WO2012006861A1 - 一种微颗粒捕获装置及应用该装置的微颗粒输运设备 - Google Patents
一种微颗粒捕获装置及应用该装置的微颗粒输运设备 Download PDFInfo
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- WO2012006861A1 WO2012006861A1 PCT/CN2011/000439 CN2011000439W WO2012006861A1 WO 2012006861 A1 WO2012006861 A1 WO 2012006861A1 CN 2011000439 W CN2011000439 W CN 2011000439W WO 2012006861 A1 WO2012006861 A1 WO 2012006861A1
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- Prior art keywords
- base
- microparticle
- nozzle
- core
- microparticles
- Prior art date
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- XDTMQSROBMDMFD-UHFFFAOYSA-N C1CCCCC1 Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B25—HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
- B25J—MANIPULATORS; CHAMBERS PROVIDED WITH MANIPULATION DEVICES
- B25J9/00—Programme-controlled manipulators
- B25J9/10—Programme-controlled manipulators characterised by positioning means for manipulator elements
- B25J9/104—Programme-controlled manipulators characterised by positioning means for manipulator elements with cables, chains or ribbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B25—HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
- B25J—MANIPULATORS; CHAMBERS PROVIDED WITH MANIPULATION DEVICES
- B25J15/00—Gripping heads and other end effectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B25—HAND TOOLS; PORTABLE POWER-DRIVEN TOOLS; MANIPULATORS
- B25J—MANIPULATORS; CHAMBERS PROVIDED WITH MANIPULATION DEVICES
- B25J11/00—Manipulators not otherwise provided for
Definitions
- Microparticle capture device and microparticle transport device using the same
- the present invention relates to a microparticle capture device, and a microparticle transport device to which the capture device is applied.
- micro-manufacturing technology and its products have developed rapidly in the past decade.
- countries such as the United States, Japan, and Germany have placed micro-manufacturing in a relatively high position, and as one of the mainstream of manufacturing science, the development of micro-manufacturing technology and industry is a breakthrough for China's leap into high technology.
- Stacking is an important concept in the field of microfabrication. By controlling the microparticles, stacking can stack or assemble the required 2D or 3D microstructures and components “bottom up". Among them, the smooth capture, directional transport and precise positioning of microparticles are one of the key technologies and important foundations of "stacking forming”. Therefore, how to realize the capture and manipulation of microparticles has become a research hotspot and difficulty in the field of microfabrication.
- Optical Tweezers is the most representative method to achieve microparticle capture and manipulation.
- the so-called “optical” is a three-dimensional gradient optical potential well formed by the mechanical effect of momentum transfer between light and matter.
- Bell Labs Ashkin introduced a single-beam laser into a high-aperture objective lens to form a three-dimensional optical potential well, which proved that it can achieve sub-contact and non-destructive operation of the trap without affecting the surrounding environment. And it is called "light”.
- the "single” has evolved from the original single-beam gradient force trap to different types of optical potential wells such as two-beam, three-beam, four-beam, array stop, beam workstation and holographic diaphragm. Provides clever and effective tools for microfabrication research based on microparticle capture and manipulation.
- TACT non-contact three-axis atomic force microscopy
- dielectrophoresis to manipulate nanomaterials in aqueous media. They applied RF voltage to the TACT tip and inner casing. The housing is grounded and the tip is designed to allow the electric field to escape and create a zero electric field outside the surface. Since the dielectric constant of water is larger than most materials, water pushes the nanoparticles toward the minimum value of the electric field. Since the area around the tip is a repulsive area, it is ensured that only one particle is captured at a time.
- the first technical problem to be solved by the present invention is to provide a microparticle trapping device which is simple in structure, low in manufacturing cost, and easy to implement in view of the above state of the art.
- a second technical problem to be solved by the present invention is to provide a microparticle transporting apparatus using the above microparticle capturing device, which is simple in structure, low in manufacturing cost, and easy to provide for the above-mentioned prior art. achieve.
- a microparticle capturing device characterized in that: the microparticle capturing device comprises a microjet nozzle, a voltage regulator and the microjet nozzle
- the micro-jet nozzle is provided with an annular spray chamber extending in the axial direction, the inner diameter of the annular spray chamber is matched with the diameter of the microparticles to be captured, and the top end of the annular spray chamber is provided with an entrance port.
