the chemical solution immediately disappears when the air in the indoor space is replaced. Therefore, there is a drawback in terms of durability of the effect of the chemical solution.
  • the chemical solution in the spray type evaporator, can be drifted in the space in an instant, but the effect is limited to the sprayed space part, and it is difficult to evaporate the chemical solution throughout the indoor space, The effect of the chemical solution is also temporary and has a drawback of low sustainability.
  • a heating type evaporator there is known an electric heating evaporator that electrically heats the chemical solution to actively evaporate the chemical solution and efficiently fills the indoor space with the chemical solution.
  • Most of the conventional heating-type evaporators evaporate in a state where the chemical solution cannot be visually recognized (that is, in a non-aerosol state).
  • the transpiration rate of the chemical solution is increased compared to the case of the natural transpiration type, but as with the case of the natural transpiration type, when the air in the indoor space is replaced, the chemical solution The desired effect of disappears.
  • a heating type evaporator such as a candle or an aroma pot is used to evaporate the chemical liquid in a smoke-like state that can be visually recognized (ie, in an aerosol state) using fire.
  • a heating type evaporator such as a candle or an aroma pot is used to evaporate the chemical liquid in a smoke-like state that can be visually recognized (ie, in an aerosol state) using fire.
  • chemicals are evaporated using fire in a room, there is a risk of causing a fire, which is not preferable from the viewpoint of safety.
  • Patent Document 1 a heating type transpiration device has been proposed in which a perfume oil impregnated with perfume oil is heated at a temperature higher than the boiling point of the perfume oil to evaporate the perfume oil in the form of smoke (steam).
  • Patent Document 1 benzine or ether is used as a solvent blended with the perfume oil, and when these solvents are heated at a temperature higher than the boiling point of the perfume oil, smoke-like transpiration may not actually be possible.
  • smoke-like perfume oil even if it evaporates in the form of smoke, there is a problem that the smoke-like perfume oil immediately disappears in the space and becomes invisible, and the sustainability of the effect of the chemical solution is insufficient.
  • the chemical solution can be evaporated into the indoor space in a visible state (ie, aerosol state), and the effect of the chemical solution remains even if the air in the indoor space is replaced. Therefore, there has been a demand for the development of chemical transpiration technology that can be performed continuously.
  • the problem of the present invention is to solve the above-mentioned problems of the prior art. Specifically, the present invention is capable of evaporating into the indoor space in a state where the chemical solution is smoked and visible (that is, in an aerosol state), and the effect of the chemical solution remains even if the air in the indoor space is replaced. It is an object of the present invention to provide a chemical liquid transpiration technique that can be performed continuously.
  • the present inventor has conducted intensive studies to solve the above problems, and can supply the chemical solution containing a solvent having a boiling point of 170 ° C. or higher to a heating element having a temperature of 100 ° C. or higher so that the chemical solution can be visually recognized. It was found that it can evaporate in the form of smoke (ie aerosol). Furthermore, when evaporated as an aerosol as described above, the chemical solution can be attached to the wall surface or article in the indoor space, and even if the air in the indoor space is replaced, the chemical solution attached to the wall surface or article etc. It was released into the space, and as a result, it was found that the sustainability of the effect of the chemical solution was also increased. The present invention has been completed by further studies based on this finding.
  • a chemical solution comprising: a chemical solution containing a solvent having a boiling point of 170 ° C. or higher; a heating element heated to a temperature of 100 ° C. or higher; and a chemical solution supply means capable of supplying the chemical solution to the heating element.
  • a chemical vaporizer that evaporates in the form of smoke.
  • Item 2. Item 2. The chemical vaporizer according to Item 1, wherein the solvent has a boiling point of 170 to 350 ° C, and the heating temperature of the heating element is 100 to 350 ° C.
  • Item 3. Item 3.
  • Item 4. The chemical solution transpiration according to any one of Items 1 to 3, wherein the chemical solution supply means is an impregnated body containing the chemical solution, and at least a part of the impregnated body is disposed in contact with the heating element. vessel.
  • Item 5. The chemical liquid evaporator according to any one of Items 1 to 4, wherein the solvent is at least one selected from the group consisting of alcohol solvents, glycol ether solvents, glycol solvents, and hydrocarbon solvents.
  • the solvent is at least one selected from the group consisting of alcohol solvents, glycol ether solvents, glycol solvents, and hydrocarbon solvents.
  • the solvent is 3-methoxy-3-methyl-1-butanol, benzyl alcohol, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, dipropylene glycol n-propyl ether, dipropylene glycol n-butyl ether, tripropylene glycol n.