- the bottom of the annular spray chamber is provided with an injection port, and an input end of the voltage regulator is connected to an outlet of the hydraulic device, and an output end of the voltage regulator and an incident surface of the microjet nozzle The mouth is connected.
- the following relationship is satisfied between the inner diameter of the annular spray chamber and the diameter of the microparticles: w -10 ym W pi cp w , where ⁇ ⁇ denotes the inner diameter of the annular spray chamber, 0) w denotes the diameter of the microparticles, and the units of the ⁇ ⁇ ⁇ and 0) w are ⁇ ⁇ .
- the micro-jet nozzle includes a nozzle housing and a nozzle core, and the nozzle housing has a through hole extending through the axial direction, and the nozzle core includes a core and a core.
- the core is fixedly connected to the top of the nozzle housing, the core is inserted into the through hole, and the ring is formed between the inner wall of the through hole of the nozzle housing and the core of the nozzle core a spray chamber, and a liquid inlet hole corresponding to the incident port is opened on the core of the shower head core.
- the nozzle core has a cross-sectional shape cut along a central axis, and the liquid inlet holes are a plurality of through holes that are circumferentially spaced apart along a core of the nozzle core.
- the dome-shaped nozzle core can be easily inserted into different nozzle housings, and the top of the dome can facilitate the connection with the core.
- the plurality of inlet holes distributed along the circumference of the nozzle core can increase the amount of liquid and accelerate the liquid inlet. speed.
- the hydraulic device may employ various hydraulic systems of the prior art, preferably may have the following structure: including a plunger capable of generating hydraulic oil a pump, a motor for driving the plunger pump, and a supercharger capable of realizing the suction and discharge of the injection liquid, wherein the hydraulic oil passage is connected between the supercharger and the plunger pump through a directional control valve .
- a microparticle transporting device which is characterized by:
- a table disposed on the base and capable of linearly moving along a length and a width direction of the base; a container containing microparticles fixedly disposed on the table, and a microjet disposed above the container Nozzle
- the bracket is mounted with a bracket capable of linearly moving in a vertical direction and extending perpendicularly to the support, one end of the bracket and the microjet nozzle
- the regulators are fixedly connected.
- the table includes a first base and a second base, and further includes a first motor and a second a first rail disposed along the length direction, the first base being linearly movable along the first rail by the first motor, the first base A second guide rail disposed along a width direction of the base is provided, and the second base is linearly movable along the second guide rail by the second motor.
- the side surface of the first rail is provided with a first grating scale for tracking and feeding back the moving position of the first base.
- a side of the second rail is provided with a second grating that tracks and feeds back the position of the second base.
- the first base and the second base moving stroke are prevented from slipping off the rail.
- the base is further provided with a movement limit for the first base.
- the first anti-collision device is provided with a second anti-collision device for restricting the movement of the second base.
- the first motor and the second The motor is a linear motor.
- the invention has the advantages that: a liquid is used as a medium, and a micro-jet nozzle having an annular spray chamber is used to generate a force capable of supporting the microparticles upward and a direction perpendicular to the jet of the microparticles.
- the flow around the lift, the upward support force and the flow lift generated by the liquid act on the microparticles in a week, and have a "clamping" effect on the microparticles, which will be firmly clamped to the microjet nozzle like a scorpion.
- microparticles below which enable the capture of microparticles, are a new means and means of capturing microparticles; in addition, the microparticle capture device is microparticle-captured compared to conventional laser, RF voltage and plasma.
- the device is easier to implement and manufacture, and the device of the present invention can be built and operated in an ordinary daily life environment, does not require a specific application environment, greatly reduces the implementation cost of the capture device, and facilitates the popularization and use of the capture device. Expanded the application and Field.
- FIG. 1 is a schematic view showing the structure of a microparticle capturing device of the present invention.
- FIG. 2 is a schematic view showing the operation of the microparticle trapping device of the present invention.
- Fig. -3 is a partial enlarged view of the portion I shown in Fig. 2 (the principle of microparticle force).
- Figure 4 is a cross-sectional view showing the structure of the microjet head of the present invention.