  • Items 1 to 5 which is at least one selected from the group consisting of butyl ether, dipropylene glycol methyl ether acetate, propylene glycol phenyl ether, propylene glycol, ethylene glycol, hexylene glycol, dipropylene glycol, and diethylene glycol Chemical liquid evaporator.
  • Item 7. Item 7.
  • Item 8. The chemical liquid evaporator according to any one of Items 1 to 7, wherein a mixing ratio of the solvent contained in the chemical solution is 10 to 99.9% by weight.
  • Item 9 A chemical liquid transpiration method characterized in that a chemical liquid containing a solvent having a boiling point of 170 ° C. or higher is supplied to a heating element having a temperature of 100 ° C. or higher to evaporate the chemical liquid in a smoke form.
  • Item 11. The chemical liquid transpiration method according to Item 9 or 10, wherein the solvent is at least one selected from the group consisting of alcohol solvents, glycol ether solvents, glycol solvents, and hydrocarbon solvents.
  • the solvent is 3-methoxy-3-methyl-1-butanol, benzyl alcohol, dipropylene glycol monomethyl ether, tripropylene glycol monomethyl ether, dipropylene glycol n-propyl ether, dipropylene glycol n-butyl ether, tripropylene glycol n.
  • the chemical solution since the chemical solution is in an aerosol form and can be evaporated in the form of a visible smoke, the chemical solution can be efficiently distributed in the indoor space. Further, the chemical liquid evaporated by the present invention can maintain a smoke-like (aerosol-like) state that can be visually recognized in an indoor space, and is less likely to disappear in a visible state compared to normal steam or the like. Real feeling and satisfaction can be further enhanced.
  • the chemical liquid evaporated in the form of smoke can be attached to the wall surface or article of the indoor space, and even if the air in the indoor space is replaced, the chemical liquid adheres to the wall surface or the article. Since the obtained chemical solution is released again into the indoor space, the effect of the chemical solution is high and the convenience is further enhanced.
  • the smoke and aerosol forms mean a state in which a chemical solution is transpirated but is visually recognized as incense smoke.
  • the chemical liquid transpiration method of the present invention is characterized in that a chemical liquid containing a solvent having a boiling point of 170 ° C. or higher is supplied to a heating element having a temperature of 100 ° C. or higher to evaporate the chemical liquid in the form of smoke. To do.
  • the chemical liquid transpiration method of the present invention will be described in detail.
  • a chemical solution containing a solvent having a boiling point of 170 ° C. or higher is used.
  • the solvent to be blended in the chemical solution is not particularly limited as long as it has a boiling point of 170 ° C. or higher and can be used for transpiration into an indoor space, but the boiling point is preferably 170 to 350 ° C., more preferably Examples are those of 170 to 300 ° C, more preferably 170 to 250 ° C.
  • the solvent include alcohol solvents such as 3-methoxy-3-methyl-1-butanol (boiling point 174 ° C.) and benzyl alcohol (boiling point 205 ° C.); dipropylene glycol monomethyl ether (boiling point 190 ° C.), Tripropylene glycol monomethyl ether (boiling point 242 ° C), dipropylene glycol n-propyl ether (boiling point 212 ° C), dipropylene glycol n-butyl ether (boiling point 229 ° C), tripropylene glycol n-butyl ether (boiling point 274 ° C), dipropylene Glycol ether solvents such as glycol methyl ether acetate (boiling point 209 ° C.) and propylene glycol phenyl ether (boiling point 243 ° C.); propylene glycol (boiling point 178 ° C
  • glycol-based solvents are preferably used in order to enhance the ability to form smoke (aerosol).
  • these solvents may be used alone or in combination of two or more.
  • the blending ratio of the solvent is not particularly limited, but may be, for example, 10 to 99.9% by weight based on the total amount of the chemical solution.
  • the blending ratio of the solvent in the chemical liquid is preferably set to 25 to 99.9% by weight. .
  • the chemical solution used in the present invention has a function to be provided in the chemical solution, that is, a perfume and a deodorant depending on a desired function to be exhibited when the chemical solution is evaporated into the indoor space.
  • Pharmaceutical ingredients such as ingredients, insect repellent ingredients, antibacterial ingredients, and disinfectant ingredients are blended.
  • Such a drug component may be either oily or aqueous as long as it can be evaporated in the air in the environment in which it is used.
  • the chemical solution used in the present invention is an aromatic liquid when it contains a fragrance, as a deodorant liquid when it contains a deodorant component, and as an aroma deodorant liquid when it contains a fragrance and a deodorant component, When it contains an insect repellent component, it is used as an insect repellent solution, and when it contains an antibacterial component, it is used as an antibacterial solution.
  • the chemical liquid transpiration method of the present invention is suitable for evaporating a fragrance and imparting a fragrance effect to an indoor space.
  • the chemical liquid used in the present invention is preferably a fragrance containing a fragrance, a fragrance and a deodorant.
  • An aromatic deodorizing liquid containing components can be mentioned.
  • flavor may be sufficient, It is using the well-known fragrance
  • fragrances include aldehydes having 6 to 12 carbon atoms, anisaldehyde, acetal R, acetophenone, acetyl cedrene, adoxal, allyl amyl glycolate, allyl cyclohexane propionate, alpha damascon, ambrett lid, ambro Xanthine, amylcinnamic aldehyde, amylcinnamic aldehyde dimethyl acetal, amyl valericate, amyl salicylate, isoamyl acetate, acetyl eugenol, isoamyl salicylate, indole, ⁇ ionone, ⁇ ionone, ⁇ methyl ionone, ⁇ methyl ionone, ⁇ methyl ionone, indene, Ethyl vanillin, uranium thiol, oak moss No.
  • examples of the deodorant component to be blended in the chemical solution include plant extracts such as rice, pine, hinoki, persimmon and green tea; quaternary ammonium such as alkylbenzyldimethylammonium salt and didecyldimethylammonium salt.
  • Heterocyclic compounds such as cetylviridinium salts and benzoisothiazolines; Silver oxides, silver-containing water-soluble glasses, silver-supported zeolites, silver nanoparticles, silver ions, silver nitrate, silver sulfides and other silver compounds; oxidation Metal compounds such as zinc, copper oxide, zinc ions, copper ions and gold nanoparticles; inclusion compounds such as cyclodextrin and cyclophane; amphoteric compounds such as amphoteric surfactant deodorants and amino acid deodorants; silica gel And fine powders of adsorbents such as alumina, activated carbon and zeolite. These deodorant components may be used alone or in any combination of two or more.
  • insect repellent ingredients to be blended in the above chemical solution include DEET, pisabolol, isopine pinerin, bergabten, xanthotoxin, coxagin, dihydrocoxagine, dimethyl terephthalate, diethyl terephthalate, N, N-diethyl-m-toluamide, dimethyl phthalate , Dibutyl phthalate, p-menthane-3,8-diol, 2-ethyl-1,3-hexanediol, di-n-propylisocincomellonate, p-dichlorobenzene, di-n-butyl succinate, Examples include caran-3,4-diol, 1-methylpropyl-2- (2-hydroxyethyl) -1-piperidinecarboxylate, and allyl isothiocyanate.
  • terpene hydrocarbon fragrance flavor
  • terpene alcohol fragrance flavor
  • phenol fragrance flavor
  • flavor aldevid fragrance
  • insect repellent components may be used alone or in any combination of two or more.
  • antibacterial component blended in the chemical solution examples include octyltrimethylammonium chloride, didecyldimethylammonium gluconic acid, chlorhexidine, chlorhexidine gluconate, allyl isothiocyanate, propylene glycol monomethyl ether, propylene glycol monopropyl ether, and the like. . These antibacterial components may be used alone or in any combination of two or more.
  • These drug components may be used alone or in combination of two or more.
  • the blending ratio of the above-mentioned drug component is appropriately set according to the type of the component, and is, for example, 0.01 to 90% by weight, preferably 1 to 75% by weight. .
  • a solubilizer for pharmaceutical components such as water and ethanol; a nonionic surfactant (polyoxyethylene alkyl ether, poly Oxyethylene hydrogenated castor oil), anionic surfactants, amphoteric surfactants and other surfactants; 1,2-benzisothiazolin-3-one, 2n-octyl-isothiazolin-3-one and other antiseptics; antioxidants
  • a solubilizer for pharmaceutical components such as water and ethanol
  • a nonionic surfactant polyoxyethylene alkyl ether, poly Oxyethylene hydrogenated castor oil
  • anionic surfactants amphoteric surfactants and other surfactants
  • 1,2-benzisothiazolin-3-one 1,2-benzisothiazolin-3-one, 2n-octyl-isothiazolin-3-one and other antiseptics
  • antioxidants An ultraviolet absorber; a pigment such as a pigment or a dye; and an additive such as silicone may be contained in an appropriate amount
  • the chemical liquid can be supplied to the heating element using a chemical supply means capable of supplying the chemical liquid to the heating element.
  • the supply of the chemical liquid means that the chemical liquid is brought into contact with or close to the heating element in an air atmosphere (in the air in the indoor space).
  • the chemical liquid is preferably brought into contact with the heating element.
  • the chemical solution supply unit include an impregnated body, a droplet dropping unit, and a coating unit.
  • the impregnated material is not particularly limited as long as it is impregnated with a chemical solution and has heat resistance capable of withstanding heating by a heating element.
  • the material of the impregnated body include glass fiber and carbon fiber.
  • the heating element is preferably brought into contact with at least a part of the impregnated body.
  • the impregnated body may be impregnated with a predetermined amount of the above chemical solution in advance, and as shown in FIG. 2, the chemical solution can be sucked up by a capillary phenomenon from a container containing the chemical solution.
  • the chemical solution may be continuously supplied to the impregnated body portion in contact with the heating element.
  • the droplet dropping means is not particularly limited as long as it can drop a chemical on the heating element.
  • the application means is not particularly limited as long as it can apply a chemical solution on the heating element.
  • the heating element used for heating the chemical solution may be any heating element that can be heated to a predetermined temperature, but an electric heating element that generates heat when energized is preferably used.
  • Examples of such an electric heating body include a heating wire, a PTC heater, a ceramic heater, and a fixed resistance heater. When power is applied in a battery type, a heating wire is preferable from the viewpoint of power consumption.
  • the chemical solution supplied by the chemical solution supply means is heated by a heating element at 100 ° C. or higher in an atmospheric atmosphere (that is, in the air in the indoor space), thereby allowing the impregnation body and the heating element to contact or In the impregnated body portion close to the heating element, the chemical solution forms an aerosol, which can be evaporated in a visible smoke-like form.