- Fig. 5 is a schematic view showing the variation and characteristics of the flow velocity of the boundary layer of the microfluid according to the present invention.
- Figure 6 is a roadmap of the microparticle capture technology of the present invention.
- Fig. 7 is a schematic view showing the structure of a microparticle transporting apparatus to which the microparticle capturing device of the present invention is applied.
- Figure 8 is a schematic view showing the structure of the feed system of the microparticle transporting device shown in Figure 7.
- Figure 9 is a cross-sectional view showing the structure of the container in the microparticle transporting apparatus shown in Figure 7.
- FIG. 10 is a schematic view showing the structure of the microparticle transport process of the present invention. detailed description
- FIG. 6 is a schematic structural view and a working principle diagram of the microparticle capturing device of the present embodiment
- the microparticle capturing device includes a microjet nozzle 1 and a hydraulic device capable of providing a jetting liquid for the microjet nozzle 1.
- the spray liquid may be water, or other fluid medium capable of causing the fine particles to float on the surface of the liquid.
- pure water containing no impurities is selected as the spray liquid.
- the micro-jet nozzle 1 includes a nozzle housing 11 and a nozzle core 12.
- the nozzle housing 11 has a through hole extending through the axial direction.
- the nozzle core 12 has a T-shaped cross section along the central axis.
- the nozzle core 12 includes The core 121 and the core 122, and the core 121 is fixedly connected to the top of the nozzle housing 11 by bolts or screws, and the core 122 is inserted into the through hole of the nozzle housing 11, and the inner wall of the through hole of the nozzle housing 11 and the nozzle
- An annular spray chamber 13 penetrating in the axial direction is formed between the cores 122 of the core 12, and a plurality of liquid inlet holes 121a communicating with the entrance opening 131 of the annular spray chamber 13 are circumferentially spaced apart from the core head 121.
- the through hole of the nozzle housing 11 may preferably be a stepped hole, the large diameter portion 111 of the stepped hole is opposed to the entrance opening 131 of the core, and the small diameter portion 112 of the stepped hole is The ejection port 132 is opposed to the microparticles 9.
- a voltage regulator 2 must be provided between the microjet nozzle 1 and the hydraulic device 3.
- the input of the regulator 2 is connected to the discharge line of the hydraulic device 3, and the output of the regulator 2 passes through the core 121.
- the inlet hole 121a is connected to the inlet port 131 of the annular spray chamber 13.
- the hydraulic device 3 used in this embodiment may be various hydraulic systems in the prior art.
- the hydraulic device 3 includes a plunger pump 31 and a motor 32 that drives the plunger pump 31 to operate. And a supercharger 33 capable of inhaling and discharging the injection liquid, wherein the supercharger 33 is connected to the water inlet pipe 331 and the water outlet pipe 332, and the supercharger 33 and the plunger pump 31 are connected by the hydraulic oil passage 35,
- a directional control valve 34 is mounted on the hydraulic oil passage 35. The hydraulic oil is alternately introduced into the pistons of the supercharger 33 through the directional control valve 34.
- the direction control width 34 is controlled by the PLC electrical control system 36 through the control circuit.
- the adjustment of the pressure range is to control the shape of the output microfluid 14.
- the PLC electrical control method is prior art, and will not be described in detail in this embodiment.
- the motor 32 drives the plunger pump 31 to output hydraulic oil to alternately enter the two sides of the piston in the supercharger 33 along the hydraulic oil passage 35, thereby driving the piston to reciprocate, thereby achieving alternately inhaling water flow on both sides of the supercharger 33,
- the liquid water enters the annular spray chamber 13 through the liquid inlet hole 121a of the core 121, and is ejected from the injection port 132 to finally form the microjet 14.
- the spherical coordinate system is used to analyze the jet distribution and pressure change of the liquid-solid boundary layer, and a vertical plane is taken.
- the micro-particles are orthogonal to the micro-particles at the largest section of the micro-particles, and a circular section plane is obtained, and the micro-jet 14 is used.
- the first intersection A of the microparticle surface 93 is the coordinate origin, and the intersection line is selected along the microparticle surface 93 as the X axis, the direction is downward, and the Y axis is perpendicular to the microparticle surface 93.
- point A to point C is the step-down acceleration section (i.e., ⁇ G ), in this section, although viscous
- ⁇ G step-down acceleration section
- the force causes the loss of fluid kinetic energy, but because part of the pressure energy of the fluid is converted into the kinetic energy of the fluid, this loss can be compensated, so that the fluid still has enough kinetic energy to continue to advance
- the action also continues to consume kinetic energy, so the fluid velocity reduction process is accelerated, and the boundary layer is continuously thickened; when the fluid flows to a certain point D of the microparticle surface 93, the kinetic energy of the fluid micelle near the surface is exhausted.
- the fluid micelles at this point are stagnant, and point D is referred to as the separation point.
- the boundary layer fluid characteristics of the microparticle surface 93 are shown in Table 1. Boundary layer fluid properties of microparticle surfaces
- the boundary layer of the microparticle surface 93 is a layer of viscous flow which appears on the solid surface upon liquid-solid contact, and when the microjet 14 is in contact with the microparticle surface 93, the fluid micelles in the boundary layer Blocked by viscous forces, consuming kinetic energy.
- the boundary layer corresponding to the surface of the microparticles 93 from point A to point C is in a state of a gradient gradient, so that the force along the flow direction of the boundary layer helps to overcome the shear stress of the surface 93 of the microparticles, and the boundary layer
- the flow of the internal fluid has a speed increasing effect, which weakens the growth rate of the boundary layer thickness, and the thickness of the boundary layer increases little.
- the fluid micelles in the boundary layer of the second half of the microparticles will be more retarded, causing some of the fluid micelles to be forced to flow in the opposite direction, forcing the boundary layer to continue to leave the surface 93 of the microparticles.
- the microjet 14 is caused to form a symmetric vortex 141 (also referred to as a swirling flow) in the lower portion of the microparticle, and the symmetric vortex 141 is in the lower portion of the microparticle to support the microparticle, see FIG.
- the force of the micro-jet 14 acting on the micro-particles also has a traveling lift 92 perpendicular to the direction of the jet. The force of the micro-particles is as shown in FIG.
- the boundary layer is generated from the leading edge of the microparticles and proceeds rearward along the surface 93 of the microparticles.
- the boundary layer will The surface of the microparticles 93 is separated, forcing a reverse flow of fluid between the surface 93 of the microparticles and the boundary layer, and induces a symmetrical vortex 141 (cyclotron flow) in the lower portion of the microparticle, thereby forming an upward supporting force 91 to the microparticle; Jet 14 due to micro The hindrance of the particles will form a flow lift 92 perpendicular to the jet direction of the microparticles; thus, the support force 91 of the symmetric vortex 141 (cyclotron flow) and the bypass lift 92 act on the microparticles, thereby generating a micro-particle
- the singularity method is used to calculate the condition that the microjet 14 forms a "water raft".
- the flow function of the synthetic flow field should be the flow function of the jet and the flow function ⁇ ⁇ of the dipole, ie: 4 ⁇ 2 4 ⁇ )
- ⁇ 0, the streamline (face) is zero streamline (face), and equation (1) becomes:
- equation (3) the first equation is a spherical equation, written in the standard form:
- the intensity of the dipole must be:
- ⁇ COS0 (7)
- ⁇ is the flow function
- ⁇ is the velocity potential function
- V is the jet velocity
- ⁇ is the microparticle half Path
- M is the intensity of the spatial dipole
- 0 is the angle between the line connecting the point and the dipole in the flow field and the positive direction of the Z axis
- ? is the point between the point and the dipole in the flow field distance.
- the position of the D point of the separation point can also be obtained by calculation.
- the speed of any point in the flow field is:
- the flow velocity and pressure of the microjet 14 at the surface 93 of the microparticles can be controlled, and the position of the separation point D can be controlled, so that the microjet 14 can form a symmetric vortex 141 in the lower portion of the microparticle. (Swiveling flow), support for the microparticles 9 and pliers production.
- the microfluidic flow 14 is generated by the hydraulic device 3 through the microjet nozzle 1.
- a "water raft” is formed on the surface of the microparticles 9, and by visual control, the leeches can be "Parameter optimization (such as adjusting the jet velocity, microparticle radius, micro-jet nozzle 1 inner diameter and other parameters) to form a stable "water raft", and then using the "water raft” to capture and manipulate the micro-particles 9.