  • the temperature of the heating element is not particularly limited as long as it is 100 ° C. or higher. However, from the viewpoint of improving the ability to form smoke while providing indoor use safety, 100 to 350 ° C. Preferably, the temperature is 120 to 310 ° C., and further considering the safety of use, the temperature is preferably 120 to 250 ° C.
  • one heating element when an impregnated body is used as the chemical liquid supply means, one heating element may be brought into contact with or close to one impregnated body impregnated with the chemical liquid, but the amount of smoke-like chemical liquid transpiration is increased. For this reason, two or more heating elements may be brought into contact or close to each other.
  • the chemical vaporizer of the present invention is used for carrying out the above chemical vaporization method. Specifically, the chemical vaporizer is heated to a chemical liquid containing a solvent having a boiling point of 170 ° C. or higher and a temperature of 100 ° C. or higher. And a chemical liquid supply means capable of supplying the chemical liquid to the heat generating element.
  • the chemical vaporizer of the present invention is configured such that an impregnated body 1 impregnated with a chemical liquid is held by a support 3, and the heating element 2 is in contact with the impregnated body 3. May be.
  • the impregnated body impregnated with the chemical liquid or the support body holding the impregnated body is removable, and the impregnated body impregnated with the chemical liquid or the impregnated body is retained after use. You may be comprised so that the support body which was made can be replaced
  • a container 4 containing a chemical liquid 5 is provided, and the impregnated body 1 can suck up the chemical liquid 5 contained in the container.
  • the impregnated body 1 may be fixed to the container 4 by the support 3 and held, and the heating element 2 may be in contact with the impregnated body 1.
  • the heating element 2 is described as an example of a heating wire.
  • the heating element is not limited to the heating wire.
  • the chemical vaporizer of the present invention includes means for generating heat from the heating element, that is, a conductive wire for conducting the heating element, and voltage applying means for applying power to the heating element. May be.
  • Aroma liquids shown in Table 1-2 were prepared. About 0.5 g of this aromatic liquid was impregnated into a cylindrical impregnated body (outer diameter 5 mm, height 10 mm) made of glass fiber. Next, the impregnated body impregnated with the aromatic liquid is a evaporator having the same mechanism as in FIG. 1 (a heating element is a 6.5 ⁇ heating wire, a voltage applying means is a constant voltage power source, and a temperature of the heating element is controlled by adjusting an applied voltage.
  • a heating element is a 6.5 ⁇ heating wire
  • a voltage applying means is a constant voltage power source
  • a temperature of the heating element is controlled by adjusting an applied voltage.
  • the evaporator used for transpiration of aromatic liquid in Table 1 has a structure in which two heating wires are in contact with one impregnated body, and the evaporator used for transpiration of aromatic liquid in Table 2 is one impregnated body. 1), and the side surface of the impregnated body and the heating element of the evaporator are brought into contact with each other. This was placed in a 30 cm 3 sealable box, the box was sealed, the power was turned on, and the heating element was heated to a predetermined temperature. The state where the power was turned on was held for 30 seconds, and the transpiration state of the aromatic liquid was observed to examine the presence or absence of generation of soot (aerosol).
  • the heating temperature of the heating element was set to 100 ° C. for the aromatic liquids of Example 1-3 and Reference Example 1-2, and 150 ° C. for the aromatic liquids of Example 4-6 and Reference Example 3-4.
  • Test example 2 About 0.5 g of the solvent shown in Table 3 was impregnated into a cylindrical impregnated body (outer diameter 5 mm, height 10 mm) made of glass fiber. Next, using an impregnated body impregnated with a solvent, as in Test Example 1 above, a evaporator (a heating element is a 6.5 ⁇ heating wire, a voltage applying means is a constant voltage power source, and a temperature of the heating element is an adjustment of an applied voltage) In addition, this evaporation device is equipped with a structure in which one heating wire is brought into contact with one impregnated body), and the presence / absence of smoke generation and the smoke disappearance time were measured. The heating temperature of the heating element was set to the temperature described in Table 3.
  • Test example 3 Aroma and transpiration type evaporators (Example 7-8, Comparative Example 1-3) shown in Table 4 were prepared. Using an aromatic liquid evaporator, the aromatic liquid was evaporated in a 30 cm 3 volume sealable box by the evaporation method shown in Table 4. In addition, the usage-amount of aromatic liquid was adjusted so that the intensity
  • Table 5 shows the obtained results. From this result, in any fragrance, immediately after the transpiration, a certain amount of aroma was noticed in the box. On the other hand, with respect to the cloth after being allowed to stand for one hour from the transpiration of the fragrance, almost no aroma was felt in Comparative Example 1-3, but in Example 7-8, the cloth was scented. That is, it has been clarified from the results that the aromatic liquid has a function of perfume the box wall or the article in the box by evaporating the aromatic liquid in the form of smoke.

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  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Catching Or Destruction (AREA)

Abstract

[Problème] La présente invention concerne une technique de volatilisation chimique capable de volatiliser une substance chimique visiblement en fumée (c'est-à-dire, transformée en aérosol) dans des espaces intérieurs, et permettant à l'effet de la substance chimique de durer plus longtemps, même exposée à la ventilation de l'air dans les espaces intérieurs. [Solution] La présente invention est capable de volatiliser une substance chimique visiblement en fumée (c'est-à-dire, transformée en aérosol) en fournissant une unité de chauffage ayant une température de 100 °C ou plus avec le solvant contenant une substance chimique dont le point d'ébullition est de 170 ºC ou plus.
PCT/JP2011/071807 2010-09-30 2011-09-26 Procédé de volatilisation chimique et volatilisateur chimique WO2012043437A1 (fr)

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JP2010223314A JP5660834B2 (ja) 2010-09-30 2010-09-30 薬液蒸散方法及び薬液蒸散器

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EP4079157A4 (fr) * 2020-01-06 2023-08-16 Fumakilla Limited Agent de stérilisation d'espace à usage intérieur et appareil de stérilisation d'espace à usage intérieur

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JP2015204850A (ja) * 2012-08-28 2015-11-19 株式会社クラレ 芳香剤組成物
JP6862098B2 (ja) * 2016-03-31 2021-04-21 小林製薬株式会社 液状発煙性蒸散剤、及びその使用方法
JP6850668B2 (ja) * 2017-04-25 2021-03-31 ライオン株式会社 燻煙剤組成物
KR102332586B1 (ko) * 2021-06-25 2021-12-01 박지훈 차량용 연무장치

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JPH0543412A (ja) * 1991-08-19 1993-02-23 Earth Chem Corp Ltd 吸液芯用殺虫剤組成物
JP2005537918A (ja) * 2002-09-06 2005-12-15 クリサリス テクノロジーズ インコーポレイテッド エアロゾル発生装置およびその使用方法
JP2009232915A (ja) * 2008-03-26 2009-10-15 Dainippon Jochugiku Co Ltd 水性消臭剤組成物の加熱蒸散方法

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Publication number Priority date Publication date Assignee Title
EP4079157A4 (fr) * 2020-01-06 2023-08-16 Fumakilla Limited Agent de stérilisation d'espace à usage intérieur et appareil de stérilisation d'espace à usage intérieur

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