- the microparticles 9 are plastic fluorescent particles that are insoluble in water and can float above the water surface.
- the purpose of the microparticles 9 to select fluorescent particles is to facilitate visual tracking and image capture.
- the inner diameter of the water bundle is matched with the diameter of the microparticle 9, that is, the relationship between the inner diameter of the annular spray chamber 13 of the microjet nozzle 1 and the diameter of the microparticle 9 is satisfied.
- the microjet 14 is blocked by the microparticles 9, generating a flow lift 92 perpendicular to the flow direction of the jet;
- support force 91 and the bypass lift 92 directly act on the micro-particles 9, clamp the micro-particles like a scorpion, and form a "water raft";
- microparticles 9 are wrapped in the interior of the hollow microjet 14 under the action of the resultant force, and when the upward force is balanced with the gravity of the microparticles 9 themselves, the microparticles 9 stay at a certain position inside the water bundle, and then The capture of the microparticles 9 by the "water raft" can be achieved.
- the microparticles 9 are subjected to the inward traveling lift 92, and the microparticles 9 are also subjected to the upward symmetric vortex 141 (swirl flow) supporting force 91. Since the micro-particles 9 are light and the supporting force 91 is larger than the self-gravity, the resultant force of the micro-particles 9 is inward and upward. In the environment of the micro-jet 14, the symmetric vortex 141 (swirl flow) and the differential pressure are combined to form.
- the present embodiment proposes a new device and method for capturing microparticles 9 " ⁇ "Water raft", “water raft” is easier and simpler to implement, and is advantageous for popularization and application, and realizes microparticles in the field of microfabrication.
- the "stacking formation” of 9 provides a new type of technical means with important theoretical significance and potential application value.
- the microparticle transporting device includes
- the workbench includes a first base 51 and a second base 52, and further includes a first motor and a second motor, and the base 4 is provided with a first rail 511 arranged along the length direction (X-axis), the first base
- the seat 51 is linearly movable along the first rail 511 under the driving of the first motor
- the first base 51 is provided with a second rail 521 disposed along the width direction (Y-axis) of the base 4
- the second base 52 is
- the second motor is linearly movable along the second rail 521, wherein the first motor and the second motor are linear motors, and the side of the first rail 511 is provided with tracking and feedback of the moving position of the first base 51.
- the first grating scale 512, the side surface of the second rail 521 is provided with a second grating scale 522 for tracking and feeding back the moving position of the second base 52, and the base 4 is further provided with a first anti-theft preventing the movement of the first base 51 Collision device 513, the first base 51 is provided with a second anti-collision device 523 that limits the movement of the second base 52;
- the container 6 is provided with micro-particles 9, and the bottom of the container 6 has a fixing device.
- the fixing device can be fixedly disposed on the second base 52 of the table by bolts, so that the container 6 can be fixed on the workbench.
- the micro-jet nozzle 1 is disposed above the container 6, and the container 6 is further provided with a micro-particle accommodating case 62 for forming the micro-particles 9 for forming, see FIG.
- the support 7 is disposed perpendicular to the base 4, and the support 7 is mounted with a bracket 8 which is linearly movable in the vertical direction (Z-axis) and extends perpendicularly to the support 7.
- the bracket 8 is driven by the third motor to be lifted and lowered.
- One end of the bracket 8 is fixedly coupled to the regulator 2 provided on the microjet head 1, and when the carriage 8 is moved along the holder 7, the microjet head 1 can adjust the ejection height in the vertical direction.
- the microparticle transporting device in this embodiment mainly comprises a microjet nozzle 1 and a high precision feeding system, and the microjet nozzle 1 generates a microjet 14 by the hydraulic device 3, and the high precision feeding system is used to realize the microparticles.
- the movement of the container 6 of 9 in the horizontal plane enables the micro-jet nozzle 1 to always align with the micro-particles 9 in the container 6; wherein the high-precision feed system is driven by a linear motor, enabling work in the X-axis and Y-axis directions
- the movement of the table and the lifting and lowering of the bracket 8 in the Z-axis direction ensure that the linear motor can have extremely low thrust ripple at low speed and high speed to ensure uniform speed performance and precise positioning performance, regardless of the direction of motion.
- the linear motor in this embodiment has a positioning accuracy of ⁇ 2 ⁇ ⁇ , the repeating positioning accuracy is 1 ⁇ ⁇ , the maximum speed is lm/s, and the acceleration is lm/ s 2 ;
- the first scale 512 mounted on the first rail 511 can track the movement of the first base 51 and feed back the position of the first base 51, and the first collision avoidance device 513 can implement the first base
- the stroke control of 51; the second scale 522 mounted on the second rail 521 can track the movement of the second base 52 and feed back the position of the second base 52, and the second collision avoidance device 523 can achieve The stroke control of the second base 52;
- the bracket 8 moving in the vertical direction can also be provided with a third scale and a third anti-collision device to detect and feedback the position of the bracket 8 on the support 7 and to limit the support of the bracket 8. Lifting trip.
- the table stroke (in the X-axis and the Y-axis, respectively) of this embodiment is 500 mm x 400 mm, and the stroke of the bracket 8 in the vertical direction (Z-axis) is 100 mm to 200 mm;
- the table when working, the table is moved and the height of the bracket 8 is adjusted so that the microjet nozzle 1 is sprayed against the microparticles 9 in the container 6, and when the "water sputum" generated by the microjet nozzle 1 clamps the microparticles 9, again The table is moved so that the clamped microparticles 9 can be moved into the microparticle accommodating case, thereby completing the transport of the primary granules 9 once.
- the present embodiment utilizes the boundary layer fluid property of the surface of the microparticle to realize a "water raft" capable of clamping the microparticles 9, and the leeches enclose the microparticles 9 inside to realize the capture of the microparticles 9 when the water
- the center position of the microjet 14 deviates from the center of the captured microparticles 9, and a pressure difference between the microparticles 9 is formed around the microparticles 9, and the microparticles 9 are moved under the action of the pressure difference to realize the transport of the microparticles 9. And manipulation.
- the microparticle capture device of the present embodiment can realize the "water raft" effect under ordinary experimental conditions, is simple and practical, and is easier to implement and operate, and not only provides a novel microparticle operation mode, but also performs in the microfabrication field. Stacking of microparticles provides new ideas and methods.
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Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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US13/807,490 US9067323B2 (en) | 2010-07-12 | 2011-03-18 | Device used for capturing micro-particles and a micro-particles transporting equipment provided with the device thereof |
JP2013513520A JP5345747B2 (ja) | 2010-07-12 | 2011-03-18 | 微粒子捕集装置及び当該装置を用いた微粒子輸送設備 |
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CN201010228289.4 | 2010-07-12 | ||
CN201010228289 | 2010-07-12 |
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WO2012006861A1 true WO2012006861A1 (zh) | 2012-01-19 |
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US (1) | US9067323B2 (zh) |
JP (1) | JP5345747B2 (zh) |
CN (1) | CN102180442B (zh) |
WO (1) | WO2012006861A1 (zh) |
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CN103418847B (zh) * | 2013-07-31 | 2015-07-15 | 宁波工程学院 | 一种切削装置 |
CN105818383B (zh) * | 2016-04-19 | 2017-12-26 | 西安交通大学 | 一种基于全息光镊的超材料光固化3d打印方法 |
CN114509311B (zh) * | 2022-04-20 | 2022-08-23 | 浙江大学 | 一种悬浮光镊高效捕获气溶胶的装置及其应用方法 |
CN115290385B (zh) * | 2022-08-02 | 2023-09-08 | 中国矿业大学 | 一种应用有微颗粒捕获装置的微颗粒输运设备 |
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- 2011-03-18 WO PCT/CN2011/000439 patent/WO2012006861A1/zh active Application Filing
- 2011-03-18 US US13/807,490 patent/US9067323B2/en active Active
- 2011-03-18 JP JP2013513520A patent/JP5345747B2/ja active Active
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US20130101378A1 (en) | 2013-04-25 |
JP2013538697A (ja) | 2013-10-17 |
CN102180442B (zh) | 2013-07-31 |
JP5345747B2 (ja) | 2013-11-20 |
CN102180442A (zh) | 2011-09-14 |
US9067323B2 (en) | 2015-06-30 |
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